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Alain Walcarius



Research Director at CNRS Head of the « Analytical Chemistry and Electrochemistry » (ELAN) group of LCPME Laboratory of Physical Chemistry and Microbiology for Materials and the Environment (LCPME) Address: LCPME-CNRS, 405 rue de Vandoeuvre, 54600 Villers-les-Nancy Tel. : 03 72 74 73 75 ; Fax : 03 83 27 54 44 ; E-mail : []( **Main research themes** \# Reactivity of silica-based organic-inorganic hybrid materials in aqueous media \# Functional mesoporous materials in electrochemistry, analytical chemistry, and environment \# Electrochemically-assisted generation of functionalized and/or mesostructured sol-gel films \# Development of bioelectrocatalytic reactors of novel generation based on nanomaterials **Educational background and career** **1994** PhD level in Sciences (Facultés Universitaires Notre-Dame de la Paix, Namur, Belgique) **1995** Post-doctoral fellow (New Mexico State University, USA, Pr. J. Wang) **1996** Post-doctoral fellow, then Research Associate to CNRS at LCPME **2000** Habilitation for managing Research (University Henri Poincaré, Nancy I) **2001** Head of the « Analytical Chemistry and Electrochemistry » (ELAN) group at LCPME **2004** Research Director at CNRS (DR2, LCPME; DR1 in 2011, DRCE in 2021) **2005-2010** Deputy Director of LCPME **2011-2020** Director of LCPME **Fields of expertise** \# Electroanalytical chemistry and sensors – Electrogeneration of sol-gel-derived materials \# Analytical investigation of solid/liquid interfaces (mass transport and charge transfert) \# Chemistry and physical chemistry with silica-based, porous and functionalized materials **Student supervison** \- 27 PhD students (24 graduated). \- 7 Bachelor final year projects (Belgium) and 8 Master theses (France) + ~20 interns. **Some responsibilities** \- "Chargé de Mission" (officer) at the CNRS Direction (Chemistry Institute) \- Officer at the International Society of Electrochemistry (Chair of the Analytical Electrochemistry Division) \- Member of the Editorial Board of Sensors & Actuators B (Elsevier) and Electroanalysis (Wiley) \- Member of the scientific committees of national and international conferences (24 int. + 6 nat.) \- Expert for a number of national funding agencies (France, Ireland, Germany, Italy, Belgium, Czech Republic) **Awards** \- June 1999: Award for Analytical Electrochemistry (Radiometer & Electrochemistry group & SFC) \- January 2001: Award from the Analytical Chemistry Division of the French Society of Chemistry \- September 2007: *Tajima Prize 2006* of ISE (International Society of Electrochemistry) \- November 2013: *Doctor Honoris Causa* from University of Medicine and Pharmacy (Cluj-Napoca, Romania) \- October 2015: Senior Researcher Award, Physical Chemistry Division of the French Society of Chemistry \- August 2016: *Fellow* of the International Society of Electrochemistry \- October 2019: *Prix Langevin* of the French Academy of Sciences \- March 2021: *Fellow* of the International Association of Advanced Materials **Publications (~335)** \- Peer-reviewed international papers: 295 (> 13 100 cit., H = 60 (WoS) or > 17 700 cit., H = 70 (google scholar)) \- Book chapters: 12 + 1 book (*Electroanalysis with Carbon Paste Electrodes*) \- Proceedings: 23 \- Patents: 3 ***5 significant publications*** \# A. Walcarius, E. Sibottier, M. Etienne and J. Ghanbaja, Electrochemically-assisted self assembly of mesoporous silica thin films, *Nature Materials*, 2007, 6, 602-608. \# A. Walcarius, Mesoporous materials and electrochemistry, *Chemical Society Reviews*, 2013, 42, 4098-4140. \# N. Vilà, J. Ghanbaja, E. Aubert and A. Walcarius, Electrochemically assisted generation of highly ordered azide-functionalized mesoporous silica for oriented hybrid films, *Angewandte Chemie International Edition*, 2014, 53, 2945-2950. \# N. Vilà, E. André, R. Ciganda, J. Ruiz, D. Astruc and A. Walcarius, Molecular sieving with vertically-aligned mesoporous silica films and electronic wiring through isolating nanochannels, *Chemistry of Materials*, 2016, 28, 2511-2514. \# A. Walcarius, Electro-induced surfactant self-assembly driven to vertical growth of oriented mesoporous films, *Accounts of Chemical Research*, 2021, 54, 3563-3575.


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Ultra-thin silver nanowires’ synthesis in pore-confined space of mesoporous silica thin film

Magdalena Laskowska , Alain Walcarius , Andrii Fedorchuk , Maciej Zubko , Łukasz Laskowski
Journal of Materials Research and Technology, 2023, 24, pp.7771-7781. ⟨10.1016/j.jmrt.2023.05.029⟩
Journal articles hal-04262816v1
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Electrochemical approaches based on micro- and nanomaterials for diagnosing oxidative stress

Mahdi Jamshidi , Alain Walcarius , Madasamy Thangamuthu , Masoud Mehrgardi , Akram Ranjbar
Microchimica Acta, 2023, 190 (4), pp.117. ⟨10.1007/s00604-023-05681-7⟩
Journal articles hal-04262777v1
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Visualization of working electrode reactivity from an electrochromic counter electrode

Qiao Liu , Mariela Alicia Brites Helú , Alain Walcarius , Liang Liu
Electrochimica Acta, 2023, 444, pp.142010. ⟨10.1016/j.electacta.2023.142010⟩
Journal articles hal-04262764v1
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Scanning gel electrochemical microscopy: Combination with quartz crystal microbalance for studying the electrolyte residue

Gustavo Adrián Echeveste Salazar , Mariela Alicia Brites Helú , Alain Walcarius , Liang Liu
Electrochimica Acta, 2023, 437, pp.141455. ⟨10.1016/j.electacta.2022.141455⟩
Journal articles hal-04262754v1
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Modelling of a hybrid bioelectrocatalytic flow reactor with NADH cofactor regeneration by immobilized rhodium mediator for pyruvate bioconversion

Wassim El Housseini , Mathieu Etienne , Elisabeth Lojou , Alain Walcarius , François Lapicque
Chemical Engineering and Processing: Process Intensification, 2023, 187, pp.109326. ⟨10.1016/j.cep.2023.109326⟩
Journal articles hal-04255050v1
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Electrogeneration of non-electroactive and non-conducting materials: a counterintuitive concept for the functionalization and nanostructuration of electrode surfaces

Alain Walcarius
Comptes Rendus. Chimie, 2023, 26, pp.99-143. ⟨10.5802/crchim.242⟩
Journal articles hal-04262822v1
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Laser Cutting Coupled with Electro-Exfoliation to Prepare Versatile Planar Graphene Electrodes for Energy Storage

Jianren Wang , Tianshuo Yang , Neus Vilà , Alain Walcarius
International Journal of Molecular Sciences, 2023, 24 (6), pp.5599. ⟨10.3390/ijms24065599⟩
Journal articles hal-04262810v1
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Electrochemical Determination of Hg2+ on a Poly (Eriochrome Blue Black R) Modified Carbon Paste Electrode

Abdoulkadri Ayouba Mahamane , Abdoulaye Idrissa Kalidou , Hassane Adamou , Bachir Mijitaba Sahirou , Alain Walcarius
International Research Journal of Pure and Applied Chemistry, 2023, 24 (1), pp.49-64. ⟨10.9734/irjpac/2023/v24i1801⟩
Journal articles hal-04262805v1

Emerging electrochemical methods at the nanointerface: general discussion

Mark Buckingham , Xiangkun Elvis Cao , Shuai Chang , Hong-Yuan Chen , Qianjin Chen
Faraday Discussions, 2022, 233, pp.257-282. ⟨10.1039/D2FD90003C⟩
Journal articles hal-04262739v1

Getting closer to the intrinsic properties of Ni 2+ salen polymer semiconductors accessed by chain isolation inside silica nanochannels

Kamila Łępicka , Piyush Sindhu Sharma , Paweł Borowicz , Grégory Francius , Alain Walcarius
Journal of Materials Chemistry C, 2022, 10 (24), pp.9287-9300. ⟨10.1039/d2tc00976e⟩
Journal articles hal-03838207v1
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Multiphase chemical engineering as a tool in modelling electromediated reactions-Example of Rh complex-mediated regeneration of NADH

Wassim El Housseini , Mathieu Etienne , Alain Walcarius , Francois Lapicque
Chemical Engineering Science, 2022, 247, pp.117055. ⟨10.1016/j.ces.2021.117055⟩
Journal articles hal-03407265v1
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A hybrid electrochemical flow reactor to couple H 2 oxidation to NADH regeneration for biochemical reactions

Wassim El Housseini , François Lapicque , Alain Walcarius , Mathieu Etienne
Electrochemical Science Advances, 2022, 2, pp.e202100012. ⟨10.1002/elsa.202100012⟩
Journal articles hal-03425413v1
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Improved Productivity of NAD+ Reduction under Forced Convection in Aerated Solutions

Thi Xuan Huong Le , Julius Gajdar , Neus Vilà , Alain Celzard , Vanessa Fierro
ChemElectroChem, 2022, 9 (5), ⟨10.1002/celc.202101225⟩
Journal articles hal-03562062v1
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Polyaniline nanowire arrays generated through oriented mesoporous silica films: effect of pore size and spectroelectrochemical response

Wahid Ullah , Grégoire Herzog , Neus Vilà , Alain Walcarius
Faraday Discussions, 2022, 233, pp.77-99. ⟨10.1039/D1FD00034A⟩
Journal articles hal-03795840v1
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Hybrid Flow Bioreactor with All Catalysts Immobilized for Enzymatic Electrosynthesis

Wassim El Housseini , François Lapicque , Steve Pontvianne , Neus Vilà , Ievgen Mazurenko
ChemElectroChem, 2022, 9 (16), ⟨10.1002/celc.202200463⟩
Journal articles hal-03796322v1

State of the art energy conversion at the nanointerface: general discussion

Tim Albrecht , Paul W. Bohn , Mark Buckingham , Xiangkun Elvis Cao , Dongfei Chen
Faraday Discussions, 2022, 233, pp.112-121. ⟨10.1039/D2FD90002E⟩
Journal articles hal-04262731v1
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Weak coordinating character of organosulfonates in oriented silica films: an efficient approach for immobilizing cationic metal-transition complexes

Samuel Ahoulou , Clara Richart , Cédric Carteret , Sébastien Pillet , Neus Vilà
Molecules, 2022, 27 (17), pp.5444. ⟨10.3390/molecules27175444⟩
Journal articles hal-03796349v1

Advanced nanoelectrochemistry implementation: from concept to application: general discussion

Paul W. Bohn , Xiangkun Elvis Cao , Shuai Chang , Dongfei Chen , Samuel Confederat
Faraday Discussions, 2022, 233, pp.354-373. ⟨10.1039/D2FD90004A⟩
Journal articles hal-04262740v1

Electroanalysis based on Carbon Nanomaterials

Guobao Xu , Alain Walcarius , Yasuaki Einaga , Robert Dryfe
Electroanalysis, 2022, 34 (4), pp.573-573. ⟨10.1002/elan.202200017⟩
Journal articles hal-03795910v1
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Preparation of functionalized Ayous sawdust-carbon nanotubes composite for the electrochemical determination of carbendazim pesticide

Ghislaine Ariane Fozing Mekeuo , Christelle Despas , Charles Péguy Nanseu-Njiki , Alain Walcarius , Emmanuel Ngameni
Electroanalysis, 2022, 34 (4), pp.667-676. ⟨10.1002/elan.202100262⟩
Journal articles hal-03795957v1
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Fabrication of polyaniline (PANI) through parallel nanopores; transport properties of PANI@SiO2 nanopore molecular junctions

Xiaonan Sun , Wahid Ullah , Jean-Christophe Lacroix , Alain Walcarius , Grégoire Herzog
ECS Journal of Solid State Science and Technology, 2022, 11 (6), pp.065009. ⟨10.1149/2162-8777/ac76b7⟩
Journal articles hal-03796316v1
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Get closer to the intrinsic properties of Ni 2+ salen polymer semiconductors accessed by chain isolation inside silica nanochannels

Kamila Łępicka , Piyush Sindhu Sharma , Paweł Borowicz , Grégory Francius , Alain Walcarius
Journal of Materials Chemistry C, 2022, 10 (24), pp.9287-9300. ⟨10.1039/D2TC00976E⟩
Journal articles hal-03796281v1
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Carbon paste electrode modified with 5-Br-PADAP as a new electrochemical sensor for the detection of inorganic mercury(II)

Abdoulkadri Ayouba Mahamane , Christelle Despas , Rabani Adamou , Alain Walcarius
Journal of Materials and Environmental Science , 2022
Journal articles hal-03796290v1
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Electrografting and electropolymerization of nanoarrays of PANI filaments through silica mesochannels

Wahid Ullah , Grégoire Herzog , Neus Vilà , Alain Walcarius
Electrochemistry Communications, 2021, 122, pp.106896. ⟨10.1016/j.elecom.2020.106896⟩
Journal articles hal-03040482v1
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Multi‐stimuli Photo and Redox‐active Nanostructured Mesoporous Silica Films on Transparent Electrodes

Samuel Ahoulou , Neus Vilà , Sébastien Pillet , Cédric Carteret , Dominik Schaniel
ChemPhysChem, 2021, 22 (23), pp.2464-2477. ⟨10.1002/cphc.202100608⟩
Journal articles hal-03534155v1
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Synthesis of Vertically Aligned Porous Silica Thin Films Functionalized by Silver Ions

Andrii Fedorchuk , Alain Walcarius , Magdalena Laskowska , Neus Vila , Paweł Kowalczyk
International Journal of Molecular Sciences, 2021, 22 (14), pp.7505. ⟨10.3390/ijms22147505⟩
Journal articles hal-03355509v1

Switchable voltammetric response of electrodes modified with a mesoporous silica thin film and a polyelectrolyte multilayer

Karolina Sipa , Konrad Rudnicki , Neus Vila , Grégoire Herzog , Sławomira Skrzypek
Electrochemistry Communications, 2021, 132, pp.107142. ⟨10.1016/j.elecom.2021.107142⟩
Journal articles hal-03496584v1
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A Sensitive Electrochemical Sensor for Moxifloxacin Hydrochloride Based on Nafion/Graphene Oxide/Zeolite Modified Carbon Paste Electrode

Amany Fekry , Soha Abdel‐gawad , Shereen Azab , Alain Walcarius
Electroanalysis, 2021, 33 (4), pp.964-974. ⟨10.1002/elan.202060355⟩
Journal articles hal-03355460v1
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Electrochemically Assisted Deposition of Nanoporous Silica Membranes on Gold Electrodes: Effect of 3‐Mercaptopropyl(trimethoxysilane) “Molecular Glue” on Film Formation, Permeability and Metal Underpotential Deposition

Wahid Ullah , Grégoire Herzog , Neus Vilà , Mariela Brites Helú , Alain Walcarius
ChemElectroChem, 2021, 8, pp.142-150. ⟨10.1002/celc.202001347⟩
Journal articles hal-03033135v1
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Electroinduced Surfactant Self-Assembly Driven to Vertical Growth of Oriented Mesoporous Films

Alain Walcarius
Accounts of Chemical Research, 2021, 54 (18), pp.3563-3575. ⟨10.1021/acs.accounts.1c00233⟩
Journal articles hal-03355572v1
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Electroactive organically modified mesoporous silicates on graphene oxide-graphite 3D architectures operating with electron-hopping for high rate energy storage

Jianren Wang , Neus Vila , Alain Walcarius
Electrochimica Acta, 2021, 366, pp.137407 -. ⟨10.1016/j.electacta.2020.137407⟩
Journal articles hal-03493610v1
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Electrochemical stripping analysis from micro-counter electrode

Qiao Liu , Liang Liu , Michel Perdicakis , Alain Walcarius
Electrochimica Acta, 2021, 393, pp.139095. ⟨10.1016/j.electacta.2021.139095⟩
Journal articles hal-03355545v1

Electron transfers in graphitized HZSM-5 zeolites

Alain Moissette , Isabelle Batonneau-Gener , Matthieu Hureau , Ludovic Pinard , Herve Vezin
Physical Chemistry Chemical Physics, 2021, Physical Chemistry Chemical Physics, 23 (3), pp.1914-1922. ⟨10.1039/d0cp06148d⟩
Journal articles hal-03269523v1
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Integrated probe for electrochemical analysis of small volume droplets

Ning Dang , Nader Djelidi , Gustavo Adrián Echeveste Salazar , Alain Walcarius , Liang Liu
Sensors and Actuators B: Chemical, 2021, 347, pp.130542. ⟨10.1016/j.snb.2021.130542⟩
Journal articles hal-03355536v1
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Electrogeneration of a Free-Standing Cytochrome c—Silica Matrix at a Soft Electrified Interface

Alonso Gamero-Quijano , Manuel Dossot , Alain Walcarius , Micheál Scanlon , Grégoire Herzog
Journal articles hal-03180535v1
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Permeability of Dawson–type polyoxometalates through vertically oriented nanoporous silica membranes on electrode: Effect of pore size and probe charge

Neus Vilà , Pedro de Oliveira , Alain Walcarius , Israël Mbomekallé
Electrochimica Acta, 2020, 353, pp.136577. ⟨10.1016/j.electacta.2020.136577⟩
Journal articles hal-02981482v1
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Moxifloxacin Hydrochloride Electrochemical Detection at Gold Nanoparticles Modified Screen-Printed Electrode

M. Shehata , Amany Fekry , Alain Walcarius
Sensors, 2020, 20 (10), pp.2797. ⟨10.3390/s20102797⟩
Journal articles hal-02981481v1
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Redox-Active Vertically Aligned Mesoporous Silica Thin Films as Transparent Surfaces for Energy Storage Applications

Jianren Wang , Neus Vilà , Alain Walcarius
ACS Applied Materials & Interfaces, 2020, 12 (21), pp.24262-24270. ⟨10.1021/acsami.0c03650⟩
Journal articles hal-02981478v1
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Electrochemically assisted polyamide deposition at three-phase junction

Karolina Sipa , Karolina Kowalewska , Andrzej Leniart , Alain Walcarius , Grégoire Herzog
Electrochemistry Communications, 2020, pp.106910. ⟨10.1016/j.elecom.2020.106910⟩
Journal articles hal-03090265v1
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Scanning Gel Electrochemical Microscopy (SGECM): Lateral Physical Resolution by Current and Shear Force Feedback

Ning Dang , Mathieu Etienne , Alain Walcarius , Liang Liu
Analytical Chemistry, 2020, 92 (9), pp.6415-6422. ⟨10.1021/acs.analchem.9b05538⟩
Journal articles hal-02981474v1
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Voltammetric behaviour of cationic redox probes at mesoporous silica film electrodes

Deomila Basnig , Neus Vilà , Grégoire Herzog , Alain Walcarius
Journal of Electroanalytical Chemistry, 2020, pp.113993. ⟨10.1016/j.jelechem.2020.113993⟩
Journal articles hal-02484251v1
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Selective Detection of Cysteine at a Mesoporous Silica Film Electrode Functionalized with Ferrocene in the Presence of Glutathione

Himanshu Maheshwari , Neus Vilà , Grégoire Herzog , Alain Walcarius
ChemElectroChem, 2020, 7 (9), pp.2095-2101. ⟨10.1002/celc.202000396⟩
Journal articles hal-02887146v2
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Bis(terpyridine) Iron(II) Functionalized Vertically-Oriented Nanostructured Silica Films: Toward Electrochromic Materials

Neus Vilà , Alain Walcarius
Frontiers in Chemistry, 2020, 8, ⟨10.3389/fchem.2020.00830⟩
Journal articles hal-02981486v1

Voltammetric detection of caffeine in pharmacological and beverages samples based on simple nano- Co (II, III) oxide modified carbon paste electrode in aqueous and micellar media

A.M. Fekry , M. Shehata , S.M. Azab , Alain Walcarius
Sensors and Actuators B: Chemical, 2020, 302, pp.127172. ⟨10.1016/j.snb.2019.127172⟩
Journal articles hal-02981472v1

An imidazolium ionic liquid as effective structure-directing agent for the fabrication of silica thin films with vertically aligned nanochannels

Szilvia Vavra , Neus Vilà , Antiope Lotsari , Alain Walcarius , Anna Martinelli
Microporous and Mesoporous Materials, 2020, pp.110407. ⟨10.1016/j.micromeso.2020.110407⟩
Journal articles hal-02981489v1
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Signal amplification by electro-oligomerisation for improved isoproturon detection

Tauqir Nasir , Alonso Gamero-Quijano , Christelle Despas , Manuel Dossot , Grégoire Herzog
Talanta, 2020, 220, pp.121347. ⟨10.1016/j.talanta.2020.121347⟩
Journal articles hal-02947712v1
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Amino-grafting of montmorillonite improved by acid activation and application to the electroanalysis of catechol

Liliane Dongmo , Sherman L.Z. Jiokeng , Chancellin Pecheu , Alain Walcarius , Ignas Tonle
Applied Clay Science, 2020, 191, pp.105602. ⟨10.1016/j.clay.2020.105602⟩
Journal articles hal-02981476v1
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Local removal of oxygen for NAD(P)+ detection in aerated solutions

Thi Xuan Huong Le , Mathieu Etienne , François Lapicque , Alain Hehn , Neus Vilà
Electrochimica Acta, 2020, 353, pp.136546. ⟨10.1016/j.electacta.2020.136546⟩
Journal articles hal-02917647v1
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Promises of the “Nano-World” for electrochemical sensing and energy devices

Alain Walcarius
Journal of Solid State Electrochemistry, 2020, 24 (9), pp.2189-2191. ⟨10.1007/s10008-020-04684-1⟩
Journal articles hal-02981485v1
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Non‐covalent Immobilization of Iron‐triazole (Fe(Htrz) 3 ) Molecular Mediator in Mesoporous Silica Films for the Electrochemical Detection of Hydrogen Peroxide

Samuel Ahoulou , Neus Vilà , Sébastien Pillet , Dominik Schaniel , Alain Walcarius
Electroanalysis, 2020, 32 (4), pp.690-697. ⟨10.1002/elan.201900444⟩
Journal articles hal-02981470v1
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Layer-by-Layer modification of graphite felt with MWCNT for vanadium redox flow battery

Mathieu Etienne , Jose F Vivo-Vilches , Ivan Vakulko , Claire Genois , Liang Liu
Electrochimica Acta, 2019, 313, pp.131-140. ⟨10.1016/j.electacta.2019.04.022⟩
Journal articles hal-02149600v1
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Synthesis, Crystal Structure, Electrochemistry and Electro-Catalytic Properties of the Manganese-Containing Polyoxotungstate, [(Mn(H2O)3)2(H2W12O42)]6−

Anne-Lucie Teillout , Pedro de Oliveira , Jérôme Marrot , Robertha Howell , Neus Vilà
Inorganics, 2019, 7 (2), pp.15. ⟨10.3390/inorganics7020015⟩
Journal articles hal-02089707v1
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Critical Effect of Film Thickness on Preconcentration Electroanalysis with Oriented Mesoporous Silica Modified Electrodes

Tauqir Nasir , Natalya Vodolazkaya , Grégoire Herzog , Alain Walcarius
Electroanalysis, 2019, 31, pp.202-207. ⟨10.1002/elan.201800533⟩
Journal articles hal-01916919v1
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Coordination Polymers as Template for Mesoporous Silica Films: A Novel Composite Material Fe(Htrz) 3 @SiO 2 with Remarkable Electrochemical Properties

Samuel Ahoulou , Neus Vilà , Sébastien Pillet , Dominik Schaniel , Alain Walcarius
Chemistry of Materials, 2019, 31 (15), pp.5796-5807. ⟨10.1021/acs.chemmater.9b01879⟩
Journal articles hal-02324674v1
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Sensitive Determination of Acetaminophen in the Presence of Dopamine and Pyridoxine Facilitated by their Extent of Interaction with Single‐walled Carbon Nanotubes

Mamta Yadav , Vellaichamy Ganesan , Biswajit Maiti , Rupali Gupta , Piyush Kumar Sonkar
Electroanalysis, 2019, ⟨10.1002/elan.201900178⟩
Journal articles hal-02324690v1
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Evaluation of the electrocatalytic properties of Tungsten electrode towards hydrogen evolution reaction in acidic solutions

Ghada Abd El-Hafez , Nady Mahmoud , Alain Walcarius , Amany Fekry
International Journal of Hydrogen Energy, 2019, 44 (31), pp.16487-16496. ⟨10.1016/j.ijhydene.2019.04.223⟩
Journal articles hal-02324670v1
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Thickness control in electrogenerated mesoporous silica films by wet etching and electrochemical monitoring of the process

Taisiia Sikolenko , Christelle Despas , Neus Vilà , Alain Walcarius
Electrochemistry Communications, 2019, 100, pp.11-15. ⟨10.1016/j.elecom.2019.01.013⟩
Journal articles hal-02089703v1
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Amino-attapulgite/mesoporous silica composite films generated by electro-assisted self-assembly for the voltammetric determination of diclofenac

Sherman L.Z. Jiokeng , Ignas Tonle , Alain Walcarius
Sensors and Actuators B: Chemical, 2019, 287, pp.296-305. ⟨10.1016/j.snb.2019.02.038⟩
Journal articles hal-02089711v1
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Mesoporous Silica-Based Materials for Electronics-Oriented Applications

Łukasz Laskowski , Magdalena Laskowska , Neus Vilà , Mateusz Schabikowski , Alain Walcarius
Molecules, 2019, 24 (13), pp.2395. ⟨10.3390/molecules24132395⟩
Journal articles hal-02324679v1
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Voltammetric and microscopic characteristics of MnO2 and silica-MnO2 hybrid films electrodeposited on the surface of planar electrodes

Anastasiia Kovalyk , Oksana Tananaiko , Anna Borets , Mathieu Etienne , Alain Walcarius
Electrochimica Acta, 2019, 306, pp.680-687. ⟨10.1016/j.electacta.2019.03.156⟩
Journal articles hal-02089714v1
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pH-modulated ion transport and amplified redox response of Keggin-type polyoxometalates through vertically-oriented mesoporous silica nanochannels

Neus Vilà , Pedro de Oliveira , Alain Walcarius , Israël Mbomekallé
Electrochimica Acta, 2019, 309, pp.209-218. ⟨10.1016/j.electacta.2019.03.119⟩
Journal articles hal-02149606v1
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Cu Nanodendrite Foams on Integrated Band Array Electrodes for the Nonenzymatic Detection of Glucose

Vuslat Juska , Alain Walcarius , Martyn Pemble
ACS Applied Nano Materials, 2019, 2 (9), pp.5878-5889. ⟨10.1021/acsanm.9b01325⟩
Journal articles hal-02324683v1
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Multi-step functionalization procedure for fabrication of vertically aligned mesoporous silica thin films with metal-containing molecules localized at the pores bottom

Łukasz Laskowski , Magdalena Laskowska , Mateusz Dulski , Maciej Zubko , Jerzy Jelonkiewicz
Microporous and Mesoporous Materials, 2019, 274, pp.356-362. ⟨10.1016/j.micromeso.2018.09.008⟩
Journal articles hal-01941800v1
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Structure-reactivity requirements with respect to nickel-salen based polymers for enhanced electrochemical stability

Kamila Łępicka , Piotr Pieta , Gregory Francius , Alain Walcarius , Wlodzimierz Kutner
Electrochimica Acta, 2019, 315, pp.75-83. ⟨10.1016/j.electacta.2019.05.075⟩
Journal articles hal-02149614v1

Scanning Gel Electrochemical Microscopy for Topography and Electrochemical Imaging

Liang Liu , Mathieu Etienne , Alain Walcarius
Analytical Chemistry, 2018, 90 (15), pp.8889-8895. ⟨10.1021/acs.analchem.8b01011⟩
Journal articles hal-01941805v1

Electrodeposition of silver amalgam particles on ITO – Towards novel electrode material

Ales Danhel , Filip Ligmajer , Tomas Sikola , Alain Walcarius , Miroslav Fojta
Journal of Electroanalytical Chemistry, 2018, 821, pp.53-59. ⟨10.1016/j.jelechem.2017.12.008⟩
Journal articles hal-01941809v1
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Design and properties of a novel radiopaque injectable apatitic calcium phosphate cement, suitable for image-guided implantation

Myriam Le Ferrec , Charlotte Mellier , Florian Boukhechba , Thomas Le Corroller , Daphne Guenoun
Journal of Biomedical Materials Research Part B: Applied Biomaterials, 2018, 106, pp.2786-2795. ⟨10.1002/jbm.b.34059⟩
Journal articles hal-01898264v1

Scanning gel electrochemical microscopy (SGECM): The potentiometric measurements

Ning Dang , Mathieu Etienne , Alain Walcarius , Liang Liu
Electrochemistry Communications, 2018, 97, pp.64-67. ⟨10.1016/j.elecom.2018.10.020⟩
Journal articles hal-01941799v1

Electrocatalytic Biosynthesis using a Bucky Paper Functionalized by [Cp*Rh(bpy)Cl] + and a Renewable Enzymatic Layer

Lin Zhang , Mathieu Etienne , Neus Vilà , Thi Xuan Huong Le , Gert-Wieland Kohring
ChemCatChem, 2018, 10 (18), pp.4067-4073. ⟨10.1002/cctc.201800681⟩
Journal articles hal-01941802v1

Molecular and Biological Catalysts Coimmobilization on Electrode by Combining Diazonium Electrografting and Sequential Click Chemistry

Lin Zhang , Neus Vilà , Alain Walcarius , Mathieu Etienne
ChemElectroChem, 2018, 5 (16), pp.2208-2217. ⟨10.1002/celc.201800258⟩
Journal articles hal-01941804v1

Mesoporous Silica Thin Films for Improved Electrochemical Detection of Paraquat

Tauqir Nasir , Grégoire Herzog , M. Hebrant , Christelle Despas , Liang Liu
ACS Sensors, 2018, 3 (2), pp.484 - 493. ⟨10.1021/acssensors.7b00920⟩
Journal articles hal-01795506v1

Silica-based electrochemical sensors and biosensors: Recent trends

Alain Walcarius
Current Opinion in Electrochemistry, 2018, 10, pp.88-97. ⟨10.1016/j.coelec.2018.03.017⟩
Journal articles hal-01941803v1

L’essor des films de silice mésoporeuse en électrochimie

Alain Walcarius
L'Actualité Chimique, 2018, 430-431, pp.73-78
Journal articles hal-01941808v1

Palladium-Prussian blue nanoparticles; as homogeneous and heterogeneous electrocatalysts

Prem.C. Pandey , Shwarnima Singh , Alain Walcarius
Journal of Electroanalytical Chemistry, 2018, 823, pp.747-754. ⟨10.1016/j.jelechem.2018.07.026⟩
Journal articles hal-01941806v1

MS2 and Qβ bacteriophages reveal the contribution of surface hydrophobicity on the mobility of non-enveloped icosahedral viruses in SDS-based capillary zone electrophoresis

Guillaume Sautrey , Adrien Brié , C. Gantzer , Alain Walcarius
Electrophoresis, 2018, 39 (2), pp.377 - 385. ⟨10.1002/elps.201700352⟩
Journal articles hal-01891111v1

Porous and Transparent Metal-oxide Electrodes : Preparation Methods and Electroanalytical Application Prospects

Maciej Mierzwa , Emmanuel Lamouroux , Alain Walcarius , Mathieu Etienne
Electroanalysis, 2018, 30 (7), pp.1241 - 1258. ⟨10.1002/elan.201800020⟩
Journal articles hal-01889029v1
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Kinetics of the electrochemically-assisted deposition of sol–gel films

Liang Liu , Alain Walcarius
Physical Chemistry Chemical Physics, 2017, 19 (23), pp.14972 - 14983. ⟨10.1039/c7cp01775h⟩
Journal articles hal-01804035v1
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A straightforward approach to enhance the textural, mechanical and biological properties of injectable calcium phosphate apatitic cements (CPCs): CPC/blood composites, a comprehensive study

Charlotte Mellier , François-Xavier Lefèvre , Franck Fayon , Valerie Montouillout , Christelle Despas
Acta Biomaterialia, 2017, 62, pp.328 - 339. ⟨10.1016/j.actbio.2017.08.040⟩
Journal articles inserm-01856304v1

Covalent Immobilization of (2,2′-Bipyridyl) (Pentamethylcyclopentadienyl)-Rhodium Complex on a Porous Carbon Electrode for Efficient Electrocatalytic NADH Regeneration

Lin Zhang , Neus Vilà , Gert-Wieland Kohring , Alain Walcarius , Mathieu Etienne
ACS Catalysis, 2017, 7 (7), pp.4386-4394. ⟨10.1021/acscatal.7b00128⟩
Journal articles hal-01941812v1

Vertically Aligned and Ordered One-Dimensional Mesoscale Polyaniline

Grégoire Herzog , Alonso Gamero-Quijano , Cheryl Karman , Neus Vilà , Alain Walcarius
Langmuir, 2017, 33 (17), pp.4224 - 4234. ⟨10.1021/acs.langmuir.7b00892⟩
Journal articles hal-01795561v1

Multi-layered, vertically-aligned and functionalized mesoporous silica films generated by sequential electrochemically assisted self-assembly

Gianmarco Giordano , Neus Vila , Emmanuel Aubert , Jaafar Ghanbaja , Alain Walcarius
Electrochimica Acta, 2017, 237, pp.227 - 236. ⟨10.1016/j.electacta.2017.03.220⟩
Journal articles hal-01804022v1

Copper Nanowires through Oriented Mesoporous Silica: A Step towards Protected and Parallel Atomic Switches

Yong Ai , Hassiba Smida , Jalal Ghilane , Neus Vilà , Jaafar Ghanbaja
Scientific Reports, 2017, 7 (1), pp.17752. ⟨10.1038/s41598-017-17048-z⟩
Journal articles hal-01941810v1

Physical Chemistry in France

Francesca Ingrosso , Manuel Ruiz-Lopez , Alain Walcarius
ChemPhysChem, 2017, 18 (19), pp.2558-2559. ⟨10.1002/cphc.201700907⟩
Journal articles hal-01941811v1
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Decorating soft electrified interfaces: From molecular assemblies to nano-objects

Lukasz Poltorak , Alonso Gamero-Quijano , Grégoire Herzog , Alain Walcarius
Applied Materials Today, 2017, 9, pp.533 - 550. ⟨10.1016/j.apmt.2017.10.001⟩
Journal articles hal-01795577v1

Recent Trends on Electrochemical Sensors Based on Ordered Mesoporous Carbon

Alain Walcarius
Sensors, 2017, 17 (8), ⟨10.3390/s17081863⟩
Journal articles hal-01767802v1

3-Aminopropyltrimethoxysilane mediated solvent induced synthesis of gold nanoparticles for biomedical applications

Prem Pandey , Gunjan Pandey , Alain Walcarius
Materials Science and Engineering: C, 2017, 79, pp.45 - 54. ⟨10.1016/j.msec.2017.05.009⟩
Journal articles hal-01804030v1

Indirect amperometric detection of non-redox ions using a ferrocene-functionalized and oriented mesoporous silica thin film electrode

Cheryl Karman , Neus Vilà , Christelle Despas , Alain Walcarius
Electrochimica Acta, 2017, 228, pp.659-666. ⟨10.1016/j.electacta.2017.01.126⟩
Journal articles hal-01941813v1

Clickable Bifunctional and Vertically Aligned Mesoporous Silica Films

Neus Vilà , Jaafar Ghanbaja , Alain Walcarius
Advanced Materials Interfaces, 2016, 3 (2), ⟨10.1002/admi.201500440⟩
Journal articles hal-01498438v1

An inorganic-organic hybrid material from the co-intercalation of a cationic surfactant and thiourea within montmorillonite layers: application to the sensitive stripping voltammetric detection of Pb2+ and Cd2+ ions

Guy B. Ngassa Piegang , Ignas Kenfack Tonle , Alain Walcarius , Emmanuel Ngameni
Comptes Rendus. Chimie, 2016, 19 (7), pp.789-797. ⟨10.1016/j.crci.2015.08.008⟩
Journal articles hal-01503742v1

Molecular Sieving with Vertically Aligned Mesoporous Silica Films and Electronic Wiring through Isolating Nanochannels

Neus Vilà , Erwan André , Roberto Ciganda , Jaime Ruiz , Didier Astruc
Chemistry of Materials, 2016, 28 (8), pp.2511-2514. ⟨10.1021/acs.chemmater.6b00716⟩
Journal articles hal-01505214v1
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Local pH changes triggered by photoelectrochemistry for silica condensation at the liquid-liquid interface

Lukasz Poltorak , Marc Hébrant , Mohana Afsharian , Mathieu Etienne , Grégoire Herzog
Electrochimica Acta, 2016, 188, pp.71-77. ⟨10.1016/j.electacta.2015.11.107⟩
Journal articles hal-01504769v1

Visualization of Diffusion within Nanoarrays

Yang Liu , Angelika Holzinger , Peter Knittel , Lukasz Poltorak , Alonso Gamero-Quijano
Analytical Chemistry, 2016, 88 (13), pp.6689-6695. ⟨10.1021/acs.analchem.6b00513⟩
Journal articles hal-01507495v1

Electrografting of 3-Aminopropyltriethoxysilane on a Glassy Carbon Electrode for the Improved Adhesion of Vertically Oriented Mesoporous Silica Thin Films

Tauqir Nasir , Lin Zhang , Neus Vilà , Grégoire Herzog , Alain Walcarius
Langmuir, 2016, 32 (17), pp.4323 - 4332. ⟨10.1021/acs.langmuir.6b00798⟩
Journal articles hal-01500705v1

Immobilization of Cysteine-Tagged Proteins on Electrode Surfaces by Thiol–Ene Click Chemistry

Lin Zhang , Neus Vilà , Tobias Klein , Gert-Wieland Kohring , Ievgen Mazurenko
ACS Applied Materials & Interfaces, 2016, 8 (27), pp.17591-17598. ⟨10.1021/acsami.6b02364⟩
Journal articles hal-01941817v1

Amplified Charge Transfer for Anionic Redox Probes through Oriented Mesoporous Silica Thin Films

Cheryl Karman , Neus Vilà , Alain Walcarius
ChemElectroChem, 2016, 3 (12), pp.2130-2137. ⟨10.1002/celc.201600303⟩
Journal articles hal-01941814v1

Enzymatic bioreactor for simultaneous electrosynthesis and energy production

Ievgen Mazurenko , Mathieu Etienne , Gert-Wieland Kohring , François Lapicque , Alain Walcarius
Electrochimica Acta, 2016, 199, pp.342 - 348. ⟨10.1016/j.electacta.2016.02.126⟩
Journal articles hal-01924811v1

Macroporous carbon nanotube-carbon composite electrodes

Ievgen Mazurenko , Mathieu Etienne , Gregory Francius , Ivan Vakulko , Alain Walcarius
Carbon, 2016, 109, pp.106-116. ⟨10.1016/j.carbon.2016.07.050⟩
Journal articles hal-01941816v1

Surface modification and porosimetry of vertically aligned hexagonal mesoporous silica films

Calum Robertson , Andrew w. Lodge , Peter Basa , Marina Carravetta , Andrew Hector
RSC Advances, 2016, 6 (114), pp.113432-113441. ⟨10.1039/C6RA23059H⟩
Journal articles hal-01941815v1

Mesoporous Materials-Based Electrochemical Enzymatic Biosensors

Mathieu Etienne , Lin Zhang , Neus Vilà , Alain Walcarius
Electroanalysis, 2015, 27 (9, SI), pp.2028-2054. ⟨10.1002/elan.201500172⟩
Journal articles hal-01504775v1
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Mesoporous silica thin films for molecular sieving and electrode surface protection against biofouling

Maria Bueno Serrano , Christelle Despas , Grégoire Herzog , Alain Walcarius
Electrochemistry Communications, 2015, 52, pp.34-36. ⟨10.1016/j.elecom.2015.01.010⟩
Journal articles hal-01504773v1

Electrochemical response of vertically-aligned, ferrocene-functionalized mesoporous silica films: effect of the supporting electrolyte

Neus Vilà , Alain Walcarius
Electrochimica Acta, 2015, 179, pp.304 - 314. ⟨10.1016/j.electacta.2015.02.169⟩
Journal articles hal-01498766v1

Preparation of ordered and oriented mesoporous silica thin films bearing octyl or hexadecyl groups by electrochemically assisted self-assembly and evaluation of their transport properties

Christelle Despas , Nataliya A. Vodolazkaya , Jaafar Ghanbaja , Alain Walcarius
Journal of Solid State Electrochemistry, 2015, 19 (7), pp.2075-2085. ⟨10.1007/s10008-014-2726-2⟩
Journal articles hal-01343998v1

Electrochemically-assisted deposition by local pH tuning: a versatile tool to generate ordered mesoporous silica thin films and layered double hydroxide materials

Mousty Christine , Alain Walcarius
Journal of Solid State Electrochemistry, 2015, 19, pp.1905-1931. ⟨10.1007/s10008-014-2570-4⟩
Journal articles hal-01180242v1

Mesoporous Materials-Based Electrochemical Sensors

Alain Walcarius
Electroanalysis, 2015, 27 (6), pp.1303-1340. ⟨10.1002/elan.201400628⟩
Journal articles hal-01504774v1

Ordered mesoporous silica films with pores oriented perpendicular to a titanium nitride substrate

Calum Robertson , Richard Beanland , Stuart A. Boden , Andrew L. Hector , Reza J. Kashtiban
Physical Chemistry Chemical Physics, 2015, 17 (6), pp.4763-4770. ⟨10.1039/c4cp05730a⟩
Journal articles hal-01505370v1

Immobilization of membrane-bounded (S)-mandelate dehydrogenase in sol-gel matrix for electroenzymatic synthesis

Ievgen Mazurenko , Wissam Ghach , Gert-Wieland Kohring , Christelle Despas , Alain Walcarius
Bioelectrochemistry, 2015, 104, pp.65-70. ⟨10.1016/j.bioelechem2015.03.004⟩
Journal articles hal-01501638v1

Organoclay-modified electrodes: preparation, characterization and recent electroanalytical applications

Ignas K. Tonle , Emmanuel Ngameni , Francis M. M. Tchieno , Alain Walcarius
Journal of Solid State Electrochemistry, 2015, 19 (7), pp.1949-1973. ⟨10.1007/s10008-014-2728-0⟩
Journal articles hal-01505371v1

Tetrazine-functionalized and vertically-aligned mesoporous silica films with electrochemical activity and fluorescence properties

Neus Vilà , Clémence Allain , Pierre Audebert , Alain Walcarius
Electrochemistry Communications, 2015, 59, pp.9-12. ⟨10.1016/j.elecom.2015.06.012⟩
Journal articles hal-01507497v1

Highly Organized Ferrocene-Functionalized Nanoporous Silica Films with an Extremely Fast Electron-Transfer Rate for an Intrinsically Nonconducting Oxide-Modified Electrode

Pierre Audebert , Neus Vilà , Clémence Allain , Franck Maisonneuve , Alain Walcarius
ChemElectroChem, 2015, 2 (11), pp.1695--1698. ⟨10.1002/celc.201500227⟩
Journal articles hal-01242907v1

Electrochemistry supported by zeolites, clays, layered double hydroxides, ordered mesoporous (organo)silicas, and related materials

Antonio Doménech-Carbó , Alain Walcarius
Journal of Solid State Electrochemistry, 2015, 19 (7), pp.1885 - 1886. ⟨10.1007/s10008-015-2927-3⟩
Journal articles hal-01500442v1

Électrogénération de films mésoporeux orientés et fonctionnalisés

Alain Walcarius
Les Techniques de l'Ingenieur, 2015, pp.RE246 v1
Journal articles hal-01500597v1
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Electrochemical characterization of liquid-liquid micro-interfaces modified with mesoporous silica

Lukasz Poltorak , Karima Morakchi , Grégoire Herzog , Alain Walcarius
Electrochimica Acta, 2015, 179, pp.9 - 15. ⟨10.1016/j.electacta.2015.01.129⟩
Journal articles hal-01498764v1
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Electrochemically Assisted Generation of Silica Deposits Using a Surfactant Template at Liquid/Liquid Microinterfaces

Lukasz Poltorak , Grégoire Herzog , Alain Walcarius
Langmuir, 2014, 30 (38), pp.11453-11463. ⟨10.1021/la501938g⟩
Journal articles hal-01498771v1
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Interfacial processes studied by coupling electrochemistry at the polarised liquid-liquid interface with in situ confocal Raman spectroscopy

Lukasz Poltorak , M. Dossot , Grégoire Herzog , Alain Walcarius
Physical Chemistry Chemical Physics, 2014, 16 (48), pp.26955-26962. ⟨10.1039/c4cp03254c⟩
Journal articles hal-01503744v1

Glassy carbon electrode modified with a film of poly(Toluidine Blue O) and carbon nanotubes for nitrite detection

Delia Gligor , Alain Walcarius
Journal of Solid State Electrochemistry, 2014, 18 (6), pp.1519 - 1528. ⟨10.1007/s10008-013-2365-z⟩
Journal articles hal-01496944v1

High Frequency Impedance Measurement as a Relevant Tool to Monitor Apatitic Cement Setting Reaction

Christelle Despas , Verena Schnitzler , Pascal Janvier , Franck Fayon , Dominique Massiot
Acta Biomaterialia, 2014, 10 (2), pp.940-950. ⟨10.1016/j.actbio.2013.10.019⟩
Journal articles hal-00904162v1

Silica-Based Nanoporous Materials

Veronika Urbanova , Alain Walcarius
Journal of Inorganic and General Chemistry / Zeitschrift für anorganische und allgemeine Chemie, 2014, 640 (3-4, SI), pp.537-546. ⟨10.1002/zaac.201300442⟩
Journal articles hal-01507498v1

Sol-gel based `artificial' biofilm from Pseudomonas fluorescens using bovine heart cytochrome c as electron mediator

Wissam Ghach , Mathieu Etienne , Veronika Urbanova , Frédéric P. A. Jorand , Alain Walcarius
Electrochemistry Communications, 2014, 38, pp.71-74. ⟨10.1016/j.elecom.2013.11.001⟩
Journal articles hal-01507026v1

Application of ammonium-selective zeolite for enhancement of conductometric bi-enzyme biosensor for L-arginine detection

O. Y. Saiapina , N. J. Matsishin , V. M. Pyeshkova , O. P. Soldatkin , V. G. Melnik
Sensorna elektronìka ì mìkrosistemnì tehnologìï = Sensor Electronics and Microsystem Technologies, 2014, 9 (4), pp.49-66. ⟨10.18524/1815-7459.2012.4.115126⟩
Journal articles hal-01941832v1

One-step co-intercalation of cetyltrimethylammonium and thiourea in smectite and application of the organoclay to the sensitive electrochemical detection of Pb(II)

Guy B. Ngassa Piegang , Ignas K. Tonle , Alain Walcarius , Emmanuel Ngameni
Applied Clay Science, 2014, 99, pp.297-305. ⟨10.1016/j.c1ay.2014.07.014⟩
Journal articles hal-01505374v1

Electrochemically Assisted Generation of Highly Ordered Azide-Functionalized Mesoporous Silica for Oriented Hybrid Films

Neus Vila , Jaafar Ghanbaja , Emmanuel Aubert , Alain Walcarius
Angewandte Chemie International Edition, 2014, 53 (11), pp.2945-2950. ⟨10.1002/anie.201309447⟩
Journal articles hal-01343999v1

Electro-Assisted Self-Assembly of Cetyltrimethylammonium-Templated Silica Films in Aqueous Media: Critical Effect of Counteranions on the Morphology and Mesostructure Type

Yann Guillemin , Jaafar Ghanbaja , Emmanuel Aubert , Mathieu Etienne , Alain Walcarius
Chemistry of Materials, 2014, 26 (5), pp.1848-1858. ⟨10.1021/cm404014c⟩
Journal articles hal-01344000v1

Tetrabutylammonium-modified clay film electrodes: Characterization and application to the detection of metal ions

Adela Maghear , Mihaela Tertis , Lumina Fritea , Iuliu O. Marian , Emil Indrea
Talanta, 2014, 125, pp.36-44. ⟨10.1016/j.talanta.2014.02.042⟩
Journal articles hal-01507500v1

An l-glucitol oxidizing dehydrogenase from Bradyrhizobium japonicum USDA 110 for production of d-sorbose with enzymatic or electrochemical cofactor regeneration

Sabrina Gauer , Zhijie Wang , Harm Otten , Mathieu Etienne , Morten Jannik Bjerrum
Applied Microbiology and Biotechnology, 2014, 98 (7), pp.3023 - 3032. ⟨10.1007/s00253-013-5180-7⟩
Journal articles hal-01497266v1

Clay-mesoporous silica composite films generated by electro-assisted self-assembly

Adela Maghear , Mathieu Etienne , Mihaela Tertiş , Robert Săndulescu , Alain Walcarius
Electrochimica Acta, 2013, 112, pp.333 - 341. ⟨10.1016/j.electacta.2013.08.119⟩
Journal articles hal-01498434v1

Electrochemically assisted self-assembly of ordered and functionalized mesoporous silica films: impact of the electrode geometry and size on film formation and properties

Grégoire Herzog , Emilie Sibottier , Mathieu Etienne , Alain Walcarius
Faraday Discussions, 2013, 164, ⟨10.1039/C3FD00021D⟩
Journal articles hal-01500427v1

Metal ion removal by ultrafiltration of colloidal suspensions of organically modified silica

Marc Hébrant , Maureen Rose-Helene , Alain Walcarius
Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2013, 417, pp.65-72. ⟨10.1016/j.colsurfa.2012.10.046⟩
Journal articles hal-01504777v1

Reagentless D-sorbitol biosensor based on D-sorbitol dehydrogenase immobilized in a sol-gel carbon nanotubes-poly(methylene green) composite

Zhijie Wang , Mathieu Etienne , Veronika Urbanova , Gert-Wieland Kohring , Alain Walcarius
Analytical and Bioanalytical Chemistry, 2013, 405 (11), pp.3899-3906. ⟨10.1007/s00216-013-6820-6⟩
Journal articles hal-01505609v1

Interest of the Sol-Gel Approach for Multiscale Tailoring of Porous Bioelectrode Surfaces

Yemima Bon Saint Come , Hélène Lalo , Zhijie Wang , Gert-Wieland Kohring , Rolf Hempelmann
Electroanalysis, 2013, 25 (3, SI), pp.621-629. ⟨10.1002/elan.201200319⟩
Journal articles hal-01503747v1

Characterization of MCM-41 with Immobilized Bi-functional SH/SO3H Layer

N. V. Zaitsev , Alain Walcarius , V. N. Zaitsev
Journal of Inorganic and Organometallic Polymers and Materials, 2013, 23 (6), pp.1409 - 1416. ⟨10.1007/s10904-013-9943-5⟩
Journal articles hal-01497894v1

Platinum Ultramicroelectrodes Modified with Electrogenerated Surfactant-Templated Mesoporous Organosilica Films: Effect of Film Formation Conditions on Its Performance in Preconcentration Electroanalysis

Gregoire Herzog , Natalya A. Vodolazkaya , Alain Walcarius
Electroanalysis, 2013, 25 (12), pp.2595-2603. ⟨10.1002/elan.201300415⟩
Journal articles hal-01505610v1

Electrophoretic deposition of macroporous carbon nanotube assemblies for electrochemical applications

Ievgen Mazurenko , Mathieu Etienne , Oksana Tananaiko , Veronika Urbanova , Vladimir Zaitsev
Carbon, 2013, 53, pp.302 - 312. ⟨10.1016/j.carbon.2012.11.011⟩
Journal articles hal-01500715v1

Electrochemically assisted bacteria encapsulation in thin hybrid sol–gel films

Wissam Ghach , Mathieu Etienne , Patrick Billard , Frédéric P. A. Jorand , Alain Walcarius
Journal of materials chemistry‎ B, 2013, 1 (7), pp.1052-1059. ⟨10.1039/c2tb00421f⟩
Journal articles hal-01115124v1

Mesoporous materials and electrochemistry

Alain Walcarius
Chemical Society Reviews, 2013, 42 (9), pp.4098-4140. ⟨10.1039/c2cs35322a⟩
Journal articles hal-01504778v1

Sol-gel Approaches for Elaboration of Polyol Dehydrogenase-Based Bioelectrodes

Veronika Urbanova , Gert-Wieland Kohring , Tobias Klein , Zhijie Wang , Olcay Mert
Zeitschrift für Physikalische Chemie, 2013, 227 (5), pp.667-689. ⟨10.1524/zpch.2013.0324⟩
Journal articles hal-01507027v1

One Step Deposition of Sol-Gel Carbon Nanotubes Biocomposite for Reagentless Electrochemical Devices

Veronika Urbanova , Mathieu Etienne , Alain Walcarius
Electroanalysis, 2013, 25 (1, SI), pp.85-93. ⟨10.1002/elan.201200407⟩
Journal articles hal-01505375v1
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Bimodal mesoporous titanium dioxide anatase films templated by a block polymer and an ionic liquid: influence of the porosity on the permeability

Sébastien Sallard , Michael Schröder , Cédric Boissière , Christian Dunkel , Mathieu Etienne
Nanoscale, 2013, 5 (24), pp.12316-12329. ⟨10.1039/c3nr02732e⟩
Journal articles hal-01118857v1
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In-situ formation of mesoporous silica films controlled by ion transfer voltammetry at the polarized liquid-liquid interface

Lukasz Poltorak , Gregoire Herzog , Alain Walcarius
Electrochemistry Communications, 2013, 37, pp.76-79. ⟨10.1016/j.elecom.2013.10.018⟩
Journal articles hal-01503748v1

Functionalized carbon nanotubes for bioelectrochemical applications: Critical influence of the linker

Veronika Urbanova , Naoual Allali , Wissam Ghach , Victor Mamane , Mathieu Etienne
Journal of Electroanalytical Chemistry, 2013, 707, pp.129-133. ⟨10.1016/j.jelechem.2013.08.029⟩
Journal articles hal-01493932v1

Electrochemical approaches for the fabrication and/or characterization of pure and hybrid templated mesoporous oxide thin films: a review

Mathieu Etienne , Yann Guillemin , David Grosso , Alain Walcarius
Analytical and Bioanalytical Chemistry, 2013, 405 (5), pp.1497-1512. ⟨10.1007/s00216-012-6334-7⟩
Journal articles hal-01289744v1

Chromium(VI) removal via reduction–sorption on bi-functional silica adsorbents

Nataliya Zaitsev , Vladimir Zaitsev , Alain Walcarius
Journal of Hazardous Materials, 2013, 250-251, pp.454 - 461. ⟨10.1016/j.jhazmat.2013.02.019⟩
Journal articles hal-01497952v1

Nanomaterials for bio-functionalized electrodes: recent trends

Alain Walcarius , Shelley D. Minteer , Joseph Wang , Yuehe Lin , Arben Merkoci
Journal of materials chemistry‎ B, 2013, 1 (38), pp.4878-4908. ⟨10.1039/c3tb20881h⟩
Journal articles hal-01505219v1

Amperometric biosensor for the D-sorbitol determination based on glassy carbon electrode modified with biocomposite film

Ievgen Mazurenko , O Shevchenko , Oksana Tananaiko , Mathieu Etienne , Alain Walcarius
Metody i Ob'ekty Khimicheskogo Analiza = Methods and Objects of Chemical Analysis, 2012, 7 (4), pp.176-183
Journal articles hal-01941823v1

Durable cofactor immobilization in sol–gel bio-composite thin films for reagentless biosensors and bioreactors using dehydrogenases

Zhijie Wang , Mathieu Etienne , Fabienne Quilès , Gert-Wieland Kohring , Alain Walcarius
Biosensors and Bioelectronics, 2012, 32 (1), pp.111-117. ⟨10.1016/j.bios.2011.11.043⟩
Journal articles hal-01941837v1

Covalent functionalization of few-wall carbon nanotubes by ferrocene derivatives for bioelectrochemical devices

Naoual Allali , Veronika Urbanova , Victor Mamane , Jeremy Waldbock , Mathieu Etienne
physica status solidi (b), 2012, 249 (12), pp.2349-2352. ⟨10.1002/pssb.201200098⟩
Journal articles hal-01941822v1

Electrocatalysis, sensors and biosensors in analytical chemistry based on ordered mesoporous and macroporous carbon-modified electrodes

Alain Walcarius
Trends in Analytical Chemistry, 2012, 38, pp.79-97. ⟨10.1016/j.trac.2012.05.003⟩
Journal articles hal-01941828v1

One pot synthesis of ordered mesoporous organosilica particles bearing propyl-, octyl- and hexadecyl-chains

Natalya Vodolazkaya , Christelle Despas , Bénédicte Lebeau , Claire Marichal , Alain Walcarius
Journal of Sol-Gel Science and Technology, 2012, 63 (3), pp.587-594. ⟨10.1007/s10971-012-2816-5⟩
Journal articles hal-01941827v1

A novel highly sensitive zeolite-based conductometric microsensor for ammonium determination

O. Y. Saiapina , S. V. Dzyadevych , Alain Walcarius , Nicole Jaffrezic-Renault
Analytical Letters, 2012, 45 (11), pp.1467-1484. ⟨10.1080/00032719.2012.675487⟩
Journal articles hal-00879584v1

Electrophoretically deposited carbon nanotubes as a novel support for electrogenerated silica–dehydrogenase bioelectrodes

Ievgen Mazurenko , Mathieu Etienne , Oksana Tananaiko , Vladimir Zaitsev , Alain Walcarius
Electrochimica Acta, 2012, 83, pp.359-366. ⟨10.1016/j.electacta.2012.07.068⟩
Journal articles hal-01941826v1

Speciation of partly oxidized thiol-organosilica surface

Nataliya Shevchenko Zaitseva , N.G. Kobylinska , Alain Walcarius , Vladimir N. Zaitsev
Metody i Ob'ekty Khimicheskogo Analiza = Methods and Objects of Chemical Analysis, 2012, 7, pp.60-67
Journal articles hal-01941820v1

Site Selective Generation of Sol–Gel Deposits in Layered Bimetallic Macroporous Electrode Architectures

Hélène Lalo , Yémima Bon-Saint-Côme , Bernard Plano , Mathieu Etienne , Alain Walcarius
Langmuir, 2012, 28 (5), pp.2323-2326. ⟨10.1021/la204679u⟩
Journal articles hal-01941835v1

Electrocatalytic and Sensors Properties of Natural Smectite Type Clay towards the Detection of Paraquat Using a Film-Modified Electrode

H. Tcheumi , I. Tonle , Alain Walcarius , E. Ngameni
American Journal of Analytical Chemistry, 2012, 03 (11), pp.746-754. ⟨10.4236/ajac.2012.311099⟩
Journal articles hal-01941821v1

Dehydrogenase-Based Reagentless Biosensors: Electrochemically Assisted Deposition of Sol-Gel Thin Films on Functionalized Carbon Nanotubes

Zhijie Wang , Mathieu Etienne , Sascha Pöller , Wolfgang Schuhmann , Gert-Wieland Kohring
Electroanalysis, 2012, 24 (2), pp.376-385. ⟨10.1002/elan.201100574⟩
Journal articles hal-01941836v1

Few-wall carbon nanotubes covalently functionalized by ferrocene groups for bioelectrochemical devices.

Naoual Allali , Veronika Urbanova , Victor Mamane , Jeremy Waldbock , Mathieu Etienne
MRS Proceedings, 2012, 1451, pp.111-116. ⟨10.1557/opl.2012.1337⟩
Journal articles hal-02445352v1

Microscale Controlled Electrogeneration of Patterned Mesoporous Silica Thin Films

Yann Guillemin , Mathieu Etienne , Émilie Sibottier , Alain Walcarius
Chemistry of Materials, 2011, 23 (24), pp.5313-5322. ⟨10.1021/cm202668t⟩
Journal articles hal-01941840v1

Investigation of alendronate-doped Apatitic Cements as a Potential Technology for the Prevention of Osteoporotic Hip Fractures: Critical Influence of the Drug Introduction Mode on the In Vitro Cement Properties.

V. Schnitzler , F. Fayon , C. Despas , I. Khairoun , C. Mellier
Acta Biomaterialia, 2011, 7, pp.759-770. ⟨10.1016/j.actbio.2010.09.017⟩
Journal articles hal-00608513v1

Controlled Electrochemically-Assisted Deposition of Sol−Gel Biocomposite on Electrospun Platinum Nanofibers

Ievgen Mazurenko , Mathieu Etienne , Rainer Ostermann , Bernd Smarsly , Oksana Tananaiko
Langmuir, 2011, 27 (11), pp.7140-7147. ⟨10.1021/la200069z⟩
Journal articles hal-01941873v1

Electrogeneration of ultra-thin silica films for the functionalization of macroporous electrodes

Fengli Qu , Rihab Nasraoui , Mathieu Etienne , Yémima Bon Saint Côme , Alexander Kuhn
Electrochemistry Communications, 2011, 13 (2), pp.138-142. ⟨10.1016/j.elecom.2010.11.034⟩
Journal articles hal-01941882v1

Electrochemically assisted deposition of sol–gel bio-composite with co-immobilized dehydrogenase and diaphorase

Zhijie Wang , Mathieu Etienne , Gert-Wieland Kohring , Yémima Bon-Saint-Côme , Alexander Kuhn
Electrochimica Acta, 2011, 56 (25), pp.9032-9040. ⟨10.1016/j.electacta.2011.05.130⟩
Journal articles hal-01941867v1

Kinetics of the complexation of Ni2+ ions by 5-phenyl-azo-8-hydroxyquinoline grafted on colloidal silica particles

Marc Hébrant , Maureen Rose-Hélène , Jean-Pierre Joly , Alain Walcarius
Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2011, 380 (1-3), pp.261-269. ⟨10.1016/j.colsurfa.2011.02.047⟩
Journal articles hal-01941875v1

Multiscale-Tailored Bioelectrode Surfaces for Optimized Catalytic Conversion Efficiency

Yémima Bon Saint Côme , Hélène Lalo , Zhijie Wang , Mathieu Etienne , Janine Gajdzik
Langmuir, 2011, 27 (20), pp.12737-12744. ⟨10.1021/la201930m⟩
Journal articles hal-01941841v1

Conductometric enzyme biosensors based on natural zeolite clinoptilolite for urea determination

O. Y. Saiapina , V. M. Pyeshkova , O. O. Soldatkin , V. G. Melnik , B. Akata Kurç
Materials Science and Engineering: C, 2011, 31 (7), pp.1490-1497. ⟨10.1016/j.msec.2011.06.003⟩
Journal articles hal-00809643v1

Factors affecting the electrochemical regeneration of NADH by (2,2′-bipyridyl) (pentamethylcyclopentadienyl)-rhodium complexes: Impact on their immobilization onto electrode surfaces

Alain Walcarius , Rihab Nasraoui , Zhijie Wang , Fengli Qu , Veronika Urbanova
Bioelectrochemistry, 2011, 82 (1), pp.46-54. ⟨10.1016/j.bioelechem.2011.05.002⟩
Journal articles hal-01941842v1

Electrochemical response of ascorbic and uric acids at organoclay film modified glassy carbon electrodes and sensing applications

Justin Claude Kemmegne Mbouguen , Ignas Tonle Kenfack , Alain Walcarius , Emmanuel Ngameni
Talanta, 2011, 85 (1), pp.754-762. ⟨10.1016/j.talanta.2011.04.064⟩
Journal articles hal-01941871v1

Square Wave Voltammetric Determination of Lead(II) Ions Using a Carbon Paste Electrode Modified by a Thiol-Functionalized Kaolinite

Ignas Tonle , Sadok Letaief , Emmanuel Ngameni , Alain Walcarius , Christian Detellier
Electroanalysis, 2011, 23 (1), pp.245-252. ⟨10.1002/elan.201000467⟩
Journal articles hal-01941879v1

Electrochemical Screening of Redox Mediators for Electrochemical Regeneration of NADH

J. Gajdzik , J. Lenz , H. Natter , Alain Walcarius , G. Kohring
Journal of The Electrochemical Society, 2011, 159 (2), pp.F10-F16. ⟨10.1149/2.056202jes⟩
Journal articles hal-01941839v1

Electrochemical Generation of Thin Silica Films with Hierarchical Porosity

Mathieu Etienne , Sébastien Sallard , Michael Schröder , Yann Guillemin , Simone Mascotto
Chemistry of Materials, 2010, 22 (11), pp.3426-3432. ⟨10.1021/cm1004278⟩
Journal articles hal-01941890v1

Iron-enriched natural zeolite modified carbon paste electrode for H2O2 detection

Delia Gligor , Andrada Maicaneanu , Alain Walcarius
Electrochimica Acta, 2010, 55 (12), pp.4050-4056. ⟨10.1016/j.electacta.2010.02.058⟩
Journal articles hal-01941893v1

Electrochemical analysis of methylparathion pesticide by a gemini surfactant-intercalated clay-modified electrode

Hervé Leclerc Tcheumi , Ignas Kenfack Tonle , Emmanuel Ngameni , Alain Walcarius
Talanta, 2010, 81 (3), pp.972-979. ⟨10.1016/j.talanta.2010.01.049⟩
Journal articles hal-01941894v1

Surfactant-templated sol–gel silica thin films bearing 5-mercapto-1-methyl-tetrazole on carbon electrode for Hg(II) detection

Alfredo Sanchez , Alain Walcarius
Electrochimica Acta, 2010, 55 (13), pp.4201-4207. ⟨10.1016/j.electacta.2010.02.016⟩
Journal articles hal-01941891v1

Critical Effect of Polyelectrolytes on the Electrochemical Response of Dehydrogenases Entrapped in Sol-Gel Thin Films

Zhijie Wang , Mathieu Etienne , Gert Kohring , Alain Walcarius
Electroanalysis, 2010, 22 (17-18), pp.2092-2100. ⟨10.1002/elan.201000079⟩
Journal articles hal-01941886v1

Template-directed porous electrodes in electroanalysis

Alain Walcarius
Analytical and Bioanalytical Chemistry, 2010, 396 (1), pp.261-272. ⟨10.1007/s00216-009-3069-1⟩
Journal articles hal-01941896v1

Electrogeneration of highly methylated mesoporous silica thin films with vertically-aligned mesochannels and electrochemical monitoring of mass transport issues

Yann Guillemin , Mathieu Etienne , Emmanuel Aubert , Alain Walcarius
Journal of Materials Chemistry, 2010, 20 (32), pp.6799. ⟨10.1039/C0JM00305K⟩
Journal articles hal-01941884v1

Mesoporous organosilica adsorbents: nanoengineered materials for removal of organic and inorganic pollutants

Alain Walcarius , Louis Mercier
Journal of Materials Chemistry, 2010, 20 (22), pp.4478-4511. ⟨10.1039/B924316J⟩
Journal articles hal-01941895v1

Factors affecting the reactivity of thiol-functionalized mesoporous silica adsorbents toward mercury(II)

Cyril Delacôte , Fabrice O.M. Gaslain , Bénédicte Lebeau , Alain Walcarius
Talanta, 2009, 79 (3), pp.877-886. ⟨10.1016/j.talanta.2009.05.020⟩
Journal articles hal-01941903v1

Electroanalytical properties of haemoglobin in silica-nanocomposite films electrogenerated on pyrolitic graphite electrode

T. Rozhanchuk , O. Tananaiko , I. Mazurenko , M. Etienne , Alain Walcarius
Journal of Electroanalytical Chemistry, 2009, 625 (1), pp.33 - 39. ⟨10.1016/j.jelechem.2008.10.003⟩
Journal articles hal-01848482v1

Factors affecting copper(II) binding to multiarmed cyclam-grafted mesoporous silica in aqueous solution

Stéphanie Goubert-Renaudin , Mathieu Etienne , Stéphane Brandès , Michel Meyer , Franck Denat
Langmuir, 2009, 25 (17), pp.9804-9813. ⟨10.1021/la900892q⟩
Journal articles hal-00458563v1

Multiarm cyclam-grafted mesoporous silica: a strategy to improve the chemical stability of silica materials functionalized with amine ligands

Mathieu Etienne , Stéphanie Goubert-Renaudin , Yoann Rousselin , Claire Marichal , Franck Denat
Langmuir, 2009, 25 (5), pp.3137-3145. ⟨10.1021/la8032379⟩
Journal articles hal-00458562v1

Electrochemical sensors and biosensors based on heterogeneous carbon materials

Kurt Kalcher , Ivan Svancara , Marijo Buzuk , Karel Vytras , Alain Walcarius
Chemical Monthly = Monatshefte für Chemie, 2009, 140 (8), pp.861-889. ⟨10.1007/s00706-009-0131-9⟩
Journal articles hal-01941902v1

Carbon paste electrodes in the new millennium

Ivan Švancara , Alain Walcarius , Kurt Kalcher , Karel Vytřas
Central European Journal of Chemistry, 2009, 7 (4), pp.598-656. ⟨10.2478/s11532-009-0097-9⟩
Journal articles hal-01941899v1

1,8-Bis[3-(triethoxysilyl)propyl]-1,8-diazoniatricyclo[,8]hexadecane diiodide

Yoann Rousselin , Franck Denat , Bénédicte Lebeau , Alain Walcarius
Acta Crystallographica Section E : Structure Reports Online [2001-2014], 2009, E65 (10), pp.o2531. ⟨10.1107/S1600536809038112⟩
Journal articles hal-00458337v1

Oriented Mesoporous Silica Films Obtained by Electro-Assisted Self-Assembly (EASA)

Aurélie Goux , Mathieu Etienne , Emmanuel Aubert , Claude Lecomte , Jaafar Ghanbaja
Chemistry of Materials, 2009, 21 (4), pp.731-741. ⟨10.1021/cm8029664⟩
Journal articles hal-01941906v1

Analytical Chemistry with Silica Sol-Gels: Traditional Routes to New Materials for Chemical Analysis

Alain Walcarius , Maryanne Collinson
Annual Review of Analytical Chemistry, 2009, 2 (1), pp.121-143. ⟨10.1146/annurev-anchem-060908-155139⟩
Journal articles hal-01941905v1

Synthesis of dithiocarbamate-functionalized mesoporous silica-based materials: interest of one-step grafting

Stéphanie Goubert-Renaudin , Fabrice Gaslain , Claire Marichal , Bénédicte Lebeau , Raphaël Schneider
New Journal of Chemistry, 2009, 33, pp.528-537. ⟨10.1039/b811780b⟩
Journal articles hal-00371676v1

Carbon Paste Electrodes in Facts, Numbers, and Notes: A Review on the Occasion of the 50-Years Jubilee of Carbon Paste in Electrochemistry and Electroanalysis

Ivan Švancara , Karel Vytřas , Kurt Kalcher , Alain Walcarius , Joseph Wang
Electroanalysis, 2009, 21 (1), pp.7-28. ⟨10.1002/elan.200804340⟩
Journal articles hal-01941911v1

One-Step Preparation of Thiol-Functionalized Porous Clay Heterostructures: Application to Hg(II) Binding and Characterization of Mass Transport Issues

Aurélien Jieumboué Tchinda , Emmanuel Ngameni , Ignas Tonlé Kenfack , Alain Walcarius
Chemistry of Materials, 2009, 21 (18), pp.4111-4121. ⟨10.1021/cm8024022⟩
Journal articles hal-01941900v1

One-step preparation of thiol-modified mesoporous silica spheres with various functionalization levels and different pore structures

Fabrice Gaslain , Cyril Delacôte , Alain Walcarius , Bénédicte Lebeau
Journal of Sol-Gel Science and Technology, 2009, 49 (1), pp.112-124. ⟨10.1007/s10971-008-1845-6⟩
Journal articles hal-01941908v1

ChemInform Abstract: Electrochemistry with Micro- and Mesoporous Silicates

Alain Walcarius
ChemInform, 2009, 40 (16), ⟨10.1002/chin.200916221⟩
Journal articles hal-01849360v1

Prussian Blue electrodeposition within an oriented mesoporous silica film: preliminary observations

Aurélie Goux , Jaafar Ghanbaja , Alain Walcarius
Journal of Materials Science, 2009, 44 (24), pp.6601-6607. ⟨10.1007/s10853-009-3611-8⟩
Journal articles hal-01941897v1

Oriented Mesoporous Organosilica Films on Electrode: A New Class of Nanomaterials for Sensing

Mathieu Etienne , Aurélie Goux , Émilie Sibottier , Alain Walcarius
Journal of Nanoscience and Nanotechnology, 2009, 9 (4), pp.2398-2406. ⟨10.1166/jnn.2009.SE39⟩
Journal articles hal-01941913v1

Cyclam-functionalized silica-modified electrodes for selective determination of Cu(II)

Stéphanie Goubert-Renaudin , Mathieu Etienne , Yoann Rousselin , Franck Denat , Bénédicte Lebeau
Electroanalysis, 2009, 21 (3-5), pp.280-289. ⟨10.1002/elan.200804378⟩
Journal articles hal-00458565v1

Voltammetric detection of lead(II) using amide-cyclam-functionalized silica-modified carbon paste electrodes

Stéphanie Goubert-Renaudin , Mathieu Moreau , Christelle Despas , Michel Meyer , Franck Denat
Electroanalysis, 2009, 21 (15), pp.1731-1742. ⟨10.1002/elan.200904661⟩
Journal articles hal-00458568v1

Simultaneous Determination of Nickel and Cobalt as Chelates with 1-(2-Pyridylazo)-2-naphthol Using an LC Switching Column Method

Lydie Tzanis , Patrice Simon , Alain Walcarius
Chromatographia, 2008, 67 (11-12), pp.857-861. ⟨10.1365/s10337-008-0632-4⟩
Journal articles hal-01941917v1

Theory and Simulation of Diffusion−Reaction into Nano- and Mesoporous Structures. Experimental Application to Sequestration of Mercury(II)

Christian Amatore , Alexander Oleinick , Oleksiy Klymenko , Cyril Delacôte , Alain Walcarius
Analytical Chemistry, 2008, 80 (9), pp.3229-3243. ⟨10.1021/ac702420p⟩
Journal articles hal-01941920v1

Ordered porous thin films in electrochemical analysis

Alain Walcarius , Alexander Kuhn
Trends in Analytical Chemistry, 2008, 27 (7), pp.593 - 603. ⟨10.1016/j.trac.2008.03.011⟩
Journal articles hal-01827959v1

Orthopositronium annihilation and emission in mesostructured thin silica and silicalite-1 films

L. Liszkay , M.-F. Barthe , C. Corbel , P. Crivelli , P. Desgardin
Applied Surface Science, 2008, 255 (1), pp.187-190. ⟨10.1016/j.apsusc.2008.05.210⟩
Journal articles hal-01941914v1

Naphthidine di(radical cation)s-stabilized palladium nanoparticles for efficient catalytic Suzuki–Miyaura cross-coupling reactions

Christophe Desmarets , Rafik Omar-Amrani , Alain Walcarius , Jacques Lambert , Benoît Champagne
Tetrahedron, 2008, 64 (2), pp.372 - 381. ⟨10.1016/j.tet.2007.10.091⟩
Journal articles hal-01849614v1

Ion exchange and ion exchange voltammetry with functionalized mesoporous silica materials

V. Ganesan , Alain Walcarius
Materials Science and Engineering: B, 2008, 149 (2), pp.123-132. ⟨10.1016/j.mseb.2007.11.022⟩
Journal articles hal-01941921v1

Bifunctionalized Mesoporous Silicas for Cr(VI) Reduction and Concomitant Cr(III) Immobilization

Nataliya Shevchenko , Vladimir Zaitsev , Alain Walcarius
Environmental Science and Technology, 2008, 42 (18), pp.6922-6928. ⟨10.1021/es800677b⟩
Journal articles hal-01941915v1

Sorption of methylene blue on an organoclay bearing thiol groups and application to electrochemical sensing of the dye

Ignas K. Tonlé , Emmanuel Ngameni , Hervé Tcheumi , Victor Tchiéda , Cédric Carteret
Talanta, 2008, 74 (4), pp.489 - 497. ⟨10.1016/j.talanta.2007.06.006⟩
Journal articles hal-01849617v1

Positronium reemission yield from mesostructured silica films

L. Liszkay , C. Corbel , P. Perez , P. Desgardin , M.-F. Barthe
Applied Physics Letters, 2008, 92 (6), pp.063114. ⟨10.1063/1.2844888⟩
Journal articles hal-01941918v1

Electroanalytical Applications of Microporous Zeolites and Mesoporous (Organo)Silicas: Recent Trends

Alain Walcarius
Electroanalysis, 2008, 20 (7), pp.711 - 738. ⟨10.1002/elan.200704144⟩
Journal articles hal-01827806v1

Preconcentration Electroanalysis at Surfactant-Templated Thiol-Functionalized Silica Thin Films

Mathieu Etienne , Jérôme Cortot , Alain Walcarius
Electroanalysis, 2007, 19 (2-3), pp.129 - 138. ⟨10.1002/elan.200603677⟩
Journal articles hal-01848657v1

Quaternary ammonium functionalized clay film electrodes modified with polyphenol oxidase for the sensitive detection of catechol

Justin Kemmegne Mbouguen , Emmanuel Ngameni , Alain Walcarius
Biosensors and Bioelectronics, 2007, 23 (2), pp.269 - 275. ⟨10.1016/j.bios.2007.04.008⟩
Journal articles hal-01848982v1

A chemical solution deposition route to nanopatterned inorganic material surfaces.

Mathieu Etienne , Alida Quach , David Grosso , Lionel Nicole , Clément Sanchez
Chemistry of Materials, 2007, 19, pp.3717-3725
Journal articles hal-00334271v1

Electrochemically assisted self-assembly of mesoporous silica thin films

Alain Walcarius , E. Sibottier , M. Etienne , J. Ghanbaja
Nature Materials, 2007, 6 (8), pp.602 - 608. ⟨10.1038/nmat1951⟩
Journal articles hal-01848968v1

Molecular transport into mesostructured silica thin films : electrochemical monitoring and comparison between p6m, P63/mmc, and Pm3n structures.

Mathieu Etienne , Alida Quach , David Grosso , Lionel Nicole , Clément Sanchez
Chemistry of Materials, 2007, 19, pp.844-856
Journal articles hal-00334270v1

Direct electrochemistry of hemoglobin and glucose oxidase in electrodeposited sol–gel silica thin films on glassy carbon

Oksana Nadzhafova , Matieu Etienne , Alain Walcarius
Electrochemistry Communications, 2007, 9 (5), pp.1189 - 1195. ⟨10.1016/j.elecom.2007.01.010⟩
Journal articles hal-01848768v1

Synthesis of new dithiocarbamate-based organosilanes for grafting on silica

Stéphanie Goubert-Renaudin , Raphaël Schneider , Alain Walcarius
Tetrahedron Letters, 2007, 48 (12), pp.2113 - 2116. ⟨10.1016/j.tetlet.2007.01.119⟩
Journal articles hal-01849321v1

Thiol-functionalized porous clay heterostructures (PCHs) deposited as thin films on carbon electrode: Towards mercury(II) sensing

A Tchinda , A Ngameni , Alain Walcarius
Sensors and Actuators B: Chemical, 2007, Special Issue: 25th Anniversary of Sensors and Actuators B : Chemical, 121 (1), pp.113-123. ⟨10.1016/j.snb.2006.09.005⟩
Journal articles hal-01941924v1

An Aqueous Route to Organically-Functionalized Silica Diatom Skeletons

Christabel E. Fowler , Catherine Buchberger , Bénédicte Lebeau , Joël Patarin , Cyril Delacote
Applied Surface Science, 2007, 2007 (253), pp.5485-5493
Journal articles hal-00161213v1

Theoretical investigation of the EPR hyperfine coupling constants in amino derivatives

Agnieszka Rogowska , Sébastien Kuhl , Raphaël Schneider , Alain Walcarius , Benoît Champagne
Physical Chemistry Chemical Physics, 2007, 9 (7), ⟨10.1039/B613275H⟩
Journal articles hal-01849323v1

Voltammetric response of ferrocene-grafted mesoporous silica

Cyril Delacôte , J.-P. Bouillon , Alain Walcarius
Electrochimica Acta, 2006, 51 (28), pp.6373-6383. ⟨10.1016/j.electacta.2006.04.042⟩
Journal articles hal-01941950v1

Factors Affecting the Preparation and Properties of Electrodeposited Silica Thin Films Functionalized with Amine or Thiol Groups

Émilie Sibottier , Stephanie Sayen , Fabien Gaboriaud , Alain Walcarius
Langmuir, 2006, 22 (20), pp.8366-8373. ⟨10.1021/la060984r⟩
Journal articles hal-01941946v1

Ion-Exchange Properties and Electrochemical Characterization of Quaternary Ammonium-Functionalized Silica Microspheres Obtained by the Surfactant Template Route

Alain Walcarius , Vellaichamy Ganesan
Langmuir, 2006, 22 (1), pp.469-477. ⟨10.1021/la051916s⟩
Journal articles hal-01941955v1

Analytical Investigation of the Interactions between SC3 Hydrophobin and Lipid Layers: Elaborating of Nanostructured Matrixes for Immobilizing Redox Systems

Yohann Corvis , Gerald Brezesinski , Rick Rink , Alain Walcarius , Angéline van Der Heyden
Analytical Chemistry, 2006, 78 (14), pp.4850-4864. ⟨10.1021/ac0602064⟩
Journal articles hal-01941949v1

Sulfidation of Lead-Loaded Zeolite Microparticles and Flotation by Amylxanthate

Alain Walcarius , Bouchaïb Marouf , Ali Lamdaouar , Khadija Chlihi , Jacques Bessière
Langmuir, 2006, 22 (4), pp.1671-1679. ⟨10.1021/la0522404⟩
Journal articles hal-01941951v1

Zeolite-modified paraffin-impregnated graphite electrode

Alain Walcarius
Journal of Solid State Electrochemistry, 2006, 10 (7), pp.469-478. ⟨10.1007/s10008-005-0020-z⟩
Journal articles hal-01941953v1

Organoclay-enzyme film electrodes

Justin Kemmegne Mbouguen , Emmanuel Ngameni , Alain Walcarius
Analytica Chimica Acta, 2006, 578 (2), pp.145-155. ⟨10.1016/j.aca.2006.06.075⟩
Journal articles hal-01941947v1

Permselective and Preconcentration Properties of a Surfactant-Intercalated Clay Modified Electrode

E. Ngameni , I. k. Tonlé , J. t. Apohkeng , R. g. b. Bouwé , A. t. Jieumboué
Electroanalysis, 2006, 18 (22), pp.2243-2250. ⟨10.1002/elan.200603654⟩
Journal articles hal-01941945v1

Facile Synthesis and Characterization of Naphthidines as a New Class of Highly Nonplanar Electron Donors Giving Robust Radical Cations

Christophe Desmarets , Benoît Champagne , Alain Walcarius , Christine Bellouard , Rafik Omar-Amrani
Journal of Organic Chemistry, 2006, 71 (4), pp.1351-1361. ⟨10.1021/jo0517444⟩
Journal articles hal-01941952v1

Electrochemical modulation of the ligand properties of organically modified mesoporous silicas

Stephanie Sayen , Alain Walcarius
Journal of Electroanalytical Chemistry, 2005, 581 (1), pp.70-78. ⟨10.1016/j.jelechem.2005.04.013⟩
Journal articles hal-01941961v1

Evaporation induced self-assembly of templated silica and organosilica thin films on various electrode surfaces

Mathieu Etienne , Alain Walcarius
Electrochemistry Communications, 2005, 7 (12), pp.1449-1456. ⟨10.1016/j.elecom.2005.10.010⟩
Journal articles hal-01941956v1

Electrochemically-Induced Deposition of Amine-Functionalized Silica Films on Gold Electrodes and Application to Cu(II) Detection in (Hydro)Alcoholic Medium

Alain Walcarius , Émilie Sibottier
Electroanalysis, 2005, 17 (19), pp.1716-1726. ⟨10.1002/elan.200503300⟩
Journal articles hal-01941959v1

Preconcentration and voltammetric analysis of mercury(II) at a carbon paste electrode modified with natural smectite-type clays grafted with organic chelating groups

Ignas Tonle , Emmanuel Ngameni , Alain Walcarius
Sensors and Actuators B: Chemical, 2005, 110 (2), pp.195-203. ⟨10.1016/j.snb.2005.01.027⟩
Journal articles hal-01941972v1

Electrochemical evidences of morphological transformation in ordered mesoporous titanium oxide thin films

Mathieu Etienne , David Grosso , Cédric Boissière , Clément Sanchez , Alain Walcarius
Chemical Communications, 2005, 36, pp.4566. ⟨10.1039/B508093B⟩
Journal articles hal-01941960v1

Novel Single-Phase and Gram-Scale Synthesis of Thiol-Uncapped Stable Colloidal Gold Nanoparticles

Xavier Jurvilliers , Raphaël Schneider , Yves Fort , Alain Walcarius , Jaafar Ghanbaja
Journal of Nanoscience and Nanotechnology, 2005, 5 (2), pp.282-287. ⟨10.1166/jnn.2005.032⟩
Journal articles hal-01941980v1

Bienzyme HRP–GOx-modified gold nanoelectrodes for the sensitive amperometric detection of glucose at low overpotentials

Marc Delvaux , Alain Walcarius , Sophie Demoustier-Champagne
Biosensors and Bioelectronics, 2005, 20 (8), pp.1587-1594. ⟨10.1016/j.bios.2004.07.017⟩
Journal articles hal-01941979v1

Impact of mesoporous silica-based materials on electrochemistry and feedback from electrochemical science to the characterization of these ordered materials

Alain Walcarius
Comptes Rendus. Chimie, 2005, 8 (3-4), pp.693-712. ⟨10.1016/j.crci.2004.10.003⟩
Journal articles hal-01941978v1

New tetrakis(4-aminophenyl)ethenes: synthesis and electrochemical investigations

Jean-François Kuntz , Raphaël Schneider , Alain Walcarius , Yves Fort
Tetrahedron Letters, 2005, 46 (50), pp.8793-8797. ⟨10.1016/j.tetlet.2005.10.071⟩
Journal articles hal-01941958v1

Mercury(II) binding to thiol-functionalized mesoporous silicas: critical effect of pH and sorbent properties on capacity and selectivity

Alain Walcarius , Cyril Delacôte
Analytica Chimica Acta, 2005, 547 (1), pp.3-13. ⟨10.1016/j.aca.2004.11.047⟩
Journal articles hal-01941976v1

Preparing Catalytic Surfaces for Sensing Applications by Immobilizing Enzymes via Hydrophobin Layers

Yohann Corvis , Alain Walcarius , Rick Rink , Nadir Mrabet , Ewa Rogalska
Analytical Chemistry, 2005, 77 (6), pp.1622-1630. ⟨10.1021/ac048897w⟩
Journal articles hal-01941970v1

Exciting new directions in the intersection of functionalized sol–gel materials with electrochemistry

Alain Walcarius , Daniel Mandler , James Cox , Maryanne Collinson , Ovadia Lev
Journal of Materials Chemistry, 2005, 15 (35-36), pp.3663-3689. ⟨10.1039/B504839G⟩
Journal articles hal-01941968v1

Dipeptide-functionalized mesoporous silica spheres

Alain Walcarius , Stephanie Sayen , Christine Gérardin , Faouzia Hamdoune , Ludwig Rodehüser
Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2004, 234 (1-3), pp.145-151. ⟨10.1016/j.colsurfa.2003.11.010⟩
Journal articles hal-01941991v1

From clay- to organoclay-film modified electrodes: tuning charge selectivity in ion exchange voltammetry

Ignas Tonle , Emmanuel Ngameni , Alain Walcarius
Electrochimica Acta, 2004, 49 (20), pp.3435-3443. ⟨10.1016/j.electacta.2004.03.012⟩
Journal articles hal-01941985v1

Interactions of Selenate with Copper(I) Oxide Particles

Alain Walcarius , J. Devoy , J. Bessiere
Langmuir, 2004, 20 (15), pp.6335-6343. ⟨10.1021/la0496136⟩
Journal articles hal-01941983v1

Efficient In Vitro Paraquat Removal via Irreversible Immobilization into Zeolite Particles

Alain Walcarius , R. Mouchotte
Archives of Environmental Contamination and Toxicology, 2004, 46 (1), pp.135-140. ⟨10.1007/s00244-003-2242-3⟩
Journal articles hal-01941995v1

Electrochemical probing of mass transfer rates in mesoporous silica-based organic–inorganic hybrids

Alain Walcarius , Cyril Delacôte , Stephanie Sayen
Electrochimica Acta, 2004, 49 (22-23), pp.3775-3783. ⟨10.1016/j.electacta.2003.11.037⟩
Journal articles hal-01941988v1

Surfactant Templated Sulfonic Acid Functionalized Silica Microspheres as New Efficient Ion Exchangers and Electrode Modifiers

Vellaichamy Ganesan , Alain Walcarius
Langmuir, 2004, 20 (9), pp.3632-3640. ⟨10.1021/la0364082⟩
Journal articles hal-01941986v1

Use of a Commercially Available Wood-Free Resin Pencil as Convenient Electrode for the ?Voltammetry of Microparticles? Technique

Michel Perdicakis , Hugues Aubriet , Alain Walcarius
Electroanalysis, 2004, 16 (24), pp.2042-2050. ⟨10.1002/elan.200403056⟩
Journal articles hal-01941984v1

Uptake of inorganic HgII by organically modified silicates: influence of pH and chloride concentration on the binding pathways and electrochemical monitoring of the processes

Alain Walcarius , Mathieu Etienne , Cyril Delacôte
Analytica Chimica Acta, 2004, 508 (1), pp.87-98. ⟨10.1016/j.aca.2003.11.055⟩
Journal articles hal-01941992v1

Electrocatalytic H2O2 amperometric detection using gold nanotube electrode ensembles

Marc Delvaux , Alain Walcarius , Sophie Demoustier-Champagne
Analytica Chimica Acta, 2004, 525 (2), pp.221-230. ⟨10.1016/j.aca.2004.08.054⟩
Journal articles hal-01941982v1

Low Temperature Synthesis of Zeolite Films on Glassy Carbon: Towards Designing Molecularly Selective Electrochemical Devices

Alain Walcarius , Vellaichamy Ganesan , Olivier Larlus , Valentin Valtchev
Electroanalysis, 2004, 16 (18), pp.1550-1554. ⟨10.1002/elan.200302991⟩
Journal articles hal-01941990v1

Flow Injection Amperometric Detection at Enzyme-Modified Gold Nanoelectrodes

Marc Delvaux , Sophie Demoustier-Champagne , Alain Walcarius
Electroanalysis, 2004, 16 (3), pp.190-198. ⟨10.1002/elan.200402778⟩
Journal articles hal-01941994v1

Grafted Silicas in Electroanalysis: Amorphous Versus Ordered Mesoporous Materials

Alain Walcarius , Mathieu Etienne , Stephanie Sayen , Bénédicte Lebeau
Electroanalysis, 2003, 15 (5-6), pp.414-421. ⟨10.1002/elan.200390048⟩
Journal articles hal-01942007v1

Rate of Access to the Binding Sites in Organically Modified Silicates. 3. Effect of Structure and Density of Functional Groups in Mesoporous Solids Obtained by the Co-Condensation Route

Alain Walcarius , Cyril Delacôte
Chemistry of Materials, 2003, 15 (22), pp.4181-4192. ⟨10.1021/cm031089l⟩
Journal articles hal-01941998v1

Rate of Access to the Binding Sites in Organically Modified Silicates. 2. Ordered Mesoporous Silicas Grafted with Amine or Thiol Groups

Alain Walcarius , Mathieu Etienne , Bénédicte Lebeau
Chemistry of Materials, 2003, 15 (11), pp.2161-2173. ⟨10.1021/cm021310e⟩
Journal articles hal-01942004v1

Analytical investigation of the chemical reactivity and stability of aminopropyl-grafted silica in aqueous medium

M. Etienne , Alain Walcarius
Talanta, 2003, 59 (6), pp.1173-1188. ⟨10.1016/S0039-9140(03)00024-9⟩
Journal articles hal-01942002v1

Zeolite-modified solid carbon paste electrodes

Alain Walcarius , Pascal Mariaulle , Luc Lamberts
Journal of Solid State Electrochemistry, 2003, 7 (10), pp.671-677. ⟨10.1007/s10008-003-0369-9⟩
Journal articles hal-01941999v1

Functionalization of natural smectite-type clays by grafting with organosilanes: physico-chemical characterization and application to mercury(ii) uptake

Ignas Tonle , Emmanuel Ngameni , Daniel Njopwouo , Cédric Carteret , Alain Walcarius
Physical Chemistry Chemical Physics, 2003, 5 (21), pp.4951. ⟨10.1039/B308787E⟩
Journal articles hal-01941996v1

Electronic properties of 1,3,5-tris[4-morpholinophenyl]benzene: a new molecular switch

Christophe Desmarets , Raphaël Schneider , Yves Fort , Alain Walcarius
Inorganic Chemistry Communications, 2003, 6 (3), pp.278-280. ⟨10.1016/S1387-7003(02)00746-3⟩
Journal articles hal-01942000v1

Electrochemical Detection of Copper(II) at an Electrode Modified by a Carnosine-Silica Hybrid Material

Stephanie Sayen , Christine Gérardin , Ludwig Rodehüser , Alain Walcarius
Electroanalysis, 2003, 15 (5-6), pp.422-430. ⟨10.1002/elan.200390049⟩
Journal articles hal-01942008v1

Electro-assisted generation of functionalized silica films on gold

Stephanie Sayen , Alain Walcarius
Electrochemistry Communications, 2003, 5 (4), pp.341-348. ⟨10.1016/S1388-2481(03)00065-1⟩
Journal articles hal-01941997v1

Immobilization of iodide on copper(I) sulfide minerals

Grégory Lefèvre , Jacques Bessière , Jacques Ehrhardt , Alain Walcarius
Journal of Environmental Radioactivity, 2003, 70 (1-2), pp.73-83. ⟨10.1016/S0265-931X(03)00119-X⟩
Journal articles hal-01942006v1

Organically-modified mesoporous silica spheres with MCM-41 architecture

Mathieu Etienne , Bénédicte Lebeau , Alain Walcarius
New Journal of Chemistry, 2002, 26 (4), pp.384-386
Journal articles hal-01942020v1

Chemical Mechanisms Responsible for the Immobilization of Selenite Species from an Aqueous Medium in the Presence of Copper(I) Oxide Particles

Jérôme Devoy , Alain Walcarius , Jacques Bessière
Langmuir, 2002, 18 (22), pp.8472-8480. ⟨10.1021/la025780z⟩
Journal articles hal-01942011v1

Development of a urea biosensor based on a polymeric membrane including zeolite

M.L Hamlaoui , K Reybier , M. Marrakchi , N. Jaffrezic-Renault , M Martelet
Analytica Chimica Acta, 2002, 466 (1), pp.39-45. ⟨10.1016/S0003-2670(02)00548-2⟩
Journal articles hal-01942012v1

Development of an ammonium ISFET sensor with a polymeric membrane including zeolite

M.L Hamlaoui , R. Kherrat , M. Marrakchi , R Jaffrezic-Renault , Alain Walcarius
Materials Science and Engineering: C, 2002, 21 (1-2), pp.25-28. ⟨10.1016/S0928-4931(02)00059-0⟩
Journal articles hal-01942018v1

Rate of Access to the Binding Sites in Organically Modified Silicates. 1. Amorphous Silica Gels Grafted with Amine or Thiol Groups

Alain Walcarius , Mathieu Etienne , Jacques Bessière
Chemistry of Materials, 2002, 14 (6), pp.2757-2766. ⟨10.1021/cm021117k⟩
Journal articles hal-01942017v1

Tuning the Sensitivity of Electrodes Modified with an Organic‐Inorganic Hybrid by Tailoring the Structure of the Nanocomposite Material

Stephanie Sayen , Mathieu Etienne , Jacques Bessière , Alain Walcarius
Journal articles hal-01942014v1

1,3,5-Tris(4-aminophenyl)benzene derivatives: design, synthesis via nickel-catalysed aromatic amination and electrochemical properties

Christophe Desmarets , Raphaël Schneider , Yves Fort , Alain Walcarius
Journal of the Chemical Society, Perkin Transactions 2, 2002, 2 (11), pp.1844-1849. ⟨10.1039/B206689K⟩
Journal articles hal-01942010v1

Electrochemical Applications of Silica-Based Organic−Inorganic Hybrid Materials

Alain Walcarius
Chemistry of Materials, 2001, 13 (10), pp.3351-3372. ⟨10.1021/cm0110167⟩
Journal articles hal-01942023v1

Voltammetric detection of copper(II) at a carbon paste electrode containing an organically modified silica

M. Etienne , J. Bessiere , Alain Walcarius
Sensors and Actuators B: Chemical, 2001, 76 (1-3), pp.531-538. ⟨10.1016/S0925-4005(01)00614-1⟩
Journal articles hal-01942026v1

Electroanalysis with Pure, Chemically Modified and Sol-Gel-Derived Silica-Based Materials

Alain Walcarius
Electroanalysis, 2001, 13 (8-9), pp.701-718. ⟨10.1002/1521-4109(200105)13:8/9<701::AID-ELAN701>3.0.CO;2-6⟩
Journal articles hal-01942028v1