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Caroline Salzemann

Caroline Salzemann - Associate Professor
Current affiliations
  • 1081095
  • 542076


**My research topics** since the end of my PhD until today are the rational elaboration, by chemical way, of mono- and bimetallic nanomaterials that can be used in catalysis and/or in information storage. For that, I am interested in the understanding of the reduction/nucleation/growth mechanisms involved in colloidal syntheses. This approach is motivated by the ambition to go towards predictive syntheses by acquiring the knowledge necessary to control the various experimental parameters. It becomes possible to elaborate complex nanocrystals characterized by weak structural dispersions (size, shape, crystallinity, ...). It is then necessary to organize them in super networks in order to obtain specific collective properties, modulable by a fine control of the mesoscopic order and interactions.


Chemical synthesis of Nanomaterials Size and shape control magnetic and opical properties


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The five shades of oleylamine in a morphological transition of cobalt nanospheres to nanorods

Arthur Moisset , Alexandre Sodreau , Anthony Vivien , Caroline Salzemann , Pascal Andreazza et al.
Nanoscale, In press, ⟨10.1039/D1NR01502H⟩
Journal articles hal-03269446v1

Simpler and Cleaner Synthesis of Variously Capped Cobalt Nanocrystals Applied in the Semihydrogenation of Alkynes

A. Sodreau , A. Vivien , A. Moisset , C. Salzemann , C. Petit et al.
Inorganic Chemistry, 2020, 59 (19), pp.13972--13978. ⟨10.1021/acs.inorgchem.0c01641⟩
Journal articles hal-03133037v1
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Enhanced structural and magnetic properties of fcc colloidal crystals of cobalt nanoparticles

S. Costanzo , A. Ngo , V. Russier , P. Albouy , G. Simon et al.
Nanoscale, 2020, 12 (47), pp.24020-24029. ⟨10.1039/d0nr05517d⟩
Journal articles hal-03315789v1
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Phase diagram of a three-dimensional dipolar model on an fcc lattice

Vincent Russier , Juan J Alonso , I Lisiecki , A T Ngo , C Salzemann et al.
Physical Review B, 2020, 102, ⟨10.1103/PhysRevB.102.174410⟩
Journal articles hal-03000085v1

Chemical Evolution of Pt–Zn Nanoalloys Dressed in Oleylamine

Alter Zakhtser , Ahmed Naitabdi , Rabah Benbalagh , François Rochet , Caroline Salzemann et al.
Journal articles hal-03035440v1
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Protective Effect of Polyoxometalates in {Mo 132 }/Maghemite Binary Superlattices Under Annealing

Romain Breitwieser , Adrien Garnier , Thomas Auvray , Anh-Tu Ngo , Benoît Baptiste et al.
Frontiers in Chemistry, 2019, 1, ⟨10.3389/fchem.2019.00830⟩
Journal articles hal-02881428v1

Role of Oleylamine Revisited: An Original Disproportionation Route to Monodispersed Cobalt and Nickel Nanocrystals

Anthony Vivien , Maya Guillaumont , Lynda Meziane , Caroline Salzemann , Corinne Aubert et al.
Chemistry of Materials, 2019, 31 (3), pp.960-968. ⟨10.1021/acs.chemmater.8b04435⟩
Journal articles hal-02128663v1
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Directed Organization of Platinum Nanocrystals through Organic Supramolecular Nanoporous Templates

Farid Kameche , Alice Six , Fabrice Charra , Anh-Tu Ngo , Fabrice Mathevet et al.
Langmuir, 2017, 33 (44), pp.12759 - 12765. ⟨10.1021/acs.langmuir.7b01893⟩
Journal articles hal-01656972v1
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Hcp cobalt nanocrystals with high magnetic anisotropy prepared by easy one-pot synthesis

L. Meziane , C. Salzemann , Corinne Aubert , H. Gérard , C. Petit et al.
Nanoscale, 2016, 8, pp.18640-18645 ⟨10.1039/C6NR05792F⟩
Journal articles hal-01393430v1
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Binary Superlattices from {Mo132} Polyoxometalates and Maghemite Nanocrystals: Long-Range Ordering and Fine-Tuning of Dipole Interactions

Romain Breitwieser , Thomas Auvray , Florence Volatron , Caroline Salzemann , Anh-Tu Ngo et al.
Small, 2016, 12 (2), pp.220-228. ⟨10.1002/smll.201502127⟩
Journal articles hal-01480743v1
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Platinum and platinum based nanoalloys synthesized by wet chemistry

Caroline Salzemann , Farid Kameche , Anh-Tu Ngo , Pascal Andreazza , Monica Calatayud et al.
Faraday Discussions, 2015, 181, pp.19-36. ⟨10.1039/c5fd00002e⟩
Journal articles hal-01281747v1
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Role of the nanocrystallinity on the chemical ordering of Co x Pt 100-x nanocrystals synthesized by wet chemistry

Farid Kameche , Anh-Tu Ngo , Caroline Salzemann , Marco Cordeiro , Eli Sutter et al.
Physical Chemistry Chemical Physics, 2015, 17 (42), pp.28162-28170. ⟨10.1039/C5CP01062D⟩
Journal articles hal-01142461v2
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Synthesis of tin nanocrystals in room temperature ionic liquids

Steven Le Vot , Damien Dambournet , Henri Groult , Anh-Tu Ngo , Christophe Petit et al.
Dalton Transactions, 2014, 43, pp.18025-18034. ⟨10.1039/C4DT02289K⟩
Journal articles hal-01102801v1
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Understanding How in Situ Generated Hydrogen Controls the Morphology of Platinum Nanoparticles

Neus Aguilera-Porta , Monica Calatayud , Caroline Salzemann , Christophe Petit
Journal of Physical Chemistry C, 2014, 118 (17), pp.9290-9298. ⟨10.1021/jp502174b⟩
Journal articles hal-01978606v1
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Influence of Hydrogen on the Morphology of Platinum and Palladium Nanocrystals

Caroline Salzemann , Petit Christophe
Langmuir, 2012, 28 (10), pp.4835-4841. ⟨10.1021/la205023z⟩
Journal articles hal-01978623v1

Mesoscopic void structures in cobalt nanocrystal films formed from drying concentrated colloidal solutions.

M.P. Pileni , Jean-Jacques Weis , C. Salzemann , J. Richardi , I. Lisiecki et al.
Physical Review Letters, 2009, 102, pp.144502-1 144502-4
Journal articles hal-00374293v1

Tuning of Copper Nanocrystals Optical Properties with Their Shapes

C. Salzemann , A. Brioude , M-P. Pileni
Journal of Physical Chemistry B, 2006, 110 (14), pp.7208 - 7212. ⟨10.1021/jp0601567⟩
Journal articles hal-01597232v1

Light emission spectroscopy of self-assembled arrays of silver nano-crystals with the STM

N. Nilius , H.-M. Benia , C. Salzemann , G. Rupprechter , H.-J. Freund et al.
Chemical Physics Letters, 2005, 413 (1-3), pp.10 - 15. ⟨10.1016/j.cplett.2005.06.127⟩
Journal articles hal-01597236v1

Is it possible to correlate a collection of copper nanocrystals with their optical response ?

C. Salzemann , J. Lermé , Jakub Urban , I. Lisiecki
Chemistry of Materials, 2005, 17 (6), pp.1279. ⟨10.1021/cm048970z⟩
Journal articles hal-00141294v1

Collections of Copper Nanocrystals Characterized by Different Sizes and Shapes: Optical Response of These Nanoobjects

C. Salzemann , I. Lisiecki , A. Brioude , Jakub Urban , M.-P. Pileni et al.
Journal of Physical Chemistry B, 2004, 108 (35), pp.13242 - 13248. ⟨10.1021/jp048491n⟩
Journal articles hal-01597243v1

Elaboration of plasmonic enantiomorphs

Nada khalfaoui HASSANI , Nicolas Goubet , Caroline Salzemann
C'Nano Poitiers 2023, Mar 2023, Futuroscope, Poitiers, France
Conference papers hal-04033082v1

Morphological transition of spherical (bi-)metallic nanoparticles to nanorods

Arthur Moisset , Alexandre Sodreau , Anthony Vivien , Caroline Salzemann , Pascal Andreazza et al.
IMN 2021, congrés online, Ewald Janssens, Apr 2021, Leuven, Belgium
Conference papers hal-03944004v1

Rational Elaboration of mono- and bimetallic nanocrystals

Caroline Salzemann
10th International Conference on Materials for Advanced Technologies, ICMAT 2019, Jun 2019, SINGAPORE, Singapore
Conference papers hal-03937748v1

Facile route towards mono and bi metallic Nanocrystals with size and shape control

Christophe Petit , Antony Vivien , Maya Guillaumont , Caroline Salzemann , Hélène Gérard et al.
17th European Conference on Solid State Chemistry, Sep 2019, Lille, France
Conference papers hal-03943955v1

How in situ generated hydrogen controls the morphology of platinum nanocrystals : in situ SAXS and WAXS study of the growth process

C. Petit , C Salzemann , Monica Calatayud , Pascal Andreazza , Florian Meneau et al.
Liquid X-ray Spectroscopy LIXS 2017, Jan 2017, Saclay, France
Conference papers hal-03945802v1

Elaboration of mesostructures based on magnetic nanocrystals: modulation of dipolar interactions from super-ferromagnetism to magnetic decorellation

Caroline Salzemann , Mario Avila Guiterrez , Anh-Tu Ngo , Sawako Nakamae , Caroline Raepsaet et al.
4th Conférence Internationale de Nanosciences, Nanotechnologie et Nanotechnobiologie, Dec 2017, Paris, France
Conference papers hal-03937817v1