Iker Del Rosal

Publications

Article dans une revue (111)

Mono- to Tetra-nuclear Iron Dichloride Complexes Bearing N -(Fluoro)-aryl-Substituted Iminopyridine Ligands: Synthesis, Structures, Magnetic Properties, and Polymerization of Isoprene Obaid Hashmi,Raphael Caulier,Frederic Capet,Olivier Mentré,Claire Minaudet al. Inorganic Chemistry, 2025, 64 (29), pp.14836-14852. ⟨10.1021/acs.inorgchem.5c01030⟩ Article dans une revue hal-05163264v1
Synergistic C–H bond activation across molybdenum–iridium multiply bonded complexes: a cascade of transformations Zachary Dubrawski,Iker del Rosal,Erwann Jeanneau,Laurent Maron,Chloé Thieuleuxet al. Chemical Science, 2025, ⟨10.1039/D5SC03465E⟩ Article dans une revue hal-05173362v1
Biplane-like small N-heterocyclic carbenes as effective ligands in challenging Ru-catalyzed metathesis of sterically crowded olefins Paweł Krzesiński,Chiara Dinoi,Iker Del rosal,Laure Vendier,Pavel Kumandinet al. Chem Catalysis, 2025, 5 (5), pp.101292. ⟨10.1016/j.checat.2025.101292⟩ Article dans une revue hal-04542322v2
Probing Structural Diversity in a Series of Perhydrocarbyl Heterobimetallic Complexes Associating Tantalum and 3d (Cr, Mn, Fe, Co, Ni) Transition Metals Till Neumann,Iker del Rosal,Laurent Maron,Erwann Jeanneau,Vincent Maurelet al. Inorganic Chemistry, 2025, 64 (43), pp.21353-21367. ⟨10.1021/acs.inorgchem.5c02380⟩ Article dans une revue hal-05505845v1
Effect of Nitrogen and Phosphorus Doping of Reduced Graphene Oxide in the Hydrogen Evolution Catalytic Activity of Supported Ru Nanoparticles Laura Mallón,Javier Navarro-Ruiz,Christian Cerezo-Navarrete,Nuria Romero,Iker del Rosalet al. ACS Applied Materials & Interfaces, 2025, 17 (4), pp.6198-6210. ⟨10.1021/acsami.4c15547⟩ Article dans une revue hal-04931941v1
Room-Temperature H&lt;sub&gt;2&lt;/sub&gt; Splitting and N&lt;sub&gt;2&lt;/sub&gt;-Hydrogenation Induced by a Neutral Lu(II) Complex Evangelos Papangelis,Luca Demonti,Iker del Rosal,Angus Shephard,Laurent Maronet al. Journal of the American Chemical Society, 2025, 147 (11), pp.9752-9763. ⟨10.1021/jacs.4c18416⟩ Article dans une revue hal-05213394v1
Oxidative Addition of E-H (E=C, N) Bonds to Transient Uranium(II) Centers Wei Fang,Yafei Li,Tianze Zhang,Thayalan Rajeshkumar,Iker Del rosalet al. Angewandte Chemie International Edition, 2024, 63 (32), ⟨10.1002/anie.202407339⟩ Article dans une revue hal-04707677v1
Photolysis-driven bond activation by thorium and uranium tetraosmate polyhydride complexes Christopher Ye,Iker del Rosal,Sheridon Kelly,I. Joseph Brackbill,Laurent Maronet al. Chemical Science, In press, ⟨10.1039/D4SC02380C⟩ Article dans une revue hal-04611467v1
Straightforward construction of a rare-earth diphosphanato complex from white phosphorus: synthesis and reactivity Fangjun Zhang,Iker Del rosal,Keyu Han,Jie Zhang,Laurent Maronet al. Inorganic Chemistry Frontiers, 2024, 11 (6), pp.1742-1753. ⟨10.1039/d3qi02680a⟩ Article dans une revue hal-04707645v1
Probing Basal and Prismatic Planes of Graphitic Materials for Metal Single Atom and Subnanometer Cluster Stabilization Mathieu Vidal,Jyoti Pandey,Javier Navarro-Ruiz,Joris Langlois,Yann Tisonet al. Chemistry - A European Journal, 2024, 30 (50), pp.e202400669. ⟨10.1002/chem.202400669⟩ Article dans une revue hal-04677240v1
Synthesis, Structure, and Bonding of Actinide–Rhenium Polyhydrides Christopher Ye,Iker del Rosal,Sheridon Kelly,Erik Ouellette,Laurent Maronet al. Inorganic Chemistry, In press, ⟨10.1021/acs.inorgchem.4c03449⟩ Article dans une revue hal-04749940v1
Reduction of CS 2 to an ethanetetrathiolate by a hydride-bridged uranium–iridium heterobimetallic complex Christopher Z Ye,Iker del Rosal,Erik T Ouellette,Stephan Hohloch,Laurent Maronet al. Chemical Communications, In press, ⟨10.1039/D4CC02482F⟩ Article dans une revue hal-04724457v1
π-Bonding of Group 11 Metals to a Tantalum Alkylidyne Alkyl Complex Promotes Unusual Tautomerism to Bis-alkylidene and CO 2 to Ketenyl Transformation Abdelhak Lachguar,Iker del Rosal,Laurent Maron,Erwann Jeanneau,Laurent Veyreet al. Journal of the American Chemical Society, 2024, ⟨10.1021/jacs.4c02172⟩ Article dans une revue hal-04630141v1
Mechanism of Hydrogen Spillover on Metal-Doped Carbon Materials: Surface Carboxylic Groups Are Key Javier Navarro-Ruiz,Jérémy Audevard,Mathieu Vidal,Cristian Campos,Iker del Rosalet al. ACS Catalysis, 2024, 14 (9), pp.7111-7126. ⟨10.1021/acscatal.4c00293⟩ Article dans une revue hal-04587084v1
CO&lt;sub&gt;2&lt;/sub&gt; cleavage by tantalum/M (M = iridium, osmium) heterobimetallic complexes Abdelhak Lachguar,Christopher Z Ye,Sheridon N Kelly,Erwann Jeanneau,Iker del Rosalet al. Chemical Communications, 2024, 60 (61), pp.7878-7881. ⟨10.1039/D4CC02207F⟩ Article dans une revue hal-04738526v1
Isolation of C1 through C4 derivatives from CO using heteroleptic uranium( iii ) metallocene aryloxide complexes Robert Ward,Iker Del Rosal,Steven Kelley,Laurent Maron,Justin Walensky Chemical Science, 2023, 14 (8), pp.2024-2032. ⟨10.1039/d2sc06375a⟩ Article dans une revue hal-04218352v1
“Cocktail”-type catalysis on bimetallic systems for cinnamaldehyde selective hydrogenation: Role of isolated single atoms, nanoparticles and single atom alloys Jérémy Audevard,Javier Navarro-Ruiz,Vincent Bernardin,Régis Philippe,Anna Corriaset al. Journal of Catalysis, 2023, 425, pp.245-259. ⟨10.1016/j.jcat.2023.06.023⟩ Article dans une revue hal-04139552v1
Deactivation of Pd/C catalysts by irreversible loss of hydrogen spillover ability of the carbon support Laurent Vanoye,Boris Guicheret,Camila Rivera-Cárcamo,Jérémy Audevard,Javier Navarro-Ruizet al. Journal of Catalysis, 2023, 424, pp.173-188. ⟨10.1016/j.jcat.2023.05.006⟩ Article dans une revue hal-04113228v1
A binuclear guanidinate yttrium carbyne complex: unique reactivity toward unsaturated C-N, C-O and C-S bonds Wen Jiang,Feng Kong,Iker Del rosal,Meng Li,Kai Wanget al. Chemical Science, 2023, ⟨10.1039/d3sc03483f⟩ Article dans une revue hal-04707640v1
Synthesis and Reactivity of a Zinc Diazoalkyl Complex: [3+2] Cycloaddition Reaction with Carbon Monoxide Shengjie Jiang,Yanping Cai,Thayalan Rajeshkumar,Iker Del rosal,Laurent Maronet al. Angewandte Chemie International Edition, 2023, 62 (34), ⟨10.1002/anie.202307244⟩ Article dans une revue hal-04707653v1
An Experimental and Computational Investigation Rules Out Direct Nucleophilic Addition on the N2 Ligand in Manganese Dinitrogen Complex [Cp(CO)2Mn(N2)] Quentin Le Dé,Amal Bouammali,Christian Bijani,Laure Vendier,Iker Del rosalet al. Angewandte Chemie International Edition, 2023, 62 (40), pp.e202305235. ⟨10.1002/anie.202305235⟩ Article dans une revue hal-04159061v1
Adjustment of the Single Atom/Nanoparticle Ratio in Pd/CNT Catalysts for Phenylacetylene Selective Hydrogenation Jérémy Audevard,Javier Navarro-Ruiz,Vincent Bernardin,Yann Tison,Anna Corriaset al. ChemCatChem, 2023, 15 (11), pp.e202300036. ⟨10.1002/cctc.202300036⟩ Article dans une revue hal-04102599v1
On the use of 17 O NMR for understanding molecular and silica-grafted tungsten oxo siloxide complexes Y. Bouhoute,D. Grekov,N. Merle,K. Szeto,C. Larabiet al. Dalton Transactions, 2023, 52 (28), pp.9573-9581. ⟨10.1039/D3DT01593A⟩ Article dans une revue hal-04238255v1
Multimetallic Uranium Nitride Cubane Clusters from Dinitrogen Cleavage Mikhail S. Batov,Iker Del rosal,Rosario Scopelliti,Farzaneh Fadaei-Tirani,Ivica Zivkovicet al. Journal of the American Chemical Society, 2023, 145 (48), pp.26435-26443. ⟨10.1021/jacs.3c10617⟩ Article dans une revue hal-04707678v1
Isolation of C1 through C4 derivatives from CO using heteroleptic uranium(III) metallocene aryloxide complexes (vol 14, pg 2024, 2023) Robert J. Ward,Iker Del Rosal,Steven P. Kelley,Laurent Maron,Justin R. Walensky Chemical Science, 2023, 14 (12), pp.3385. ⟨10.1039/d3sc90046k⟩ Article dans une revue hal-04707634v1
Organotitanium Complexes Supported by a Dianionic Pentadentate Ligand Daniel Beh,Alejandro Cuellar de Lucio,Iker del Rosal,Laurent Maron,Denis Spasyuket al. Organometallics, 2023, 42 (11), pp.1149-1157. ⟨10.1021/acs.organomet.2c00609⟩ Article dans une revue hal-04218412v1
1,2-Palladasilacyclobutene: The Missing Link in the Pd-Catalyzed Annulation of Alkynes for the Silirene-to-Silole Transformation Marc Devillard,Chiara Dinoi,Iker Del rosal,Clément Orione,Marie Cordieret al. Inorganic Chemistry, 2023, 62 (19), pp.7250-7263. ⟨10.1021/acs.inorgchem.3c00045⟩ Article dans une revue hal-04115375v1
A Versatile Strategy for the Formation of Hydride-Bridged Actinide-Iridium Multimetallics Christopher Z Ye,Iker Del rosal,Michael A Boreen,Erik T Ouellette,Dominic Russoet al. Chemical Science, 2022, ⟨10.1039/D2SC04903A⟩ Article dans une revue hal-03909474v1
Ruthenium icosahedra and ultrathin platelets: the role of surface chemistry on the nanoparticle structure Raj Kumar Ramamoorthy,Katerina Soulantica,Iker Del rosal,Raul Arenal,Philippe Decorseet al. Chemistry of Materials, 2022, 34 (7), pp.2931-2944. ⟨10.1021/acs.chemmater.1c03452⟩ Article dans une revue hal-03644170v1
Ruthenium nanoparticles canopied by heptagon-containing saddle-shaped nanographenes as efficient aromatic hydrogenation catalysts Christian Cerezo-Navarrete,Arthur David,Adrián García-Zaragoza,Marcos Codesal,Pascual Oña-Burgoset al. Chemical Science, 2022, 13 (44), pp.13046-13059. ⟨10.1039/d2sc04228b⟩ Article dans une revue hal-04104569v1
Hydroboration of vinyl halides with mesitylborane: a direct access to (mesityl)(alkyl)haloboranes Marc Devillard,Marie Cordier,Thierry Roisnel,Chiara Dinoi,Iker Del rosalet al. Chemical Communications, 2022, 58 (10), pp.1589-1592. ⟨10.1039/D1CC06365K⟩ Article dans une revue hal-03539282v1
Rational Preparation of Well-Defined Multinuclear Iridium-Aluminum Polyhydride Clusters and Comparative Reactivity Leon Escomel,Naime Soule,Emmanuel Robin,Iker del Rosal,Laurent Maronet al. Inorganic Chemistry, 2022, 61 (15), pp.5715-5730. ⟨10.1021/acs.inorgchem.1c03120⟩ Article dans une revue hal-03714651v1
Synthesis and Reactivity of Triangular Heterometallic ComplexesContaining Zn-Zn Bond br Shengjie Jiang,Yanping Cai,Ambre Carpentier,Iker del Rosal,Laurent Maronet al. Inorganic Chemistry, 2022, 61 (20), pp.8083-8089. ⟨10.1021/acs.inorgchem.2c00956⟩ Article dans une revue hal-03714644v1
Supramolecular nanocapsules as two-fold stabilizers of outer-cavity sub-nanometric Ru NPs and inner-cavity ultra-small Ru clusters Ernest Ubasart,Irene Mustieles Marin,Juan Manuel Asensio,Gabriel Mencia,Ángela M López-Vinascoet al. Nanoscale Horizons, 2022, 7 (6), pp.607 - 615. ⟨10.1039/d1nh00677k⟩ Article dans une revue hal-04222757v1
A Masked Form of an O‐Borylated Breslow Intermediate for the Diastereoselective FLP‐Type Activation of Aldehydes Angelica Mejia Fajardo,Nicolas Queyriaux,Aurèle Camy,Laure Vendier,Mary Grellieret al. Chemistry - A European Journal, 2022, 28 (10), pp.e202104122. ⟨10.1002/chem.202104122⟩ Article dans une revue hal-03669849v1
Surface reactions of ammonia on ruthenium nanoparticles revealed by 15 N and 13 C solid-state NMR Niels Rothermel,Hans-Heinrich Limbach,Iker del Rosal,Romuald Poteau,Gabriel Menciaet al. Catalysis Science & Technology, 2021, 11 (13), pp.4509-4520. ⟨10.1039/d0cy02476g⟩ Article dans une revue hal-04222858v1
Bimetallic RuNi nanoparticles as catalysts for upgrading biomass: metal dilution and solvent effects on selectivity shifts Miquel Cardona-Farreny,Pierre Lecante,Jerome Esvan,Chiara Dinoi,Iker Del rosalet al. Green Chemistry, 2021, 23 (21), pp.8480-8500. ⟨10.1039/D1GC02154K⟩ Article dans une revue hal-03412846v1
A Uranium(II) Arene Complex That Acts as a Uranium(I) Synthon Mark D. Straub,Erik T. Ouellette,Michael A. Boreen,R. David Britt,Khetpakorn Chakarawetet al. Journal of the American Chemical Society, 2021, 143 (47), pp.19748-19760. ⟨10.1021/jacs.1c07854⟩ Article dans une revue hal-03717277v1
Hydrosilylative reduction of carbon dioxide by a homoleptic lanthanum aryloxide catalyst with high activity and selectivity Kejian Chang,Iker del Rosal,Xizhou Zheng,Laurent Maron,Xin Xu Dalton Transactions, 2021, 50 (22), pp.7804-7809. ⟨10.1039/d1dt01074c⟩ Article dans une revue hal-03717252v1
Synthesis, Characterization, and Comparative Theoretical Investigation of Dinitrogen-Bridged Group 6-Gold Heterobimetallic Complexes David Specklin,Anaïs Coffinet,Laure Vendier,Iker Del rosal,Chiara Dinoiet al. Inorganic Chemistry, 2021, 60 (8), pp.5545-5562. ⟨10.1021/acs.inorgchem.0c03271⟩ Article dans une revue hal-03176320v2
Computational Design of Pd Nanocluster and Pd Single-Atom Catalysts Supported on O-Functionalized Graphene Javier Navarro-Ruiz,Camila Rivera-Cárcamo,Bruno Machado,Philippe Serp,Iker Del rosalet al. ACS Applied Nano Materials, 2021, 4 (11), pp.12235-12249. ⟨10.1021/acsanm.1c02743⟩ Article dans une revue hal-03627539v1
Nickel-catalyzed synthesis of Zn(i)-Zn(i) bonded compounds Shengjie Jiang,Yanping Cai,Ambre Carpentier,Iker del Rosal,Laurent Maronet al. Chemical Communications, 2021, 57 (100), pp.13696-13699. ⟨10.1039/d1cc05719g⟩ Article dans une revue hal-03717250v1
Uncatalyzed Formation of Polyaminoboranes from Diisopropylaminoborane and Primary Amines: a Kinetically Controlled Polymerization Reaction Marc Devillard,Carlos Antonio de Albuquerque Pinheiro,Elsa Caytan,Claire Roiland,Chiara Dinoiet al. Advanced Synthesis and Catalysis, 2021, 363 (9), pp.2417-2426. ⟨10.1002/adsc.202001458⟩ Article dans une revue hal-03127420v1
A combined theoretical/experimental study highlighting the formation of carbides on Ru nanoparticles during CO hydrogenation Ionut-Tudor Moraru,Luis Martínez-Prieto,Yannick Coppel,Bruno Chaudret,Lucy Cusinatoet al. Nanoscale, 2021, 13 (14), pp.6902-6915. ⟨10.1039/D0NR08735A⟩ Article dans une revue hal-03202748v1
Scandium and lanthanum hydride complexes stabilized by super-bulky penta-arylcyclopentadienyl ligands Yang Wang,Iker del Rosal,Guorui Qin,Lanxiao Zhao,Laurent Maronet al. Chemical Communications, 2021, 57 (63), pp.7766-7769. ⟨10.1039/d1cc01841h⟩ Article dans une revue hal-03717282v1
Strongly Polarized Iridium δ− –Aluminum δ+ Pairs: Unconventional Reactivity Patterns Including CO 2 Cooperative Reductive Cleavage Léon Escomel,Iker del Rosal,Laurent Maron,Erwann Jeanneau,Laurent Veyreet al. Journal of the American Chemical Society, 2021, 143 (12), pp.4844-4856. ⟨10.1021/jacs.1c01725⟩ Article dans une revue hal-03357324v1
Control of the single atom/nanoparticle ratio in Pd/C catalysts to optimize the cooperative hydrogenation of alkenes Camila Rivera‐cárcamo,I.C. Gerber,Iker Del rosal,B. Guicheret,Rubén Castro Contreraset al. Catalysis Science & Technology, 2021, 11 (3), pp.984-999. ⟨10.1039/d0cy01938k⟩ Article dans une revue hal-03148510v1
Calcium-mediated C(sp(3))-H Activation and Alkylation of Alkylpyridines Xizhou Zheng,Iker del Rosal,Xian Xu,Yingming Yao,Laurent Maronet al. Inorganic Chemistry, 2021, 60 (7), pp.5114-5121. ⟨10.1021/acs.inorgchem.1c00161⟩ Article dans une revue hal-03717254v1
Molecular Thorium Trihydrido Clusters Stabilized by Cyclopentadienyl Ligands Runhai Chen,Guorui Qin,Shihui Li,Alison J. Edwards,Ross O. Piltzet al. Angewandte Chemie International Edition, 2020, 59 (28), pp.11250-11255. ⟨10.1002/anie.202002303⟩ Article dans une revue hal-03925198v1
Catalysis to discriminate single atoms from subnanometric ruthenium particles in ultra-high loading catalysts Camila Rivera‐cárcamo,Faqiang Leng,I.C. Gerber,Iker Del rosal,Romuald Poteauet al. Catalysis Science & Technology, 2020, 10 (14), pp.4673-4683. ⟨10.1039/D0CY00540A⟩ Article dans une revue hal-02904642v1
Comparative Insertion Reactivity of CO, CO2, (BuCN)-Bu-t, and (BuNC)-Bu-t into Thorium- and Uranium-Phosphorus Bonds Michael L. Tarlton,Iker del Rosal,Sean P. Vilanova,Steven P. Kelley,Laurent Maronet al. Organometallics, 2020, 39 (11), pp.2152-2161. ⟨10.1021/acs.organomet.0c00221⟩ Article dans une revue hal-03925196v1
Mechanistic Investigations via DFT Support the Cooperative Heterobimetallic C-H and O-H Bond Activation Across Ta=Ir Multiple Bonds Iker Del rosal,Sébastien Lassalle,Laurent Maron,Chiara Dinoi,Chloé Thieuleuxet al. Dalton Transactions, 2020, ⟨10.1039/D0DT03818K⟩ Article dans une revue hal-03009651v1
Hydrogen isotope exchange catalyzed by Ru nanocatalysts: labelling of complex molecules containing N-heterocycles and reaction mechanism insights Viktor Pfeifer,Marie Certiat,Donia Bouzouita,Alberto Palazzolo,Sébastien Garcia-Argoteet al. Chemistry - A European Journal, 2020, 26, pp.4988-4996. ⟨10.1002/chem.201905651⟩ Article dans une revue cea-02487414v1
How Cu I and Na I Interact with Faujasite Zeolite? A Theoretical Investigation Hugo Petitjean,Christine Lepetit,Zalfa Nour,Romuald Poteau,Iker Del rosalet al. Journal of Physical Chemistry C, 2020, 124 (51), pp.28026-28037. ⟨10.1021/acs.jpcc.0c06862⟩ Article dans une revue hal-03117227v1
NH3 formation from N2 and H2 mediated by molecular tri-iron complexes Matthias Reiners,Dirk Baabe,Katharina Münster,Marc-Kevin Zaretzke,Matthias Freytaget al. Nature Chemistry, 2020, 12 (8), pp.740-746. ⟨10.1038/s41557-020-0483-7⟩ Article dans une revue hal-03150029v1
Nickel(0)-Induced beta-H Elimination of Magnesium Alkyls: Formation and Reactivity of Heterometallic Hydrides Jiasu Huang,Xizhou Zheng,Iker del Rosal,Bei Zhao,Laurent Maronet al. INORGANIC CHEMISTRY, 2020, 59 (18), pp.13473-13480. ⟨10.1021/acs.inorgchem.0c01885⟩ Article dans une revue hal-03925186v1
Divergent uranium-versusphosphorus-based reduction of Me(3)SiN(3)with steric modification of phosphido ligands Robert J. Ward,Pokpong Rungthanaphatsophon,Iker del Rosal,Steven P. Kelley,Laurent Maronet al. Chemical Science, 2020, 11 (22), pp.5830-5835. ⟨10.1039/d0sc02261f⟩ Article dans une revue hal-03925194v1
3D Ruthenium Nanoparticle Covalent Assemblies from Polymantane Ligands for Confined Catalysis Yuanyuan Min,Houssein Nasrallah,Didier Poinsot,Pierre Lecante,Yann Tisonet al. Chemistry of Materials, 2020, 32 (6), pp.2365-2378. ⟨10.1021/acs.chemmater.9b04737⟩ Article dans une revue hal-02541912v1
When organophosphorus ruthenium complexes covalently bind to ruthenium nanoparticles to form nanoscale hybrid materials Elena Martín Morales,Yannick Coppel,Pierre Lecante,Iker Del rosal,Romuald Poteauet al. Chemical Communications, 2020, 56 (29), pp.4059-4062. ⟨10.1039/d0cc00442a⟩ Article dans une revue hal-02569549v1
Rationalizing the Reactivity of Mixed Allyl Rare-Earth Borohydride Complexes with DFT Studies Sami Fadlallah,Jashvini Jothieswaran,Iker Del rosal,Laurent Maron,Fanny Bonnetet al. Catalysts, 2020, 10, pp.820. ⟨10.3390/catal10080820⟩ Article dans une revue hal-02926044v1
Stepwise Construction of Silica-supported Tantalum/Iridium Heteropolymetallic Catalysts Using Surface Organometallic Chemistry Sébastien Lassalle,Ribal Jabbour,Iker Del rosal,Laurent Maron,Emiliano Fondaet al. Journal of Catalysis, 2020, ⟨10.1016/j.jcat.2020.10.016⟩ Article dans une revue hal-02985281v1
DFT calculations in periodic boundary conditions of gas-phase acidities and of transition-metal anionic clusters: case study with carboxylate-stabilized ruthenium clusters Roberto Gonzalez-Gomez,Iker Del rosal,Karine Philippot,Romuald Poteau Theoretical Chemistry Accounts: Theory, Computation, and Modeling, 2019, 138 (8), pp.95. ⟨10.1007/s00214-019-2484-4⟩ Article dans une revue hal-02388707v1
Reductive CO 2 Homocoupling: Synthesis of a Borylated C 3 Carbohydrate Aurélien Béthegnies,Yannick Escudié,Nelson Nuñez‐dallos,Laure Vendier,John Hurtadoet al. ChemCatChem, 2019, 11, pp.760-765. ⟨10.1002/cctc.201801875⟩ Article dans une revue hal-02330570v1
Carboxylic acid-capped ruthenium nanoparticles: experimental and theoretical case study with ethanoic acid Roberto Gonzalez-Gomez,Lucy Cusinato,Christian Bijani,Yannick Coppel,Pierre Lecanteet al. Nanoscale, 2019, 11 (19), pp.9392-9409. ⟨10.1039/c9nr00391f⟩ Article dans une revue hal-02131929v1
Alternative (kappa(1)-N:eta(6)-arene vs. kappa(2)-N,N) coordination of a sterically demanding amidinate ligand: are size and electronic structure of the Ln ion decisive factors? Aleksei O. Tolpygin,Andrei S. Shavyrin,Anton V. Cherkasov,Georgy K. Fukin,Iker del Rosalet al. Dalton Transactions, 2019, 48 (23), pp.8317-8326. ⟨10.1039/c9dt01162e⟩ Article dans une revue hal-04022178v1
Formation of an alpha-Diimine from Isocyanide Coupling Using Thorium(IV) and Uranium(IV) Phosphido-Methyl Complexes Pokpong Rungthanaphatsophon,Iker del Rosal,Robert J. Ward,Sean P. Vilanova,Steven P. Kelleyet al. Organometallics, 2019, 38 (8), pp.1733-1740. ⟨10.1021/acs.organomet.9b00043⟩ Article dans une revue hal-04022184v1
Supported lanthanide catalysts: Role of the grafting on the stereochemical outcome of beta-butyrolactone ROP reaction Adrien Bathellier,Chiara Dinoi,Iker del Rosal,Laurent Maron Abstracts of Papers of the American Chemical Society, 2019, 258 Article dans une revue hal-03925218v1
Polymerization of rac ‐Lactide Using Achiral Iron Complexes: Access to Thermally Stable Stereocomplexes Paul Marin,Mathieu J.‐l. Tschan,Florence Isnard,Carine Robert,Pierre Haquetteet al. Angewandte Chemie International Edition, 2019, 58 (36), pp.12585-12589. ⟨10.1002/anie.201903224⟩ Article dans une revue hal-03365174v1
Efficient CO2 transformation under ambient condition by heterobimetallic rare earth complexes: Experimental and computational evidences of a synergistic effect Liye Qu,Iker del Rosal,Qingyan Li,Yaorong Wang,Dan Yuanet al. Journal of CO2 Utilization, 2019, 33, pp.413-418. ⟨10.1016/j.jcou.2019.07.008⟩ Article dans une revue hal-04022172v1
Corrigendum: Surprising Differences of Alkane C‐H Activation Catalyzed by Ruthenium Nanoparticles: Complex Surface‐Substrate Recognition? Niels Rothermel,Donia Bouzouita,Tobias Röther,Iker Del rosal,Simon Tricardet al. ChemCatChem, 2019, 11 (2), pp.893-893. ⟨10.1002/cctc.201802065⟩ Article dans une revue hal-04962114v1
Single-site cobalt and zinc catalysts for the ring-opening polymerization of lactide Paul Marin,M.J.-L. Tschan,P. Haquette,Thierry Roisnel,Iker Del rosalet al. European Polymer Journal, 2019, 120, pp.109208. ⟨10.1016/j.eurpolymj.2019.08.035⟩ Article dans une revue hal-02310251v1
Grafting of a new bis-silylamido aluminum species on silica: insight from solid-state NMR into interactions with the surface Tom Vancompernolle,Nicolas Merle,Frédéric Capet,Iker Del rosal,Laurent Maronet al. Dalton Transactions, 2019, 48 (16), pp.5243 - 5252. ⟨10.1039/c9dt00845d⟩ Article dans une revue hal-03096927v1
Monomeric thorium dihydrido complexes: versatile precursors to actinide metallacycles Guorui Qin,Yang Wang,Xianghui Shi,Iker del Rosal,Laurent Maronet al. Chemical Communications, 2019, 55 (59), pp.8560-8563. ⟨10.1039/c9cc04013g⟩ Article dans une revue hal-04022175v1
Scandium alkyl and hydride complexes supported by a pentadentate diborate ligand: reactions with CO2 and N2O Daniel W. Beh,Warren E. Piers,Iker del Rosal,Laurent Maron,Benjamin S. Gelfandet al. Dalton Transactions, 2018, 47 (38), pp.13680-13688. ⟨10.1039/c8dt03313g⟩ Article dans une revue hal-04037764v1
Mechanistic Studies on the Catalytic Synthesis of BN Heterocycles (1H-2,1-Benzazaboroles) at Ruthenium Marion Beguerie,Chiara Dinoi,Iker Del rosal,Charly Faradji,Gilles Alcarazet al. ACS Catalysis, 2018, 8 (2), pp.939-948. ⟨10.1021/acscatal.7b03461⟩ Article dans une revue hal-01737380v1
Surprising Differences of Alkane C‐H Activation Catalyzed by Ruthenium Nanoparticles: Complex Surface‐Substrate Recognition? Niels Rothermel,Donia Bouzouita,Tobias Röther,Torsten Gutmann,Iker Del rosalet al. ChemCatChem, 2018, 10 (19), pp.4243-4247. ⟨10.1002/cctc.201801022⟩ Article dans une revue hal-02296026v1
Functionalization of Carbon Monoxide and tert-Butyl Nitrile by Intramolecular Proton Transfer in a Bis(Phosphido) Thorium Complex Sean P. Vilanova,Iker del Rosal,Michael L. Tarlton,Laurent Maron,Justin R. Walensky Angewandte Chemie International Edition, 2018, 57 (51), pp.16748-16753. ⟨10.1002/anie.201810511⟩ Article dans une revue hal-04037748v1
Side Arm Twist on Zn-Catalyzed Hydrosilylative Reduction of CO2 to Formate and Methanol Equivalents with High Selectivity and Activity Guoqin Feng,Chongyang Du,Li Xiang,Iker del Rosal,Guangyu Liet al. ACS Catalysis, 2018, 8 (5), pp.4710-4718. ⟨10.1021/acscatal.8b01033⟩ Article dans une revue hal-04037769v1
Unprecedented Reaction Mode of Phosphorus in Phosphinidene Rare-Earth Complexes: A Joint Experimental-Theoretical Study Haiwen Tian,Jianquan Hong,Kai Wang,Iker del Rosal,Laurent Maronet al. Journal of the American Chemical Society, 2018, 140 (1), pp.102-105. ⟨10.1021/jacs.7b11032⟩ Article dans une revue hal-04037754v1
Reversing Conventional Reactivity of Mixed Oxo/Alkyl Rare-Earth Complexes: Non-Redox Oxygen Atom Transfer Jianquan Hong,Haiwen Tian,Lixin Zhang,Xigeng Zhou,Iker del Rosalet al. Angewandte Chemie International Edition, 2018, 57 (4), pp.1062-1067. ⟨10.1002/anie.201711305⟩ Article dans une revue hal-04037752v1
Silica-Grafted Lanthanum Benzyl Species: Synthesis, Characterization, and Catalytic Applications Tom Vancompernolle,Andreia Valente,Thomas Chenal,Philippe Zinck,Iker Del rosalet al. Organometallics, 2017, 36 (20), pp.3912 - 3920. ⟨10.1021/acs.organomet.7b00538⟩ Article dans une revue hal-01872744v1
Shape, electronic structure and steric effects of organometallic nanocatalysts: relevant tools to improve the synergy between theory and experiment Lucy Cusinato,Iker Del rosal,Romuald Poteau Dalton Transactions, 2017, 46 (2), pp.378-395. ⟨10.1039/C6DT04207D⟩ Article dans une revue hal-01961183v1
Mechanistic Aspects of the Polymerization of Lactide Using a Highly Efficient Aluminum(III) Catalytic System Carine Robert,Thibault E. Schmid,Vincent Richard,Pierre Haquette,Sumesh K. Ramanet al. Journal of the American Chemical Society, 2017, 139 (17), pp.6217--6225. ⟨10.1021/jacs.7b01749.s001⟩ Article dans une revue hal-01961168v1
Zwitterionic amidinates as effective ligands for platinum nanoparticle hydrogenation catalysts Luis Miguel Martinez-Pietro,Israel Cano,A. Marquez,Edwin A Baquero,Simon Tricardet al. Chemical Science, 2017, 8 (4), pp.2931-2941. ⟨10.1039/C6SC05551F⟩ Article dans une revue hal-01940898v1
Gold(I)-Catalysed Asymmetric Hydroamination of Alkenes: A Silver- and Solvent-Dependent Enantiodivergent Reaction Marc-Antoine Abadie,Xavier Trivelli,Florian Medina,Nathalie Duhal,Mostafa Kouachet al. Chemistry - A European Journal, 2017, 23 (45), pp.10777 - 10788. ⟨10.1002/chem.201701301⟩ Article dans une revue hal-01663092v1
Silica-Supported Tungsten Neosilyl Oxo Precatalysts: Impact of the Podality on Activity and Stability in Olefin Metathesis D. Grekov,Y. Bouhoute,K. Szeto,Nicolas Merle,A. de Mallmannet al. Organometallics, 2016, 35 (13), pp.2188-2196. ⟨10.1021/acs.organomet.6b00220⟩ Article dans une revue hal-01968826v1
Effects of the Grafting of Lanthanum Complexes on a Silica Surface on the Reactivity: Influence on Ethylene, Propylene, and 1,3-Butadiene Homopolymerization Iker Del rosal,Ahmed Yahia,Laurent Maron Inorganic Chemistry, 2016, 55 (20), pp.10024-10033 Article dans une revue hal-01968797v1
The Nature of Secondary Interactions at Electrophilic Metal Sites of Molecular and Silica-Supported Organolutetium Complexes from Solid-State NMR Spectroscopy. Matthew P Conley,Giuseppe Lapadula,Kevin Sanders,David Gajan,Anne Lesageet al. Journal of the American Chemical Society, 2016, 138 (11), pp.3831-3843. ⟨10.1021/jacs.6b00071⟩ Article dans une revue hal-01546479v1
New perspectives in organolanthanide chemistry from redox to bond metathesis: insights from theory Christos E. Kefalidis,Ludovic Castro,Iker Del rosal,Laurent Maron,Lionel Perrin Chemical Society Reviews, 2016, 45 (9), pp.2516-2543 Article dans une revue hal-01968866v1
Theoretical characterization of the surface composition of ruthenium nanoparticles in equilibrium with syngas Lucy Cusinato,Luis Miguel Martinez-Pietro,Bruno Chaudret,Iker Del rosal,Romuald Poteau Nanoscale, 2016, 8 (21), pp.10974-10992 Article dans une revue hal-01960027v1
17 O MAS NMR studies of oxo-based olefin metathesis catalysts: a critical assessment of signal enhancement methods D. Grekov,Y. Bouhoute,Iker Del rosal,Laurent Maron,M. Taoufiket al. Physical Chemistry Chemical Physics, 2016, 18 (40), pp.28157-28163. ⟨10.1039/C6CP04667C⟩ Article dans une revue hal-01968823v1
Modification of silica-supported tungsten neosilyl oxo precatalysts: impact of substituted phenol on activity and stability in olefin metathesis Yassine Bouhoute,Iker Del rosal,K. Szeto,Nicolas Merle,D. Grekovet al. Catalysis Science & Technology, 2016, 6 (24), pp.8532-8539 Article dans une revue hal-01968728v1
Grafting of lanthanide complexes on silica surfaces dehydroxylated at 200 °C: a theoretical investigation Iker Del rosal,I.C. Gerber,Romuald Poteau,Laurent Maron New Journal of Chemistry, 2015, 39 (10), pp.7703-7715 Article dans une revue hal-01969145v1
DFT investigations on the ring-opening polymerization of substituted cyclic carbonates catalyzed by zinc-{β-diketiminate} complexes Iker Del rosal,Pierre Brignou,Sophie M. Guillaume,Jean-François Carpentier,Laurent Maron Polymer Chemistry, 2015, 6 (17), pp.3336--3352. ⟨10.1039/C5PY00313J⟩ Article dans une revue hal-01154160v1
Enantiospecific C-H activation using ruthenium nanocatalysts Céline Taglang,Luis Miguel Martinez-Pietro,Iker Del rosal,Laurent Maron,Romuald Poteauet al. Angewandte Chemie International Edition, 2015, 54 (36), pp.10474-10477. ⟨10.1002/anie.201504554⟩ Article dans une revue istex hal-01920824v1
Amido Analogues of Nonbent Lanthanide (II) and Calcium Metallocenes. Heterolytic Cleavage of π-Bond Ln–Carbazolyl Ligand Promoted by Lewis Base Coordination Alexander Selikhov,Anton Cherkasov,Georgy Fukin,Alexander A. Trifonov,Iker Del rosalet al. Organometallics, 2015, 34 (3), pp.555-562 Article dans une revue hal-01968821v1
Accessing Realistic Models for the WO 3 –SiO 2 Industrial Catalyst through the Design of Organometallic Precursors Y. Bouhoute,D. Grekov,K. Szeto,Nicolas Merle,A. de Mallmannet al. ACS Catalysis, 2015, ACS Catalysis, 6 (1), pp.1-18. ⟨10.1021/acscatal.5b01744⟩ Article dans une revue hal-01968734v1
Metallacyclic yttrium alkyl and hydrido complexes: synthesis, structures and catalytic activity in intermolecular olefin hydrophosphination and hydroamination Alexander A. Kissel,Tatyana V. Mahrova,Dmitry M. Lyubov,Anton V. Cherkasov,Georgy K. Fukinet al. Dalton Transactions, 2015, 44 (27), pp.12137-12148 Article dans une revue hal-01969009v1
Yttrium Dihydride Cation [YH 2 (THF) 2 ] + n : Aggregate Formation and Reaction with (NNNN)-Type Macrocycles Stefan Arndt,Mathias Kramer,Waldemar Fegler,Yumiko Nakajima,Iker Del rosalet al. Organometallics, 2015, 34 (15), pp.3739-3747 Article dans une revue hal-01969418v1
Heteronuclear NMR Spectroscopy as a Surface-Selective Technique: A Unique Look at the Hydroxyl Groups of γ-Alumina. Mostafa Taoufik,Kai Szeto,Nicolas Merle,Iker Del rosal,Laurent Maronet al. Chemistry - A European Journal, 2014, 20 (14), pp.4038-4046 Article dans une revue hal-01969452v1
To Bend or Not To Bend: Experimental and Computational Studies of Structural Preference in Ln(Tp iPr 2 ) 2 (Ln = Sm, Tm) Aurélien Momin,Lee Carter,Yi Yang,Robert Mcdonald,Stéphanie Essafi (née Labouille)et al. Inorganic Chemistry, 2014, 53 (22), pp.12066-12075 Article dans une revue hal-01969571v1
Well-Defined Supported Mononuclear Tungsten Oxo Species as Olefin Metathesis Pre-Catalysts Yassine Bouhoute,Anthony Garron,Denys Grekov,Nicolas Merle,Kai Szetoet al. ACS Catalysis, 2014, 4 (11), pp.4232-4241 Article dans une revue hal-01969421v1
PMLABe Diol Synthesized by Ring-Opening Polymerization of Racemic Benzyl β-Malolactonate Initiated by Rare-Earth Trisborohydride Complexes: An Experimental and DFT Study Cédric C. Jaffredo,Matthias Schmid,Iker Del rosal,Teddy Mevel,Peter Roeskyet al. Chemistry - A European Journal, 2014, 20 (44), pp.14387-14402 Article dans une revue hal-01969536v1
Speciation of [Cp*2M2O5] in Polar and Donor Solvents Pelin Sözen-Aktaş,Iker Del rosal,Eric Manoury,Funda Demirhan,Agustí Lledóset al. Chemistry - A European Journal, 2013, 19 (12), pp.3969-3985. ⟨10.1002/chem.201203075⟩ Article dans une revue istex hal-02908715v1
Ring-opening polymerization of racemic β-butyrolactone promoted by rare earth trisborohydride complexes towards a PHB-diol: an experimental and DFT study Sophie M. Guillaume,Liana Annunziata,Iker Del rosal,Christophe Iftner,Laurent Maronet al. Polymer Chemistry, 2013, 4 (10), pp.3077-3087. ⟨10.1039/C3PY00056G⟩ Article dans une revue hal-00844464v1
Small Changes Have Consequences: Lessons from Tetrabenzyltitanium and -zirconium Surface Organometallic Chemistry Nicolas Popoff,Jeff Espinas,Jérémie Pelletier,Benoît Macqueron,Kai Szetoet al. Chemistry - A European Journal, 2013, 19 (3), pp.964-973. ⟨10.1002/chem.201202737⟩ Article dans une revue istex hal-02043430v1
Ligand-Field Theory-Based Analysis of the Adsorption Properties of Ruthenium Nanoparticles Iker Del rosal,Maxime Mercy,I.C. Gerber,Romuald Poteau ACS Nano, 2013, ⟨10.1021/nn403364p⟩ Article dans une revue hal-02366322v1
17 O NMR Gives Unprecedented Insights into the Structure of Supported Catalysts and Their Interaction with the Silica Carrier Nicolas Merle,Julien Trébosc,Anne Baudouin,Iker Del rosal,Laurent Maronet al. Journal of the American Chemical Society, 2012, 134 (22), pp.9263 - 9275. ⟨10.1021/ja301085m⟩ Article dans une revue hal-01702437v1
DFT investigations on the ring-opening polymerization of cyclic carbonates catalyzed by zinc-{β-diiminate} complexes Iker Del rosal,Pierre Brignou,Sophie M. Guillaume,Jean-François Carpentier,Laurent Maron Polymer Chemistry, 2011, 2 (11), pp.2564-2573. ⟨10.1039/C1PY00309G⟩ Article dans une revue hal-00652161v1
Multicentered effective group potentials: ligand-field effects in organometallic clusters and dynamical study of chemical reactivity Christophe Raynaud,Iker Del rosal,Franck Jolibois,Laurent Maron,Romuald Poteau Theoretical Chemistry Accounts: Theory, Computation, and Modeling, 2010, 126 (3-4), pp.151-163. ⟨10.1007/s00214-009-0615-z⟩ Article dans une revue istex hal-00493604v1
Hydrido-Ruthenium Cluster Complexes as Models for Reactive Surface Hydrogen Species of Ruthenium Nanoparticles. Solid-State 2 H NMR and Quantum Chemical Calculations Torsten Gutmann,Bernadeta Walaszek,Xu Yeping,Maria Wächtler,Iker Del rosalet al. Journal of the American Chemical Society, 2010, 132 (33), pp.11759-11767. ⟨10.1021/ja104229a⟩ Article dans une revue hal-02350833v1

Poster de conférence (1)

Versatile coordination of iron dichloride with N-(fluoro)-aryl-substituted iminopyridine ligands: Synthesis, structures, magnetic properties and polymerization of isoprene Yohan Champouret,Marc Visseaux,Raphael Caulier,Obaid Hashmi,Claire Minaudet al. Coordination Chemistry Days 2025, Jan 2025, Saclay, France Poster de conférence hal-05166862v1

Communication dans un congrès (13)

A one-pot organometallic approach to access hybrid nanomaterials based on organophosphorous transition metal complexes covalenttly bonded to metal nanoparticles Elena Martín Morales,Yannick Coppel,Iker Del rosal,Romuald Poteau,Pierre Sutraet al. Polymat 2019, 10th International Conference on Polymers and Advanced Materials, Oct 2019, Huatulco, Mexico. pp.67-70 Communication dans un congrès hal-03056924v1
A one-pot organometallic approach to access hybrid nanomaterials based on organophosphorus transition metal complexes covalently bonded to metal nanoparticles Elena Martín Morales,Yannick Coppel,Iker Del rosal,Romuald Poteau,Pierre Sutraet al. Polymat 2019 : 10th International Conference on Polymers and Advanced Materials, Oct 2019, Huatulco, Mexico. pp.67-70 Communication dans un congrès hal-03234973v1
Phosphine Based Gold Catalysts for the Asymmetric Hydroamination of Alkenes: Effects of Silver, Anion and Solven Christophe Michon,Marc O. Abadie,Fernando Torres Medina,Xavier Trivelli,Frédéric Capetet al. 28th International Conference on Organometallic Chemistry, ICOMC 2018, Jul 2018, Florence (IT), France Communication dans un congrès hal-04411195v1
Advanced Solid-State NMR as a Key Tool for the Deeper Understanding of Heterogeneous Catalysts D. Grekov,Nicolas Merle,Kai Chung Szeto,Yassine Bouhoute,Iker Del rosalet al. ZING conference, May 2016, Varna, Bulgaria Communication dans un congrès hal-02309346v1
17O MAS NMR as a tool for understanding the molecular structure of supported catalysts D. Grekov,L. Delevoye,Régis M. Gauvin,Yassine Bouhoute,Mostafa Taoufiket al. SMARTER 5, Sep 2016, Bayreuth, Germany Communication dans un congrès hal-02309317v1
Accessing the structure of well-defined grafted catalysts with experimental and first principles 17O Solid State NMR methodology D. Grekov,Yassine Bouhoute,Iker Del rosal,Mostafa Taoufik,Régis M. Gauvinet al. Journées Nord-Ouest Européennes des Jeunes Chercheurs (JNOEJC), Jun 2016, Lille, France Communication dans un congrès hal-02309335v1
Advanced solid-state NMR as a key tool for the deeper understanding of heterogeneous catalysts Régis M. Gauvin,L. Delevoye,Mostafa Taoufik,Iker Del rosal,Laurent Maron Indo-French Symposium 2016 “Catalysis for Sustainable and Environmental Chemistry” – NCL, Jun 2016, Lille, France Communication dans un congrès hal-02309342v1
Advanced Solid-State NMR as a Key Tool for the Deeper Understanding of Heterogeneous Catalysts D. Grekov,Nicolas Merle,Kai Chung Szeto,Yassine Bouhoute,Iker Del rosalet al. 1st French-Portuguese NMR GERM Conference, Apr 2016, Lisbon, Portugal Communication dans un congrès hal-02309343v1
Well-defined group VI oxo derivatives supported on silica by SOMC: Model of industrial olefin metathesis catalyst Nicolas Merle,Yassine Bouhoute,Kai Chung Szeto,Aimery de Mallmann,Iker Del rosalet al. 251th ACS Meeting, Mar 2016, San Diego, United States Communication dans un congrès hal-02333529v1
17O MAS NMR Studies of oxo-based Olefin Metathesis Catalysts: a Critical Assessment of Signal Enhancement Methods D. Grekov,L. Delevoye,Régis M. Gauvin,Yassine Bouhoute,Mostafa Taoufiket al. Conférence du Réseau RMN Grand Bassin Parisien, Sep 2016, Rennes, France Communication dans un congrès hal-02309320v1
17O MAS NMR as a tool for understanding the molecular structure of supported catalysts Denys Grekov,Laurent Delevoye,Régis Gauvin,Yassine Bouhoute,Mostafa Taoufiket al. Congrès du Groupement d’Études de Résonance Magnétique (GERM 2015), May 2015, Sète, France Communication dans un congrès hal-02309314v1
17O MAS NMR as a tool for understanding the molecular structure of supported catalysts Denys Grekov,Laurent Delevoye,Régis Gauvin,Yassine Bouhoute,Mostafa Taoufiket al. Congrès de la Société Chimique de France (SCF 2015), Jul 2015, Lille, France Communication dans un congrès hal-02309310v1
On the Track to Silica-Supported Tungsten Oxo Metathesis Catalysts: Input from 17O Solid-State NMR Nicolas Merle,Guillaume Girard,Nicolas Popoff,Julien Trébosc,Iker Del rosalet al. 9th Alpine Conference, Sep 2015, Chamonix, France Communication dans un congrès hal-02310779v1