Laurent Maron

497
Documents

Publications

Publications

Deposit thumbnail

Synergistic C–H bond activation across molybdenum–iridium multiply bonded complexes: a cascade of transformations

Zachary Dubrawski , Iker del Rosal , Erwann Jeanneau , Laurent Maron , Chloé Thieuleux et al.

Chemical Science, 2025, ⟨10.1039/D5SC03465E⟩

Article dans une revue hal-05173362v1
Deposit thumbnail

Solvatochromism and Redox Multi‐Switch in a Trinuclear Cobalt(II) Complex

Solène Delaporte , Nathalie Bridonneau , François Lambert , Régis Guillot , Nicolas Suaud et al.

Chemistry - A European Journal, 2025, 31 (45), pp.e202501455. ⟨10.1002/chem.202501455⟩

Article dans une revue hal-05224360v1
Deposit thumbnail

Lanthanide‐mediated Defluorinative Transformations of Trifluoromethylated Benzofulvenes: Access to Functionalized Difluoroalkenes and Mechanistic Insights

Tarun Kumar , Yan Yang , Amira Ben Hassine , Deepak Mali , Yogita Prajapat et al.

Chemistry - An Asian Journal, 2025, ⟨10.1002/asia.202500071⟩

Article dans une revue hal-05027934v1
Deposit thumbnail

On the Mechanism of Acrylate and Propionate Silyl Esters Synthesis by Ruthenium-Catalyzed Coupling of CO<sub>2</sub> with C<sub>2</sub>H<sub>4</sub> in the Presence of Hydrosilanes: Combined Experimental and Computational Investigations

Kana Kunihiro , Thayalan Rajeshkumar , Laurent Maron , Svetlana Heyte , Sébastien Paul et al.

Molecular Catalysis, 2025, 570, pp.114660. ⟨10.1016/j.mcat.2024.114660⟩

Article dans une revue hal-04836282v1

Room temperature dinitrogen cleavage and hydrogenation with organometallic complexes of uranium

Angus C. G. Shephard , Lucie Pedussaut , Linda de Marchi , Luca Demonti , Thayalan Rajeshkumar et al.

Chemical Science, 2025, ⟨10.1039/D5SC07194A⟩

Article dans une revue hal-05361812v1
Deposit thumbnail

Probing Structural Diversity in a Series of Perhydrocarbyl Heterobimetallic Complexes Associating Tantalum and 3d (Cr, Mn, Fe, Co, Ni) Transition Metals

Till Neumann , Iker del Rosal , Laurent Maron , Erwann Jeanneau , Vincent Maurel et al.

Inorganic Chemistry, 2025, 64 (43), pp.21353-21367. ⟨10.1021/acs.inorgchem.5c02380⟩

Article dans une revue hal-05505845v1
Deposit thumbnail

Visible light activation of C–Cl and C–F bonds in persistent organic pollutants using cerium(III) triamidoamine complex

Adrien Combourieu , Stella Christodoulou , Laurent Maron , Eachann Assendjee , Nicolas Casaretto et al.

Chemical Science, 2025, 16 (34), pp.15510-15517. ⟨10.1039/D5SC03626G⟩

Article dans une revue hal-05344584v1
Deposit thumbnail

Room-Temperature H<sub>2</sub> Splitting and N<sub>2</sub>-Hydrogenation Induced by a Neutral Lu(II) Complex

Evangelos Papangelis , Luca Demonti , Iker del Rosal , Angus Shephard , Laurent Maron et al.

Journal of the American Chemical Society, 2025, 147 (11), pp.9752-9763. ⟨10.1021/jacs.4c18416⟩

Article dans une revue hal-05213394v1

Styrene Polymerization with Group III Metallocenes: A Generative and Interpretable Catalyst Design Strategy Combining Density Functional Theory and Machine Learning

Stella Christodoulou , Etienne dos Santos , Romuald Poteau , Laurent Maron

ChemistryEurope, 2025, 12 (52), pp.18537-18554. ⟨10.1002/ceur.202500250⟩

Article dans une revue hal-05297886v1

Rare-Earth Metal Complexes Bearing Electrophilic Carbon and Strongly Polarized Metallacyclopropane Moiety: Synthesis and Diverse Reactivity toward Small Molecules

Weikang Wu , Thayalan Rajeshkumar , Dongjing Hong , Shan Zhu , Zeming Huang et al.

Inorganic Chemistry, 2024, ⟨10.1021/acs.inorgchem.4c02316⟩

Article dans une revue hal-04707672v1

Planar Tetranuclear Uranium Hydride Cluster Supported by <i>ansa</i>-Bis(cyclopentadienyl) Ligands

Kai Li , Iker Del Rosal , Yue Zhao , Laurent Maron , Congqing Zhu

Angewandte Chemie International Edition, 2024, 63 (29), ⟨10.1002/anie.202405494⟩

Article dans une revue hal-04707659v1

Straightforward construction of a rare-earth diphosphanato complex from white phosphorus: synthesis and reactivity

Fangjun Zhang , Iker Del rosal , Keyu Han , Jie Zhang , Laurent Maron et al.

Inorganic Chemistry Frontiers, 2024, 11 (6), pp.1742-1753. ⟨10.1039/d3qi02680a⟩

Article dans une revue hal-04707645v1

Hypervalent zinc( <span style="font-variant:small-caps;">i</span> ) complexes with an <i>NNNN</i> -macrocycle: C–H bond activation across the zinc( <span style="font-variant:small-caps;">i</span> )–zinc( <span style="font-variant:small-caps;">i</span> ) bond

Pritam Mahawar , Thayalan Rajeshkumar , Thomas P. Spaniol , Laurent Maron , Jun Okuda

Chemical Communications, 2024, 60, pp.11359-11362. ⟨10.1039/D4CC04266B⟩

Article dans une revue hal-04844111v1

Oxidation-induced ambiphilicity triggers N-N bond formation and dinitrogen release in octahedral terminal molybdenum(<sc>v</sc>) nitrido complexes

C. Christopher Almquist , Thayalan Rajeshkumar , H. D. A. Chathumal Jayaweera , Nicole Removski , Wen Zhou et al.

Chemical Science, 2024, 15 (14), pp.5152-5162. ⟨10.1039/d4sc00090k⟩

Article dans une revue hal-04707633v1
Deposit thumbnail

Synthesis, Structure, and Bonding of Actinide–Rhenium Polyhydrides

Christopher Ye , Iker del Rosal , Sheridon Kelly , Erik Ouellette , Laurent Maron et al.

Inorganic Chemistry, In press, ⟨10.1021/acs.inorgchem.4c03449⟩

Article dans une revue hal-04749940v1

Synthesis, structure and redox properties of single-atom bridged diuranium complexes supported by aryloxides

Fang-Che Hsueh , Luciano Barluzzi , Thayalan Rajeshkumar , Rosario Scopelliti , Ivica Zivkovic et al.

Dalton Transactions, 2024, 53 (32), pp.13416-13426. ⟨10.1039/d4dt01819b⟩

Article dans une revue hal-04707673v1

Oxidative Addition of E-H (E=C, N) Bonds to Transient Uranium(II) Centers

Wei Fang , Yafei Li , Tianze Zhang , Thayalan Rajeshkumar , Iker Del rosal et al.

Angewandte Chemie International Edition, 2024, 63 (32), ⟨10.1002/anie.202407339⟩

Article dans une revue hal-04707677v1

Homoleptic Organolanthanum-Catalyzed Carbohalogenation

Huiyue Yang , Thayalan Rajeshkumar , Shanshan Liu , Hengjiang Cong , Guipeng Yu et al.

Journal of the American Chemical Society, 2024, 146 (36), pp.25361-25370. ⟨10.1021/jacs.4c10445⟩

Article dans une revue hal-04707657v1

Directed Aromatic Deuteration and Tritiation of Pharmaceuticals by Heavy Alkali Metal Amide Catalysts

Hui-Zhen Du , Jingwei Li , Stella Christodoulou , Si-Yuan Li , Yun-Shu Cui et al.

ACS Catalysis, 2024, 14 (13), pp.9640-9647. ⟨10.1021/acscatal.4c01807⟩

Article dans une revue hal-04707648v1

Multi-electron redox reactivity of a samarium(II) hydrido complex

Xianghui Shi , Peng Deng , Thayalan Rajeshkumar , Laurent Maron , Jianhua Cheng

Chemical Science, 2024, 15 (30), pp.11965-11971. ⟨10.1039/d4sc03104k⟩

Article dans une revue hal-04707637v1

Electronic Delocalization and σ-Aromaticity in Heterometallic Cluster with Multiple Thorium-Palladium Bonds

Weiming Sheng , Thayalan Rajeshkumar , Yue Zhao , Laurent Maron , Congqing Zhu

Journal of the American Chemical Society, 2024, 146 (18), pp.12790-12798. ⟨10.1021/jacs.4c03058⟩

Article dans une revue hal-04707668v1
Deposit thumbnail

Photolysis-driven bond activation by thorium and uranium tetraosmate polyhydride complexes

Christopher Ye , Iker del Rosal , Sheridon Kelly , I. Joseph Brackbill , Laurent Maron et al.

Chemical Science, In press, ⟨10.1039/D4SC02380C⟩

Article dans une revue hal-04611467v1

Synthesis and Reactivity of Discrete Europium(II) Hydride Complexes

Georgia M. Richardson , Matthew J. Evans , Thayalan Rajeshkumar , Jordan A. J. Mccone , Scott A. Cameron et al.

Chemistry - A European Journal, 2024, 30 (27), ⟨10.1002/chem.202400681⟩

Article dans une revue hal-04707660v1

Stabilization and One Electron Reduction of a Silicon Analogue of a Carboxylic Acid Anhydride

Yixiao Jiang , K. Yuvaraj , Thayalan Rajeshkumar , Li Feng Lim , Nicholas Cox et al.

Chemistry - A European Journal, 2024, 30 (15), ⟨10.1002/chem.202303949⟩

Article dans une revue hal-04707638v1

Two-Electron Redox Reactivity of Thorium Supported by Redox-Active Tripodal Frameworks

Fang-Che Hsueh , Damien Chen , Thayalan Rajeshkumar , Rosario Scopelliti , Laurent Maron et al.

Angewandte Chemie International Edition, 2024, 63 (6), ⟨10.1002/anie.202317346⟩

Article dans une revue hal-04707680v1

Spectroscopic and Computational Evidence of Uranium Dihydrogen Complexes

I. Joseph Brackbill , Thayalan Rajeshkumar , Laurent Maron , Robert G. Bergman , John Arnold

Journal of the American Chemical Society, 2024, 146 (2), pp.1257-1261. ⟨10.1021/jacs.3c12636⟩

Article dans une revue hal-04707664v1
Deposit thumbnail

Efficient Machine-Learning-Based New Tools to Design Eutectic Mixtures and Predict Their Viscosity

Stella Christodoulou , Camille Cousseau , Emmanuelle Limanton , Lorris Toucouere , Fabienne Gauffre et al.

ACS Sustainable Chemistry & Engineering, 2024, 12 (52), pp.18537-18554. ⟨10.1021/acssuschemeng.4c05869⟩

Article dans une revue hal-04867220v1

Rare-earth metal complexes bearing electrophilic and nucleophilic carbon centres and their unique reactivity patterns towards pyridine derivatives

Weikang Wu , Thayalan Rajeshkumar , Shan Zhu , Fuxiang Chai , Dongjing Hong et al.

Chemical Science, 2024, pp.10.1039.D4SC04197F. ⟨10.1039/D4SC04197F⟩

Article dans une revue hal-04844097v1

Hydrogenolysis of Cationic Half-Sandwich Zinc Complexes Containing a Chelating Amine: Facile Cleavage of Zinc-Carbon Bond by Dihydrogen to Give Zinc Hydride Cations

Pritam Mahawar , Thayalan Rajeshkumar , Thomas P. Spaniol , Laurent Maron , Jun Okuda

Chemistry - A European Journal, 2024, 30 (42), ⟨10.1002/chem.202401262⟩

Article dans une revue hal-04707654v1

Panoply of P: An Array of Rhenium-Phosphorus Complexes Generated from a Transition Metal Anion

David P. Hales , Thayalan Rajeshkumar , Angela A. Shiau , Guodong Rao , Erik T. Ouellette et al.

Inorganic Chemistry, 2024, 63 (24), pp.11296-11310. ⟨10.1021/acs.inorgchem.4c01085⟩

Article dans une revue hal-04707639v1

Iron promoted end-on dinitrogen-bridging in heterobimetallic complexes of uranium and lanthanides

Nadir Jori , Juan J. Moreno , R. A. Keerthi Shivaraam , Thayalan Rajeshkumar , Rosario Scopelliti et al.

Chemical Science, 2024, 15 (18), pp.6842-6852. ⟨10.1039/d4sc01050g⟩

Article dans une revue hal-04707675v1
Deposit thumbnail

The photo-isomerization of the cyclononatetraenyl ligand and related rare earth complexes

Lucie Pedussaut , Nolwenn Mahieu , Camille Chartier , Thayalan Rajeshkumar , Maxime Tricoire et al.

Chemical Science, 2024, 15 (46), pp.19273-19282. ⟨10.1039/d4sc04767b⟩

Article dans une revue hal-04831267v1

Triple Inverse Sandwich versus End-On Diazenido: Bonding Motifs across a Series of Rhenium-Lanthanide and -Actinide Complexes

Erik T. Ouellette , I. Joseph Brackbill , Amy E. Kynman , Stella Christodoulou , Laurent Maron et al.

Inorganic Chemistry, 2024, 63 (16), pp.7177-7188. ⟨10.1021/acs.inorgchem.3c04248⟩

Article dans une revue hal-04707647v1

Siloxide tripodal ligands as a scaffold for stabilizing lanthanides in the+4 oxidation state

Maxime Tricoire , Fang-Che Hsueh , Megan Keener , Thayalan Rajeshkumar , Rosario Scopelliti et al.

Chemical Science, 2024, 15 (18), pp.6874-6883. ⟨10.1039/d4sc00051j⟩

Article dans une revue hal-04707674v1

Rare-earth metal ethylene and ethyne complexes

Wen Jiang , Thayalan Rajeshkumar , Mengyue Guo , Yuejian Lin , Laurent Maron et al.

Chemical Science, 2024, 15 (10), pp.3495-3501. ⟨10.1039/d3sc06599e⟩

Article dans une revue hal-04707663v1

Anti-Selective Carbosilylation: Nickel-Catalyzed Multicomponent Reaction of Solid Me<sub>3</sub>SiZnI

Revathi Chandrasekaran , Keerthika Selvam , Thayalan Rajeshkumar , Tamilselvi Chinnusamy , Laurent Maron et al.

Angewandte Chemie International Edition, 2024, 63 (23), ⟨10.1002/anie.202318689⟩

Article dans une revue hal-04707661v1
Deposit thumbnail

π-Bonding of Group 11 Metals to a Tantalum Alkylidyne Alkyl Complex Promotes Unusual Tautomerism to Bis-alkylidene and CO 2 to Ketenyl Transformation

Abdelhak Lachguar , Iker del Rosal , Laurent Maron , Erwann Jeanneau , Laurent Veyre et al.

Journal of the American Chemical Society, 2024, ⟨10.1021/jacs.4c02172⟩

Article dans une revue hal-04630141v1

Reductive Dimerization of Alkenes and Allenes Enabled by Photochemically Activated Zinc-Zinc Bonded Compounds

Shuilian Xu , Qiujie Wang , Thayalan Rajeshkumar , Shengjie Jiang , Laurent Maron et al.

Journal of the American Chemical Society, 2024, 146 (28), pp.19590-19598. ⟨10.1021/jacs.4c07390⟩

Article dans une revue hal-04707646v1

Dihydrogen Cleavage by a Zinc-Zinc Bond of a Heteroleptic Dizinc(I) Cation

Pritam Mahawar , Thayalan Rajeshkumar , Thomas P. Spaniol , Laurent Maron , Jun Okuda

Inorganic Chemistry, 2024, 63 (18), pp.8493-8501. ⟨10.1021/acs.inorgchem.4c01116⟩

Article dans une revue hal-04707635v1

Light-induced splitting of P-C bonds in a lanthanum(<sc>iii</sc>) hemiphosphinal complex

Benjamin Wittwer , Karl N. Mccabe , Daniel Leitner , Michael Seidl , Laurent Maron et al.

Inorganic Chemistry Frontiers, 2024, 11 (14), ⟨10.1039/d4qi00868e⟩

Article dans une revue hal-04707624v1

Temperature induced single-crystal to single-crystal transformation of uranium azide complexes

Kai Li , Thayalan Rajeshkumar , Yue Zhao , Tianwei Wang , Laurent Maron et al.

Chemical Communications, 2024, 60 (21), pp.2966-2969. ⟨10.1039/d4cc00546e⟩

Article dans une revue hal-04707658v1

Dinitrogen Reduction and Functionalization by a Siloxide Supported Thulium-Potassium Complex for the Formation of Ammonia or Hydrazine Derivatives

R. A. Keerthi Shivaraam , Thayalan Rajeshkumar , Rosario Scopelliti , Ivica Z̆ivković , Laurent Maron et al.

Angewandte Chemie International Edition, 2024, pp.e202414051. ⟨10.1002/anie.202414051⟩

Article dans une revue hal-04844099v1
Deposit thumbnail

CO<sub>2</sub> cleavage by tantalum/M (M = iridium, osmium) heterobimetallic complexes

Abdelhak Lachguar , Christopher Z Ye , Sheridon N Kelly , Erwann Jeanneau , Iker del Rosal et al.

Chemical Communications, 2024, 60 (61), pp.7878-7881. ⟨10.1039/D4CC02207F⟩

Article dans une revue hal-04738526v1

Covalency-Driven Differences in the Hydrogenation Chemistry of Lanthanide- and Actinide-Based Frustrated Lewis Pairs

I. Joseph Brackbill , Thayalan Rajeshkumar , Iskander Douair , Laurent Maron , Michael A. Boreen et al.

Journal of the American Chemical Society, 2024, 146 (31), pp.21932-21947. ⟨10.1021/jacs.4c06777⟩

Article dans une revue hal-04707662v1

Steric control of Mg-Mg bond formation <i>vs.</i> N<sub>2</sub> activation in the reduction of bulky magnesium diamide complexes

Rahul Mondal , Matthew J. Evans , Dat T. Nguyen , Thayalan Rajeshkumar , Laurent Maron et al.

Chemical Communications, 2024, 60 (8), pp.1016-1019. ⟨10.1039/d3cc05787a⟩

Article dans une revue hal-04707627v1

Experimental and Computational Studies on Uranium Diazomethanediide Complexes

Tongyu Li , Dongwei Wang , Yi Heng , Guohua Hou , Guofu Zi et al.

Angewandte Chemie International Edition, 2023, 62 (50), ⟨10.1002/anie.202313010⟩

Article dans une revue hal-04707669v1

A binuclear guanidinate yttrium carbyne complex: unique reactivity toward unsaturated C-N, C-O and C-S bonds

Wen Jiang , Feng Kong , Iker Del rosal , Meng Li , Kai Wang et al.

Chemical Science, 2023, ⟨10.1039/d3sc03483f⟩

Article dans une revue hal-04707640v1
Deposit thumbnail

Heterotrimetallic clusters with U-Ni-Ge and U-Ni-Sn units

Kai Li , Genfeng Feng , Stella Christodolou , Yue Zhao , Laurent Maron et al.

Polyhedron, 2023, 243, ⟨10.1016/j.poly.2023.116548⟩

Article dans une revue hal-04707655v1

Synthesis and Reactivity of a Zinc Diazoalkyl Complex: [3+2] Cycloaddition Reaction with Carbon Monoxide

Shengjie Jiang , Yanping Cai , Thayalan Rajeshkumar , Iker Del rosal , Laurent Maron et al.

Angewandte Chemie International Edition, 2023, 62 (34), ⟨10.1002/anie.202307244⟩

Article dans une revue hal-04707653v1

Synthesis and Reactivity of Redox-Active Cerium(IV) Aryloxide Complexes

Hoang-Long Pham , Thayalan Rajeshkumar , Lily Ueh-Hsi Wang , Yat Hei Ng , Kai-Hong Wong et al.

Organometallics, 2023, 42 (11), pp.1094-1105. ⟨10.1021/acs.organomet.2c00569⟩

Article dans une revue hal-04707643v1

Molybdenum carbonyl assisted reductive tetramerization of CO by activated magnesium(i) compounds: squarate dianion vs. metallo-ketene formation

K. Yuvaraj , Jeremy C. Mullins , Thayalan Rajeshkumar , Iskander Douair , Laurent Maron et al.

Chemical Science, 2023, 14 (19), pp.5188-5195. ⟨10.1039/d3sc01487h⟩

Article dans une revue hal-04707630v1

Heterobimetallic Hydrides with a Germanium(II)-Zinc Bond

Thomas P. P. Spaniol , Jun Okuda , Pritam Mahawar , Thayalan Rajeshkumar , Laurent Maron

Chemistry - A European Journal, 2023, 29 (53), ⟨10.1002/chem.202301496⟩

Article dans une revue hal-04707651v1

Lanthanum-Catalyzed Stereospecific Cross-Coupling of Propargylic Substrates with Grignard Reagents

Dandan Sun , Thayalan Rajeshkumar , Yifan Li , Jiaxin Xu , Runkai Chen et al.

Organic Letters, 2023, 25 (36), pp.6730-6735. ⟨10.1021/acs.orglett.3c02600⟩

Article dans une revue hal-04707649v1
Deposit thumbnail

Isolation of C1 through C4 derivatives from CO using heteroleptic uranium( iii ) metallocene aryloxide complexes

Robert Ward , Iker Del Rosal , Steven Kelley , Laurent Maron , Justin Walensky

Chemical Science, 2023, 14 (8), pp.2024-2032. ⟨10.1039/d2sc06375a⟩

Article dans une revue hal-04218352v1

La-Catalyzed Decarbonylation of Formamides and Its Applications

Shaocheng Li , Thayalan Rajeshkumar , Jincheng Liu , Laurent Maron , Xigeng Zhou

Organic Letters, 2023, 25 (1), pp.163-168. ⟨10.1021/acs.orglett.2c03981⟩

Article dans une revue hal-04707644v1

Heterometallic Clusters with Cerium-Transition-Metal Bonding Supported by Nitrogen-Phosphorus Ligands

Xiong Sun , Jinghang Shen , Thayalan Rajeshkumar , Laurent Maron , Congqing Zhu

Inorganic Chemistry, 2023, 62 (39), pp.16077-16083. ⟨10.1021/acs.inorgchem.3c02259⟩

Article dans une revue hal-04707656v1
Deposit thumbnail

Dinitrogen cleavage and hydrogenation to ammonia with a uranium complex

Xiaoqing Xin , Iskander Douair , Yue Zhao , Shuao Wang , Laurent Maron et al.

National Science Review, 2023, 10 (2), ⟨10.1093/nsr/nwac144⟩

Article dans une revue hal-04349711v1

Dinitrogen cleavage by a dinuclear uranium(III) complex

Nadir Jori , Megan Keener , Thayalan Rajeshkumar , Rosario Scopelliti , Laurent Maron et al.

Chemical Science, 2023, 14 (46), pp.13485-13494. ⟨10.1039/d3sc05253b⟩

Article dans une revue hal-04707671v1

Variable Ca-C<sub>aryl</sub> Hapticity and its Consequences in Arylcalcium Dimers

Kyle G. Pearce , Chiara Dinoi , Ryan J. Schwamm , Laurent Maron , Mary F. Mahon et al.

Advanced Science, 2023, 10 (31), ⟨10.1002/advs.202304765⟩

Article dans une revue hal-04707632v1

A Route to Stabilize Uranium(II) and Uranium(I) Synthons in Multimetallic Complexes

R. Keerthi Shivaraam , Megan Keener , Dieuwertje Modder , Thayalan Rajeshkumar , Ivica Živković et al.

Angewandte Chemie International Edition, 2023, 62 (23), pp.e202304051. ⟨10.1002/anie.202304051⟩

Article dans une revue hal-04281546v1

Multielectron Redox Chemistry of Uranium by Accessing the plus II Oxidation State and Enabling Reduction to a U(I) Synthon

Megan Keener , R. A. Keerthi Shivaraam , Thayalan Rajeshkumar , Maxime Tricoire , Rosario Scopelliti et al.

Journal of the American Chemical Society, 2023, 145 (29), pp.16271-16283. ⟨10.1021/jacs.3c05626⟩

Article dans une revue hal-04707676v1

Quest for Active Species in Al/B-Catalyzed CO<sub>2</sub> Hydrosilylation

Sheetal Kathayat Bisht , Deepti Sharma , Ramkumar Kannan , Thayalan Rajeshkumar , Laurent Maron et al.

Inorganic Chemistry, 2023, 62 (45), pp.18543-18552. ⟨10.1021/acs.inorgchem.3c02771⟩

Article dans une revue hal-04707667v1

Photocatalytic dechlorination of unactivated chlorocarbons including PVC using organolanthanide complexes

Amy E. Kynman , Stella Christodoulou , Erik T. Ouellette , Appie Peterson , Sheridon N. Kelly et al.

Chemical Communications, 2023, 59 (73), pp.10924-10927. ⟨10.1039/d3cc02906a⟩

Article dans une revue hal-04707666v1
Deposit thumbnail

C (1)-Symmetric {cyclopentadienyl/indenyl}-metallocene catalysts: synthesis, structure, isospecific polymerization of propylene and stereocontrol mechanism

Dimitra Theodosopoulou , Miguel Alonso de La Peña , Sary Abou Derhamine , Iskander Douair , Thierry Roisnel et al.

Dalton Transactions, 2023, 52 (25), pp.8620-8630. ⟨10.1039/d3dt01306e⟩

Article dans une revue hal-04166074v1
Deposit thumbnail

On the use of 17 O NMR for understanding molecular and silica-grafted tungsten oxo siloxide complexes

Y. Bouhoute , D. Grekov , N. Merle , K. Szeto , C. Larabi et al.

Dalton Transactions, 2023, 52 (28), pp.9573-9581. ⟨10.1039/D3DT01593A⟩

Article dans une revue hal-04238255v1

Monodentate Alkoxy/Aryloxy Anchored Yttrium Dihydrides; Anticipated Outcomes and Surprises

Yi Yang , Iker del Rosal , Michael J. Ferguson , Robert Mcdonald , Laurent Maron et al.

Inorganic Chemistry, 2023, 62 (28), pp.11179-11187. ⟨10.1021/acs.inorgchem.3c01319⟩

Article dans une revue hal-04707631v1

Aryl C-H bond functionalization with diphenyldiazomethane induced by rare-earth metal alkyl complexes

Dianjun Guo , Thayalan Rajeshkumar , Shan Zhu , Qingbing Yuan , Dongjing Hong et al.

Dalton Transactions, 2023, 52 (32), pp.11315-11324. ⟨10.1039/d3dt01714a⟩

Article dans une revue hal-04707670v1
Deposit thumbnail

Isolation and redox reactivity of cerium complexes in four redox states

Fang-Che Hsueh , Thayalan Rajeshkumar , Laurent Maron , Rosario Scopelliti , Andrzej Sienkiewicz et al.

Chemical Science, 2023, 14 (22), pp.6011-6021. ⟨10.1039/d3sc01478a⟩

Article dans une revue hal-04311295v1

Bonding and Reactivity in Terminal versus Bridging Arenide Complexes of Thorium Acting as Th II Synthons

Fang‐che Hsueh , Thayalan Rajeshkumar , Bastiaan Kooij , Rosario Scopelliti , Kay Severin et al.

Angewandte Chemie International Edition, 2023, 62 (9), ⟨10.1002/anie.202215846⟩

Article dans une revue hal-04184322v1

Isolation of C1 through C4 derivatives from CO using heteroleptic uranium(III) metallocene aryloxide complexes (vol 14, pg 2024, 2023)

Robert J. Ward , Iker Del Rosal , Steven P. Kelley , Laurent Maron , Justin R. Walensky

Chemical Science, 2023, 14 (12), pp.3385. ⟨10.1039/d3sc90046k⟩

Article dans une revue hal-04707634v1

Multimetallic Uranium Nitride Cubane Clusters from Dinitrogen Cleavage

Mikhail S. Batov , Iker Del rosal , Rosario Scopelliti , Farzaneh Fadaei-Tirani , Ivica Zivkovic et al.

Journal of the American Chemical Society, 2023, 145 (48), pp.26435-26443. ⟨10.1021/jacs.3c10617⟩

Article dans une revue hal-04707678v1

Highly Regioselective Propargylation/Allenylation of Organolanthanum Reagents with Aldehydes

Xue-Lin Dai , Jingdi Ran , Thayalan Rajeshkumar , Zhengping Xu , Shanshan Liu et al.

Organic Letters, 2023, 25 (17), pp.3060-3065. ⟨10.1021/acs.orglett.3c00824⟩

Article dans une revue hal-04284945v1

Mechanistic Investigations on Bismuth Catalyzed Reduction of Ketones and Phosphine Oxides

Annabel Benny , Deepti Sharma , Thayalan Ankur , Thayalan Rajeshkumar , Laurent Maron et al.

Chemistry - A European Journal, 2023, 29 (42), ⟨10.1002/chem.202300588⟩

Article dans une revue hal-04707665v1

Coordination and Activation of N<sub>2</sub> at Low-Valent Magnesium using a Heterobimetallic Approach: Synthesis and Reactivity of a Masked Dimagnesium Diradical

Rahul Mondal , Matthew J. J. Evans , Thayalan Rajeshkumar , Laurent Maron , Cameron Jones

Angewandte Chemie International Edition, 2023, 62 (37), ⟨10.1002/anie.202308347⟩

Article dans une revue hal-04707629v1

Magnesium(I) Reduction of Aluminum(III) Hydride Complexes: Generation of Mixed Valence Aluminum (Al<SUP>I</SUP>/Al<SUP>0</SUP>) Hydride Cluster Compounds, [Al<sub>6</sub>H<sub>8</sub>(NR<sub>3</sub>)<sub>2</sub>\Mg(β-diketim inate)\<sub>4</sub>]

Sneha Mullassery , K. Yuvaraj , Deepak Dange , Dafydd D. L. Jones , Iker Del Rosal et al.

Angewandte Chemie International Edition, 2023, 62 (30), ⟨10.1002/anie.202305582⟩

Article dans une revue hal-04707636v1

Organotitanium Complexes Supported by a Dianionic Pentadentate Ligand

Daniel Beh , Alejandro Cuellar de Lucio , Iker del Rosal , Laurent Maron , Denis Spasyuk et al.

Organometallics, 2023, 42 (11), pp.1149-1157. ⟨10.1021/acs.organomet.2c00609⟩

Article dans une revue hal-04218412v1
Deposit thumbnail

Group 12 and 13 metal-alkenyl promoted generation of long-chain branching in metallocene-based polyethylene

Orlando Santoro , Lorenzo Piola , Karl Mc Cabe , Olivier Lhost , Katty den Dauw et al.

European Polymer Journal, 2022, 173, pp.111257. ⟨10.1016/j.eurpolymj.2022.111257⟩

Article dans une revue hal-04013388v1
Deposit thumbnail

Cation assisted binding and cleavage of dinitrogen by uranium complexes

Nadir Jori , Thayalan Rajeshkumar , Rosario Scopelliti , Ivica Z̆ivković , Andrzej Sienkiewicz et al.

Chemical Science, 2022, 13 (32), pp.9232-9242. ⟨10.1039/d2sc02530b⟩

Article dans une revue hal-03969626v1
Deposit thumbnail

Assembling diuranium complexes in different states of charge with a bridging redox-active ligand

Dieuwertje Modder , Mikhail Batov , Thayalan Rajeshkumar , Andrzej Sienkiewicz , Ivica Zivkovic et al.

Chemical Science, 2022, 13 (38), pp.11294-11303. ⟨10.1039/d2sc03592h⟩

Article dans une revue hal-04037086v1

Strontium Hydride Cations Supported by a Large NNNNN Type Macrocycle: Synthesis, Structure, and Hydrofunctionalization Catalysis

Thomas Hoellerhage , Thomas P. Spaniol , Ambre Carpentier , Laurent Maron , Jun Okuda

Inorganic Chemistry, 2022, 61 (7), pp.3309-3316. ⟨10.1021/acs.inorgchem.1c03894⟩

Article dans une revue hal-03714655v1
Deposit thumbnail

Rational Preparation of Well-Defined Multinuclear Iridium-Aluminum Polyhydride Clusters and Comparative Reactivity

Leon Escomel , Naime Soule , Emmanuel Robin , Iker del Rosal , Laurent Maron et al.

Inorganic Chemistry, 2022, 61 (15), pp.5715-5730. ⟨10.1021/acs.inorgchem.1c03120⟩

Article dans une revue hal-03714651v1
Deposit thumbnail

Photochemical Synthesis of Transition Metal-Stabilized Uranium(VI) Nitride Complexes

Xiaoqing Xin , Iskander Douair , Thayalan Rajeshkumar , Yue Zhao , Shuao Wang et al.

Nature Communications, 2022, 13 (1), pp.3809. ⟨10.1038/s41467-022-31582-z⟩

Article dans une revue hal-03956091v1
Deposit thumbnail

Spectroscopic, Magnetic, and Computational Investigations on a Series of Rhenium(III) Cyclopentadienide β-diketiminate Halide and Pseudohalide Complexes

Erik Ouellette , Jorge Ivan Amaro Estrada , Daniel Lussier , Khetpakorn Chakarawet , Trevor Lohrey et al.

Organometallics, 2022, 41 (22), pp.3128-3137. ⟨10.1021/acs.organomet.1c00516⟩

Article dans une revue hal-04117025v1

Synthesis of Molecular Phenylcalcium Derivatives: Application to the Formation of Biaryls

Andrew S. S. Wilson , Kyle G. Pearce , Chiara Dinoi , Michael S. Hill , Mary F. Mahon et al.

Angewandte Chemie International Edition, 2022, ⟨10.1002/anie.202200305⟩

Article dans une revue hal-03714648v1

A Combined Experimental and Theoretical Investigation of Arene-Supported Actinide and Ytterbium Tetraphenolate Complexes

Francis Y. T. Lam , Jordann A. L. Wells , Tatsumi Ochiai , Connor J. Halliday , Karl N. Mccabe et al.

Inorganic Chemistry, 2022, 61 (11), pp.4581-4591. ⟨10.1021/acs.inorgchem.1c03365⟩

Article dans une revue hal-03714643v1
Deposit thumbnail

The mechanism of Fe induced bond stability of uranyl( v )

Tonya Vitova , Radmila Faizova , Jorge Amaro-Estrada , Laurent Maron , Tim Pruessmann et al.

Chemical Science, 2022, 13 (37), pp.11038-11047. ⟨10.1039/d2sc03416f⟩

Article dans une revue hal-04005908v1

Synthesis, Characterization, and Reactivity of a Hydrido- and Imido-Bridged Dinuclear Ytterbium(III) Complex

Qingqing Wen , Thayalan Rajeshkumar , Laurent Maron , Xuebing Leng , Yaofeng Chen

Angewandte Chemie International Edition, 2022, 61 (25), ⟨10.1002/anie.202200540⟩

Article dans une revue hal-03714649v1

Heterometallic Clusters with Uranium-Metal Bonds Supported by Double-Layer Nitrogen-Phosphorus Ligands

Qin Zhu , Wei Fang , Laurent Maron , Congqing Zhu

Accounts of Chemical Research, 2022, 55 (12), pp.1718-1730. ⟨10.1021/acs.accounts.2c00180⟩

Article dans une revue hal-03714652v1

Molecular and Electronic Structure of Linear Uranium Metallocenes Stabilized by Pentabenzyl-Cyclopentadienyl Ligands

Sascha Löffler , Frank Heinemann , Ambre Carpentier , Laurent Maron , Karsten Meyer

Organometallics, 2022, 41 (15), pp.2077-2087. ⟨10.1021/acs.organomet.2c00217⟩

Article dans une revue hal-03969656v1
Deposit thumbnail

A Versatile Strategy for the Formation of Hydride-Bridged Actinide-Iridium Multimetallics

Christopher Z Ye , Iker Del rosal , Michael A Boreen , Erik T Ouellette , Dominic Russo et al.

Chemical Science, 2022, ⟨10.1039/D2SC04903A⟩

Article dans une revue hal-03909474v1

Elemental chalcogen reactions of a tetravalent uranium imidophosphorane complex: cleavage of dioxygen

Luis Aguirre Quintana , Thayalan Rajeshkumar , Ningxin Jiang , Julie Niklas , John Bacsa et al.

Chemical Communications, 2022, 58 (95), pp.13242-13245. ⟨10.1039/d2cc05066h⟩

Article dans une revue hal-04103267v1
Deposit thumbnail

Structure, reactivity and luminescence studies of triphenylsiloxide complexes of tetravalent lanthanides

Aurelien R. Willauer , Iskander Douair , Anne-Sophie Chauvin , Farzaneh Fadaei-Tirani , Jean-Claude G. Bunzli et al.

Chemical Science, 2022, 13 (3), pp.681-691. ⟨10.1039/d1sc05517h⟩

Article dans une revue hal-03717274v1
Deposit thumbnail

A Bronsted Acidic Gallium Hydride: Facile Interconversion of NNNN-Macrocycle Supported [Ga-I](+) and [(GaH)-H-III](2+)

Louis J. Morris , Priyabrata Ghana , Thayalan Rajeshkumar , Ambre Carpentier , Laurent Maron et al.

Angewandte Chemie International Edition, 2022, 61 (11), pp.e202114629. ⟨10.1002/anie.202114629⟩

Article dans une revue hal-03714658v1

A Planar Nickelaspiropentane Complex with Magnesium-Based Metalloligands: Synthesis, Structure, and Synergistic Dihydrogen Activation

Yanping Cai , Shengjie Jiang , Thayalan Rajeshkumar , Laurent Maron , Xin Xu

Journal of the American Chemical Society, 2022, 144 (36), pp.16647-16655. ⟨10.1021/jacs.2c07402⟩

Article dans une revue hal-04037097v1

Formation and Reactivity of a Hexahydridosilicate [SiH6](2-) Coordinated by a Macrocycle-Supported Strontium Cation

Thomas Hoellerhage , Priyabrata Ghana , Thomas P. Spaniol , Ambre Carpentier , Laurent Maron et al.

Angewandte Chemie International Edition, 2022, 61 (10), ⟨10.1002/anie.202115379⟩

Article dans une revue hal-03714657v1

Does Reduction-Induced Isomerization of a Uranium(III) Aryl Complex Proceed via C-H Oxidative Addition and Reductive Elimination across the Uranium(II/IV) Redox Couple?

Michael A. Boreen , Christopher Z. Ye , Andrew Kerridge , Karl N. Mccabe , Brighton A. Skeel et al.

Inorganic Chemistry, 2022, 61 (23), pp.8955-8965. ⟨10.1021/acs.inorgchem.2c01563⟩

Article dans une revue hal-03714654v1

Activation of CO Using a 1,2‐Disilylene: Facile Synthesis of an Abnormal N‐Heterocyclic Silylene

Palak Garg , Ambre Carpentier , Iskander Douair , Deepak Dange , Yixiao Jiang et al.

Angewandte Chemie International Edition, 2022, 61 (20), ⟨10.1002/anie.202201705⟩

Article dans une revue hal-04013295v1

Reactivity of Multimetallic Thorium Nitrides Generated by Reduction of Thorium Azides

Fang-Che Hsueh , Luciano Barluzzi , Megan Keener , Thayalan Rajeshkumar , Laurent Maron et al.

Journal of the American Chemical Society, 2022, 144 (7), pp.3222-3232. ⟨10.1021/jacs.1c13150⟩

Article dans une revue hal-03714653v1

Reversible Oxidative Addition of Zinc Hydride at a Gallium(I)‐Centre: Labile Mono‐ and Bis(hydridogallyl)zinc Complexes

Louis Morris , Thayalan Rajeshkumar , Laurent Maron , Jun Okuda

Chemistry - A European Journal, 2022, 28 (56), ⟨10.1002/chem.202201480⟩

Article dans une revue hal-04041541v1

Uranium(III)–Phosphorus(III) Synergistic Activation of White Phosphorus and Arsenic

Wei Fang , Iskander Douair , Adrian Hauser , Kai Li , Yue Zhao et al.

CCS Chemistry, 2022, 4 (8), pp.2630-2638. ⟨10.31635/ccschem.021.202101485⟩

Article dans une revue hal-04023410v1

Reductive activation of N 2 using a calcium/potassium bimetallic system supported by an extremely bulky diamide ligand

Rahul Mondal , K. Yuvaraj , Thayalan Rajeshkumar , Laurent Maron , Cameron Jones

Chemical Communications, 2022, 58 (91), pp.12665-12668. ⟨10.1039/d2cc04841h⟩

Article dans une revue hal-04088737v1
Deposit thumbnail

CO reductive oligomerization by a divalent thulium complex and CO2-induced functionalization

Thomas Simler , Karl N. Mccabe , Laurent Maron , Gregory Nocton

Chemical Science, 2022, 13 (25), pp.7449-7461. ⟨10.1039/d2sc01798a⟩

Article dans une revue hal-03714642v1

Heterometallic uranium/molybdenum nitride synthesis via partial N-atom transfer

Luciano Barluzzi , Nadir Jori , Tianyi He , Thayalan Rajeshkumar , Rosario Scopelliti et al.

Chemical Communications, 2022, 58 (29), pp.4655-4658. ⟨10.1039/d2cc00473a⟩

Article dans une revue hal-03714647v1

Synthesis and Reactivity of Triangular Heterometallic ComplexesContaining Zn-Zn Bond br

Shengjie Jiang , Yanping Cai , Ambre Carpentier , Iker del Rosal , Laurent Maron et al.

Inorganic Chemistry, 2022, 61 (20), pp.8083-8089. ⟨10.1021/acs.inorgchem.2c00956⟩

Article dans une revue hal-03714644v1
Deposit thumbnail

Facile Synthesis of Uranium Complexes with a Pendant Borane Lewis Acid and 1,2‐Insertion of CO into a U−N Bond

Wei Su , Thayalan Rajeshkumar , Libo Xiang , Laurent Maron , Qing Ye

Angewandte Chemie International Edition, 2022, 61 (51), ⟨10.1002/anie.202212823⟩

Article dans une revue hal-04115729v1
Deposit thumbnail

Role of the Meso Substituent in Defining the Reduction of Uranyl Dipyrrin Complexes

Karlotta van Rees , Thayalan Rajeshkumar , Laurent Maron , Stephen Sproules , Jason Love

Inorganic Chemistry, 2022, 61 (50), pp.20424-20432. ⟨10.1021/acs.inorgchem.2c03048⟩

Article dans une revue hal-04116999v1

Thorium- and Uranium-Mediated C–H Activation of a Silyl-Substituted Cyclobutadienyl Ligand

Nikolaos Tsoureas , Thayalan Rajeshkumar , Oliver Townrow , Laurent Maron , Richard Layfield

Inorganic Chemistry, 2022, 61 (50), pp.20629-20635. ⟨10.1021/acs.inorgchem.2c03534⟩

Article dans une revue hal-04158681v1

CO, CO2 and CS2 activation by divalent ytterbium hydrido complexes

Xianghui Shi , Thayalan Rajeshkumar , Laurent Maron , Jianhua Cheng

Chemical Communications, 2022, 58 (9), pp.1362-1365. ⟨10.1039/d1cc06449e⟩

Article dans une revue hal-03717270v1
Deposit thumbnail

Electron Shuttle in N-Heteroaromatic Ni Catalysts for Alkene Isomerization

Maxime Tricoire , Ding Wang , Thayalan Rajeshkumar , Laurent Maron , Grégory Danoun et al.

JACS Au, 2022, 2 (8), pp.1881-1888. ⟨10.1021/jacsau.2c00251⟩

Article dans une revue hal-03768030v1
Deposit thumbnail

Selective hydroboration of terminal alkynes catalyzed by heterometallic clusters with uranium metal triple bonds

Penglong Wang , Iskander Douair , Yue Zhao , Rile Ge , Junhu Wang et al.

Chem, 2022, 8 (5), pp.1361-1375. ⟨10.1016/j.chempr.2022.03.005⟩

Article dans une revue hal-03714650v1

Solvent‐Dependent Oxidative Addition and Reductive Elimination of H 2 Across a Gallium‐Zinc Bond

Louis Morris , Thayalan Rajeshkumar , Akira Okumura , Laurent Maron , Jun Okuda

Angewandte Chemie International Edition, 2022, 61 (36), ⟨10.1002/anie.202208855⟩

Article dans une revue hal-03988989v1

Stereospecific Polymerization of Bulky Methacrylates Using Organocatalyst in Strong Donating Solvent via Self-Controlled Mechanism

Yangyang Sun , Ambre Carpentier , Yixin Zhang , Biwei Weng , Yaoyao Ling et al.

Macromolecules, 2022, 55 (18), pp.8292-8302. ⟨10.1021/acs.macromol.2c01333⟩

Article dans une revue hal-04065843v1

A Masked Form of an O‐Borylated Breslow Intermediate for the Diastereoselective FLP‐Type Activation of Aldehydes

Angelica Mejia Fajardo , Nicolas Queyriaux , Aurèle Camy , Laure Vendier , Mary Grellier et al.

Chemistry - A European Journal, 2022, 28 (10), pp.e202104122. ⟨10.1002/chem.202104122⟩

Article dans une revue hal-03669849v1
Deposit thumbnail

Electronic structure studies reveal 4f/5d mixing and its effect on bonding characteristics in Ce-imido and -oxo complexes

Liane M. Moreau , Ekaterina Lapsheva , Jorge Amaro-Estrada , Michael R. Gau , Patrick J. Carroll et al.

Chemical Science, 2022, 13 (6), pp.1759-1773. ⟨10.1039/d1sc06623d⟩

Article dans une revue hal-03714645v1

Controlled monodefluorination and alkylation of C(sp<SUP>3</SUP>)-F bonds by lanthanide photocatalysts: importance of metal-ligand cooperativity

Amy E. Kynman , Luca K. Elghanayan , Addison N. Desnoyer , Yan Yang , Laurent Severy et al.

Chemical Science, 2022, 13 (47), pp.14090-14100. ⟨10.1039/d2sc04192h⟩

Article dans une revue hal-04707642v1
Deposit thumbnail

Tuning the Regioselective Functionalization of Trifluoromethylated Dienes via Lanthanum‐Mediated Single C−F Bond Activation

Tarun Kumar , Yan Yang , Sirine Sghaier , Yassir Zaid , X. F Le Goff et al.

Chemistry - A European Journal, 2021, 27 (12), pp.4016-4021. ⟨10.1002/chem.202005239⟩

Article dans une revue hal-03264465v1
Deposit thumbnail

A Uranium(II) Arene Complex That Acts as a Uranium(I) Synthon

Mark D. Straub , Erik T. Ouellette , Michael A. Boreen , R. David Britt , Khetpakorn Chakarawet et al.

Journal of the American Chemical Society, 2021, 143 (47), pp.19748-19760. ⟨10.1021/jacs.1c07854⟩

Article dans une revue hal-03717277v1

Reduced Arene Complexes of Hafnium Supported by a Triamidoamine Ligand

Priyabrata Ghana , Sebastian Schrader , Thayalan Rajeshkumar , Thomas P. Spaniol , Ulli Englert et al.

Angewandte Chemie International Edition, 2021, 60 (25), pp.14179-14187. ⟨10.1002/anie.202103755⟩

Article dans une revue hal-03717260v1

Isolation of a [Fe(CO)(4)](2-)-Bridged Diuranium Complex Obtained via Reduction of Fe(CO)(5) with Uranium(III)

Robert J. Ward , Daniel Pividori , Ambre Carpentier , Michael L. Tarlton , Steven P. Kelley et al.

Organometallics, 2021, 40 (10), pp.1411-1415. ⟨10.1021/acs.organomet.1c00205⟩

Article dans une revue hal-03717253v1

Hydrosilylative reduction of carbon dioxide by a homoleptic lanthanum aryloxide catalyst with high activity and selectivity

Kejian Chang , Iker del Rosal , Xizhou Zheng , Laurent Maron , Xin Xu

Dalton Transactions, 2021, 50 (22), pp.7804-7809. ⟨10.1039/d1dt01074c⟩

Article dans une revue hal-03717252v1
Deposit thumbnail

Catalytic Deoxygenation of Nitroarenes Mediated by High-Valent Molybdenum(VI)-NHC Complexes

Shenyu Liu , Jorge Ivan Amaro-Estrada , Marc Baltrun , Iskander Douair , Roland Schoch et al.

Organometallics, 2021, 40 (2), pp.107-118. ⟨10.1021/acs.organomet.0c00352⟩

Article dans une revue hal-03717280v1
Deposit thumbnail

Reductive Hexamerization of CO Involving Cooperativity Between Magnesium(I) Reductants and [Mo(CO)(6)]: Synthesis of Well-Defined Magnesium Benzenehexolate Complexes

Albert Paparo , K. Yuvaraj , Aidan J. R. Matthews , Iskander Douair , Laurent Maron et al.

Angewandte Chemie International Edition, 2021, 60 (2), pp.630-634. ⟨10.1002/anie.202009523⟩

Article dans une revue hal-03925182v1

Photochemically Activated Dimagnesium(I) Compounds: Reagents for the Reduction and Selective C-H Bond Activation of Inert Arenes

Dafydd D. L. Jones , Iskander Douair , Laurent Maron , Cameron Jones

Angewandte Chemie International Edition, 2021, 60 (13), pp.7087-7092. ⟨10.1002/anie.202017126⟩

Article dans une revue hal-03717283v1

Computational Insights into Different Mechanisms for Ag-, Cu-, and Pd-Catalyzed Cyclopropanation of Alkenes and Sulfonyl Hydrazones

Yong Wu , Shanshan Cao , Iskander Douair , Laurent Maron , Xihe Bi

Chemistry - A European Journal, 2021, 27 (19), pp.5999-6006. ⟨10.1002/chem.202005193⟩

Article dans une revue hal-03717247v1

Deaggregation of Zinc Dihydride by Lewis Acids Including Carbon Dioxide in the Presence of Nitrogen Donors

Florian Ritter , Louis J. Morris , Karl N. Mccabe , Thomas P. Spaniol , Laurent Maron et al.

Inorganic Chemistry, 2021, 60 (20), pp.15583-15592. ⟨10.1021/acs.inorgchem.1c02207⟩

Article dans une revue hal-03717263v1
Deposit thumbnail

Hydroarylation of olefins catalysed by a dimeric ytterbium(II) alkyl

Georgia M. Richardson , Iskander Douair , Scott A. Cameron , Joe Bracegirdle , Robert A. Keyzers et al.

Nature Communications, 2021, 12, pp.3147. ⟨10.1038/s41467-021-23444-x⟩

Article dans une revue hal-03717276v1

Scandium-Terminal Boronylphosphinidene Complex

Bin Feng , Li Xiang , Ambre Carpentier , Laurent Maron , Xuebing Leng et al.

Journal of the American Chemical Society, 2021, 143 (7), pp.2705-2709. ⟨10.1021/jacs.1c00148⟩

Article dans une revue hal-03717269v1

Cationic Zinc Hydride Catalyzed Carbon Dioxide Reduction to Formate: Deciphering Elementary Reactions, Isolation of Intermediates, and Computational Investigations

Raju Chambenahalli , R. M. Bhargav , Karl N. Mccabe , Alex P. Andrews , Florian Ritter et al.

Chemistry - A European Journal, 2021, 27 (26), pp.7391-7401. ⟨10.1002/chem.202005392⟩

Article dans une revue hal-03717258v1

Stepwise Reduction of Dinitrogen by a Uranium-Potassium Complex Yielding a U(VI)/U(IV) Tetranitride Cluster

Nadir Jori , Luciano Barluzzi , Iskander Douair , Laurent Maron , Farzaneh Fadaei-Tirani et al.

Journal of the American Chemical Society, 2021, 143 (29), pp.11225-11234. ⟨10.1021/jacs.1c05389⟩

Article dans une revue hal-03717248v1

Calcium Hydride Catalysts for Olefin Hydrofunctionalization: Ring-Size Effect of Macrocyclic Ligands on Activity

Thomas Hoellerhage , Danny Schuhknecht , Alisha Mistry , Thomas P. Spaniol , Yan Yang et al.

Chemistry - A European Journal, 2021, 27 (9), pp.3002-3007. ⟨10.1002/chem.202004931⟩

Article dans une revue hal-03717259v1

Nickel-catalyzed synthesis of Zn(i)-Zn(i) bonded compounds

Shengjie Jiang , Yanping Cai , Ambre Carpentier , Iker del Rosal , Laurent Maron et al.

Chemical Communications, 2021, 57 (100), pp.13696-13699. ⟨10.1039/d1cc05719g⟩

Article dans une revue hal-03717250v1

[(Me6TREN)MgOCHPh2][B(C6F5)(4)]: A Model Complex to Explore the Catalytic Activity of Magnesium Alkoxides in Ketone Hydroboration

A Ankur , Ramkumar Kannan , Raju Chambenahalli , Sumanta Banerjee , Yan Yang et al.

European Journal of Inorganic Chemistry, 2021, 2021 (45), pp.4632-4638. ⟨10.1002/ejic.202100651⟩

Article dans une revue hal-03717246v1
Deposit thumbnail

sigma or pi? Bonding interactions in a series of rhenium metallotetrylenes

Erik T. Ouellette , Ambre Carpentier , I. Joseph Brackbill , Trevor D. Lohrey , Iskander Douair et al.

Dalton Transactions, 2021, 50 (6), pp.2083-2092. ⟨10.1039/d1dt00129a⟩

Article dans une revue hal-03717285v1
Deposit thumbnail

Single metal four-electron reduction by U(II) and masked "U(II)" compounds

Dieuwertje K. Modder , Chad T. Palumbo , Iskander Douair , Rosario Scopelliti , Laurent Maron et al.

Chemical Science, 2021, 12 (17), pp.6153-6158. ⟨10.1039/d1sc00668a⟩

Article dans une revue hal-03717255v1

Zinc hydride cation [ZnH](+) supported by TMPDA (TMPDA = N,N,N ',N '-tetramethylpropane-1,3-diamine)

Florian Ritter , Karl N. Mccabe , Laurent Maron , Thomas P. Spaniol , Jun Okuda

Polyhedron, 2021, 204, ⟨10.1016/j.poly.2021.115264⟩

Article dans une revue hal-03717272v1

Dihydrogen cleavage by a dimetalloxycarbene-borane frustrated Lewis pair

Albert Paparo , Anh L. P. Nguyen , Jared S. Silvia , Thomas P. Spaniol , Laurent Maron et al.

Dalton Transactions, 2021, 50 (31), pp.10692-10695. ⟨10.1039/d1dt02273c⟩

Article dans une revue hal-03717268v1

Reductive elimination of [AlH2](+) from a cationic Ga-Al dihydride

Louis J. Morris , Ambre Carpentier , Laurent Maron , Jun Okuda

Chemical Communications, 2021, 57 (74), pp.9454-9457. ⟨10.1039/d1cc03706d⟩

Article dans une revue hal-03717267v1

Facile Dinitrogen and Dioxygen Cleavage by a Uranium(III) Complex: Cooperativity Between the Non-Innocent Ligand and the Uranium Center

Penglong Wang , Iskander Douair , Yue Zhao , Shuao Wang , Jun Zhu et al.

Angewandte Chemie International Edition, 2021, 60 (1), pp.473-479. ⟨10.1002/anie.202012198⟩

Article dans une revue hal-03717278v1
Deposit thumbnail

Evidence for ligand- and solvent-induced disproportionation of uranium(IV)

Jingzhen Du , Iskander Douair , Erli Lu , John A. Seed , Floriana Tuna et al.

Nature Communications, 2021, 12, pp.4832. ⟨10.1038/s41467-021-25151-z⟩

Article dans une revue hal-03717266v1

Heterometallic Clusters with Multiple Rare Earth Metal-Transition Metal Bonding

Iskander Douair , Genfeng Feng , Penglong Wang , Yue Zhao , Laurent Maron et al.

Journal of the American Chemical Society, 2021, 143 (15), pp.5998-6005. ⟨10.1021/jacs.1c01771⟩

Article dans une revue hal-03717256v1

Ytterbium (II) Hydride as a Powerful Multielectron Reductant

Georgia M. Richardson , Iskander Douair , Scott A. Cameron , Laurent Maron , Mathew D. Anker

Chemistry - A European Journal, 2021, 27 (52), pp.13144-13148. ⟨10.1002/chem.202102428⟩

Article dans une revue hal-03717249v1
Deposit thumbnail

Activation of ammonia and hydrazine by electron rich Fe(ii) complexes supported by a dianionic pentadentate ligand platform through a common terminal Fe(iii) amido intermediate

Lucie Nurdin , Yan Yang , Peter G. N. Neate , Warren E. Piers , Laurent Maron et al.

Chemical Science, 2021, 12 (6), pp.2231-2241. ⟨10.1039/d0sc06466a⟩

Article dans une revue hal-03717265v1
Deposit thumbnail

Dehydrohalogenation of halobenzenes and C(sp(3))-X (X = F, OPh) bond activation by a molecular calcium hydride

Andrew S. S. Wilson , Michael S. Hill , Mary F. Mahon , Chiara Dinoi , Laurent Maron

Tetrahedron, 2021, 82, ⟨10.1016/j.tet.2021.131931⟩

Article dans une revue hal-03717244v1

C-N and C-H Activation of an N-Heterocyclic Carbene by Magnesium(II) Hydride and Magnesium(I) Complexes

K. Yuvaraj , Ambre Carpentier , Cory D. Smith , Laurent Maron , Cameron Jones

Inorganic Chemistry, 2021, 60 (8), pp.6065-6072. ⟨10.1021/acs.inorgchem.1c00552⟩

Article dans une revue hal-03717245v1
Deposit thumbnail

Al-alkenyl-induced formation of long-chain branched polyethylene via coordinative tandem insertion and chain-transfer polymerization using (nBuCp)2ZrCl2/MAO systems: An experimental and theoretical study

O. Santoro , L. Piola , K. Mc Cabe , O. Lhost , K. den Dauw et al.

European Polymer Journal, 2021, 154, pp.110567. ⟨10.1016/j.eurpolymj.2021.110567⟩

Article dans une revue hal-03284278v1

Scandium and lanthanum hydride complexes stabilized by super-bulky penta-arylcyclopentadienyl ligands

Yang Wang , Iker del Rosal , Guorui Qin , Lanxiao Zhao , Laurent Maron et al.

Chemical Communications, 2021, 57 (63), pp.7766-7769. ⟨10.1039/d1cc01841h⟩

Article dans une revue hal-03717282v1

Organocalcium Complex-Catalyzed Selective Redistribution of ArSiH3 or Ar(alkyl)SiH2 to Ar3SiH or Ar-2(alkyl)SiH

Tao Li , Karl N. Mccabe , Laurent Maron , Xuebing Leng , Yaofeng Chen

ACS Catalysis, 2021, 11 (11), pp.6348-6356. ⟨10.1021/acscatal.1c00463⟩

Article dans une revue hal-03717273v1

Delivery of a Masked Uranium(II) by an Oxide-Bridged Diuranium(III) Complex

Dieuwertje K. Modder , Chad T. Palumbo , Iskander Douair , Farzaneh Fadaei-Tirani , Laurent Maron et al.

Angewandte Chemie International Edition, 2021, 60 (7), pp.3737-3744. ⟨10.1002/anie.202013473⟩

Article dans une revue hal-03925181v1
Deposit thumbnail

Strongly Polarized Iridium δ− –Aluminum δ+ Pairs: Unconventional Reactivity Patterns Including CO 2 Cooperative Reductive Cleavage

Léon Escomel , Iker del Rosal , Laurent Maron , Erwann Jeanneau , Laurent Veyre et al.

Journal of the American Chemical Society, 2021, 143 (12), pp.4844-4856. ⟨10.1021/jacs.1c01725⟩

Article dans une revue hal-03357324v1

Redox-induced reversible P-P coupling in a uranium complex

Wei Fang , Ambre Carpentier , Xiong Sun , Yue Zhao , Laurent Maron et al.

Chemical Communications, 2021, 57 (91), pp.12175-12178. ⟨10.1039/d1cc04765e⟩

Article dans une revue hal-03717284v1

Formation and Reactivity with (BuCN)-Bu-t of a Thorium Phosphinidiide through a Combined Experimental and Computational Analysis

Michael L. Tarlton , Yan Yang , Steven P. Kelley , Laurent Maron , Justin R. Walensky

Organometallics, 2021, 40 (15), pp.2701-2708. ⟨10.1021/acs.organomet.1c00330⟩

Article dans une revue hal-03717279v1

Cationic strontium hydride complexes supported by an NNNN-type macrocycle

Thomas Hoellerhage , Ambre Carpentier , Thomas P. Spaniol , Laurent Maron , Ulli Englert et al.

Chemical Communications, 2021, 57 (51), pp.6316-6319. ⟨10.1039/d1cc02040d⟩

Article dans une revue hal-03717262v1

Insights into Rare-Earth Metal Complex-Mediated Hydroamination

Shuqi Dong , Jinjin Chen , Kening Qiao , Jian Fang , Yan Yang et al.

ACS Catalysis, 2021, 11 (7), pp.3790-3800. ⟨10.1021/acscatal.1c00566⟩

Article dans une revue hal-03717257v1

A mononuclear divalent ytterbium hydrido complex supported by a super-bulky scorpionate ligand

Xianghui Shi , Peng Deng , Thayalan Rajeshkumar , Lanxiao Zhao , Laurent Maron et al.

Chemical Communications, 2021, 57 (78), pp.10047-10050. ⟨10.1039/d1cc04488e⟩

Article dans une revue hal-03717251v1

A monoanionic pentadentate ligand platform for scandium-pnictogen multiple bonds

Evan A. Patrick , Yan Yang , Warren E. Piers , Laurent Maron , Benjamin S. Gelfand

Chemical Communications, 2021, 57 (69), pp.8640-8643. ⟨10.1039/d1cc03481b⟩

Article dans une revue hal-03717264v1

Calcium-mediated C(sp(3))-H Activation and Alkylation of Alkylpyridines

Xizhou Zheng , Iker del Rosal , Xian Xu , Yingming Yao , Laurent Maron et al.

Inorganic Chemistry, 2021, 60 (7), pp.5114-5121. ⟨10.1021/acs.inorgchem.1c00161⟩

Article dans une revue hal-03717254v1
Deposit thumbnail

Atom economical coupling of benzophenone and N-heterocyclic aromatics with SmI 2

Arnaud Jaoul , Yan Yang , Nicolas Casaretto , Carine Clavaguéra , Laurent Maron et al.

Chemical Communications, 2020, ⟨10.1039/D0CC05164K⟩

Article dans une revue hal-02941564v1
Deposit thumbnail

Terminal uranium(V)-nitride hydrogenations involving direct addition or Frustrated Lewis Pair mechanisms

Lucile Chatelain , Elisa Louyriac , Iskander Douair , Erli Lu , Floriana Tuna et al.

Nature Communications, 2020, 11 (1), pp.337. ⟨10.1038/s41467-019-14221-y⟩

Article dans une revue hal-03925214v1
Deposit thumbnail

Synthesis and versatile reactivity of scandium phosphinophosphinidene complexes

Bin Feng , Li Xiang , Karl N. Mccabe , Laurent Maron , Xuebing Leng et al.

Nature Communications, 2020, 11 (1), ⟨10.1038/s41467-020-16773-w⟩

Article dans une revue hal-03925195v1

Molecular Thorium Trihydrido Clusters Stabilized by Cyclopentadienyl Ligands

Runhai Chen , Guorui Qin , Shihui Li , Alison J. Edwards , Ross O. Piltz et al.

Angewandte Chemie International Edition, 2020, 59 (28), pp.11250-11255. ⟨10.1002/anie.202002303⟩

Article dans une revue hal-03925198v1

A transient lanthanum phosphinidene complex

Fabian A. Watt , Karl N. Mccabe , Roland Schoch , Laurent Maron , Stephan Hohloch

Chemical Communications, 2020, 56 (98), ⟨10.1039/d0cc06670b⟩

Article dans une revue hal-03925180v1

Dinitrogen Cleavage by a Heterometallic Cluster Featuring Multiple Uranium-Rhodium Bonds

Congqing Zhu , Xiaoqing Xin , Iskander Douair , Yue Zhao , Shuao Wang et al.

Journal of the American Chemical Society, 2020, 142 (35), pp.15004-15011. ⟨10.1021/jacs.0c05788⟩

Article dans une revue hal-03925189v1

Accessing the plus IV Oxidation State in Molecular Complexes of Praseodymium

Aurelien R. Willauer , Chad T. Palumbo , Farzaneh Fadaei-Tirani , Ivica Zivkovic , Iskander Douair et al.

Journal of the American Chemical Society, 2020, 142 (12), pp.5538-5542. ⟨10.1021/jacs.0c01204⟩

Article dans une revue hal-03925207v1
Deposit thumbnail

Mechanistic Investigations via DFT Support the Cooperative Heterobimetallic C-H and O-H Bond Activation Across Ta=Ir Multiple Bonds

Iker Del rosal , Sébastien Lassalle , Laurent Maron , Chiara Dinoi , Chloé Thieuleux et al.

Dalton Transactions, 2020, ⟨10.1039/D0DT03818K⟩

Article dans une revue hal-03009651v1

Access to Hydroxy-Functionalized Polypropylene through Coordination Polymerization

Yuanhao Zhong , Iskander Douair , Tiantian Wang , Chunji Wu , Laurent Maron et al.

Angewandte Chemie International Edition, 2020, 59 (12), pp.4947-4952. ⟨10.1002/anie.201914747⟩

Article dans une revue hal-03925211v1

Two-Electron Oxidative Atom Transfer at a Homoleptic, Tetravalent Uranium Complex

Natalie T. Rice , Karl Mccabe , John Bacsa , Laurent Maron , Henry S. La Pierre

Journal of the American Chemical Society, 2020, 142 (16), pp.7368-7373. ⟨10.1021/jacs.0c02693⟩

Article dans une revue hal-03925204v1
Deposit thumbnail

Long-Chain Branched Polyethylene via Coordinative Tandem Insertion and Chain-Transfer Polymerization Using rac-{EBTHI}ZrCl2/MAO/Al-alkenyl Combinations: An Experimental and Theoretical Study

M. Santoro , Lorenzo Piola , Karl Mc Cabe , Olivier Lhost , Katty den Dauw et al.

Macromolecules, 2020, 53 (20), pp.8847-8857. ⟨10.1021/acs.macromol.0c01671⟩

Article dans une revue hal-03040883v1

A tetranuclear nickel cluster isolated in multiple high-valent states

Samuel Jacob , Iskander Douair , Guang Wu , Laurent Maron , Gabriel Menard

Chemical Communications, 2020, 56 (59), pp.8182-8185. ⟨10.1039/d0cc01699c⟩

Article dans une revue hal-03925191v1

Grafting of Lanthanum Complexes on a Functionalized Graphene Surface: Theoretical Investigation on Ethylene and 1,3-Butadiene Homo- and Co-Polymerization

Adrien Bathellier , Diego Moreno , Laurent Maron , Chiara Dinoi , Iker Del Rosal

CHEMISTRY-A EUROPEAN JOURNAL, 2020, 26 (58), pp.13213-13225. ⟨10.1002/chem.202001056⟩

Article dans une revue hal-03925188v1

Hydrolysis of scandium alkyl derivatives supported by a pentadentate diborate ligand: Interconversion of hydroxo and oxo complexes

Daniel W. Beh , Warren E. Piers , Laurent Maron , Yan Yang , Benjamin S. Gelfand et al.

Polyhedron, 2020, 179, ⟨10.1016/j.poly.2020.114410⟩

Article dans une revue hal-03925208v1
Deposit thumbnail

Selective oxo ligand functionalisation and substitution reactivity in an oxo/catecholate-bridged U-IV/U(IV)Pacman complex

Bradley E. Cowie , Iskander Douair , Laurent Maron , Jason B. Love , Polly L. Arnold

Chemical Science, 2020, 11 (27), pp.7144-7157. ⟨10.1039/d0sc02297g⟩

Article dans une revue hal-03925219v1
Deposit thumbnail

Sterically controlled reductive oligomerisations of CO by activated magnesium(i) compounds: deltate vs. ethenediolate formation

K. Yuvaraj , Iskander Douair , Dafydd D. L. Jones , Laurent Maron , Cameron Jones

Chemical Science, 2020, 11 (13), pp.3516-3522. ⟨10.1039/d0sc00836b⟩

Article dans une revue hal-03925205v1

Comparative Insertion Reactivity of CO, CO2, (BuCN)-Bu-t, and (BuNC)-Bu-t into Thorium- and Uranium-Phosphorus Bonds

Michael L. Tarlton , Iker del Rosal , Sean P. Vilanova , Steven P. Kelley , Laurent Maron et al.

Organometallics, 2020, 39 (11), pp.2152-2161. ⟨10.1021/acs.organomet.0c00221⟩

Article dans une revue hal-03925196v1

Activation of Ethylene by N-Heterocyclic Carbene Coordinated Magnesium(I) Compounds

K. Yuvaraj , Iskander Douair , Laurent Maron , Cameron Jones

CHEMISTRY-A EUROPEAN JOURNAL, 2020, 26 (64), pp.14665-14670. ⟨10.1002/chem.202002380⟩

Article dans une revue hal-03925185v1

Uranium Metallocene Azides, Isocyanates, and Their Borane-Capped Lewis Adducts

Michael A. Boreen , Karl N. Mccabe , Trevor D. Lohrey , Fabian A. Watt , Laurent Maron et al.

INORGANIC CHEMISTRY, 2020, 59 (12), pp.8580-8588. ⟨10.1021/acs.inorgchem.0c01038⟩

Article dans une revue hal-03925193v1

Metallacyclic actinide catalysts for dinitrogen conversion to ammonia and secondary amines (vol 15, pg 312, 2020)

Polly L. Arnold , Tatsumi Ochiai , Francis Y. T. Lam , Rory P. Kelly , Megan L. Seymour et al.

NATURE CHEMISTRY, 2020, 12 (7), pp.660. ⟨10.1038/s41557-020-0485-5⟩

Article dans une revue hal-03925197v1

Synthesis and Structure of Uranium-Silylene Complexes

I. Joseph Brackbill , Iskander Douair , Daniel J. Lussier , Michael A. Boreen , Laurent Maron et al.

CHEMISTRY-A EUROPEAN JOURNAL, 2020, 26 (11), pp.2360-2364. ⟨10.1002/chem.202000214⟩

Article dans une revue hal-03925210v1
Deposit thumbnail

Hydrogen isotope exchange catalyzed by Ru nanocatalysts: labelling of complex molecules containing N-heterocycles and reaction mechanism insights

Viktor Pfeifer , Marie Certiat , Donia Bouzouita , Alberto Palazzolo , Sébastien Garcia-Argote et al.

Chemistry - A European Journal, 2020, 26, pp.4988-4996. ⟨10.1002/chem.201905651⟩

Article dans une revue cea-02487414v1
Deposit thumbnail

Interactions in saccharide/cation/water systems: Insights from density functional theory

Johanne Teychené , Hélène Roux De-Balmann , Laurent Maron , Sylvain Galier

Food Chemistry, 2020, 327, pp.127054. ⟨10.1016/j.foodchem.2020.127054⟩

Article dans une revue hal-02747033v1

NH3 formation from N2 and H2 mediated by molecular tri-iron complexes

Matthias Reiners , Dirk Baabe , Katharina Münster , Marc-Kevin Zaretzke , Matthias Freytag et al.

Nature Chemistry, 2020, 12 (8), pp.740-746. ⟨10.1038/s41557-020-0483-7⟩

Article dans une revue hal-03150029v1

Nickel(0)-Induced beta-H Elimination of Magnesium Alkyls: Formation and Reactivity of Heterometallic Hydrides

Jiasu Huang , Xizhou Zheng , Iker del Rosal , Bei Zhao , Laurent Maron et al.

INORGANIC CHEMISTRY, 2020, 59 (18), pp.13473-13480. ⟨10.1021/acs.inorgchem.0c01885⟩

Article dans une revue hal-03925186v1

Reactivity of Ce(iv) imido compounds with heteroallenes

Ekaterina N. Lapsheva , Thibault Cheisson , Carlos Alvarez Lamsfus , Patrick J. Carroll , Michael R. Gau et al.

Chemical Communications, 2020, 56 (35), pp.4781-4784. ⟨10.1039/c9cc10052k⟩

Article dans une revue hal-03925202v1
Deposit thumbnail

Alkali Metal Triphenyl- and Trihydridosilanides Stabilized by a Macrocyclic Polyamine Ligand

Danny Schuhknecht , Valeri Leich , Thomas P. Spaniol , Iskander Douair , Laurent Maron et al.

Chemistry - A European Journal, 2020, 26 (13), pp.2821-2825. ⟨10.1002/chem.202000187⟩

Article dans une revue hal-03925209v1
Deposit thumbnail

Divergent uranium-versusphosphorus-based reduction of Me(3)SiN(3)with steric modification of phosphido ligands

Robert J. Ward , Pokpong Rungthanaphatsophon , Iker del Rosal , Steven P. Kelley , Laurent Maron et al.

Chemical Science, 2020, 11 (22), pp.5830-5835. ⟨10.1039/d0sc02261f⟩

Article dans une revue hal-03925194v1
Deposit thumbnail

Metallacyclic actinide catalysts for dinitrogen conversion to ammonia and secondary amines

Polly Arnold , Tatsumi Ochiai , Francis Lam , Rory Kelly , Megan Seymour et al.

Nature Chemistry, 2020, 12 (7), pp.654-659. ⟨10.1038/s41557-020-0457-9⟩

Article dans une revue hal-03885963v1
Deposit thumbnail

Regioselective Hydrosilylation of Olefins Catalyzed by a Molecular Calcium Hydride Cation

Danny Schuhknecht , Thomas P. Spaniol , Laurent Maron , Jun Okuda

Angewandte Chemie International Edition, 2020, 59 (1), pp.310-314. ⟨10.1002/anie.201909585⟩

Article dans une revue hal-03925217v1
Deposit thumbnail

Construction of heterometallic clusters with multiple uranium-metal bonds by using dianionic nitrogen-phosphorus ligands

Genfeng Feng , Karl N. Mccabe , Shuao Wang , Laurent Maron , Congqing Zhu

Chemical Science, 2020, 11 (29), pp.7585-7592. ⟨10.1039/d0sc00389a⟩

Article dans une revue hal-03925190v1
Deposit thumbnail

Ethene Activation and Catalytic Hydrogenation by a Low-Valent Uranium Pentalene Complex

Nikolaos Tsoureas , Laurent Maron , Alexander F R Kilpatrick , Richard A Layfield , F. Geoffrey N. Cloke

Journal of the American Chemical Society, 2020, 142 (1), pp.89-92. ⟨10.1021/jacs.9b11929⟩

Article dans une revue hal-03925215v1
Deposit thumbnail

Rationalizing the Reactivity of Mixed Allyl Rare-Earth Borohydride Complexes with DFT Studies

Sami Fadlallah , Jashvini Jothieswaran , Iker Del rosal , Laurent Maron , Fanny Bonnet et al.

Catalysts, 2020, 10, pp.820. ⟨10.3390/catal10080820⟩

Article dans une revue hal-02926044v1
Deposit thumbnail

Calcium Hydride Reduction of Polycyclic Aromatic Hydrocarbons

Andrew S. S. Wilson , Chiara Dinoi , Michael S. Hill , Mary F. Mahon , Laurent Maron et al.

Angewandte Chemie International Edition, 2020, 59 (3), pp.1232-1237. ⟨10.1002/anie.201913895⟩

Article dans une revue hal-04022181v1

Reactivity of a Molecular Calcium Hydride Cation ([CaH](+)) Supported by an NNNN Macrocycle

Danny Schuhknecht , Thomas P. Spaniol , Yan Yang , Laurent Maron , Jun Okuda

INORGANIC CHEMISTRY, 2020, 59 (13), pp.9406-9415. ⟨10.1021/acs.inorgchem.0c01289⟩

Article dans une revue hal-03925192v1

Molecular Zinc Hydride Cations [ZnH](+): Synthesis, Structure, and CO(2)Hydrosilylation Catalysis

Florian Ritter , Thomas P. Spaniol , Iskander Douair , Laurent Maron , Jun Okuda

Angewandte Chemie International Edition, 2020, 59 (51), pp.23335-23342. ⟨10.1002/anie.202011480⟩

Article dans une revue hal-03925183v1

Incorporation of Boron into Uranium Metallacycles: Synthesis, Structure, and Reactivity of Boron-Containing Uranacycles Derived from Bis(alkynyl)boranes

Wangyang Ma , Iskander Douair , Laurent Maron , Qing Ye

CHEMISTRY-A EUROPEAN JOURNAL, 2020, 26 (60), pp.13573-13577. ⟨10.1002/chem.202003611⟩

Article dans une revue hal-03925187v1

Stabilization of the Oxidation State plus IV in Siloxide-Supported Terbium Compounds

Aurelien R. Willauer , Chad T. Palumbo , Rosario Scopelliti , Ivica Zivkovic , Iskander Douair et al.

Angewandte Chemie International Edition, 2020, 59 (9), pp.3549-3553. ⟨10.1002/anie.201914733⟩

Article dans une revue hal-03925212v1
Deposit thumbnail

Stepwise Construction of Silica-supported Tantalum/Iridium Heteropolymetallic Catalysts Using Surface Organometallic Chemistry

Sébastien Lassalle , Ribal Jabbour , Iker Del rosal , Laurent Maron , Emiliano Fonda et al.

Journal of Catalysis, 2020, ⟨10.1016/j.jcat.2020.10.016⟩

Article dans une revue hal-02985281v1
Deposit thumbnail

Understanding the Multiconfigurational Ground and Excited States in Lanthanide Tetrakis Bipyridine Complexes from Experimental and CASSCF Computational Studies

Robert Halbach , Grégory Nocton , Jorge Amaro-Estrada , Laurent Maron , Corwin A Booth et al.

Inorganic Chemistry, 2019, 58 (18), pp.12083-12098. ⟨10.1021/acs.inorgchem.9b01393⟩

Article dans une revue hal-02289195v1

CS2 Reductive Coupling to Acetylenedithiolate by a Dinuclear Ytterbium(II) Complex

Davide Toniolo , Aurelien R. Willauer , Julie Andrez , Yan Yang , Rosario Scopelliti et al.

Chemistry - A European Journal, 2019, 25 (33), pp.7831-7834. ⟨10.1002/chem.201901321⟩

Article dans une revue hal-04022170v1

Divalent Ytterbium Complex-Catalyzed Homo- and Cross-Coupling of Primary Arylsilanes

Xiaojuan Liu , Li Xiang , Elisa Louyriac , Laurent Maron , Xuebing Leng et al.

Journal of the American Chemical Society, 2019, 141 (1), pp.138-142. ⟨10.1021/jacs.8b12138⟩

Article dans une revue hal-04022166v1
Deposit thumbnail

Investigation of ions hydration using molecular modeling

Johanne Teychené , Hélène Roux De-Balmann , Laurent Maron , Sylvain Galier

Journal of Molecular Liquids, 2019, 294, pp.111394. ⟨10.1016/j.molliq.2019.111394⟩

Article dans une revue hal-02325699v1

Studies on Molybdena- and Tungstenacyclobutadiene Complexes Supported by Fluoroalkoxy Ligands as Intermediates of Alkyne Metathesis

Henrike Ehrhorn , Dirk Bockfeld , Matthias Freytag , Thomas Bannenberg , Christos E. Kefalidis et al.

Organometallics, 2019, 38 (7), pp.1627-1639. ⟨10.1021/acs.organomet.9b00068⟩

Article dans une revue hal-04022180v1
Deposit thumbnail

Thorium-nitrogen multiple bonds provide evidence for pushing-from-below for early actinides

Jingzhen Du , Carlos Alvarez-Lamsfus , Elizabeth P. Wildman , Ashley J. Wooles , Laurent Maron et al.

Nature Communications, 2019, 10, ⟨10.1038/s41467-019-12206-5⟩

Article dans une revue hal-04022176v1

Efficient CO2 transformation under ambient condition by heterobimetallic rare earth complexes: Experimental and computational evidences of a synergistic effect

Liye Qu , Iker del Rosal , Qingyan Li , Yaorong Wang , Dan Yuan et al.

Journal of CO2 Utilization, 2019, 33, pp.413-418. ⟨10.1016/j.jcou.2019.07.008⟩

Article dans une revue hal-04022172v1
Deposit thumbnail

Single-site cobalt and zinc catalysts for the ring-opening polymerization of lactide

Paul Marin , M.J.-L. Tschan , P. Haquette , Thierry Roisnel , Iker Del rosal et al.

European Polymer Journal, 2019, 120, pp.109208. ⟨10.1016/j.eurpolymj.2019.08.035⟩

Article dans une revue hal-02310251v1

Supported lanthanide catalysts: Role of the grafting on the stereochemical outcome of beta-butyrolactone ROP reaction

Adrien Bathellier , Chiara Dinoi , Iker del Rosal , Laurent Maron

Abstracts of Papers of the American Chemical Society, 2019, 258

Article dans une revue hal-03925218v1

Polymerization of rac ‐Lactide Using Achiral Iron Complexes: Access to Thermally Stable Stereocomplexes

Paul Marin , Mathieu J.‐l. Tschan , Florence Isnard , Carine Robert , Pierre Haquette et al.

Angewandte Chemie International Edition, 2019, 58 (36), pp.12585-12589. ⟨10.1002/anie.201903224⟩

Article dans une revue hal-03365174v1

Reductive CO 2 Homocoupling: Synthesis of a Borylated C 3 Carbohydrate

Aurélien Béthegnies , Yannick Escudié , Nelson Nuñez‐dallos , Laure Vendier , John Hurtado et al.

ChemCatChem, 2019, 11, pp.760-765. ⟨10.1002/cctc.201801875⟩

Article dans une revue hal-02330570v1

Reductive Trimerization of CO to the Deltate Dianion Using Activated Magnesium(I) Compounds

K. Yuvaraj , Iskander Douair , Albert Paparo , Laurent Maron , Cameron Jones

Journal of the American Chemical Society, 2019, 141 (22), pp.8764-8768. ⟨10.1021/jacs.9b04085⟩

Article dans une revue hal-04022183v1
Deposit thumbnail

Thorium- and uranium-azide reductions: a transient dithorium-nitride versus isolable diuranium-nitrides

Jingzhen Du , David M. King , Lucile Chatelain , Erli Lu , Floriana Tuna et al.

Chemical Science, 2019, 10 (13), pp.3738-3745. ⟨10.1039/c8sc05473h⟩

Article dans une revue hal-04022188v1

Transition-metal-bridged bimetallic clusters with multiple uranium-metal bonds

Genfeng Feng , Mingxing Zhang , Dong Shao , Xinyi Wang , Shuao Wang et al.

Nature Chemistry, 2019, 11 (3), pp.248-253. ⟨10.1038/s41557-018-0195-4⟩

Article dans une revue hal-04022179v1

Transition metal-induced dehydrogenative coupling of zinc hydrides

Min Chen , Shengjie Jiang , Laurent Maron , Xin Xu

Dalton Transactions, 2019, 48 (6), pp.1931-1935. ⟨10.1039/c8dt04651d⟩

Article dans une revue hal-04022169v1

Alternative (kappa(1)-N:eta(6)-arene vs. kappa(2)-N,N) coordination of a sterically demanding amidinate ligand: are size and electronic structure of the Ln ion decisive factors?

Aleksei O. Tolpygin , Andrei S. Shavyrin , Anton V. Cherkasov , Georgy K. Fukin , Iker del Rosal et al.

Dalton Transactions, 2019, 48 (23), pp.8317-8326. ⟨10.1039/c9dt01162e⟩

Article dans une revue hal-04022178v1

Formation of an alpha-Diimine from Isocyanide Coupling Using Thorium(IV) and Uranium(IV) Phosphido-Methyl Complexes

Pokpong Rungthanaphatsophon , Iker del Rosal , Robert J. Ward , Sean P. Vilanova , Steven P. Kelley et al.

Organometallics, 2019, 38 (8), pp.1733-1740. ⟨10.1021/acs.organomet.9b00043⟩

Article dans une revue hal-04022184v1

Cyaarside (CAs-) and 1,3-Diarsaallendiide (AsCAs2-) Ligands Coordinated to Uranium and Generated via Activation of the Arsaethynolate Ligand (OCAs-)

Christopher J. Hoerger , Frank W. Heinemann , Elisa Louyriac , Massimo Rigo , Laurent Maron et al.

Angewandte Chemie International Edition, 2019, 58 (6), pp.1679-1683. ⟨10.1002/anie.201811332⟩

Article dans une revue hal-04022171v1
Deposit thumbnail

Grafting of a new bis-silylamido aluminum species on silica: insight from solid-state NMR into interactions with the surface

Tom Vancompernolle , Nicolas Merle , Frédéric Capet , Iker Del rosal , Laurent Maron et al.

Dalton Transactions, 2019, 48 (16), pp.5243 - 5252. ⟨10.1039/c9dt00845d⟩

Article dans une revue hal-03096927v1

Cationic magnesium hydride [MgH](+) stabilized by an NNNN-type macrocycle

Lara E. Lemmerz , Debabrata Mukherjee , Thomas P. Spaniol , Anthony Wong , Gabriel Menard et al.

Chemical Communications, 2019, 55 (22), pp.3199-3202. ⟨10.1039/c9cc00490d⟩

Article dans une revue hal-04022177v1

A Uranium Tri-Rhenium Triple Inverse Sandwich Compound

Michael A. Boreen , Trevor D. Lohrey , Guodong Rao , R. David Britt , Laurent Maron et al.

Journal of the American Chemical Society, 2019, 141 (13), pp.5144-5148. ⟨10.1021/jacs.9b01331⟩

Article dans une revue hal-04022182v1

Heterotetrametallic Re-Zn-Zn-Re Complex Generated by an Anionic Rhenium(I) beta-Diketiminate

Trevor D. Lohrey , Laurent Maron , Robert G. Bergman , John Arnold

Journal of the American Chemical Society, 2019, 141 (2), pp.800-804. ⟨10.1021/jacs.8b12494⟩

Article dans une revue hal-04022173v1

A complete series of uranium(iv) complexes with terminal hydrochalcogenido (EH) and chalcogenido (E) ligands E = O, S, Se, Te

Michael W. Rosenzweig , Julian Huemmer , Andreas Scheurer , Carlos Alvarez Lamsfus , Frank W. Heinemann et al.

Dalton Transactions, 2019, 48 (29), pp.10853-10864. ⟨10.1039/c9dt00530g⟩

Article dans une revue hal-04022174v1

A Combined Experimental and Theoretical Study of the Versatile Reactivity of an Oxocerium(IV) Complex: Concerted Versus Reductive Addition

Ludovic Castro , Yat-Ming So , Chang-Woo Cho , Rolf Lortz , Kai-Hong Wong et al.

Chemistry - A European Journal, 2019, 25 (46), pp.10834-10839. ⟨10.1002/chem.201903035⟩

Article dans une revue hal-04022190v1

A tetranuclear calcium hydride cluster with a highly symmetric [Ca4H6](2+) core

Danny Schuhknecht , Thomas P. Spaniol , Iskander Douair , Laurent Maron , Jun Okuda

Chemical Communications, 2019, 55 (98), pp.14837-14839. ⟨10.1039/c9cc08540h⟩

Article dans une revue hal-04022186v1
Deposit thumbnail

Reduction of 1,3,5,7-cyclooctatetraene by a molecular calcium hydride: an even electron polarised insertion/deprotonation mechanism

Michael S. Hill , Mary F. Mahon , Andrew S. S. Wilson , Chiara Dinoi , Laurent Maron et al.

Chemical Communications, 2019, 55 (40), pp.5732-5735. ⟨10.1039/c9cc02418b⟩

Article dans une revue hal-04022189v1

Monomeric thorium dihydrido complexes: versatile precursors to actinide metallacycles

Guorui Qin , Yang Wang , Xianghui Shi , Iker del Rosal , Laurent Maron et al.

Chemical Communications, 2019, 55 (59), pp.8560-8563. ⟨10.1039/c9cc04013g⟩

Article dans une revue hal-04022175v1

Identification of a uranium-rhodium triple bond in a heterometallic cluster

Genfeng Feng , Mingxing Zhang , Penglong Wang , Shuao Wang , Laurent Maron et al.

Proceedings of the National Academy of Sciences of the United States of America, 2019, 116 (36), pp.17654-17658. ⟨10.1073/pnas.1904895116⟩

Article dans une revue hal-04022187v1

Thermally Stable Ln(II) and Ca(II) Bis(benzhydryl) Complexes: Excellent Precatalysts for Intermolecular Hydrophosphination of C-C Multiple Bonds

Alexander N. Selikhov , Gleb S. Plankin , Anton V. Cherkasov , Andrey S. Shavyrin , Elisa Louyriac et al.

Inorganic Chemistry, 2019, 58 (8), pp.5325-5334. ⟨10.1021/acs.inorgchem.9b00490⟩

Article dans une revue hal-04022167v1
Deposit thumbnail

Magnesium hydride alkene insertion and catalytic hydrosilylation

Lucia Garcia , Chiara Dinoi , Mary F. Mahon , Laurent Maron , Michael S. Hill

Chemical Science, 2019, 10 (35), pp.8108-8118. ⟨10.1039/c9sc02056j⟩

Article dans une revue hal-04022185v1

The role of uranium-arene bonding in H2O reduction catalysis

Dominik P. Halter , Frank W. Heinemann , Laurent Maron , Karsten Meyer

Nature Chemistry, 2018, 10 (3), pp.259-267. ⟨10.1038/NCHEM.2899⟩

Article dans une revue hal-04037749v1

(C5Me5)(2)Y(mu-H)(mu-CH2C5Me4)Y(C5Me5) as a reservoir of electrons for the reduction of PhSSPh and CO2: A theoretical study

Ludovic Castro , Laurent Maron

Journal of Organometallic Chemistry, 2018, 857, pp.80-87. ⟨10.1016/j.jorganchem.2017.09.033⟩

Article dans une revue hal-04037733v1
Deposit thumbnail

Why Are Saccharides Dehydrated in the Presence of Electrolytes? Insights from Molecular Modeling and Thermodynamic Measurements

Johanne Teychené , Hélène Roux De-Balmann , Laurent Maron , Sylvain Galier

ACS Central Science, 2018, 4 (11), pp.1531-1536. ⟨10.1021/acscentsci.8b00610⟩

Article dans une revue hal-02338970v1
Deposit thumbnail

Phenylacetylene and Carbon Dioxide Activation by an Organometallic Samarium Complex

Violaine Goudy , Mathieu Xemard , Simon Karleskind , Marie Cordier , Carlos A. Lamsfus et al.

Inorganics, 2018, 6 (3), pp.82. ⟨10.3390/inorganics6030082⟩

Article dans une revue hal-01999468v1
Deposit thumbnail

Small molecule activation with divalent samarium triflate: a synergistic effort to cleave O2

Mathieu Xemard , Marie Cordier , Elisa Louyriac , Laurent Maron , Carine Clavaguera et al.

Dalton Transactions, 2018, 47 (28), pp.9226-9230. ⟨10.1039/c8dt02196a⟩

Article dans une revue hal-01999446v1

The "Wanderlust" of Me3Si groups in rare-earth triple-decker complexes: a combined experimental and computational study

Volker Lorenz , Phil Liebing , Adrien Bathelier , Felix Engelhardt , Laurent Maron et al.

Chemical Communications, 2018, 54 (73), pp.10280-10283. ⟨10.1039/c8cc05317k⟩

Article dans une revue hal-04037768v1

Formation of thorium and uranium - phosphorano - stabilized carbene

Pokpong Rungthanaphatsophon , Laurent Maron , Justin Walensky

Abstracts of Papers of the American Chemical Society, 2018, 255

Article dans une revue hal-04037762v1
Deposit thumbnail

Isolation of a TMTAA-Based Radical in Uranium bis-TMTAA Complexes

Stephan Hohloch , Mary E. Garner , Corwin H. Booth , Wayne W. Lukens , Colin A. Gould et al.

Angewandte Chemie International Edition, 2018, 57 (49), pp.16136-16140. ⟨10.1002/anie.201810971⟩

Article dans une revue hal-04037753v1

Experimental and Theoretical Studies on the Implications of Halide-Dependent Aqueous Solvation of Sm(II)

Alejandro Ramirez-Solis , Caroline O. Bartulovich , Tesia Chciuk , Jorge Hernandez-Cobos , Humberto Saint-Martin et al.

Journal of the American Chemical Society, 2018, 140 (48), pp.16731-16739. ⟨10.1021/jacs.8b09857⟩

Article dans une revue hal-04037751v1

Cerium Tetrakis(tropolonate) and Cerium Tetrakis(acetylacetonate) Are Not Diamagnetic but Temperature-Independent Paramagnets

Robert Halbach , Grégory Nocton , Corwin A Booth , Laurent Maron , Richard A Andersen

Inorganic Chemistry, 2018, 57 (12), pp.7290-7298

Article dans une revue hal-01999443v1

Scandium alkyl and hydride complexes supported by a pentadentate diborate ligand: reactions with CO2 and N2O

Daniel W. Beh , Warren E. Piers , Iker del Rosal , Laurent Maron , Benjamin S. Gelfand et al.

Dalton Transactions, 2018, 47 (38), pp.13680-13688. ⟨10.1039/c8dt03313g⟩

Article dans une revue hal-04037764v1

Substitution effects in highly syndioselective styrene polymerization catalysts based on single-component allyl ansa-lanthanidocenes: A theoretical study

Elisa Louyriac , Laurent Maron

Abstracts of Papers of the American Chemical Society, 2018, 255

Article dans une revue hal-04037740v1

Cerium Tetrakis(tropolonate) and Cerium Tetrakis(acethylacetonate) Are Not Diamagnetic but Temperature-Independent Paramagnets (vol 57, pg 7290, 2018)

Robert L. Halbach , Grégory Nocton , Corwin H. Booth , Laurent Maron , Richard A. Andersen

Inorganic Chemistry, 2018, 57 (14), pp.8692-8692. ⟨10.1021/acs.inorgchem.8b01686⟩

Article dans une revue hal-04037760v1

The Nature of the Heavy Alkaline Earth Metal-Hydrogen Bond: Synthesis, Structure, and Reactivity of a Cationic Strontium Hydride Cluster

Debabrata Mukherjee , Thomas Hoellerhage , Valeri Leich , Thomas P. Spaniol , Ulli Englert et al.

Journal of the American Chemical Society, 2018, 140 (9), pp.3403-3411. ⟨10.1021/jacs.7b13796⟩

Article dans une revue hal-04037750v1

Oxygen Atom Transfer to Cationic PCPNi(II) Complexes Using Amine-N-Oxides

Etienne A. Lapierre , Marissa L. Clapson , Warren E. Piers , Laurent Maron , Denis M. Spasyuk et al.

Inorganic Chemistry, 2018, 57 (1), pp.495-506. ⟨10.1021/acs.inorgchem.7b02766⟩

Article dans une revue hal-04037743v1
Deposit thumbnail

A Theoretical Outlook on the Stereoselectivity Origins of Isoselective Zirconocene Propylene Polymerization Catalysts

Ludovic Castro , Gabriel Theurkauff , Aurelien Vantomme , Alexandre Welle , Luc Haspeslagh et al.

Chemistry - A European Journal, 2018, 24 (42), pp.10784-10792. ⟨10.1002/chem.201801438⟩

Article dans une revue hal-01807879v1
Deposit thumbnail

Heterolysis of Dihydrogen by Nucleophilic Calcium Alkyls

Andrew S. S. Wilson , Chiara Dinoi , Michael S. Hill , Mary F. Mahon , Laurent Maron

Angewandte Chemie International Edition, 2018, 57 (47), pp.15500-15504. ⟨10.1002/anie.201809833⟩

Article dans une revue hal-04037758v1

Kinetic stabilisation of a molecular strontium hydride complex using an extremely bulky amidinate ligand

Caspar N. de Bruin-Dickason , Thomas Sutcliffe , Carlos Alvarez Lamsfus , Glen B. Deacon , Laurent Maron et al.

Chemical Communications, 2018, 54 (7), pp.786-789. ⟨10.1039/c7cc09362d⟩

Article dans une revue hal-04037746v1

Are ScC and ScP Bonds Reactive in Scandium Phosphinoalkylidene Complex? Insights on a Versatile Reactivity

Weiqing Mao , Li Xiang , Carlos Alvarez Lamsfus , Laurent Maron , Xuebing Leng et al.

Acta Chimica Sinica, 2018, 36 (10), pp.904-908. ⟨10.1002/cjoc.201800253⟩

Article dans une revue hal-04037759v1

Oxygen-Oxygen Bond Cleavage and Formation in Co(II)-Mediated Stoichiometric O-2 Reduction via the Potential Intermediacy of a Co(IV) Oxyl Radical

Lucie Nurdin , Denis M. Spasyuk , Laura Fairburn , Warren E. Piers , Laurent Maron

Journal of the American Chemical Society, 2018, 140 (47), pp.16094-16105. ⟨10.1021/jacs.8b07726⟩

Article dans une revue hal-04037765v1

Functionalization of Carbon Monoxide and tert-Butyl Nitrile by Intramolecular Proton Transfer in a Bis(Phosphido) Thorium Complex

Sean P. Vilanova , Iker del Rosal , Michael L. Tarlton , Laurent Maron , Justin R. Walensky

Angewandte Chemie International Edition, 2018, 57 (51), pp.16748-16753. ⟨10.1002/anie.201810511⟩

Article dans une revue hal-04037748v1

Side Arm Twist on Zn-Catalyzed Hydrosilylative Reduction of CO2 to Formate and Methanol Equivalents with High Selectivity and Activity

Guoqin Feng , Chongyang Du , Li Xiang , Iker del Rosal , Guangyu Li et al.

ACS Catalysis, 2018, 8 (5), pp.4710-4718. ⟨10.1021/acscatal.8b01033⟩

Article dans une revue hal-04037769v1

Monomeric Rare-Earth Metal Silyl-Thiophosphinoyl-Alkylidene Complexes: Synthesis, Structure, and Reactivity

Chen Wang , Weiqing Mao , Li Xiang , Yan Yang , Jian Fang et al.

Chemistry - A European Journal, 2018, 24 (52), pp.13903-13917. ⟨10.1002/chem.201802791⟩

Article dans une revue hal-04037766v1

Unprecedented Reaction Mode of Phosphorus in Phosphinidene Rare-Earth Complexes: A Joint Experimental-Theoretical Study

Haiwen Tian , Jianquan Hong , Kai Wang , Iker del Rosal , Laurent Maron et al.

Journal of the American Chemical Society, 2018, 140 (1), pp.102-105. ⟨10.1021/jacs.7b11032⟩

Article dans une revue hal-04037754v1
Deposit thumbnail

Chemical structure and bonding in a thorium(III)-aluminum heterobimetallic complex

Alison B. Altman , Alexandra C. Brown , Guodong Rao , Trevor D. Lohrey , R. David Britt et al.

Chemical Science, 2018, 9 (18), pp.4317-4324. ⟨10.1039/c8sc01260a⟩

Article dans une revue hal-04037761v1

Dianionic Carbon-Bridged Scandium-Copper/Silver Heterobimetallic Complexes: Synthesis, Bonding, and Reactivity

Chen Wang , Li Xiang , Yan Yang , Jian Fang , Laurent Maron et al.

Chemistry - A European Journal, 2018, 24 (21), pp.5637-5643. ⟨10.1002/chem.201706147⟩

Article dans une revue hal-04037744v1

Hydration of CH3HgOH and CH3HgCl compared to HgCl2, HgClOH, and Hg(OH)(2): A DFT microsolvation cluster approach

Jorge I. Amaro-Estrada , Jorge Hernandez-Cobos , Humberto Saint-Martin , Laurent Maron , Alejandro Ramirez-Solis

The Journal of Chemical Physics, 2018, 149 (14), ⟨10.1063/1.5038418⟩

Article dans une revue hal-04037739v1

Reversing Conventional Reactivity of Mixed Oxo/Alkyl Rare-Earth Complexes: Non-Redox Oxygen Atom Transfer

Jianquan Hong , Haiwen Tian , Lixin Zhang , Xigeng Zhou , Iker del Rosal et al.

Angewandte Chemie International Edition, 2018, 57 (4), pp.1062-1067. ⟨10.1002/anie.201711305⟩

Article dans une revue hal-04037752v1

A tetranuclear samarium(ii) inverse sandwich from direct reduction of toluene by a samarium(ii) siloxide

Rory P. Kelly , Davide Toniolo , Farzaneh Fadaei Tirani , Laurent Maron , Marinella Mazzanti

Chemical Communications, 2018, 54 (73), pp.10268-10271. ⟨10.1039/c8cc04169e⟩

Article dans une revue hal-04037741v1

Mechanism and Effect of Polar Styrenes on Scandium-Catalyzed Copolymerization with Ethylene

Bo Liu , Kening Qiao , Jian Fang , Tiantian Wang , Zichuan Wang et al.

Angewandte Chemie International Edition, 2018, 57 (45), pp.14896-14901. ⟨10.1002/anie.201808836⟩

Article dans une revue hal-04037735v1
Deposit thumbnail

Coordination of arenes and phosphines by charge separated alkaline earth cations

Lucia Garcia , Mathew D. Anker , Mary F. Mahon , Laurent Maron , Michael S. Hill

Dalton Transactions, 2018, 47 (36), pp.12684-12693. ⟨10.1039/c8dt03124j⟩

Article dans une revue hal-04037734v1
Deposit thumbnail

Steric control in the metal-ligand electron transfer of iminopyridine-ytterbocene complexes

Alexander A. Trifonov , Tatyana V. Mahrova , Lapo Luconi , Giuliano Giambastiani , Dmitry M. Lyubov et al.

Dalton Transactions, 2018, 47 (5), pp.1566-1576. ⟨10.1039/c7dt04299j⟩

Article dans une revue hal-04037757v1

Aqueous Solvation of SmI3: A Born-Oppenheimer Molecular Dynamics Density Functional Theory Cluster Approach

Alejandro Ramirez-Solis , Jorge Ivan Amaro-Estrada , Jorge Hernandez-Cobos , Laurent Maron

Inorganic Chemistry, 2018, 57 (5), pp.2843-2850. ⟨10.1021/acs.inorgchem.7b03220⟩

Article dans une revue hal-04037763v1

Dinitrogen functionalization at a ditantalum center. Balancing N-2 displacement and N-2 functionalization in the reaction of coordinated N-2 with CS2

Richard J. Burford , Ludovic Castro , Laurent Maron , Jason E. Hein , Michael D. Fryzuk

Dalton Transactions, 2018, 47 (24), pp.7983-7991. ⟨10.1039/c8dt01615a⟩

Article dans une revue hal-04037742v1

Synthesis and Reactions of [Cp*Yb-2](2)(mu-Me) and [Cp*Yb-2](2)(mu-Me)(Me) and Related Yb-2(II, III) and Yb-2(III, III) Compounds

Marc D. Walter , Philip T. Matsunaga , Carol J. Burns , Laurent Maron , Richard A. Andersen

Organometallics, 2017, 36 (23), pp.4564--4578

Article dans une revue hal-01961151v1

Formation of Methane versus Benzene in the Reactions of (C5Me5)(2)Th(CH3)(2) with [CH3PPh3]X (X=Cl, Br, I) Yielding Thorium-Carbene or Thorium-Ylide Complexes

Pokpong Rungthanaphatsophon , Adrien Bathelier , Ludovic Castro , Andrew C. Behrle , Charles L. Barnes et al.

Angewandte Chemie International Edition, 2017, 56 (42), pp.12925-12929. ⟨10.1002/anie.201706496⟩

Article dans une revue hal-01961160v1
Deposit thumbnail

Inner-sphere vs. outer-sphere reduction of uranyl supported by a redox-active, donor-expanded dipyrrin

James R. Pankhurst , Nicola L. Bell , Markus Zegke , Lucy N. Platts , Carlos A. Lamsfus et al.

Chemical Science, 2017, 8 (1), pp.108-116. ⟨10.1039/c6sc02912d⟩

Article dans une revue hal-01961185v1
Deposit thumbnail

Silica-Grafted Lanthanum Benzyl Species: Synthesis, Characterization, and Catalytic Applications

Tom Vancompernolle , Andreia Valente , Thomas Chenal , Philippe Zinck , Iker Del rosal et al.

Organometallics, 2017, 36 (20), pp.3912 - 3920. ⟨10.1021/acs.organomet.7b00538⟩

Article dans une revue hal-01872744v1
Deposit thumbnail

Organocalcium-mediated nucleophilic alkylation of benzene

Andrew Wilson , Michael Hill , Mary Mahon , Chiara Dinoi , Laurent Maron

Science, 2017, 358 (6367), pp.1168-1171. ⟨10.1126/science.aao5923⟩

Article dans une revue hal-01961155v1

Efficient Reduction of Carbon Dioxide to Methanol Equivalents Catalyzed by Two-Coordinate Amido-Germanium(II) and -Tin(II) Hydride Complexes

Terrance J. Hadlington , Christos E. Kefalidis , Laurent Maron , Cameron Jones

ACS Catalysis, 2017, 7 (3), pp.1853--1859

Article dans une revue hal-01961178v1
Deposit thumbnail

A Structurally Characterized Organometallic Plutonium(IV) Complex

Christos Apostolidis , Olaf Walter , Jochen Vogt , Phil Liebing , Laurent Maron et al.

Angewandte Chemie International Edition, 2017, 56 (18), pp.5066-5070. ⟨10.1002/anie.201701858⟩

Article dans une revue hal-01961171v1

Reversible Insertion of a C = C Bond into Magnesium(I) Dimers: Generation of Highly Active 1,2-Dimagnesioethane Compounds

Aaron J. Boutland , Ashlea Carroll , Carlos A. Lamsfus , Andreas Stasch , Laurent Maron et al.

Journal of the American Chemical Society, 2017, 139 (50), pp.18190-18193. ⟨10.1021/jacs.7b11368⟩

Article dans une revue hal-01961149v1

Aqueous Solvation of SmI2: A Born-Oppenheimer Molecular Dynamics Density Functional Theory Cluster Approach

A. Ramirez-Solis , J. I. Amaro-Estrada , J. Hernandez-Cobos , Laurent Maron

Journal of Physical Chemistry A, 2017, 121 (11), pp.2293--2297

Article dans une revue hal-01961176v1

Reactions of Neutral Cobalt(II) Complexes of a Dianionic Tetrapodal Pentadentate Ligand: Cobalt(III) Amides from Imido Radicals

Lucie Nurdin , Denis M. Spasyuk , Warren E. Piers , Laurent Maron

Inorganic Chemistry, 2017, 56 (7), pp.4157--4168

Article dans une revue hal-01961174v1

Incipient class II mixed valency in a plutonium solid-state compound

Samantha K. Cary , Shane S. Galley , Matthew L. Marsh , David L. Hobart , Ryan E. Baumbach et al.

Nature Chemistry, 2017, 9 (9), pp.856--861

Article dans une revue hal-01961164v1

Synthesis and Reactivity of a Scandium Terminal Hydride: H-2 Activation by a Scandium Terminal Imido Complex

Xianghao Han , Li Xiang , Carlos A. Lamsfus , Weiqing Mao , Erli Lu et al.

Chemistry - A European Journal, 2017, 23 (59), pp.14728--14732

Article dans une revue hal-01961159v1
Deposit thumbnail

Evidence for single metal two electron oxidative addition and reductive elimination at uranium

Benedict M. Gardner , Christos E. Kefalidis , Erli Lu , Dipti Patel , Eric J. L. Mcinnes et al.

Nature Communications, 2017, 8, ⟨10.1038/s41467-017-01363-0⟩

Article dans une revue hal-01961154v1

Hydrodeoxygenation of isocyanates: snapshots of a magnesium-mediated C=O bond cleavage

Yan Yang , Mathew D. Anker , Jian Fang , Mary F. Mahon , Laurent Maron et al.

Chemical Science, 2017, 8 (5), pp.3529-3537. ⟨10.1039/c7sc00117g⟩

Article dans une revue hal-01961169v1

Bulky Ytterbium Formamidinates Stabilise Complexes with Radical Ligands, and Related Samarium \textquotedblleftTetracyclone\textquotedblright Chemistry

Daniel Werner , Xuefei Zhao , Stephen P. Best , Laurent Maron , Peter C. Junk et al.

Chemistry - A European Journal, 2017, 23 (9), pp.2084--2102

Article dans une revue hal-01961180v1

Mechanistic Aspects of the Polymerization of Lactide Using a Highly Efficient Aluminum(III) Catalytic System

Carine Robert , Thibault E. Schmid , Vincent Richard , Pierre Haquette , Sumesh K. Raman et al.

Journal of the American Chemical Society, 2017, 139 (17), pp.6217--6225. ⟨10.1021/jacs.7b01749.s001⟩

Article dans une revue hal-01961168v1
Deposit thumbnail

Substitution Effects in Highly Syndioselective Styrene Polymerization Catalysts Based on Single-Component Allyl ansa-Lanthanidocenes: An Experimental and Theoretical Study

Eva Laur , Elisa Louyriac , Vincent Dorcet , Alexandre Welle , Aurélien Vantomme et al.

Macromolecules, 2017, 50 (17), pp.6539-6551. ⟨10.1021/acs.macromol.7b00853⟩

Article dans une revue hal-01614773v1

Molecular and Electronic Structures of Eight-Coordinate Uranium Bipyridine Complexes: A Rare Example of a Bipy(2-) Ligand Coordinated to a U4+ Ion

Michael W. Rosenzweig , Frank W. Heinemann , Laurent Maron , Karsten Meyer

Inorganic Chemistry, 2017, 56 (5), pp.2792--2800

Article dans une revue hal-01961177v1

SO2 and SO3 reactions with [(C5Me5)(2)Sm-O-Sm (C5Me5)(2)]: a DFT investigation and comparison with CO2 reactivity

Elisa Louyriac , Peter W. Roesky , Laurent Maron

Dalton Transactions, 2017, 46 (24), pp.7660--7663

Article dans une revue hal-01961167v1

Reductive Disproportionation of CO2 with Bulky Divalent Samarium Complexes

Mathieu Xemard , Violaine Goudy , Augustin Braun , Maxime Tricoire , Marie Cordier et al.

Organometallics, 2017, 36 (23), pp.4660--4668. ⟨10.1021/acs.organomet.7b00630⟩

Article dans une revue hal-01961152v1

Electronic Structure and Properties of Berkelium Iodates

Mark A. Silver , Samantha K. Cary , Alejandro J. Garza , Ryan E. Baumbach , Alexandra A. Arico et al.

Journal of the American Chemical Society, 2017, 139 (38), pp.13361-13375. ⟨10.1021/jacs.7b05569⟩

Article dans une revue hal-01961162v1

Nonchelated Phosphoniomethylidene Complexes of Scandium and Lutetium

Weiqing Mao , Li Xiang , Laurent Maron , Xuebing Leng , Yaofeng Chen

Journal of the American Chemical Society, 2017, 139 (49), pp.17759--17762

Article dans une revue hal-01961150v1

Half-Sandwich Alkyl, Amido, and Iodo Samarium(II) Complexes: Non-Conventional Sterically Governed Oxidation of (tBu(4)Carb)(2)Sm

Alexander N. Selikhov , Tatyana V. Mahrova , Anton V. Cherkasov , Georgy K. Fukin , Laurent Maron et al.

Chemistry - A European Journal, 2017, 23 (6), pp.1436--1443

Article dans une revue hal-01961184v1
Deposit thumbnail

Understanding the Scarcity of Thorium Peroxide Clusters

Shane S. Galley , Cayla E. van Alstine , Laurent Maron , Thomas E. Albrecht-Schmitt

Inorganic Chemistry, 2017, 56 (21), pp.12692-12694. ⟨10.1021/acs.inorgchem.7b02216⟩

Article dans une revue hal-01961158v1

Formation of a Uranium-Bound eta(1)-Cyaphide (CP-) Ligand via Activation and C-O Bond Cleavage of Phosphaethynolate (OCP-)

Christopher J. Hoerger , Frank W. Heinemann , Elisa Louyriac , Laurent Maron , Hansjoerg Gruetzmacher et al.

Organometallics, 2017, 36 (22), pp.4351--4354

Article dans une revue hal-01961156v1

Reduction of a Cerium(III) Siloxide Complex To Afford a Quadruple-Decker Arene-Bridged Cerium(II) Sandwich

Rory P. Kelly , Laurent Maron , Rosario Scopelliti , Marinella Mazzanti

Angewandte Chemie International Edition, 2017, 56 (49), pp.15663--15666

Article dans une revue hal-01961153v1
Deposit thumbnail

Terminal Uranium(V/VI) Nitride Activation of Carbon Dioxide and Carbon Disulfide: Factors Governing Diverse and Well-Defined Cleavage and Redox Reactions

Peter A. Cleaves , Christos E. Kefalidis , Benedict M. Gardner , Floriana Tuna , Eric J. L. Mcinnes et al.

Chemistry - A European Journal, 2017, 23 (12), pp.2950-2959. ⟨10.1002/chem.201605620⟩

Article dans une revue hal-01961181v1
Deposit thumbnail

Metathesis of a U-V imido complex: a route to a terminal U-V sulfide

Rory P. Kelly , Marta Falcone , Carlos A. Lamsfus , Rosario Scopelliti , Laurent Maron et al.

Chemical Science, 2017, 8 (8), pp.5319-5328. ⟨10.1039/c7sc01111c⟩

Article dans une revue hal-01961165v1
Deposit thumbnail

Alkaline Earth-Centered CO Homologation, Reduction, and Amine Carbonylation

Mathew D. Anker , Christos E. Kefalidis , Yan Yang , Jian Fang , Michael S. Hill et al.

Journal of the American Chemical Society, 2017, 139 (29), pp.10036-10054. ⟨10.1021/jacs.7b04926⟩

Article dans une revue hal-01961166v1

Reactivity studies on [Cp ` Fe(mu-I)](2): nitrido-, sulfido- and diselenide iron complexes derived from pseudohalide activation

Matthias Reiners , Miyuki Maekawa , Constantin G. Daniliuc , Matthias Freytag , Peter G. Jones et al.

Chemical Science, 2017, 8 (5), pp.4108-4122. ⟨10.1039/c7sc00570a⟩

Article dans une revue hal-01961170v1

Samarium-Catalyzed Diastereoselective Double Addition of Phenylphosphine to Imines and Mechanistic Studies by DFT Calculations

Jianfeng Li , Carlos A. Lamsfus , Changhong Song , Jinxi Liu , Guilan Fan et al.

ChemCatChem, 2017, 9 (8), pp.1368--1372

Article dans une revue hal-01961172v1
Deposit thumbnail

Gold(I)-Catalysed Asymmetric Hydroamination of Alkenes: A Silver- and Solvent-Dependent Enantiodivergent Reaction

Marc-Antoine Abadie , Xavier Trivelli , Florian Medina , Nathalie Duhal , Mostafa Kouach et al.

Chemistry - A European Journal, 2017, 23 (45), pp.10777 - 10788. ⟨10.1002/chem.201701301⟩

Article dans une revue hal-01663092v1
Deposit thumbnail

Accessing Stable Magnesium Acyl Compounds: Reductive Cleavage of Esters by Magnesium(I) Dimers

Aaron J. Boutland , Carlos A. Lamsfus , Brant Maitland , Laurent Maron , Andreas Stasch et al.

Chemistry - A European Journal, 2017, 23 (56), pp.14049-14055. ⟨10.1002/chem.201703061⟩

Article dans une revue hal-01961161v1

Valorization of CO2: Preparation of 2-Oxazolidinones by Metal-Ligand Cooperative Catalysis with SCS lndenediide Pd Complexes

Paul Brunel , Julien Monot , Christos E. Kefalidis , Laurent Maron , Blanca Martin-Vaca et al.

ACS Catalysis, 2017, 7 (4), pp.2652-2660. ⟨10.1021/acscatal.7b00209⟩

Article dans une revue hal-01961175v1

Calcium Hydride Cation [CaH](+) Stabilized by an NNNN-type Macrocyclic Ligand: A Selective Catalyst for Olefin Hydrogenation

Danny Schuhknecht , Carolin Lhotzky , Thomas P. Spaniol , Laurent Maron , Jun Okuda

Angewandte Chemie International Edition, 2017, 56 (40), pp.12367--12371

Article dans une revue hal-01961163v1

Highly Reactive Scandium Phosphinoalkylidene Complex: C-H and H-H Bonds Activation

Weiqing Mao , Li Xiang , Carlos A. Lamsfus , Laurent Maron , Xuebing Leng et al.

Journal of the American Chemical Society, 2017, 139 (3), pp.1081--1084

Article dans une revue hal-01961182v1
Deposit thumbnail

Synthesis and reactivity of a terminal uranium(IV) sulfide supported by siloxide ligands

Julie Andrez , Jacques Pécaut , Rosario Scopelliti , Christos E. Kefalidis , Laurent Maron et al.

Chemical Science, 2016, 7 (9), pp.5846-5856. ⟨10.1039/C6SC00675B⟩

Article dans une revue hal-01979899v1

Carbon-Nitrogen Bond Cleavage by a Thorium-NHC-bpy Complex

Mary Garner , Stephan Hohloch , Laurent Maron , John Arnold

Angewandte Chemie International Edition, 2016, 55 (44), pp.13789-13792

Article dans une revue hal-01968816v1

Activation of Heteroallenes CO x S 2- x ( x = 0-2): Experimental and Theoretical Evidence of the Synthetic Versatility of a Bulky Guanidinato Sm II Complex

Ludovic Castro , David Mills , Cameron Jones , Laurent Maron

European Journal of Inorganic Chemistry, 2016, 2016 (6), pp.792-796

Article dans une revue hal-01968747v1

Effects of the Grafting of Lanthanum Complexes on a Silica Surface on the Reactivity: Influence on Ethylene, Propylene, and 1,3-Butadiene Homopolymerization

Iker Del rosal , Ahmed Yahia , Laurent Maron

Inorganic Chemistry, 2016, 55 (20), pp.10024-10033

Article dans une revue hal-01968797v1

Mechanistic insights from theory on the reduction of CO 2 , N 2 O, and SO 2 molecules using tripodal diimine-enolate substituted magnesium( i ) dimers

Christos E. Kefalidis , Cameron Jones , Laurent Maron

Dalton Transactions, 2016, 45 (37), pp.14789-14800

Article dans une revue hal-01968870v1

Insights into the Cascade Reaction of CO and Heteroallenes Mediated by Dinitrogen Hafnocene Complexes: The Indirect Effect of Nitride's Nucleophilicity

Christos E. Kefalidis , Laurent Maron

Chemistry - A European Journal, 2016, 22 (14), pp.4743-4747

Article dans une revue hal-01968872v1

Reductive disproportionation of nitric oxide mediated by low-valent uranium

Christopher Hoerger , Henry La Pierre , Laurent Maron , Andreas Scheurer , Frank Heinemann et al.

Chemical Communications, 2016, 52 (72), pp.10854-10857. ⟨10.1039/c6cc06095a⟩

Article dans une revue hal-01968833v1
Deposit thumbnail

A case study of proton shuttling in palladium catalysis

Julien Monot , Paul Brunel , Christos E. Kefalidis , Noel Ángel Espinosa-Jalapa , Laurent Maron et al.

Chemical Science, 2016, 7 (3), pp.2179-2187. ⟨10.1039/c5sc04232a⟩

Article dans une revue hal-01968887v1

New perspectives in organolanthanide chemistry from redox to bond metathesis: insights from theory

Christos E. Kefalidis , Ludovic Castro , Iker Del rosal , Laurent Maron , Lionel Perrin

Chemical Society Reviews, 2016, 45 (9), pp.2516-2543

Article dans une revue hal-01968866v1

Silica-Supported Tungsten Neosilyl Oxo Precatalysts: Impact of the Podality on Activity and Stability in Olefin Metathesis

D. Grekov , Y. Bouhoute , K. Szeto , Nicolas Merle , A. de Mallmann et al.

Organometallics, 2016, 35 (13), pp.2188-2196. ⟨10.1021/acs.organomet.6b00220⟩

Article dans une revue hal-01968826v1

The role of H 2 O in the electron transfer-activation of substrates using SmI 2 : insights from DFT

Xuefei Zhao , Lionel Perrin , David Procter , Laurent Maron

Dalton Transactions, 2016, 45 (9), pp.3706-3710

Article dans une revue hal-01969001v1

The Nature of Secondary Interactions at Electrophilic Metal Sites of Molecular and Silica-Supported Organolutetium Complexes from Solid-State NMR Spectroscopy.

Matthew P Conley , Giuseppe Lapadula , Kevin Sanders , David Gajan , Anne Lesage et al.

Journal of the American Chemical Society, 2016, 138 (11), pp.3831-3843. ⟨10.1021/jacs.6b00071⟩

Article dans une revue hal-01546479v1

Two-coordinate terminal zinc hydride complexes: synthesis, structure and preliminary reactivity studies

Michael Dawkins , Ewart Middleton , Christos E. Kefalidis , Deepak Dange , Martin Juckel et al.

Chemical Communications, 2016, 52 (69), pp.10490-10492

Article dans une revue hal-01968783v1

17 O MAS NMR studies of oxo-based olefin metathesis catalysts: a critical assessment of signal enhancement methods

D. Grekov , Y. Bouhoute , Iker Del rosal , Laurent Maron , M. Taoufik et al.

Physical Chemistry Chemical Physics, 2016, 18 (40), pp.28157-28163. ⟨10.1039/C6CP04667C⟩

Article dans une revue hal-01968823v1
Deposit thumbnail

Versatile coordination of a reactive P,N-ligand toward boron, aluminum and gallium and interconversion reactivity

M. Devillard , Carlos A. Lamsfus , V. Vreeken , Laurent Maron , J. I van Der Vlugt

Dalton Transactions, 2016, 45 (27), pp.10989-10998. ⟨10.1039/c6dt02087a⟩

Article dans une revue hal-01968804v1

A New Supporting Ligand in Actinide Chemistry Leads to Reactive Bis(NHC)borate-Supported Thorium Complexes

Mary Garner , Stephan Hohloch , Laurent Maron , John Arnold

Organometallics, 2016, 35 (17), pp.2915-2922

Article dans une revue hal-01968815v1
Deposit thumbnail

Uranium( iv ) terminal hydrosulfido and sulfido complexes: insights into the nature of the uranium–sulfur bond

Michael W Rosenzweig , Andreas Scheurer , Carlos A. Lamsfus , Frank Heinemann , Laurent Maron et al.

Chemical Science, 2016, 7 (9), pp.5857-5866. ⟨10.1039/c6sc00677a⟩

Article dans une revue hal-01968915v1

Two-Coordinate Magnesium(I) Dimers Stabilized by Super Bulky Amido Ligands

Aaron Boutland , Deepak Dange , Andreas Stasch , Laurent Maron , Cameron Jones

Angewandte Chemie International Edition, 2016, 55 (32), pp.9239-9243

Article dans une revue hal-01968739v1

Facile CO Cleavage by a Multimetallic CsU 2 Nitride Complex

Marta Falcone , Christos E. Kefalidis , Rosario Scopelliti , Laurent Maron , Marinella Mazzanti

Angewandte Chemie International Edition, 2016, 55 (40), pp.12290-12294

Article dans une revue hal-01968807v1

Characterization of berkelium(III) dipicolinate and borate compounds in solution and the solid state

M. A Silver , S. K Cary , J. Johnson , R. E Baumbach , A. A Arico et al.

Science, 2016, 353 (6302), pp.aaf3762-aaf3762. ⟨10.1126/science.aaf3762⟩

Article dans une revue hal-01968947v1

The role of H2O in the electron transfer-activation of substrates using Sml2 : a theoretical study

Xuefei Zhao , L Perrin , Dj Procter , Laurent Maron

Dalton Transactions, 2016, 45 (9), pp.3706-3710. ⟨10.1039/C6DT00241B⟩

Article dans une revue hal-01484013v1

Modification of silica-supported tungsten neosilyl oxo precatalysts: impact of substituted phenol on activity and stability in olefin metathesis

Yassine Bouhoute , Iker Del rosal , K. Szeto , Nicolas Merle , D. Grekov et al.

Catalysis Science & Technology, 2016, 6 (24), pp.8532-8539

Article dans une revue hal-01968728v1

Non-Pincer-Type Mononuclear Scandium Alkylidene Complexes: Synthesis, Bonding, and Reactivity

Chen Wang , Jiliang Zhou , Xuefei Zhao , Laurent Maron , Xuebing Leng et al.

Chemistry - A European Journal, 2016, 22 (4), pp.1258-1261

Article dans une revue hal-01968987v1

Molecular Calcium Hydride: Dicalcium Trihydride Cation Stabilized by a Neutral NNNN-Type Macrocyclic Ligand

Valeri Leich , Thomas Spaniol , Laurent Maron , Jun Okuda

Angewandte Chemie International Edition, 2016, 55 (15), pp.4794-4797

Article dans une revue hal-01968880v1

Yb(II) Triple-Decker Complex with the μ-Bridging Naphthalene Dianion [CpBn5Yb(DME)]2(μ-η4:η4-C10H8). Oxidative Substitution of [C10H8]2- by 1,4-Diphenylbuta-1,3-diene and P4 and Protonolysis of the Yb-C10H8 Bond by PhPH2

A.N. Selikhov , T.V. Mahrova , A.V. Cherkasov , G.K. Fukin , E. Kirillov et al.

Organometallics, 2016, 35 (14), pp.2401--2409. ⟨10.1021/acs.organomet.6b00428⟩

Article dans une revue hal-01367220v1
Deposit thumbnail

Activation of SO 2 by [Zn(Cp*) 2 ] and [(Cp*)Zn I –Zn I (Cp*)]

Rory P Kelly , Neda Kazeminejad , Carlos A. Lamsfus , Laurent Maron , Peter Roesky

Chemical Communications, 2016, 52 (89), pp.13090-13093. ⟨10.1039/c6cc05638e⟩

Article dans une revue hal-01968877v1
Deposit thumbnail

Facile hydrogen atom transfer to iron( iii ) imido radical complexes supported by a dianionic pentadentate ligand

Denis M Spasyuk , Stephanie H Carpenter , Christos E. Kefalidis , Warren E Piers , Michael L. Neidig et al.

Chemical Science, 2016, 7 (9), pp.5939-5944. ⟨10.1039/c6sc01433j⟩

Article dans une revue hal-01968953v1

Actinide-Catalyzed Intermolecular Addition of Alcohols to Carbodiimides

Rami Batrice , Christos E. Kefalidis , Laurent Maron , Moris Eisen

Journal of the American Chemical Society, 2016, 138 (7), pp.2114-2117

Article dans une revue hal-01968720v1

Concomitant Carboxylate and Oxalate Formation From the Activation of CO 2 by a Thorium(III) Complex

Alasdair Formanuik , Fabrizio Ortu , Christopher Inman , Andrew Kerridge , Ludovic Castro et al.

Chemistry - A European Journal, 2016, 22 (50), pp.17976-17979

Article dans une revue hal-01968810v1

Formation and Reactivity of a Molecular Magnesium Hydride with a Terminal Mg—H Bond

Silvia Schnitzler , Thomas Spaniol , Laurent Maron , Jun Okuda

Chemistry - A European Journal, 2015, 21 (32), pp.11330-11334

Article dans une revue hal-01968831v1
Deposit thumbnail

Ultrathin Gold Nanowires: Soft-Templating versus Liquid Phase Synthesis, a Quantitative Study

Anais Loubat , Lise-Marie Lacroix , Antoine Robert , Marianne Imperor-Clerc , Romuald Poteau et al.

Journal of Physical Chemistry C, 2015, 119 (8), pp.4422-4430. ⟨10.1021/acs.jpcc.5b00242⟩

Article dans une revue hal-02020268v1

Amido Analogues of Nonbent Lanthanide (II) and Calcium Metallocenes. Heterolytic Cleavage of π-Bond Ln–Carbazolyl Ligand Promoted by Lewis Base Coordination

Alexander Selikhov , Anton Cherkasov , Georgy Fukin , Alexander A. Trifonov , Iker Del rosal et al.

Organometallics, 2015, 34 (3), pp.555-562

Article dans une revue hal-01968821v1

A Mixed-Valence Tri-Zinc Complex, [LZnZnZnL] (L=Bulky Amide), Bearing a Linear Chain of Two-Coordinate Zinc Atoms

Jamie Hicks , Emma J. Underhill , Christos E. Kefalidis , Laurent Maron , Cameron Jones

Angewandte Chemie International Edition, 2015, 54 (34), pp.10000-10004

Article dans une revue hal-01969079v1

Control of Oxo-Group Functionalization and Reduction of the Uranyl Ion

Polly Arnold , Anne-Frédérique Pécharman , Rianne Lord , Guy Jones , Emmalina Hollis et al.

Inorganic Chemistry, 2015, 54 (7), pp.3702-3710

Article dans une revue hal-01969412v1

Structure vs 119Sn NMR Chemical Shift in Three-Coordinated Tin(II) Complexes: Experimental Data and Predictive DFT Computations

Lingfang Wang , Christos E. Kefalidis , Thierry Roisnel , Sourisak Sinbandhit , Laurent Maron et al.

Organometallics, 2015, 34 (11), pp.2139-2150. ⟨10.1021/om5007566⟩

Article dans une revue hal-01114324v1
Deposit thumbnail

On the Dehydrocoupling of Alkenylacetylenes Mediated by Various Samarocene Complexes: A Charming Story of Metal Cooperativity Revealing a Novel Dual Metal σ-Bond Metathesis Type of Mechanism (DM|σ-BM)

Christos E. Kefalidis , Laurent Maron

Inorganics, 2015, 3 (4), pp.573-588. ⟨10.3390/inorganics3040573⟩

Article dans une revue hal-01969047v1

Hydroboration of Carbon Dioxide Using Ambiphilic Phosphine–Borane Catalysts: On the Role of the Formaldehyde Adduct

Richard Declercq , Ghenwa Bouhadir , Didier Bourissou , Marc-André Légaré , Marc-André Courtemanche et al.

ACS Catalysis, 2015, 5 (4), pp.2513-2520

Article dans une revue hal-01969164v1
Deposit thumbnail

CO2 conversion to isocyanate via multiple N-Si bond cleavage at a bulky uranium(III) complex

Clément Camp , Lucile Chatelain , Christos E. Kefalidis , Jacques Pécaut , Laurent Maron et al.

Chemical Communications, 2015, 51 (84), pp.15454-15457. ⟨10.1039/c5cc06707c⟩

Article dans une revue hal-01588142v1

A Dimetalloxycarbene Bonding Mode and Reductive Coupling Mechanism for Oxalate Formation from CO 2

Albert Paparo , Jared Silvia , Christos E. Kefalidis , Thomas Spaniol , Laurent Maron et al.

Angewandte Chemie International Edition, 2015, 54 (31), pp.9115-9119

Article dans une revue hal-01968885v1
Deposit thumbnail

Grafting of lanthanide complexes on silica surfaces dehydroxylated at 200 °C: a theoretical investigation

Iker Del rosal , I.C. Gerber , Romuald Poteau , Laurent Maron

New Journal of Chemistry, 2015, 39 (10), pp.7703-7715

Article dans une revue hal-01969145v1

Calcium Hydride Catalyzed Highly 1,2-Selective Pyridine Hydrosilylation

Julia Intemann , Heiko Bauer , Jürgen Pahl , Laurent Maron , Sjoerd Harder

Chemistry - A European Journal, 2015, 21 (32), pp.11452-11461

Article dans une revue hal-01969068v1

Enantiospecific C-H activation using ruthenium nanocatalysts

Céline Taglang , Luis Miguel Martinez-Pietro , Iker Del rosal , Laurent Maron , Romuald Poteau et al.

Angewandte Chemie International Edition, 2015, 54 (36), pp.10474-10477. ⟨10.1002/anie.201504554⟩

Article dans une revue istex hal-01920824v1

Formation of a Bridging Phosphinidene Thorium Complex

Andrew Behrle , Ludovic Castro , Laurent Maron , Justin Walensky

Journal of the American Chemical Society, 2015, 137 (47), pp.14846-14849

Article dans une revue hal-01969408v1
Deposit thumbnail

DFT investigations on the ring-opening polymerization of substituted cyclic carbonates catalyzed by zinc-{β-diketiminate} complexes

Iker Del rosal , Pierre Brignou , Sophie M. Guillaume , Jean-François Carpentier , Laurent Maron

Polymer Chemistry, 2015, 6 (17), pp.3336--3352. ⟨10.1039/C5PY00313J⟩

Article dans une revue hal-01154160v1

Discrete Magnesium Hydride Aggregates: A Cationic Mg 13 H 18 Cluster Stabilized by NNNN-Type Macrocycles

Daniel Martin , Klaus Beckerle , Silvia Schnitzler , Thomas Spaniol , Laurent Maron et al.

Angewandte Chemie International Edition, 2015, 54 (13), pp.4115-4118

Article dans une revue hal-01968889v1

Early Main Group Metal Catalysis: How Important is the Metal?

Johanne Penafiel , Laurent Maron , Sjoerd Harder

Angewandte Chemie International Edition, 2015, 54 (1), pp.201-206

Article dans une revue hal-01968875v1
Deposit thumbnail

Can a pentamethylcyclopentadienyl ligand act as a proton-relay in f-element chemistry? Insights from a joint experimental/theoretical study

Christos E. Kefalidis , Lionel Perrin , Carol J. Burns , David J. Berg , Laurent Maron et al.

Dalton Transactions, 2015, 44 (6), pp.2575-2587. ⟨10.1039/C4DT02387K⟩

Article dans une revue hal-01969038v1

Accessing Realistic Models for the WO 3 –SiO 2 Industrial Catalyst through the Design of Organometallic Precursors

Y. Bouhoute , D. Grekov , K. Szeto , Nicolas Merle , A. de Mallmann et al.

ACS Catalysis, 2015, ACS Catalysis, 6 (1), pp.1-18. ⟨10.1021/acscatal.5b01744⟩

Article dans une revue hal-01968734v1

Metallacyclic yttrium alkyl and hydrido complexes: synthesis, structures and catalytic activity in intermolecular olefin hydrophosphination and hydroamination

Alexander A. Kissel , Tatyana V. Mahrova , Dmitry M. Lyubov , Anton V. Cherkasov , Georgy K. Fukin et al.

Dalton Transactions, 2015, 44 (27), pp.12137-12148

Article dans une revue hal-01969009v1
Deposit thumbnail

A Scandium Complex Bearing Both Methylidene and Phosphinidene Ligands: Synthesis, Structure, and Reactivity

Jiliang Zhou , Tengfei Li , Laurent Maron , Xuebing Leng , Yaofeng Chen

Organometallics, 2015, 34 (2), pp.470-476. ⟨10.1021/om500997j⟩

Article dans une revue hal-01968713v1

Activation of CO by Hydrogenated Magnesium(I) Dimers: Sterically Controlled Formation of Ethenediolate and Cyclopropanetriolate Complexes

Ralte Lalrempuia , Christos E. Kefalidis , Simon J. Bonyhady , Benedikt Schwarze , Laurent Maron et al.

Journal of the American Chemical Society, 2015, 137 (28), pp.8944-8947

Article dans une revue hal-01968965v1

Yttrium Dihydride Cation [YH 2 (THF) 2 ] + n : Aggregate Formation and Reaction with (NNNN)-Type Macrocycles

Stefan Arndt , Mathias Kramer , Waldemar Fegler , Yumiko Nakajima , Iker Del rosal et al.

Organometallics, 2015, 34 (15), pp.3739-3747

Article dans une revue hal-01969418v1

Coordination of a Triphosphine–Silane to Gold: Formation of a Trigonal Pyramidal Complex Featuring Au + →Si Interaction

Pauline Gualco , Sonia Mallet-Ladeira , Hajime Kameo , Hiroshi Nakazawa , Maxime Mercy et al.

Organometallics, 2015, 34 (8), pp.1449-1453

Article dans une revue hal-01969121v1

Thorium Mono- and Bis(imido) Complexes Made by Reprotonation of cyclo -Metalated Amides

Nicola Bell , Laurent Maron , Polly Arnold

Journal of the American Chemical Society, 2015, 137 (33), pp.10492-10495

Article dans une revue hal-01969404v1
Deposit thumbnail

Uranium and thorium complexes of the phosphaethynolate ion

Clément Camp , Nicholas Settineri , Julia Lefèvre , Andrew R Jupp , José M Goicoechea et al.

Chemical Science, 2015, 6 (11), pp.6379--6384. ⟨10.1039/c5sc02150b⟩

Article dans une revue hal-01877473v1

Synthesis and Reactivity of Palladium Complexes Featuring a Diphosphinoborane Ligand

Tobias Schindler , Marcel Lux , Marius Peters , Lennart Scharf , Hassan Osseili et al.

Organometallics, 2015, 34 (10), pp.1978-1984

Article dans une revue hal-01968865v1

Activation of White Phosphorus by Low-Valent Group 5 Complexes: Formation and Reactivity of cyclo-P4 Inverted Sandwich Compounds

Clément Camp , Laurent Maron , Robert G Bergman , John Arnold

Journal of the American Chemical Society, 2014, 136 (50), pp.17652--17661

Article dans une revue hal-01877475v1

Reducing CO 2 to Methanol Using Frustrated Lewis Pairs: On the Mechanism of Phosphine–Borane-Mediated Hydroboration of CO 2

Marc-André Courtemanche , Marc-André Légaré , Laurent Maron , Frédéric-Georges Fontaine

Journal of the American Chemical Society, 2014, 136 (30), pp.10708-10717

Article dans une revue hal-01969448v1

Lewis Acid Triggered Reactivity of a Lewis Base Stabilized Scandium-Terminal Imido Complex: C–H Bond Activation, Cycloaddition, and Dehydrofluorination

Jiaxiang Chu , Xianghao Han , Christos E. Kefalidis , Jiliang Zhou , Laurent Maron et al.

Journal of the American Chemical Society, 2014, 136 (31), pp.10894-10897

Article dans une revue hal-01969441v1

Computational insights into carbon–carbon homocoupling reactions mediated by organolanthanide(iii) complexes

Christos E. Kefalidis , Lionel Perrin , Laurent Maron

Dalton Transactions, 2014, 43 (11), pp.4520

Article dans une revue hal-01969549v1

Formation of cyanates in low-valent uranium chemistry: a synergistic experimental/theoretical study

Christos E. Kefalidis , Alistair Frey , S. Mark Roe , F. Geoffrey N. Cloke , Laurent Maron

Dalton Transactions, 2014, 43 (29), pp.11202-11208

Article dans une revue hal-01969545v1

Heteronuclear NMR Spectroscopy as a Surface-Selective Technique: A Unique Look at the Hydroxyl Groups of γ-Alumina.

Mostafa Taoufik , Kai Szeto , Nicolas Merle , Iker Del rosal , Laurent Maron et al.

Chemistry - A European Journal, 2014, 20 (14), pp.4038-4046

Article dans une revue hal-01969452v1

Qualitative Estimation of the Single-Electron Transfer Step Energetics Mediated by Samarium(II) Complexes: A “SOMO–LUMO Gap” Approach

Christos E. Kefalidis , Stéphanie Essafi , Lionel Perrin , Laurent Maron

Inorganic Chemistry, 2014, 53 (7), pp.3427-3433

Article dans une revue hal-01969540v1

An Actinide Metallacyclopropene Complex: Synthesis, Structure, Reactivity, and Computational Studies

Bo Fang , Wenshan Ren , Guohua Hou , Guofu Zi , De-Cai Fang et al.

Journal of the American Chemical Society, 2014, 136 (49), pp.17249-17261

Article dans une revue hal-01969494v1
Deposit thumbnail

Near-IR Two Photon Microscopy Imaging of Silica Nanoparticles Functionalized with Isolated Sensitized Yb(III) Centers

Giuseppe Lapadula , Adrien Bourdolle , Florian Allouche , Matthew Conley , Iker del Rosal et al.

Chemistry of Materials, 2014, 26 (2), pp.1062-1073. ⟨10.1021/cm404140q⟩

Article dans une revue hal-01245486v1

A Cationic Zinc Hydride Cluster Stabilized by an N-Heterocyclic Carbene: Synthesis, Reactivity, and Hydrosilylation Catalysis

Arnab Rit , Alessandro Zanardi , Thomas Spaniol , Laurent Maron , Jun Okuda

Angewandte Chemie International Edition, 2014, 53 (48), pp.13273-13277

Article dans une revue hal-01969490v1
Deposit thumbnail

Controlling selectivity in the reductive activation of CO 2 by mixed sandwich uranium( iii ) complexes

Nikolaos Tsoureas , Ludovic Castro , Alexander Kilpatrick , F. Geoffey N. Cloke , Laurent Maron

Chemical Science, 2014, 5 (10), pp.3777-3788. ⟨10.1039/x0xx00000x⟩

Article dans une revue hal-01969447v1

On the mechanism of the reaction of a magnesium( i ) complex with CO 2 : a concerted type of pathway

Christos E. Kefalidis , Andreas Stasch , Cameron Jones , Laurent Maron

Chemical Communications, 2014, 50 (82), pp.12318-12321

Article dans une revue hal-01969555v1
Deposit thumbnail

Aqueous microsolvation of CdCl 2 : Density functional theory and Born-Oppenheimer molecular dynamics studies

A. Ramirez-Solis , Laurent Maron

The Journal of Chemical Physics, 2014, 141 (9), pp.094304. ⟨10.1063/1.447334⟩

Article dans une revue hal-01969513v1

Multimetallic cooperativity in uranium-mediated CO2 activation

Oliver Cooper , Clément Camp , Jacques Pécaut , Christos E. Kefalidis , Laurent Maron et al.

Journal of the American Chemical Society, 2014, 136 (18), pp.6716--6723. ⟨10.1021/ja5017624⟩

Article dans une revue hal-01877478v1

Activation of SO 2 and CO 2 by Trivalent Uranium Leading to Sulfite/Dithionite and Carbonate/Oxalate Complexes

Anna-Corina Schmidt , Frank Heinemann , Christos E. Kefalidis , Laurent Maron , Peter Roesky et al.

Chemistry - A European Journal, 2014, 20 (42), pp.13501-13506

Article dans une revue hal-01969463v1

Hydroaminomethylation of Styrene Catalyzed by Rhodium Complexes Containing Chiral Diphosphine Ligands and Mechanistic Studies: Why Is There a Lack of Asymmetric Induction?

Delphine Crozet , Christos E. Kefalidis , Martine Urrutigoity , Laurent Maron , Philippe Kalck

ACS Catalysis, 2014, 4 (2), pp.435-447. ⟨10.1021/cs400906b⟩

Article dans une revue hal-01969481v1

Hydrosilylation catalysis by an earth alkaline metal silyl: synthesis, characterization, and reactivity of bis(triphenylsilyl)calcium

Valeri Leich , Thomas Spaniol , Laurent Maron , Jun Okuda

Chemical Communications, 2014, 50 (18), pp.2311

Article dans une revue hal-01969530v1

Theoretical treatment of one electron redox transformation of a small molecule using f-element complexes

Ludovic Castro , Christos E. Kefalidis , David Mckay , Stéphanie Essafi , Laurent Maron et al.

Dalton Transactions, 2014, 43 (32), pp.12124-12134. ⟨10.1039/C4DT01002G⟩

Article dans une revue hal-01969429v1

Insights into the Formation of Borabenzene Adducts via Ligand Exchange Reactions and TMSCl Elimination from Boracyclohexadiene Precursors

Marc-André Légaré , Guillaume Bélanger-Chabot , Guillaume de Robillard , André Languérand , Laurent Maron et al.

Organometallics, 2014, 33 (13), pp.3596-3606

Article dans une revue hal-01969522v1

A Series of Uranium (IV, V, VI) Tritylimido Complexes, Their Molecular and Electronic Structures and Reactivity with CO 2

Anna-Corina Schmidt , Frank Heinemann , Laurent Maron , Karsten Meyer

Inorganic Chemistry, 2014, 53 (24), pp.13142-13153

Article dans une revue hal-01969459v1

Aqueous solvation of HgClOH. Stepwise DFT solvation and Born–Oppenheimer molecular dynamics studies of the HgClOH–(H 2 O) 24 complex

J. Amaro-Estrada , Laurent Maron , A. Ramirez-Solis

Physical Chemistry Chemical Physics, 2014, 16 (18), pp.8455-8464

Article dans une revue hal-01969410v1

Two-Electron Reductive Carbonylation of Terminal Uranium(V) and Uranium(VI) Nitrides to Cyanate by Carbon Monoxide

Peter Cleaves , David King , Christos E. Kefalidis , Laurent Maron , Floriana Tuna et al.

Angewandte Chemie International Edition, 2014, 53 (39), pp.10412-10415

Article dans une revue hal-01969445v1

Direct evidence for intermolecular oxidative addition of sigma(Si-Si) bonds to gold

M. Joost , P. Gualco , Yannick Coppel , Karinne Miqueu , Christos E. Kefalidis et al.

Angewandte Chemie International Edition, 2014, 53 (3), pp.747-751. ⟨10.1002/anie.201307613⟩

Article dans une revue istex hal-00991874v1

An Intermediate Cobalt(IV) Nitrido Complex and its N-Migratory Insertion Product

Eva Zolnhofer , Martina Käss , Marat Khusniyarov , Frank Heinemann , Laurent Maron et al.

Journal of the American Chemical Society, 2014, 136 (42), pp.15072-15078

Article dans une revue hal-01969435v1
Deposit thumbnail

The role of 5f-orbital participation in unexpected inversion of the σ-bond metathesis reactivity trend of triamidoamine thorium( iv ) and uranium( iv ) alkyls

Benedict M Gardner , Peter Cleaves , Christos E. Kefalidis , Jian Fang , Laurent Maron et al.

Chemical Science, 2014, 5 (6), pp.2489-2497. ⟨10.1039/c4sc00182f⟩

Article dans une revue hal-01969511v1

To Bend or Not To Bend: Experimental and Computational Studies of Structural Preference in Ln(Tp iPr 2 ) 2 (Ln = Sm, Tm)

Aurélien Momin , Lee Carter , Yi Yang , Robert Mcdonald , Stéphanie Essafi (née Labouille) et al.

Inorganic Chemistry, 2014, 53 (22), pp.12066-12075

Article dans une revue hal-01969571v1
Deposit thumbnail

Reversible Sigma C-C Bond Formation Between Phenanthroline Ligands Activated by (C5Me5)2Yb

Grégory A Nocton , Wayne A Lukens , Corwin A Booth , Sergio A Rozenel , Scott A Medling et al.

Journal of the American Chemical Society, 2014, 136 (24), pp.8626-8641. ⟨10.1021/ja502271q⟩

Article dans une revue hal-01388838v1
Deposit thumbnail

Carbon-Hydrogen Bond Breaking and Making in the Open-Shell Singlet Molecule Cp* 2 Yb(4,7-Me 2 phen)

Grégory A Nocton , Corwin A Booth , Laurent Maron , Louis Ricard , Richard A Andersen

Organometallics, 2014, 33 (23), pp.6819-6829. ⟨10.1021/om500843z⟩

Article dans une revue hal-01388873v1

Mixed Alkyl Hydrido Complexes of Zinc: Synthesis, Structure, and Reactivity

Arnab Rit , Thomas Spaniol , Laurent Maron , Jun Okuda

Organometallics, 2014, 33 (8), pp.2039-2047

Article dans une revue hal-01969495v1

Well-Defined Supported Mononuclear Tungsten Oxo Species as Olefin Metathesis Pre-Catalysts

Yassine Bouhoute , Anthony Garron , Denys Grekov , Nicolas Merle , Kai Szeto et al.

ACS Catalysis, 2014, 4 (11), pp.4232-4241

Article dans une revue hal-01969421v1

On the thermal stability of the branched hexasulfane isomers. A DFT molecular dynamics study of H2S6 conformers

A. Ramirez-Solis , Laurent Maron

Chemical Physics Letters, 2014, 607, pp.64-69. ⟨10.1016/j.cplett.2014.05.028⟩

Article dans une revue istex hal-01969503v1

An ion pair scandium hydride supported by a dianionic (NNNN)-type macrocycle ligand

Peng Cui , Thomas Spaniol , Laurent Maron , Jun Okuda

Chemical Communications, 2014, 50 (4), pp.424-426

Article dans une revue hal-01969486v1

PMLABe Diol Synthesized by Ring-Opening Polymerization of Racemic Benzyl β-Malolactonate Initiated by Rare-Earth Trisborohydride Complexes: An Experimental and DFT Study

Cédric C. Jaffredo , Matthias Schmid , Iker Del rosal , Teddy Mevel , Peter Roesky et al.

Chemistry - A European Journal, 2014, 20 (44), pp.14387-14402

Article dans une revue hal-01969536v1

Are Solvent and Dispersion Effects Crucial in Olefin Polymerization DFT Calculations? Some Insights from Propylene Coordination and Insertion Reactions with Group 3 and 4 Metallocenes

Ludovic Castro , Evgueni Kirillov , Olivier Miserque , Alexandre Welle , Luc Haspeslagh et al.

ACS Catalysis, 2014, 5 (1), pp.416-425

Article dans une revue hal-01969167v1

C(sp₃)-H bond activation with triel metals: indium and gallium zwitterions through internal hydride abstraction in rigid salan ligands.

Nicolas Maudoux , Jian Fang , Thierry Roisnel , Vincent Dorcet , Laurent Maron et al.

Chemistry - A European Journal, 2014, 20 (25), pp.7706-17. ⟨10.1002/chem.201402358⟩

Article dans une revue istex hal-01114342v1

Yttrium catalysts for syndioselective β-butyrolactone polymerization: on the origin of ligand-induced stereoselectivity

Jian Fang , Mathieu J.-L. Tschan , Thierry Roisnel , Xavier Trivelli , Régis M. Gauvin et al.

Polymer Chemistry, 2013, 4 (2), pp.360-367. ⟨10.1039/c2py20590d⟩

Article dans une revue hal-02042830v1

Cleaving bonds in CH3OSO2CF3 with [1,2,4-(Me3C)3C5H2]2CeH; an experimental and computational study

Evan L. Werkema , Ludovic Castro , Laurent Maron , Odile Eisenstein , Richard A. Andersen

New Journal of Chemistry, 2013, 37, pp.132-142. ⟨10.1039/C2NJ40624A⟩

Article dans une revue hal-00763834v1

Organometallic strontium borohydrides - synthesis, catalytic studies, and DFT calculations

Magdalena Kuzdrowska , Liana Annunziata , Sébastian Marks , Matthias Schmid , Cédric G Jaffredo et al.

Dalton Transactions, 2013, 42, pp.9352-9360. ⟨10.1039/C3DT00037K⟩

Article dans une revue hal-00874609v1

The influence of the Torsion Angle in 3,3'-Dimethyl,2,2'-bipyridine on the Intermediate Valence in (C5Me5)2Yb(3,3'-Me2-bipy).

Grégory Nocton , Corwin H Booth , Laurent Maron , Richard a Andersen

Organometallics, 2013, 32 (19), pp.5305-5312. ⟨10.1021/om400528d⟩

Article dans une revue hal-00905903v1

Controlled Thermolysis of Uranium (Alkoxy) siloxy Complexes: A Route to Polymetallic Complexes of Low-Valent Uranium

Clément Camp , Christos E. Kefalidis , Jacques Pécaut , Laurent Maron , Marinella Mazzanti

Angewandte Chemie International Edition, 2013, 52 (48), pp.12646--12650. ⟨10.1002/anie.201307291⟩

Article dans une revue istex hal-01877480v1

Polymerization of cyclic esters using N-heterocyclic carbene carboxylate catalysts

E. Brule , Vincent Guérineau , P. Vermault , F. Prima , J. Balogh et al.

Polymer Chemistry, 2013, 4 (8), pp.2414-2423. ⟨10.1039/c3py00108c⟩

Article dans une revue hal-00913428v1

Thermal Dihydrogen Elimination from Cp☆2Yb(4,5-diazafluorene)

Richard A Andersen , Corwin H Booth , Laurent Maron , Grégory Nocton

Organometallics, 2013, 32 (5), pp.1150-1158. ⟨10.1021/om300876b⟩

Article dans une revue hal-00906381v1

Heteroleptic Tin(II) Initiators for the Ring-Opening (Co)Polymerization of Lactide and Trimethylene Carbonate: Mechanistic Insights from Experiments and Computations.

Lingfang Wang , Christos E. Kefalidis , Sourisak Sinbandhit , Vincent Dorcet , Jean-Francois Carpentier et al.

Chemistry - A European Journal, 2013, 19, pp.13463--13478. ⟨10.1002/chem.201301751⟩

Article dans une revue istex hal-01069851v1

Novel phospholyl(diphenylphosphino)methane-ruthenium complexes: unexpected non-assisted cis to trans isomerization of [RuCl 2 (κ 2 -P–P′) 2 ]

Duc Hanh Nguyen , Jean-Claude Daran , Sonia Mallet-Ladeira , Thomas Davin , Laurent Maron et al.

Dalton Transactions, 2013, 42 (1), pp.75-81. ⟨10.1039/C2DT32032K⟩

Article dans une revue hal-02908438v1

Ring-opening polymerization of racemic β-butyrolactone promoted by rare earth trisborohydride complexes towards a PHB-diol: an experimental and DFT study

Sophie M. Guillaume , Liana Annunziata , Iker Del rosal , Christophe Iftner , Laurent Maron et al.

Polymer Chemistry, 2013, 4 (10), pp.3077-3087. ⟨10.1039/C3PY00056G⟩

Article dans une revue hal-00844464v1

Cation-Mediated Conversion of the State of Charge in Uranium Arene Inverted-Sandwich Complexes

Clément Camp , Victor Mougel , Jacques Pécaut , Laurent Maron , Marinella Mazzanti

Chemistry - A European Journal, 2013, 19 (51), pp.17528--17540. ⟨10.1002/chem.201302752⟩

Article dans une revue istex hal-01877482v1

Discrete divalent rare-earth cationic ROP catalysts : ligand-dependent redox behavior and discrepancies with alkaline-earth analogues in a ligand-assisted activated monomer mechanism.

Bo Liu , Thierry Roisnel , Laurent Maron , Jean-François Carpentier , Yann Sarazin

Chemistry - A European Journal, 2013, 19 (12), pp.3986-94. ⟨10.1002/chem.201204340⟩

Article dans une revue istex hal-00824594v1

Small Changes Have Consequences: Lessons from Tetrabenzyltitanium and -zirconium Surface Organometallic Chemistry

Nicolas Popoff , Jeff Espinas , Jérémie Pelletier , Benoît Macqueron , Kai Szeto et al.

Chemistry - A European Journal, 2013, 19 (3), pp.964-973. ⟨10.1002/chem.201202737⟩

Article dans une revue istex hal-02043430v1

Decamethylscandocinium-hydrido-(perfluorophenyl)borate: fixation and tandem tris(perfluorophenyl)borane catalysed deoxygenative hydrosilation of carbon dioxide

Andreas Berkefeld , Warren E. Piers , Masood Parvez , Ludovic Castro , Laurent Maron et al.

Chemical Science, 2013, 4, pp.2152-2162. ⟨10.1039/C3SC50145K⟩

Article dans une revue hal-00807145v1

Bis(phosphinimino)methanide borohydride complexes of the rare-earth elements as initiators for the ring-opening polymerization of trimethylene carbonate: combined experimental and computational investigations

Sophie M. Guillaume , Sophie Guillaume , Pierre Brignou , Nicolas Susperregui , Laurent Maron et al.

Polymer Chemistry, 2012, 3 (2), pp.429-435. ⟨10.1039/c1py00487e⟩

Article dans une revue hal-03327010v1

β-Diketiminate alkaline-earth cationic complexes: synthesis, structures, lactide polymerization and unusual oxidative reactivity of the ancillary ligand

Bo Liu , Vincent Dorcet , Laurent Maron , Jean-François Carpentier , Yann Sarazin

European Journal of Inorganic Chemistry, 2012, 2012 (18), pp.3023-3031. ⟨10.1002/ejic.201200183⟩

Article dans une revue istex hal-00874211v1

Carbon Monoxide Activation via O-Bound CO Using Decamethylscandocinium-Hydridoborate Ion Pairs

Andreas Berkefeld , Warren E. Piers , Masood Parvez , Ludovic Castro , Laurent Maron et al.

Journal of the American Chemical Society, 2012, 134, pp.10843-10851. ⟨10.1021/ja300591v⟩

Article dans une revue hal-00714378v1

Organometallic Strontium Borohydrides: Synthesis, X-ray Structures, Catalytic Polymerization of ε-Caprolactone, and Density Functional Calculations

Sébastian Marks , Magdalena Kuzdrowska , Peter W. Roesky , Liana Annunziata , Sophie M. Guillaume et al.

ChemPlusChem, 2012, 77, pp.350-353. ⟨10.1002/cplu.201200052⟩

Article dans une revue istex hal-01477680v1

A Theoretical Study of Abiotic Methylation Reactions of Gaseous Elemental Mercury by Halogen-Containing Molecules

Ludovic Castro , A. Dommerguet , Catherine Larose , C. Ferrari , Laurent Maron

Journal of Physical Chemistry A, 2012, 115 (22), pp.5602-5608. ⟨10.1021/jp200643n⟩

Article dans une revue insu-00646712v1

Selectivity in the C-H Activation Reaction of CH3OSO2CH3 with [1,2,4-(Me3C)3C5H2]2CeH or [1,2,4-(Me3C)3C5H2][1,2-(Me3C)2-4-(Me2CCH2)C5H2]Ce: To Choose or Not To Choose

Evan L. Werkema , Ludovic Castro , Laurent Maron , Odile Eisenstein , Richard A. Andersen

Organometallics, 2012, 31, pp.870-881. ⟨10.1021/om200842t⟩

Article dans une revue hal-00671293v1

Interception of a Rh(I)–Rh(III) dinuclear trihydride complex revealing the dihydrogen activation by [Rh(CO)2{(R,R)-Ph–BPE}]

Delphine Crozet , David Mckay , Christian Bijani , Aitor Gual , Cyril Godard et al.

Dalton Transactions, 2012, 41 (12), pp.3369. ⟨10.1039/c2dt12400a⟩

Article dans une revue hal-02909585v1

Siloxides as Supporting Ligands in Uranium (III)-Mediated Small-Molecule Activation

Victor Mougel , Clément Camp , Jacques Pécaut , Christophe Copéret , Laurent Maron et al.

Angewandte Chemie, 2012, 124 (49), pp.12446--12450. ⟨10.1002/anie.201206955⟩

Article dans une revue istex hal-01877486v1

17 O NMR Gives Unprecedented Insights into the Structure of Supported Catalysts and Their Interaction with the Silica Carrier

Nicolas Merle , Julien Trébosc , Anne Baudouin , Iker Del rosal , Laurent Maron et al.

Journal of the American Chemical Society, 2012, 134 (22), pp.9263 - 9275. ⟨10.1021/ja301085m⟩

Article dans une revue hal-01702437v1

Insights into the Mechanism of Reaction of [(C5Me5)2SmII(thf)2] with CO2 and COS by DFT Studies

Ludovic Castro , Stéphanie Labouille , Doug K Kindra , Joseph W Ziller , François Nief et al.

Chemistry - A European Journal, 2012, 18 (25), pp.78867895. ⟨10.1002/chem.201103192⟩

Article dans une revue istex hal-00906056v1

Ligand Influence on the Redox Chemistry of Organosamarium Complexes: Experimental and Theoretical Studies of the Reactions of (C5Me5)(2)Sm(THF)(2) and (C4Me4P)(2)Sm with Pyridine and Acridine

Stéphanie Labouille , François Nief , X. F Le Goff , Laurent Maron , Douglas R Kindra et al.

Organometallics, 2012, 31 (14), pp.5196-5203. ⟨10.1021/om300573z⟩

Article dans une revue hal-00905893v1
Deposit thumbnail

Mechanistic insights into β-oxygen atom transfer in olefinepoxidation mediated by W( vi ) complexes and H 2 O 2

Chiara Dinoi , Rinaldo Poli , Lionel Perrin , Laurent Maron

Dalton Transactions, 2012, 41 (4), pp.1131-1133. ⟨10.1039/c1dt10924c⟩

Article dans une revue hal-02909748v1

Interplay between Cationic and Neutral Species in the Rhodium-Catalyzed Hydroaminomethylation Reaction

Delphine Crozet , Aitor Gual , David Mckay , Chiara Dinoi , Cyril Godard et al.

Chemistry - A European Journal, 2012, 18 (23), pp.7128-7140. ⟨10.1002/chem.201103474⟩

Article dans une revue istex hal-02909581v1

Mechanistic Insights of the Initiation Process of the Ring-Opening Polymerization of epsilon-Caprolactone by Divalent Sm(BH4)2THF2 with DFT: Concerted or Oxidative Reaction?

Christophe Iftner , Fanny Bonnet , François Nief , Marc Visseaux , Laurent Maron

Organometallics, 2011, 30 (17), pp.4482-4485. ⟨10.1021/om200512g⟩

Article dans une revue hal-00694171v1

Isoselective Styrene Polymerization Catalyzed by ansa-Bis(indenyl) Allyl Rare Earth Complexes. Stereochemical and Mechanistic Aspects

Liana Annunziata , Anne-Sophie Rodrigues , Evgeny Kirillov , Yann Sarazin , Jun Okuda et al.

Macromolecules, 2011, 44 (9), pp.3312-3322. ⟨10.1021/ma2003757⟩

Article dans une revue hal-00632223v1

Original transition metal→indium interactions upon coordination of a triphosphine-indane

E.J. Derrah , M. Sircoglou , Maxime Mercy , S. Ladeira , G. Bouhadir et al.

Organometallics, 2011, 30 (4), pp.657-660. ⟨10.1021/om1011769⟩

Article dans une revue hal-01613240v1

Direct Involvement of the Acetato Ligand in the Reductive Elimination Step of Rhodium-Catalyzed Methanol Carbonylation

Nicolas Lassauque , Thomas Davin , Duc Hanh Nguyen , Romain Adcock , Yannick Coppel et al.

Inorganic Chemistry, 2011, 51 (1), pp.4-6. ⟨10.1021/ic201574m⟩

Article dans une revue hal-02910011v1

Bis(phosphinimino)methanide borohydride complexes of the rare-earth elements as initiators for the polymerization of methyl methacrylate: combined experimental and computational investigations

Sophie M. Guillaume , Pierre Brignou , Nicolas Susperregui , Laurent Maron , Magdalena Kuzdrowska et al.

Polymer Chemistry, 2011, 2 (4), pp.1728-1736. ⟨10.1039/C1PY00133G⟩

Article dans une revue hal-00877858v1

Theoretical study of the solvation of HgCl2, HgClOH, Hg(OH)2 and HgCl3−: a density functional theory cluster approach

Ludovic Castro , A. Dommergue , A. Renard , C. Ferrari , A. Ramírez-Solís et al.

Physical Chemistry Chemical Physics, 2011, 13 (37), pp.16772-16779. ⟨10.1039/C1CP22154J⟩

Article dans une revue insu-00646729v1

Discrete, solvent-free alkaline-earth metal cations: metal***fluorine interactions and ROP catalytic activity.

Yann Sarazin , Bo Liu , Thierry Roisnel , Laurent Maron , Jean-François Carpentier

Journal of the American Chemical Society, 2011, 133 (23), pp.9069-87. ⟨10.1021/ja2024977⟩

Article dans une revue hal-00632235v1

DFT investigations on the ring-opening polymerization of cyclic carbonates catalyzed by zinc-{β-diiminate} complexes

Iker Del rosal , Pierre Brignou , Sophie M. Guillaume , Jean-François Carpentier , Laurent Maron

Polymer Chemistry, 2011, 2 (11), pp.2564-2573. ⟨10.1039/C1PY00309G⟩

Article dans une revue hal-00652161v1

Synthesis and structure of divalent thulium borohydrides and their application in epsilon-caprolactone polymerisation

Aurélien Momin , Fanny Bonnet , Marc Visseaux , Laurent Maron , Josef Takats et al.

Chemical Communications, 2011, pp.12203-12205

Article dans une revue hal-00695041v1

Theoretical Treatment of Redox Processes Involving Lanthanide(II) Compounds: Reactivity of Organosamarium(II) and Organothulium(II) Complexes with CO2 and Pyridine

Stéphanie Labouille , François Nief , Laurent Maron

Journal of Physical Chemistry A, 2011, pp.8295-8301

Article dans une revue hal-00694174v1

DFT Investigation of the Tacticity Control during Styrene Polymerization Catalyzed by Single-Component Allyl ansa-Lanthanidocenes {(C5H4CMe2(9-C13H8)}Ln(C3H5)

Lionel Perrin , Evgeny Kirillov , Jean-François Carpentier , Laurent Maron

Macromolecules, 2010, 43 (15), pp.6330-6336. ⟨10.1021/ma101061r⟩

Article dans une revue hal-00917568v1
Deposit thumbnail

Multicentered effective group potentials: ligand-field effects in organometallic clusters and dynamical study of chemical reactivity

Christophe Raynaud , Iker Del rosal , Franck Jolibois , Laurent Maron , Romuald Poteau

Theoretical Chemistry Accounts: Theory, Computation, and Modeling, 2010, 126 (3-4), pp.151-163. ⟨10.1007/s00214-009-0615-z⟩

Article dans une revue istex hal-00493604v1

Bridging Silyl Groups in σ-Bond Metathesis and [1,2]-Shifts. Experimental and Computational Study of the Reaction between Cerium Metallocenes and MeOSiMe3

Evan L. Werkema , Ahmed Yahia , Laurent Maron , Odile Eisenstein , Richard A. Andersen

Organometallics, 2010, 29, pp.5103-5110. ⟨10.1021/om1003286⟩

Article dans une revue hal-00535770v1

Intermediate-Valence Tautomerism in Decamethylytterbocene Complexes of Methyl-Substituted Bipyridines

Corwin H. Booth , Daniel Kazhdan , Evan L. Werkema , Marc D. Walter , Wayne W. Lukens et al.

Journal of the American Chemical Society, 2010, 132, pp.17537-17549. ⟨10.1021/ja106902s⟩

Article dans une revue hal-00547435v1

Copper(I) complexes derived from mono- and diphosphino-boranes: Cu→b interactions supported by arene coordination

M. Sircoglou , Sébastien Bontemps , Maxime Mercy , Karinne Miqueu , S. Ladeira et al.

Inorganic Chemistry, 2010, 49 (9), pp.3983-3990. ⟨10.1021/ic901896z⟩

Article dans une revue hal-01613247v1

Facile Interconversion of [Cp2(Cl)Hf(SnH3)] and [Cp2(Cl)Hf(μ-H)SnH2]: DFT Investigations of Hafnocene Stannyl Complexes as Masked Stannylenes

Julie Guihaume , Christophe Raynaud , Odile Eisenstein , Lionel Perrin , Laurent Maron et al.

Angewandte Chemie International Edition, 2010, 49 (10), pp.1816 - 1819. ⟨10.1002/anie.200906476⟩

Article dans une revue istex hal-00459000v1

The reaction of bis(1,2,4-tri-t-butylcyclopentadienyl)ceriumbenzyl, Cp<sub>2</sub>CeCH<sub>2</sub>Ph, with methylhalides: a metathesis reaction that does not proceed by a metathesis transition state

Evan L. Renkema , Richard A. Andersen , Laurent Maron , Odile Eisenstein

Dalton Transactions, 2010, 39, pp.6648-6660. ⟨10.1039/b918103b⟩

Article dans une revue istex hal-00507075v1

Splitting a C–O bond in dialkylethers with bis(1,2,4-tri-tert-butylcyclopentadienyl)cerium hydride does not occur by a σ-bond metathesis pathway: a combined experimental and DFT computational study

Evan L. Werkema , Ahmed Yahia , Laurent Maron , Odile Eisenstein , Richard A. Andersen

New Journal of Chemistry, 2010, pp.2189-2196. ⟨10.1039/C0NJ00261E⟩

Article dans une revue istex hal-00529431v1

Bis(phosphinimino)methanide borohydride complexes of the rare earth elements as initiators for the ring-opening polymerization of -caprolactone: combined experimental and computational investigations

J. Jenter , P. W. Roesky , N. Ajellal , Sophie M. Guillaume , Nicolas Susperregui et al.

Chemistry - A European Journal, 2010, 16 (15), pp.4629-4638. ⟨10.1002/chem.200903107⟩

Article dans une revue istex hal-00497872v1
Deposit thumbnail

Olefin Epoxidation by H2O2/MeCN Catalysed by Cyclopentadienyloxidotungsten(VI) and Molybdenum(VI) Complexes: Experiments and Computations

Chiara Dinoi , Marco Ciclosi , Eric Manoury , Laurent Maron , Lionel Perrin et al.

Chemistry - A European Journal, 2010, 3rd European Chemistry Congress, Nürnberg, 16 (31), pp.9572-9584. ⟨10.1002/chem.201000298⟩

Article dans une revue istex hal-03177754v1

Bis(dimethylsilyl)amide complexes of the alkaline-earth metals stabilized by β-Si-H agostic interactions: synthesis, characterization, and catalytic activity

Yann Sarazin , D. Roşca , Valentin Poirier , Thierry Roisnel , A. Silvestru et al.

Organometallics, 2010, 29 (23), pp.6569-6577. ⟨10.1021/om100908q⟩

Article dans une revue hal-00589178v1

Catalytic hydrosilylation of olefins with organolanthanides: a DFT study. Part I: Hydrosilylation of propene by SiH<sub>4</sub>

Noémi Barros , Odile Eisenstein , Laurent Maron

Dalton Transactions, 2010, 39, pp.10749-10756. ⟨10.1039/C0DT00329H⟩

Article dans une revue istex hal-00531502v1

Catalytic hydrosilylation of olefins with organolanthanide complexes: A DFT study. Part II: Influence of the substitution on olefin and silane

Noémi Barros , Odile Eisenstein , Laurent Maron

Dalton Transactions, 2010, 39, pp.10757-10767. ⟨10.1039/C0DT00330A⟩

Article dans une revue istex hal-00531504v1
Deposit thumbnail

Uranyl oxo activation and functionalization by metal cation coordination

Polly L. Arnold , Anne-Frédérique Pécharman , Emmalina Hollis , Ahmed Yahia , Laurent Maron et al.

Nature Chemistry, 2010, 2 (12), pp.1056-1061. ⟨10.1038/nchem.904⟩

Article dans une revue cea-02060610v1

Ionic-type reactivity of 1,3-dibora-2,4-diphosphoniocyclobutane-1,3-diyls : regio- and stereoselective addition of hydracids

Guy Bertrand , D. Bourissou , Gad Fuks , Nathalie Saffon , Laurent Maron

Journal of the American Chemical Society, 2009, 132, pp.13681-13689

Article dans une revue hal-00444590v1

Gold(I) complexes of phosphanyl-gallanes: from interconverting to separable coordination isomers

G. Bouhadir , Laurent Maron , Maxime Mercy , Nathalie Saffon , Marie Sircoglou et al.

Angewandte Chemie International Edition, 2009, 48, pp.3454-3457

Article dans une revue hal-00443926v1

Bond Activations of PhSiH<sub>3</sub> by Cp<sub>2</sub>SmH: A Mechanistic Investigation by the DFT Method

Lionel Perrin , Laurent Maron , Odile Eisenstein , T. Don Tilley

Organometallics, 2009, 28, pp.3767-3775. ⟨10.1021/om900106n⟩

Article dans une revue hal-00390648v1

2-Indenylidene pincer complexes of zirconium and palladium

D. Bourissou , Laurent Maron , B. Martin-Vaca , Pascal Oulie , Nathalie Saffon et al.

Journal of the American Chemical Society, 2009, 131, pp.3493-3498

Article dans une revue hal-00443921v1

2,6-bis(imidazol-2-ylidene) pyridine complexes of lanthanoïdes: a theoretical study of the bonding situation and selective complexation

D. Bourissou , Laurent Maron

Organometallics, 2009, 28, pp.3686-3690

Article dans une revue hal-00443945v1
Deposit thumbnail

Hydrogen for X-group exchange in CHX (X = Cl, Br, I , OMe, and NMe) by monomeric [1,2,4-(Me3C)3C5H2]2CeH: experimental and computational support for a carbenoid mechanism

Evan L. Werkema , Richard A. Andersen , Ahmed Yahia , Laurent Maron , Odile Eisenstein

Organometallics, 2009, 28, pp.3173-3185. ⟨10.1021/om9001846⟩

Article dans une revue hal-00384982v1

On the Initiation Mechanism of Syndiospecific Styrene Polymerization Catalyzed by Single-Component ansa -Lanthanidocenes

Lionel Perrin , Yann Sarazin , Evgueni Kirillov , Jean-François Carpentier , Laurent Maron

Chemistry - A European Journal, 2009, 15 (15), pp.3773 - 3783. ⟨10.1002/chem.200802036⟩

Article dans une revue istex hal-00411131v1

A DFT study of the reactions of O3 with Hg° or Br−

Ludovic Castro , Aurélien Dommergue , Christophe P. Ferrari , Laurent Maron

Atmospheric Environment, 2009, 43 (35), pp.5708-5711. ⟨10.1016/j.atmosenv.2009.07.038⟩

Article dans une revue istex insu-00497852v1

The Bond Between CO and Cp'<sub>3</sub>U in Cp'<sub>3</sub>U(CO) involves Backbonding from the Cp'<sub>3</sub>U Ligand-based Orbitals of π-Symmetry, where Cp' represents a substituted cyclopentadienyl ligand

Laurent Maron , Odile Eisenstein , Richard A. Andersen

Organometallics, 2009, 28, pp.3629-3635. ⟨10.1021/om801098b⟩

Article dans une revue hal-00390371v1

Gold→Silane and Gold→Stannane Complexes: Coordination of Saturated Molecules as Acceptor Ligands

Pauline Gualco , T.P Lin , Maxime Mercy , Marie Sircoglou , Sonia Ladeira et al.

Angewandte Chemie International Edition, 2009, 48, pp.9892-9895

Article dans une revue hal-00458851v1

Theoretical proposal for an organometallic route to cis-peptides

Georges Trinquier , Romuald Poteau , Laurent Maron , Bruno Chaudret

New Journal of Chemistry, 2009, 33 (9), pp.1833-1836. ⟨10.1039/B904139G⟩

Article dans une revue istex hal-00835609v1

Decamethylytterbocene Complexes of Bipyridines and Diazabutadienes: Multiconfigurational Ground States and Open-Shell Singlet Formation

Corwin H. Booth , Marc D. Walter , Daniel Kazhdan , Yung-Jin Hu , Wayne W. Lukens et al.

Journal of the American Chemical Society, 2009, 131, pp.6480. ⟨10.1021/ja809624w⟩

Article dans une revue hal-00383199v1

Group 10 and 11 metal boratranes (Ni, Pd, Pt, CuCl, AgCl, AuCl, and Au +) derived from a triphosphine-borane

M. Sircoglou , Sébastien Bontemps , G. Bouhadir , N. Saffon , Karinne Miqueu et al.

Journal of the American Chemical Society, 2008, 130 (49), pp.16729-16738. ⟨10.1021/ja8070072⟩

Article dans une revue istex hal-01613260v1

Tracking reactive intermediates in phosphine-promoted reactions with ambiphilic phosphino-boranes

G. Bouhadir , D. Bourissou , Laurent Maron , Nathalie Saffon , Sylvie Moebs-Sanchez

Chemical Communications, 2008, pp.3435-3437

Article dans une revue hal-00371336v1

New Insights into the Polymerization of Methyl Methacrylate Initiated by Rare-Earth Borohydride Complexes: A Combined Experimental and Computational Approach

Noémi Barros , Michèle Schappacher , Paul Dessuge , Laurent Maron , Sophie M. Guillaume

Chemistry - A European Journal, 2008, 14 (6), pp.1881-1890. ⟨10.1002/chem.200701438⟩

Article dans une revue istex hal-00340293v1

DFT Investigation of the Catalytic Hydromethylation of Olefins by Scandocenes. 2. Influence of the Ansa Ligand on Propene and Isobutene Hydromethylation

Noémi Barros , Laurent Maron , Odile Eisenstein , T. Don Tilley

Organometallics, 2008, 27, pp.2252-2257. ⟨10.1021/om701270w⟩

Article dans une revue istex hal-00282172v1

Cationic methyl complexes of the rare-earth metals: an experimental and computational study on synthesis, structure, and reactivity

Mathias U. Kramer , Dominique Robert , Stefan Arndt , Peter M. Zeimentz , Thomas R. Spaniol et al.

Inorganic Chemistry, 2008, 47, pp.9265. ⟨10.1021/ic801259n⟩

Article dans une revue istex hal-00329846v1

A DFT study of the mechanism of the polymerization of Ε-caprolactone initiated by organolanthanide (boro)hydride complexes

Noémi Barros , P. Mountford , Sophie M. Guillaume , Laurent Maron

Chemistry - A European Journal, 2008, 14, pp.5507-5518

Article dans une revue hal-00343603v1

Metallaboratranes derived from a triphosphanyl-borane : intrinsic C3 symmetry supported by a Z-type ligand

Sébastien Bontemps , G. Bouhadir , D. Bourissou , Laurent Maron , Maxime Mercy et al.

Angewandte Chemie International Edition, 2008, 47, pp.1481-1484

Article dans une revue hal-00345190v1

Linear Uranium Complexes X2UL5 with L=Cyanide, Isocyanate: DFT Evidence for Similarities between Uranyl (X=O) and Uranocene (X=Cp) Derivatives

Nathalie Tarrat , Noémi Barros , Colin J. Marsden , Laurent Maron

Chemistry - A European Journal, 2008, 14 (7), pp.2093-2099. ⟨10.1002/chem.200701511⟩

Article dans une revue istex hal-00951616v1

How Elementary Mercury Reacts in the Presence of Halogen Radicals and/or Halogen Anions: A DFT Investigation

Laurent Maron , Aurélien Dommergue , Christophe P. Ferrari , Marlène Delacour-Larose , Xavier Faïn

Chemistry - A European Journal, 2008, 14 (27), pp.8322 à 8329. ⟨10.1002/chem.200800491⟩

Article dans une revue istex insu-00379686v1

Transition-metal complexes featuring Z-type ligands : agreement or discrepancy between geometry and dn configuration ?

Nathalie Saffon , Marie Sircoglou , Sébastien Bontemps , G. Bouhadir , Laurent Maron et al.

Angewandte Chemie, 2007, 46, pp.8583-8586

Article dans une revue hal-00266276v1

Enforced n1-fluorenyl and indenyl coordination to zirconium : geometrically constrained and sterically-expanded complexes derived from the bifunctional (FluPPh2NAr)- and (IndPPh2NAr)- ligands

C. Freund , Pascal Oulie , D. Bourissou , B. Martin-Vaca , Nathalie Saffon et al.

Organometallics, 2007, 26, pp.6793-6804

Article dans une revue hal-00266301v1

Chemoselectivity in r bond activation by lanthanocene complexes from a DFT perspective: reactions of Cp2LnR (R = CH3, H, SiH3) with SiH4 and CH3-SiH3

Lionel Perrin , Odile Eisenstein , Laurent Maron

New Journal of Chemistry, 2007, 31, pp.549-555. ⟨10.1039/b617425f⟩

Article dans une revue istex hal-00142996v1

Reactions of Monomeric [1,2,4 (Me3C)3C5H2]2CeH and CO with or without H2: An Experimental and Computational Study

Evan Werkema , Laurent Maron , Odile Eisenstein , Richard a Andersen

Journal of the American Chemical Society, 2007, 129, pp.2529-2541. ⟨10.1021/ja066482h⟩

Article dans une revue istex hal-00139898v1

Lanthanide complexes of amino-carbenes : on the Samarium-carbene bond from DFT calculations

D. Bourissou , Laurent Maron

Organometallics, 2007, 26, pp.1100-1103

Article dans une revue hal-00274176v1

Single but Stronger UO, Double but Weaker UNMe Bonds: The Tale Told by Cp2UO and Cp2UNR

Noémi Barros , Daniel Maynau , Laurent Maron , Odile Eisenstein , Guofu Zi et al.

Organometallics, 2007, 26, pp.5059-5065. ⟨10.1021/om700628e⟩

Article dans une revue istex hal-00171205v1

Transient palladadiphosphanylcarbenes : singlet carbenes with an "inverse" electronic configuration (p2 instead of 2) and unusual transannular metal-carbene interactions (C Pd donation and Pd C back-donation)

Heinz Gornitzka , J. Vignolle , G. Bertrand , D. Bourissou , Laurent Maron et al.

Journal of the American Chemical Society, 2007, 129, pp.978-985

Article dans une revue hal-00274170v1

DFT studies of the methyl exchange reaction between Cp2M–CH3 or Cp*2M–CH3 (Cp = C5H5, Cp* = C5Me5, M = Y, Sc, Ln) and CH4. Does M ionic radius control the reaction?

Noémi Barros , Odile Eisenstein , Laurent Maron

Dalton Transactions, 2006, pp.3052-3057. ⟨10.1039/b600021e⟩

Article dans une revue istex hal-00139901v1

Enforced N1-fluorenyl coordination to rhodium (I) with the (FluPPh2NPh) ligand

C. Freund , Noémi Barros , Heinz Gornitzka , B. Martin-Vaca , Laurent Maron et al.

Organometallics, 2006, 25, pp.4927-4930

Article dans une revue hal-00144966v1

Ab Initio Dynamic Study of the Reaction of Cl2LaR (R = H, CH3) with H2

Christophe Raynaud , Jean-Pierre Daudey , Franck Jolibois , Laurent Maron

Journal of Physical Chemistry A, 2006, 110 (1), pp.101-105. ⟨10.1021/jp050771v⟩

Article dans une revue istex hal-00171222v1

Berry Pseudorotation Mechanism for the Interpretation of the 19F NMR Spectrum in PF5 by Ab Initio Molecular Dynamics Simulations.

Christophe Raynaud , Laurent Maron , Jean-Pierre Daudey , Franck Jolibois

ChemPhysChem, 2006, 7 (2), pp.407-413. ⟨10.1002/cphc.200500297⟩

Article dans une revue hal-00171227v1

Ab initio molecular dynamics simulation of the UV absorption spectrum of β-ionone

Christophe Raynaud , Romuald Poteau , Laurent Maron , Franck Jolibois

Journal of Molecular Structure: THEOCHEM, 2006, 771 (1-3), pp.43-50. ⟨10.1016/j.theochem.2006.03.038⟩

Article dans une revue istex hal-00171228v1

A DFT Study of Stannane Dehydrocoupling Catalyzed by Cp2LaH

Christophe Raynaud , Lionel Perrin , Laurent Maron

Organometallics, 2006, 25 (13), pp.3143-3151. ⟨10.1021/om051060m⟩

Article dans une revue istex hal-00171216v1

1,4- vs 1,3-Prototropic Mechanism for Intramolecular Double Proton Transfer Reaction in Monothiooxalic Acid. Theoretical Investigation of Potential Energy Surface

Christophe Raynaud , Jean-Pierre Daudey , Laurent Maron , Franck Jolibois

Journal of Physical Chemistry A, 2005, 109 (42), pp.9646-9652. ⟨10.1021/jp052782u⟩

Article dans une revue istex hal-00431282v1

Ab initio molecular dynamics: Plane waves vs. local basis - The role of energy cutoff on the convergence of molecular properties

Christophe Raynaud , Laurent Maron , Franck Jolibois , Jean-Pierre Daudey , Pierre M. Esteves et al.

Chemical Physics Letters, 2005, 414, pp.161-165. ⟨10.1016/j.cplett.2005.08.034⟩

Article dans une revue istex hal-00382889v1

1,4-vs 1,3-prototropic mechanism for intramolecular double proton transfer reaction in monothiooxalic acid. Theoretical investigation of potential energy surface

Christophe Raynaud , Jean-Pierre Daudey , Laurent Maron , Franck Jolibois

Journal of Physical Chemistry A, 2005, 109, pp.9646-9652. ⟨10.1021/jp052782u⟩

Article dans une revue istex hal-00382884v1

Hydrogen for Fluorine Exchange in C6F6 and C6F5H by Monomeric [1,3,4-(Me3C)3C5H2]2CeH: Experimental and Computational Studies

Laurent Maron , E. L. Werkema , L. Perrin , O. Eisenstein , R. A. Andersen

Journal of the American Chemical Society, 2005, 127, pp.279

Article dans une revue hal-00020400v1

Hydrogen for Fluorine Exchange in CH4-xFx Monomeric by [1,2,4-(Me3C)3C5H2]2CeH: Experimental and Computational Studies

E. L. Werkema , E. Messines , L. Perrin , Laurent Maron , O. Eisenstein et al.

Journal of the American Chemical Society, 2005, 127, pp.7781

Article dans une revue hal-00020392v1

Reconsidering Car–Parrinello molecular dynamics using direct propagation of molecular orbitals developed upon Gaussian type atomic orbitals

Christophe Raynaud , Laurent Maron , Jean-Pierre Daudey , Franck Jolibois

Physical Chemistry Chemical Physics, 2004, 2004 (6), pp.4226-4232. ⟨10.1039/b402163k⟩

Article dans une revue istex hal-00410105v1

Two-electron pseudopotential investigation of the electronic structure of the CaAr molecule

Fernand Spiegelman , Laurent Maron , W.H. Breckenridge , J.-M. Mestdagh , J.P. Visticot

The Journal of Chemical Physics, 2002, 117 (16), pp.7534-7550. ⟨10.1063/1.1506921⟩

Article dans une revue hal-00144543v1

Dinuclear Reactivity Between the Two Metal Centers

Laurent Maron , Philippe Kalck

Kalck, P. Modes of Cooperative Effects in Dinuclear Complexes, 70, Springer International Publishing, pp.157-205, 2023, Topics in Organometallic Chemistry, 978-3-031-32250-1; 978-3-031-32249-5. ⟨10.1007/3418_2023_88⟩

Chapitre d'ouvrage hal-04707626v1

Involvement of an acetato ligand in the reductive elimination step of the rhodium-catalyzed methanol carbonylation

Duc Hanh Nguyen , Nicolas Lassauque , T. Davin , Laurent Maron , Carole Le Berre et al.

Plombeiro, A.J.L. Advances in Organometallic Chemistry and Catalysis: The Silver/Gold Jubilee International Conference on Organometallic Chemistry Celebratory Book, 20, John Wiley & Sons, Inc., pp.259-268, 2014, 978-1-118-74295-2

Chapitre d'ouvrage hal-02042504v1

Catalytic Behavior of Rare-Earth Borohydride Complexes in Polymerization of Polar Monomers

Sophie M. Guillaume , Laurent Maron , Peter W. Roesky

J.-C. G. Bünzli, V. K. Pecharsky. Handbook on the Physics and Chemistry of Rare Earths, Elsevier Science, pp.1-86, 2014, ⟨10.1016/B978-0-444-62711-7.00259-0⟩

Chapitre d'ouvrage hal-00881590v1

Phosphine Based Gold Catalysts for the Asymmetric Hydroamination of Alkenes: Effects of Silver, Anion and Solven

Christophe Michon , Marc O. Abadie , Fernando Torres Medina , Xavier Trivelli , Frédéric Capet et al.

28th International Conference on Organometallic Chemistry, ICOMC 2018, Jul 2018, Florence (IT), France

Communication dans un congrès hal-04411195v1

Advanced Solid-State NMR as a Key Tool for the Deeper Understanding of Heterogeneous Catalysts

D. Grekov , Nicolas Merle , Kai Chung Szeto , Yassine Bouhoute , Iker Del rosal et al.

ZING conference, May 2016, Varna, Bulgaria

Communication dans un congrès hal-02309346v1

17O MAS NMR as a tool for understanding the molecular structure of supported catalysts

D. Grekov , L. Delevoye , Régis M. Gauvin , Yassine Bouhoute , Mostafa Taoufik et al.

SMARTER 5, Sep 2016, Bayreuth, Germany

Communication dans un congrès hal-02309317v1

Accessing the structure of well-defined grafted catalysts with experimental and first principles 17O Solid State NMR methodology

D. Grekov , Yassine Bouhoute , Iker Del rosal , Mostafa Taoufik , Régis M. Gauvin et al.

Journées Nord-Ouest Européennes des Jeunes Chercheurs (JNOEJC), Jun 2016, Lille, France

Communication dans un congrès hal-02309335v1

Advanced solid-state NMR as a key tool for the deeper understanding of heterogeneous catalysts

Régis M. Gauvin , L. Delevoye , Mostafa Taoufik , Iker Del rosal , Laurent Maron

Indo-French Symposium 2016 “Catalysis for Sustainable and Environmental Chemistry” – NCL, Jun 2016, Lille, France

Communication dans un congrès hal-02309342v1

Advanced Solid-State NMR as a Key Tool for the Deeper Understanding of Heterogeneous Catalysts

D. Grekov , Nicolas Merle , Kai Chung Szeto , Yassine Bouhoute , Iker Del rosal et al.

1st French-Portuguese NMR GERM Conference, Apr 2016, Lisbon, Portugal

Communication dans un congrès hal-02309343v1

Well-defined group VI oxo derivatives supported on silica by SOMC: Model of industrial olefin metathesis catalyst

Nicolas Merle , Yassine Bouhoute , Kai Chung Szeto , Aimery de Mallmann , Iker Del rosal et al.

251th ACS Meeting, Mar 2016, San Diego, United States

Communication dans un congrès hal-02333529v1

17O MAS NMR Studies of oxo-based Olefin Metathesis Catalysts: a Critical Assessment of Signal Enhancement Methods

D. Grekov , L. Delevoye , Régis M. Gauvin , Yassine Bouhoute , Mostafa Taoufik et al.

Conférence du Réseau RMN Grand Bassin Parisien, Sep 2016, Rennes, France

Communication dans un congrès hal-02309320v1

17O MAS NMR as a tool for understanding the molecular structure of supported catalysts

Denys Grekov , Laurent Delevoye , Régis Gauvin , Yassine Bouhoute , Mostafa Taoufik et al.

Congrès du Groupement d’Études de Résonance Magnétique (GERM 2015), May 2015, Sète, France

Communication dans un congrès hal-02309314v1

17O MAS NMR as a tool for understanding the molecular structure of supported catalysts

Denys Grekov , Laurent Delevoye , Régis Gauvin , Yassine Bouhoute , Mostafa Taoufik et al.

Congrès de la Société Chimique de France (SCF 2015), Jul 2015, Lille, France

Communication dans un congrès hal-02309310v1

On the Track to Silica-Supported Tungsten Oxo Metathesis Catalysts: Input from 17O Solid-State NMR

Nicolas Merle , Guillaume Girard , Nicolas Popoff , Julien Trébosc , Iker Del rosal et al.

9th Alpine Conference, Sep 2015, Chamonix, France

Communication dans un congrès hal-02310779v1

Ligands cyclopentadiényle à bras phosphazène : vers de nouveaux complexes géométriquement contraints

D. Bourissou , C. Freund , Laurent Maron , B. Martin-Vaca

Ligands cyclopentadiényle à bras phosphazène : vers de nouveaux complexes géométriquement contraints, May 2006, NOIRMOUTIER, France

Communication dans un congrès hal-00156787v1

Ambiphilic PB and PA1 ligands : from M Lewis acid interaction to M-X activation

Sylvain Bontemps , G. Bouhadir , D. Bourissou , Laurent Maron , Karinne Miqueu et al.

Ambiphilic PB and PA1 ligands : from M Lewis acid interaction to M-X activation, Aug 2008, Rennes, France

Communication dans un congrès hal-00399259v1

Metal boron interactions from ambiphilic phosphine-borane ligands

Sylvain Bontemps , G. Bouhadir , D. Bourissou , Laurent Maron , Karinne Miqueu et al.

Metal boron interactions from ambiphilic phosphine-borane ligands, Sep 2008, Spain

Communication dans un congrès hal-00378985v1

XXXth Workshop on Rare Earth Elements

M. Schappacher , P. Dessuge , Noémi Barros , Laurent Maron , Sophie M. Guillaume

MMA Polymerization initiated by rare earth (boro)hydride complexes: a combined experimental and computational approach, 2007, Koeln, Germany

Communication dans un congrès hal-00341611v1