Agnès MINGOT

Publications

Article dans une revue (49)

Regulating the Acidity of HF/Pyridine Media to Control the Chemodivergent Fluoro- and Hydro-Heteroalkylation of Olefins Mélissa Longuet,Fabien Naullet,Alexandre Pérochon,Agnès Martin-Mingot,Frédéric Guéganet al. Journal of the American Chemical Society, 2025, 147 (32), pp.29079-29087. ⟨10.1021/jacs.5c07526⟩ Article dans une revue hal-05221813v1
Activation of N-containing olefins and alkynes with superacids Delphine Pichon-Barré,Hélène Carreyre,Frédéric Lecornué,Agnès Martin-Mingot,Bastien Micheletet al. Comptes Rendus. Chimie, 2025, 28, pp.727-754. ⟨10.5802/crchim.416⟩ Article dans une revue (compte-rendu de lecture) hal-05321953v1
Determination of the Hammett Acidity of HF/Base Reagents Mélissa Longuet,Kassandra Vitse,Agnès Martin-Mingot,Bastien Michelet,Frédéric Guéganet al. Journal of the American Chemical Society, 2024, ⟨10.1021/jacs.4c02344⟩ Article dans une revue (article de synthèse) hal-04552304v1
Glycosylium Ions in Superacid Mimic the Transition State of Enzyme Reactions Mathilde Armand,Alba Nin-Hill,Ana Ardá,Emanuela Berrino,Jérôme Désiréet al. Journal of the American Chemical Society, 2024, 146 (47), pp.32618-32626. ⟨10.1021/jacs.4c11677⟩ Article dans une revue hal-05326476v1
Accumulation, Characterization and Reactivity of Chiral Ammonium-Carboxonium Dications in Superacid Emanuela Berrino,Thomas Cantin,Maxime Artault,Frédéric Guégan,Agnès Mingotet al. Angewandte Chemie International Edition, 2024, 63 (23), pp.e202404066. ⟨10.1002/anie.202404066⟩ Article dans une revue hal-04626794v1
Leveraging long-lived arenium ions in superacid for meta-selective methylation Paul Bourbon,Kassandra Vitse,Agnès Martin-Mingot,Hugo Geindre,Frédéric Guéganet al. Nature Communications, 2024, 15 (1), pp.7435. ⟨10.1038/s41467-024-49421-8⟩ Article dans une revue hal-04680872v1
Glycosylium Ions in Superacid Mimic the Transition State of Enzyme Reactions Mathilde Armand,Alba Nin-Hill,Ana Ardá,Emanuela Berrino,Jérôme Désiréet al. Journal of the American Chemical Society, 2024, 146 (47), pp.32618-32626. ⟨10.1021/jacs.4c11677⟩ Article dans une revue hal-05176253v1
Superacid-Synthesized Fluorinated Diamines Act as Selective hCA IV Inhibitors Emanuela Berrino,Bastien Michelet,Kassandra Vitse,Alessio Nocentini,Gianluca Bartolucciet al. Journal of Medicinal Chemistry, 2024, ⟨10.1021/acs.jmedchem.4c01795⟩ Article dans une revue hal-04753033v1
Enantioselective Organocatalysis and Superacid Activation: Challenges and Opportunities Bastien Michelet,Agnès Martin-Mingot,Jean Rodriguez,Sébastien Thibaudeau,Damien Bonne Chemistry - A European Journal, 2023, 29 (35), pp.e202300440. ⟨10.1002/chem.202300440⟩ Article dans une revue hal-04047011v1
Exploring F/CF3 substituted oxocarbenium ions for the diastereoselective assembly of highly substituted tetrahydrofurans Anthony J Fernandes,Bastien Michelet,Armen Panossian,Agnès Martin-Mingot,Frédéric R Lerouxet al. Chemical Communications, 2023, 59 (27), pp.4083-4086. ⟨10.1039/d2cc06521e⟩ Article dans une revue hal-04046996v1
Exploring Superacid‐Promoted Skeletal Reorganization of Aliphatic Nitrogen‐Containing Compounds Maxime Artault,Thomas Cantin,Mélissa Longuet,Kassandra Vitse,Christ Daniel Matatu Mbengoet al. Angewandte Chemie International Edition, 2023, 63 (1), pp.e202316458. ⟨10.1002/anie.202316458⟩ Article dans une revue hal-04520297v1
Hidden Heptacyclic Chiral N-Acyl Iminium Ions: a New Entry to Enantioenriched Polycyclic Azepanes and Azocanes by Superacid-Promoted Intramolecular Pictet-Spengler Reaction Yasmin Reviriot,Bastien Michelet,Rodolphe Beaud,Agnès Martin-Mingot,Frédéric Guéganet al. Chemistry - A European Journal, 2022, 28 (25), pp.e202200432. ⟨10.1002/chem.202200432⟩ Article dans une revue hal-03769652v1
Direct Superacid‐Promoted Difluoroethylation of Aromatics Maxime Artault,Kassandra Vitse,Agnès Martin-Mingot,Sébastien Thibaudeau Chemistry - A European Journal, 2022, 28 (6), ⟨10.1002/chem.202103926⟩ Article dans une revue hal-04139314v1
Superacid‐Mediated Late‐Stage Aromatic Polydeuteration of Pharmaceuticals Emeline Appert,Agnès Martin-Mingot,Omar Karam,Fabien Zunino,Bastien Micheletet al. Chemistry - A European Journal, 2022, 28 (49), pp.e202201583. ⟨10.1002/chem.202201583⟩ Article dans une revue hal-03769665v1
CF3-substituted carbocations: underexploited intermediates with great potential in modern synthetic chemistry Anthony J Fernandes,Armen Panossian,Bastien Michelet,Agnès Martin-Mingot,Frédéric Lerouxet al. Beilstein Journal of Organic Chemistry, 2021, 17, pp.343-378. ⟨10.3762/bjoc.17.32⟩ Article dans une revue hal-03154651v1
Complementary Site-Selective Sulfonylation of Aromatic Amines by Superacid Activation Paul Bourbon,Emeline Appert,Agnès Martin-Mingot,Bastien Michelet,Sébastien Thibaudeau Organic Letters, 2021, 23 (11), pp.4115-4120. ⟨10.1021/acs.orglett.1c00994⟩ Article dans une revue hal-03358394v1
Insight into the Ferrier rearrangement by combining flash chemistry and superacids Naresh Bhuma,Ludivine Lebedel,Hiroki Yamashita,Yutaka Shimizu,Zahra Abadaet al. Angewandte Chemie International Edition, 2021, 60 (4), pp.2036-2041. ⟨10.1002/anie.202010175⟩ Article dans une revue hal-03007376v1
Modulating the Efficacy of Carbonic Anhydrase Inhibitors through Fluorine Substitution Emanuela Berrino,Bastien Michelet,Agnès Martin-Mingot,Fabrizio Carta,Claudiu T Supuranet al. Angewandte Chemie International Edition, 2021, 60 (43), pp.23068-23082. ⟨10.1002/anie.202103211⟩ Article dans une revue hal-03358401v1
Formation of synthetically relevant CF3-substituted phenonium ions in superacid media Anthony J Fernandes,Bastien Michelet,Armen Panossian,Agnès Martin-Mingot,Frédéric R. Lerouxet al. RSC Advances, 2021, 11 (41), pp.25695 - 25699. ⟨10.1039/d1ra04901a⟩ Article dans une revue hal-03325280v1
Enantioenriched Methylene-Bridged Benzazocanes Synthesis by Organocatalytic and Superacid Activations Rodolphe Beaud,Bastien Michelet,Yasmin Reviriot,Agnès Martin-Mingot,Jean Rodriguezet al. Angewandte Chemie International Edition, 2020, 59 (3), pp.1279-1285. ⟨10.1002/anie.201912043⟩ Article dans une revue hal-02436747v1
Superelectrophilic Csp 3 –H bond fluorination of aliphatic amines in superacid: the striking role of ammonium–carbenium dications Maxime Artault,N. Mokhtari,T. Cantin,Agnès Martin-Mingot,Sébastien Thibaudeau Chemical Communications, 2020, 56 (44), pp.5905-5908. ⟨10.1039/d0cc02081h⟩ Article dans une revue hal-04537283v1
Complementary Site‐Selective Halogenation of Nitrogen‐Containing (Hetero)Aromatics with Superacids Alexander Mamontov,Agnès Martin-Mingot,Benoit Métayer,Omar Karam,Fabien Zuninoet al. Chemistry - A European Journal, 2020, 26 (46), pp.10411-10416. ⟨10.1002/chem.202000902⟩ Article dans une revue hal-04537186v1
Evidence and exploitation of dicationic ammonium–nitrilium superelectrophiles: direct synthesis of unsaturated piperidinones Thomas Cantin,Yvonne Morgenstern,Agnès Mingot,Andreas Kornath,Sébastien Thibaudeau Chemical Communications, 2020, 56 (75), pp.11110-11113. ⟨10.1039/d0cc02910f⟩ Article dans une revue hal-04537571v1
Access to Optically-Pure Benzosultams by Superelectrophilic Activation Bastien Michelet,Ugo Castelli,Emeline Appert,Maude Boucher,Kassandra Vitseet al. Organic Letters, 2020, 22 (13), pp.4944-4948. ⟨10.1021/acs.orglett.0c01301⟩ Article dans une revue hal-03016554v1
Direct and Selective C-H Carbamoylation of (Hetero)aromatics with TMSOTf-Activated Carbamoyl Chloride Ayaka Uehara,Sandra Olivero,Bastien Michelet,Agnès Martin-Mingot,Sébastien Thibaudeauet al. European Journal of Organic Chemistry, 2019, 2019 (1), pp.46-49. ⟨10.1002/ejoc.201801338⟩ Article dans une revue hal-03007761v1
Evidence of Phosphonium-Carbenium Dication Formation in a Superacid: Precursor to Fluorinated Phosphine Oxides Ugo Castelli,Jean-François Lohier,Ines Drukenmüller,Agnès Mingot,Christian Bachmanet al. Angewandte Chemie International Edition, 2019, 58 (5), pp.1355-1360. ⟨10.1002/anie.201811032⟩ Article dans une revue hal-02159927v1
Superelectrophilic activation in superacid HF/SbF5: Expanding molecular diversity in nitrogen-containing compounds series by fluorination Bastien Michelet,Hélène Carreyre,Frédéric Lecornué,Agnès Mingot,Sébastien Thibaudeau Journal of Fluorine Chemistry, 2018, 214, pp.68-79. ⟨10.1016/j.jfluchem.2018.04.017⟩ Article dans une revue istex hal-03007791v1
Fluoroenesulphonamides: N -sulphonylurea isosteres showing nanomolar selective cancer-related transmembrane human carbonic anhydrase inhibition Benoit Metayer,Andrea Angeli,Agnès Mingot,Kévin Jouvin,Gwilherm Evanoet al. Journal of Enzyme Inhibition and Medicinal Chemistry, 2018, 33 (1), pp.804-808. ⟨10.1080/14756366.2018.1461097⟩ Article dans une revue hal-02169774v1
Cationic polycyclization of ynamides: building up molecular complexity Cédric Theunissen,Benoit Metayer,Morgan Lecomte,Nicolas Henry,Hwai-Chien Chanet al. Organic & Biomolecular Chemistry, 2017, 15 (20), pp.4399-4416. ⟨10.1039/C7OB00850C⟩ Article dans une revue hal-02173400v1
HF-Induced Intramolecular C -Arylation and C -Alkylation/Fluorination of 2-Aminoglycopyranoses Nicolas Probst,Amélie Martin,Jérôme Désiré,Agnès Mingot,Jerome Marrotet al. Organic Letters, 2017, 19 (5), pp.1040 - 1043. ⟨10.1021/acs.orglett.7b00003⟩ Article dans une revue hal-01743477v1
Superacid-Catalyzed Trifluoromethylthiolation of Aromatic Amines Longin Justin Clair Bonazaba milandou,Hélène Carreyre,Sébastien Alazet,Gino Greco,Agnès Martin-Mingotet al. Angewandte Chemie, 2017, 129 (1), pp.175 - 178. ⟨10.1002/ange.201609574⟩ Article dans une revue hal-01598373v1
Innenrücktitelbild: Superacid-Catalyzed Trifluoromethylthiolation of Aromatic Amines (Angew. Chem. 1/2017) Longin Justin Clair Bonazaba milandou,Hélène Carreyre,Sébastien Alazet,Gino Greco,Agnès Martin-Mingotet al. Angewandte Chemie, 2017, 129 (1), pp.429 - 429. ⟨10.1002/ange.201611312⟩ Article dans une revue hal-01610193v1
Inside Back Cover: Superacid-Catalyzed Trifluoromethylthiolation of Aromatic Amines (Angew. Chem. Int. Ed. 1/2017) Longin Justin Clair Bonazaba milandou,Hélène Carreyre,Sébastien Alazet,Gino Greco,Agnès Martin-Mingotet al. Angewandte Chemie International Edition, 2017, 56 (1), pp.417 - 417. ⟨10.1002/anie.201611312⟩ Article dans une revue hal-01610196v1
A Journey in the Chemistry of Ynamides: From Synthesis to Applications Gwilherm Evano,Nicolas Blanchard,Guillaume Compain,Alexis Coste,Charles Demmeret al. Chemistry Letters, 2016, 45 (6), pp.574-585. ⟨10.1246/cl.160260⟩ Article dans une revue hal-03007853v1
Tandem superelectrophilic activation for the regioselective chlorofluorination of recalcitrant allylic amines Le Darz Alexandre,Ugo Castelli,Naima Mokhtari,Agnès Martin-Mingot,Jerôme Marrotet al. Tetrahedron, 2016, 72, pp.674-689 ⟨10.1016/j.tet.2015.12.013⟩ Article dans une revue istex hal-01505611v1
Catching elusive glycosyl cations in a condensed phase with HF/SbF₅ superacid A. Martin,A. Arda,J. Désiré,A. Martin-Mingot,N. Probstet al. Nature Chemistry, 2016, ⟨10.1038/nchem.2399⟩ Article dans une revue hal-01505628v1
Synthetic deoxynojirimycin derivatives bearing a thiolated, fluorinated or unsaturated N-alkyl chain: identification of potent α-glucosidase and trehalase inhibitors as well as F508del-CFTR correctors. V. Cendret,T. Legigan,A. Martin-Mingot,S. Thibaudeau,I. Adachiet al. Organic & Biomolecular Chemistry, 2015, 13 (43), pp.10734-10744. ⟨10.1039/c5ob01526j⟩ Article dans une revue hal-01500682v1
Chemo- and Stereoselective Synthesis of Fluorinated Enamides from Ynamides in HF/Pyridine: Second-Generation Approach to Potent Ureas Bioisosteres Benoit Metayer,Guillaume Compain,Kevin Jouvin,Agnès Martin-Mingot,Christian Bachmannet al. Journal of Organic Chemistry, 2015, 80, pp.3397-3410. ⟨10.1021/jo502699y⟩ Article dans une revue hal-01360121v1
Keteniminium Ion-Initiated Cascade Cationic Polycyclization C. Theunissen,B. Metayer,E. Henry,G. Compain,J. Marrotet al. Journal of the American Chemical Society, 2014, 136 (36), pp.12528-12531. ⟨10.1021/ja504818p⟩ Article dans une revue hal-01063189v1
Superacid synthesized tertiary benzenesulfonamides and benzofuzed sultams act as selective hCA IX inhibitors: toward understanding a new mode of inhibition by tertiary sulfonamides B. Metayer,A. Martin-Mingot,D. Vullo,C.T. Supuran,S. Thibaudeau Organic & Biomolecular Chemistry, 2013, 11 (43), pp.7540-7549. ⟨10.1039/c3ob41538d⟩ Article dans une revue hal-00964957v1
Superacid synthesis of halogen containing N-substituted-4-aminobenzene sulfonamides: New selective tumor-associated carbonic anhydrase inhibitors G. Compain,A. Martin-Mingot,A. Maresca,S. Thibaudeau,C. T. Supuran Bioorganic and Medicinal Chemistry, 2013, 21 (6), pp.1555-1563. ⟨10.1016/j.bmc.2012.05.037⟩ Article dans une revue hal-00839204v1
Selective Anti-Markovnikov Cyclization and Hydrofluorination2 Reaction in Superacid HF/SbF5: A Tool in the Design of Nitrogen-Containing (Fluorinated) Polycyclic Systems G. Compain,C. Bonneau,A. Martin-Mingot,S. Thibaudeau Journal of Organic Chemistry, 2013, 78, pp.4463-4472. ⟨10.1021/jo400398y⟩ Article dans une revue hal-00918382v1
Dications in superacid HF/SbF5: When superelectrophilic activation makes possible fluorination and/or C-H bond activation A. Martin-Mingot,G. Compain,Franklin Liu,M.P. Jouannetaud,C. Bachmannet al. Journal of Fluorine Chemistry, 2012, 134 (SI), pp.56-62. ⟨10.1016/j.jfluchem.2011.04.022⟩ Article dans une revue istex hal-00826922v1
Anti-Markovnikov additions to N-allylic derivatives involving ammonium-carbenium superelectrophiles G. Compain,A. Martin-Mingot,G. Frapper,M.P. Jouannetaud,S. Thibaudeau Chemical Communications, 2012, 48 (47), pp.5877-5879. ⟨10.1039/c2cc32246c⟩ Article dans une revue hal-00820212v1
Stereoselective hydrofluorination of ynamides: a straightforward synthesis of novel alpha-fluoroenamides G. Compain,K. Jouvin,A. Martin-Mingot,G. Evano,J. Marrotet al. Chemical Communications, 2012, 48 (42), pp.5196-5198. ⟨10.1039/c2cc31768k⟩ Article dans une revue hal-00834286v1
High efficiency of superacid HF-SbF5 for the selective decrystallization-depolymerization of cellulose to glucose. Agnès Martin-Mingot,Karine de Oliveira Vigier,François Jérôme,Sébastien Thibaudeau Organic & Biomolecular Chemistry, 2012, 10 (13), pp.2521-4. ⟨10.1039/c2ob07143f⟩ Article dans une revue hal-00726568v1
Carbonic Anhydrases inhibitory effects of new benzenesulfonamides synthesized by using superacid chemistry F. Lin,A. Martin-Mingot,F. Lecornué,M.P. Jouannetaud,A. Marescaet al. Journal of Enzyme Inhibition and Medicinal Chemistry, 2012, 27 (6), pp.886-891. ⟨10.3109/14756366.2011.638921⟩ Article dans une revue hal-00823328v1
Deactivation and reactivation of noble metal catalysts tested in the Catalytic Wet Air Oxidation of phenol Sylvain Keav,Agnès Martin,Jacques Barbier Jr.,Daniel Duprez Catalysis Today, 2010, 151 (1-2), pp.143-147. ⟨10.1016/j.cattod.2010.01.025⟩ Article dans une revue hal-04999424v1
Nature du dépôt formé au cours de l’oxydation en voie humide catalysée du phénol Sylvain Keav,Agnès Martin,Jacques Barbier Jr.,Daniel Duprez Comptes Rendus. Chimie, 2010, 13 (5), pp.508-514. ⟨10.1016/j.crci.2010.02.001⟩ Article dans une revue hal-04999419v1

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Enantioselective Organocatalysis and Superacid Activation: Challenges and Opportunities Bastien Michelet,Agnès Martin-Mingot,Jean Rodriguez,Sébastien Thibaudeau,Damien Bonne France. 2023 Image hal-04414104v1
Enantioenriched Methylene-Bridged Benzazocanes Synthesis by Organocatalytic and Superacid Activations Rodolphe Beaud,Bastien Michelet,Yasmin Reviriot,Agnès Martin-Mingot,Jean Rodriguezet al. Illustration. France. 2020 Image (illustration) hal-02436606v1