Eder Tomás González de Mendivil

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Publications

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Are N-heterocyclic carbene radical cations relevant intermediates in radical transformations?

Preslav Smits , Ludivine Delfau , Sheima Bougoffa , Florian Molton , Jacques Pecaut et al.

Organic Chemistry Frontiers, 2025, ⟨10.1039/d5qo01285f⟩

Article dans une revue hal-05361627v1
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Improved Protocols for the Synthesis of Precursors of Thiazol-2-ylidene N-Heterocyclic Carbenes

Ludivine Delfau , Jacques Pecaut , Eder Tomás-Mendivil , David Martin

SYNLETT, 2024, ⟨10.1055/a-2284-4798⟩

Article dans une revue (article de synthèse) hal-04570734v1
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A simple N-heterocyclic carbene for the catalytic up-conversion of aldehydes into stoichiometric super electron donors

Nadhrata Assani , Ludivine Delfau , Preslav Smits , Sébastien Redon , Youssef Kabri et al.

Chemical Science, 2024, 15, pp.14699-14704. ⟨10.1039/d4sc04011b⟩

Article dans une revue hal-04688001v1
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Boosting N-Heterocyclic Carbene Radical Organocatalysis with Nickel Chemistry: A Rational Mechanistic Study-based Approach

Ludivine Delfau , Elena Mauro , Jacques Pecaut , David Martin , Eder Tomás-Mendivil

ACS Catalysis, 2024, 14 (9), pp.7149-7156. ⟨10.1021/acscatal.4c01253⟩

Article dans une revue (article de synthèse) hal-04570741v1
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Benchmarking Methanophosphocines as Versatile P III /P V Redox Organocatalysts

Lucas Mele , Raphael El Bekri Saudain , Jean‐luc Pirat , Eder Tomás-Mendivil , David Martin et al.

Advanced Synthesis and Catalysis, 2024, ⟨10.1002/adsc.202400468⟩

Article dans une revue hal-04688149v1
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Beyond the Limits of Atropochirality: Design of Highly Conformationally Restrained Biaryls with Bridgehead Phosphine Oxide

Lucas Mele , Rachida Babouri , Jean‐luc Pirat , Eder Tomás-Mendivil , David Martin et al.

Chemistry - A European Journal, 2023, 29 (42), ⟨10.1002/chem.202300452⟩

Article dans une revue hal-04234742v1
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Bending Enamine Patterns of Stabilized Pentalenes into “Polymethine Ylides”

Valentin Thery , Cyriac Barra , Alexandra Simeoni , Jacques Pecaut , Eder Tomás-Mendivil et al.

Organic Letters, 2023, 25 (3), pp.560-564. ⟨10.1021/acs.orglett.3c00037⟩

Article dans une revue hal-04234557v1
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On the Redox Properties of the Dimers of Thiazol-2-ylidenes That Are Relevant for Radical Catalysis

Ludivine Delfau , Nadhrata Assani , Samantha Nichilo , Jacques Pecaut , Christian Philouze et al.

ACS Organic & Inorganic Au, 2023, 3 (3), pp.136-142. ⟨10.1021/acsorginorgau.3c00008⟩

Article dans une revue hal-04234462v1
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An air-stable radical with a redox-chameleonic amide

Jesse L Peltier , Melinda R Serrato , Valentin Thery , Jacques Pecaut , Eder Tomás-Mendivil et al.

Chemical Communications, 2023, 59 (5), pp.595. ⟨10.1039/d2cc05404c⟩

Article dans une revue hal-03936050v1
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The curious case of a sterically crowded Stenhouse salt

Valentin Théry , Florian Molton , Selim Sirach , Neven Tillet , Jacques Pécaut et al.

Chemical Science, 2022, 13, pp.9755-9760. ⟨10.1039/D2SC01895K⟩

Article dans une revue hal-03752613v1
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Critical Assessment of the Reducing Ability of Breslow‐type Derivatives and Implications for Carbene‐catalyzed Radical Reactions.

Ludivine Delfau , Samantha Nichilo , Florian Molton , Julie Broggi , Eder Tomás-Mendivil et al.

Angewandte Chemie International Edition, 2021, 60 (51), pp.26783-26789. ⟨10.1002/anie.202111988⟩

Article dans une revue hal-03411268v1
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Air-Stable Oxyallyl Patterns and a Switchable N-Heterocyclic Carbene

Eder Tomas-Mendivil , Marc Devillard , Vianney Regnier , Jacques Pécaut , David Martin

Angewandte Chemie International Edition, 2020, 59 (28), pp.11516-11520. ⟨10.1002/anie.202002669⟩

Article dans une revue hal-02797042v1
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Realizing Metal-Free Carbene-Catalyzed Carbonylation Reactions with CO

Jesse L Peltier , Eder Tomás-Mendivil , Daniel R Tolentino , Max M Hansmann , Rodolphe Jazzar et al.

Journal of the American Chemical Society, 2020, 142 (43), pp.18336-18340. ⟨10.1021/jacs.0c09938⟩

Article dans une revue hal-03083226v1

Cooperative NHC/Nickel Radical Catalysis for the Synthesis of Ketones employing Aldehydes and Tertiary Alkyl Iodides.

Eder Tomás-Mendivil

Journée d’automne DCO 2024, Dec 2024, Paris, France

Communication dans un congrès hal-04937605v1

Merging N-heterocyclic carbene organocatalysis and nickel radical catalysis through a SET event.

Eder Tomás-Mendivil

GECOM-CONCOORD 2024, May 2024, Ax-les-Thermes, France

Communication dans un congrès hal-04937600v1

Vitamin B1 inspired N-heterocyclic carbene radical catalysis

Eder Tomás-Mendivil

ARCANE Scientific Day, May 2023, Grenoble, France

Communication dans un congrès hal-04937586v1

Reducing ability of Breslow-type derivatives in NHC-catalyzed reactions

David Martin , Ludivine Delfau , Eder Tomás-Mendivil

JCO2022, 2022, Palaiseau (Ecole Polytechnique), France

Communication dans un congrès hal-04945252v1

Breslow type enolates as reducing agents in N-heterocyclic carbene radical catalysis

Eder Tomás-Mendivil

GECO 62, Aug 2022, Carry-le-Rouet, France

Communication dans un congrès hal-04937568v1

A proton-responsive “smart” N-heterocyclic carbene: switching the electronics through a pH-reactive backbone.

Eder Tomás-Mendivil

GECOM-CONCOORD 2022, May 2022, Sevrier, France

Communication dans un congrès hal-04937576v1

Understanding organic functionalities: the case of an oxyallyl group-functionalized N-heterocyclic carbene and vice versa.

Eder Tomás-Mendivil

JCO 2019, Oct 2019, Palaiseau, France

Communication dans un congrès hal-04937559v1

Ambiphilic Singlet Carbenes for Small Molecule Activation: the Case of Carbonylation

Eder Tomás-Mendivil

XXXVII Reunión Bienal de la Real Sociedad Española de Química, May 2019, San Sebastian-Donostia, Spain

Communication dans un congrès hal-04937548v1