Zakaria Halime

Publications

Article dans une revue (61)

Tailoring porphyrinic MOF-545 performances for CO 2 photocatalytic reduction through linker chlorination Amanda Lyn Robinson,Sadiya Sadiya,Sandeep Kumar,Francesc Penas-Hidalgo,Khadija Talbiet al. Dalton Transactions, 2026, 55 (8), pp.3534-3541. ⟨10.1039/d5dt02590g⟩ Article dans une revue hal-05548544v1
Cyano‐Capped Porphyrins Embedded With First‐Row Transition Metals and Evaluation for Electrocatalytic Syngas Production Inderpal Yadav,Adrien Smith,Naba Abuhafez,Zakaria Halime,Rafael Gramage‐doria ChemistrySelect, 2026, 11 (1), pp.e07497. ⟨10.1002/slct.202507497⟩ Article dans une revue hal-05449925v1
Metal-free visible-light carbonylation of alkyl iodides to amides &lt;i&gt;via&lt;/i&gt; consecutive photoinduced electron transfer Fatima Akhssas,Guillaume Chu,Meriem El Malamy,Naomi Illi,Jasmine Hertzoget al. Chemical Science, 2026, ⟨10.1039/d5sc09778a⟩ Article dans une revue hal-05448010v1
Boosting Effect of Encapsulated Polyoxometalates in the Photocatalytic CO 2 Reduction by MOF-545 Khadija Talbi,Amanda Lyn Robinson,Albert Solé-Daura,Hongmei Chen,Jérémy Delafoulhouzeet al. Applied Catalysis B: Environmental, 2025, 378, pp.125644. ⟨10.1016/j.apcatb.2025.125644⟩ Article dans une revue hal-05357908v1
Hinged Carboxylate in the Artificial Distal Pocket of an Iron Porphyrin Enhances CO2 Electroreduction at Low Overpotential Adrien Smith,Philipp Gotico,Régis Guillot,,Stéphane Le Gac,Winfried Leiblet al. Advanced Science, 2025, pp.2500482. ⟨10.1002/advs.202500482⟩ Article dans une revue hal-04919704v1
Defect‐Rich Graphdiyne Quantum Dots as Efficient Electron‐Donors for Hydrogen Generation Wahid Ullah,Amine Slassi,Cong Wang,Erwan Paineau,Minh-Huong Ha-Thiet al. Advanced Energy Materials, 2024, 14 (30), pp.2401547. ⟨10.1002/aenm.202401547⟩ Article dans une revue hal-04731743v1
Cobalt tetracationic 3,4‐pyridinoporphyrazine for direct CO 2 to methanol conversion escaping the CO intermediate pathway Chanjuan Zhang,Jorge Follana-Berna,Diana Dragoe,Zakaria Halime,Philipp Goticoet al. Angewandte Chemie International Edition, 2024, 63 (50), pp.e202411967. ⟨10.1002/anie.202411967⟩ Article dans une revue hal-05352180v1
Second Coordination Sphere Effect Shifts CO 2 to CO Reduction by Iron Porphyrin from Fe 0 to Fe I Sk Amanullah,Philipp Gotico,Marie Sircoglou,Winfried Leibl,Manuel Llansola-Portoleset al. Angewandte Chemie International Edition, 2024, 63 (4), pp.e202314439. ⟨10.1002/anie.202314439⟩ Article dans une revue hal-04441669v1
Time‐Resolved Mechanistic Depiction of Photoinduced CO 2 Reduction Catalysis on a Urea‐Modified Iron Porphyrin Daniel H Cruz Neto,Eva Pugliese,Philipp Gotico,Annamaria Quaranta,Winfried Leiblet al. Angewandte Chemie International Edition, 2024, 63 (32), ⟨10.1002/anie.202407723⟩ Article dans une revue hal-04735575v1
A Trinuclear Co(II) Complex Based on the Tris-Dioxolene Triphenylene Non-Innocent Bridge: Complementary Redox, Magnetic Behavior and Theoretical Calculations Aristide Colin,Yiting Wang,François Lambert,Nathalie Bridonneau,Nicolas Suaudet al. Magnetochemistry, 2024, 10 (12), pp.102. ⟨10.3390/magnetochemistry10120102⟩ Article dans une revue hal-05354209v1
Tracking photoinduced charge separation in a perfluorinated Zn-tetraphenylporphyrin sensitizer Daniel H Cruz Neto,Philipp Gotico,Thu-Trang Tran,Caroline Szantai,Zakaria Halimeet al. New Journal of Chemistry, 2024, 48 (34), pp.14896-14903. ⟨10.1039/d4nj02484b⟩ Article dans une revue hal-04735554v1
Efficient Hydrogen Production at pH 7 in Water with a Heterogeneous Electrocatalyst Based on a Neutral Dimeric Cobalt-Dithiolene Complex Chanjuan Zhang,Erwan Prignot,Olivier Jeannin,Antoine Vacher,Diana Dragoeet al. ACS Catalysis, 2023, 13, pp.2367-2373. ⟨10.1021/acscatal.2c04939⟩ Article dans une revue hal-03969970v1
Bio‐Inspired Bimetallic Cooperativity Through a Hydrogen Bonding Spacer in CO 2 Reduction Chanjuan Zhang,Philipp Gotico,Regis Guillot,Diana Dragoe,Winfried Leiblet al. Angewandte Chemie International Edition, 2023, 62 (8), ⟨10.1002/anie.202214665⟩ Article dans une revue hal-04231635v1
Bimetallic Molecular Catalyst Design for Carbon Dioxide Reduction Philipp Gotico,Zakaria Halime,Winfried Leibl,Ally Aukauloo ChemPlusChem, In press, 88 (8), pp.e202300222. ⟨10.1002/cplu.202300222⟩ Article dans une revue hal-04173491v1
Unlocking full and fast conversion in photocatalytic carbon dioxide reduction for applications in radio-carbonylation Serena Monticelli,Alex Talbot,Philipp Gotico,Fabien Caillé,Olivier Loreauet al. Nature Communications, 2023, 14 (1), pp.4451. ⟨10.1038/s41467-023-40136-w⟩ Article dans une revue hal-04231644v1
Divergent behavior in the chemistry of metal‐bis(dithiolene) complexes appended with peripheral aliphatic butyl chains Erwan Prignot,Chanjuan Zhang,Olivier Jeannin,Zakaria Halime,Rafael Gramage-Doriaet al. European Journal of Inorganic Chemistry, 2023, 26 (6), ⟨10.1002/ejic.202200591⟩ Article dans une revue hal-03881382v1
Photocatalytic generation of a non-heme Fe(III)-hydroperoxo species with O_2 in water for oxygen atom transfer reaction Eva Pugliese,Nhat Tam Vo,Alain Boussac,Frédéric Banse,Yasmina Mekmoucheet al. Chemical Science, 2022, 2012, ⟨10.1039/D2SC03129A⟩ Article dans une revue hal-03795563v1
Proton-controlled Action of an Imidazole as Electron Relay in a Photoredox Triad Philipp Gotico,Christian Herrero,Stefano Protti,Annamaria Quaranta,Sujitraj Shethet al. Photochemical & Photobiological Sciences , 2022, 21 (2), pp.247-259. ⟨10.1007/s43630-021-00163-2⟩ Article dans une revue hal-03865137v1
Photocatalytic hydrogen production and carbon dioxide reduction catalyzed by an artificial cobalt hemoprotein Guillermo A Oliveira Udry,Laura Tiessler-Sala,Eva Pugliese,Agathe Urvoas,Zakaria Halimeet al. International Journal of Molecular Sciences, 2022, 23 (23), pp.14640. ⟨10.3390/ijms232314640⟩ Article dans une revue hal-04231641v1
Dissection of light-induced charge accumulation at a highly active iron porphyrin: insights in the photocatalytic CO$_2$ reduction Eva Pugliese,Philipp Gotico,Iris Wehrung,Bernard Boitrel,Annamaria Quarantaet al. Angewandte Chemie International Edition, 2022, 61 (14), pp.e202117530. ⟨10.1002/anie.202117530⟩ Article dans une revue hal-03594100v1
Through‐Space Electrostatic Interactions Surpass Classical Through‐Bond Electronic Effects in Enhancing CO 2 Reduction Performance of Iron Porphyrins Asma Khadhraoui,Philipp Gotico,Winfried Leibl,Zakaria Halime,Ally Aukauloo ChemSusChem, 2021, 14 (5), pp.1308-1315. ⟨10.1002/cssc.202002718⟩ Article dans une revue hal-03279600v1
Shaping the Electrocatalytic Performance of Metal Complexes for CO2 Reduction Philipp Gotico,Winfried A Leibl,Zakaria Halime,Ally Aukauloo ChemElectroChem, In press, ⟨10.1002/celc.202100476⟩ Article dans une revue hal-03279622v1
Tracking Charge Accumulation in a Functional Triazole‐Linked Ruthenium‐Rhenium Dyad Towards Photocatalytic Carbon Dioxide Reduction Philipp Gotico,Thu‐trang Tran,Aurelie Baron,Boris Vauzeilles,Christophe Lefumeuxet al. ChemPhotoChem, In press, ⟨10.1002/cptc.202100010⟩ Article dans une revue hal-03279658v1
Imbroglio at a photoredox-iron-porphyrin catalyst dyad for the photocatalytic CO 2 reduction Adelais Trapali,Philipp Gotico,Christian Herrero,Minh-Huong Ha-Thi,Thomas Pinoet al. Comptes Rendus. Chimie, 2021, 24 (S3), pp.1-14. ⟨10.5802/crchim.104⟩ Article dans une revue hal-03423940v1
Ligand Radical Mediated Water Oxidation by a Family of Copper o -Phenylene Bis-oxamidate Complexes Samir Chattopadhyay,Arnab Ghatak,Youngju Ro,Régis Guillot,Zakaria Halimeet al. Inorganic Chemistry, 2021, 60 (13), pp.9442-9455. ⟨10.1021/acs.inorgchem.1c00546⟩ Article dans une revue hal-03279640v1
Second-sphere hydrogen-bonding enhances heterogeneous electrocatalytic CO 2 to CO reduction by iron porphyrins in water Chanjuan Zhang,Diana Dragoe,François Brisset,Bernard Boitrel,Benedikt Lassalle-Kaiseret al. Green Chemistry, 2021, 23 (22), pp.8979-8987. ⟨10.1039/D1GC02546E⟩ Article dans une revue hal-03406009v1
Recent advances in metalloporphyrin-based catalyst design towards carbon dioxide reduction: from bio-inspired second coordination sphere modifications to hierarchical architectures Philipp Gotico,Zakaria Halime,Ally Aukauloo Dalton Transactions, 2020, ⟨10.1039/c9dt04709c⟩ Article dans une revue hal-02481325v1
Cover Feature: Spectroscopic Characterisation of a Bio‐Inspired Ni‐Based Proton Reduction Catalyst Bearing a Pentadentate N 2 S 3 Ligand with Improved Photocatalytic Activity Philipp Gotico,Dooshaye Moonshiram,Cunming Liu,Xiaoyi Zhang,Régis Guillotet al. Chemistry - A European Journal, 2020, 26 (13), pp.2763-2763. ⟨10.1002/chem.202000227⟩ Article dans une revue hal-03279666v1
Atropisomeric Hydrogen Bonding Control for CO 2 Binding and Enhancement of Electrocatalytic Reduction at Iron Porphyrins Philipp Gotico,Loïc Roupnel,Regis Guillot,Marie Sircoglou,Winfried Leiblet al. Angewandte Chemie International Edition, 2020, ⟨10.1002/anie.202010859⟩ Article dans une revue hal-03016806v1
Spectroscopic Characterization of Bio-inspired Ni-based Proton Reduction Catalyst Bearing Pentadentate N2S3 Ligand with Improved Photocatalytic Activity Annamaria Quaranta,Winfried Leibl,Ally Aukauloo,Philipp Gotico,Dooshaye Moonshiramet al. Chemistry - A European Journal, 2019, ⟨10.1002/chem.201904934⟩ Article dans une revue hal-02379389v1
Second-Sphere Biomimetic Multipoint Hydrogen-Bonding Patterns to Boost CO2 Reduction of Iron Porphyrins Philipp Gotico,Bernard Boitrel,Régis Guillot,Marie Sircoglou,Annamaria Quarantaet al. Angewandte Chemie International Edition, 2019, 58 (14), pp.4504-4509. ⟨10.1002/anie.201814339⟩ Article dans une revue hal-02050269v1
A Reversible Electron Relay to Exclude Sacrificial Electron Donors in the Photocatalytic Oxygen Atom Transfer Reaction with O2 in Water Nhat Tam Vo,Yasmina Mekmouche,Thierry Tron,Régis Guillot,Frédéric Banseet al. Angewandte Chemie International Edition, 2019, ⟨10.1002/anie.201907337⟩ Article dans une revue hal-02301619v1
Time-resolved X-ray absorption spectroelectrochemistry of redox active species in solution Khaled Cheaib,Baptiste Maurice,Tiphaine Mateo,Zakaria Halime,Benedikt Lassalle-Kaiser Journal of Synchrotron Radiation, 2019, 26 (6), pp.1980-1985. ⟨10.1107/S1600577519013614⟩ Article dans une revue hal-02385904v1
Design and Synthesis of Hybrid PEGylated Metal Monopicolinate Cyclam Ligands for Biomedical Applications Fatima Aouidat,Zakaria Halime,Rosalba Moretta,Ilaria Rea,Stefania Filosaet al. ACS Omega, 2019, 4 (2), pp.2500-2509. ⟨10.1021/acsomega.8b03266⟩ Article dans une revue hal-02337561v1
Electronic and spin delocalization in a switchable trinuclear triphenylene trisemiquinone bridged Ni3 complex Yiting Wang,François Lambert,Eric Rivière,Régis Guillot,Christian Herreroet al. Chemical Communications, 2019, 55 (82), pp.12336-12339. ⟨10.1039/C9CC05183J⟩ Article dans une revue hal-02322279v1
Visible-Light-Driven Reduction of CO2 to CO and Its Subsequent Valorization in Carbonylation Chemistry and 13C Isotope Labeling Philipp Gotico,Antonio Vecchio,Davide Audisio,Annamaria Quaranta,Zakaria Halimeet al. ChemPhotoChem, 2018, 2 (8), pp.715-719. ⟨10.1002/cptc.201800012⟩ Article dans une revue cea-02503934v1
Local ionic liquid environment at a modified iron porphyrin catalyst enhances the electrocatalytic performance of CO2 to CO reduction in water Asma Khadhraoui,Philipp Gotico,Bernard Boitrel,Winfried Leibl,Zakaria Halimeet al. Chemical Communications, 2018, 54 (82), pp.11630-11633. ⟨10.1039/c8cc06475j⟩ Article dans une revue hal-01935369v1
Comparison of Immuno-PET of CD138 and PET imaging with 64CuCl2 and 18F-FDG in a preclinical syngeneic model of multiple myeloma Clément Bailly,Sébastien Gouard,Marie Lacombe,Patricia Remaud-Le Saëc,Benjamin Chalopinet al. Oncotarget, 2018, 9, pp.9061-9072. ⟨10.18632/oncotarget.23886⟩ Article dans une revue hal-01677118v1
Water Molecules Gating a Photoinduced One Electron Two Protons Transfer in a Tyr/His model of Photosystem II Georgios Chararalambidis,Syamal Das,Adelais Trapali,Annamaria Quaranta,Maylis Orioet al. Angewandte Chemie International Edition, 2018, ⟨10.1002/anie.201804498⟩ Article dans une revue hal-02176998v1
Light-Induced Activation of the Du Bois [Rh ^\textrmII _\textrm2 (Esp) _\textrm2 ] Catalyst for Nitrogen Atom Transfer Reactions Rajaa Farran,Clémence Ducloiset,Julien Buendia,Nhat Tam Vo,Régis Guillotet al. ChemPhotoChem, 2017, 1 (12), pp.562--567. ⟨10.1002/cptc.201700138⟩ Article dans une revue hal-02281873v1
Correction: New synthesis of phenyl-isothiocyanate C-functionalised cyclams. Bioconjugation and 64Cu phenotypic PET imaging studies of multiple myeloma with the te2a derivative Zakaria Halime,M. Frindel,N. Camus,Pierre Yves Orain,M. Lacombeet al. Organic & Biomolecular Chemistry, 2016, 14 (15), pp.3838. ⟨10.1039/c6ob90046a⟩ Article dans une revue hal-01770457v1
Cyclams with Ambidentate Methylthiazolyl Pendants for Stable, Inert, and Selective Cu(II) Coordination Aurora Rodríguez-Rodríguez,Zakaria Halime,Luís M. P. Lima,Maryline Beyler,David Deniaudet al. Inorganic Chemistry, 2016, 55 (2), pp.619-632. ⟨10.1021/acs.inorgchem.5b01779⟩ Article dans une revue hal-01517782v1
New synthesis of phenyl-isothiocyanate C-functionalised cyclams. Bioconjugation and 64 Cu phenotypic PET imaging studies of multiple myeloma with the te2a derivative † Zakaria Halime,Mathieu Frindel,Nathalie Camus,Pierre-Yves Orain,Marie Lacombeet al. Organic & Biomolecular Chemistry, 2015, 13 (46), pp.11302-14. ⟨10.1039/c5ob01618e⟩ Article dans une revue inserm-02418040v1
A [two-step/one week] synthesis of C-functionalized homocyclens and cyclams. Application to the preparation of conjugable BCAs without chelating properties alteration Nathalie Camus,Zakaria Halime,Nathalie Le Bris,Hélène Bernard,Maryline Beyleret al. RSC Advances, 2015, 5 (104), pp.85898 - 85910. ⟨10.1039/c5ra17133d⟩ Article dans une revue hal-01517785v1
Full Control of the Regiospecific N -Functionalization of C -Functionalized Cyclam Bisaminal Derivatives and Application to the Synthesis of their TETA, TE2A, and CB-TE2A Analogues Nathalie Le Bris,Nathalie Camus,Zakaria Halime,Hélène Bernard,Carlos Platas-Iglesiaset al. Journal of Organic Chemistry, 2014, 79 (5), pp.1885 - 1899. ⟨10.1021/jo4028566⟩ Article dans une revue hal-01629496v1
Monopicolinate Cross-Bridged Cyclam Combining Very Fast Complexation with Very High Stability and Inertness of Its Copper(II) Complex Luís M. P. Lima,Zakaria Halime,Ronan Marion,Nathalie Camus,Rita Delgadoet al. Inorganic Chemistry, 2014, 53 (10), pp.5269 - 5279. ⟨10.1021/ic500491c⟩ Article dans une revue hal-01535878v1
Functionalization of porphyrins: towards the synthesis of bifunctional chelates for bismuth coordination Zakaria Halime,Sébastien Balieu,Btissam Najjari,Mohammed Lachkar,Thierry Roisnelet al. Journal of Porphyrins and Phthalocyanines, 2010, 14 (5), pp.412-420. ⟨10.1142/S1088424610002215⟩ Article dans une revue hal-00738771v1
The coordination of bismuth by porphyrins Bernard Boitrel,Zakaria Halime,Sébastien Balieu,Mohammed Lachkar Comptes Rendus. Chimie, 2009, 10 (7), pp.583 - 589. ⟨10.1016/j.crci.2006.09.016⟩ Article dans une revue istex hal-01470248v1
Coordination of bismuth and lead in porphyrins: Towards an in-situ generator for α-radiotherapy? Zakaria Halime,Mohammed Lachkar,Bernard Boitrel Biochimie, 2009, 91 (10), pp.1318 - 1320. ⟨10.1016/j.biochi.2009.03.001⟩ Article dans une revue istex hal-01470245v1
Bismuth insertion in functionalized porphyrins: influence of the structure delivering substituted malonic acid groups Sébastien Balieu,Zakaria Halime,Mohammed Lachkar,Bernard Boitrel J. Porphyrins Phthalocyanines, 2008, 12, pp.1223-1231 Article dans une revue hal-00357084v1
Structural and Coordination Studies of “Pearl Oyster-like” Porphyrins Zakaria Halime,Mohammed Lachkar,Thierry Roisnel,Philippe Richard,Bernard Boitrel Inorganic Chemistry, 2007, 46 (16), pp.6338-6346 Article dans une revue hal-00357123v1
Coordination and structural studies of crowned-porphyrins Zakaria Halime,Mohammed Lachkar,Loic Toupet,Athanassios G. Coutsolelos,Bernard Boitrel Dalton Transactions, 2007, pp.3684-3689 Article dans une revue hal-00357115v1
Bismuth and lead hanging-carboxylate porphyrins: Unprecedented homobimetallic lead(II) complex Zakaria Halime,Mohammed Lachkar,Thierry Roisnel,Eric Furet,Jean-François Haletet al. Angewandte Chemie International Edition, 2007, 46, pp.5120-5124 Article dans une revue hal-00357111v1
Bismuth and lead hanging-carboxylate porphyrins: an unexpected homobimetallic lead(II) complex. Zakaria Halime,Mohammed Lachkar,Thierry Roisnel,Eric Furet,Jean-François Haletet al. Angewandte Chemie International Edition, 2007, 46 (27), pp.5120-4. ⟨10.1002/anie.200700543⟩ Article dans une revue istex hal-00354917v1
Linear and pre-organized carboxylic acid picket porphyrins as bismuth chelators. Zakaria Halime,Mohammed Lachkar,Eric Furet,Jean-François Halet,Bernard Boitrel Inorganic Chemistry, 2006, 45 (26), pp.10661-9. ⟨10.1021/ic061422y⟩ Article dans une revue istex hal-00862721v1
Functionalization of Porphyrins: Mechanistic Insights, Conformational Studies, and Structural Characterizations Zakaria Halime,Sébastien Balieu,Mohammed Lachkar,Thierry Roisnel,Philippe Richardet al. European Journal of Organic Chemistry, 2006, 2006 (5), pp.1207 - 1215. ⟨10.1002/ejoc.200500685⟩ Article dans une revue istex hal-01470273v1
Novel crowned-porphyrin ligands. Synthesis and conformational studies Zakaria Halime,Mohammed Lachkar,Niki Matsouki,Georgios Charalambidis,Massimo Di Vairaet al. Tetrahedron, 2006, 62 (13), pp.3056 - 3064. ⟨10.1016/j.tet.2006.01.029⟩ Article dans une revue istex hal-01470269v1
Pre-shaped Aromatic Picket Porphyrins Bearing Neutral Oxygen Donors and Their Bismuth Complexes: Synthesis and Coordination Studies Bernard Boitrel,Lydie Michaudet,Zakaria Halime,Mohammed Lachkar Letters in Organic Chemistry, 2006, 3 (10), pp.753-758. ⟨10.2174/157017806779025906⟩ Article dans une revue istex hal-01470264v1
Influence of Pendant Arms Bearing Ligating Groups on the Structure of Bismuth Porphyrins: Implications for Labeling Immunoglobulins Used in Medical Applications Zakaria Halime,Lydie Michaudet,Mohammed Lachkar,Pierre Brossier,Bernard Boitrel Bioconjugate Chemistry, 2004, 15 (6), pp.1193 - 1200. ⟨10.1021/bc049844o⟩ Article dans une revue istex hal-01469287v1
Structural characterisation of the first mononuclear bismuth porphyrin Bernard Boitrel,Zakaria Halime,Lydie Michaudet,Mohamed Lachkar,Loic Toupet Chemical Communications, 2003, 21, pp.2670-2671. ⟨10.1039/b309615g⟩ Article dans une revue istex hal-01469410v1
Synthesis, characterisation and properties of bismuth( iii ) ester pendant arm picket porphyrins Zakaria Halime,Lydie Michaudet,Mathieu Razavet,Christian Ruzié,Bernard Boitrel Dalton Transactions, 2003, 22, pp.4250 - 4254. ⟨10.1039/b308776j⟩ Article dans une revue istex hal-01469361v1

Communication dans un congrès (1)

Photocatalytic reduction by molecular systems combining Porphyrins and N-Heterocyclic Carbene-Metal complexes Asmae Bousfiha,Ludivine Poyac,Philipp Gotico,Charles Devillers,Zakaria Halimeet al. Meeting Club I2BC Transverse Axis 4, Oct 2023, Gif sur Yvette, France Communication dans un congrès hal-04762857v1

Poster de conférence (2)

Urea functionalized second coordination sphere on iron porphyrin catalyst for CO2 reduction under aprotic and protic conditions Ashutosh Vishwakarma,Philipp Gotico,Zakaria Halime JED 2025 - Journée de l'Ecole Doctorale 2MIB, Jun 2025, gif-sur-yvette, France. Poster de conférence hal-05523904v1
Development of porphyrin-based photocathodes for CO2 reduction Sana Fatima,Philipp Gotico,Zakaria Halime 9ièmes Journées Nationales des Carburants Solaires, Jul 2025, Strasbourg, France Poster de conférence hal-05493257v1

Brevet (1)

Picolinate cross-bridged cyclam, chelate with metallic cations and use thereof Raphaël Tripier,Zakaria Halime France, Patent n° : WO2015071334 -2015-05-21. 2015 Brevet hal-01620527v1