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Phenylseleno trifluoromethoxylation of alkenes
Clément Delobel
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Unlocking the Power of Acyl Fluorides: A Comprehensive Guide to Synthesis and Properties
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Direct Introduction of the 1‐Fluorocyclopropyl Group <i>via</i> Stille Cross‐Coupling – A Way of Getting Around Per‐ and Polyfluoroalkyl Substances (PFASs)
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3‐Amido‐benzo[b]silines: straightforward modular 2‐step synthesis and photophysical properties
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hal-04538289
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Trifluoromethoxylation of Arynes using 2,4‐Dinitro‐1‐(trifluoromethoxybenzene) as Trifluoromethoxide Anion Source
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Article dans une revue
hal-04591124
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Synthesis of 2-amidoindenone derivatives through an ynamide carbosilylation / Houben-Hoesch cyclization 2-step sequence
Pierre Hansjacob
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Article dans une revue
hal-04316905
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Synthesis of Polyfluoroalkyl Aryl Ethers Mediated by Sulfuryl Fluoride as a Traceless Activator
Clotilde Plaçais
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Article dans une revue
hal-04804896
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On a seamlessly replicable circular photoreactor for lab-scale continuous flow applications
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Article dans une revue
hal-04558234
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Traceless N ‐Polyfluoroalkylation of Weakly Nucleophilic Nitrogen Containing Compounds
Laura Santos
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Article dans une revue
hal-04100627
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Zinc-Catalyzed Hydrocyanation of Ynamides and Photoisomerization, a General and Selective Access to E and Z Trisubstituted Alpha-Enamidonitriles
Pierre Hansjacob
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Article dans une revue
hal-04051662
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Comprehensive Study and Development of a Metal-Free and Mild Nucleophilic Trifluoromethoxylation
Clémence Bonnefoy
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Article dans une revue
hal-04165325
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Ruthenium‐catalyzed Synthesis of Aryl and Alkenyl Halides from Fluorosulfonates
Clotilde Plaçais
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hal-04100620
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(NHC-olefin)-nickel(0) nanoparticles as catalysts for the (Z)-selective semi-hydrogenation of alkynes and ynamides
Marta G. Avello
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hal-03909675
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Direct Deprotonative Functionalization of α,α‐Difluoromethyl Ketones using a Catalytic Organosuperbase
Amélia Messara
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Koichi Mikami
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Frederic Leroux
Article dans une revue
hal-03933942
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Exploring F/CF3 substituted oxocarbenium ions for the diastereoselective assembly of highly substituted tetrahydrofurans
Anthony J Fernandes
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Agnès Martin-Mingot
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Article dans une revue
hal-04046996
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Reactions of substituted arynes and diphenylphosphine oxide or diphenylphosphine-borane complex toward dibenzophospholes – impact of aryne substituents
Marie-Charlotte Belhomme
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Article dans une revue
hal-04057602
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New Chemical Transformations Involving SO 2 F 2 ‐Mediated Alcohol Activation
Florian Audet
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David Bernier
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Article dans une revue
hal-04164625
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Difluoromethoxylated Ketones as Building Blocks for the Synthesis of Challenging OCF2H‐Bearing N‐Heterocycles.
Anaïs Loison
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Article dans une revue
hal-04163739
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Palladium‐Catalyzed Silylcyanation of Ynamides: Regio‐ and Stereoselective Access to Tetrasubstituted 3‐Silyl‐2‐Aminoacrylonitriles
Pierre Hansjacob
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Vincent Gandon
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Article dans une revue
hal-03541070
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Study of Carbamoyl Fluoride: Synthesis, Properties and Applications
Clémence Bonnefoy
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Emmanuel Chefdeville
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Christian Tourvieille
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Article dans une revue
hal-03744602
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One‐step Oxidative Monofluorination of Electron‐deficient Sulfoxides to Access Highly Lewis Acidic Sulfur(VI) Cations
Jordan Berreur
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Alberto Diez-Varga
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Augustin Manel
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Frédéric Leroux
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Article dans une revue
hal-03795951
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Ketenimines as Intermediates To Access Difluoromethoxylated Scaffolds
Anaïs Loison
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Article dans une revue
hal-03843401
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Direct Access to 2,3-Disubstituted Amido-Indenones through Annulation of 2-Iodobenzaldehydes with Ynamides
Stéphane Golling
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Pierre Hansjacob
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Nassim Bami
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Frédéric R Leroux
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Article dans une revue
hal-03883448
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SO2F2-Mediated N-Alkylation of Imino-Thiazolidinones
Laura Santos
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Armen Panossian
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Jean-Pierre Vors
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Article dans une revue
hal-03325274
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Recent synthetic methods towards the –OCHF2 moiety
Anaïs Loison
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Article dans une revue
hal-03517915
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CF3-substituted carbocations: underexploited intermediates with great potential in modern synthetic chemistry
Anthony J Fernandes
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Bastien Michelet
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Agnès Martin-Mingot
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Article dans une revue
hal-03154651
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Electrophilic fluorosulfoxonium cations as hidden Brønsted acid catalysts in (n+2) annulations of strained cycloalkanes
Augustin Manel
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Jordan Berreur
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Article dans une revue
hal-03325336
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Direct trifluoromethoxylation without OCF3 ‐carrier via in‐situ generation of fluorophosgene
Jérémy Saiter
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Morgan Donnard
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Armen Panossian
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Gilles Hanquet
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Article dans une revue
hal-03228836
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Versatile Access to Tetrasubstituted 2-Amidoacroleins through Formal Silylformylation of Ynamides
Stéphane Golling
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Frédéric R. Leroux
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Morgan Donnard
Article dans une revue
hal-03369636
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The winding road towards an atropo-enantioselective 'ARYNE coupling
David Augros
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Corinne Comoy
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Yves Fort
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Frédéric Leroux
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Article dans une revue
hal-03170152
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Study of a Stable “Trifluoromethoxide Anion Solution” Arising from 2,4‐Dinitro‐Trifluoromethoxybenzene
Clémence Bonnefoy
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Emmanuel Chefdeville
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Armen Panossian
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Gilles Hanquet
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Frédéric R. Leroux
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Article dans une revue
hal-03582991
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Practical Synthesis and Application of Halogen-Doped Pyrrole Building Blocks
Andrej Emanuel Cotman
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Ivana Kovačević
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Davide Benedetto Tiz
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Martina Durcik
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Article dans une revue
hal-03228819
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Aryl Fluoroalkyl Sulfoxides: Optical Stability and p K a Measurement
Amélia Messara
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Nicolas Vanthuyne
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Patrick Diter
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Mourad Elhabiri
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Armen Panossian
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Article dans une revue
hal-03319682
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Synthesis of 3-Amino-5-fluoroalkylfurans by Intramolecular Cyclization
Clotilde Plaçais
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Morgan Donnard
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Armen Panossian
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Jean-Pierre Vors
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David Bernier
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Article dans une revue
hal-03325240
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Formation of synthetically relevant CF3-substituted phenonium ions in superacid media
Anthony J Fernandes
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Bastien Michelet
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Armen Panossian
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Agnès Martin-Mingot
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Frédéric R. Leroux
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Article dans une revue
hal-03325280
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Deprotonative Functionalization of the Difluoromethyl Group
Laura Santos
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Armen Panossian
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Morgan Donnard
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Jean-Pierre Vors
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Sergii Pazenok
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Article dans une revue
hal-02989088
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Synthesis and Use of Trifluoromethylthiolated Ketenimines
Frédéric R. Leroux
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Nadiia Pikun
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Ryutaro Morioka
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Article dans une revue
hal-02990038
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Transition-Metal-Free Heterobiaryl Synthesis via Aryne Coupling
Tarak Saied
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Catherine Demangeat
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Armen Panossian
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Frédéric Leroux
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Article dans une revue
hal-02186792
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Efficient asymmetric synthesis of aryl difluoromethyl sulfoxides and their use to access enantiopure α-difluoromethyl alcohols
Chloé Batisse
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Marco Castello
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Amélia Messara
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Article dans une revue
hal-02400108
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Transition-Metal-Free Approach for the Direct Arylation of Thiophene: Experimental and Theoretical Investigations towards the (Het)-Aryne Route
Catherine Demangeat
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Romain Ramozzi
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Francesca Ingrosso
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Article dans une revue
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A physico-chemical investigation of fluorine-enriched quinolines
F. Aribi
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Article dans une revue
hal-02105499
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Stereoselectivity Switch in the Trapping of Polar Organometallics with Andersen’s Reagent—Access to Highly Stereoenriched Transformable Biphenyls
J. Bortoluzzi
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Article dans une revue
hal-02105503
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A fluorine scan of a tubulin polymerization inhibitor isocombretastatin A-4: Design, synthesis, molecular modelling, and biological evaluation
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Article dans une revue
hal-02105508
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Access towards enantiopure α,α-difluoromethyl alcohols by means of sulfoxides as traceless chiral auxiliaries
Chloé Batisse
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Armen Panossian
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Gilles Hanquet
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Frédéric Leroux
Article dans une revue
hal-02150060
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Synthesis of Mono- and Bis(fluoroalkyl)pyrimidines from FARs, Fluorinated Acetoacetates, and Malononitrile Provides Easy Access to Novel High-Value Pyrimidine Scaffolds
E. Schmitt
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J.-P. Vors
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Article dans une revue
hal-02105509
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Towards biphenyl based frustrated Lewis pairs
Julien Bortoluzzi
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Armen Panossian
Abstracts of Papers of the American Chemical Society, 2018, 256
Article dans une revue
hal-04889950
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Fluoroalkyl Amino Reagents for the Introduction of the Fluoro(trifluoromethoxy)methyl Group onto Arenes and Heterocycles
Etienne Schmitt
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Sebastien Bouvet
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Bruce Pegot
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Armen Panossian
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Article dans une revue
hal-02105321
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Control of axial chirality in absence of transition metals based on arynes
Frédéric R. Leroux
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David Augros
Article dans une revue
hal-02105315
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Switchable Diastereoselectivity in the Fluoride-Promoted Vinylogous Mukaiyama–Michael Reaction of 2-[(Trimethylsilyl)oxy]furan Catalyzed by Crown Ethers
Giorgio Della Sala
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Rosaria Schettini
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Francesco de Riccardis
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Article dans une revue
hal-02105791
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Fluoroalkyl Amino Reagents (FARs): A General Approach towards the Synthesis of Heterocyclic Compounds Bearing Emergent Fluorinated Substituents
Bruno Commare
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Fallia Aribi
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Armen Panossian
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Jean-Pierre Vors
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Article dans une revue
hal-02105792
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Le fluor, un élément qui vous veut du bien
Frédéric Leroux
L'Actualité Chimique, 2017, 421
Article dans une revue
hal-05020031
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Tri- and difluoromethoxylated N-based heterocycles − Synthesis and insecticidal activity of novel F3CO- and F2HCO-analogues of Imidacloprid and Thiacloprid
Grégory Landelle
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Etienne Schmitt
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Armen Panossian
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Jean-Pierre Vors
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Article dans une revue
hal-02105310
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Transition-Metal-Free Synthesis of a Known Intermediate in the Formal Synthesis of (-)-Steganacin
David Augros
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Matthieu Chessé
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Article dans une revue
hal-02105793
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Asymmetric α-Sulfonyl- and α-Phosphoryl-Oxylation of Ketones by a Chiral Hypervalent Iodine(III)
Guillaume Levitre
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Audrey Dumoulin
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Pascal Retailleau
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Armen Panossian
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Article dans une revue
hal-02105318
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When Chirality Meets “Buchwald-Type” Phosphines: Synthesis and Evaluation in Frustrated Lewis Pair-, Lewis Base- and Palladium-Promoted Asymmetric Catalysis
Frédéric R. Leroux
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Mickaël Fer
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Joséphine Cinqualbre
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Julien Bortoluzzi
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Matthieu Chessé
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Article dans une revue
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hal-03004119
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A Major Advance in the Synthesis of Fluoroalkyl Pyrazoles: Tuneable Regioselectivity and Broad Substitution Patterns
Etienne Schmitt
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Jean-Pierre Vors
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Christian Funke
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Article dans une revue
hal-03004108
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A new approach toward the synthesis of 2,4-bis(fluoroalkyl)-substituted quinoline derivatives using fluoroalkyl amino reagent chemistry
Fallia Aribi
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Jean-Pierre Vors
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Sergiy Pazenok
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Article dans une revue
hal-03004130
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Access to Atropisomerically Enriched Biaryls by the Coupling of Aryllithiums with Arynes under Control by Homochiral Oxazolines
Boubacar Yalcouye
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David Augros
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Sabine Choppin
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Article dans une revue
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hal-02304102
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Atropo-diastereoselective coupling of aryllithiums and arynes — variations around the chiral auxiliary
Frédéric R. Leroux
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Anaïs Berthelot-Bréhier
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Matthieu Chessé
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Article dans une revue
hal-03004140
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Lithium/Element Exchange as an Efficient Tool for Accessing Atropo-enriched Biaryls <i>via</i> Arynes
Armen Panossian
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Article dans une revue
hal-03004175
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The French Connection : Editorial
Frédéric R. Leroux
CHIMIA, 2016, 70 (1-2), pp.6-7
Article dans une revue
hal-04876344
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In Situ Generated Fluorinated Iminium Salts for Difluoromethylation and Difluoroacetylation
Frédéric R. Leroux
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Baptiste Rugeri
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Armen Panossian
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Jean-Pierre Vors
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Article dans une revue
hal-03004193
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Determination of the absolute configuration of phosphinic analogues of glutamate
Bruno Commare
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Isabelle Lemasson
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Patrick Deschamps
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Article dans une revue
hal-02268872
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Recent advances and new concepts for the synthesis of axially stereoenriched biaryls
Joanna Wencel‐delord
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Frédéric Leroux
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Françoise Colobert
Article dans une revue
hal-02305225
v1
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Modular Synthesis of Biaryl-Substituted Phosphine Ligands: Application in Microwave-Assisted Palladium-Catalyzed C-N Cross-Coupling Reactions
Chandani Singh
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Jayant Rathod
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Vishwajeet Jha
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Armen Panossian
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Pradeep Kumar
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Article dans une revue
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hal-02304103
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Substituent effects on the relative rates and free energies of ortho-lithiation reactions: families of fluorobenzenes as the substrates
F Mongin
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E Marzi
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Frédéric Leroux
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M Schlosser
Article dans une revue
hal-02304104
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Unusual phosphine oxidation: new triazolopyridyl-quinolyl phosphine oxide fluorescent dyes
R. Ballesteros-Garrido
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F. Colobert
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Frédéric R. Leroux
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Article dans une revue
hal-03004215
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Atroposelective synthesis of axially chiral P,S-ligands based on arynes
Anais Berthelot-Brehier
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Armen Panossian
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Francoise Colobert-Leuenberger
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Frédéric Leroux
Article dans une revue
hal-02306240
v1
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Synthesis and biological evaluation of new nucleosides derived from trifluoromethoxy-4-quinolones
Kristína Plevová
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Francoise Colobert-Leuenberger
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Jela Mistríková
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Viktor Milata
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Article dans une revue
hal-02305222
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Asymmetric Bromine-Lithium Exchange: Application toward the Synthesis of New Biaryl-Diphosphine Ligands
Frédéric R. Leroux
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Julien Graff
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Elżbieta Łastawiecka
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Laure Guénée
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Frédéric Leroux
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Article dans une revue
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hal-03004211
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Tribute to Prof. Manfred Schlosser (1934-2013) Obituary
Renzo Ruzziconi
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Frédéric Leroux
Article dans une revue
hal-02304109
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Multi-nuclear NMR of axially chiral biaryls in polypeptide orienting solvents: spectral discriminations and enantiorecognition mechanisms
Philippe Berdagué
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Jose-Enrique Herbert-Pucheta
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Vishwajeet Jha
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Armen Panossian
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Frédéric Leroux
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Article dans une revue
hal-02314357
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A General Approach towards NH-Pyrazoles That Bear Diverse Fluoroalkyl Groups by Means of Fluorinated Iminium Salts
Étienne Schmitt
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Gregory Landelle
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Jean-Pierre Vors
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Norbert Lui
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Sergiy Pazenok
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Article dans une revue
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hal-02305226
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Fluorine Chemistry Special Feature
Frédéric Leroux
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Mark Ford
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Sergiy Pazenok
Article dans une revue
hal-02306238
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Trifluoromethyl Ethers and -Thioethers as Tools for Medicinal Chemistry and Drug Discovery
Gregory Landelle
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Armen Panossian
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Frédéric Leroux
Current Topics in Medicinal Chemistry, 2014, 14 (7), pp.941-951
Article dans une revue
hal-02306242
v1
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Novel C1-symmetric dibenzophosphole ligands: application in hydroformylation reactions
Abdelouahd Oukhrib
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Laurence Bonnafoux
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Armen Panossian
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Sandrine Waifang
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Duc Hanh Nguyen
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Article dans une revue
hal-00992450
v1
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A theoretical and experimental study of the racemization process of hexaaza[5]helicenes
Belen Abarca
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Rafael Ballesteros
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Rosa Adam
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Rafael Ballesteros-Garrido
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Frédéric Leroux
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Article dans une revue
hal-02307797
v1
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A concise atroposelective formal synthesis of (-)-steganone
Boubacar Yalcouye
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Sabine Choppin
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Armen Panossian
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Frédéric Leroux
,
Francoise Colobert-Leuenberger
Article dans une revue
istex
hal-02304105
v1
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A New Synthesis and Process Development of Bis(fluoroalkyl)pyrazoles As Novel Agrophores
F Giornal
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G Landelle
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N Lui
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J Vors
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S Pazenok
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Article dans une revue
hal-02342504
v1
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Recent advances in transition metal-catalyzed Csp(2)-monofluoro-, difluoro-, perfluoromethylation and trifluoromethylthiolation
Gregory Landelle
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Armen Panossian
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Sergiy Pazenok
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Jean-Pierre Vors
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Frédéric Leroux
Article dans une revue
hal-02304098
v1
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Convenient and Reliable Routes Towards 2-Aminothiazoles: Palladium-Catalyzed versus Copper-Catalyzed Aminations of Halothiazoles
Stéphanie Toulot
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Timo Heinrich
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Frédéric Leroux
Article dans une revue
hal-02342506
v1
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Manfred Schlosser (1934-2013) Obituary
Frédéric Leroux
Article dans une revue
istex
hal-02307800
v1
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A New Life for an Old Reagent: Fluoroalkyl Amino Reagents as Efficient Tools for the Synthesis of Diversely Fluorinated Pyrazoles
Sergiy Pazenok
,
Florence Giornal
,
Grégory Landelle
,
Norbert Lui
,
Jean-Pierre Vors
et al.
Article dans une revue
istex
hal-03004227
v1
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Synthesis and structural properties of hexaaza[5]helicene containing two [1,2,3]triazolo[1,5-a]pyridine moieties
Rosa Adam
,
Rafael Ballesteros-Garrido
,
Oriol Vallcorba
,
Belen Abarca
,
Rafael Ballesteros
et al.
Article dans une revue
istex
hal-02306243
v1
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Palladium-Catalyzed Intramolecular Direct Arylation of 2-Bromo-diaryl Sulfoxides via C-H Bond Activation
Thomas Wesch
,
Anaïs Brehier
,
Frédéric Leroux
,
Francoise Colobert-Leuenberger
Article dans une revue
hal-02304107
v1
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Atropodiastereoselective C-H Olefination of Biphenyl p-Tolyl Sulfoxides with Acrylates
Thomas Wesch
,
Frédéric Leroux
,
Francoise Colobert-Leuenberger
Article dans une revue
istex
hal-02304106
v1
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Synthesis of diversely fluorinated pyrazoles as novel active agrochemical ingredients
Florence Giornal
,
Lars Rodefeld
,
Norbert Lui
,
Jean-Pierre Vors
,
Frédéric Leroux
Article dans une revue
istex
hal-02307799
v1
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Aryne-mediated fluorination: Synthesis of fluorinated biaryls via a sequential desilylation-halide elimination-fluoride addition process
Vincent Diemer
,
Juan Garcia
,
Frédéric Leroux
,
Francoise Colobert-Leuenberger
Article dans une revue
istex
hal-02306231
v1
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Triazolopyridines. Part 28. The ring-chain isomerization strategy: triazolopyridine- and triazoloquinoline-pyridine based fluorescence ligands
Rafael Ballesteros-Garrido
,
Estefania Delgado-Pinar
,
Belen Abarca
,
Rafael Ballesteros
,
Frédéric Leroux
et al.
Article dans une revue
istex
hal-02306237
v1
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Construction of the biaryl-part of vancomycin aglycon via atropo-diastereoselective Suzuki-Miyaura coupling
Timo Leermann
,
Pierre-Emmanuel Broutin
,
Frédéric Leroux
,
Francoise Colobert-Leuenberger
Article dans une revue
hal-02306241
v1
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Transition-Metal-Free Atropo-Selective Synthesis of Biaryl Compounds Based on Arynes
Frédéric Leroux
,
Anaïs Brehier
,
Laurence Bonnafoux
,
Armen Panossian
,
Francoise Colobert-Leuenberger
Article dans une revue
istex
hal-02306232
v1
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Stereoselective Synthesis of o -Bromo (or Iodo)aryl P-Chirogenic Phosphines Based on Aryne Chemistry
Frédéric R. Leroux
,
Jérôme Bayardon
,
Hugo Laureano
,
Vincent Diemer
,
Mathieu Dutartre
et al.
Article dans une revue
hal-03004233
v1
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Stereoselective Synthesis of P-Chirogenic Dibenzophosphole-Boranes via Aryne Intermediates
Vincent Diemer
,
Anaïs Brehier
,
Jérôme Bayardon
,
Sylvain Juge
,
Frédéric Leroux
et al.
Article dans une revue
hal-02306244
v1
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Efficient and Complementary Methods Offering Access to Synthetically Valuable 1,2-Dibromobenzenes
Vincent Diemer
,
Frédéric Leroux
,
Francoise Colobert-Leuenberger
Article dans une revue
istex
hal-02306234
v1
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Polar Organometallic Chemistry
Frédéric Leroux
Current Organic Chemistry, 2011, 15 (13)
Article dans une revue
hal-02305223
v1
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Catalytic Palladium Phosphination: Modular Synthesis of C1-Symmetric Biaryl-Based Diphosphines
Laurence Bonnafoux
,
Rafael Gramage-Doria
,
Francoise Colobert
,
Frederic R. Leroux
Article dans une revue
istex
hal-01472931
v1
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Bromine-lithium exchange: An efficient tool in the modular construction of biaryl ligands
Laurence Bonnafoux
,
Frédéric Leroux
,
Francoise Colobert-Leuenberger
Article dans une revue
hal-02307798
v1
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Highly Efficient One-Pot Access to Functionalized Arylboronic Acids via Noncryogenic Bromine/Magnesium Exchanges
Timo Leermann
,
Frédéric Leroux
,
Francoise Colobert-Leuenberger
Article dans une revue
hal-02305220
v1
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Through-Space J(P,P) and J(P,F) Spin-Spin Coupling in C-1-Symmetric Biaryl Diphosphanes
Laurence Bonnafoux
,
Ludger Ernst
,
Frédéric Leroux
,
Francoise Colobert-Leuenberger
Article dans une revue
istex
hal-02306233
v1
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Regioselectivity in the Aryne Cross-Coupling of Aryllithiums with Functionalized 1,2-Dibromobenzenes
Vincent Diemer
,
Manon Begaud
,
Frédéric Leroux
,
Francoise Colobert-Leuenberger
Article dans une revue
istex
hal-02306235
v1
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[1,2,3]Triazolo[1,5-a]pyridyl phosphines reflecting the influence of phosphorus lone pair orientation on spectroscopic properties
Rafael Ballesteros-Garrido
,
Laurence Bonnafoux
,
Fernando Blanco
,
Rafael Ballesteros
,
Frédéric Leroux
et al.
Article dans une revue
hal-02306239
v1
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A General Approach to (Trifluoromethoxy)pyridines: First X-ray Structure Determinations and Quantum Chemistry Studies
Baptiste Manteau
,
Pierre Genix
,
Lydia Brelot
,
Jean-Pierre Vors
,
Sergiy Pazenok
et al.
Article dans une revue
istex
hal-03370334
v1
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2,2′,6-Tribromobiphenyl via Transition-Metal-Free ARYNE Coupling: A Valuable Tool in the Synthesis of Biphenyls
Frédéric R. Leroux
,
Laurence Bonnafoux
,
Françoise Colobert
Article dans une revue
hal-03366549
v1
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Efficient synthesis of quaternary and P-stereogenic phosphonium triflates
Emmanuelle Remond
,
Arnaud Tessier
,
Frédéric Leroux
,
Jérome Bayardon
,
Sylvain Jugé
Article dans une revue
hal-00474388
v1
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