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Stéphane Rigaut

Prof. Stéphane Rigaut


Institut des Sciences Chimiques de Rennes UMR 6226 CNRS - Université de Rennes1 Personal webpage : <>
Institut des Sciences Chimiques de Rennes UMR 6226 CNRS - Université de Rennes1 Page web : <>


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Solid-State and Solution Self-assembly Properties of Mono- and Bis-acetylide Ru-II Complexes Bearing Hydrogen-Bonding Amide Functions

Olivier Galangau , Elsa Caytan , William T. Gallonde , Isabelle de Waele , Franck Camerel et al.
European Journal of Inorganic Chemistry, 2023, 26 (1), ⟨10.1002/ejic.202200579⟩
Journal articles hal-03884965v1
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Ytterbium(III) Complex with Photochromic Ruthenium(II) Acetylide Ligand: All Visible Light Photoswitching of NIR Luminescence

Pramila Selvanathan , Elsa Tufenkjian , Olivier Galangau , Thierry Roisnel , François Riobé et al.
Inorganic Chemistry, 2023, ⟨10.1021/acs.inorgchem.2c03628⟩
Journal articles hal-03971589v1
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A photochromic metallacycle with highly anisotropic Dy-F magnetic units

Nour El Beyrouti , Felix Houard , Marie Cordier , Elzbieta Trzop , Stephane Rigaut et al.
Chemical Communications, 2023, 59, pp.5265-5268. ⟨10.1039/d3cc01037f⟩
Journal articles hal-04087412v1
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Electronic transport through single-molecule oligophenyl-diethynyl junctions with direct gold-carbon bonds formed at low temperature

Gautam Mitra , Vincent Delmas , Hassan Al Sabea , Lucie Norel , Olivier Galangau et al.
Nanoscale Advances, 2022, ⟨10.1039/d1na00650a⟩
Journal articles hal-03512454v1
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Dual-gated single-molecule field-effect transistors beyond Moore's law

Linan Meng , Na Xin , Chen Hu , Hassan Al Sabea , Miao Zhang et al.
Nature Communications, 2022, 13 (1), pp.1410. ⟨10.1038/s41467-022-28999-x⟩
Journal articles hal-03631009v1
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Metal complexes bearing photochromic ligands: photocontrol of functions and processes

Olivier Galangau , Lucie Norel , Stéphane Rigaut
Dalton Transactions, 2021, 50 (48), pp.17879-17891. ⟨10.1039/d1dt03397b⟩
Journal articles hal-03464737v1

Quantifying Image Charge Effects in Molecular Tunnel Junctions Based on Self-Assembled Monolayers of Substituted Oligophenylene Ethynylene Dithiols

Zuoti Xie , Valentin Diez Cabanes , Quyen van Nguyen , Sandra Rodriguez-Gonzalez , Lucie Norel et al.
ACS Applied Materials & Interfaces, 2021, 13 (47), pp.56404-56412. ⟨10.1021/acsami.1c16398⟩
Journal articles hal-03467606v1
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Remote Control of Near Infrared Emission with Lanthanide Complexes

Lucie Norel , Olivier Galangau , Hassan Al Sabea , Stéphane Rigaut
ChemPhotoChem, 2021, 5 (5), pp.393-405. ⟨10.1002/cptc.202000248⟩
Journal articles hal-03163655v1
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Molecular Engineering onto Ru-II Bis(1,2-diphenylphosphinoethane) Synthon: Toward an Original Organometallic Gelator

Olivier Galangau , Dania Daou , Nour El Beyrouti , Elsa Caytan , Cristelle Mériadec et al.
Inorganic Chemistry, 2021, 60 (15), pp.11474-11484. ⟨10.1021/acs.inorgchem.1c01488⟩
Journal articles hal-03330805v1

Tunable Symmetry-Breaking-Induced Dual Functions in Stable and Photoswitched Single-Molecule Junctions

Na Xin , Chen Hu , Hassan Al Sabea , Miao Zhang , Chenguang Zhou et al.
Journal of the American Chemical Society, 2021, 143 (49), pp.20811-20817. ⟨10.1021/jacs.1c08997⟩
Journal articles hal-03467703v1
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Photoinduced Architectural Transformation of Noncovalent Fluorescent Photochromic Organic Nanoparticles as Evidenced by Amplified Fluorescence Photoswitching

Thibault Gallavardin , Andrea Mulas , Lucie Norel , Stéphane Rigaut , Arnaud Brosseau et al.
Journal of Physical Chemistry C, 2021, 125 (8), pp.4665-4674. ⟨10.1021/acs.jpcc.0c10287⟩
Journal articles hal-03217020v1
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Hysteresis Photomodulation via Single-Crystal-to-Single-Crystal Isomerization of a Photochromic Chain of Dysprosium Single-Molecule Magnets

Maher Hojorat , Hassan Al Sabea , Lucie Norel , Kevin Bernot , Thierry Roisnel et al.
Journal of the American Chemical Society, 2020, 142 (2), pp.931-936. ⟨10.1021/jacs.9b10584⟩
Journal articles hal-02432642v1
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Efficient luminescence control in dithienylethene functionalized cyclen macrocyclic lanthanide complexes

Hassan Al Sabea , Nadège Hamon , Olivier Galangau , Lucie Norel , Olivier Maury et al.
Inorganic Chemistry Frontiers, 2020, 7 (16), pp.2979-2989. ⟨10.1039/D0QI00354A⟩
Journal articles hal-02903552v1
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Efficient Photomodulation of Visible Eu(III) and Invisible Yb(III) Luminescences using DTE Photochromic Ligands for Optical Encryption

Hassan Al Sabea , Lucie Norel , Olivier Galangau , Thierry Roisnel , Olivier Maury et al.
Advanced Functional Materials, 2020, 30 (30), pp.2002943. ⟨10.1002/adfm.202002943⟩
Journal articles hal-02886431v1
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Coordination-enhanced photochromism in dysprosium dinuclear complexes with photomodulated single-molecule magnet behavior

Lucie Norel , Kevin Bernot , Frédéric Gendron , Colin Gould , Thierry Roisnel et al.
Chemistry Squared - Chem2, 2020, 4, ⟨10.28954/2020.csq.08.001⟩
Journal articles hal-02934618v1
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Self-Assembled Monolayers of Redox-Active 4d-4f Heterobimetallic Complexes

Andrea Mulas , Galina V Dubacheva , Hassan Al Sabea , Fabien Miomandre , Jean-Frédéric Audibert et al.
Langmuir, 2019, 35 (42), pp.13711-13717. ⟨10.1021/acs.langmuir.9b02083⟩
Journal articles hal-02364872v1
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Dual Light and Redox Control of NIR Luminescence with Complementary Photochromic and Organometallic Antennae

Hassan Al Sabea , Lucie Norel , Olivier Galangau , Rémi Métivier , Thierry Roisnel et al.
Journal of the American Chemical Society, 2019, 141 (51), pp.20026-20030. ⟨10.1021/jacs.9b11318⟩
Journal articles hal-02413092v1
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Redox-driven porphyrin based systems for new luminescent molecular switches

Lucie Norel , Clarisse Tourbillon , Julien Warnan , Jean-Frédéric Audibert , Yann Pellegrin et al.
Dalton Transactions, 2018, 47 (25), pp.8364-8374. ⟨10.1039/c8dt01493k⟩
Journal articles hal-01834007v1

Des interrupteurs moléculaires multifonctionnels

L. Norel , S. Rigaut
L'Actualité Chimique, 2018, 430-431, pp.96-100
Journal articles hal-01875203v1

Novel electron-deficient oligo(phenyleneethynylene) derivatives for molecular electronics

R. Kitouni , P. Selvanathan , Olivier Galangau , L. Norel , B. Ouarda et al.
Synthetic Communications, 2018, 48 (9), pp.1052-1059. ⟨10.1080/00397911.2018.1434205⟩
Journal articles hal-01809163v1

Ruthenium(II) sigma-arylacetylide complexes as redox active units for (multi-)functional molecular devices

Xiaoyan He , Corinne Lagrost , Lucie Norel , Stéphane Rigaut
Polyhedron, 2018, 140, pp.169-180. ⟨10.1016/j.poly.2017.08.025⟩
Journal articles hal-01737371v1
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trans to cis photo-isomerization in merocyanine dysprosium and yttrium complexes

Pramila Selvanathan , Vincent Dorcet , Thierry Roisnel , Kevin Bernot , Gang Huang et al.
Dalton Transactions, 2018, 47 (12), pp.4139-4148. ⟨10.1039/c8dt00299a⟩
Journal articles hal-01744292v1
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Dual Redox and Optical Control of Chiroptical Activity in Photochromic Dithienylethenes Decorated with Hexahelicene and Bis-Ethynyl-Ruthenium Units

Chengshuo Shen , Xiaoyan He , Loic Toupet , Lucie Norel , Stéphane Rigaut et al.
Organometallics, 2018, 37 (5), pp.697-705. ⟨10.1021/acs.organomet.7b00534⟩
Journal articles hal-01586567v1
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HOMO Level Pinning in Molecular Junctions Joint Theoretical and Experimental Evidence

S. Rodriguez-Gonzalez , Z. Xie , Olivier Galangau , P. Selvanathan , L. Norel et al.
Journal of Physical Chemistry Letters, 2018, 9 (9), pp.2394-2403. ⟨10.1021/acs.jpclett.8b00575⟩
Journal articles hal-01807082v1
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A Terminal Fluoride Ligand Generates Axial Magnetic Anisotropy in Dysprosium Complexes

Lucie Norel , Lucy E. Darago , Boris Le Guennic , Khetpakorn Chakarawet , Miguel I. Gonzalez et al.
Angewandte Chemie International Edition, 2018, 57 (7), pp.1933-1938. ⟨10.1002/anie.201712139⟩
Journal articles hal-01717763v1
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Ruthenium Carbon-Rich Group as a Redox-Switchable Metal Coupling Unit in Linear Trinuclear Complexes

E. Di Piazza , C. Boilleau , A. Vacher , K. Merahi , L. Norel et al.
Inorganic Chemistry, 2017, 56 (23), pp.14540-14555. ⟨10.1021/acs.inorgchem.7b02288⟩
Journal articles hal-01671622v1
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Dual-Responsive Molecular Switches Based on Dithienylethene-Ru-II Organometallics in Self-Assembled Monolayers Operating at Low Voltage

Andrea Mulas , Xiaoyan He , Yves-Marie Hervault , Lucie Norel , Stéphane Rigaut et al.
Chemistry - A European Journal, 2017, 23 (42), pp.10205--10214. ⟨10.1002/chem.201701903⟩
Journal articles hal-01578549v1
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Highly axial magnetic anisotropy in a N3O5 dysprosium(III) coordination environment generated by a merocyanine ligand

Pramila Selvanathan , Gang Huang , Thierry Guizouarn , Thierry Roisnel , Guglielmo Fernandez-Garcia et al.
Chemistry - A European Journal, 2016, 22 (43), pp.15222-15226. ⟨10.1002/chem.201603439⟩
Journal articles hal-01360879v1
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Modulation of Eu(III) and Yb(III) Luminescence Using a DTE Photochromic Ligand

Xiaoyan He , Lucie Norel , Yves-Marie Hervault , Rémi Métivier , Anthony d'Aléo et al.
Inorganic Chemistry, 2016, 55 (24), pp.12635--12643. ⟨10.1021/acs.inorgchem.6b01797⟩
Journal articles hal-01438123v1

NIR Electrofluorochromic Properties of Aza-Boron-dipyrromethene Dyes

Hanwhuy Lim , Seogjae Seo , Simon Pascal , Quentin Bellier , Stéphane Rigaut et al.
Scientific Reports, 2016, 6 (1), pp.18867. ⟨10.1038/srep18867⟩
Journal articles hal-01256841v1

Ruthenium Carbon-Rich Complexes as Redox Switchable Metal Coupling Units

Emmanuel Di Piazza , Areej Merhi , Lucie Norel , Stéphane Rigaut , Sylvie Choua et al.
Inorganic Chemistry, 2015, 54 (13), pp.6347-6355. ⟨10.1021/acs.inorgchem.5b00667⟩
Journal articles hal-01166769v1

Vinyl ruthenium-modified biphenyl and 2,2'-bipyridines

Stefan Scheerer , Nils Rotthowe , Obadah S. Abdel-Rahman , Rainer F. Winter , Xiaoyan He et al.
Inorganic Chemistry, 2015, 54 (7), pp.3387--402. ⟨10.1021/ic503075e⟩
Journal articles hal-01153433v1

Fast Electron Transfer Exchange at Self-Assembled Monolayers of Organometallic Ruthenium(II) σ-Arylacetylide Complexes

Andrea Mulas , Yves-Marie Hervault , Xiaoyan He , Emmanuel Di Piazza , Lucie Norel et al.
Langmuir, 2015, 31 (25), pp.7138--7147. ⟨10.1021/acs.langmuir.5b01629⟩
Journal articles hal-01169304v1

Electron-Transfer Kinetics in Polymetallic Carbon-Rich Ruthenium(II) Bis(σ-arylacetylides) Wires Connected to Gold

Andrea Mulas , Yves-Marie Hervault , Lucie Norel , Stéphane Rigaut , Corinne Lagrost et al.
ChemElectroChem, 2015, 2 (11), pp.1799-1805. ⟨10.1002/celc.201500206⟩
Journal articles hal-01188235v1

Divinylphenylene- and Ethynylvinylphenylene-Bridged Mono-, Di-, and Triruthenium Complexes for Covalent Binding to Gold Electrodes

Evelyn Wuttke , Yves-Marie Hervault , Polit Walther , Linseis Michael , Erler Philipp et al.
Organometallics, 2014, 33 (18), pp.4672-4686. ⟨10.1021/om400642j⟩
Journal articles hal-01092417v1

Ferromagnetic intermolecular exchange interaction in ethynyl-verdazyl radical crystals

Areej Merhi , Thierry Roisnel , Stéphane Rigaut , Cyrille Train , Lucie Norel et al.
CrystEngComm, 2014, 16 (42), pp.9783-9787. ⟨10.1039/C4CE01437E⟩
Journal articles hal-01115018v1

Diarylethene-Containing Carbon-Rich Ruthenium Organometallics: Tuning of Electrochromism

Yifei Liu , Cheikh Mbacké Ndiaye , Corinne Lagrost , Karine Costuas , Sylvie Choua et al.
Inorganic Chemistry, 2014, 53 (15), pp.8172-8188. ⟨10.1021/ic5013044⟩
Journal articles hal-01092872v1

Orthogonally modulated molecular transport junctions for resettable electronic logic gates

Fanben Meng , Yves-Marie Hervault , Shao Qi , Hu Benhui , Lucie Norel et al.
Nature Communications, 2014, 5 (1), pp.3023. ⟨10.1038/ncomms4023⟩
Journal articles hal-01092362v1

Lanthanide Sensitization with Ruthenium Carbon-Rich Complexes and Redox Commutation of Near-IR Luminescence

Lucie Norel , Emmanuel Di Piazza , Min Feng , Antoine Vacher , Xiaoyan He et al.
Organometallics, 2014, 33 (18), pp.4824-4835. ⟨10.1021/om500059d⟩
Journal articles hal-01151676v1

Redox Modulation of Magnetic Slow Relaxation in a 4f-​Based Single-​Molecule Magnet with a 4d Carbon-​Rich Ligand

Lucie Norel , Min Feng , Kevin Bernot , Thierry Roisnel , Thierry Guizouarn et al.
Inorganic Chemistry, 2014, 53 (5), pp.2361-2363. ⟨10.1021/ic403081y⟩
Journal articles hal-00973431v1
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Metal Complexes in Molecular Junctions.

Stéphane Rigaut
Dalton Transactions, 2013, 42, pp.15859-15863. ⟨10.1039/C3DT51487K⟩
Journal articles hal-00916585v1
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Photo-modulable Molecular Transport Junctions based on Organometallic Molecular Wires

Fanben Meng , Yves-Marie Hervault , Lucie Norel , Karine Costuas , Colin van Dyck et al.
Chemical Science, 2012, 3 (10), pp.3113-3118. ⟨10.1039/C2SC20323E⟩
Journal articles hal-00753710v1

Controlling the stepwise closing of identical DTE photochromic units with electrochemical and optical stimuli.

Yves-Marie Hervault , Cheikh Mbacké Ndiaye , Lucie Norel , Corinne Lagrost , Stéphane Rigaut et al.
Organic Letters, 2012, 14 (17), pp.4454-7. ⟨10.1021/ol301954u⟩
Journal articles hal-00743710v1

A carbon-rich ruthenium decorated dysprosium single molecule magnet

Lucie Norel , Kevin Bernot , Min Feng , Thierry Roisnel , Andrea Caneschi et al.
Chemical Communications, 2012, 48 (33), pp.3948-3950. ⟨10.1039/c2cc30604b⟩
Journal articles hal-00757296v1

Ruthenium-vinylhelicenes: remote metal-based enhancement and redox switching of the chiroptical properties of a helicene core.

Emmanuel Anger , Monika Srebro , Nicolas Vanthuyne , Loïc Toupet , Stéphane Rigaut et al.
Journal of the American Chemical Society, 2012, 134 (38), pp.15628-31. ⟨10.1021/ja304424t⟩
Journal articles hal-00848193v1
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Excited state absorption : a key phenomenon for the improvement of biphotonic based optical limiting at telecommunication wavelengths

Quentin Bellier , Nikolay S. Makarov , Pierre-Antoine Bouit , Stéphane Rigaut , Kenji Kamada et al.
Physical Chemistry Chemical Physics, 2012, 14 (44), pp.15299-15307. ⟨10.1039/C2CP40779E⟩
Journal articles hal-00833259v1

Fully delocalized (ethynyl)(vinyl)phenylene bridged triruthenium complexes in up to five different oxidation states

Evelyn Wuttke , Florian Pevny , Yves-Marie Hervault , Lucie Norel , Malte Drescher et al.
Inorganic Chemistry, 2012, 51 (3), pp.1902-1915. ⟨10.1021/ic2022177⟩
Journal articles hal-00833251v1
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Polynuclear carbon-rich organometallic complexes: clarification of the role of the bridging ligand in the redox properties.

Karine Costuas , Stéphane Rigaut
Dalton Transactions, 2011, 40 (21), pp.5643-58. ⟨10.1039/c0dt01388a⟩
Journal articles hal-00860419v1

Length and Temperature Dependent Conduction of Ruthenium-Containing Redox-Active Molecular Wires

Liang Luo , Ahmed Benameur , Pierre Brignou , Seong Ho Choi , Stéphane Rigaut et al.
Journal of Physical Chemistry C, 2011, 115 (40), pp.19955-19961. ⟨10.1021/jp207336v⟩
Journal articles hal-00874709v1

d-f heterobimetallic association between ytterbium and ruthenium carbon-rich complexes: redox commutation of near-IR luminescence.

Emmanuel Di Piazza , Lucie Norel , Karine Costuas , Adrien Bourdolle , Olivier Maury et al.
Journal of the American Chemical Society, 2011, 133 (16), pp.6174-6. ⟨10.1021/ja2023515⟩
Journal articles hal-00860780v1

Redox -active ruthenium(II) σ-arylacetylide wires for molecular electronics incorporating insulating chains

Ahmed Benameur , Pierre Brignou , Emmanuel Di Piazza , Yves-Marie Hervault , Lucie Norel et al.
New Journal of Chemistry, 2011, 35, pp.2105-2113. ⟨10.1039/C1NJ20235A⟩
Journal articles hal-00874700v1

Fully delocalized (ethynyl)(vinyl)phenylene-bridged diruthenium radical complexes.

Florian Pevny , Emmanuel Di Piazza , Lucie Norel , Malte Drescher , Rainer F. Winter et al.
Organometallics, 2010, 29 (Copyright (C) 2017 American Chemical Society (ACS). All Rights Reserved.), pp.5912--5918. ⟨10.1021/om1007133⟩
Journal articles hal-01475543v1

"Chain-like" trimetallic ruthenium complexes with C7 carbon-rich bridges: experimental and theoretical investigations of electronic communication tuning in five distinct oxidation states.

Céline Olivier , Karine Costuas , Sylvie Choua , Vincent Maurel , Philippe Turek et al.
Journal of the American Chemical Society, 2010, 132 (16), pp.5638-51. ⟨10.1021/ja908948g⟩
Journal articles hal-00860803v1
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A “Cyanine−Cyanine” Salt Exhibiting Photovoltaic Properties

Pierre-Antoine Bouit , Daniel Rauh , Stefan Neugebauer , Juan Luis Delgado , Emmanuel Di Piazza et al.
Organic Letters, 2009, 11 (21), pp.4806-4809. ⟨10.1021/ol901764t⟩
Journal articles hal-01089801v1
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Flexible Strategy for Immobilizing Redox-Active Compounds Using in Situ Generation of Diazonium Salts. Investigations of the Blocking and Catalytic Properties of the Layers

Jean-Marc Noël , Béatrice Sjöberg , Remi Marsac , Dodzi Zigah , Jean-François Bergamini et al.
Langmuir, 2009, 25 (21), pp.12742 - 12749. ⟨10.1021/la901765e⟩
Journal articles hal-01904363v1

Bonding and Electron Delocalization in Ruthenium(III) σ-Arylacetylide Radicals [trans-Cl(η2-dppe)2RuC≡C(4-C6H4X)]+ (X = NO2, C(O)H, C(O)Me, F, H, OMe, NMe2): Misleading Aspects of the ESR Anisotropy

Nicolas Gauthier , Noureddine Tchouar , Frederic Justaud , Gilles Argouarch , Marie P. Cifuentes et al.
Organometallics, 2009, 28 (7), pp.2253-2266. ⟨10.1021/om801138q⟩
Journal articles hal-00442450v1

Linked C7 Carbon-Rich Bridges: a New Dimension for Ruthenium Redox-Active Organometallics

Antoine Vacher , Ahmed Benameur , Cheikh Mbacke Ndiaye , Daniel Touchard , S. Rigaut et al.
Organometallics, 2009, 28, pp.6096-6100. ⟨10.1021/OM9006449⟩
Journal articles hal-00442466v1

REdox-Active Molecular Wires Incorporating Ruthenium(II) Σ-Arylacetylide Complexes for Molecular Electronics

C. Olivier , B.-S. Kim , Daniel Touchard , S. Rigaut
Organometallics, 2008, 27, pp.509-518. ⟨10.1021/om700779x⟩
Journal articles hal-00369602v1

A multifunctional organometallic switch with carbon-rich ruthenium and diarylethene units

Yifei Liu , C. Lagrost , K. Costuas , N. Tchouar , Hubert Le Bozec et al.
Chemical Communications, 2008, pp.6117-6119
Journal articles hal-00355532v1

Intramolecular Optical Electron Transfer in Mixed-Valent Dinuclear Iron-Ruthenium Complexes Featuring a 1,4-Diethynylaryl Spacer

N. Gauthier , C. Olivier , S. Rigaut , Daniel Touchard , Thierry Roisnel et al.
Organometallics, 2008, 27, pp.1063-1072. ⟨10.1021/om700584m⟩
Journal articles hal-00369227v1

A ruthenium(II) allenylidene complex with a 4,5-diazafluorene functional group: A new building-block for organometallic molecular assemblies

O. Pelerin , C. Olivier , Thierry Roisnel , Daniel Touchard , S. Rigaut et al.
Journal of Organometallic Chemistry, 2008, 693, pp.2153-2158. ⟨10.1016/j.jorganchem.2008.03.014⟩
Journal articles hal-00369595v1
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Stable Near-Infrared Anionic Polymethine Dyes: Structure, Photophysical, and Redox Properties

Pierre-Antoine Bouit , Emmanuel Di Piazza , Stéphane Rigaut , Boris Le Guennic , Christophe Aronica et al.
Organic Letters, 2008, 10 (19), pp.4159-4162. ⟨10.1021/ol801416n⟩
Journal articles hal-00369219v1

Guanidinium as powerful cation for the design of lanthanate tris-dipicolinate crystalline materials: Synthesis, structure and photophysical properties

Anthony d'Aléo , Loic Toupet , Stéphane Rigaut , Chantal Andraud , Olivier Maury et al.
Optical Materials, 2008, 30 (11), pp.1682-1688. ⟨10.1016/j.optmat.2007.07.007⟩
Journal articles hal-00369599v1

Electronic communication in "chain-like" trimetallic ruthenium complexes with two C7 carbon-rich conjugated bridges

C. Olivier , S. Choua , P. Turek , Daniel Touchard , S. Rigaut et al.
Chemical Communications, 2007, pp.3100-3102. ⟨10.1039/b704241h⟩
Journal articles hal-00369145v1

Temperature and Length Dependence of Charge Transport in Redox-Avtive Molecular Wires Incorparating Ruthenium(II)Bis(a-arylacetylide) Complexes

B.S. Kim , J. M. Beebe , C. Olivier , S. Rigaut , Daniel Touchard et al.
The Journal of physical chemistry, 2007, 111, pp.7521-7526. ⟨10.1021/jp068824b⟩
Journal articles hal-00369213v1

C7 and C9 carbon-rich bridges in diruthenium systems: synthesis, spectroscopic, and theoretical investigations of different oxidation States.

Stéphane Rigaut , Céline Olivier , Karine Costuas , Sylvie Choua , Omrane Fadhel et al.
Journal of the American Chemical Society, 2006, 128 (17), pp.5859-76. ⟨10.1021/ja0603453⟩
Journal articles hal-00322290v1

Carbon-rich ruthenium complexes containing Bis(allenylidene) and mixed alkynyl-allenylidene bridges

Stéphane Rigaut , J Perruchon , S Guesmi , C Fave , D Touchard et al.
European Journal of Inorganic Chemistry, 2005, 3, pp.447--460. ⟨10.1002/ejic.200400457⟩
Journal articles hal-01475054v1

Ruthenium-allenylidene complexes and their specific behaviour

Stéphane Rigaut , D Touchard , Ph Dixneuf
Coordination Chemistry Reviews, 2004, 248 (15-16), pp.1585--1601. ⟨10.1016/j.ccr.2004.04.016⟩
Journal articles hal-01475056v1

Bis-allenylidene metal complex and unique related radical with delocalization of one electron over both trans carbon-rich chains

Stéphane Rigaut , K Costuas , D Touchard , Jy Saillard , S Golhen et al.
Journal of the American Chemical Society, 2004, 126 (13), pp.4072--4073. ⟨10.1021/ja049631+⟩
Journal articles hal-01475055v1

Amphoteric allenylidene ruthenium complexes and the first dinuclear ruthenium species with a bis-alkenyl carbyne bridging ligand

Stéphane Rigaut , D Touchard , Ph Dixneuf
Organometallics, 2003, 22 (20), pp.3980--3984. ⟨10.1021/om0304098⟩
Journal articles hal-01475058v1

New coupling reactions for the construction of carbon-rich C-7 bridged di-ruthenium complexes

Stéphane Rigaut , D Touchard , Ph Dixneuf
Journal of Organometallic Chemistry, 2003, 684 (1-2), pp.68--76. ⟨10.1016/S0022-328X(03)00505-9⟩
Journal articles hal-01475060v1

Synthesis of an organometallic complex - The allenylidene trans-[Cl(dppe)(2)Ru-II=C=C-CPh2](+),PF6-

D Touchard , M Hissler , Stéphane Rigaut
L'Actualité Chimique, 2003, 7, pp.37--40
Journal articles hal-01475059v1

Electronic structure of ruthenium cumulene complexes [Cl(PH3)(4)RuCnH2]+ (n=1-8) and of their reduced states. Bonding and properties of the cationic, neutral, and anionic series with respect to the cumulenic chain length

N Auger , D Touchard , Stéphane Rigaut , Jf Halet , Jy Saillard et al.
Organometallics, 2003, 22 (8), pp.1638--1644. ⟨10.1021/om020543c⟩
Journal articles hal-01475057v1

Ruthenium Acetylide Oxidation: From Stable Radicals to Allenylidene Synthesis via -Elimination of H+

Florian Monnier , Stephane Rigaut , Francois Mousset , Daniel Touchard , Pierre H. Dixneuf et al.
Organometallics, 2002, 21 (13), pp.2654 -2661. ⟨10.1021/om0200555⟩
Journal articles hal-00164262v1

Water-soluble mono- and star-shaped hexanuclear functional organo-iron catalysts for nitrate and nitrite reduction in water: syntheses and electroanalytical study

Stéphane Rigaut , Mh Delville , J Losada , D Astruc
Inorganica Chimica Acta, 2002, 334, pp.225--242. ⟨10.1016/S0020-1693(02)00764-8⟩
Journal articles hal-01475062v1

Unprecedented coupling of allenylidene and diynyl metal complexes: A bimetallic ruthenium system with a C-7 conjugated bridge

Stéphane Rigaut , J Massue , D Touchard , Jl Fillaut , S Golhen et al.
Angewandte Chemie International Edition, 2002, 41 (23), pp.4513+. ⟨10.1002/1521-3773(20021202)41:23<4513::AID-ANIE4513>3.0.CO;2-3⟩
Journal articles hal-01475061v1

A new binuclear ruthenium complex with an annelated C-7 bridge via an unprecedented [2+2] coupling reaction

Stéphane Rigaut , L Le Pichon , Jc Daran , D Touchard , Ph Dixneuf et al.
Chemical Communications, 2001, 13, pp.1206--1207. ⟨10.1039/b103301h⟩
Journal articles hal-01475064v1

New paramagnetic ruthenium complexes via one-electron reduction of metallacumulenes

Stéphane Rigaut , O Maury , D Touchard , Ph Dixneuf
Chemical Communications, 2001, 4, pp.373--374. ⟨10.1039/b008893p⟩
Journal articles hal-01475066v1

Metallodendrimers towards enzyme mimics and molecular electronics: new-generation catalysts, sensors and molecular batteries

B Alonso , D Astruc , Jc Blais , S Nlate , Stéphane Rigaut et al.
Comptes rendus de l’Académie des sciences. Série IIc, Chimie, 2001, 4 (3), pp.173--180. ⟨10.1016/S1387-1609(00)01225-1⟩
Journal articles hal-01475065v1

Conductivity of triiodide salts in vapor-swollen commodity polymers

Ll Miller , Dc Boyd , Aj Schmidt , Sc Nitzkowski , Stéphane Rigaut et al.
Chemistry of Materials, 2001, 13 (1), pp.9+. ⟨10.1021/cm0006300⟩
Journal articles hal-01475063v1

“Vapoconductivity”. Sorption of organic vapors causes large increases in the conductivity of a dendrimer

Ll Miller , Y Kunugi , A Canavesi , Stéphane Rigaut , Cn Moorefield et al.
Chemistry of Materials, 1998, 10 (7), pp.1751+. ⟨10.1021/cm980313h⟩
Journal articles hal-01475069v1

Electron-reservoir Fe-I complexes: Multiple applications as electron-transfer reagents and the extraordinary reactivity of superoxide generated from dioxygen

D Astruc , Stéphane Rigaut , E Alonso , C Valerio , Mh Delville et al.
ACH-MODELS IN CHEMISTRY, 1998, 135 (5), pp.751--769
Journal articles hal-01475068v1

Engineering nanoscopic macromolecules for applications: Stars versus dendrimers for catalysis and sensoring

C Valerio , Stéphane Rigaut , J Ruiz , Jl Fillaut , Mh Delville et al.
Journal articles hal-01475070v1

Triple C-H/N-H activation by O-2 for molecular engineering: Heterobifunctionalization of the 19-electron redox catalysts Fe(I)-Cp-I(arene)

Stéphane Rigaut , Mh Delville , D Astruc
Journal of the American Chemical Society, 1997, 119 (45), pp.11132--11133. ⟨10.1021/ja9725458⟩
Journal articles hal-01475071v1


C Bossard , Stéphane Rigaut , D Astruc , Mh Delville , G Felix et al.
Journal of the Chemical Society, Chemical Communications, 1993, 3, pp.333--334. ⟨10.1039/c39930000333⟩
Journal articles hal-01475072v1

Temperature and length dependence of charge transport in redox-active molecular wires incorporating ruthenium (II) bis (σ-arylacetylide) complexes.

Bongsoo Kim , Jeremy M. Beebe , Celine Olivier , Stéphane Rigaut , Daniel Touchard et al.
Abstracts of Papers, 233rd ACS National Meeting, Chicago, IL, United States, March 25-29, 2007, 2007, Unknown, Unknown Region. pp.INOR--627
Conference papers hal-01475544v1

Redox Active Architectures and Carbon-Rich Ruthenium Complexes as Models For Molecular Wires

S. Rigaut , D. Touchard , Pierre H. Dixneuf
Toshikazu Hirao. Redox Systems Under Nano-Space Control, Ed. Springer, pp.55-84, 2006
Book sections hal-00324118v1

Dendrimers containing ferrocenyl- or other transition-metal sandwich groups

B. Alonso , E. Alonso , Dominique Astruc , J.C. Blais , L. Djakovitch et al.
NEWKOME G R. Advances in Dendritic Macromolecules, Elsevier, pp.89-127, 2002, Vol. 5
Book sections hal-00010263v1

The first organometallic dendrimers: Design and redox functions

D Astruc , Jc Blais , E Cloutet , L Djakovitch , Stéphane Rigaut et al.
Book sections hal-01475067v1

The First Organometallic Dendrimers: Design and Redox Functions

Didier Astruc , Jean-Claude Blais , Eric Cloutet , Laurent Djakovitch , Stéphane Rigaut et al.
Dendrimers II, 210, Springer Berlin Heidelberg, pp.229-259, 2000, Topics in Current Chemistry, ⟨10.1007/3-540-46577-4_5⟩
Book sections hal-02930304v1