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Matthieu Raynal is a CNRS researcher at Sorbonne Université, IPCM, ECP, (CRCN, 39 yo, 37 pub, 24 pub as corresponding or first author, 1 book chapter, 1 patent, h = 19, 50%). Since 2012 (CNRS position), his research fields encompass the development of supramolecular helical catalysts and the structural and chiroptical characterization of supramolecular functional assemblies and gels. The development of chirally-amplified and switchable scaffold for asymmetric catalysis have been recognized as highly original and solid work by his peers (3 J. Am.Chem.Soc.\[10, 11c\] and 3 Angew.Chem.Int.Ed.\[11a, 11d\] papers published on that topic in the last 8 years).


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Switchable supramolecular helices for asymmetric stereodivergent catalysis

Ran Chen , Ahmad Hammoud , Paméla Aoun , Mayte A Martínez-Aguirre , Nicolas Vanthuyne
Nature Communications, 2024, 15 (1), pp.4116. ⟨10.1038/s41467-024-48412-z⟩
Journal articles hal-04580260v1
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Rationalizing the Extent of the “Sergeants‐and‐Soldiers” Effect in Supramolecular Helical Catalysts: Effect of Copper Coordination

Ahmad Hammoud , Yan Li , Mayte Martínez-Aguirre , Huanjun Kong , Ludovic Dubreucq
Chemistry - A European Journal, 2023, 29 (28), pp.e202300189. ⟨10.1002/chem.202300189⟩
Journal articles hal-04103492v1
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Probing Achiral Benzene‐1,3,5‐tricarboxamide Monomers as Inducers of Homochirality in Supramolecular Helical Catalysts**

Huanjun Kong , Yan Li , Ahmad Hammoud , Ludovic Dubreucq , Claire Troufflard
ChemistryEurope, 2023, 1 (2), ⟨10.1002/ceur.202300027⟩
Journal articles hal-04235176v1
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Interplay Between Hydrogen Bonding and Electron Transfer in Mixed Valence Assemblies of Triarylamine Trisamides

Quentin Sallembien , Paméla Aoun , Sébastien Blanchard , Laurent Bouteiller , Matthieu Raynal
Chemistry - A European Journal, 2023, 29 (9), ⟨10.1002/chem.202203199⟩
Journal articles hal-03989447v1
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Asymmetric hydroamination with far fewer chiral species than copper centers achieved by tuning the structure of supramolecular helical catalysts

Paméla Aoun , Ahmad Hammoud , Mayte A Martínez-Aguirre , Laurent Bouteiller , Matthieu Raynal
Catalysis Science & Technology, 2022, 12 (3), pp.834-842. ⟨10.1039/D1CY02168K⟩
Journal articles hal-03510512v1
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Possible chemical and physical scenarios towards biological homochirality

Quentin Sallembien , Laurent Bouteiller , Jeanne Crassous , Matthieu Raynal
Chemical Society Reviews, 2022, 51 (9), pp.3436-3476. ⟨10.1039/D1CS01179K⟩
Journal articles hal-03632805v1
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Cyclometallated Pt(II) Complexes Containing a Functionalized Bis-Urea Alkynyl Ligand: Probing Aggregation Mediated by Hydrogen Bonds versus Pt...Pt and pi-pi Interactions

Gaëtan Basuyaux , Anissa Amar , Claire Troufflard , Abdou Boucekkine , Rémi Métivier
European Journal of Inorganic Chemistry, 2021, 2021 (35), pp.3622-3631. ⟨10.1002/ejic.202100499⟩
Journal articles hal-03331385v1
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Experimental and computational diagnosis of the fluxional nature of a benzene-1,3,5-tricarboxamide-based hydrogen-bonded dimer

Matthieu Raynal , Yan Li , Claire Troufflard , Cédric Przybylski , Geoffrey Gontard
Physical Chemistry Chemical Physics, 2021, ⟨10.1039/D0CP06128J⟩
Journal articles hal-03142819v1
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Dissecting the role of the sergeants in supramolecular helical catalysts: from chain capping to intercalation

Mayte A. Martínez-Aguirre , Yan Li , Nicolas Vanthuyne , Laurent Bouteiller , Matthieu Raynal
Angewandte Chemie International Edition, 2021, 60, pp.4183-4191. ⟨10.1002/anie.202012457⟩
Journal articles hal-03009425v1
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Energetics of competing chiral supramolecular polymers

Virgile Ayzac , Mohammed Dirany , Matthieu Raynal , Benjamin Isare , Laurent Bouteiller
Chemistry - A European Journal, 2021, ⟨10.1002/chem.202100645⟩
Journal articles hal-03209211v1
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Tuning the Organogelating and Spectroscopic Properties of a C3‐Symmetric Pyrene‐Based Gelator through Charge Transfer

Adrian Gainar , Thanh‐loan Lai , Cristina Oliveras‐gonzález , Flavia Pop , Matthieu Raynal
Chemistry - A European Journal, 2021, 27 (7), pp.2410-2420. ⟨10.1002/chem.202003914⟩
Journal articles hal-03454002v1
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Emergence of homochiral benzene-1,3,5-tricarboxamide helical as- semblies and catalysts upon addition of an achiral monomer

Yan Li , Ahmad Hammoud , Laurent Bouteiller , Matthieu Raynal
Journal of the American Chemical Society, 2020, 142 (12), pp.5676-5688. ⟨10.1021/jacs.9b13157⟩
Journal articles hal-02877177v1
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A Competing Hydrogen Bonding Pattern to Yield Thermo-Thickening Supramolecular Polymer

Virgile Ayzac , Quentin Sallembien , Matthieu Raynal , Benjamin Isare , Jacques Jestin
Angewandte Chemie International Edition, 2019, ⟨10.1002/anie.201908954⟩
Journal articles hal-02285031v1
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Modulation of catalyst enantioselectivity through reversible assembly of supramolecular helices

Yan Li , Xavier Caumes , Matthieu Raynal , Laurent Bouteiller
Chemical Communications, 2019, 55 (15), pp.2162-2165. ⟨10.1039/C8CC09819K⟩
Journal articles hal-02021141v1
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N‐Substituted Benzene‐1‐Urea‐3,5‐Biscarboxamide (BUBA): Easily Accessible C 2 ‐Symmetric Monomers for the Construction of Reversible and Chirally Amplified Helical Assemblies

Yan Li , Ludovic Dubreucq , Bruno G Alvarenga , Matthieu Raynal , Laurent Bouteiller
Chemistry - A European Journal, 2019, 25 (45), pp.10650-10661. ⟨10.1002/chem.201901332⟩
Journal articles hal-02304536v1
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Catalysts supported by homochiral molecular helices: a new concept to implement asymmetric amplification in catalytic science

Yan Li , Laurent Bouteiller , Matthieu Raynal
ChemCatChem, 2019, ⟨10.1002/cctc.201901246⟩
Journal articles hal-02303651v1
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Organogel Formation Rationalized by Hansen Solubility Parameters: Shift of the Gelation Sphere with the Gelator Structure

Danilo Rosa Nunes , Manuel Reche-Tamayo , Emilie Ressouche , Matthieu Raynal , Benjamin Isare
Langmuir, 2019, 35 (24), pp.7970-7977. ⟨10.1021/acs.langmuir.9b00966⟩
Journal articles hal-02285236v1
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Extra hydrogen bonding interactions by peripheral indole groups stabilize benzene-1,3,5-tricarboxamide helical assemblies

Gaëtan Basuyaux , Alaric Desmarchelier , Geoffrey Gontard , Nicolas Vanthuyne , Jamal Moussa
Chemical Communications, 2019, 55 (59), pp.8548-8551. ⟨10.1039/C9CC03906F⟩
Journal articles hal-02304426v1
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Organogel formation rationalized by Hansen solubility parameters: improved methodology

Danilo Rosa Nunes , Matthieu Raynal , Benjamin Isare , Pierre-Antoine Albouy , Laurent Bouteiller
Soft Matter, 2018, 14 (23), pp.4805-4809. ⟨10.1039/c8sm00562a⟩
Journal articles hal-02357562v1
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Probing halogen–halogen interactions in solution

V. Ayzac , Matthieu Raynal , B. Isare , J. Idé , P. Brocorens
Physical Chemistry Chemical Physics, 2017, 19 (48), pp.32443-32450. ⟨10.1039/C7CP06996K⟩
Journal articles hal-01668774v1
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Real-Time Control of the Enantioselectivity of a Supramolecular Catalyst Allows Selecting the Configuration of Consecutively Formed Stereogenic Centers

Jeremy M Zimbron , Xavier Caumes , Yan Li , Christophe M Thomas , Matthieu Raynal
Angewandte Chemie, 2017, ⟨10.1002/ange.201706757⟩
Journal articles hal-01611679v1
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Unexpected Solvent Influence on the Rheology of Supramolecular Polymers

Bruno G Alvarenga , Matthieu Raynal , Laurent Bouteiller , Edvaldo Sabadini
Macromolecules, 2017, 50 (17), pp.6631-6636. ⟨10.1021/acs.macromol.7b00786⟩
Journal articles hal-01698885v1
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Bisurea-based supramolecular polymers: From structure to properties

Benjamin Isare , Sandrine Pensec , Matthieu Raynal , Laurent Bouteiller
Comptes Rendus. Chimie, 2016, Emerging Chemistry in France, 19 (1-2), pp.148-156. ⟨10.1016/j.crci.2015.06.013⟩
Journal articles hal-01390906v1
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Tuning the structure of 1,3,5-benzene tricarboxamide self-assemblies through stereochemistry

Xavier Caumes , Arianna Baldi , Geoffrey Gontard , Patrick Brocorens , Roberto Lazzaroni
Chemical Communications, 2016, 52 (91), pp.13369 - 13372. ⟨10.1039/C6CC07325E⟩
Journal articles hal-01394304v1
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Induced Circular Dichroism in Phosphine Gold(I) Aryl Acetylide Urea Complexes through Hydrogen-Bonded Chiral Co-Assemblies

Julien Dubarle-Offner , Jamal Moussa , Hani Amouri , Benjamin Jouvelet , Laurent Bouteiller
Chemistry - A European Journal, 2016, 22 (12), pp.3985-3990. ⟨10.1002/chem.201504441⟩
Journal articles hal-01318173v1
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Tuning the nature and stability of self-assemblies formed by ester benzene 1,3,5-tricarboxamides: the crucial role played by the substituents

Alaric Desmarchelier , Bruno Giordano Alvarenga , Xavier Caumes , Ludovic Dubreucq , Claire Troufflard
Soft Matter, 2016, 12, pp.7824-7838 ⟨10.1039/C6SM01601D⟩
Journal articles hal-01362222v1
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Correlation between the Selectivity and the Structure of an Asymmetric Catalyst Built on a Chirally Amplified Supramolecular Helical Scaffold

Alaric Desmarchelier , Xavier Caumes , Matthieu Raynal , Anton Vidal-Ferran , Piet W N M van Leeuwen
Journal of the American Chemical Society, 2016, 138 (14), pp.4908-4916. ⟨10.1021/jacs.6b01306⟩
Journal articles hal-01698907v1
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Structural Control of Bisurea‐Based Supramolecular Polymers: Influence of an Ester Moiety

Mohammed Dirany , Virgile Ayzac , Benjamin Isare , Matthieu Raynal , Laurent Bouteiller
Langmuir, 2015, 31 (42), pp.11443--11451. ⟨10.1021/acs.langmuir.5b02974⟩
Journal articles hal-01696685v1
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Revisiting the assembly of amino ester-based benzene-1,3,5-tricarboxamides: chiral rods in solution

Alaric Desmarchelier , Matthieu Raynal , Patrick Brocorens , Nicolas Vanthuyne , Laurent Bouteiller
Chemical Communications, 2015, 51, pp.7397-7400 ⟨10.1039/C5CC01513H⟩
Journal articles hal-01141988v1
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Organogel formation rationalized by Hansen solubility parameters: influence of gelator structure

Julien Bonnet , Gad Suissa , Matthieu Raynal , Laurent Bouteiller
Soft Matter, 2015, 11 (11), pp.2308 - 2308. ⟨10.1039/c5sm00017c⟩
Journal articles hal-01671934v1
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Supramolecular catalysis. Part 2: artificial enzyme mimics

Matthieu Raynal , Pablo Ballester , Anton Vidal-Ferran , Piet W. N. M. van Leeuwen
Chemical Society Reviews, 2014, 43 (5), pp.1734-1787. ⟨10.1039/C3CS60037H⟩
Journal articles hal-01637213v1
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Organogel formation rationalized by Hansen solubility parameters: dos and don'ts

Julien Bonnet , Gad Suissa , Matthieu Raynal , Laurent Bouteiller
Soft Matter, 2014, 10, pp.3154-3160. ⟨10.1039/c4sm00244j⟩
Journal articles hal-01122532v1
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Supramolecular catalysis. Part 1: non-covalent interactions as a tool for building and modifying homogeneous catalysts

Matthieu Raynal , Pablo Ballester , Anton Vidal-Ferran , Piet W N M van Leeuwen
Chemical Society Reviews, 2014, 43 (5), pp.1660-1733. ⟨10.1039/C3CS60027K⟩
Journal articles hal-01637204v1
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Tunable Asymmetric Catalysis through Ligand Stacking in Chiral Rigid Rods

Matthieu Raynal , François Portier , Piet W. N. M. Van Leeuwen , Laurent Bouteiller
Journal of the American Chemical Society, 2013, 135 (47), pp.17687--17690. ⟨10.1021/ja408860s⟩
Journal articles hal-01696696v1
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Organogel formation rationalized by Hansen solubility parameters

Matthieu Raynal , Laurent Bouteiller
Chemical Communications, 2011, 47 (29), pp.8271. ⟨10.1039/c1cc13244j⟩
Journal articles hal-01696704v1
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Hydrogen bonded supramolecular polymers in moderately polar solvents

Farid Ouhib , Matthieu Raynal , Benjamin Jouvelet , Benjamin Isare , Laurent Bouteiller
Chemical Communications, 2011, 47 (38), pp.10683. ⟨10.1039/c1cc14590h⟩
Journal articles hal-01696706v1