Dominique Cahard

Documents

Publications

	Stereodivergent Hydrohalogenation of SCF3 Alkynes and Cross-Coupling Reactions Nicolas Marie , Kim Uyen Ly , Norio Shibata , Vincent Bizet , Dominique Cahard Organic Letters, 2024, 26 (42), pp.9168-9172. ⟨10.1021/acs.orglett.4c03760⟩ Journal articles hal-04757383v1
	Photocatalyzed Cascade Hydrogen Atom Transfers for Assembly of Multi-Substituted -SCF3 and -SCF2H Cyclopentanones Nicolas Marie , Jun‐an Ma , Vincent Tognetti , Dominique Cahard Angewandte Chemie International Edition, 2024, 63 (34), ⟨10.1002/anie.202407689⟩ Journal articles hal-04757388v1
	10-Phenylphenothiazine-Organophotocatalyzed Bromo-Perfluoroalkylation of Unactivated Olefins Koto Tagami , Moeko Nakayama , Tadashi Kanbara , Dominique Cahard , Tomoko Yajima Journal of Organic Chemistry, 2024, 89 (10), pp.7084 - 7094. ⟨10.1021/acs.joc.4c00470⟩ Journal articles hal-04632131v1
	Specific Antidermatophytic Activity of Trifluoromethylthiolated Cinnamate Derivatives: A New Approach to the Therapy of Superficial Fungal Infections of the Skin Luana Candice Genz Bazana , Daiane Flores Dalla Lana , Rodrigo Foss da Silva , Solange Cristina Garcia , Marcelo Dutra Arbo ChemistrySelect, 2024, 9 (35), pp.e202401750. ⟨10.1002/slct.202401750⟩ Journal articles hal-04757385v1
	Stereoselective Nucleophilic Halogenation at CF₃-Substituted Nonclassical Carbocation Veronika Myronova , Dominique Cahard , Ilan Marek Organic Letters, 2024, 26 (17), pp.3657 - 3660. ⟨10.1021/acs.orglett.4c01161⟩ Journal articles hal-04632115v1
	Expanding Radical Chloropentafluorosulfanylation of Alkynes Thi Mo Nguyen , Lucas Popek , David Matchavariani , Nicolas Blanchard , Vincent Bizet Organic Letters, 2024, 26 (1), pp.365-369. ⟨10.1021/acs.orglett.3c04043⟩ Journal articles hal-04631759v1
	Ambiphilic Reactivity of SF₅‐Alkynes Applied to Regioselective and Stereodivergent Halogenation Reactions: An Experimental and Theoretical Case Study David Matchavariani , Lucas Popek , Jorge Cabrera-Trujillo , Thi Mo Nguyen , Nicolas Blanchard Advanced Synthesis and Catalysis, 2024, 366 (16), pp.3481-3493. ⟨10.1002/adsc.202400446⟩ Journal articles hal-04606248v1
	Tracking SF5I in the Iodopentafluorosulfanylation of Alkynes Thi Mo Nguyen , Claude Legault , Nicolas Blanchard , Vincent Bizet , Dominique Cahard Chemistry - A European Journal, 2023, ⟨10.1002/chem.202302914⟩ Journal articles hal-04234753v1
	Tuning catalyst performance in asymmetric carbene transfer toward CF3-cyclopropenes Nicolas Marie , Dominique Cahard Chem Catalysis, 2023, 3 (6), pp.100665. ⟨10.1016/j.checat.2023.100665⟩ Journal articles hal-04234771v1
	Structure-property relationships of fluorinated carboxylic acid bioisosteres Thibault Alle , Sipak Joyasawal , Killian Oukoloff , Keith Long , Zachary Owyang Bioorganic and Medicinal Chemistry Letters, 2023, 91, pp.129363. ⟨10.1016/j.bmcl.2023.129363⟩ Journal articles hal-04234785v1
	Monofluoromethylation of Cyclic Sulfamidates and Sulfates with a-Fluorocarbanions of Fluorobis(phenylsulfonyl)methane and Ethyl 2-Fluoroacetoacetate Jun‐liang Zeng , Liangfeng Niu , Zhiwen Wang , Renjie Wei , Dominique Cahard European Journal of Organic Chemistry, 2023, 26 (38), ⟨10.1002/ejoc.202300651⟩ Journal articles hal-04234760v1
	Using fluoroform in trifluoromethylation reactions Ziwei Luo , Dominique Cahard , Gavin Chit Tsui Journal of Fluorine Chemistry, 2023, 266, pp.110092. ⟨10.1016/j.jfluchem.2023.110092⟩ Journal articles hal-04234803v1
	Exploring the 5-Substituted 2-Aminobenzothiazole-Based DNA Gyrase B Inhibitors Active against ESKAPE Pathogens Maša Sterle , Martina Durcik , Clare Stevenson , Sara Henderson , Petra Eva Szili ACS Omega, 2023, 8 (27), pp.24387-24395. ⟨10.1021/acsomega.3c01930⟩ Journal articles hal-04234777v1
	N‐Fluoro Ammonium Salts of Cinchona Alkaloids in Enantioselective Electrophilic Fluorination Norio N Shibata , Dominique Cahard Chemical Record, 2023, Synthesis and Applications of Organofluorine Compounds, 23 (9), pp.e202300096. ⟨10.1002/tcr.202300096⟩ Journal articles hal-04234794v1
	Synthesis and further use of SF5 -alkynes as platforms for the design of more complex SF5 -containing products Lucas Popek , Thi Mo Nguyen , Nicolas Blanchard , Dominique Cahard , Vincent Bizet Tetrahedron, 2022, 117-118, pp.132814. ⟨10.1016/j.tet.2022.132814⟩ Journal articles hal-03717188v1
	Flow dearomatization of electron-poor 3-fluoromethylthioindoles by 1,3-dipolar cycloaddition Maxime Manneveau , Batoul Rkein , Dominique Cahard , Julien Legros , Isabelle Chataigner Journal of flow chemistry, 2022, 12 (2), pp.141-145. ⟨10.1007/s41981-021-00203-z⟩ Journal articles hal-03361388v1
	KHMDS/Triglyme Cryptate as an Alternative to Phosphazene Base in Stereodivergent Pentafluoroethylation of N -Sulfinylimines Using HFC-125 Yuji Sumii , Hiroto Iwasaki , Yamato Fujihira , Elsayed Mahmoud , Hiroaki Adachi Journal of Organic Chemistry, 2022, 87 (23), pp.15806-15819. ⟨10.1021/acs.joc.2c01821⟩ Journal articles hal-04234835v1
	Catalytic Stereoconvergent Synthesis of Homochiral β-CF 3 , β-SCF 3 , and β-OCF 3 Benzylic Alcohols Andrej Emanuel Cotman , Pavel Dub , Maša Sterle , Matic Lozinšek , Jaka Dernovšek ACS Organic & Inorganic Au, 2022, 2 (5), pp.396-404. ⟨10.1021/acsorginorgau.2c00019⟩ Journal articles hal-03808161v1
	Stereoselective Preparation of CF 3 -Containing Cyclopropanes Veronika Myronova , Dominique Cahard , Ilan Marek Organic Letters, 2022, 24 (49), pp.9076-9080. ⟨10.1021/acs.orglett.2c03714⟩ Journal articles hal-04234818v1
	State of knowledge in photoredox-catalysed direct difluoromethylation Jiaxu Feng , Xiaodong Jia , Shuyue Zhang , Kui Lu , Dominique Cahard Organic Chemistry Frontiers, 2022, 9 (13), pp.3598-3623. ⟨10.1039/D2QO00551D⟩ Journal articles hal-03808164v1
	Amphiphilic Polyfluorinated Amino Ethers from Cyclic Sulfamidates Nicolas Marie , Jun-An Ma , Dominique Cahard Journal of Organic Chemistry, 2022, 87 (24), pp.16665-16675. ⟨10.1021/acs.joc.2c02337⟩ Journal articles hal-04234824v1
	Chinese Chemical Letters Metal-free regioselective construction of 2-aryl-2H-tetrazol-5-yl difluoromethylene phosphonates Dominique Cahard , Shi-Jing Zhai , Fa-Guang Zhang , Jun-An Ma Chinese Chemical Letters, 2021, ⟨10.1016/j.cclet.2021.08.007⟩ Journal articles hal-03357199v1
	Radical 1,5-Chloropentafluorosulfanylation of Unactivated Vinylcyclopropanes and Transformation into α-SF 5 Ketones Fang-Fang Feng , Jun-An Ma , Dominique Cahard Journal of Organic Chemistry, In press, ⟨10.1021/acs.joc.1c01886⟩ Journal articles hal-03357178v1
	Asymmetric Synthesis of Chiral Amino Carboxylic‐Phosphonic Acid Derivatives Dominique Cahard , Hao‐qiang Cao , Jun‐kuan Li , Fa‐guang Zhang , Jun‐an Ma Advanced Synthesis and Catalysis, 2021, 363 (3), pp.688-729. ⟨10.1002/adsc.202001345⟩ Journal articles hal-03357213v1
	Enantioselective catalytic synthesis of α-aryl-α-SCF 3 -β 2,2 -amino acids Andreas Eitzinger , Jean-François Brière , Dominique Cahard , Mario Waser Organic & Biomolecular Chemistry, 2020, 18 (3), pp.405-408. ⟨10.1039/c9ob02666e⟩ Journal articles hal-02442629v1
	Asymmetric Synthesis of Chiral Amino Carboxylic‐Phosphonic Acid Derivatives Hao‐qiang Cao , Jun‐kuan Li , Fa‐guang Zhang , Dominique Cahard , Jun‐an Ma Advanced Synthesis and Catalysis, 2020, ⟨10.1002/adsc.202001345⟩ Journal articles hal-03100423v1
	Asymmetric Electrophilic Difluoromethylthiolation of Indanone-Based β-Keto Esters Using Difluoromethanesulfonyl Hypervalent Iodonium Ylides Satoshi Gondo , Okiya Matsubara , Hélène Chachignon , Yuji Sumii , Dominique Cahard Molecules, 2019, 24 (2), pp.221. ⟨10.3390/molecules24020221⟩ Journal articles hal-02321615v1
	Advances in Asymmetric Di‐and Trifluoromethylthiolation, and Di‐ and Trifluoromethoxylation Reactions Melissa Hardy , Hélène Chachignon , Dominique Cahard Asian Journal of Organic Chemistry, 2019, 8 (5), pp.591-609. ⟨10.1002/ajoc.201900004⟩ Journal articles hal-02321614v1
	Regioselectivity Issues in the Addition of Grignard Reagents to Trifluoromethylated α-Bromoenones Alexey Romanov , Dominique Cahard , Alexander Yu. Rulev European Journal of Organic Chemistry, 2019, 2019 (11), pp.2143-2149. ⟨10.1002/ejoc.201900155⟩ Journal articles hal-02321613v1
	Telescoping Reactions with Trifluorodiazoethane-Derived Aza-Wittig Reagents and Allenyl esters Fa-Guang Zhang , Jun-Liang Zeng , Yi-Quiang Tian , Yan Zheng , Dominique Cahard Chemistry - A European Journal, 2018, 24 (30), pp.7749-7754. ⟨10.1002/chem.201801171⟩ Journal articles hal-02024538v1
	Mechanistic Insights into the Decarboxylative Electrophilic Trifluoromethylthiolation of β‐Ketocarboxylic Acids Hélène Guyon , Hélène Chachignon , Vincent Tognetti , Laurent Joubert , Dominique Cahard European Journal of Organic Chemistry, 2018, Special Issue: Organofluorine Chemistry in Europe, 2018 (27-28), pp.3756-3763. ⟨10.1002/ejoc.201800305⟩ Journal articles hal-02024501v1
	Diastereoselective Electrophilic Trifluoromethylthiolation of Chiral Oxazolidinones: Access to Enantiopure α‐SCF3 Alcohols Hélène Chachignon , Evgeniy V. Kondrashov , Dominique Cahard Advanced Synthesis and Catalysis, 2018, 360 (5), pp.965-971. ⟨10.1002/adsc.201701474⟩ Journal articles hal-02024484v1
	SelectfluorTM on a PolyHIPE Material as Regenerative and Reusable Polymer‐Supported Electrophilic Fluorinating Agent Kosuke Kawada , Koji Okano , Jernej Iskra , Peter Krajnc , Dominique Cahard Advanced Synthesis and Catalysis, 2017, 359 (4), pp.584-589. ⟨10.1002/adsc.201601312⟩ Journal articles hal-02046288v1
	Interrupted reduction of CF3SO2Cl using tricyclohexylphosphine allows for electrophilic trifluoromethylsulfinylation Hélène Chachignon , Dominique Cahard Journal of Fluorine Chemistry, 2017, 198, pp.82-88. ⟨10.1016/j.jfluchem.2016.11.020⟩ Journal articles hal-02046268v1
	CF3SO2X (X = Na, Cl) as reagents for trifluoromethylation, trifluoromethylsulfenyl-, -sulfinyl- and -sulfonylation and chlorination. Part 2: Use of CF3SO2Cl Hélène Chachignon , Hélène Guyon , Dominique Cahard Beilstein Journal of Organic Chemistry, 2017, 13, pp.2800-2818. ⟨10.3762/bjoc.13.273⟩ Journal articles hal-02046269v1
	Nucleophilic Trifluoromethylthiolation of Cyclic Sulfamidates: Access to Chiral β- and γ-SCF3 Amines and α-Amino Esters Jun-Liang Zeng , Hélène Chachignon , Jun-An Ma , Dominique Cahard Organic Letters, 2017, 19 (8), pp.1974-1977. ⟨10.1021/acs.orglett.7b00501⟩ Journal articles hal-02046315v1
	New pluses in carbanion chemistry Jacques Maddaluno , Michaël de Paolis , Xavier Franck , Dominique Cahard Comptes Rendus Chimie , 2017, 20 (6), pp.593-594. ⟨10.1016/j.crci.2017.05.002⟩ Journal articles hal-02024981v1
	CF3SO2X (X = Na, Cl) as reagents for trifluoromethylation, trifluoromethylsulfenyl-, -sulfinyl- and -sulfonylation. Part 1: Use of CF3SO2Na Hélène Guyon , Hélène Chachignon , Dominique Cahard Beilstein Journal of Organic Chemistry, 2017, 13, pp.2764-2799. ⟨10.3762/bjoc.13.272⟩ Journal articles hal-02046280v1
	State-of-the-Art in Electrophilic Trifluoromethylthiolation Reagents Hélène Chachignon , Dominique Cahard Chinese Journal of Chemistry, 2016, Special Issue: Trifluoromethylation and Trifluoromethylthiolation Reactions, 34 (5), pp.445-454. ⟨10.1002/cjoc.201500890⟩ Journal articles hal-02046193v1
	Pd-Catalyzed Directed Chlorination of Unactivated C(sp3)–H Bonds at Room Temperature Heng-Ying Xiong , Dominique Cahard , Xavier Pannecoucke , Tatiana Besset European Journal of Organic Chemistry, 2016, 2016 (21), pp.3625-3630. ⟨10.1002/ejoc.201600600⟩ Journal articles hal-01404921v1
	Trifluorodiazoethane (CF3CHN2) in the Uncatalyzed Cyclopropanation of 3-Arylmethylenebenzofuran-2(3H)-ones C.-L. Zhu , J.-A. Ma , Dominique Cahard Asian Journal of Organic Chemistry, 2016, 5 (1), pp.66-69. ⟨10.1002/ajoc.201500409⟩ Journal articles hal-02046247v1
	Novel Use of CF3SO2Cl for the Metal-Free Electrophilic Trifluoromethylthiolation Hélène Chachignon , Mayaka Maeno , H. Kondo , N. Shibata , Dominique Cahard Organic Letters, 2016, 18 (10), pp.2467-2470. ⟨10.1021/acs.orglett.6b01026⟩ Journal articles hal-02046194v1
	Enantiomerization of Allylic Trifluoromethyl Sulfoxides Studied by HPLC Analysis and DFT Calculations Laëtitia Bailly , Emilie Petit , Mayaka Maeno , Norio Shibata , Oliver Trapp Chirality, 2016, 28 (2), pp.136-142. ⟨10.1002/chir.22552⟩ Journal articles hal-01928560v1
	Stereoarrayed CF3-Substituted 1,3-Diols by Dynamic Kinetic Resolution: Ruthenium(II)-Catalyzed Asymmetric Transfer Hydrogenation A.E. Cotman , Dominique Cahard , B. Mohar Angewandte Chemie International Edition, 2016, 55 (17), pp.5294-5298. ⟨10.1002/anie.201600812⟩ Journal articles hal-02046198v1
	The ﬂuoroalkene motif as a surrogate of the amide bond: syntheses of AA-Y[(Z) and (E)-CF=CH]-Pro pseudodipeptides and an Enalapril analogue Emilie Villiers , Samuel Couve-Bonnaire , Dominique Cahard , Xavier Pannecoucke Tetrahedron, 2015, 71 (38), pp.7054-7062. ⟨10.1016/j.tet.2015.06.093⟩ Journal articles hal-01226904v1
	Preface J.-M. Vincent , T. Brigaud , Dominique Cahard Journal of Fluorine Chemistry, 2015, 171, pp.1. ⟨10.1016/j.jfluchem.2014.10.011⟩ Journal articles hal-02024989v1
	Regio- and stereocontrolled nucleophilic trifluoromethylthiolation of Morita-Baylis-Hillman carbonates Xiaoyang Dai , Dominique Cahard SYNLETT, 2015, 26 (1), pp.40-44. ⟨10.1055/s-0034-1379162⟩ Journal articles hal-02046149v1
	Palladium(II)-Catalyzed Directed Trifluoromethylthiolation of Unactivated C(sp3)–H Bonds Heng-Ying Xiong , Tatiana Besset , Dominique Cahard , Xavier Pannecoucke Journal of Organic Chemistry, 2015, 80 (8), pp.4204-4212. ⟨10.1021/acs.joc.5b00505⟩ Journal articles hal-01149628v1
	Asymmetric isomerization of allylic alcohols Dominique Cahard , Sylvain Gaillard , J.L. Renaud Tetrahedron Letters, 2015, 56 (45), pp.6159-6169. ⟨10.1016/j.tetlet.2015.09.098⟩ Journal articles hal-01848011v1
	Trifluoromethyl Sulfoxides from Allylic Alcohols and Electrophilic SCF3 Donor by [2,3]-Sigmatropic Rearrangement Mayaka Maeno , N. Shibata , Dominique Cahard Organic Letters, 2015, 17 (8), pp.1990-1993. ⟨10.1021/acs.orglett.5b00750⟩ Journal articles hal-02046161v1
	Copper-Mediated Direct Functionalization of Unsaturated C–C Bonds with Ethyl Bromo(difluoro)acetate: A Straightforward Access to Highly Valuable Difluoromethylated Alkenes Marie-Charlotte Belhomme , Delphine Dru , Heng-Ying Xiong , Dominique Cahard , Tatiana Besset Synthesis: Journal of Synthetic Organic Chemistry, 2014, 46 (14), pp.1859-1870. ⟨10.1055/s-0033-1338637⟩ Journal articles hal-01149614v1
	Regio- and Diastereoselective Cu-Mediated Triﬂuoromethylation of Functionalized Alkenes Tatiana Besset , Dominique Cahard , Xavier Pannecoucke Journal of Organic Chemistry, 2014, 79 (1), pp.413-418. ⟨10.1021/jo402385g⟩ Journal articles hal-01149530v1
	Recent Progress in Asymmetric Fluorination and Trifluoromethylation Reactions Vincent Bizet , Tatiana Besset , Jun-An Ma , Dominique Cahard Current Topics in Medicinal Chemistry, 2014, 14, pp.901-940. ⟨10.2174/1568026614666140202205531⟩ Journal articles hal-01149612v1
	Rescue of fragile X syndrome phenotypes in Fmr1 KO mice by a BKCa channel opener molecule. Betty Hébert , Susanna Pietropaolo , Sandra Même , Béatrice Laudier , Anthony Laugeray Orphanet Journal of Rare Diseases, 2014, 9, pp.124. ⟨10.1186/s13023-014-0124-6⟩ Journal articles inserm-01089760v1
	P-Spiro phosphonium salts catalyzed asymmetric fluorination of 3-substituted benzofuran-2(3H)-ones Chuan-Le Zhu , Xiao-Yun Fu , Ai-Jia Wei , Dominique Cahard , Jun-An Ma Journal of Fluorine Chemistry, 2013, 150, pp.60-66. ⟨10.1016/j.jfluchem.2013.03.007⟩ Journal articles hal-01015804v1
	Synthesis of β-CF3 ketones from trifluoromethylated allylic alcohols by ruthenium catalyzed isomerization Vincent Bizet , Xavier Pannecoucke , Jean-Luc Renaud , Dominique Cahard Journal of Fluorine Chemistry, 2013, 152, pp.56-61. ⟨10.1016/j.jfluchem.2013.01.004⟩ Journal articles hal-01015319v1
	Fluorinated pseudopeptide analogues of the neuropeptide 26RFa: synthesis, biological, and structural studies. Camille Pierry , Samuel Couve-Bonnaire , Laure Guilhaudis , Cindy Neveu , Amélie Marotte ChemBioChem, 2013, 14 (13), pp.1620-1633. ⟨10.1002/cbic.201300325⟩ Journal articles hal-01939216v1
	Iron(II) complexes are suitable catalysts for the isomerization of trifluoromethylated allylic alcohols. Synthesis of trifluoromethylated dihydrochalcones Dominique Cahard , Vincent Bizet , Xiaoyang Dai , Sylvain Gaillard , Jean-Luc Renaud Journal of Fluorine Chemistry, 2013, 55, pp.78-82. ⟨10.1016/j.jfluchem.2013.05.028⟩ Journal articles hal-01015799v1
	Chiral N-Fluorodibenzenesulfonimide Analogues for Enantioselective Electrophilic Fluorination and Oxidative Fluorination Chuan-Le Zhu , Mayaka Maeno , Faguang Zang , Taiki Shigehiro , Takumi Kagawa European Journal of Organic Chemistry, 2013, 2013 (29), pp.6501-6505. ⟨10.1002/ejoc.201300956⟩ Journal articles hal-01015793v1
	Isomérisation rédox : une réaction économe en atome à fort potentiel d'innovation Vincent Bizet , Dominique Cahard , Sylvain Gaillard , Jean-Luc Renaud Techniques de l'Ingénieur, 2013, pp.LN159 Journal articles hal-01015807v1
	Ruthenium-Catalyzed One-Pot Tandem Isomerization-Transfer Hydrogenation Reactions of γ-Trifluoromethylated Allylic Alcohols and β-Trifluoromethylated Enones [Erratum to document cited in CA159:515982] Vincent Bizet , Xavier Pannecoucke , Jean-Luc Renaud , Dominique Cahard Advanced Synthesis and Catalysis, 2013, 355 (11-12), pp.2113-2113. ⟨10.1002/adsc.201381141⟩ Journal articles hal-01015313v1
	Tamed arene and heteroarene trifluoromethylation Tatiana Besset , Cédric Schneider , Dominique Cahard Angewandte Chemie International Edition, 2012, 51 (21), pp.5048-5050. ⟨10.1002/anie.201201012⟩ Journal articles hal-00996588v1
	Decarboxylative allylation of trifluoroethyl sulfones and approach to difluoromethyl compounds. Norio Shibata , Kazunobu Fukushi , Tatsuya Furukawa , Satoru Suzuki , Etsuko Tokunaga Organic Letters, 2012, 14 (20), pp.5366-5369. ⟨10.1021/ol302589w⟩ Journal articles hal-00996604v1
	Ruthenium-catalyzed redox isomerization of trifluoromethylated allylic alcohols: mechanistic evidence for an enantiospecific pathway. Vincent Bizet , Xavier Pannecoucke , Jean-Luc Renaud , Dominique Cahard Angewandte Chemie International Edition, 2012, 51 (26), pp.6467-6470. ⟨10.1002/anie.201200827⟩ Journal articles hal-00996590v1
	Chiral Brønsted acid-catalyzed diastereo- and enantioselective synthesis of CF3-substituted aziridines. Zhuo Chai , J.-P. Bouillon , Dominique Cahard Chemical Communications, 2012, 48 (76), pp.9471-9473. ⟨10.1039/c2cc35246j⟩ Journal articles hal-00996595v1
	Diastereoselective synthesis of trans-trifluoromethyl-β-lactams and α-alkyl-β-trifluoromethyl-β-amino esters Vitaliy Petrik , G.-V. Roeschenthaler , Dominique Cahard Tetrahedron, 2011, 67 (18), pp.3254-3259. ⟨10.1016/j.tet.2011.03.001⟩ Journal articles hal-01017713v1
	Enantioselective base-free electrophilic amination of benzofuran-2(3H)-ones: catalysis by binol-derived P-spiro quaternary phosphonium salts. Chuan-Le Zhu , Fa-Guang Zhang , Wei Meng , Jing Nie , Dominique Cahard Angewandte Chemie International Edition, 2011, 50 (26), pp.5869-5872. ⟨10.1002/anie.201100283⟩ Journal articles hal-00991654v1
	Synthesis of α-CF3-substituted carbonyl compounds with relative and absolute stereocontrol using electrophilic CF3-transfer reagents. Václav Matoušek , Antonio Togni , Vincent Bizet , Dominique Cahard Organic Letters, 2011, 13 (21), pp.5762-5765. ⟨10.1021/ol2023328⟩ Journal articles hal-00991658v1
	Asymmetric construction of stereogenic carbon centers featuring a trifluoromethyl group from prochiral trifluoromethylated substrates. Jing Nie , Hong-Chao Guo , Dominique Cahard , Jun-An Ma Chemical Reviews, 2011, 111 (2), pp.455-529. ⟨10.1021/cr100166a⟩ Journal articles hal-00991650v1
	Synthesis of fluorinated pseudopeptides: metal mediated reversal of stereochemistry in diastereoselective addition of organometallic reagents to N-(tert-butanesulfinyl)-α-fluoroenimines. Camille Pierry , Dominique Cahard , Samuel Couve-Bonnaire , Xavier Pannecoucke Organic & Biomolecular Chemistry, 2011, 9 (7), pp.2378-2386. ⟨10.1039/c0ob00773k⟩ Journal articles hal-00991652v1
	Construction of Trifluoromethyl-Bearing Quaternary Carbon Centers by Intramolecular Decarboxylative Allylation of α-Trifluoromethyl β-Keto Esters Norio Shibata , Satoru Suzuki , Tatsuya Furukawa , Hiroyuki Kawai , Etsuko Tokunaga Advanced Synthesis and Catalysis, 2011, 353 (11-12), pp.2037-2041. ⟨10.1002/adsc.201100359⟩ Journal articles hal-01017733v1
	Fluorine & chirality: how to create a nonracemic stereogenic carbon-fluorine centre? Dominique Cahard , Xiuhua Xu , Samuel Couve-Bonnaire , Xavier Pannecoucke Chemical Society Reviews, 2010, 39 (2), pp.558-568. ⟨10.1039/b909566g⟩ Journal articles hal-00991924v1
	Shelf-stable electrophilic trifluoromethylating reagents: A brief historical perspective. Norio Shibata , Andrej Matsnev , Dominique Cahard Beilstein Journal of Organic Chemistry, 2010, 6, pp.e65. ⟨10.3762/bjoc.6.65⟩ Journal articles hal-00991935v1
	Diastereocontrolled addition of organometallic reagents to S-chiral N-(tert-butanesulfinyl)-α-fluoroenimines Camille Pierry , Ludivine Zoute , Philippe Jubault , Emmanuel Pfund , Thierry Lequeux Tetrahedron Letters, 2009, 50 (3), pp.264-266. ⟨10.1016/j.tetlet.2008.10.140⟩ Journal articles hal-02384442v1
	Chiral dipeptide mimics possessing a fluoroolefin moiety: a relevant tool for conformational and medicinal studies Samuel Couve-Bonnaire , Dominique Cahard , Xavier Pannecoucke Organic & Biomolecular Chemistry, 2007, 5 (8), pp.1151-1157. ⟨10.1039/b701559c⟩ Journal articles hal-02384465v1
	Association of a functional deficit of the BKCa channel, a synaptic regulator of neuronal excitability, with autism and mental retardation Frédéric Laumonnier , Sébastien Roger , Pascaline Guerin , Florence Molinari , Ridha M'Rad The American Journal of Psychiatry, 2006, 163 (9), pp.1622 - 1629. ⟨10.1176/appi.ajp.163.9.1622⟩ Journal articles hal-02658023v1
	Enantioselective and diastereoselective synthesis of fluorinated dipeptides by late electrophilic fluorination Barbara Mohar , Damjan Sterk , Laurent Ferron , Dominique Cahard Tetrahedron Letters, 2005, 46 (30), pp.5029-5031. ⟨10.1016/j.tetlet.2005.05.074⟩ Journal articles hal-01935543v1
	Enantioselective electrophilic fluorination: a study of the fluorine-transfer from achiral N–F reagents to cinchona alkaloids Christine Baudequin , Jean-François Loubassou , Jean-Christophe Plaquevent , Dominique Cahard Journal of Fluorine Chemistry, 2003, 122 (2), pp.189-193. ⟨10.1016/S0022-1139(03)00085-X⟩ Journal articles hal-02385385v1
	Ionic liquids and chirality: opportunities and challenges Christine Baudequin , Jérôme Baudoux , Jocelyne Levillain , Dominique Cahard , Annie-Claude Gaumont Tetrahedron: Asymmetry, 2003, 14 (20), pp.3081-3093. ⟨10.1016/S0957-4166(03)00596-2⟩ Journal articles hal-02385379v1
	Enantioselective electrophilic fluorination in ionic liquids Christine Baudequin , Jean-Christophe Plaquevent , Christophe C. Audouard , Dominique Cahard Green Chemistry, 2002, 4 (6), pp.584-586. ⟨10.1039/B208817G⟩ Journal articles hal-02385390v1

	Fluorine effects in asymmetric hydrogen atom transfer reactions Dominique Cahard American Chemical Society (ACS) National Meeting (257, 2019), Mar 2019, Orlando (FL), United States Conference papers hal-02413435v1
	Direct introduction of fluorinated groups on versatile scaffolds Tatiana Besset , Heng-Ying Xiong , Dominique Cahard , Thomas Poisson , Xavier Pannecoucke International Symposium on Fluorine Chemistry (ISFC, 21, 2015) - International Symposium on Fluorous Technologies (ISoFT, 6, 2015), Aug 2015, Côme, Italy Conference papers hal-02378894v1
	Palladium(II)-catalyzed direct trifluoromethylthiolation of unactivated C(sp3)-H bonds Heng-Ying Xiong , Dominique Cahard , Tatiana Besset , Xavier Pannecoucke Journées Nord-Ouest Européennes des Jeunes Chercheurs (JNOEJC, 2015), May 2015, Rouen, France Conference papers hal-02378621v1

	Asymmetric synthesis of fluoropseudopeptides towards constrained prolines and analogue of neuropeptide 26 RFa Samuel Couve-Bonnaire , Camille Pierry , Emilie Villiers , Guillaume Dutheuil , Laure Guilhaudis Congrès du Groupe français des peptides et des protéines (GFPP, 19, 2015), May 2015, Port-Bail, France Conference poster hal-02543329v1
	Chiral Brønsted acid-catalyzed diastereo- and enantioselective synthesis of CF3-substituted aziridines Zhuo Chai , Vincent Terrasson , Jean-Philippe Bouillon , Dominique Cahard ESFC, 2013, Paris, France Conference poster hal-02913343v1

	Emerging Fluorinated Motifs: Synthesis, Properties, and Applications Dominique Cahard , Jun-An Ma Wiley-VCH, 1 vol. (i-XIV, 837 p.), 2020, 978-3-527-82434-2. ⟨10.1002/9783527824342⟩ Books hal-02558234v1

	Oxidation : C–X Bond Formation (X=Halogen, S, Se) Samir Bouzbouz , Dominique Cahard Hisashi Yamamoto; Erick Carreira. Comprehensive Chirality, In press, ⟨10.1016/B978-0-32-390644-9.00027-5⟩ Book sections hal-03858965v1
	Direct Trifluoromethylthiolation Toward C(sp3)–SCF3 Compounds Dominique Cahard , Norio Shibata Emerging Fluorinated Motifs: Synthesis, Properties, and Applications, 2020, ⟨10.1002/9783527824342.ch15⟩ Book sections hal-03018487v1

Dominique Cahard

Publications

Stereodivergent Hydrohalogenation of SCF3 Alkynes and Cross-Coupling Reactions

Photocatalyzed Cascade Hydrogen Atom Transfers for Assembly of Multi-Substituted -SCF3 and -SCF2H Cyclopentanones

10-Phenylphenothiazine-Organophotocatalyzed Bromo-Perfluoroalkylation of Unactivated Olefins

Specific Antidermatophytic Activity of Trifluoromethylthiolated Cinnamate Derivatives: A New Approach to the Therapy of Superficial Fungal Infections of the Skin

Stereoselective Nucleophilic Halogenation at CF3-Substituted Nonclassical Carbocation

Expanding Radical Chloropentafluorosulfanylation of Alkynes

Ambiphilic Reactivity of SF5‐Alkynes Applied to Regioselective and Stereodivergent Halogenation Reactions: An Experimental and Theoretical Case Study

Tracking SF5I in the Iodopentafluorosulfanylation of Alkynes

Tuning catalyst performance in asymmetric carbene transfer toward CF3-cyclopropenes

Structure-property relationships of fluorinated carboxylic acid bioisosteres

Monofluoromethylation of Cyclic Sulfamidates and Sulfates with a-Fluorocarbanions of Fluorobis(phenylsulfonyl)methane and Ethyl 2-Fluoroacetoacetate

Using fluoroform in trifluoromethylation reactions

Exploring the 5-Substituted 2-Aminobenzothiazole-Based DNA Gyrase B Inhibitors Active against ESKAPE Pathogens

N‐Fluoro Ammonium Salts of Cinchona Alkaloids in Enantioselective Electrophilic Fluorination

Synthesis and further use of SF5 -alkynes as platforms for the design of more complex SF5 -containing products

Flow dearomatization of electron-poor 3-fluoromethylthioindoles by 1,3-dipolar cycloaddition

KHMDS/Triglyme Cryptate as an Alternative to Phosphazene Base in Stereodivergent Pentafluoroethylation of N -Sulfinylimines Using HFC-125

Catalytic Stereoconvergent Synthesis of Homochiral β-CF 3 , β-SCF 3 , and β-OCF 3 Benzylic Alcohols

Stereoselective Preparation of CF 3 -Containing Cyclopropanes

State of knowledge in photoredox-catalysed direct difluoromethylation

Amphiphilic Polyfluorinated Amino Ethers from Cyclic Sulfamidates

Chinese Chemical Letters Metal-free regioselective construction of 2-aryl-2H-tetrazol-5-yl difluoromethylene phosphonates

Radical 1,5-Chloropentafluorosulfanylation of Unactivated Vinylcyclopropanes and Transformation into α-SF 5 Ketones

Asymmetric Synthesis of Chiral Amino Carboxylic‐Phosphonic Acid Derivatives

Enantioselective catalytic synthesis of α-aryl-α-SCF 3 -β 2,2 -amino acids

Asymmetric Synthesis of Chiral Amino Carboxylic‐Phosphonic Acid Derivatives

Asymmetric Electrophilic Difluoromethylthiolation of Indanone-Based β-Keto Esters Using Difluoromethanesulfonyl Hypervalent Iodonium Ylides

Advances in Asymmetric Di‐and Trifluoromethylthiolation, and Di‐ and Trifluoromethoxylation Reactions

Regioselectivity Issues in the Addition of Grignard Reagents to Trifluoromethylated α-Bromoenones

Telescoping Reactions with Trifluorodiazoethane-Derived Aza-Wittig Reagents and Allenyl esters

Mechanistic Insights into the Decarboxylative Electrophilic Trifluoromethylthiolation of β‐Ketocarboxylic Acids

Diastereoselective Electrophilic Trifluoromethylthiolation of Chiral Oxazolidinones: Access to Enantiopure α‐SCF3 Alcohols

SelectfluorTM on a PolyHIPE Material as Regenerative and Reusable Polymer‐Supported Electrophilic Fluorinating Agent

Interrupted reduction of CF3SO2Cl using tricyclohexylphosphine allows for electrophilic trifluoromethylsulfinylation

CF3SO2X (X = Na, Cl) as reagents for trifluoromethylation, trifluoromethylsulfenyl-, -sulfinyl- and -sulfonylation and chlorination. Part 2: Use of CF3SO2Cl

Nucleophilic Trifluoromethylthiolation of Cyclic Sulfamidates: Access to Chiral β- and γ-SCF3 Amines and α-Amino Esters

New pluses in carbanion chemistry

CF3SO2X (X = Na, Cl) as reagents for trifluoromethylation, trifluoromethylsulfenyl-, -sulfinyl- and -sulfonylation. Part 1: Use of CF3SO2Na

State-of-the-Art in Electrophilic Trifluoromethylthiolation Reagents

Pd-Catalyzed Directed Chlorination of Unactivated C(sp3)–H Bonds at Room Temperature

Trifluorodiazoethane (CF3CHN2) in the Uncatalyzed Cyclopropanation of 3-Arylmethylenebenzofuran-2(3H)-ones

Novel Use of CF3SO2Cl for the Metal-Free Electrophilic Trifluoromethylthiolation

Enantiomerization of Allylic Trifluoromethyl Sulfoxides Studied by HPLC Analysis and DFT Calculations

Stereoarrayed CF3-Substituted 1,3-Diols by Dynamic Kinetic Resolution: Ruthenium(II)-Catalyzed Asymmetric Transfer Hydrogenation

The ﬂuoroalkene motif as a surrogate of the amide bond: syntheses of AA-Y[(Z) and (E)-CF=CH]-Pro pseudodipeptides and an Enalapril analogue

Preface

Regio- and stereocontrolled nucleophilic trifluoromethylthiolation of Morita-Baylis-Hillman carbonates

Palladium(II)-Catalyzed Directed Trifluoromethylthiolation of Unactivated C(sp3)–H Bonds

Asymmetric isomerization of allylic alcohols

Trifluoromethyl Sulfoxides from Allylic Alcohols and Electrophilic SCF3 Donor by [2,3]-Sigmatropic Rearrangement

Copper-Mediated Direct Functionalization of Unsaturated C–C Bonds with Ethyl Bromo(difluoro)acetate: A Straightforward Access to Highly Valuable Difluoromethylated Alkenes

Regio- and Diastereoselective Cu-Mediated Triﬂuoromethylation of Functionalized Alkenes

Recent Progress in Asymmetric Fluorination and Trifluoromethylation Reactions

Rescue of fragile X syndrome phenotypes in Fmr1 KO mice by a BKCa channel opener molecule.

P-Spiro phosphonium salts catalyzed asymmetric fluorination of 3-substituted benzofuran-2(3H)-ones

Synthesis of β-CF3 ketones from trifluoromethylated allylic alcohols by ruthenium catalyzed isomerization

Fluorinated pseudopeptide analogues of the neuropeptide 26RFa: synthesis, biological, and structural studies.

Iron(II) complexes are suitable catalysts for the isomerization of trifluoromethylated allylic alcohols. Synthesis of trifluoromethylated dihydrochalcones

Chiral N-Fluorodibenzenesulfonimide Analogues for Enantioselective Electrophilic Fluorination and Oxidative Fluorination

Isomérisation rédox : une réaction économe en atome à fort potentiel d'innovation

Ruthenium-Catalyzed One-Pot Tandem Isomerization-Transfer Hydrogenation Reactions of γ-Trifluoromethylated Allylic Alcohols and β-Trifluoromethylated Enones [Erratum to document cited in CA159:515982]

Tamed arene and heteroarene trifluoromethylation

Decarboxylative allylation of trifluoroethyl sulfones and approach to difluoromethyl compounds.

Ruthenium-catalyzed redox isomerization of trifluoromethylated allylic alcohols: mechanistic evidence for an enantiospecific pathway.

Chiral Brønsted acid-catalyzed diastereo- and enantioselective synthesis of CF3-substituted aziridines.

Diastereoselective synthesis of trans-trifluoromethyl-β-lactams and α-alkyl-β-trifluoromethyl-β-amino esters

Enantioselective base-free electrophilic amination of benzofuran-2(3H)-ones: catalysis by binol-derived P-spiro quaternary phosphonium salts.

Synthesis of α-CF3-substituted carbonyl compounds with relative and absolute stereocontrol using electrophilic CF3-transfer reagents.

Asymmetric construction of stereogenic carbon centers featuring a trifluoromethyl group from prochiral trifluoromethylated substrates.

Synthesis of fluorinated pseudopeptides: metal mediated reversal of stereochemistry in diastereoselective addition of organometallic reagents to N-(tert-butanesulfinyl)-α-fluoroenimines.

Construction of Trifluoromethyl-Bearing Quaternary Carbon Centers by Intramolecular Decarboxylative Allylation of α-Trifluoromethyl β-Keto Esters

Fluorine & chirality: how to create a nonracemic stereogenic carbon-fluorine centre?

Shelf-stable electrophilic trifluoromethylating reagents: A brief historical perspective.

Diastereocontrolled addition of organometallic reagents to S-chiral N-(tert-butanesulfinyl)-α-fluoroenimines

Chiral dipeptide mimics possessing a fluoroolefin moiety: a relevant tool for conformational and medicinal studies

Association of a functional deficit of the BKCa channel, a synaptic regulator of neuronal excitability, with autism and mental retardation

Enantioselective and diastereoselective synthesis of fluorinated dipeptides by late electrophilic fluorination

Enantioselective electrophilic fluorination: a study of the fluorine-transfer from achiral N–F reagents to cinchona alkaloids

Stereoselective Nucleophilic Halogenation at CF₃-Substituted Nonclassical Carbocation

Ambiphilic Reactivity of SF₅‐Alkynes Applied to Regioselective and Stereodivergent Halogenation Reactions: An Experimental and Theoretical Case Study