Laurent Maron

489
Documents

Publications

Publications

On the Mechanism of Acrylate and Propionate Silyl Esters Synthesis by Ruthenium-Catalyzed Coupling of CO2 with C2H4 in the Presence of Hydrosilanes: Combined Experimental and Computational Investigations

Kana Kunihiro , Thayalan Rajeshkumar , Laurent Maron , Svetlana Heyte , Sébastien Paul et al.
Molecular Catalysis, 2025, 570, pp.114660. ⟨10.1016/j.mcat.2024.114660⟩
Article dans une revue hal-04836282 v1

Directed Aromatic Deuteration and Tritiation of Pharmaceuticals by Heavy Alkali Metal Amide Catalysts

Hui-Zhen Du , Jingwei Li , Stella Christodoulou , Si-Yuan Li , Yun-Shu Cui et al.
ACS Catalysis, 2024, 14 (13), pp.9640-9647. ⟨10.1021/acscatal.4c01807⟩
Article dans une revue hal-04707648 v1

Homoleptic Organolanthanum-Catalyzed Carbohalogenation

Huiyue Yang , Thayalan Rajeshkumar , Shanshan Liu , Hengjiang Cong , Guipeng Yu et al.
Journal of the American Chemical Society, 2024, 146 (36), pp.25361-25370. ⟨10.1021/jacs.4c10445⟩
Article dans une revue hal-04707657 v1

Multi-electron redox reactivity of a samarium(II) hydrido complex

Xianghui Shi , Peng Deng , Thayalan Rajeshkumar , Laurent Maron , Jianhua Cheng
Chemical Science, 2024, 15 (30), pp.11965-11971. ⟨10.1039/d4sc03104k⟩
Article dans une revue hal-04707637 v1

Synthesis, structure and redox properties of single-atom bridged diuranium complexes supported by aryloxides

Fang-Che Hsueh , Luciano Barluzzi , Thayalan Rajeshkumar , Rosario Scopelliti , Ivica Zivkovic et al.
Dalton Transactions, 2024, 53 (32), pp.13416-13426. ⟨10.1039/d4dt01819b⟩
Article dans une revue hal-04707673 v1

Electronic Delocalization and σ-Aromaticity in Heterometallic Cluster with Multiple Thorium-Palladium Bonds

Weiming Sheng , Thayalan Rajeshkumar , Yue Zhao , Laurent Maron , Congqing Zhu
Journal of the American Chemical Society, 2024, 146 (18), pp.12790-12798. ⟨10.1021/jacs.4c03058⟩
Article dans une revue hal-04707668 v1

Oxidative Addition of E-H (E=C, N) Bonds to Transient Uranium(II) Centers

Wei Fang , Yafei Li , Tianze Zhang , Thayalan Rajeshkumar , Iker Del rosal et al.
Angewandte Chemie International Edition, 2024, 63 (32), ⟨10.1002/anie.202407339⟩
Article dans une revue hal-04707677 v1
Image document

Photolysis-driven bond activation by thorium and uranium tetraosmate polyhydride complexes

Christopher Ye , Iker del Rosal , Sheridon Kelly , I. Joseph Brackbill , Laurent Maron et al.
Chemical Science, In press, ⟨10.1039/D4SC02380C⟩
Article dans une revue hal-04611467 v1

Oxidation-induced ambiphilicity triggers N-N bond formation and dinitrogen release in octahedral terminal molybdenum(<sc>v</sc>) nitrido complexes

C. Christopher Almquist , Thayalan Rajeshkumar , H. D. A. Chathumal Jayaweera , Nicole Removski , Wen Zhou et al.
Chemical Science, 2024, 15 (14), pp.5152-5162. ⟨10.1039/d4sc00090k⟩
Article dans une revue hal-04707633 v1
Image document

Synthesis, Structure, and Bonding of Actinide–Rhenium Polyhydrides

Christopher Ye , Iker del Rosal , Sheridon Kelly , Erik Ouellette , Laurent Maron et al.
Inorganic Chemistry, In press, ⟨10.1021/acs.inorgchem.4c03449⟩
Article dans une revue hal-04749940 v1

Hypervalent zinc( <span style="font-variant:small-caps;">i</span> ) complexes with an <i>NNNN</i> -macrocycle: C–H bond activation across the zinc( <span style="font-variant:small-caps;">i</span> )–zinc( <span style="font-variant:small-caps;">i</span> ) bond

Pritam Mahawar , Thayalan Rajeshkumar , Thomas P. Spaniol , Laurent Maron , Jun Okuda
Chemical Communications, 2024, 60, pp.11359-11362. ⟨10.1039/D4CC04266B⟩
Article dans une revue hal-04844111 v1

Spectroscopic and Computational Evidence of Uranium Dihydrogen Complexes

I. Joseph Brackbill , Thayalan Rajeshkumar , Laurent Maron , Robert G. Bergman , John Arnold
Journal of the American Chemical Society, 2024, 146 (2), pp.1257-1261. ⟨10.1021/jacs.3c12636⟩
Article dans une revue hal-04707664 v1

Synthesis and Reactivity of Discrete Europium(II) Hydride Complexes

Georgia M. Richardson , Matthew J. Evans , Thayalan Rajeshkumar , Jordan A. J. Mccone , Scott A. Cameron et al.
Chemistry - A European Journal, 2024, 30 (27), ⟨10.1002/chem.202400681⟩
Article dans une revue hal-04707660 v1

Two-Electron Redox Reactivity of Thorium Supported by Redox-Active Tripodal Frameworks

Fang-Che Hsueh , Damien Chen , Thayalan Rajeshkumar , Rosario Scopelliti , Laurent Maron et al.
Angewandte Chemie International Edition, 2024, 63 (6), ⟨10.1002/anie.202317346⟩
Article dans une revue hal-04707680 v1

Rare-earth metal complexes bearing electrophilic and nucleophilic carbon centres and their unique reactivity patterns towards pyridine derivatives

Weikang Wu , Thayalan Rajeshkumar , Shan Zhu , Fuxiang Chai , Dongjing Hong et al.
Chemical Science, 2024, pp.10.1039.D4SC04197F. ⟨10.1039/D4SC04197F⟩
Article dans une revue hal-04844097 v1

Stabilization and One Electron Reduction of a Silicon Analogue of a Carboxylic Acid Anhydride

Yixiao Jiang , K. Yuvaraj , Thayalan Rajeshkumar , Li Feng Lim , Nicholas Cox et al.
Chemistry - A European Journal, 2024, 30 (15), ⟨10.1002/chem.202303949⟩
Article dans une revue hal-04707638 v1
Image document

Efficient Machine-Learning-Based New Tools to Design Eutectic Mixtures and Predict Their Viscosity

Stella Christodoulou , Camille Cousseau , Emmanuelle Limanton , Lorris Toucouere , Fabienne Gauffre et al.
ACS Sustainable Chemistry & Engineering, 2024, 12 (52), pp.18537-18554. ⟨10.1021/acssuschemeng.4c05869⟩
Article dans une revue hal-04867220 v1

Straightforward construction of a rare-earth diphosphanato complex from white phosphorus: synthesis and reactivity

Fangjun Zhang , Iker Del rosal , Keyu Han , Jie Zhang , Laurent Maron et al.
Inorganic Chemistry Frontiers, 2024, 11 (6), pp.1742-1753. ⟨10.1039/d3qi02680a⟩
Article dans une revue hal-04707645 v1

Rare-Earth Metal Complexes Bearing Electrophilic Carbon and Strongly Polarized Metallacyclopropane Moiety: Synthesis and Diverse Reactivity toward Small Molecules

Weikang Wu , Thayalan Rajeshkumar , Dongjing Hong , Shan Zhu , Zeming Huang et al.
Inorganic Chemistry, 2024, ⟨10.1021/acs.inorgchem.4c02316⟩
Article dans une revue hal-04707672 v1

Planar Tetranuclear Uranium Hydride Cluster Supported by <i>ansa</i>-Bis(cyclopentadienyl) Ligands

Kai Li , Iker Del Rosal , Yue Zhao , Laurent Maron , Congqing Zhu
Angewandte Chemie International Edition, 2024, 63 (29), ⟨10.1002/anie.202405494⟩
Article dans une revue hal-04707659 v1
Image document

The photo-isomerization of the cyclononatetraenyl ligand and related rare earth complexes

Lucie Pedussaut , Nolwenn Mahieu , Camille Chartier , Thayalan Rajeshkumar , Maxime Tricoire et al.
Chemical Science, 2024, 15 (46), pp.19273-19282. ⟨10.1039/d4sc04767b⟩
Article dans une revue hal-04831267 v1

Hydrogenolysis of Cationic Half-Sandwich Zinc Complexes Containing a Chelating Amine: Facile Cleavage of Zinc-Carbon Bond by Dihydrogen to Give Zinc Hydride Cations

Pritam Mahawar , Thayalan Rajeshkumar , Thomas P. Spaniol , Laurent Maron , Jun Okuda
Chemistry - A European Journal, 2024, 30 (42), ⟨10.1002/chem.202401262⟩
Article dans une revue hal-04707654 v1

Iron promoted end-on dinitrogen-bridging in heterobimetallic complexes of uranium and lanthanides

Nadir Jori , Juan J. Moreno , R. A. Keerthi Shivaraam , Thayalan Rajeshkumar , Rosario Scopelliti et al.
Chemical Science, 2024, 15 (18), pp.6842-6852. ⟨10.1039/d4sc01050g⟩
Article dans une revue hal-04707675 v1

Panoply of P: An Array of Rhenium-Phosphorus Complexes Generated from a Transition Metal Anion

David P. Hales , Thayalan Rajeshkumar , Angela A. Shiau , Guodong Rao , Erik T. Ouellette et al.
Inorganic Chemistry, 2024, 63 (24), pp.11296-11310. ⟨10.1021/acs.inorgchem.4c01085⟩
Article dans une revue hal-04707639 v1

Triple Inverse Sandwich versus End-On Diazenido: Bonding Motifs across a Series of Rhenium-Lanthanide and -Actinide Complexes

Erik T. Ouellette , I. Joseph Brackbill , Amy E. Kynman , Stella Christodoulou , Laurent Maron et al.
Inorganic Chemistry, 2024, 63 (16), pp.7177-7188. ⟨10.1021/acs.inorgchem.3c04248⟩
Article dans une revue hal-04707647 v1

Siloxide tripodal ligands as a scaffold for stabilizing lanthanides in the+4 oxidation state

Maxime Tricoire , Fang-Che Hsueh , Megan Keener , Thayalan Rajeshkumar , Rosario Scopelliti et al.
Chemical Science, 2024, 15 (18), pp.6874-6883. ⟨10.1039/d4sc00051j⟩
Article dans une revue hal-04707674 v1

Anti-Selective Carbosilylation: Nickel-Catalyzed Multicomponent Reaction of Solid Me<sub>3</sub>SiZnI

Revathi Chandrasekaran , Keerthika Selvam , Thayalan Rajeshkumar , Tamilselvi Chinnusamy , Laurent Maron et al.
Angewandte Chemie International Edition, 2024, 63 (23), ⟨10.1002/anie.202318689⟩
Article dans une revue hal-04707661 v1

Rare-earth metal ethylene and ethyne complexes

Wen Jiang , Thayalan Rajeshkumar , Mengyue Guo , Yuejian Lin , Laurent Maron et al.
Chemical Science, 2024, 15 (10), pp.3495-3501. ⟨10.1039/d3sc06599e⟩
Article dans une revue hal-04707663 v1

Light-induced splitting of P-C bonds in a lanthanum(<sc>iii</sc>) hemiphosphinal complex

Benjamin Wittwer , Karl N. Mccabe , Daniel Leitner , Michael Seidl , Laurent Maron et al.
Inorganic Chemistry Frontiers, 2024, 11 (14), ⟨10.1039/d4qi00868e⟩
Article dans une revue hal-04707624 v1

Dihydrogen Cleavage by a Zinc-Zinc Bond of a Heteroleptic Dizinc(I) Cation

Pritam Mahawar , Thayalan Rajeshkumar , Thomas P. Spaniol , Laurent Maron , Jun Okuda
Inorganic Chemistry, 2024, 63 (18), pp.8493-8501. ⟨10.1021/acs.inorgchem.4c01116⟩
Article dans une revue hal-04707635 v1

Reductive Dimerization of Alkenes and Allenes Enabled by Photochemically Activated Zinc-Zinc Bonded Compounds

Shuilian Xu , Qiujie Wang , Thayalan Rajeshkumar , Shengjie Jiang , Laurent Maron et al.
Journal of the American Chemical Society, 2024, 146 (28), pp.19590-19598. ⟨10.1021/jacs.4c07390⟩
Article dans une revue hal-04707646 v1

Temperature induced single-crystal to single-crystal transformation of uranium azide complexes

Kai Li , Thayalan Rajeshkumar , Yue Zhao , Tianwei Wang , Laurent Maron et al.
Chemical Communications, 2024, 60 (21), pp.2966-2969. ⟨10.1039/d4cc00546e⟩
Article dans une revue hal-04707658 v1
Image document

π-Bonding of Group 11 Metals to a Tantalum Alkylidyne Alkyl Complex Promotes Unusual Tautomerism to Bis-alkylidene and CO 2 to Ketenyl Transformation

Abdelhak Lachguar , Iker del Rosal , Laurent Maron , Erwann Jeanneau , Laurent Veyre et al.
Journal of the American Chemical Society, 2024, ⟨10.1021/jacs.4c02172⟩
Article dans une revue hal-04630141 v1

Steric control of Mg-Mg bond formation <i>vs.</i> N<sub>2</sub> activation in the reduction of bulky magnesium diamide complexes

Rahul Mondal , Matthew J. Evans , Dat T. Nguyen , Thayalan Rajeshkumar , Laurent Maron et al.
Chemical Communications, 2024, 60 (8), pp.1016-1019. ⟨10.1039/d3cc05787a⟩
Article dans une revue hal-04707627 v1

Dinitrogen Reduction and Functionalization by a Siloxide Supported Thulium-Potassium Complex for the Formation of Ammonia or Hydrazine Derivatives

R. A. Keerthi Shivaraam , Thayalan Rajeshkumar , Rosario Scopelliti , Ivica Z̆ivković , Laurent Maron et al.
Angewandte Chemie International Edition, 2024, pp.e202414051. ⟨10.1002/anie.202414051⟩
Article dans une revue hal-04844099 v1
Image document

CO<sub>2</sub> cleavage by tantalum/M (M = iridium, osmium) heterobimetallic complexes

Abdelhak Lachguar , Christopher Z Ye , Sheridon N Kelly , Erwann Jeanneau , Iker del Rosal et al.
Chemical Communications, 2024, 60 (61), pp.7878-7881. ⟨10.1039/D4CC02207F⟩
Article dans une revue hal-04738526 v1

Covalency-Driven Differences in the Hydrogenation Chemistry of Lanthanide- and Actinide-Based Frustrated Lewis Pairs

I. Joseph Brackbill , Thayalan Rajeshkumar , Iskander Douair , Laurent Maron , Michael A. Boreen et al.
Journal of the American Chemical Society, 2024, 146 (31), pp.21932-21947. ⟨10.1021/jacs.4c06777⟩
Article dans une revue hal-04707662 v1
Image document

Isolation of C1 through C4 derivatives from CO using heteroleptic uranium( iii ) metallocene aryloxide complexes

Robert Ward , Iker Del Rosal , Steven Kelley , Laurent Maron , Justin Walensky
Chemical Science, 2023, 14 (8), pp.2024-2032. ⟨10.1039/d2sc06375a⟩
Article dans une revue hal-04218352 v1

La-Catalyzed Decarbonylation of Formamides and Its Applications

Shaocheng Li , Thayalan Rajeshkumar , Jincheng Liu , Laurent Maron , Xigeng Zhou
Organic Letters, 2023, 25 (1), pp.163-168. ⟨10.1021/acs.orglett.2c03981⟩
Article dans une revue hal-04707644 v1

Heterometallic Clusters with Cerium-Transition-Metal Bonding Supported by Nitrogen-Phosphorus Ligands

Xiong Sun , Jinghang Shen , Thayalan Rajeshkumar , Laurent Maron , Congqing Zhu
Inorganic Chemistry, 2023, 62 (39), pp.16077-16083. ⟨10.1021/acs.inorgchem.3c02259⟩
Article dans une revue hal-04707656 v1
Image document

Dinitrogen cleavage and hydrogenation to ammonia with a uranium complex

Xiaoqing Xin , Iskander Douair , Yue Zhao , Shuao Wang , Laurent Maron et al.
National Science Review, 2023, 10 (2), ⟨10.1093/nsr/nwac144⟩
Article dans une revue hal-04349711 v1

Synthesis and Reactivity of Redox-Active Cerium(IV) Aryloxide Complexes

Hoang-Long Pham , Thayalan Rajeshkumar , Lily Ueh-Hsi Wang , Yat Hei Ng , Kai-Hong Wong et al.
Organometallics, 2023, 42 (11), pp.1094-1105. ⟨10.1021/acs.organomet.2c00569⟩
Article dans une revue hal-04707643 v1

Lanthanum-Catalyzed Stereospecific Cross-Coupling of Propargylic Substrates with Grignard Reagents

Dandan Sun , Thayalan Rajeshkumar , Yifan Li , Jiaxin Xu , Runkai Chen et al.
Organic Letters, 2023, 25 (36), pp.6730-6735. ⟨10.1021/acs.orglett.3c02600⟩
Article dans une revue hal-04707649 v1

Synthesis and Reactivity of a Zinc Diazoalkyl Complex: [3+2] Cycloaddition Reaction with Carbon Monoxide

Shengjie Jiang , Yanping Cai , Thayalan Rajeshkumar , Iker Del rosal , Laurent Maron et al.
Angewandte Chemie International Edition, 2023, 62 (34), ⟨10.1002/anie.202307244⟩
Article dans une revue hal-04707653 v1

Heterobimetallic Hydrides with a Germanium(II)-Zinc Bond

Thomas P. P. Spaniol , Jun Okuda , Pritam Mahawar , Thayalan Rajeshkumar , Laurent Maron
Chemistry - A European Journal, 2023, 29 (53), ⟨10.1002/chem.202301496⟩
Article dans une revue hal-04707651 v1

Molybdenum carbonyl assisted reductive tetramerization of CO by activated magnesium(i) compounds: squarate dianion vs. metallo-ketene formation

K. Yuvaraj , Jeremy C. Mullins , Thayalan Rajeshkumar , Iskander Douair , Laurent Maron et al.
Chemical Science, 2023, 14 (19), pp.5188-5195. ⟨10.1039/d3sc01487h⟩
Article dans une revue hal-04707630 v1

Photocatalytic dechlorination of unactivated chlorocarbons including PVC using organolanthanide complexes

Amy E. Kynman , Stella Christodoulou , Erik T. Ouellette , Appie Peterson , Sheridon N. Kelly et al.
Chemical Communications, 2023, 59 (73), pp.10924-10927. ⟨10.1039/d3cc02906a⟩
Article dans une revue hal-04707666 v1

Quest for Active Species in Al/B-Catalyzed CO<sub>2</sub> Hydrosilylation

Sheetal Kathayat Bisht , Deepti Sharma , Ramkumar Kannan , Thayalan Rajeshkumar , Laurent Maron et al.
Inorganic Chemistry, 2023, 62 (45), pp.18543-18552. ⟨10.1021/acs.inorgchem.3c02771⟩
Article dans une revue hal-04707667 v1

Dinitrogen cleavage by a dinuclear uranium(III) complex

Nadir Jori , Megan Keener , Thayalan Rajeshkumar , Rosario Scopelliti , Laurent Maron et al.
Chemical Science, 2023, 14 (46), pp.13485-13494. ⟨10.1039/d3sc05253b⟩
Article dans une revue hal-04707671 v1

A Route to Stabilize Uranium(II) and Uranium(I) Synthons in Multimetallic Complexes

R. Keerthi Shivaraam , Megan Keener , Dieuwertje Modder , Thayalan Rajeshkumar , Ivica Živković et al.
Angewandte Chemie International Edition, 2023, 62 (23), pp.e202304051. ⟨10.1002/anie.202304051⟩
Article dans une revue hal-04281546 v1

Multielectron Redox Chemistry of Uranium by Accessing the plus II Oxidation State and Enabling Reduction to a U(I) Synthon

Megan Keener , R. A. Keerthi Shivaraam , Thayalan Rajeshkumar , Maxime Tricoire , Rosario Scopelliti et al.
Journal of the American Chemical Society, 2023, 145 (29), pp.16271-16283. ⟨10.1021/jacs.3c05626⟩
Article dans une revue hal-04707676 v1

Variable Ca-C<sub>aryl</sub> Hapticity and its Consequences in Arylcalcium Dimers

Kyle G. Pearce , Chiara Dinoi , Ryan J. Schwamm , Laurent Maron , Mary F. Mahon et al.
ADVANCED SCIENCE, 2023, 10 (31), ⟨10.1002/advs.202304765⟩
Article dans une revue hal-04707632 v1
Image document

C (1)-Symmetric {cyclopentadienyl/indenyl}-metallocene catalysts: synthesis, structure, isospecific polymerization of propylene and stereocontrol mechanism

Dimitra Theodosopoulou , Miguel Alonso de La Peña , Sary Abou Derhamine , Iskander Douair , Thierry Roisnel et al.
Dalton Transactions, 2023, 52 (25), pp.8620-8630. ⟨10.1039/d3dt01306e⟩
Article dans une revue hal-04166074 v1

A binuclear guanidinate yttrium carbyne complex: unique reactivity toward unsaturated C-N, C-O and C-S bonds

Wen Jiang , Feng Kong , Iker Del rosal , Meng Li , Kai Wang et al.
Chemical Science, 2023, ⟨10.1039/d3sc03483f⟩
Article dans une revue hal-04707640 v1

Experimental and Computational Studies on Uranium Diazomethanediide Complexes

Tongyu Li , Dongwei Wang , Yi Heng , Guohua Hou , Guofu Zi et al.
Angewandte Chemie International Edition, 2023, 62 (50), ⟨10.1002/anie.202313010⟩
Article dans une revue hal-04707669 v1
Image document

On the use of 17 O NMR for understanding molecular and silica-grafted tungsten oxo siloxide complexes

Y. Bouhoute , D. Grekov , N. Merle , K. Szeto , C. Larabi et al.
Dalton Transactions, 2023, 52 (28), pp.9573-9581. ⟨10.1039/D3DT01593A⟩
Article dans une revue hal-04238255 v1

Aryl C-H bond functionalization with diphenyldiazomethane induced by rare-earth metal alkyl complexes

Dianjun Guo , Thayalan Rajeshkumar , Shan Zhu , Qingbing Yuan , Dongjing Hong et al.
Dalton Transactions, 2023, 52 (32), pp.11315-11324. ⟨10.1039/d3dt01714a⟩
Article dans une revue hal-04707670 v1

Bonding and Reactivity in Terminal versus Bridging Arenide Complexes of Thorium Acting as Th II Synthons

Fang‐che Hsueh , Thayalan Rajeshkumar , Bastiaan Kooij , Rosario Scopelliti , Kay Severin et al.
Angewandte Chemie International Edition, 2023, 62 (9), ⟨10.1002/anie.202215846⟩
Article dans une revue hal-04184322 v1
Image document

Isolation and redox reactivity of cerium complexes in four redox states

Fang-Che Hsueh , Thayalan Rajeshkumar , Laurent Maron , Rosario Scopelliti , Andrzej Sienkiewicz et al.
Chemical Science, 2023, 14 (22), pp.6011-6021. ⟨10.1039/d3sc01478a⟩
Article dans une revue hal-04311295 v1

Monodentate Alkoxy/Aryloxy Anchored Yttrium Dihydrides; Anticipated Outcomes and Surprises

Yi Yang , Iker del Rosal , Michael J. Ferguson , Robert Mcdonald , Laurent Maron et al.
Inorganic Chemistry, 2023, 62 (28), pp.11179-11187. ⟨10.1021/acs.inorgchem.3c01319⟩
Article dans une revue hal-04707631 v1

Heterotrimetallic clusters with U-Ni-Ge and U-Ni-Sn units

Kai Li , Genfeng Feng , Stella Christodolou , Yue Zhao , Laurent Maron et al.
Polyhedron, 2023, 243, ⟨10.1016/j.poly.2023.116548⟩
Article dans une revue hal-04707655 v1

Isolation of C1 through C4 derivatives from CO using heteroleptic uranium(III) metallocene aryloxide complexes (vol 14, pg 2024, 2023)

Robert J. Ward , Iker Del Rosal , Steven P. Kelley , Laurent Maron , Justin R. Walensky
Chemical Science, 2023, 14 (12), pp.3385. ⟨10.1039/d3sc90046k⟩
Article dans une revue hal-04707634 v1

Multimetallic Uranium Nitride Cubane Clusters from Dinitrogen Cleavage

Mikhail S. Batov , Iker Del rosal , Rosario Scopelliti , Farzaneh Fadaei-Tirani , Ivica Zivkovic et al.
Journal of the American Chemical Society, 2023, 145 (48), pp.26435-26443. ⟨10.1021/jacs.3c10617⟩
Article dans une revue hal-04707678 v1

Highly Regioselective Propargylation/Allenylation of Organolanthanum Reagents with Aldehydes

Xue-Lin Dai , Jingdi Ran , Thayalan Rajeshkumar , Zhengping Xu , Shanshan Liu et al.
Organic Letters, 2023, 25 (17), pp.3060-3065. ⟨10.1021/acs.orglett.3c00824⟩
Article dans une revue hal-04284945 v1

Mechanistic Investigations on Bismuth Catalyzed Reduction of Ketones and Phosphine Oxides

Annabel Benny , Deepti Sharma , Thayalan Ankur , Thayalan Rajeshkumar , Laurent Maron et al.
Chemistry - A European Journal, 2023, 29 (42), ⟨10.1002/chem.202300588⟩
Article dans une revue hal-04707665 v1

Coordination and Activation of N<sub>2</sub> at Low-Valent Magnesium using a Heterobimetallic Approach: Synthesis and Reactivity of a Masked Dimagnesium Diradical

Rahul Mondal , Matthew J. J. Evans , Thayalan Rajeshkumar , Laurent Maron , Cameron Jones
Angewandte Chemie International Edition, 2023, 62 (37), ⟨10.1002/anie.202308347⟩
Article dans une revue hal-04707629 v1

Magnesium(I) Reduction of Aluminum(III) Hydride Complexes: Generation of Mixed Valence Aluminum (Al<SUP>I</SUP>/Al<SUP>0</SUP>) Hydride Cluster Compounds, [Al<sub>6</sub>H<sub>8</sub>(NR<sub>3</sub>)<sub>2</sub>\Mg(β-diketim inate)\<sub>4</sub>]

Sneha Mullassery , K. Yuvaraj , Deepak Dange , Dafydd D. L. Jones , Iker Del Rosal et al.
Angewandte Chemie International Edition, 2023, 62 (30), ⟨10.1002/anie.202305582⟩
Article dans une revue hal-04707636 v1

Organotitanium Complexes Supported by a Dianionic Pentadentate Ligand

Daniel Beh , Alejandro Cuellar de Lucio , Iker del Rosal , Laurent Maron , Denis Spasyuk et al.
Organometallics, 2023, 42 (11), pp.1149-1157. ⟨10.1021/acs.organomet.2c00609⟩
Article dans une revue hal-04218412 v1

Heterometallic Clusters with Uranium-Metal Bonds Supported by Double-Layer Nitrogen-Phosphorus Ligands

Qin Zhu , Wei Fang , Laurent Maron , Congqing Zhu
Accounts of Chemical Research, 2022, 55 (12), pp.1718-1730. ⟨10.1021/acs.accounts.2c00180⟩
Article dans une revue hal-03714652 v1

Molecular and Electronic Structure of Linear Uranium Metallocenes Stabilized by Pentabenzyl-Cyclopentadienyl Ligands

Sascha Löffler , Frank Heinemann , Ambre Carpentier , Laurent Maron , Karsten Meyer
Organometallics, 2022, 41 (15), pp.2077-2087. ⟨10.1021/acs.organomet.2c00217⟩
Article dans une revue hal-03969656 v1

Synthesis, Characterization, and Reactivity of a Hydrido- and Imido-Bridged Dinuclear Ytterbium(III) Complex

Qingqing Wen , Thayalan Rajeshkumar , Laurent Maron , Xuebing Leng , Yaofeng Chen
Angewandte Chemie International Edition, 2022, 61 (25), ⟨10.1002/anie.202200540⟩
Article dans une revue hal-03714649 v1
Image document

The mechanism of Fe induced bond stability of uranyl( v )

Tonya Vitova , Radmila Faizova , Jorge Amaro-Estrada , Laurent Maron , Tim Pruessmann et al.
Chemical Science, 2022, 13 (37), pp.11038-11047. ⟨10.1039/d2sc03416f⟩
Article dans une revue hal-04005908 v1
Image document

A Versatile Strategy for the Formation of Hydride-Bridged Actinide-Iridium Multimetallics

Christopher Z Ye , Iker Del rosal , Michael A Boreen , Erik T Ouellette , Dominic Russo et al.
Chemical Science, 2022, ⟨10.1039/D2SC04903A⟩
Article dans une revue hal-03909474 v1
Image document

Photochemical Synthesis of Transition Metal-Stabilized Uranium(VI) Nitride Complexes

Xiaoqing Xin , Iskander Douair , Thayalan Rajeshkumar , Yue Zhao , Shuao Wang et al.
Nature Communications, 2022, 13 (1), pp.3809. ⟨10.1038/s41467-022-31582-z⟩
Article dans une revue hal-03956091 v1

Synthesis of Molecular Phenylcalcium Derivatives: Application to the Formation of Biaryls

Andrew S. S. Wilson , Kyle G. Pearce , Chiara Dinoi , Michael S. Hill , Mary F. Mahon et al.
Angewandte Chemie International Edition, 2022, ⟨10.1002/anie.202200305⟩
Article dans une revue hal-03714648 v1

A Combined Experimental and Theoretical Investigation of Arene-Supported Actinide and Ytterbium Tetraphenolate Complexes

Francis Y. T. Lam , Jordann A. L. Wells , Tatsumi Ochiai , Connor J. Halliday , Karl N. Mccabe et al.
Inorganic Chemistry, 2022, 61 (11), pp.4581-4591. ⟨10.1021/acs.inorgchem.1c03365⟩
Article dans une revue hal-03714643 v1
Image document

Spectroscopic, Magnetic, and Computational Investigations on a Series of Rhenium(III) Cyclopentadienide β-diketiminate Halide and Pseudohalide Complexes

Erik Ouellette , Jorge Ivan Amaro Estrada , Daniel Lussier , Khetpakorn Chakarawet , Trevor Lohrey et al.
Organometallics, 2022, 41 (22), pp.3128-3137. ⟨10.1021/acs.organomet.1c00516⟩
Article dans une revue hal-04117025 v1

Elemental chalcogen reactions of a tetravalent uranium imidophosphorane complex: cleavage of dioxygen

Luis Aguirre Quintana , Thayalan Rajeshkumar , Ningxin Jiang , Julie Niklas , John Bacsa et al.
Chemical Communications, 2022, 58 (95), pp.13242-13245. ⟨10.1039/d2cc05066h⟩
Article dans une revue hal-04103267 v1

A Planar Nickelaspiropentane Complex with Magnesium-Based Metalloligands: Synthesis, Structure, and Synergistic Dihydrogen Activation

Yanping Cai , Shengjie Jiang , Thayalan Rajeshkumar , Laurent Maron , Xin Xu
Journal of the American Chemical Society, 2022, 144 (36), pp.16647-16655. ⟨10.1021/jacs.2c07402⟩
Article dans une revue hal-04037097 v1

Does Reduction-Induced Isomerization of a Uranium(III) Aryl Complex Proceed via C-H Oxidative Addition and Reductive Elimination across the Uranium(II/IV) Redox Couple?

Michael A. Boreen , Christopher Z. Ye , Andrew Kerridge , Karl N. Mccabe , Brighton A. Skeel et al.
Inorganic Chemistry, 2022, 61 (23), pp.8955-8965. ⟨10.1021/acs.inorgchem.2c01563⟩
Article dans une revue hal-03714654 v1
Image document

Structure, reactivity and luminescence studies of triphenylsiloxide complexes of tetravalent lanthanides

Aurelien R. Willauer , Iskander Douair , Anne-Sophie Chauvin , Farzaneh Fadaei-Tirani , Jean-Claude G. Bunzli et al.
Chemical Science, 2022, 13 (3), pp.681-691. ⟨10.1039/d1sc05517h⟩
Article dans une revue hal-03717274 v1
Image document

A Bronsted Acidic Gallium Hydride: Facile Interconversion of NNNN-Macrocycle Supported [Ga-I](+) and [(GaH)-H-III](2+)

Louis J. Morris , Priyabrata Ghana , Thayalan Rajeshkumar , Ambre Carpentier , Laurent Maron et al.
Angewandte Chemie International Edition, 2022, 61 (11), pp.e202114629. ⟨10.1002/anie.202114629⟩
Article dans une revue hal-03714658 v1

Formation and Reactivity of a Hexahydridosilicate [SiH6](2-) Coordinated by a Macrocycle-Supported Strontium Cation

Thomas Hoellerhage , Priyabrata Ghana , Thomas P. Spaniol , Ambre Carpentier , Laurent Maron et al.
Angewandte Chemie International Edition, 2022, 61 (10), ⟨10.1002/anie.202115379⟩
Article dans une revue hal-03714657 v1

Strontium Hydride Cations Supported by a Large NNNNN Type Macrocycle: Synthesis, Structure, and Hydrofunctionalization Catalysis

Thomas Hoellerhage , Thomas P. Spaniol , Ambre Carpentier , Laurent Maron , Jun Okuda
Inorganic Chemistry, 2022, 61 (7), pp.3309-3316. ⟨10.1021/acs.inorgchem.1c03894⟩
Article dans une revue hal-03714655 v1
Image document

Group 12 and 13 metal-alkenyl promoted generation of long-chain branching in metallocene-based polyethylene

Orlando Santoro , Lorenzo Piola , Karl Mc Cabe , Olivier Lhost , Katty den Dauw et al.
European Polymer Journal, 2022, 173, pp.111257. ⟨10.1016/j.eurpolymj.2022.111257⟩
Article dans une revue hal-04013388 v1
Image document

Rational Preparation of Well-Defined Multinuclear Iridium-Aluminum Polyhydride Clusters and Comparative Reactivity

Leon Escomel , Naime Soule , Emmanuel Robin , Iker del Rosal , Laurent Maron et al.
Inorganic Chemistry, 2022, 61 (15), pp.5715-5730. ⟨10.1021/acs.inorgchem.1c03120⟩
Article dans une revue hal-03714651 v1
Image document

Cation assisted binding and cleavage of dinitrogen by uranium complexes

Nadir Jori , Thayalan Rajeshkumar , Rosario Scopelliti , Ivica Z̆ivković , Andrzej Sienkiewicz et al.
Chemical Science, 2022, 13 (32), pp.9232-9242. ⟨10.1039/d2sc02530b⟩
Article dans une revue hal-03969626 v1
Image document

Assembling diuranium complexes in different states of charge with a bridging redox-active ligand

Dieuwertje Modder , Mikhail Batov , Thayalan Rajeshkumar , Andrzej Sienkiewicz , Ivica Zivkovic et al.
Chemical Science, 2022, 13 (38), pp.11294-11303. ⟨10.1039/d2sc03592h⟩
Article dans une revue hal-04037086 v1

Activation of CO Using a 1,2‐Disilylene: Facile Synthesis of an Abnormal N‐Heterocyclic Silylene

Palak Garg , Ambre Carpentier , Iskander Douair , Deepak Dange , Yixiao Jiang et al.
Angewandte Chemie International Edition, 2022, 61 (20), ⟨10.1002/anie.202201705⟩
Article dans une revue hal-04013295 v1

Reactivity of Multimetallic Thorium Nitrides Generated by Reduction of Thorium Azides

Fang-Che Hsueh , Luciano Barluzzi , Megan Keener , Thayalan Rajeshkumar , Laurent Maron et al.
Journal of the American Chemical Society, 2022, 144 (7), pp.3222-3232. ⟨10.1021/jacs.1c13150⟩
Article dans une revue hal-03714653 v1

Reversible Oxidative Addition of Zinc Hydride at a Gallium(I)‐Centre: Labile Mono‐ and Bis(hydridogallyl)zinc Complexes

Louis Morris , Thayalan Rajeshkumar , Laurent Maron , Jun Okuda
Chemistry - A European Journal, 2022, 28 (56), ⟨10.1002/chem.202201480⟩
Article dans une revue hal-04041541 v1

Uranium(III)–Phosphorus(III) Synergistic Activation of White Phosphorus and Arsenic

Wei Fang , Iskander Douair , Adrian Hauser , Kai Li , Yue Zhao et al.
CCS Chemistry, 2022, 4 (8), pp.2630-2638. ⟨10.31635/ccschem.021.202101485⟩
Article dans une revue hal-04023410 v1

Synthesis and Reactivity of Triangular Heterometallic ComplexesContaining Zn-Zn Bond br

Shengjie Jiang , Yanping Cai , Ambre Carpentier , Iker del Rosal , Laurent Maron et al.
Inorganic Chemistry, 2022, 61 (20), pp.8083-8089. ⟨10.1021/acs.inorgchem.2c00956⟩
Article dans une revue hal-03714644 v1
Image document

CO reductive oligomerization by a divalent thulium complex and CO2-induced functionalization

Thomas Simler , Karl N. Mccabe , Laurent Maron , Gregory Nocton
Chemical Science, 2022, 13 (25), pp.7449-7461. ⟨10.1039/d2sc01798a⟩
Article dans une revue hal-03714642 v1

Heterometallic uranium/molybdenum nitride synthesis via partial N-atom transfer

Luciano Barluzzi , Nadir Jori , Tianyi He , Thayalan Rajeshkumar , Rosario Scopelliti et al.
Chemical Communications, 2022, 58 (29), pp.4655-4658. ⟨10.1039/d2cc00473a⟩
Article dans une revue hal-03714647 v1

Reductive activation of N 2 using a calcium/potassium bimetallic system supported by an extremely bulky diamide ligand

Rahul Mondal , K. Yuvaraj , Thayalan Rajeshkumar , Laurent Maron , Cameron Jones
Chemical Communications, 2022, 58 (91), pp.12665-12668. ⟨10.1039/d2cc04841h⟩
Article dans une revue hal-04088737 v1
Image document

Facile Synthesis of Uranium Complexes with a Pendant Borane Lewis Acid and 1,2‐Insertion of CO into a U−N Bond

Wei Su , Thayalan Rajeshkumar , Libo Xiang , Laurent Maron , Qing Ye
Angewandte Chemie International Edition, 2022, 61 (51), ⟨10.1002/anie.202212823⟩
Article dans une revue hal-04115729 v1
Image document

Role of the Meso Substituent in Defining the Reduction of Uranyl Dipyrrin Complexes

Karlotta van Rees , Thayalan Rajeshkumar , Laurent Maron , Stephen Sproules , Jason Love
Inorganic Chemistry, 2022, 61 (50), pp.20424-20432. ⟨10.1021/acs.inorgchem.2c03048⟩
Article dans une revue hal-04116999 v1

Thorium- and Uranium-Mediated C–H Activation of a Silyl-Substituted Cyclobutadienyl Ligand

Nikolaos Tsoureas , Thayalan Rajeshkumar , Oliver Townrow , Laurent Maron , Richard Layfield
Inorganic Chemistry, 2022, 61 (50), pp.20629-20635. ⟨10.1021/acs.inorgchem.2c03534⟩
Article dans une revue hal-04158681 v1
Image document

Electron Shuttle in N-Heteroaromatic Ni Catalysts for Alkene Isomerization

Maxime Tricoire , Ding Wang , Thayalan Rajeshkumar , Laurent Maron , Grégory Danoun et al.
JACS Au, 2022, 2 (8), pp.1881-1888. ⟨10.1021/jacsau.2c00251⟩
Article dans une revue hal-03768030 v1

Solvent‐Dependent Oxidative Addition and Reductive Elimination of H 2 Across a Gallium‐Zinc Bond

Louis Morris , Thayalan Rajeshkumar , Akira Okumura , Laurent Maron , Jun Okuda
Angewandte Chemie International Edition, 2022, 61 (36), ⟨10.1002/anie.202208855⟩
Article dans une revue hal-03988989 v1

CO, CO2 and CS2 activation by divalent ytterbium hydrido complexes

Xianghui Shi , Thayalan Rajeshkumar , Laurent Maron , Jianhua Cheng
Chemical Communications, 2022, 58 (9), pp.1362-1365. ⟨10.1039/d1cc06449e⟩
Article dans une revue hal-03717270 v1
Image document

Selective hydroboration of terminal alkynes catalyzed by heterometallic clusters with uranium metal triple bonds

Penglong Wang , Iskander Douair , Yue Zhao , Rile Ge , Junhu Wang et al.
Chem, 2022, 8 (5), pp.1361-1375. ⟨10.1016/j.chempr.2022.03.005⟩
Article dans une revue hal-03714650 v1

A Masked Form of an O‐Borylated Breslow Intermediate for the Diastereoselective FLP‐Type Activation of Aldehydes

Angelica Mejia Fajardo , Nicolas Queyriaux , Aurèle Camy , Laure Vendier , Mary Grellier et al.
Chemistry - A European Journal, 2022, 28 (10), pp.e202104122. ⟨10.1002/chem.202104122⟩
Article dans une revue hal-03669849 v1

Controlled monodefluorination and alkylation of C(sp<SUP>3</SUP>)-F bonds by lanthanide photocatalysts: importance of metal-ligand cooperativity

Amy E. Kynman , Luca K. Elghanayan , Addison N. Desnoyer , Yan Yang , Laurent Severy et al.
Chemical Science, 2022, 13 (47), pp.14090-14100. ⟨10.1039/d2sc04192h⟩
Article dans une revue hal-04707642 v1
Image document

Electronic structure studies reveal 4f/5d mixing and its effect on bonding characteristics in Ce-imido and -oxo complexes

Liane M. Moreau , Ekaterina Lapsheva , Jorge Amaro-Estrada , Michael R. Gau , Patrick J. Carroll et al.
Chemical Science, 2022, 13 (6), pp.1759-1773. ⟨10.1039/d1sc06623d⟩
Article dans une revue hal-03714645 v1

Stereospecific Polymerization of Bulky Methacrylates Using Organocatalyst in Strong Donating Solvent via Self-Controlled Mechanism

Yangyang Sun , Ambre Carpentier , Yixin Zhang , Biwei Weng , Yaoyao Ling et al.
Macromolecules, 2022, 55 (18), pp.8292-8302. ⟨10.1021/acs.macromol.2c01333⟩
Article dans une revue hal-04065843 v1
Image document

Hydroarylation of olefins catalysed by a dimeric ytterbium(II) alkyl

Georgia M. Richardson , Iskander Douair , Scott A. Cameron , Joe Bracegirdle , Robert A. Keyzers et al.
Nature Communications, 2021, 12, pp.3147. ⟨10.1038/s41467-021-23444-x⟩
Article dans une revue hal-03717276 v1

Scandium-Terminal Boronylphosphinidene Complex

Bin Feng , Li Xiang , Ambre Carpentier , Laurent Maron , Xuebing Leng et al.
Journal of the American Chemical Society, 2021, 143 (7), pp.2705-2709. ⟨10.1021/jacs.1c00148⟩
Article dans une revue hal-03717269 v1

Cationic Zinc Hydride Catalyzed Carbon Dioxide Reduction to Formate: Deciphering Elementary Reactions, Isolation of Intermediates, and Computational Investigations

Raju Chambenahalli , R. M. Bhargav , Karl N. Mccabe , Alex P. Andrews , Florian Ritter et al.
Chemistry - A European Journal, 2021, 27 (26), pp.7391-7401. ⟨10.1002/chem.202005392⟩
Article dans une revue hal-03717258 v1
Image document

Reductive Hexamerization of CO Involving Cooperativity Between Magnesium(I) Reductants and [Mo(CO)(6)]: Synthesis of Well-Defined Magnesium Benzenehexolate Complexes

Albert Paparo , K. Yuvaraj , Aidan J. R. Matthews , Iskander Douair , Laurent Maron et al.
Angewandte Chemie International Edition, 2021, 60 (2), pp.630-634. ⟨10.1002/anie.202009523⟩
Article dans une revue hal-03925182 v1
Image document

Catalytic Deoxygenation of Nitroarenes Mediated by High-Valent Molybdenum(VI)-NHC Complexes

Shenyu Liu , Jorge Ivan Amaro-Estrada , Marc Baltrun , Iskander Douair , Roland Schoch et al.
Organometallics, 2021, 40 (2), pp.107-118. ⟨10.1021/acs.organomet.0c00352⟩
Article dans une revue hal-03717280 v1

Computational Insights into Different Mechanisms for Ag-, Cu-, and Pd-Catalyzed Cyclopropanation of Alkenes and Sulfonyl Hydrazones

Yong Wu , Shanshan Cao , Iskander Douair , Laurent Maron , Xihe Bi
Chemistry - A European Journal, 2021, 27 (19), pp.5999-6006. ⟨10.1002/chem.202005193⟩
Article dans une revue hal-03717247 v1

Photochemically Activated Dimagnesium(I) Compounds: Reagents for the Reduction and Selective C-H Bond Activation of Inert Arenes

Dafydd D. L. Jones , Iskander Douair , Laurent Maron , Cameron Jones
Angewandte Chemie International Edition, 2021, 60 (13), pp.7087-7092. ⟨10.1002/anie.202017126⟩
Article dans une revue hal-03717283 v1

Deaggregation of Zinc Dihydride by Lewis Acids Including Carbon Dioxide in the Presence of Nitrogen Donors

Florian Ritter , Louis J. Morris , Karl N. Mccabe , Thomas P. Spaniol , Laurent Maron et al.
Inorganic Chemistry, 2021, 60 (20), pp.15583-15592. ⟨10.1021/acs.inorgchem.1c02207⟩
Article dans une revue hal-03717263 v1

Stepwise Reduction of Dinitrogen by a Uranium-Potassium Complex Yielding a U(VI)/U(IV) Tetranitride Cluster

Nadir Jori , Luciano Barluzzi , Iskander Douair , Laurent Maron , Farzaneh Fadaei-Tirani et al.
Journal of the American Chemical Society, 2021, 143 (29), pp.11225-11234. ⟨10.1021/jacs.1c05389⟩
Article dans une revue hal-03717248 v1

Reduced Arene Complexes of Hafnium Supported by a Triamidoamine Ligand

Priyabrata Ghana , Sebastian Schrader , Thayalan Rajeshkumar , Thomas P. Spaniol , Ulli Englert et al.
Angewandte Chemie International Edition, 2021, 60 (25), pp.14179-14187. ⟨10.1002/anie.202103755⟩
Article dans une revue hal-03717260 v1

Isolation of a [Fe(CO)(4)](2-)-Bridged Diuranium Complex Obtained via Reduction of Fe(CO)(5) with Uranium(III)

Robert J. Ward , Daniel Pividori , Ambre Carpentier , Michael L. Tarlton , Steven P. Kelley et al.
Organometallics, 2021, 40 (10), pp.1411-1415. ⟨10.1021/acs.organomet.1c00205⟩
Article dans une revue hal-03717253 v1

Hydrosilylative reduction of carbon dioxide by a homoleptic lanthanum aryloxide catalyst with high activity and selectivity

Kejian Chang , Iker del Rosal , Xizhou Zheng , Laurent Maron , Xin Xu
Dalton Transactions, 2021, 50 (22), pp.7804-7809. ⟨10.1039/d1dt01074c⟩
Article dans une revue hal-03717252 v1
Image document

A Uranium(II) Arene Complex That Acts as a Uranium(I) Synthon

Mark D. Straub , Erik T. Ouellette , Michael A. Boreen , R. David Britt , Khetpakorn Chakarawet et al.
Journal of the American Chemical Society, 2021, 143 (47), pp.19748-19760. ⟨10.1021/jacs.1c07854⟩
Article dans une revue hal-03717277 v1
Image document

Tuning the Regioselective Functionalization of Trifluoromethylated Dienes via Lanthanum‐Mediated Single C−F Bond Activation

Tarun Kumar , Yan Yang , Sirine Sghaier , Yassir Zaid , X. F Le Goff et al.
Chemistry - A European Journal, 2021, 27 (12), pp.4016-4021. ⟨10.1002/chem.202005239⟩
Article dans une revue hal-03264465 v1
Image document

Single metal four-electron reduction by U(II) and masked "U(II)" compounds

Dieuwertje K. Modder , Chad T. Palumbo , Iskander Douair , Rosario Scopelliti , Laurent Maron et al.
Chemical Science, 2021, 12 (17), pp.6153-6158. ⟨10.1039/d1sc00668a⟩
Article dans une revue hal-03717255 v1

[(Me6TREN)MgOCHPh2][B(C6F5)(4)]: A Model Complex to Explore the Catalytic Activity of Magnesium Alkoxides in Ketone Hydroboration

A Ankur , Ramkumar Kannan , Raju Chambenahalli , Sumanta Banerjee , Yan Yang et al.
European Journal of Inorganic Chemistry, 2021, 2021 (45), pp.4632-4638. ⟨10.1002/ejic.202100651⟩
Article dans une revue hal-03717246 v1

Calcium Hydride Catalysts for Olefin Hydrofunctionalization: Ring-Size Effect of Macrocyclic Ligands on Activity

Thomas Hoellerhage , Danny Schuhknecht , Alisha Mistry , Thomas P. Spaniol , Yan Yang et al.
Chemistry - A European Journal, 2021, 27 (9), pp.3002-3007. ⟨10.1002/chem.202004931⟩
Article dans une revue hal-03717259 v1

Zinc hydride cation [ZnH](+) supported by TMPDA (TMPDA = N,N,N ',N '-tetramethylpropane-1,3-diamine)

Florian Ritter , Karl N. Mccabe , Laurent Maron , Thomas P. Spaniol , Jun Okuda
Polyhedron, 2021, 204, ⟨10.1016/j.poly.2021.115264⟩
Article dans une revue hal-03717272 v1

Dihydrogen cleavage by a dimetalloxycarbene-borane frustrated Lewis pair

Albert Paparo , Anh L. P. Nguyen , Jared S. Silvia , Thomas P. Spaniol , Laurent Maron et al.
Dalton Transactions, 2021, 50 (31), pp.10692-10695. ⟨10.1039/d1dt02273c⟩
Article dans une revue hal-03717268 v1

Nickel-catalyzed synthesis of Zn(i)-Zn(i) bonded compounds

Shengjie Jiang , Yanping Cai , Ambre Carpentier , Iker del Rosal , Laurent Maron et al.
Chemical Communications, 2021, 57 (100), pp.13696-13699. ⟨10.1039/d1cc05719g⟩
Article dans une revue hal-03717250 v1
Image document

sigma or pi? Bonding interactions in a series of rhenium metallotetrylenes

Erik T. Ouellette , Ambre Carpentier , I. Joseph Brackbill , Trevor D. Lohrey , Iskander Douair et al.
Dalton Transactions, 2021, 50 (6), pp.2083-2092. ⟨10.1039/d1dt00129a⟩
Article dans une revue hal-03717285 v1

Reductive elimination of [AlH2](+) from a cationic Ga-Al dihydride

Louis J. Morris , Ambre Carpentier , Laurent Maron , Jun Okuda
Chemical Communications, 2021, 57 (74), pp.9454-9457. ⟨10.1039/d1cc03706d⟩
Article dans une revue hal-03717267 v1

Facile Dinitrogen and Dioxygen Cleavage by a Uranium(III) Complex: Cooperativity Between the Non-Innocent Ligand and the Uranium Center

Penglong Wang , Iskander Douair , Yue Zhao , Shuao Wang , Jun Zhu et al.
Angewandte Chemie International Edition, 2021, 60 (1), pp.473-479. ⟨10.1002/anie.202012198⟩
Article dans une revue hal-03717278 v1

Heterometallic Clusters with Multiple Rare Earth Metal-Transition Metal Bonding

Iskander Douair , Genfeng Feng , Penglong Wang , Yue Zhao , Laurent Maron et al.
Journal of the American Chemical Society, 2021, 143 (15), pp.5998-6005. ⟨10.1021/jacs.1c01771⟩
Article dans une revue hal-03717256 v1
Image document

Evidence for ligand- and solvent-induced disproportionation of uranium(IV)

Jingzhen Du , Iskander Douair , Erli Lu , John A. Seed , Floriana Tuna et al.
Nature Communications, 2021, 12, pp.4832. ⟨10.1038/s41467-021-25151-z⟩
Article dans une revue hal-03717266 v1

Ytterbium (II) Hydride as a Powerful Multielectron Reductant

Georgia M. Richardson , Iskander Douair , Scott A. Cameron , Laurent Maron , Mathew D. Anker
Chemistry - A European Journal, 2021, 27 (52), pp.13144-13148. ⟨10.1002/chem.202102428⟩
Article dans une revue hal-03717249 v1
Image document

Activation of ammonia and hydrazine by electron rich Fe(ii) complexes supported by a dianionic pentadentate ligand platform through a common terminal Fe(iii) amido intermediate

Lucie Nurdin , Yan Yang , Peter G. N. Neate , Warren E. Piers , Laurent Maron et al.
Chemical Science, 2021, 12 (6), pp.2231-2241. ⟨10.1039/d0sc06466a⟩
Article dans une revue hal-03717265 v1
Image document

Al-alkenyl-induced formation of long-chain branched polyethylene via coordinative tandem insertion and chain-transfer polymerization using (nBuCp)2ZrCl2/MAO systems: An experimental and theoretical study

O. Santoro , L. Piola , K. Mc Cabe , O. Lhost , K. den Dauw et al.
European Polymer Journal, 2021, 154, pp.110567. ⟨10.1016/j.eurpolymj.2021.110567⟩
Article dans une revue hal-03284278 v1

C-N and C-H Activation of an N-Heterocyclic Carbene by Magnesium(II) Hydride and Magnesium(I) Complexes

K. Yuvaraj , Ambre Carpentier , Cory D. Smith , Laurent Maron , Cameron Jones
Inorganic Chemistry, 2021, 60 (8), pp.6065-6072. ⟨10.1021/acs.inorgchem.1c00552⟩
Article dans une revue hal-03717245 v1

Organocalcium Complex-Catalyzed Selective Redistribution of ArSiH3 or Ar(alkyl)SiH2 to Ar3SiH or Ar-2(alkyl)SiH

Tao Li , Karl N. Mccabe , Laurent Maron , Xuebing Leng , Yaofeng Chen
ACS Catalysis, 2021, 11 (11), pp.6348-6356. ⟨10.1021/acscatal.1c00463⟩
Article dans une revue hal-03717273 v1
Image document

Dehydrohalogenation of halobenzenes and C(sp(3))-X (X = F, OPh) bond activation by a molecular calcium hydride

Andrew S. S. Wilson , Michael S. Hill , Mary F. Mahon , Chiara Dinoi , Laurent Maron
Tetrahedron, 2021, 82, ⟨10.1016/j.tet.2021.131931⟩
Article dans une revue hal-03717244 v1

Delivery of a Masked Uranium(II) by an Oxide-Bridged Diuranium(III) Complex

Dieuwertje K. Modder , Chad T. Palumbo , Iskander Douair , Farzaneh Fadaei-Tirani , Laurent Maron et al.
Angewandte Chemie International Edition, 2021, 60 (7), pp.3737-3744. ⟨10.1002/anie.202013473⟩
Article dans une revue hal-03925181 v1
Image document

Strongly Polarized Iridium δ− –Aluminum δ+ Pairs: Unconventional Reactivity Patterns Including CO 2 Cooperative Reductive Cleavage

Léon Escomel , Iker del Rosal , Laurent Maron , Erwann Jeanneau , Laurent Veyre et al.
Journal of the American Chemical Society, 2021, 143 (12), pp.4844-4856. ⟨10.1021/jacs.1c01725⟩
Article dans une revue hal-03357324 v1

Scandium and lanthanum hydride complexes stabilized by super-bulky penta-arylcyclopentadienyl ligands

Yang Wang , Iker del Rosal , Guorui Qin , Lanxiao Zhao , Laurent Maron et al.
Chemical Communications, 2021, 57 (63), pp.7766-7769. ⟨10.1039/d1cc01841h⟩
Article dans une revue hal-03717282 v1

A mononuclear divalent ytterbium hydrido complex supported by a super-bulky scorpionate ligand

Xianghui Shi , Peng Deng , Thayalan Rajeshkumar , Lanxiao Zhao , Laurent Maron et al.
Chemical Communications, 2021, 57 (78), pp.10047-10050. ⟨10.1039/d1cc04488e⟩
Article dans une revue hal-03717251 v1

Redox-induced reversible P-P coupling in a uranium complex

Wei Fang , Ambre Carpentier , Xiong Sun , Yue Zhao , Laurent Maron et al.
Chemical Communications, 2021, 57 (91), pp.12175-12178. ⟨10.1039/d1cc04765e⟩
Article dans une revue hal-03717284 v1

Cationic strontium hydride complexes supported by an NNNN-type macrocycle

Thomas Hoellerhage , Ambre Carpentier , Thomas P. Spaniol , Laurent Maron , Ulli Englert et al.
Chemical Communications, 2021, 57 (51), pp.6316-6319. ⟨10.1039/d1cc02040d⟩
Article dans une revue hal-03717262 v1

Formation and Reactivity with (BuCN)-Bu-t of a Thorium Phosphinidiide through a Combined Experimental and Computational Analysis

Michael L. Tarlton , Yan Yang , Steven P. Kelley , Laurent Maron , Justin R. Walensky
Organometallics, 2021, 40 (15), pp.2701-2708. ⟨10.1021/acs.organomet.1c00330⟩
Article dans une revue hal-03717279 v1

Calcium-mediated C(sp(3))-H Activation and Alkylation of Alkylpyridines

Xizhou Zheng , Iker del Rosal , Xian Xu , Yingming Yao , Laurent Maron et al.
Inorganic Chemistry, 2021, 60 (7), pp.5114-5121. ⟨10.1021/acs.inorgchem.1c00161⟩
Article dans une revue hal-03717254 v1

Insights into Rare-Earth Metal Complex-Mediated Hydroamination

Shuqi Dong , Jinjin Chen , Kening Qiao , Jian Fang , Yan Yang et al.
ACS Catalysis, 2021, 11 (7), pp.3790-3800. ⟨10.1021/acscatal.1c00566⟩
Article dans une revue hal-03717257 v1

A monoanionic pentadentate ligand platform for scandium-pnictogen multiple bonds

Evan A. Patrick , Yan Yang , Warren E. Piers , Laurent Maron , Benjamin S. Gelfand
Chemical Communications, 2021, 57 (69), pp.8640-8643. ⟨10.1039/d1cc03481b⟩
Article dans une revue hal-03717264 v1

Grafting of Lanthanum Complexes on a Functionalized Graphene Surface: Theoretical Investigation on Ethylene and 1,3-Butadiene Homo- and Co-Polymerization

Adrien Bathellier , Diego Moreno , Laurent Maron , Chiara Dinoi , Iker Del Rosal
CHEMISTRY-A EUROPEAN JOURNAL, 2020, 26 (58), pp.13213-13225. ⟨10.1002/chem.202001056⟩
Article dans une revue hal-03925188 v1

Hydrolysis of scandium alkyl derivatives supported by a pentadentate diborate ligand: Interconversion of hydroxo and oxo complexes

Daniel W. Beh , Warren E. Piers , Laurent Maron , Yan Yang , Benjamin S. Gelfand et al.
Polyhedron, 2020, 179, ⟨10.1016/j.poly.2020.114410⟩
Article dans une revue hal-03925208 v1

A tetranuclear nickel cluster isolated in multiple high-valent states

Samuel Jacob , Iskander Douair , Guang Wu , Laurent Maron , Gabriel Menard
CHEMICAL COMMUNICATIONS, 2020, 56 (59), pp.8182-8185. ⟨10.1039/d0cc01699c⟩
Article dans une revue hal-03925191 v1

Two-Electron Oxidative Atom Transfer at a Homoleptic, Tetravalent Uranium Complex

Natalie T. Rice , Karl Mccabe , John Bacsa , Laurent Maron , Henry S. La Pierre
Journal of the American Chemical Society, 2020, 142 (16), pp.7368-7373. ⟨10.1021/jacs.0c02693⟩
Article dans une revue hal-03925204 v1

Access to Hydroxy-Functionalized Polypropylene through Coordination Polymerization

Yuanhao Zhong , Iskander Douair , Tiantian Wang , Chunji Wu , Laurent Maron et al.
Angewandte Chemie International Edition, 2020, 59 (12), pp.4947-4952. ⟨10.1002/anie.201914747⟩
Article dans une revue hal-03925211 v1
Image document

Mechanistic Investigations via DFT Support the Cooperative Heterobimetallic C-H and O-H Bond Activation Across Ta=Ir Multiple Bonds

Iker Del rosal , Sébastien Lassalle , Laurent Maron , Chiara Dinoi , Chloé Thieuleux et al.
Dalton Transactions, 2020, ⟨10.1039/D0DT03818K⟩
Article dans une revue hal-03009651 v1
Image document

Long-Chain Branched Polyethylene via Coordinative Tandem Insertion and Chain-Transfer Polymerization Using rac-{EBTHI}ZrCl2/MAO/Al-alkenyl Combinations: An Experimental and Theoretical Study

M. Santoro , Lorenzo Piola , Karl Mc Cabe , Olivier Lhost , Katty den Dauw et al.
Macromolecules, 2020, 53 (20), pp.8847-8857. ⟨10.1021/acs.macromol.0c01671⟩
Article dans une revue hal-03040883 v1
Image document

Selective oxo ligand functionalisation and substitution reactivity in an oxo/catecholate-bridged U-IV/U(IV)Pacman complex

Bradley E. Cowie , Iskander Douair , Laurent Maron , Jason B. Love , Polly L. Arnold
Chemical Science, 2020, 11 (27), pp.7144-7157. ⟨10.1039/d0sc02297g⟩
Article dans une revue hal-03925219 v1

Uranium Metallocene Azides, Isocyanates, and Their Borane-Capped Lewis Adducts

Michael A. Boreen , Karl N. Mccabe , Trevor D. Lohrey , Fabian A. Watt , Laurent Maron et al.
INORGANIC CHEMISTRY, 2020, 59 (12), pp.8580-8588. ⟨10.1021/acs.inorgchem.0c01038⟩
Article dans une revue hal-03925193 v1
Image document

Sterically controlled reductive oligomerisations of CO by activated magnesium(i) compounds: deltate vs. ethenediolate formation

K. Yuvaraj , Iskander Douair , Dafydd D. L. Jones , Laurent Maron , Cameron Jones
Chemical Science, 2020, 11 (13), pp.3516-3522. ⟨10.1039/d0sc00836b⟩
Article dans une revue hal-03925205 v1

Comparative Insertion Reactivity of CO, CO2, (BuCN)-Bu-t, and (BuNC)-Bu-t into Thorium- and Uranium-Phosphorus Bonds

Michael L. Tarlton , Iker del Rosal , Sean P. Vilanova , Steven P. Kelley , Laurent Maron et al.
ORGANOMETALLICS, 2020, 39 (11), pp.2152-2161. ⟨10.1021/acs.organomet.0c00221⟩
Article dans une revue hal-03925196 v1

Activation of Ethylene by N-Heterocyclic Carbene Coordinated Magnesium(I) Compounds

K. Yuvaraj , Iskander Douair , Laurent Maron , Cameron Jones
CHEMISTRY-A EUROPEAN JOURNAL, 2020, 26 (64), pp.14665-14670. ⟨10.1002/chem.202002380⟩
Article dans une revue hal-03925185 v1
Image document

Terminal uranium(V)-nitride hydrogenations involving direct addition or Frustrated Lewis Pair mechanisms

Lucile Chatelain , Elisa Louyriac , Iskander Douair , Erli Lu , Floriana Tuna et al.
Nature Communications, 2020, 11 (1), pp.337. ⟨10.1038/s41467-019-14221-y⟩
Article dans une revue hal-03925214 v1

Molecular Thorium Trihydrido Clusters Stabilized by Cyclopentadienyl Ligands

Runhai Chen , Guorui Qin , Shihui Li , Alison J. Edwards , Ross O. Piltz et al.
Angewandte Chemie International Edition, 2020, 59 (28), pp.11250-11255. ⟨10.1002/anie.202002303⟩
Article dans une revue hal-03925198 v1

A transient lanthanum phosphinidene complex

Fabian A. Watt , Karl N. Mccabe , Roland Schoch , Laurent Maron , Stephan Hohloch
CHEMICAL COMMUNICATIONS, 2020, 56 (98), ⟨10.1039/d0cc06670b⟩
Article dans une revue hal-03925180 v1

Dinitrogen Cleavage by a Heterometallic Cluster Featuring Multiple Uranium-Rhodium Bonds

Congqing Zhu , Xiaoqing Xin , Iskander Douair , Yue Zhao , Shuao Wang et al.
Journal of the American Chemical Society, 2020, 142 (35), pp.15004-15011. ⟨10.1021/jacs.0c05788⟩
Article dans une revue hal-03925189 v1

Accessing the plus IV Oxidation State in Molecular Complexes of Praseodymium

Aurelien R. Willauer , Chad T. Palumbo , Farzaneh Fadaei-Tirani , Ivica Zivkovic , Iskander Douair et al.
Journal of the American Chemical Society, 2020, 142 (12), pp.5538-5542. ⟨10.1021/jacs.0c01204⟩
Article dans une revue hal-03925207 v1
Image document

Atom economical coupling of benzophenone and N-heterocyclic aromatics with SmI 2

Arnaud Jaoul , Yan Yang , Nicolas Casaretto , Carine Clavaguéra , Laurent Maron et al.
Chemical Communications, 2020, ⟨10.1039/D0CC05164K⟩
Article dans une revue hal-02941564 v1
Image document

Synthesis and versatile reactivity of scandium phosphinophosphinidene complexes

Bin Feng , Li Xiang , Karl N. Mccabe , Laurent Maron , Xuebing Leng et al.
Nature Communications, 2020, 11 (1), ⟨10.1038/s41467-020-16773-w⟩
Article dans une revue hal-03925195 v1
Image document

Hydrogen isotope exchange catalyzed by Ru nanocatalysts: labelling of complex molecules containing N-heterocycles and reaction mechanism insights

Viktor Pfeifer , Marie Certiat , Donia Bouzouita , Alberto Palazzolo , Sébastien Garcia-Argote et al.
Chemistry - A European Journal, 2020, 26, pp.4988-4996. ⟨10.1002/chem.201905651⟩
Article dans une revue cea-02487414 v1

Metallacyclic actinide catalysts for dinitrogen conversion to ammonia and secondary amines (vol 15, pg 312, 2020)

Polly L. Arnold , Tatsumi Ochiai , Francis Y. T. Lam , Rory P. Kelly , Megan L. Seymour et al.
NATURE CHEMISTRY, 2020, 12 (7), pp.660. ⟨10.1038/s41557-020-0485-5⟩
Article dans une revue hal-03925197 v1

Synthesis and Structure of Uranium-Silylene Complexes

I. Joseph Brackbill , Iskander Douair , Daniel J. Lussier , Michael A. Boreen , Laurent Maron et al.
CHEMISTRY-A EUROPEAN JOURNAL, 2020, 26 (11), pp.2360-2364. ⟨10.1002/chem.202000214⟩
Article dans une revue hal-03925210 v1
Image document

Alkali Metal Triphenyl- and Trihydridosilanides Stabilized by a Macrocyclic Polyamine Ligand

Danny Schuhknecht , Valeri Leich , Thomas P. Spaniol , Iskander Douair , Laurent Maron et al.
Chemistry - A European Journal, 2020, 26 (13), pp.2821-2825. ⟨10.1002/chem.202000187⟩
Article dans une revue hal-03925209 v1

NH3 formation from N2 and H2 mediated by molecular tri-iron complexes

Matthias Reiners , Dirk Baabe , Katharina Münster , Marc-Kevin Zaretzke , Matthias Freytag et al.
Nature Chemistry, 2020, 12 (8), pp.740-746. ⟨10.1038/s41557-020-0483-7⟩
Article dans une revue hal-03150029 v1

Nickel(0)-Induced beta-H Elimination of Magnesium Alkyls: Formation and Reactivity of Heterometallic Hydrides

Jiasu Huang , Xizhou Zheng , Iker del Rosal , Bei Zhao , Laurent Maron et al.
INORGANIC CHEMISTRY, 2020, 59 (18), pp.13473-13480. ⟨10.1021/acs.inorgchem.0c01885⟩
Article dans une revue hal-03925186 v1

Reactivity of Ce(iv) imido compounds with heteroallenes

Ekaterina N. Lapsheva , Thibault Cheisson , Carlos Alvarez Lamsfus , Patrick J. Carroll , Michael R. Gau et al.
CHEMICAL COMMUNICATIONS, 2020, 56 (35), pp.4781-4784. ⟨10.1039/c9cc10052k⟩
Article dans une revue hal-03925202 v1
Image document

Metallacyclic actinide catalysts for dinitrogen conversion to ammonia and secondary amines

Polly Arnold , Tatsumi Ochiai , Francis Lam , Rory Kelly , Megan Seymour et al.
Nature Chemistry, 2020, 12 (7), pp.654-659. ⟨10.1038/s41557-020-0457-9⟩
Article dans une revue hal-03885963 v1
Image document

Divergent uranium-versusphosphorus-based reduction of Me(3)SiN(3)with steric modification of phosphido ligands

Robert J. Ward , Pokpong Rungthanaphatsophon , Iker del Rosal , Steven P. Kelley , Laurent Maron et al.
Chemical Science, 2020, 11 (22), pp.5830-5835. ⟨10.1039/d0sc02261f⟩
Article dans une revue hal-03925194 v1
Image document

Interactions in saccharide/cation/water systems: Insights from density functional theory

Johanne Teychené , Hélène Roux De-Balmann , Laurent Maron , Sylvain Galier
Food Chemistry, 2020, 327, pp.127054. ⟨10.1016/j.foodchem.2020.127054⟩
Article dans une revue hal-02747033 v1
Image document

Ethene Activation and Catalytic Hydrogenation by a Low-Valent Uranium Pentalene Complex

Nikolaos Tsoureas , Laurent Maron , Alexander F R Kilpatrick , Richard A Layfield , F. Geoffrey N. Cloke
Journal of the American Chemical Society, 2020, 142 (1), pp.89-92. ⟨10.1021/jacs.9b11929⟩
Article dans une revue hal-03925215 v1
Image document

Construction of heterometallic clusters with multiple uranium-metal bonds by using dianionic nitrogen-phosphorus ligands

Genfeng Feng , Karl N. Mccabe , Shuao Wang , Laurent Maron , Congqing Zhu
Chemical Science, 2020, 11 (29), pp.7585-7592. ⟨10.1039/d0sc00389a⟩
Article dans une revue hal-03925190 v1
Image document

Regioselective Hydrosilylation of Olefins Catalyzed by a Molecular Calcium Hydride Cation

Danny Schuhknecht , Thomas P. Spaniol , Laurent Maron , Jun Okuda
Angewandte Chemie International Edition, 2020, 59 (1), pp.310-314. ⟨10.1002/anie.201909585⟩
Article dans une revue hal-03925217 v1
Image document

Rationalizing the Reactivity of Mixed Allyl Rare-Earth Borohydride Complexes with DFT Studies

Sami Fadlallah , Jashvini Jothieswaran , Iker Del rosal , Laurent Maron , Fanny Bonnet et al.
Catalysts, 2020, 10, pp.820. ⟨10.3390/catal10080820⟩
Article dans une revue hal-02926044 v1

Reactivity of a Molecular Calcium Hydride Cation ([CaH](+)) Supported by an NNNN Macrocycle

Danny Schuhknecht , Thomas P. Spaniol , Yan Yang , Laurent Maron , Jun Okuda
INORGANIC CHEMISTRY, 2020, 59 (13), pp.9406-9415. ⟨10.1021/acs.inorgchem.0c01289⟩
Article dans une revue hal-03925192 v1

Stabilization of the Oxidation State plus IV in Siloxide-Supported Terbium Compounds

Aurelien R. Willauer , Chad T. Palumbo , Rosario Scopelliti , Ivica Zivkovic , Iskander Douair et al.
Angewandte Chemie International Edition, 2020, 59 (9), pp.3549-3553. ⟨10.1002/anie.201914733⟩
Article dans une revue hal-03925212 v1

Incorporation of Boron into Uranium Metallacycles: Synthesis, Structure, and Reactivity of Boron-Containing Uranacycles Derived from Bis(alkynyl)boranes

Wangyang Ma , Iskander Douair , Laurent Maron , Qing Ye
CHEMISTRY-A EUROPEAN JOURNAL, 2020, 26 (60), pp.13573-13577. ⟨10.1002/chem.202003611⟩
Article dans une revue hal-03925187 v1
Image document

Calcium Hydride Reduction of Polycyclic Aromatic Hydrocarbons

Andrew S. S. Wilson , Chiara Dinoi , Michael S. Hill , Mary F. Mahon , Laurent Maron et al.
Angewandte Chemie International Edition, 2020, 59 (3), pp.1232-1237. ⟨10.1002/anie.201913895⟩
Article dans une revue hal-04022181 v1
Image document

Stepwise Construction of Silica-supported Tantalum/Iridium Heteropolymetallic Catalysts Using Surface Organometallic Chemistry

Sébastien Lassalle , Ribal Jabbour , Iker Del rosal , Laurent Maron , Emiliano Fonda et al.
Journal of Catalysis, 2020, ⟨10.1016/j.jcat.2020.10.016⟩
Article dans une revue hal-02985281 v1

Molecular Zinc Hydride Cations [ZnH](+): Synthesis, Structure, and CO(2)Hydrosilylation Catalysis

Florian Ritter , Thomas P. Spaniol , Iskander Douair , Laurent Maron , Jun Okuda
Angewandte Chemie International Edition, 2020, 59 (51), pp.23335-23342. ⟨10.1002/anie.202011480⟩
Article dans une revue hal-03925183 v1

Reductive CO 2 Homocoupling: Synthesis of a Borylated C 3 Carbohydrate

Aurélien Béthegnies , Yannick Escudié , Nelson Nuñez‐dallos , Laure Vendier , John Hurtado et al.
ChemCatChem, 2019, 11, pp.760-765. ⟨10.1002/cctc.201801875⟩
Article dans une revue hal-02330570 v1

Transition-metal-bridged bimetallic clusters with multiple uranium-metal bonds

Genfeng Feng , Mingxing Zhang , Dong Shao , Xinyi Wang , Shuao Wang et al.
Nature Chemistry, 2019, 11 (3), pp.248-253. ⟨10.1038/s41557-018-0195-4⟩
Article dans une revue hal-04022179 v1

Reductive Trimerization of CO to the Deltate Dianion Using Activated Magnesium(I) Compounds

K. Yuvaraj , Iskander Douair , Albert Paparo , Laurent Maron , Cameron Jones
Journal of the American Chemical Society, 2019, 141 (22), pp.8764-8768. ⟨10.1021/jacs.9b04085⟩
Article dans une revue hal-04022183 v1

Transition metal-induced dehydrogenative coupling of zinc hydrides

Min Chen , Shengjie Jiang , Laurent Maron , Xin Xu
Dalton Transactions, 2019, 48 (6), pp.1931-1935. ⟨10.1039/c8dt04651d⟩
Article dans une revue hal-04022169 v1
Image document

Thorium- and uranium-azide reductions: a transient dithorium-nitride versus isolable diuranium-nitrides

Jingzhen Du , David M. King , Lucile Chatelain , Erli Lu , Floriana Tuna et al.
Chemical Science, 2019, 10 (13), pp.3738-3745. ⟨10.1039/c8sc05473h⟩
Article dans une revue hal-04022188 v1
Image document

Single-site cobalt and zinc catalysts for the ring-opening polymerization of lactide

Paul Marin , M.J.-L. Tschan , P. Haquette , Thierry Roisnel , Iker Del rosal et al.
European Polymer Journal, 2019, 120, pp.109208. ⟨10.1016/j.eurpolymj.2019.08.035⟩
Article dans une revue hal-02310251 v1

Polymerization of rac ‐Lactide Using Achiral Iron Complexes: Access to Thermally Stable Stereocomplexes

Paul Marin , Mathieu J.‐l. Tschan , Florence Isnard , Carine Robert , Pierre Haquette et al.
Angewandte Chemie International Edition, 2019, 58 (36), pp.12585-12589. ⟨10.1002/anie.201903224⟩
Article dans une revue hal-03365174 v1

Efficient CO2 transformation under ambient condition by heterobimetallic rare earth complexes: Experimental and computational evidences of a synergistic effect

Liye Qu , Iker del Rosal , Qingyan Li , Yaorong Wang , Dan Yuan et al.
Journal of CO2 Utilization, 2019, 33, pp.413-418. ⟨10.1016/j.jcou.2019.07.008⟩
Article dans une revue hal-04022172 v1
Image document

Thorium-nitrogen multiple bonds provide evidence for pushing-from-below for early actinides

Jingzhen Du , Carlos Alvarez-Lamsfus , Elizabeth P. Wildman , Ashley J. Wooles , Laurent Maron et al.
Nature Communications, 2019, 10, ⟨10.1038/s41467-019-12206-5⟩
Article dans une revue hal-04022176 v1

Studies on Molybdena- and Tungstenacyclobutadiene Complexes Supported by Fluoroalkoxy Ligands as Intermediates of Alkyne Metathesis

Henrike Ehrhorn , Dirk Bockfeld , Matthias Freytag , Thomas Bannenberg , Christos E. Kefalidis et al.
Organometallics, 2019, 38 (7), pp.1627-1639. ⟨10.1021/acs.organomet.9b00068⟩
Article dans une revue hal-04022180 v1

Supported lanthanide catalysts: Role of the grafting on the stereochemical outcome of beta-butyrolactone ROP reaction

Adrien Bathellier , Chiara Dinoi , Iker del Rosal , Laurent Maron
Abstracts of Papers of the American Chemical Society, 2019, 258
Article dans une revue hal-03925218 v1
Image document

Investigation of ions hydration using molecular modeling

Johanne Teychené , Hélène Roux De-Balmann , Laurent Maron , Sylvain Galier
Journal of Molecular Liquids, 2019, 294, pp.111394. ⟨10.1016/j.molliq.2019.111394⟩
Article dans une revue hal-02325699 v1

Formation of an alpha-Diimine from Isocyanide Coupling Using Thorium(IV) and Uranium(IV) Phosphido-Methyl Complexes

Pokpong Rungthanaphatsophon , Iker del Rosal , Robert J. Ward , Sean P. Vilanova , Steven P. Kelley et al.
Organometallics, 2019, 38 (8), pp.1733-1740. ⟨10.1021/acs.organomet.9b00043⟩
Article dans une revue hal-04022184 v1

Cyaarside (CAs-) and 1,3-Diarsaallendiide (AsCAs2-) Ligands Coordinated to Uranium and Generated via Activation of the Arsaethynolate Ligand (OCAs-)

Christopher J. Hoerger , Frank W. Heinemann , Elisa Louyriac , Massimo Rigo , Laurent Maron et al.
Angewandte Chemie International Edition, 2019, 58 (6), pp.1679-1683. ⟨10.1002/anie.201811332⟩
Article dans une revue hal-04022171 v1

Alternative (kappa(1)-N:eta(6)-arene vs. kappa(2)-N,N) coordination of a sterically demanding amidinate ligand: are size and electronic structure of the Ln ion decisive factors?

Aleksei O. Tolpygin , Andrei S. Shavyrin , Anton V. Cherkasov , Georgy K. Fukin , Iker del Rosal et al.
Dalton Transactions, 2019, 48 (23), pp.8317-8326. ⟨10.1039/c9dt01162e⟩
Article dans une revue hal-04022178 v1
Image document

Understanding the Multiconfigurational Ground and Excited States in Lanthanide Tetrakis Bipyridine Complexes from Experimental and CASSCF Computational Studies

Robert Halbach , Grégory Nocton , Jorge Amaro-Estrada , Laurent Maron , Corwin A Booth et al.
Inorganic Chemistry, 2019, 58 (18), pp.12083-12098. ⟨10.1021/acs.inorgchem.9b01393⟩
Article dans une revue hal-02289195 v1

CS2 Reductive Coupling to Acetylenedithiolate by a Dinuclear Ytterbium(II) Complex

Davide Toniolo , Aurelien R. Willauer , Julie Andrez , Yan Yang , Rosario Scopelliti et al.
Chemistry - A European Journal, 2019, 25 (33), pp.7831-7834. ⟨10.1002/chem.201901321⟩
Article dans une revue hal-04022170 v1

Divalent Ytterbium Complex-Catalyzed Homo- and Cross-Coupling of Primary Arylsilanes

Xiaojuan Liu , Li Xiang , Elisa Louyriac , Laurent Maron , Xuebing Leng et al.
Journal of the American Chemical Society, 2019, 141 (1), pp.138-142. ⟨10.1021/jacs.8b12138⟩
Article dans une revue hal-04022166 v1
Image document

Grafting of a new bis-silylamido aluminum species on silica: insight from solid-state NMR into interactions with the surface

Tom Vancompernolle , Nicolas Merle , Frédéric Capet , Iker Del rosal , Laurent Maron et al.
Dalton Transactions, 2019, 48 (16), pp.5243 - 5252. ⟨10.1039/c9dt00845d⟩
Article dans une revue hal-03096927 v1

A Uranium Tri-Rhenium Triple Inverse Sandwich Compound

Michael A. Boreen , Trevor D. Lohrey , Guodong Rao , R. David Britt , Laurent Maron et al.
Journal of the American Chemical Society, 2019, 141 (13), pp.5144-5148. ⟨10.1021/jacs.9b01331⟩
Article dans une revue hal-04022182 v1

Cationic magnesium hydride [MgH](+) stabilized by an NNNN-type macrocycle

Lara E. Lemmerz , Debabrata Mukherjee , Thomas P. Spaniol , Anthony Wong , Gabriel Menard et al.
Chemical Communications, 2019, 55 (22), pp.3199-3202. ⟨10.1039/c9cc00490d⟩
Article dans une revue hal-04022177 v1

A tetranuclear calcium hydride cluster with a highly symmetric [Ca4H6](2+) core

Danny Schuhknecht , Thomas P. Spaniol , Iskander Douair , Laurent Maron , Jun Okuda
Chemical Communications, 2019, 55 (98), pp.14837-14839. ⟨10.1039/c9cc08540h⟩
Article dans une revue hal-04022186 v1

A complete series of uranium(iv) complexes with terminal hydrochalcogenido (EH) and chalcogenido (E) ligands E = O, S, Se, Te

Michael W. Rosenzweig , Julian Huemmer , Andreas Scheurer , Carlos Alvarez Lamsfus , Frank W. Heinemann et al.
Dalton Transactions, 2019, 48 (29), pp.10853-10864. ⟨10.1039/c9dt00530g⟩
Article dans une revue hal-04022174 v1

A Combined Experimental and Theoretical Study of the Versatile Reactivity of an Oxocerium(IV) Complex: Concerted Versus Reductive Addition

Ludovic Castro , Yat-Ming So , Chang-Woo Cho , Rolf Lortz , Kai-Hong Wong et al.
Chemistry - A European Journal, 2019, 25 (46), pp.10834-10839. ⟨10.1002/chem.201903035⟩
Article dans une revue hal-04022190 v1

Heterotetrametallic Re-Zn-Zn-Re Complex Generated by an Anionic Rhenium(I) beta-Diketiminate

Trevor D. Lohrey , Laurent Maron , Robert G. Bergman , John Arnold
Journal of the American Chemical Society, 2019, 141 (2), pp.800-804. ⟨10.1021/jacs.8b12494⟩
Article dans une revue hal-04022173 v1
Image document

Reduction of 1,3,5,7-cyclooctatetraene by a molecular calcium hydride: an even electron polarised insertion/deprotonation mechanism

Michael S. Hill , Mary F. Mahon , Andrew S. S. Wilson , Chiara Dinoi , Laurent Maron et al.
Chemical Communications, 2019, 55 (40), pp.5732-5735. ⟨10.1039/c9cc02418b⟩
Article dans une revue hal-04022189 v1

Thermally Stable Ln(II) and Ca(II) Bis(benzhydryl) Complexes: Excellent Precatalysts for Intermolecular Hydrophosphination of C-C Multiple Bonds

Alexander N. Selikhov , Gleb S. Plankin , Anton V. Cherkasov , Andrey S. Shavyrin , Elisa Louyriac et al.
Inorganic Chemistry, 2019, 58 (8), pp.5325-5334. ⟨10.1021/acs.inorgchem.9b00490⟩
Article dans une revue hal-04022167 v1

Identification of a uranium-rhodium triple bond in a heterometallic cluster

Genfeng Feng , Mingxing Zhang , Penglong Wang , Shuao Wang , Laurent Maron et al.
Proceedings of the National Academy of Sciences of the United States of America, 2019, 116 (36), pp.17654-17658. ⟨10.1073/pnas.1904895116⟩
Article dans une revue hal-04022187 v1

Monomeric thorium dihydrido complexes: versatile precursors to actinide metallacycles

Guorui Qin , Yang Wang , Xianghui Shi , Iker del Rosal , Laurent Maron et al.
Chemical Communications, 2019, 55 (59), pp.8560-8563. ⟨10.1039/c9cc04013g⟩
Article dans une revue hal-04022175 v1
Image document

Magnesium hydride alkene insertion and catalytic hydrosilylation

Lucia Garcia , Chiara Dinoi , Mary F. Mahon , Laurent Maron , Michael S. Hill
Chemical Science, 2019, 10 (35), pp.8108-8118. ⟨10.1039/c9sc02056j⟩
Article dans une revue hal-04022185 v1

Cerium Tetrakis(tropolonate) and Cerium Tetrakis(acethylacetonate) Are Not Diamagnetic but Temperature-Independent Paramagnets (vol 57, pg 7290, 2018)

Robert L. Halbach , Grégory Nocton , Corwin H. Booth , Laurent Maron , Richard A. Andersen
Inorganic Chemistry, 2018, 57 (14), pp.8692-8692. ⟨10.1021/acs.inorgchem.8b01686⟩
Article dans une revue hal-04037760 v1

Cerium Tetrakis(tropolonate) and Cerium Tetrakis(acetylacetonate) Are Not Diamagnetic but Temperature-Independent Paramagnets

Robert Halbach , Grégory Nocton , Corwin A Booth , Laurent Maron , Richard A Andersen
Inorganic Chemistry, 2018, 57 (12), pp.7290-7298
Article dans une revue hal-01999443 v1

Scandium alkyl and hydride complexes supported by a pentadentate diborate ligand: reactions with CO2 and N2O

Daniel W. Beh , Warren E. Piers , Iker del Rosal , Laurent Maron , Benjamin S. Gelfand et al.
Dalton Transactions, 2018, 47 (38), pp.13680-13688. ⟨10.1039/c8dt03313g⟩
Article dans une revue hal-04037764 v1

Substitution effects in highly syndioselective styrene polymerization catalysts based on single-component allyl ansa-lanthanidocenes: A theoretical study

Elisa Louyriac , Laurent Maron
Abstracts of Papers of the American Chemical Society, 2018, 255
Article dans une revue hal-04037740 v1

Oxygen Atom Transfer to Cationic PCPNi(II) Complexes Using Amine-N-Oxides

Etienne A. Lapierre , Marissa L. Clapson , Warren E. Piers , Laurent Maron , Denis M. Spasyuk et al.
Inorganic Chemistry, 2018, 57 (1), pp.495-506. ⟨10.1021/acs.inorgchem.7b02766⟩
Article dans une revue hal-04037743 v1

The Nature of the Heavy Alkaline Earth Metal-Hydrogen Bond: Synthesis, Structure, and Reactivity of a Cationic Strontium Hydride Cluster

Debabrata Mukherjee , Thomas Hoellerhage , Valeri Leich , Thomas P. Spaniol , Ulli Englert et al.
Journal of the American Chemical Society, 2018, 140 (9), pp.3403-3411. ⟨10.1021/jacs.7b13796⟩
Article dans une revue hal-04037750 v1

Experimental and Theoretical Studies on the Implications of Halide-Dependent Aqueous Solvation of Sm(II)

Alejandro Ramirez-Solis , Caroline O. Bartulovich , Tesia Chciuk , Jorge Hernandez-Cobos , Humberto Saint-Martin et al.
Journal of the American Chemical Society, 2018, 140 (48), pp.16731-16739. ⟨10.1021/jacs.8b09857⟩
Article dans une revue hal-04037751 v1

Formation of thorium and uranium - phosphorano - stabilized carbene

Pokpong Rungthanaphatsophon , Laurent Maron , Justin Walensky
Abstracts of Papers of the American Chemical Society, 2018, 255
Article dans une revue hal-04037762 v1
Image document

Isolation of a TMTAA-Based Radical in Uranium bis-TMTAA Complexes

Stephan Hohloch , Mary E. Garner , Corwin H. Booth , Wayne W. Lukens , Colin A. Gould et al.
Angewandte Chemie International Edition, 2018, 57 (49), pp.16136-16140. ⟨10.1002/anie.201810971⟩
Article dans une revue hal-04037753 v1

The "Wanderlust" of Me3Si groups in rare-earth triple-decker complexes: a combined experimental and computational study

Volker Lorenz , Phil Liebing , Adrien Bathelier , Felix Engelhardt , Laurent Maron et al.
Chemical Communications, 2018, 54 (73), pp.10280-10283. ⟨10.1039/c8cc05317k⟩
Article dans une revue hal-04037768 v1

Kinetic stabilisation of a molecular strontium hydride complex using an extremely bulky amidinate ligand

Caspar N. de Bruin-Dickason , Thomas Sutcliffe , Carlos Alvarez Lamsfus , Glen B. Deacon , Laurent Maron et al.
Chemical Communications, 2018, 54 (7), pp.786-789. ⟨10.1039/c7cc09362d⟩
Article dans une revue hal-04037746 v1
Image document

A Theoretical Outlook on the Stereoselectivity Origins of Isoselective Zirconocene Propylene Polymerization Catalysts

Ludovic Castro , Gabriel Theurkauff , Aurelien Vantomme , Alexandre Welle , Luc Haspeslagh et al.
Chemistry - A European Journal, 2018, 24 (42), pp.10784-10792. ⟨10.1002/chem.201801438⟩
Article dans une revue hal-01807879 v1
Image document

Heterolysis of Dihydrogen by Nucleophilic Calcium Alkyls

Andrew S. S. Wilson , Chiara Dinoi , Michael S. Hill , Mary F. Mahon , Laurent Maron
Angewandte Chemie International Edition, 2018, 57 (47), pp.15500-15504. ⟨10.1002/anie.201809833⟩
Article dans une revue hal-04037758 v1
Image document

Why Are Saccharides Dehydrated in the Presence of Electrolytes? Insights from Molecular Modeling and Thermodynamic Measurements

Johanne Teychené , Hélène Roux De-Balmann , Laurent Maron , Sylvain Galier
ACS Central Science, 2018, 4 (11), pp.1531-1536. ⟨10.1021/acscentsci.8b00610⟩
Article dans une revue hal-02338970 v1

(C5Me5)(2)Y(mu-H)(mu-CH2C5Me4)Y(C5Me5) as a reservoir of electrons for the reduction of PhSSPh and CO2: A theoretical study

Ludovic Castro , Laurent Maron
Journal of Organometallic Chemistry, 2018, 857, pp.80-87. ⟨10.1016/j.jorganchem.2017.09.033⟩
Article dans une revue hal-04037733 v1
Image document

Phenylacetylene and Carbon Dioxide Activation by an Organometallic Samarium Complex

Violaine Goudy , Mathieu Xemard , Simon Karleskind , Marie Cordier , Carlos A. Lamsfus et al.
Inorganics, 2018, 6 (3), pp.82. ⟨10.3390/inorganics6030082⟩
Article dans une revue hal-01999468 v1
Image document

Small molecule activation with divalent samarium triflate: a synergistic effort to cleave O2

Mathieu Xemard , Marie Cordier , Elisa Louyriac , Laurent Maron , Carine Clavaguera et al.
Dalton Transactions, 2018, 47 (28), pp.9226-9230. ⟨10.1039/c8dt02196a⟩
Article dans une revue hal-01999446 v1

The role of uranium-arene bonding in H2O reduction catalysis

Dominik P. Halter , Frank W. Heinemann , Laurent Maron , Karsten Meyer
Nature Chemistry, 2018, 10 (3), pp.259-267. ⟨10.1038/NCHEM.2899⟩
Article dans une revue hal-04037749 v1

Are ScC and ScP Bonds Reactive in Scandium Phosphinoalkylidene Complex? Insights on a Versatile Reactivity

Weiqing Mao , Li Xiang , Carlos Alvarez Lamsfus , Laurent Maron , Xuebing Leng et al.
Acta Chimica Sinica, 2018, 36 (10), pp.904-908. ⟨10.1002/cjoc.201800253⟩
Article dans une revue hal-04037759 v1

Oxygen-Oxygen Bond Cleavage and Formation in Co(II)-Mediated Stoichiometric O-2 Reduction via the Potential Intermediacy of a Co(IV) Oxyl Radical

Lucie Nurdin , Denis M. Spasyuk , Laura Fairburn , Warren E. Piers , Laurent Maron
Journal of the American Chemical Society, 2018, 140 (47), pp.16094-16105. ⟨10.1021/jacs.8b07726⟩
Article dans une revue hal-04037765 v1

Unprecedented Reaction Mode of Phosphorus in Phosphinidene Rare-Earth Complexes: A Joint Experimental-Theoretical Study

Haiwen Tian , Jianquan Hong , Kai Wang , Iker del Rosal , Laurent Maron et al.
Journal of the American Chemical Society, 2018, 140 (1), pp.102-105. ⟨10.1021/jacs.7b11032⟩
Article dans une revue hal-04037754 v1

Functionalization of Carbon Monoxide and tert-Butyl Nitrile by Intramolecular Proton Transfer in a Bis(Phosphido) Thorium Complex

Sean P. Vilanova , Iker del Rosal , Michael L. Tarlton , Laurent Maron , Justin R. Walensky
Angewandte Chemie International Edition, 2018, 57 (51), pp.16748-16753. ⟨10.1002/anie.201810511⟩
Article dans une revue hal-04037748 v1

Monomeric Rare-Earth Metal Silyl-Thiophosphinoyl-Alkylidene Complexes: Synthesis, Structure, and Reactivity

Chen Wang , Weiqing Mao , Li Xiang , Yan Yang , Jian Fang et al.
Chemistry - A European Journal, 2018, 24 (52), pp.13903-13917. ⟨10.1002/chem.201802791⟩
Article dans une revue hal-04037766 v1

Side Arm Twist on Zn-Catalyzed Hydrosilylative Reduction of CO2 to Formate and Methanol Equivalents with High Selectivity and Activity

Guoqin Feng , Chongyang Du , Li Xiang , Iker del Rosal , Guangyu Li et al.
ACS Catalysis, 2018, 8 (5), pp.4710-4718. ⟨10.1021/acscatal.8b01033⟩
Article dans une revue hal-04037769 v1
Image document

Chemical structure and bonding in a thorium(III)-aluminum heterobimetallic complex

Alison B. Altman , Alexandra C. Brown , Guodong Rao , Trevor D. Lohrey , R. David Britt et al.
Chemical Science, 2018, 9 (18), pp.4317-4324. ⟨10.1039/c8sc01260a⟩
Article dans une revue hal-04037761 v1

Reversing Conventional Reactivity of Mixed Oxo/Alkyl Rare-Earth Complexes: Non-Redox Oxygen Atom Transfer

Jianquan Hong , Haiwen Tian , Lixin Zhang , Xigeng Zhou , Iker del Rosal et al.
Angewandte Chemie International Edition, 2018, 57 (4), pp.1062-1067. ⟨10.1002/anie.201711305⟩
Article dans une revue hal-04037752 v1

Hydration of CH3HgOH and CH3HgCl compared to HgCl2, HgClOH, and Hg(OH)(2): A DFT microsolvation cluster approach

Jorge I. Amaro-Estrada , Jorge Hernandez-Cobos , Humberto Saint-Martin , Laurent Maron , Alejandro Ramirez-Solis
The Journal of Chemical Physics, 2018, 149 (14), ⟨10.1063/1.5038418⟩
Article dans une revue hal-04037739 v1

Mechanism and Effect of Polar Styrenes on Scandium-Catalyzed Copolymerization with Ethylene

Bo Liu , Kening Qiao , Jian Fang , Tiantian Wang , Zichuan Wang et al.
Angewandte Chemie International Edition, 2018, 57 (45), pp.14896-14901. ⟨10.1002/anie.201808836⟩
Article dans une revue hal-04037735 v1

Dianionic Carbon-Bridged Scandium-Copper/Silver Heterobimetallic Complexes: Synthesis, Bonding, and Reactivity

Chen Wang , Li Xiang , Yan Yang , Jian Fang , Laurent Maron et al.
Chemistry - A European Journal, 2018, 24 (21), pp.5637-5643. ⟨10.1002/chem.201706147⟩
Article dans une revue hal-04037744 v1

A tetranuclear samarium(ii) inverse sandwich from direct reduction of toluene by a samarium(ii) siloxide

Rory P. Kelly , Davide Toniolo , Farzaneh Fadaei Tirani , Laurent Maron , Marinella Mazzanti
Chemical Communications, 2018, 54 (73), pp.10268-10271. ⟨10.1039/c8cc04169e⟩
Article dans une revue hal-04037741 v1
Image document

Coordination of arenes and phosphines by charge separated alkaline earth cations

Lucia Garcia , Mathew D. Anker , Mary F. Mahon , Laurent Maron , Michael S. Hill
Dalton Transactions, 2018, 47 (36), pp.12684-12693. ⟨10.1039/c8dt03124j⟩
Article dans une revue hal-04037734 v1

Aqueous Solvation of SmI3: A Born-Oppenheimer Molecular Dynamics Density Functional Theory Cluster Approach

Alejandro Ramirez-Solis , Jorge Ivan Amaro-Estrada , Jorge Hernandez-Cobos , Laurent Maron
Inorganic Chemistry, 2018, 57 (5), pp.2843-2850. ⟨10.1021/acs.inorgchem.7b03220⟩
Article dans une revue hal-04037763 v1

Dinitrogen functionalization at a ditantalum center. Balancing N-2 displacement and N-2 functionalization in the reaction of coordinated N-2 with CS2

Richard J. Burford , Ludovic Castro , Laurent Maron , Jason E. Hein , Michael D. Fryzuk
Dalton Transactions, 2018, 47 (24), pp.7983-7991. ⟨10.1039/c8dt01615a⟩
Article dans une revue hal-04037742 v1
Image document

Steric control in the metal-ligand electron transfer of iminopyridine-ytterbocene complexes

Alexander A. Trifonov , Tatyana V. Mahrova , Lapo Luconi , Giuliano Giambastiani , Dmitry M. Lyubov et al.
Dalton Transactions, 2018, 47 (5), pp.1566-1576. ⟨10.1039/c7dt04299j⟩
Article dans une revue hal-04037757 v1
Image document

A Structurally Characterized Organometallic Plutonium(IV) Complex

Christos Apostolidis , Olaf Walter , Jochen Vogt , Phil Liebing , Laurent Maron et al.
Angewandte Chemie International Edition, 2017, 56 (18), pp.5066-5070. ⟨10.1002/anie.201701858⟩
Article dans une revue hal-01961171 v1

Reactions of Neutral Cobalt(II) Complexes of a Dianionic Tetrapodal Pentadentate Ligand: Cobalt(III) Amides from Imido Radicals

Lucie Nurdin , Denis M. Spasyuk , Warren E. Piers , Laurent Maron
Inorganic Chemistry, 2017, 56 (7), pp.4157--4168
Article dans une revue hal-01961174 v1

Aqueous Solvation of SmI2: A Born-Oppenheimer Molecular Dynamics Density Functional Theory Cluster Approach

A. Ramirez-Solis , J. I. Amaro-Estrada , J. Hernandez-Cobos , Laurent Maron
Journal of Physical Chemistry A, 2017, 121 (11), pp.2293--2297
Article dans une revue hal-01961176 v1

Incipient class II mixed valency in a plutonium solid-state compound

Samantha K. Cary , Shane S. Galley , Matthew L. Marsh , David L. Hobart , Ryan E. Baumbach et al.
Nature Chemistry, 2017, 9 (9), pp.856--861
Article dans une revue hal-01961164 v1

Reversible Insertion of a C = C Bond into Magnesium(I) Dimers: Generation of Highly Active 1,2-Dimagnesioethane Compounds

Aaron J. Boutland , Ashlea Carroll , Carlos A. Lamsfus , Andreas Stasch , Laurent Maron et al.
Journal of the American Chemical Society, 2017, 139 (50), pp.18190-18193. ⟨10.1021/jacs.7b11368⟩
Article dans une revue hal-01961149 v1

Synthesis and Reactivity of a Scandium Terminal Hydride: H-2 Activation by a Scandium Terminal Imido Complex

Xianghao Han , Li Xiang , Carlos A. Lamsfus , Weiqing Mao , Erli Lu et al.
Chemistry - A European Journal, 2017, 23 (59), pp.14728--14732
Article dans une revue hal-01961159 v1

Efficient Reduction of Carbon Dioxide to Methanol Equivalents Catalyzed by Two-Coordinate Amido-Germanium(II) and -Tin(II) Hydride Complexes

Terrance J. Hadlington , Christos E. Kefalidis , Laurent Maron , Cameron Jones
ACS Catalysis, 2017, 7 (3), pp.1853--1859
Article dans une revue hal-01961178 v1
Image document

Organocalcium-mediated nucleophilic alkylation of benzene

Andrew Wilson , Michael Hill , Mary Mahon , Chiara Dinoi , Laurent Maron
Science, 2017, 358 (6367), pp.1168-1171. ⟨10.1126/science.aao5923⟩
Article dans une revue hal-01961155 v1

Bulky Ytterbium Formamidinates Stabilise Complexes with Radical Ligands, and Related Samarium \textquotedblleftTetracyclone\textquotedblright Chemistry

Daniel Werner , Xuefei Zhao , Stephen P. Best , Laurent Maron , Peter C. Junk et al.
Chemistry - A European Journal, 2017, 23 (9), pp.2084--2102
Article dans une revue hal-01961180 v1

Mechanistic Aspects of the Polymerization of Lactide Using a Highly Efficient Aluminum(III) Catalytic System

Carine Robert , Thibault E. Schmid , Vincent Richard , Pierre Haquette , Sumesh K. Raman et al.
Journal of the American Chemical Society, 2017, 139 (17), pp.6217--6225. ⟨10.1021/jacs.7b01749.s001⟩
Article dans une revue hal-01961168 v1

Hydrodeoxygenation of isocyanates: snapshots of a magnesium-mediated C=O bond cleavage

Yan Yang , Mathew D. Anker , Jian Fang , Mary F. Mahon , Laurent Maron et al.
Chemical Science, 2017, 8 (5), pp.3529-3537. ⟨10.1039/c7sc00117g⟩
Article dans une revue hal-01961169 v1
Image document

Evidence for single metal two electron oxidative addition and reductive elimination at uranium

Benedict M. Gardner , Christos E. Kefalidis , Erli Lu , Dipti Patel , Eric J. L. Mcinnes et al.
Nature Communications, 2017, 8, ⟨10.1038/s41467-017-01363-0⟩
Article dans une revue hal-01961154 v1
Image document

Silica-Grafted Lanthanum Benzyl Species: Synthesis, Characterization, and Catalytic Applications

Tom Vancompernolle , Andreia Valente , Thomas Chenal , Philippe Zinck , Iker Del rosal et al.
Organometallics, 2017, 36 (20), pp.3912 - 3920. ⟨10.1021/acs.organomet.7b00538⟩
Article dans une revue hal-01872744 v1
Image document

Inner-sphere vs. outer-sphere reduction of uranyl supported by a redox-active, donor-expanded dipyrrin

James R. Pankhurst , Nicola L. Bell , Markus Zegke , Lucy N. Platts , Carlos A. Lamsfus et al.
Chemical Science, 2017, 8 (1), pp.108-116. ⟨10.1039/c6sc02912d⟩
Article dans une revue hal-01961185 v1

Synthesis and Reactions of [Cp*Yb-2](2)(mu-Me) and [Cp*Yb-2](2)(mu-Me)(Me) and Related Yb-2(II, III) and Yb-2(III, III) Compounds

Marc D. Walter , Philip T. Matsunaga , Carol J. Burns , Laurent Maron , Richard A. Andersen
Organometallics, 2017, 36 (23), pp.4564--4578
Article dans une revue hal-01961151 v1

Formation of Methane versus Benzene in the Reactions of (C5Me5)(2)Th(CH3)(2) with [CH3PPh3]X (X=Cl, Br, I) Yielding Thorium-Carbene or Thorium-Ylide Complexes

Pokpong Rungthanaphatsophon , Adrien Bathelier , Ludovic Castro , Andrew C. Behrle , Charles L. Barnes et al.
Angewandte Chemie International Edition, 2017, 56 (42), pp.12925-12929. ⟨10.1002/anie.201706496⟩
Article dans une revue hal-01961160 v1

Half-Sandwich Alkyl, Amido, and Iodo Samarium(II) Complexes: Non-Conventional Sterically Governed Oxidation of (tBu(4)Carb)(2)Sm

Alexander N. Selikhov , Tatyana V. Mahrova , Anton V. Cherkasov , Georgy K. Fukin , Laurent Maron et al.
Chemistry - A European Journal, 2017, 23 (6), pp.1436--1443
Article dans une revue hal-01961184 v1

SO2 and SO3 reactions with [(C5Me5)(2)Sm-O-Sm (C5Me5)(2)]: a DFT investigation and comparison with CO2 reactivity

Elisa Louyriac , Peter W. Roesky , Laurent Maron
Dalton Transactions, 2017, 46 (24), pp.7660--7663
Article dans une revue hal-01961167 v1

Molecular and Electronic Structures of Eight-Coordinate Uranium Bipyridine Complexes: A Rare Example of a Bipy(2-) Ligand Coordinated to a U4+ Ion

Michael W. Rosenzweig , Frank W. Heinemann , Laurent Maron , Karsten Meyer
Inorganic Chemistry, 2017, 56 (5), pp.2792--2800
Article dans une revue hal-01961177 v1
Image document

Understanding the Scarcity of Thorium Peroxide Clusters

Shane S. Galley , Cayla E. van Alstine , Laurent Maron , Thomas E. Albrecht-Schmitt
Inorganic Chemistry, 2017, 56 (21), pp.12692-12694. ⟨10.1021/acs.inorgchem.7b02216⟩
Article dans une revue hal-01961158 v1

Reductive Disproportionation of CO2 with Bulky Divalent Samarium Complexes

Mathieu Xemard , Violaine Goudy , Augustin Braun , Maxime Tricoire , Marie Cordier et al.
Organometallics, 2017, 36 (23), pp.4660--4668. ⟨10.1021/acs.organomet.7b00630⟩
Article dans une revue hal-01961152 v1

Electronic Structure and Properties of Berkelium Iodates

Mark A. Silver , Samantha K. Cary , Alejandro J. Garza , Ryan E. Baumbach , Alexandra A. Arico et al.
Journal of the American Chemical Society, 2017, 139 (38), pp.13361-13375. ⟨10.1021/jacs.7b05569⟩
Article dans une revue hal-01961162 v1

Nonchelated Phosphoniomethylidene Complexes of Scandium and Lutetium

Weiqing Mao , Li Xiang , Laurent Maron , Xuebing Leng , Yaofeng Chen
Journal of the American Chemical Society, 2017, 139 (49), pp.17759--17762
Article dans une revue hal-01961150 v1
Image document

Substitution Effects in Highly Syndioselective Styrene Polymerization Catalysts Based on Single-Component Allyl ansa-Lanthanidocenes: An Experimental and Theoretical Study

Eva Laur , Elisa Louyriac , Vincent Dorcet , Alexandre Welle , Aurélien Vantomme et al.
Macromolecules, 2017, 50 (17), pp.6539-6551. ⟨10.1021/acs.macromol.7b00853⟩
Article dans une revue hal-01614773 v1

Reduction of a Cerium(III) Siloxide Complex To Afford a Quadruple-Decker Arene-Bridged Cerium(II) Sandwich

Rory P. Kelly , Laurent Maron , Rosario Scopelliti , Marinella Mazzanti
Angewandte Chemie International Edition, 2017, 56 (49), pp.15663--15666
Article dans une revue hal-01961153 v1

Formation of a Uranium-Bound eta(1)-Cyaphide (CP-) Ligand via Activation and C-O Bond Cleavage of Phosphaethynolate (OCP-)

Christopher J. Hoerger , Frank W. Heinemann , Elisa Louyriac , Laurent Maron , Hansjoerg Gruetzmacher et al.
Organometallics, 2017, 36 (22), pp.4351--4354
Article dans une revue hal-01961156 v1

Reactivity studies on [Cp ` Fe(mu-I)](2): nitrido-, sulfido- and diselenide iron complexes derived from pseudohalide activation

Matthias Reiners , Miyuki Maekawa , Constantin G. Daniliuc , Matthias Freytag , Peter G. Jones et al.
Chemical Science, 2017, 8 (5), pp.4108-4122. ⟨10.1039/c7sc00570a⟩
Article dans une revue hal-01961170 v1

Samarium-Catalyzed Diastereoselective Double Addition of Phenylphosphine to Imines and Mechanistic Studies by DFT Calculations

Jianfeng Li , Carlos A. Lamsfus , Changhong Song , Jinxi Liu , Guilan Fan et al.
ChemCatChem, 2017, 9 (8), pp.1368--1372
Article dans une revue hal-01961172 v1
Image document

Metathesis of a U-V imido complex: a route to a terminal U-V sulfide

Rory P. Kelly , Marta Falcone , Carlos A. Lamsfus , Rosario Scopelliti , Laurent Maron et al.
Chemical Science, 2017, 8 (8), pp.5319-5328. ⟨10.1039/c7sc01111c⟩
Article dans une revue hal-01961165 v1
Image document

Alkaline Earth-Centered CO Homologation, Reduction, and Amine Carbonylation

Mathew D. Anker , Christos E. Kefalidis , Yan Yang , Jian Fang , Michael S. Hill et al.
Journal of the American Chemical Society, 2017, 139 (29), pp.10036-10054. ⟨10.1021/jacs.7b04926⟩
Article dans une revue hal-01961166 v1
Image document

Terminal Uranium(V/VI) Nitride Activation of Carbon Dioxide and Carbon Disulfide: Factors Governing Diverse and Well-Defined Cleavage and Redox Reactions

Peter A. Cleaves , Christos E. Kefalidis , Benedict M. Gardner , Floriana Tuna , Eric J. L. Mcinnes et al.
Chemistry - A European Journal, 2017, 23 (12), pp.2950-2959. ⟨10.1002/chem.201605620⟩
Article dans une revue hal-01961181 v1

Valorization of CO2: Preparation of 2-Oxazolidinones by Metal-Ligand Cooperative Catalysis with SCS lndenediide Pd Complexes

Paul Brunel , Julien Monot , Christos E. Kefalidis , Laurent Maron , Blanca Martin-Vaca et al.
ACS Catalysis, 2017, 7 (4), pp.2652-2660. ⟨10.1021/acscatal.7b00209⟩
Article dans une revue hal-01961175 v1
Image document

Accessing Stable Magnesium Acyl Compounds: Reductive Cleavage of Esters by Magnesium(I) Dimers

Aaron J. Boutland , Carlos A. Lamsfus , Brant Maitland , Laurent Maron , Andreas Stasch et al.
Chemistry - A European Journal, 2017, 23 (56), pp.14049-14055. ⟨10.1002/chem.201703061⟩
Article dans une revue hal-01961161 v1

Highly Reactive Scandium Phosphinoalkylidene Complex: C-H and H-H Bonds Activation

Weiqing Mao , Li Xiang , Carlos A. Lamsfus , Laurent Maron , Xuebing Leng et al.
Journal of the American Chemical Society, 2017, 139 (3), pp.1081--1084
Article dans une revue hal-01961182 v1
Image document

Gold(I)-Catalysed Asymmetric Hydroamination of Alkenes: A Silver- and Solvent-Dependent Enantiodivergent Reaction

Marc-Antoine Abadie , Xavier Trivelli , Florian Medina , Nathalie Duhal , Mostafa Kouach et al.
Chemistry - A European Journal, 2017, 23 (45), pp.10777 - 10788. ⟨10.1002/chem.201701301⟩
Article dans une revue hal-01663092 v1

Calcium Hydride Cation [CaH](+) Stabilized by an NNNN-type Macrocyclic Ligand: A Selective Catalyst for Olefin Hydrogenation

Danny Schuhknecht , Carolin Lhotzky , Thomas P. Spaniol , Laurent Maron , Jun Okuda
Angewandte Chemie International Edition, 2017, 56 (40), pp.12367--12371
Article dans une revue hal-01961163 v1

Silica-Supported Tungsten Neosilyl Oxo Precatalysts: Impact of the Podality on Activity and Stability in Olefin Metathesis

D. Grekov , Y. Bouhoute , K. Szeto , N. Merle , A. de Mallmann et al.
Organometallics, 2016, 35 (13), pp.2188-2196. ⟨10.1021/acs.organomet.6b00220⟩
Article dans une revue hal-01968826 v1

New perspectives in organolanthanide chemistry from redox to bond metathesis: insights from theory

Christos E. Kefalidis , Ludovic Castro , Iker Del rosal , Laurent Maron , Lionel Perrin
Chemical Society Reviews, 2016, 45 (9), pp.2516-2543
Article dans une revue hal-01968866 v1

Insights into the Cascade Reaction of CO and Heteroallenes Mediated by Dinitrogen Hafnocene Complexes: The Indirect Effect of Nitride's Nucleophilicity

Christos E. Kefalidis , Laurent Maron
Chemistry - A European Journal, 2016, 22 (14), pp.4743-4747
Article dans une revue hal-01968872 v1

Reductive disproportionation of nitric oxide mediated by low-valent uranium

Christopher Hoerger , Henry La Pierre , Laurent Maron , Andreas Scheurer , Frank Heinemann et al.
Chemical Communications, 2016, 52 (72), pp.10854-10857. ⟨10.1039/c6cc06095a⟩
Article dans une revue hal-01968833 v1
Image document

A case study of proton shuttling in palladium catalysis

Julien Monot , Paul Brunel , Christos E. Kefalidis , Noel Ángel Espinosa-Jalapa , Laurent Maron et al.
Chemical Science, 2016, 7 (3), pp.2179-2187. ⟨10.1039/c5sc04232a⟩
Article dans une revue hal-01968887 v1

The role of H 2 O in the electron transfer-activation of substrates using SmI 2 : insights from DFT

Xuefei Zhao , Lionel Perrin , David Procter , Laurent Maron
Dalton Transactions, 2016, 45 (9), pp.3706-3710
Article dans une revue hal-01969001 v1

The Nature of Secondary Interactions at Electrophilic Metal Sites of Molecular and Silica-Supported Organolutetium Complexes from Solid-State NMR Spectroscopy.

Matthew P Conley , Giuseppe Lapadula , Kevin Sanders , David Gajan , Anne Lesage et al.
Journal of the American Chemical Society, 2016, 138 (11), pp.3831-3843. ⟨10.1021/jacs.6b00071⟩
Article dans une revue hal-01546479 v1
Image document

Synthesis and reactivity of a terminal uranium(IV) sulfide supported by siloxide ligands

Julie Andrez , Jacques Pécaut , Rosario Scopelliti , Christos E. Kefalidis , Laurent Maron et al.
Chemical Science, 2016, 7 (9), pp.5846-5856. ⟨10.1039/C6SC00675B⟩
Article dans une revue hal-01979899 v1

Carbon-Nitrogen Bond Cleavage by a Thorium-NHC-bpy Complex

Mary Garner , Stephan Hohloch , Laurent Maron , John Arnold
Angewandte Chemie International Edition, 2016, 55 (44), pp.13789-13792
Article dans une revue hal-01968816 v1

Effects of the Grafting of Lanthanum Complexes on a Silica Surface on the Reactivity: Influence on Ethylene, Propylene, and 1,3-Butadiene Homopolymerization

Iker Del rosal , Ahmed Yahia , Laurent Maron
Inorganic Chemistry, 2016, 55 (20), pp.10024-10033
Article dans une revue hal-01968797 v1

Activation of Heteroallenes CO x S 2- x ( x = 0-2): Experimental and Theoretical Evidence of the Synthetic Versatility of a Bulky Guanidinato Sm II Complex

Ludovic Castro , David Mills , Cameron Jones , Laurent Maron
European Journal of Inorganic Chemistry, 2016, 2016 (6), pp.792-796
Article dans une revue hal-01968747 v1

Mechanistic insights from theory on the reduction of CO 2 , N 2 O, and SO 2 molecules using tripodal diimine-enolate substituted magnesium( i ) dimers

Christos E. Kefalidis , Cameron Jones , Laurent Maron
Dalton Transactions, 2016, 45 (37), pp.14789-14800
Article dans une revue hal-01968870 v1
Image document

Uranium( iv ) terminal hydrosulfido and sulfido complexes: insights into the nature of the uranium–sulfur bond

Michael W Rosenzweig , Andreas Scheurer , Carlos A. Lamsfus , Frank Heinemann , Laurent Maron et al.
Chemical Science, 2016, 7 (9), pp.5857-5866. ⟨10.1039/c6sc00677a⟩
Article dans une revue hal-01968915 v1
Image document

Versatile coordination of a reactive P,N-ligand toward boron, aluminum and gallium and interconversion reactivity

M. Devillard , Carlos A. Lamsfus , V. Vreeken , Laurent Maron , J. I van Der Vlugt
Dalton Transactions, 2016, 45 (27), pp.10989-10998. ⟨10.1039/c6dt02087a⟩
Article dans une revue hal-01968804 v1

Two-coordinate terminal zinc hydride complexes: synthesis, structure and preliminary reactivity studies

Michael Dawkins , Ewart Middleton , Christos E. Kefalidis , Deepak Dange , Martin Juckel et al.
Chemical Communications, 2016, 52 (69), pp.10490-10492
Article dans une revue hal-01968783 v1

17 O MAS NMR studies of oxo-based olefin metathesis catalysts: a critical assessment of signal enhancement methods

D. Grekov , Y. Bouhoute , Iker Del rosal , Laurent Maron , M. Taoufik et al.
Physical Chemistry Chemical Physics, 2016, 18 (40), pp.28157-28163. ⟨10.1039/C6CP04667C⟩
Article dans une revue hal-01968823 v1

A New Supporting Ligand in Actinide Chemistry Leads to Reactive Bis(NHC)borate-Supported Thorium Complexes

Mary Garner , Stephan Hohloch , Laurent Maron , John Arnold
Organometallics, 2016, 35 (17), pp.2915-2922
Article dans une revue hal-01968815 v1

Characterization of berkelium(III) dipicolinate and borate compounds in solution and the solid state

M. A Silver , S. K Cary , J. Johnson , R. E Baumbach , A. A Arico et al.
Science, 2016, 353 (6302), pp.aaf3762-aaf3762. ⟨10.1126/science.aaf3762⟩
Article dans une revue hal-01968947 v1

Two-Coordinate Magnesium(I) Dimers Stabilized by Super Bulky Amido Ligands

Aaron Boutland , Deepak Dange , Andreas Stasch , Laurent Maron , Cameron Jones
Angewandte Chemie International Edition, 2016, 55 (32), pp.9239-9243
Article dans une revue hal-01968739 v1

The role of H2O in the electron transfer-activation of substrates using Sml2 : a theoretical study

Xuefei Zhao , L Perrin , Dj Procter , Laurent Maron
Dalton Transactions, 2016, 45 (9), pp.3706-3710. ⟨10.1039/C6DT00241B⟩
Article dans une revue hal-01484013 v1

Facile CO Cleavage by a Multimetallic CsU 2 Nitride Complex

Marta Falcone , Christos E. Kefalidis , Rosario Scopelliti , Laurent Maron , Marinella Mazzanti
Angewandte Chemie International Edition, 2016, 55 (40), pp.12290-12294
Article dans une revue hal-01968807 v1

Yb(II) Triple-Decker Complex with the μ-Bridging Naphthalene Dianion [CpBn5Yb(DME)]2(μ-η4:η4-C10H8). Oxidative Substitution of [C10H8]2- by 1,4-Diphenylbuta-1,3-diene and P4 and Protonolysis of the Yb-C10H8 Bond by PhPH2

A.N. Selikhov , T.V. Mahrova , A.V. Cherkasov , G.K. Fukin , E. Kirillov et al.
Organometallics, 2016, 35 (14), pp.2401--2409. ⟨10.1021/acs.organomet.6b00428⟩
Article dans une revue hal-01367220 v1

Non-Pincer-Type Mononuclear Scandium Alkylidene Complexes: Synthesis, Bonding, and Reactivity

Chen Wang , Jiliang Zhou , Xuefei Zhao , Laurent Maron , Xuebing Leng et al.
Chemistry - A European Journal, 2016, 22 (4), pp.1258-1261
Article dans une revue hal-01968987 v1

Modification of silica-supported tungsten neosilyl oxo precatalysts: impact of substituted phenol on activity and stability in olefin metathesis

Y. Bouhoute , Iker Del rosal , K. Szeto , N. Merle , D. Grekov et al.
Catalysis Science & Technology, 2016, 6 (24), pp.8532-8539
Article dans une revue hal-01968728 v1

Molecular Calcium Hydride: Dicalcium Trihydride Cation Stabilized by a Neutral NNNN-Type Macrocyclic Ligand

Valeri Leich , Thomas Spaniol , Laurent Maron , Jun Okuda
Angewandte Chemie International Edition, 2016, 55 (15), pp.4794-4797
Article dans une revue hal-01968880 v1
Image document

Activation of SO 2 by [Zn(Cp*) 2 ] and [(Cp*)Zn I –Zn I (Cp*)]

Rory P Kelly , Neda Kazeminejad , Carlos A. Lamsfus , Laurent Maron , Peter Roesky
Chemical Communications, 2016, 52 (89), pp.13090-13093. ⟨10.1039/c6cc05638e⟩
Article dans une revue hal-01968877 v1

Concomitant Carboxylate and Oxalate Formation From the Activation of CO 2 by a Thorium(III) Complex

Alasdair Formanuik , Fabrizio Ortu , Christopher Inman , Andrew Kerridge , Ludovic Castro et al.
Chemistry - A European Journal, 2016, 22 (50), pp.17976-17979
Article dans une revue hal-01968810 v1

Actinide-Catalyzed Intermolecular Addition of Alcohols to Carbodiimides

Rami Batrice , Christos E. Kefalidis , Laurent Maron , Moris Eisen
Journal of the American Chemical Society, 2016, 138 (7), pp.2114-2117
Article dans une revue hal-01968720 v1
Image document

Facile hydrogen atom transfer to iron( iii ) imido radical complexes supported by a dianionic pentadentate ligand

Denis M Spasyuk , Stephanie H Carpenter , Christos E. Kefalidis , Warren E Piers , Michael L. Neidig et al.
Chemical Science, 2016, 7 (9), pp.5939-5944. ⟨10.1039/c6sc01433j⟩
Article dans une revue hal-01968953 v1
Image document

CO2 conversion to isocyanate via multiple N-Si bond cleavage at a bulky uranium(III) complex

Clément Camp , Lucile Chatelain , Christos E. Kefalidis , Jacques Pécaut , Laurent Maron et al.
Chemical Communications, 2015, 51 (84), pp.15454-15457. ⟨10.1039/c5cc06707c⟩
Article dans une revue hal-01588142 v1
Image document

On the Dehydrocoupling of Alkenylacetylenes Mediated by Various Samarocene Complexes: A Charming Story of Metal Cooperativity Revealing a Novel Dual Metal σ-Bond Metathesis Type of Mechanism (DM|σ-BM)

Christos E. Kefalidis , Laurent Maron
Inorganics, 2015, 3 (4), pp.573-588. ⟨10.3390/inorganics3040573⟩
Article dans une revue hal-01969047 v1

A Dimetalloxycarbene Bonding Mode and Reductive Coupling Mechanism for Oxalate Formation from CO 2

Albert Paparo , Jared Silvia , Christos E. Kefalidis , Thomas Spaniol , Laurent Maron et al.
Angewandte Chemie International Edition, 2015, 54 (31), pp.9115-9119
Article dans une revue hal-01968885 v1

Hydroboration of Carbon Dioxide Using Ambiphilic Phosphine–Borane Catalysts: On the Role of the Formaldehyde Adduct

Richard Declercq , Ghenwa Bouhadir , Didier Bourissou , Marc-André Légaré , Marc-André Courtemanche et al.
ACS Catalysis, 2015, 5 (4), pp.2513-2520
Article dans une revue hal-01969164 v1

Control of Oxo-Group Functionalization and Reduction of the Uranyl Ion

Polly Arnold , Anne-Frédérique Pécharman , Rianne Lord , Guy Jones , Emmalina Hollis et al.
Inorganic Chemistry, 2015, 54 (7), pp.3702-3710
Article dans une revue hal-01969412 v1

Amido Analogues of Nonbent Lanthanide (II) and Calcium Metallocenes. Heterolytic Cleavage of π-Bond Ln–Carbazolyl Ligand Promoted by Lewis Base Coordination

Alexander Selikhov , Anton Cherkasov , Georgy Fukin , Alexander A. Trifonov , Iker Del rosal et al.
Organometallics, 2015, 34 (3), pp.555-562
Article dans une revue hal-01968821 v1

A Mixed-Valence Tri-Zinc Complex, [LZnZnZnL] (L=Bulky Amide), Bearing a Linear Chain of Two-Coordinate Zinc Atoms

Jamie Hicks , Emma J. Underhill , Christos E. Kefalidis , Laurent Maron , Cameron Jones
Angewandte Chemie International Edition, 2015, 54 (34), pp.10000-10004
Article dans une revue hal-01969079 v1

Structure vs 119Sn NMR Chemical Shift in Three-Coordinated Tin(II) Complexes: Experimental Data and Predictive DFT Computations

Lingfang Wang , Christos E. Kefalidis , Thierry Roisnel , Sourisak Sinbandhit , Laurent Maron et al.
Organometallics, 2015, 34 (11), pp.2139-2150. ⟨10.1021/om5007566⟩
Article dans une revue hal-01114324 v1
Image document

DFT investigations on the ring-opening polymerization of substituted cyclic carbonates catalyzed by zinc-{β-diketiminate} complexes

Iker Del rosal , Pierre Brignou , Sophie M. Guillaume , Jean-François Carpentier , Laurent Maron
Polymer Chemistry, 2015, 6 (17), pp.3336--3352. ⟨10.1039/C5PY00313J⟩
Article dans une revue hal-01154160 v1
Image document

Grafting of lanthanide complexes on silica surfaces dehydroxylated at 200 °C: a theoretical investigation

Iker Del rosal , I.C. Gerber , Romuald Poteau , Laurent Maron
New Journal of Chemistry, 2015, 39 (10), pp.7703-7715
Article dans une revue hal-01969145 v1

Enantiospecific C-H activation using ruthenium nanocatalysts

Céline Taglang , Luis Miguel Martinez-Pietro , Iker Del rosal , Laurent Maron , Romuald Poteau et al.
Angewandte Chemie International Edition, 2015, 54 (36), pp.10474-10477. ⟨10.1002/anie.201504554⟩
Article dans une revue istex hal-01920824 v1

Formation of a Bridging Phosphinidene Thorium Complex

Andrew Behrle , Ludovic Castro , Laurent Maron , Justin Walensky
Journal of the American Chemical Society, 2015, 137 (47), pp.14846-14849
Article dans une revue hal-01969408 v1

Calcium Hydride Catalyzed Highly 1,2-Selective Pyridine Hydrosilylation

Julia Intemann , Heiko Bauer , Jürgen Pahl , Laurent Maron , Sjoerd Harder
Chemistry - A European Journal, 2015, 21 (32), pp.11452-11461
Article dans une revue hal-01969068 v1

Formation and Reactivity of a Molecular Magnesium Hydride with a Terminal Mg—H Bond

Silvia Schnitzler , Thomas Spaniol , Laurent Maron , Jun Okuda
Chemistry - A European Journal, 2015, 21 (32), pp.11330-11334
Article dans une revue hal-01968831 v1
Image document

Ultrathin Gold Nanowires: Soft-Templating versus Liquid Phase Synthesis, a Quantitative Study

Anais Loubat , Lise-Marie Lacroix , Antoine Robert , Marianne Imperor-Clerc , Romuald Poteau et al.
Journal of Physical Chemistry C, 2015, 119 (8), pp.4422-4430. ⟨10.1021/acs.jpcc.5b00242⟩
Article dans une revue hal-02020268 v1

Early Main Group Metal Catalysis: How Important is the Metal?

Johanne Penafiel , Laurent Maron , Sjoerd Harder
Angewandte Chemie International Edition, 2015, 54 (1), pp.201-206
Article dans une revue hal-01968875 v1

Discrete Magnesium Hydride Aggregates: A Cationic Mg 13 H 18 Cluster Stabilized by NNNN-Type Macrocycles

Daniel Martin , Klaus Beckerle , Silvia Schnitzler , Thomas Spaniol , Laurent Maron et al.
Angewandte Chemie International Edition, 2015, 54 (13), pp.4115-4118
Article dans une revue hal-01968889 v1

Accessing Realistic Models for the WO 3 –SiO 2 Industrial Catalyst through the Design of Organometallic Precursors

Y. Bouhoute , D. Grekov , K. Szeto , N. Merle , A. de Mallmann et al.
ACS Catalysis, 2015, ACS Catalysis, 6 (1), pp.1-18. ⟨10.1021/acscatal.5b01744⟩
Article dans une revue hal-01968734 v1
Image document

Can a pentamethylcyclopentadienyl ligand act as a proton-relay in f-element chemistry? Insights from a joint experimental/theoretical study

Christos E. Kefalidis , Lionel Perrin , Carol J. Burns , David J. Berg , Laurent Maron et al.
Dalton Transactions, 2015, 44 (6), pp.2575-2587. ⟨10.1039/C4DT02387K⟩
Article dans une revue hal-01969038 v1

Activation of CO by Hydrogenated Magnesium(I) Dimers: Sterically Controlled Formation of Ethenediolate and Cyclopropanetriolate Complexes

Ralte Lalrempuia , Christos E. Kefalidis , Simon J. Bonyhady , Benedikt Schwarze , Laurent Maron et al.
Journal of the American Chemical Society, 2015, 137 (28), pp.8944-8947
Article dans une revue hal-01968965 v1

Metallacyclic yttrium alkyl and hydrido complexes: synthesis, structures and catalytic activity in intermolecular olefin hydrophosphination and hydroamination

Alexander A. Kissel , Tatyana V. Mahrova , Dmitry M. Lyubov , Anton V. Cherkasov , Georgy K. Fukin et al.
Dalton Transactions, 2015, 44 (27), pp.12137-12148
Article dans une revue hal-01969009 v1
Image document

A Scandium Complex Bearing Both Methylidene and Phosphinidene Ligands: Synthesis, Structure, and Reactivity

Jiliang Zhou , Tengfei Li , Laurent Maron , Xuebing Leng , Yaofeng Chen
Organometallics, 2015, 34 (2), pp.470-476. ⟨10.1021/om500997j⟩
Article dans une revue hal-01968713 v1

Yttrium Dihydride Cation [YH 2 (THF) 2 ] + n : Aggregate Formation and Reaction with (NNNN)-Type Macrocycles

Stefan Arndt , Mathias Kramer , Waldemar Fegler , Yumiko Nakajima , Iker Del rosal et al.
Organometallics, 2015, 34 (15), pp.3739-3747
Article dans une revue hal-01969418 v1

Coordination of a Triphosphine–Silane to Gold: Formation of a Trigonal Pyramidal Complex Featuring Au + →Si Interaction

Pauline Gualco , Sonia Mallet-Ladeira , Hajime Kameo , Hiroshi Nakazawa , Maxime Mercy et al.
Organometallics, 2015, 34 (8), pp.1449-1453
Article dans une revue hal-01969121 v1

Thorium Mono- and Bis(imido) Complexes Made by Reprotonation of cyclo -Metalated Amides

Nicola Bell , Laurent Maron , Polly Arnold
Journal of the American Chemical Society, 2015, 137 (33), pp.10492-10495
Article dans une revue hal-01969404 v1
Image document

Uranium and thorium complexes of the phosphaethynolate ion

Clément Camp , Nicholas Settineri , Julia Lefèvre , Andrew R Jupp , José M Goicoechea et al.
Chemical Science, 2015, 6 (11), pp.6379--6384. ⟨10.1039/c5sc02150b⟩
Article dans une revue hal-01877473 v1

Synthesis and Reactivity of Palladium Complexes Featuring a Diphosphinoborane Ligand

Tobias Schindler , Marcel Lux , Marius Peters , Lennart Scharf , Hassan Osseili et al.
Organometallics, 2015, 34 (10), pp.1978-1984
Article dans une revue hal-01968865 v1

An Actinide Metallacyclopropene Complex: Synthesis, Structure, Reactivity, and Computational Studies

Bo Fang , Wenshan Ren , Guohua Hou , Guofu Zi , De-Cai Fang et al.
Journal of the American Chemical Society, 2014, 136 (49), pp.17249-17261
Article dans une revue hal-01969494 v1

Qualitative Estimation of the Single-Electron Transfer Step Energetics Mediated by Samarium(II) Complexes: A “SOMO–LUMO Gap” Approach

Christos E. Kefalidis , Stéphanie Essafi , Lionel Perrin , Laurent Maron
Inorganic Chemistry, 2014, 53 (7), pp.3427-3433
Article dans une revue hal-01969540 v1

Formation of cyanates in low-valent uranium chemistry: a synergistic experimental/theoretical study

Christos E. Kefalidis , Alistair Frey , S. Mark Roe , F. Geoffrey N. Cloke , Laurent Maron
Dalton Transactions, 2014, 43 (29), pp.11202-11208
Article dans une revue hal-01969545 v1

Heteronuclear NMR Spectroscopy as a Surface-Selective Technique: A Unique Look at the Hydroxyl Groups of γ-Alumina.

Mostafa Taoufik , Kai Szeto , Nicolas Merle , Iker Del rosal , Laurent Maron et al.
Chemistry - A European Journal, 2014, 20 (14), pp.4038-4046
Article dans une revue hal-01969452 v1

On the mechanism of the reaction of a magnesium( i ) complex with CO 2 : a concerted type of pathway

Christos E. Kefalidis , Andreas Stasch , Cameron Jones , Laurent Maron
Chemical Communications, 2014, 50 (82), pp.12318-12321
Article dans une revue hal-01969555 v1
Image document

Controlling selectivity in the reductive activation of CO 2 by mixed sandwich uranium( iii ) complexes

Nikolaos Tsoureas , Ludovic Castro , Alexander Kilpatrick , F. Geoffey N. Cloke , Laurent Maron
Chemical Science, 2014, 5 (10), pp.3777-3788. ⟨10.1039/x0xx00000x⟩
Article dans une revue hal-01969447 v1

A Cationic Zinc Hydride Cluster Stabilized by an N-Heterocyclic Carbene: Synthesis, Reactivity, and Hydrosilylation Catalysis

Arnab Rit , Alessandro Zanardi , Thomas Spaniol , Laurent Maron , Jun Okuda
Angewandte Chemie International Edition, 2014, 53 (48), pp.13273-13277
Article dans une revue hal-01969490 v1
Image document

Near-IR Two Photon Microscopy Imaging of Silica Nanoparticles Functionalized with Isolated Sensitized Yb(III) Centers

Giuseppe Lapadula , Adrien Bourdolle , Florian Allouche , Matthew Conley , Iker del Rosal et al.
Chemistry of Materials, 2014, 26 (2), pp.1062-1073. ⟨10.1021/cm404140q⟩
Article dans une revue hal-01245486 v1

Activation of White Phosphorus by Low-Valent Group 5 Complexes: Formation and Reactivity of cyclo-P4 Inverted Sandwich Compounds

Clément Camp , Laurent Maron , Robert G Bergman , John Arnold
Journal of the American Chemical Society, 2014, 136 (50), pp.17652--17661
Article dans une revue hal-01877475 v1

Computational insights into carbon–carbon homocoupling reactions mediated by organolanthanide(iii) complexes

Christos E. Kefalidis , Lionel Perrin , Laurent Maron
Dalton Transactions, 2014, 43 (11), pp.4520
Article dans une revue hal-01969549 v1

Reducing CO 2 to Methanol Using Frustrated Lewis Pairs: On the Mechanism of Phosphine–Borane-Mediated Hydroboration of CO 2

Marc-André Courtemanche , Marc-André Légaré , Laurent Maron , Frédéric-Georges Fontaine
Journal of the American Chemical Society, 2014, 136 (30), pp.10708-10717
Article dans une revue hal-01969448 v1

Lewis Acid Triggered Reactivity of a Lewis Base Stabilized Scandium-Terminal Imido Complex: C–H Bond Activation, Cycloaddition, and Dehydrofluorination

Jiaxiang Chu , Xianghao Han , Christos E. Kefalidis , Jiliang Zhou , Laurent Maron et al.
Journal of the American Chemical Society, 2014, 136 (31), pp.10894-10897
Article dans une revue hal-01969441 v1

Hydroaminomethylation of Styrene Catalyzed by Rhodium Complexes Containing Chiral Diphosphine Ligands and Mechanistic Studies: Why Is There a Lack of Asymmetric Induction?

Delphine Crozet , Christos E. Kefalidis , Martine Urrutigoity , Laurent Maron , Philippe Kalck
ACS Catalysis, 2014, 4 (2), pp.435-447. ⟨10.1021/cs400906b⟩
Article dans une revue hal-01969481 v1

Activation of SO 2 and CO 2 by Trivalent Uranium Leading to Sulfite/Dithionite and Carbonate/Oxalate Complexes

Anna-Corina Schmidt , Frank Heinemann , Christos E. Kefalidis , Laurent Maron , Peter Roesky et al.
Chemistry - A European Journal, 2014, 20 (42), pp.13501-13506
Article dans une revue hal-01969463 v1
Image document

Aqueous microsolvation of CdCl 2 : Density functional theory and Born-Oppenheimer molecular dynamics studies

A. Ramirez-Solis , Laurent Maron
The Journal of Chemical Physics, 2014, 141 (9), pp.094304. ⟨10.1063/1.447334⟩
Article dans une revue hal-01969513 v1

Multimetallic cooperativity in uranium-mediated CO2 activation

Oliver Cooper , Clément Camp , Jacques Pécaut , Christos E. Kefalidis , Laurent Maron et al.
Journal of the American Chemical Society, 2014, 136 (18), pp.6716--6723. ⟨10.1021/ja5017624⟩
Article dans une revue hal-01877478 v1

Hydrosilylation catalysis by an earth alkaline metal silyl: synthesis, characterization, and reactivity of bis(triphenylsilyl)calcium

Valeri Leich , Thomas Spaniol , Laurent Maron , Jun Okuda
Chemical Communications, 2014, 50 (18), pp.2311
Article dans une revue hal-01969530 v1

Insights into the Formation of Borabenzene Adducts via Ligand Exchange Reactions and TMSCl Elimination from Boracyclohexadiene Precursors

Marc-André Légaré , Guillaume Bélanger-Chabot , Guillaume de Robillard , André Languérand , Laurent Maron et al.
Organometallics, 2014, 33 (13), pp.3596-3606
Article dans une revue hal-01969522 v1

Two-Electron Reductive Carbonylation of Terminal Uranium(V) and Uranium(VI) Nitrides to Cyanate by Carbon Monoxide

Peter Cleaves , David King , Christos E. Kefalidis , Laurent Maron , Floriana Tuna et al.
Angewandte Chemie International Edition, 2014, 53 (39), pp.10412-10415
Article dans une revue hal-01969445 v1

A Series of Uranium (IV, V, VI) Tritylimido Complexes, Their Molecular and Electronic Structures and Reactivity with CO 2

Anna-Corina Schmidt , Frank Heinemann , Laurent Maron , Karsten Meyer
Inorganic Chemistry, 2014, 53 (24), pp.13142-13153
Article dans une revue hal-01969459 v1

Aqueous solvation of HgClOH. Stepwise DFT solvation and Born–Oppenheimer molecular dynamics studies of the HgClOH–(H 2 O) 24 complex

J. Amaro-Estrada , Laurent Maron , A. Ramirez-Solis
Physical Chemistry Chemical Physics, 2014, 16 (18), pp.8455-8464
Article dans une revue hal-01969410 v1

Direct evidence for intermolecular oxidative addition of sigma(Si-Si) bonds to gold

M. Joost , P. Gualco , Yannick Coppel , Karinne Miqueu , Christos E. Kefalidis et al.
Angewandte Chemie International Edition, 2014, 53 (3), pp.747-751. ⟨10.1002/anie.201307613⟩
Article dans une revue istex hal-00991874 v1

Theoretical treatment of one electron redox transformation of a small molecule using f-element complexes

Ludovic Castro , Christos E. Kefalidis , David Mckay , Stéphanie Essafi , Laurent Maron et al.
Dalton Transactions, 2014, 43 (32), pp.12124-12134. ⟨10.1039/C4DT01002G⟩
Article dans une revue hal-01969429 v1
Image document

Reversible Sigma C-C Bond Formation Between Phenanthroline Ligands Activated by (C5Me5)2Yb

Grégory A Nocton , Wayne A Lukens , Corwin A Booth , Sergio A Rozenel , Scott A Medling et al.
Journal of the American Chemical Society, 2014, 136 (24), pp.8626-8641. ⟨10.1021/ja502271q⟩
Article dans une revue hal-01388838 v1

An Intermediate Cobalt(IV) Nitrido Complex and its N-Migratory Insertion Product

Eva Zolnhofer , Martina Käss , Marat Khusniyarov , Frank Heinemann , Laurent Maron et al.
Journal of the American Chemical Society, 2014, 136 (42), pp.15072-15078
Article dans une revue hal-01969435 v1
Image document

The role of 5f-orbital participation in unexpected inversion of the σ-bond metathesis reactivity trend of triamidoamine thorium( iv ) and uranium( iv ) alkyls

Benedict M Gardner , Peter Cleaves , Christos E. Kefalidis , Jian Fang , Laurent Maron et al.
Chemical Science, 2014, 5 (6), pp.2489-2497. ⟨10.1039/c4sc00182f⟩
Article dans une revue hal-01969511 v1

To Bend or Not To Bend: Experimental and Computational Studies of Structural Preference in Ln(Tp iPr 2 ) 2 (Ln = Sm, Tm)

Aurélien Momin , Lee Carter , Yi Yang , Robert Mcdonald , Stéphanie Essafi (née Labouille) et al.
Inorganic Chemistry, 2014, 53 (22), pp.12066-12075
Article dans une revue hal-01969571 v1

Well-Defined Supported Mononuclear Tungsten Oxo Species as Olefin Metathesis Pre-Catalysts

Yassine Bouhoute , Anthony Garron , Denys Grekov , Nicolas Merle , Kai Szeto et al.
ACS Catalysis, 2014, 4 (11), pp.4232-4241
Article dans une revue hal-01969421 v1

On the thermal stability of the branched hexasulfane isomers. A DFT molecular dynamics study of H2S6 conformers

A. Ramirez-Solis , Laurent Maron
Chemical Physics Letters, 2014, 607, pp.64-69. ⟨10.1016/j.cplett.2014.05.028⟩
Article dans une revue hal-01969503 v1
Image document

Carbon-Hydrogen Bond Breaking and Making in the Open-Shell Singlet Molecule Cp* 2 Yb(4,7-Me 2 phen)

Grégory A Nocton , Corwin A Booth , Laurent Maron , Louis Ricard , Richard A Andersen
Organometallics, 2014, 33 (23), pp.6819-6829. ⟨10.1021/om500843z⟩
Article dans une revue hal-01388873 v1

C(sp₃)-H bond activation with triel metals: indium and gallium zwitterions through internal hydride abstraction in rigid salan ligands.

Nicolas Maudoux , Jian Fang , Thierry Roisnel , Vincent Dorcet , Laurent Maron et al.
Chemistry - A European Journal, 2014, 20 (25), pp.7706-17. ⟨10.1002/chem.201402358⟩
Article dans une revue istex hal-01114342 v1

Are Solvent and Dispersion Effects Crucial in Olefin Polymerization DFT Calculations? Some Insights from Propylene Coordination and Insertion Reactions with Group 3 and 4 Metallocenes

Ludovic Castro , Evgueni Kirillov , Olivier Miserque , Alexandre Welle , Luc Haspeslagh et al.
ACS Catalysis, 2014, 5 (1), pp.416-425
Article dans une revue hal-01969167 v1

PMLABe Diol Synthesized by Ring-Opening Polymerization of Racemic Benzyl β-Malolactonate Initiated by Rare-Earth Trisborohydride Complexes: An Experimental and DFT Study

Cédric C. Jaffredo , Matthias Schmid , Iker Del rosal , Teddy Mevel , Peter Roesky et al.
Chemistry - A European Journal, 2014, 20 (44), pp.14387-14402
Article dans une revue hal-01969536 v1

Mixed Alkyl Hydrido Complexes of Zinc: Synthesis, Structure, and Reactivity

Arnab Rit , Thomas Spaniol , Laurent Maron , Jun Okuda
Organometallics, 2014, 33 (8), pp.2039-2047
Article dans une revue hal-01969495 v1

An ion pair scandium hydride supported by a dianionic (NNNN)-type macrocycle ligand

Peng Cui , Thomas Spaniol , Laurent Maron , Jun Okuda
Chemical Communications, 2014, 50 (4), pp.424-426
Article dans une revue hal-01969486 v1

Controlled Thermolysis of Uranium (Alkoxy) siloxy Complexes: A Route to Polymetallic Complexes of Low-Valent Uranium

Clément Camp , Christos E. Kefalidis , Jacques Pécaut , Laurent Maron , Marinella Mazzanti
Angewandte Chemie International Edition, 2013, 52 (48), pp.12646--12650. ⟨10.1002/anie.201307291⟩
Article dans une revue istex hal-01877480 v1

Cleaving bonds in CH3OSO2CF3 with [1,2,4-(Me3C)3C5H2]2CeH; an experimental and computational study

Evan L. Werkema , Ludovic Castro , Laurent Maron , Odile Eisenstein , Richard A. Andersen
New Journal of Chemistry, 2013, 37, pp.132-142. ⟨10.1039/C2NJ40624A⟩
Article dans une revue hal-00763834 v1

The influence of the Torsion Angle in 3,3'-Dimethyl,2,2'-bipyridine on the Intermediate Valence in (C5Me5)2Yb(3,3'-Me2-bipy).

Grégory Nocton , Corwin H Booth , Laurent Maron , Richard a Andersen
Organometallics, 2013, 32 (19), pp.5305-5312. ⟨10.1021/om400528d⟩
Article dans une revue hal-00905903 v1

Organometallic strontium borohydrides - synthesis, catalytic studies, and DFT calculations

Magdalena Kuzdrowska , Liana Annunziata , Sébastian Marks , Matthias Schmid , Cédric G Jaffredo et al.
Dalton Transactions, 2013, 42, pp.9352-9360. ⟨10.1039/C3DT00037K⟩
Article dans une revue hal-00874609 v1

Heteroleptic Tin(II) Initiators for the Ring-Opening (Co)Polymerization of Lactide and Trimethylene Carbonate: Mechanistic Insights from Experiments and Computations.

Lingfang Wang , Christos E. Kefalidis , Sourisak Sinbandhit , Vincent Dorcet , Jean-Francois Carpentier et al.
Chemistry - A European Journal, 2013, 19, pp.13463--13478. ⟨10.1002/chem.201301751⟩
Article dans une revue istex hal-01069851 v1

Polymerization of cyclic esters using N-heterocyclic carbene carboxylate catalysts

E. Brule , Vincent Guérineau , P. Vermault , F. Prima , J. Balogh et al.
Polymer Chemistry, 2013, 4 (8), pp.2414-2423. ⟨10.1039/c3py00108c⟩
Article dans une revue hal-00913428 v1

Thermal Dihydrogen Elimination from Cp☆2Yb(4,5-diazafluorene)

Richard A Andersen , Corwin H Booth , Laurent Maron , Grégory Nocton
Organometallics, 2013, 32 (5), pp.1150-1158. ⟨10.1021/om300876b⟩
Article dans une revue hal-00906381 v1

Yttrium catalysts for syndioselective β-butyrolactone polymerization: on the origin of ligand-induced stereoselectivity

Jian Fang , Mathieu J.-L. Tschan , Thierry Roisnel , Xavier Trivelli , Régis M. Gauvin et al.
Polymer Chemistry, 2013, 4 (2), pp.360-367. ⟨10.1039/c2py20590d⟩
Article dans une revue hal-02042830 v1

Novel phospholyl(diphenylphosphino)methane-ruthenium complexes: unexpected non-assisted cis to trans isomerization of [RuCl 2 (κ 2 -P–P′) 2 ]

Duc Hanh Nguyen , Jean-Claude Daran , Sonia Mallet-Ladeira , Thomas Davin , Laurent Maron et al.
Dalton Transactions, 2013, 42 (1), pp.75-81. ⟨10.1039/C2DT32032K⟩
Article dans une revue hal-02908438 v1

Ring-opening polymerization of racemic β-butyrolactone promoted by rare earth trisborohydride complexes towards a PHB-diol: an experimental and DFT study

Sophie M. Guillaume , Liana Annunziata , Iker Del rosal , Christophe Iftner , Laurent Maron et al.
Polymer Chemistry, 2013, 4 (10), pp.3077-3087. ⟨10.1039/C3PY00056G⟩
Article dans une revue hal-00844464 v1

Cation-Mediated Conversion of the State of Charge in Uranium Arene Inverted-Sandwich Complexes

Clément Camp , Victor Mougel , Jacques Pécaut , Laurent Maron , Marinella Mazzanti
Chemistry - A European Journal, 2013, 19 (51), pp.17528--17540. ⟨10.1002/chem.201302752⟩
Article dans une revue istex hal-01877482 v1

Discrete divalent rare-earth cationic ROP catalysts : ligand-dependent redox behavior and discrepancies with alkaline-earth analogues in a ligand-assisted activated monomer mechanism.

Bo Liu , Thierry Roisnel , Laurent Maron , Jean-François Carpentier , Yann Sarazin
Chemistry - A European Journal, 2013, 19 (12), pp.3986-94. ⟨10.1002/chem.201204340⟩
Article dans une revue istex hal-00824594 v1

Small Changes Have Consequences: Lessons from Tetrabenzyltitanium and -zirconium Surface Organometallic Chemistry

Nicolas Popoff , Jeff Espinas , Jérémie Pelletier , Benoît Macqueron , Kai Szeto et al.
Chemistry - A European Journal, 2013, 19 (3), pp.964-973. ⟨10.1002/chem.201202737⟩
Article dans une revue istex hal-02043430 v1

Decamethylscandocinium-hydrido-(perfluorophenyl)borate: fixation and tandem tris(perfluorophenyl)borane catalysed deoxygenative hydrosilation of carbon dioxide

Andreas Berkefeld , Warren E. Piers , Masood Parvez , Ludovic Castro , Laurent Maron et al.
Chemical Science, 2013, 4, pp.2152-2162. ⟨10.1039/C3SC50145K⟩
Article dans une revue hal-00807145 v1

Bis(phosphinimino)methanide borohydride complexes of the rare-earth elements as initiators for the ring-opening polymerization of trimethylene carbonate: combined experimental and computational investigations

Sophie M. Guillaume , Sophie Guillaume , Pierre Brignou , Nicolas Susperregui , Laurent Maron et al.
Polymer Chemistry, 2012, 3 (2), pp.429-435. ⟨10.1039/c1py00487e⟩
Article dans une revue hal-03327010 v1

β-Diketiminate alkaline-earth cationic complexes: synthesis, structures, lactide polymerization and unusual oxidative reactivity of the ancillary ligand

Bo Liu , Vincent Dorcet , Laurent Maron , Jean-François Carpentier , Yann Sarazin
European Journal of Inorganic Chemistry, 2012, 2012 (18), pp.3023-3031. ⟨10.1002/ejic.201200183⟩
Article dans une revue istex hal-00874211 v1

Organometallic Strontium Borohydrides: Synthesis, X-ray Structures, Catalytic Polymerization of ε-Caprolactone, and Density Functional Calculations

Sébastian Marks , Magdalena Kuzdrowska , Peter W. Roesky , Liana Annunziata , Sophie M. Guillaume et al.
ChemPlusChem, 2012, 77, pp.350-353. ⟨10.1002/cplu.201200052⟩
Article dans une revue istex hal-01477680 v1

Carbon Monoxide Activation via O-Bound CO Using Decamethylscandocinium-Hydridoborate Ion Pairs

Andreas Berkefeld , Warren E. Piers , Masood Parvez , Ludovic Castro , Laurent Maron et al.
Journal of the American Chemical Society, 2012, 134, pp.10843-10851. ⟨10.1021/ja300591v⟩
Article dans une revue hal-00714378 v1

A Theoretical Study of Abiotic Methylation Reactions of Gaseous Elemental Mercury by Halogen-Containing Molecules

Ludovic Castro , A. Dommerguet , Catherine Larose , C. Ferrari , Laurent Maron
Journal of Physical Chemistry A, 2012, 115 (22), pp.5602-5608. ⟨10.1021/jp200643n⟩
Article dans une revue insu-00646712 v1

Selectivity in the C-H Activation Reaction of CH3OSO2CH3 with [1,2,4-(Me3C)3C5H2]2CeH or [1,2,4-(Me3C)3C5H2][1,2-(Me3C)2-4-(Me2CCH2)C5H2]Ce: To Choose or Not To Choose

Evan L. Werkema , Ludovic Castro , Laurent Maron , Odile Eisenstein , Richard A. Andersen
Organometallics, 2012, 31, pp.870-881. ⟨10.1021/om200842t⟩
Article dans une revue hal-00671293 v1

Interception of a Rh(I)–Rh(III) dinuclear trihydride complex revealing the dihydrogen activation by [Rh(CO)2{(R,R)-Ph–BPE}]

Delphine Crozet , David Mckay , Christian Bijani , Aitor Gual , Cyril Godard et al.
Dalton Transactions, 2012, 41 (12), pp.3369. ⟨10.1039/c2dt12400a⟩
Article dans une revue hal-02909585 v1

17 O NMR Gives Unprecedented Insights into the Structure of Supported Catalysts and Their Interaction with the Silica Carrier

Nicolas Merle , Julien Trébosc , Anne Baudouin , Iker Del rosal , Laurent Maron et al.
Journal of the American Chemical Society, 2012, 134 (22), pp.9263 - 9275. ⟨10.1021/ja301085m⟩
Article dans une revue hal-01702437 v1

Siloxides as Supporting Ligands in Uranium (III)-Mediated Small-Molecule Activation

Victor Mougel , Clément Camp , Jacques Pécaut , Christophe Copéret , Laurent Maron et al.
Angewandte Chemie, 2012, 124 (49), pp.12446--12450. ⟨10.1002/anie.201206955⟩
Article dans une revue istex hal-01877486 v1

Interplay between Cationic and Neutral Species in the Rhodium-Catalyzed Hydroaminomethylation Reaction

Delphine Crozet , Aitor Gual , David Mckay , Chiara Dinoi , Cyril Godard et al.
Chemistry - A European Journal, 2012, 18 (23), pp.7128-7140. ⟨10.1002/chem.201103474⟩
Article dans une revue istex hal-02909581 v1
Image document

Mechanistic insights into β-oxygen atom transfer in olefinepoxidation mediated by W( vi ) complexes and H 2 O 2

Chiara Dinoi , Rinaldo Poli , Lionel Perrin , Laurent Maron
Dalton Transactions, 2012, 41 (4), pp.1131-1133. ⟨10.1039/c1dt10924c⟩
Article dans une revue hal-02909748 v1

Ligand Influence on the Redox Chemistry of Organosamarium Complexes: Experimental and Theoretical Studies of the Reactions of (C5Me5)(2)Sm(THF)(2) and (C4Me4P)(2)Sm with Pyridine and Acridine

Stéphanie Labouille , François Nief , X. F Le Goff , Laurent Maron , Douglas R Kindra et al.
Organometallics, 2012, 31 (14), pp.5196-5203. ⟨10.1021/om300573z⟩
Article dans une revue hal-00905893 v1

Insights into the Mechanism of Reaction of [(C5Me5)2SmII(thf)2] with CO2 and COS by DFT Studies

Ludovic Castro , Stéphanie Labouille , Doug K Kindra , Joseph W Ziller , François Nief et al.
Chemistry - A European Journal, 2012, 18 (25), pp.78867895. ⟨10.1002/chem.201103192⟩
Article dans une revue istex hal-00906056 v1

Bis(phosphinimino)methanide borohydride complexes of the rare-earth elements as initiators for the polymerization of methyl methacrylate: combined experimental and computational investigations

Sophie M. Guillaume , Pierre Brignou , Nicolas Susperregui , Laurent Maron , Magdalena Kuzdrowska et al.
Polymer Chemistry, 2011, 2 (4), pp.1728-1736. ⟨10.1039/C1PY00133G⟩
Article dans une revue hal-00877858 v1

Direct Involvement of the Acetato Ligand in the Reductive Elimination Step of Rhodium-Catalyzed Methanol Carbonylation

Nicolas Lassauque , Thomas Davin , Duc Hanh Nguyen , Romain Adcock , Yannick Coppel et al.
Inorganic Chemistry, 2011, 51 (1), pp.4-6. ⟨10.1021/ic201574m⟩
Article dans une revue hal-02910011 v1

Original transition metal→indium interactions upon coordination of a triphosphine-indane

E.J. Derrah , M. Sircoglou , Maxime Mercy , S. Ladeira , G. Bouhadir et al.
Organometallics, 2011, 30 (4), pp.657-660. ⟨10.1021/om1011769⟩
Article dans une revue hal-01613240 v1

Theoretical study of the solvation of HgCl2, HgClOH, Hg(OH)2 and HgCl3−: a density functional theory cluster approach

Ludovic Castro , A. Dommergue , A. Renard , C. Ferrari , A. Ramírez-Solís et al.
Physical Chemistry Chemical Physics, 2011, 13 (37), pp.16772-16779. ⟨10.1039/C1CP22154J⟩
Article dans une revue insu-00646729 v1

Mechanistic Insights of the Initiation Process of the Ring-Opening Polymerization of epsilon-Caprolactone by Divalent Sm(BH4)2THF2 with DFT: Concerted or Oxidative Reaction?

Christophe Iftner , Fanny Bonnet , François Nief , Marc Visseaux , Laurent Maron
Organometallics, 2011, 30 (17), pp.4482-4485. ⟨10.1021/om200512g⟩
Article dans une revue hal-00694171 v1

Isoselective Styrene Polymerization Catalyzed by ansa-Bis(indenyl) Allyl Rare Earth Complexes. Stereochemical and Mechanistic Aspects

Liana Annunziata , Anne-Sophie Rodrigues , Evgeny Kirillov , Yann Sarazin , Jun Okuda et al.
Macromolecules, 2011, 44 (9), pp.3312-3322. ⟨10.1021/ma2003757⟩
Article dans une revue hal-00632223 v1

Discrete, solvent-free alkaline-earth metal cations: metal***fluorine interactions and ROP catalytic activity.

Yann Sarazin , Bo Liu , Thierry Roisnel , Laurent Maron , Jean-François Carpentier
Journal of the American Chemical Society, 2011, 133 (23), pp.9069-87. ⟨10.1021/ja2024977⟩
Article dans une revue hal-00632235 v1

DFT investigations on the ring-opening polymerization of cyclic carbonates catalyzed by zinc-{β-diiminate} complexes

Iker Del rosal , Pierre Brignou , Sophie M. Guillaume , Jean-François Carpentier , Laurent Maron
Polymer Chemistry, 2011, 2 (11), pp.2564-2573. ⟨10.1039/C1PY00309G⟩
Article dans une revue hal-00652161 v1

Theoretical Treatment of Redox Processes Involving Lanthanide(II) Compounds: Reactivity of Organosamarium(II) and Organothulium(II) Complexes with CO2 and Pyridine

Stéphanie Labouille , François Nief , Laurent Maron
Journal of Physical Chemistry A, 2011, pp.8295-8301
Article dans une revue hal-00694174 v1

Synthesis and structure of divalent thulium borohydrides and their application in epsilon-caprolactone polymerisation

Aurélien Momin , Fanny Bonnet , Marc Visseaux , Laurent Maron , Josef Takats et al.
Chemical Communications, 2011, pp.12203-12205
Article dans une revue hal-00695041 v1

Facile Interconversion of [Cp2(Cl)Hf(SnH3)] and [Cp2(Cl)Hf(μ-H)SnH2]: DFT Investigations of Hafnocene Stannyl Complexes as Masked Stannylenes

Julie Guihaume , Christophe Raynaud , Odile Eisenstein , Lionel Perrin , Laurent Maron et al.
Angewandte Chemie International Edition, 2010, 49 (10), pp.1816 - 1819. ⟨10.1002/anie.200906476⟩
Article dans une revue istex hal-00459000 v1

Splitting a C–O bond in dialkylethers with bis(1,2,4-tri-tert-butylcyclopentadienyl)cerium hydride does not occur by a σ-bond metathesis pathway: a combined experimental and DFT computational study

Evan L. Werkema , Ahmed Yahia , Laurent Maron , Odile Eisenstein , Richard A. Andersen
New Journal of Chemistry, 2010, pp.2189-2196. ⟨10.1039/C0NJ00261E⟩
Article dans une revue istex hal-00529431 v1

The reaction of bis(1,2,4-tri-t-butylcyclopentadienyl)ceriumbenzyl, Cp<sub>2</sub>CeCH<sub>2</sub>Ph, with methylhalides: a metathesis reaction that does not proceed by a metathesis transition state

Evan L. Renkema , Richard A. Andersen , Laurent Maron , Odile Eisenstein
Dalton Transactions, 2010, 39, pp.6648-6660. ⟨10.1039/b918103b⟩
Article dans une revue hal-00507075 v1

Copper(I) complexes derived from mono- and diphosphino-boranes: Cu→b interactions supported by arene coordination

M. Sircoglou , Sébastien Bontemps , Maxime Mercy , Karinne Miqueu , S. Ladeira et al.
Inorganic Chemistry, 2010, 49 (9), pp.3983-3990. ⟨10.1021/ic901896z⟩
Article dans une revue hal-01613247 v1

Intermediate-Valence Tautomerism in Decamethylytterbocene Complexes of Methyl-Substituted Bipyridines

Corwin H. Booth , Daniel Kazhdan , Evan L. Werkema , Marc D. Walter , Wayne W. Lukens et al.
Journal of the American Chemical Society, 2010, 132, pp.17537-17549. ⟨10.1021/ja106902s⟩
Article dans une revue hal-00547435 v1

Bis(phosphinimino)methanide borohydride complexes of the rare earth elements as initiators for the ring-opening polymerization of -caprolactone: combined experimental and computational investigations

J. Jenter , P. W. Roesky , N. Ajellal , Sophie M. Guillaume , Nicolas Susperregui et al.
Chemistry - A European Journal, 2010, 16 (15), pp.4629-4638. ⟨10.1002/chem.200903107⟩
Article dans une revue istex hal-00497872 v1

DFT Investigation of the Tacticity Control during Styrene Polymerization Catalyzed by Single-Component Allyl ansa-Lanthanidocenes {(C5H4CMe2(9-C13H8)}Ln(C3H5)

Lionel Perrin , Evgeny Kirillov , Jean-François Carpentier , Laurent Maron
Macromolecules, 2010, 43 (15), pp.6330-6336. ⟨10.1021/ma101061r⟩
Article dans une revue hal-00917568 v1

Bridging Silyl Groups in σ-Bond Metathesis and [1,2]-Shifts. Experimental and Computational Study of the Reaction between Cerium Metallocenes and MeOSiMe3

Evan L. Werkema , Ahmed Yahia , Laurent Maron , Odile Eisenstein , Richard A. Andersen
Organometallics, 2010, 29, pp.5103-5110. ⟨10.1021/om1003286⟩
Article dans une revue hal-00535770 v1
Image document

Multicentered effective group potentials: ligand-field effects in organometallic clusters and dynamical study of chemical reactivity

Christophe Raynaud , Iker Del rosal , Franck Jolibois , Laurent Maron , Romuald Poteau
Theoretical Chemistry Accounts: Theory, Computation, and Modeling, 2010, 126 (3-4), pp.151-163. ⟨10.1007/s00214-009-0615-z⟩
Article dans une revue istex hal-00493604 v1
Image document

Olefin Epoxidation by H2O2/MeCN Catalysed by Cyclopentadienyloxidotungsten(VI) and Molybdenum(VI) Complexes: Experiments and Computations

Chiara Dinoi , Marco Ciclosi , Eric Manoury , Laurent Maron , Lionel Perrin et al.
Chemistry - A European Journal, 2010, 3rd European Chemistry Congress, Nürnberg, 16 (31), pp.9572-9584. ⟨10.1002/chem.201000298⟩
Article dans une revue istex hal-03177754 v1

Bis(dimethylsilyl)amide complexes of the alkaline-earth metals stabilized by β-Si-H agostic interactions: synthesis, characterization, and catalytic activity

Yann Sarazin , D. Roşca , Valentin Poirier , Thierry Roisnel , A. Silvestru et al.
Organometallics, 2010, 29 (23), pp.6569-6577. ⟨10.1021/om100908q⟩
Article dans une revue hal-00589178 v1

Catalytic hydrosilylation of olefins with organolanthanides: a DFT study. Part I: Hydrosilylation of propene by SiH<sub>4</sub>

Noémi Barros , Odile Eisenstein , Laurent Maron
Dalton Transactions, 2010, 39, pp.10749-10756. ⟨10.1039/C0DT00329H⟩
Article dans une revue istex hal-00531502 v1

Catalytic hydrosilylation of olefins with organolanthanide complexes: A DFT study. Part II: Influence of the substitution on olefin and silane

Noémi Barros , Odile Eisenstein , Laurent Maron
Dalton Transactions, 2010, 39, pp.10757-10767. ⟨10.1039/C0DT00330A⟩
Article dans une revue istex hal-00531504 v1
Image document

Uranyl oxo activation and functionalization by metal cation coordination

Polly L. Arnold , Anne-Frédérique Pécharman , Emmalina Hollis , Ahmed Yahia , Laurent Maron et al.
Nature Chemistry, 2010, 2 (12), pp.1056-1061. ⟨10.1038/nchem.904⟩
Article dans une revue cea-02060610 v1
Image document

Hydrogen for X-group exchange in CHX (X = Cl, Br, I , OMe, and NMe) by monomeric [1,2,4-(Me3C)3C5H2]2CeH: experimental and computational support for a carbenoid mechanism

Evan L. Werkema , Richard A. Andersen , Ahmed Yahia , Laurent Maron , Odile Eisenstein
Organometallics, 2009, 28, pp.3173-3185. ⟨10.1021/om9001846⟩
Article dans une revue hal-00384982 v1

2,6-bis(imidazol-2-ylidene) pyridine complexes of lanthanoïdes: a theoretical study of the bonding situation and selective complexation

D. Bourissou , Laurent Maron
Organometallics, 2009, 28, pp.3686-3690
Article dans une revue hal-00443945 v1

2-Indenylidene pincer complexes of zirconium and palladium

D. Bourissou , Laurent Maron , B. Martin-Vaca , Pascal Oulie , Nathalie Saffon et al.
Journal of the American Chemical Society, 2009, 131, pp.3493-3498
Article dans une revue hal-00443921 v1

Bond Activations of PhSiH<sub>3</sub> by Cp<sub>2</sub>SmH: A Mechanistic Investigation by the DFT Method

Lionel Perrin , Laurent Maron , Odile Eisenstein , T. Don Tilley
Organometallics, 2009, 28, pp.3767-3775. ⟨10.1021/om900106n⟩
Article dans une revue hal-00390648 v1

Ionic-type reactivity of 1,3-dibora-2,4-diphosphoniocyclobutane-1,3-diyls : regio- and stereoselective addition of hydracids

Guy Bertrand , D. Bourissou , Gad Fuks , Nathalie Saffon , Laurent Maron
Journal of the American Chemical Society, 2009, 132, pp.13681-13689
Article dans une revue hal-00444590 v1

Gold(I) complexes of phosphanyl-gallanes: from interconverting to separable coordination isomers

G. Bouhadir , Laurent Maron , Maxime Mercy , Nathalie Saffon , Marie Sircoglou et al.
Angewandte Chemie International Edition, 2009, 48, pp.3454-3457
Article dans une revue hal-00443926 v1

On the Initiation Mechanism of Syndiospecific Styrene Polymerization Catalyzed by Single-Component ansa -Lanthanidocenes

Lionel Perrin , Yann Sarazin , Evgueni Kirillov , Jean-François Carpentier , Laurent Maron
Chemistry - A European Journal, 2009, 15 (15), pp.3773 - 3783. ⟨10.1002/chem.200802036⟩
Article dans une revue istex hal-00411131 v1

A DFT study of the reactions of O3 with Hg° or Br−

Ludovic Castro , Aurélien Dommergue , Christophe P. Ferrari , Laurent Maron
Atmospheric Environment, 2009, 43 (35), pp.5708-5711. ⟨10.1016/j.atmosenv.2009.07.038⟩
Article dans une revue istex insu-00497852 v1

The Bond Between CO and Cp'<sub>3</sub>U in Cp'<sub>3</sub>U(CO) involves Backbonding from the Cp'<sub>3</sub>U Ligand-based Orbitals of π-Symmetry, where Cp' represents a substituted cyclopentadienyl ligand

Laurent Maron , Odile Eisenstein , Richard A. Andersen
Organometallics, 2009, 28, pp.3629-3635. ⟨10.1021/om801098b⟩
Article dans une revue hal-00390371 v1

Gold→Silane and Gold→Stannane Complexes: Coordination of Saturated Molecules as Acceptor Ligands

Pauline Gualco , T.P Lin , Maxime Mercy , Marie Sircoglou , Sonia Ladeira et al.
Angewandte Chemie International Edition, 2009, 48, pp.9892-9895
Article dans une revue hal-00458851 v1

Theoretical proposal for an organometallic route to cis-peptides

Georges Trinquier , Romuald Poteau , Laurent Maron , Bruno Chaudret
New Journal of Chemistry, 2009, 33 (9), pp.1833-1836. ⟨10.1039/B904139G⟩
Article dans une revue istex hal-00835609 v1

Decamethylytterbocene Complexes of Bipyridines and Diazabutadienes: Multiconfigurational Ground States and Open-Shell Singlet Formation

Corwin H. Booth , Marc D. Walter , Daniel Kazhdan , Yung-Jin Hu , Wayne W. Lukens et al.
Journal of the American Chemical Society, 2009, 131, pp.6480. ⟨10.1021/ja809624w⟩
Article dans une revue hal-00383199 v1

New Insights into the Polymerization of Methyl Methacrylate Initiated by Rare-Earth Borohydride Complexes: A Combined Experimental and Computational Approach

Noémi Barros , Michèle Schappacher , Paul Dessuge , Laurent Maron , Sophie M. Guillaume
Chemistry - A European Journal, 2008, 14 (6), pp.1881-1890. ⟨10.1002/chem.200701438⟩
Article dans une revue istex hal-00340293 v1

Tracking reactive intermediates in phosphine-promoted reactions with ambiphilic phosphino-boranes

G. Bouhadir , D. Bourissou , Laurent Maron , Nathalie Saffon , Sylvie Moebs-Sanchez
Chemical Communications, 2008, pp.3435-3437
Article dans une revue hal-00371336 v1

Group 10 and 11 metal boratranes (Ni, Pd, Pt, CuCl, AgCl, AuCl, and Au +) derived from a triphosphine-borane

M. Sircoglou , Sébastien Bontemps , G. Bouhadir , N. Saffon , Karinne Miqueu et al.
Journal of the American Chemical Society, 2008, 130 (49), pp.16729-16738. ⟨10.1021/ja8070072⟩
Article dans une revue istex hal-01613260 v1

Cationic methyl complexes of the rare-earth metals: an experimental and computational study on synthesis, structure, and reactivity

Mathias U. Kramer , Dominique Robert , Stefan Arndt , Peter M. Zeimentz , Thomas R. Spaniol et al.
Inorganic Chemistry, 2008, 47, pp.9265. ⟨10.1021/ic801259n⟩
Article dans une revue istex hal-00329846 v1

DFT Investigation of the Catalytic Hydromethylation of Olefins by Scandocenes. 2. Influence of the Ansa Ligand on Propene and Isobutene Hydromethylation

Noémi Barros , Laurent Maron , Odile Eisenstein , T. Don Tilley
Organometallics, 2008, 27, pp.2252-2257. ⟨10.1021/om701270w⟩
Article dans une revue istex hal-00282172 v1

A DFT study of the mechanism of the polymerization of Ε-caprolactone initiated by organolanthanide (boro)hydride complexes

Noémi Barros , P. Mountford , Sophie M. Guillaume , Laurent Maron
Chemistry - A European Journal, 2008, 14, pp.5507-5518
Article dans une revue hal-00343603 v1

Metallaboratranes derived from a triphosphanyl-borane : intrinsic C3 symmetry supported by a Z-type ligand

Sébastien Bontemps , G. Bouhadir , D. Bourissou , Laurent Maron , Maxime Mercy et al.
Angewandte Chemie International Edition, 2008, 47, pp.1481-1484
Article dans une revue hal-00345190 v1

How Elementary Mercury Reacts in the Presence of Halogen Radicals and/or Halogen Anions: A DFT Investigation

Laurent Maron , Aurélien Dommergue , Christophe P. Ferrari , Marlène Delacour-Larose , Xavier Faïn
Chemistry - A European Journal, 2008, 14 (27), pp.8322 à 8329. ⟨10.1002/chem.200800491⟩
Article dans une revue istex insu-00379686 v1

Linear Uranium Complexes X2UL5 with L=Cyanide, Isocyanate: DFT Evidence for Similarities between Uranyl (X=O) and Uranocene (X=Cp) Derivatives

Nathalie Tarrat , Noémi Barros , Colin J. Marsden , Laurent Maron
Chemistry - A European Journal, 2008, 14 (7), pp.2093-2099. ⟨10.1002/chem.200701511⟩
Article dans une revue istex hal-00951616 v1

Reactions of Monomeric [1,2,4 (Me3C)3C5H2]2CeH and CO with or without H2: An Experimental and Computational Study

Evan Werkema , Laurent Maron , Odile Eisenstein , Richard a Andersen
Journal of the American Chemical Society, 2007, 129, pp.2529-2541. ⟨10.1021/ja066482h⟩
Article dans une revue istex hal-00139898 v1

Chemoselectivity in r bond activation by lanthanocene complexes from a DFT perspective: reactions of Cp2LnR (R = CH3, H, SiH3) with SiH4 and CH3-SiH3

Lionel Perrin , Odile Eisenstein , Laurent Maron
New Journal of Chemistry, 2007, 31, pp.549-555. ⟨10.1039/b617425f⟩
Article dans une revue istex hal-00142996 v1

Enforced n1-fluorenyl and indenyl coordination to zirconium : geometrically constrained and sterically-expanded complexes derived from the bifunctional (FluPPh2NAr)- and (IndPPh2NAr)- ligands

C. Freund , Pascal Oulie , D. Bourissou , B. Martin-Vaca , Nathalie Saffon et al.
Organometallics, 2007, 26, pp.6793-6804
Article dans une revue hal-00266301 v1

Transition-metal complexes featuring Z-type ligands : agreement or discrepancy between geometry and dn configuration ?

Nathalie Saffon , Marie Sircoglou , Sébastien Bontemps , G. Bouhadir , Laurent Maron et al.
Angewandte Chemie, 2007, 46, pp.8583-8586
Article dans une revue hal-00266276 v1

Lanthanide complexes of amino-carbenes : on the Samarium-carbene bond from DFT calculations

D. Bourissou , Laurent Maron
Organometallics, 2007, 26, pp.1100-1103
Article dans une revue hal-00274176 v1

Single but Stronger UO, Double but Weaker UNMe Bonds: The Tale Told by Cp2UO and Cp2UNR

Noémi Barros , Daniel Maynau , Laurent Maron , Odile Eisenstein , Guofu Zi et al.
Organometallics, 2007, 26, pp.5059-5065. ⟨10.1021/om700628e⟩
Article dans une revue istex hal-00171205 v1

Transient palladadiphosphanylcarbenes : singlet carbenes with an "inverse" electronic configuration (p2 instead of 2) and unusual transannular metal-carbene interactions (C Pd donation and Pd C back-donation)

Heinz Gornitzka , J. Vignolle , G. Bertrand , D. Bourissou , Laurent Maron et al.
Journal of the American Chemical Society, 2007, 129, pp.978-985
Article dans une revue hal-00274170 v1

Ab Initio Dynamic Study of the Reaction of Cl2LaR (R = H, CH3) with H2

Christophe Raynaud , Jean-Pierre Daudey , Franck Jolibois , Laurent Maron
Journal of Physical Chemistry A, 2006, 110 (1), pp.101-105. ⟨10.1021/jp050771v⟩
Article dans une revue istex hal-00171222 v1

Enforced N1-fluorenyl coordination to rhodium (I) with the (FluPPh2NPh) ligand

C. Freund , Noémi Barros , Heinz Gornitzka , B. Martin-Vaca , Laurent Maron et al.
Organometallics, 2006, 25, pp.4927-4930
Article dans une revue hal-00144966 v1

DFT studies of the methyl exchange reaction between Cp2M–CH3 or Cp*2M–CH3 (Cp = C5H5, Cp* = C5Me5, M = Y, Sc, Ln) and CH4. Does M ionic radius control the reaction?

Noémi Barros , Odile Eisenstein , Laurent Maron
Dalton Transactions, 2006, pp.3052-3057. ⟨10.1039/b600021e⟩
Article dans une revue istex hal-00139901 v1

Berry Pseudorotation Mechanism for the Interpretation of the 19F NMR Spectrum in PF5 by Ab Initio Molecular Dynamics Simulations.

Christophe Raynaud , Laurent Maron , Jean-Pierre Daudey , Franck Jolibois
ChemPhysChem, 2006, 7 (2), pp.407-413. ⟨10.1002/cphc.200500297⟩
Article dans une revue hal-00171227 v1

Ab initio molecular dynamics simulation of the UV absorption spectrum of β-ionone

Christophe Raynaud , Romuald Poteau , Laurent Maron , Franck Jolibois
Journal of Molecular Structure: THEOCHEM, 2006, 771 (1-3), pp.43-50. ⟨10.1016/j.theochem.2006.03.038⟩
Article dans une revue istex hal-00171228 v1

A DFT Study of Stannane Dehydrocoupling Catalyzed by Cp2LaH

Christophe Raynaud , Lionel Perrin , Laurent Maron
Organometallics, 2006, 25 (13), pp.3143-3151. ⟨10.1021/om051060m⟩
Article dans une revue istex hal-00171216 v1

Ab initio molecular dynamics: Plane waves vs. local basis - The role of energy cutoff on the convergence of molecular properties

Christophe Raynaud , Laurent Maron , Franck Jolibois , Jean-Pierre Daudey , Pierre M. Esteves et al.
Chemical Physics Letters, 2005, 414, pp.161-165. ⟨10.1016/j.cplett.2005.08.034⟩
Article dans une revue istex hal-00382889 v1

1,4- vs 1,3-Prototropic Mechanism for Intramolecular Double Proton Transfer Reaction in Monothiooxalic Acid. Theoretical Investigation of Potential Energy Surface

Christophe Raynaud , Jean-Pierre Daudey , Laurent Maron , Franck Jolibois
Journal of Physical Chemistry A, 2005, 109 (42), pp.9646-9652. ⟨10.1021/jp052782u⟩
Article dans une revue istex hal-00431282 v1

1,4-vs 1,3-prototropic mechanism for intramolecular double proton transfer reaction in monothiooxalic acid. Theoretical investigation of potential energy surface

Christophe Raynaud , Jean-Pierre Daudey , Laurent Maron , Franck Jolibois
Journal of Physical Chemistry A, 2005, 109, pp.9646-9652. ⟨10.1021/jp052782u⟩
Article dans une revue istex hal-00382884 v1

Hydrogen for Fluorine Exchange in C6F6 and C6F5H by Monomeric [1,3,4-(Me3C)3C5H2]2CeH: Experimental and Computational Studies

Laurent Maron , E. L. Werkema , L. Perrin , O. Eisenstein , R. A. Andersen
Journal of the American Chemical Society, 2005, 127, pp.279
Article dans une revue hal-00020400 v1

Hydrogen for Fluorine Exchange in CH4-xFx Monomeric by [1,2,4-(Me3C)3C5H2]2CeH: Experimental and Computational Studies

E. L. Werkema , E. Messines , L. Perrin , Laurent Maron , O. Eisenstein et al.
Journal of the American Chemical Society, 2005, 127, pp.7781
Article dans une revue hal-00020392 v1

Reconsidering Car–Parrinello molecular dynamics using direct propagation of molecular orbitals developed upon Gaussian type atomic orbitals

Christophe Raynaud , Laurent Maron , Jean-Pierre Daudey , Franck Jolibois
Physical Chemistry Chemical Physics, 2004, 2004 (6), pp.4226-4232. ⟨10.1039/b402163k⟩
Article dans une revue istex hal-00410105 v1

Two-electron pseudopotential investigation of the electronic structure of the CaAr molecule

Fernand Spiegelman , Laurent Maron , W.H. Breckenridge , J.-M. Mestdagh , J.P. Visticot
The Journal of Chemical Physics, 2002, 117 (16), pp.7534-7550. ⟨10.1063/1.1506921⟩
Article dans une revue hal-00144543 v1

Dinuclear Reactivity Between the Two Metal Centers

Laurent Maron , Philippe Kalck
Kalck, P. Modes of Cooperative Effects in Dinuclear Complexes, 70, Springer International Publishing, pp.157-205, 2023, Topics in Organometallic Chemistry, 978-3-031-32250-1; 978-3-031-32249-5. ⟨10.1007/3418_2023_88⟩
Chapitre d'ouvrage hal-04707626 v1

Catalytic Behavior of Rare-Earth Borohydride Complexes in Polymerization of Polar Monomers

Sophie M. Guillaume , Laurent Maron , Peter W. Roesky
J.-C. G. Bünzli, V. K. Pecharsky. Handbook on the Physics and Chemistry of Rare Earths, Elsevier Science, pp.1-86, 2014, ⟨10.1016/B978-0-444-62711-7.00259-0⟩
Chapitre d'ouvrage hal-00881590 v1

Involvement of an acetato ligand in the reductive elimination step of the rhodium-catalyzed methanol carbonylation

Duc Hanh Nguyen , Nicolas Lassauque , T. Davin , Laurent Maron , Carole Le Berre et al.
Plombeiro, A.J.L. Advances in Organometallic Chemistry and Catalysis: The Silver/Gold Jubilee International Conference on Organometallic Chemistry Celebratory Book, 20, John Wiley & Sons, Inc., pp.259-268, 2014, 978-1-118-74295-2
Chapitre d'ouvrage hal-02042504 v1

Phosphine Based Gold Catalysts for the Asymmetric Hydroamination of Alkenes: Effects of Silver, Anion and Solven

Christophe Michon , Marc O. Abadie , Fernando Torres Medina , Xavier Trivelli , Frédéric Capet et al.
28th International Conference on Organometallic Chemistry, ICOMC 2018, Jul 2018, Florence (IT), France
Communication dans un congrès hal-04411195 v1

Advanced Solid-State NMR as a Key Tool for the Deeper Understanding of Heterogeneous Catalysts

D. Grekov , Nicolas Merle , Kai Chung Szeto , Yassine Bouhoute , Iker Del rosal et al.
1st French-Portuguese NMR GERM Conference, Apr 2016, Lisbon, Portugal
Communication dans un congrès hal-02309343 v1

Accessing the structure of well-defined grafted catalysts with experimental and first principles 17O Solid State NMR methodology

D. Grekov , Yassine Bouhoute , Iker Del rosal , Mostafa Taoufik , Régis M. Gauvin et al.
Journées Nord-Ouest Européennes des Jeunes Chercheurs (JNOEJC), Jun 2016, Lille, France
Communication dans un congrès hal-02309335 v1

17O MAS NMR as a tool for understanding the molecular structure of supported catalysts

D. Grekov , L. Delevoye , Régis M. Gauvin , Yassine Bouhoute , Mostafa Taoufik et al.
SMARTER 5, Sep 2016, Bayreuth, Germany
Communication dans un congrès hal-02309317 v1

Advanced Solid-State NMR as a Key Tool for the Deeper Understanding of Heterogeneous Catalysts

D. Grekov , Nicolas Merle , Kai Chung Szeto , Yassine Bouhoute , Iker Del rosal et al.
ZING conference, May 2016, Varna, Bulgaria
Communication dans un congrès hal-02309346 v1

Advanced solid-state NMR as a key tool for the deeper understanding of heterogeneous catalysts

Régis M. Gauvin , L. Delevoye , Mostafa Taoufik , Iker Del rosal , Laurent Maron
Indo-French Symposium 2016 “Catalysis for Sustainable and Environmental Chemistry” – NCL, Jun 2016, Lille, France
Communication dans un congrès hal-02309342 v1

Well-defined group VI oxo derivatives supported on silica by SOMC: Model of industrial olefin metathesis catalyst

Nicolas Merle , Yassine Bouhoute , Kai Chung Szeto , Aimery de Mallmann , Iker Del rosal et al.
251th ACS Meeting, Mar 2016, San Diego, United States
Communication dans un congrès hal-02333529 v1

17O MAS NMR Studies of oxo-based Olefin Metathesis Catalysts: a Critical Assessment of Signal Enhancement Methods

D. Grekov , L. Delevoye , Régis M. Gauvin , Yassine Bouhoute , Mostafa Taoufik et al.
Conférence du Réseau RMN Grand Bassin Parisien, Sep 2016, Rennes, France
Communication dans un congrès hal-02309320 v1

17O MAS NMR as a tool for understanding the molecular structure of supported catalysts

Denys Grekov , Laurent Delevoye , Régis Gauvin , Yassine Bouhoute , Mostafa Taoufik et al.
Congrès du Groupement d’Études de Résonance Magnétique (GERM 2015), May 2015, Sète, France
Communication dans un congrès hal-02309314 v1

On the Track to Silica-Supported Tungsten Oxo Metathesis Catalysts: Input from 17O Solid-State NMR

Nicolas Merle , Guillaume Girard , Nicolas Popoff , Julien Trébosc , Iker Del rosal et al.
9th Alpine Conference, Sep 2015, Chamonix, France
Communication dans un congrès hal-02310779 v1

17O MAS NMR as a tool for understanding the molecular structure of supported catalysts

Denys Grekov , Laurent Delevoye , Régis Gauvin , Yassine Bouhoute , Mostafa Taoufik et al.
Congrès de la Société Chimique de France (SCF 2015), Jul 2015, Lille, France
Communication dans un congrès hal-02309310 v1

Ligands cyclopentadiényle à bras phosphazène : vers de nouveaux complexes géométriquement contraints

D. Bourissou , C. Freund , Laurent Maron , B. Martin-Vaca
Ligands cyclopentadiényle à bras phosphazène : vers de nouveaux complexes géométriquement contraints, May 2006, NOIRMOUTIER, France
Communication dans un congrès hal-00156787 v1

Ambiphilic PB and PA1 ligands : from M Lewis acid interaction to M-X activation

Sylvain Bontemps , G. Bouhadir , D. Bourissou , Laurent Maron , Karinne Miqueu et al.
Ambiphilic PB and PA1 ligands : from M Lewis acid interaction to M-X activation, Aug 2008, Rennes, France
Communication dans un congrès hal-00399259 v1

Metal boron interactions from ambiphilic phosphine-borane ligands

Sylvain Bontemps , G. Bouhadir , D. Bourissou , Laurent Maron , Karinne Miqueu et al.
Metal boron interactions from ambiphilic phosphine-borane ligands, Sep 2008, Spain
Communication dans un congrès hal-00378985 v1

XXXth Workshop on Rare Earth Elements

M. Schappacher , P. Dessuge , Noémi Barros , Laurent Maron , Sophie M. Guillaume
MMA Polymerization initiated by rare earth (boro)hydride complexes: a combined experimental and computational approach, 2007, Koeln, Germany
Communication dans un congrès hal-00341611 v1