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Alexandre CHAGNES

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*Directeur des Partenariats Industriels (*[*http://ensg.univ-lorraine.fr*](http://ensg.univ-lorraine.fr/)*)* *Directeur Scientifique du Labex Ressources21 (*[*http://ressources21.univ-lorraine.fr*](http://ressources21.univ-lorraine.fr/)*)* École Nationale Supérieure de Géologie (ENSG) - Géoressources (UMR CNRS 7359) 2 rue du Doyen Marcel Roubault - BP 10162 - 54505 Vandoeuvre-les Nancy Cedex (France) *Google Scholar :* [*https://scholar.google.fr/citations?user=YEgejnQAAAAJ&hl=fr*](https://scholar.google.fr/citations?user=YEgejnQAAAAJ&hl=fr) *Research Gate :* [*http://www.researchgate.net/profile/Alexandre\_Chagnes2*](http://www.researchgate.net/profile/Alexandre_Chagnes2) **ACTIVITES DE RECHERCHE** Procédés hydrométallurgiques, chimie des solutions, thermodynamique, électrochimie, batteries Li-ion. **123** articles dans des journaux à comité de lecture dont **18** articles dans des actes de congrès à comité de lecture, **6** livres, **8** chapitres de livre, **135** conférences dont **59** conférences invitées, **41** présentations par affiches, **2** brevets. **ENSEIGNEMENT** Thermodynamique, électrochimie, chimie des solutions, physicochimie des procédés hydrométallurgiques. **DIPLOMES-FORMATION** HDR Université d’Orsay, 24 Septembre 2012. *La physicochimie au service des ressources et de l’énergie.* Doctorat Université de Tours, France (chimie-physique), 16 Septembre 2002. *Etude thermodynamique et électrochimique d’électrolytes organiques pour les batteries lithium-ion*. **EMPLOIS** **2016-…** **Professeur des Universités**, École Nationale Supérieure de Géologie (Université de Lorraine) – **titulaire de la Prime d’Encadrement Doctorale** (PEDR) depuis Septembre 2014. *Procédés hydrométallurgiques* **2005-2016** **Maître de Conférences**, Chimie ParisTech, Ecole Nationale Supérieure de Chimie Paris (France). *- Métallurgie extractive : Procédés de purification par voie hydrométallurgique.* *- Batteries lithium-ion : Electrolytes et interface électrode/électrolyte.* **2004-2005** **Chercheur post-doctoral**, Commissariat à l’Energie Atomique, Saclay (France). *Chimie des solutions dans les réacteurs à eau pressurisée.* **2003-2004** **Attaché Temporaire d’Enseignement et de Recherche**, Laboratoire de Physicochimie des Interfaces et des Milieux Réactionnels, Université de Tours (France). *Electrochimie et thermodynamique des liquides ioniques à basse température.* **2002-2003** **Chercheur postdoctoral**, Centre de Recherche en Electrochimie et Electrocatalyse, Université de Sherbrooke (Québec, Canada). *Matériaux pour l’électrocatalyse.* **1999-2002** **Doctorant**,Laboratoire de Physicochimie des Interfaces et des Milieux Réactionnels, Université de Tours (France). *Electrochimie et chimie des solutions pour les batteries lithium-ion.*

Publications

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Boron extraction by aliphatic mono- and di-hydroxy alcohols from a representative continental brine

Abdoul Fattah Kiemde , Jérôme Marin , Victoria Flexer , Alexandre Chagnes
Hydrometallurgy, 2024, 225, pp.106280. ⟨10.1016/j.hydromet.2024.106280⟩
Journal articles hal-04454089v1
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Liquid–liquid extraction of boron from continental brines by 2-butyl-1-octanol diluted in kerosene

Abdoul Fattah Kiemde , Jérôme Marin , Victoria Flexer , Alexandre Chagnes
RSC Advances, 2024, 14 (4), pp.2170-2181. ⟨10.1039/d3ra08045e⟩
Journal articles hal-04384752v1

Environmental impact of direct lithium extraction from brines

María Vera , Walter Torres , Claudia Galli , Alexandre Chagnes , Victoria Flexer
Nature Reviews Earth & Environment, 2023, 4 (3), pp.149-165. ⟨10.1038/s43017-022-00387-5⟩
Journal articles hal-04176847v1

Recent Advances in the Chemistry of Hydrometallurgical Methods

Gauthier J.-P. Deblonde , Alexandre Chagnes , Gérard Cote
Separation and Purification Reviews, 2023, 52 (3), pp.221-241. ⟨10.1080/15422119.2022.2088389⟩
Journal articles hal-04176858v1
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Low-carbon footprint diluents in solvent extraction for lithium-ion battery recycling

Aboudaye M Ahamed , Benjamin Swoboda , Zubin Arora , Jean Yves Lansot , Alexandre Chagnes
RSC Advances, 2023, 13 (33), pp.23334-23345. ⟨10.1039/d3ra04679f⟩
Journal articles hal-04176832v1
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Novel extraction route of lithium from α-spodumene by dry chlorination

Allen Yushark Fosu , Ndue Kanari , Danièle Bartier , James Vaughan , Alexandre Chagnes
RSC Advances, 2022, 12 (33), pp.21468-21481. ⟨10.1039/d2ra03233c⟩
Journal articles hal-03744476v1
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Lithium-Ion Battery Recycling: Metal Recovery from Electrolyte and Cathode Materials by Electrodialysis

Soumaya Gmar , Laurence Muhr , Florence Lutin , Alexandre Chagnes
Metals, 2022, 12 (11), pp.1859. ⟨10.3390/met12111859⟩
Journal articles hal-03834984v1
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Conditioning of poultry manure ash for subsequent phosphorous separation and assessment for a process design

Rodolfomarin Rivera , Alexandre Chagnes , Michel Cathelineau , Marie-Christine Boiron
Sustainable Materials and Technologies, 2022, 31, pp.e00377. ⟨10.1016/j.susmat.2021.e00377⟩
Journal articles hal-03489461v1
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Antisolvent Precipitation for Metal Recovery from Citric Acid Solution in Recycling of NMC Cathode Materials

Wen Xuan , Alexandre Chagnes , Xiong Xiao , Richard Olsson , Kerstin Forsberg
Metals, 2022, 12 (4), pp.607. ⟨10.3390/met12040607⟩
Journal articles hal-03627309v1
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Application of Electrodialysis for the Selective Lithium Extraction towards Cobalt, Nickel and Manganese from Leach Solutions Containing High Divalent Cations/Li Ratio

Soumaya Gmar , Alexandre Chagnes , Florence Lutin , Laurence Muhr
Construction & Demolition Recycling, 2022, 7, ⟨10.3390/recycling7020014⟩
Journal articles hal-03594578v1
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New insights for titanium(iv) speciation in acidic media based on UV-visible and 31P NMR spectroscopies and molecular modeling

Lucas Mangold , Hubert Halleux , Sébastien Leclerc , Aurélien Moncomble , Gérard Cote
RSC Advances, 2021, 11 (43), pp.27059 - 27073. ⟨10.1039/d1ra04284j⟩
Journal articles hal-03324044v1
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New insights in the leaching kinetics of cathodic materials in acidic chloride media for lithium-ion battery recycling

Wen Xuan , Antônio de Souza Braga , Chloé Korbel , Alexandre Chagnes
Hydrometallurgy, 2021, 204, pp.105705. ⟨10.1016/j.hydromet.2021.105705⟩
Journal articles hal-03297024v1
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The Future of Scandium Recovery from Wastes

Olga Chernoburova , Alexandre Chagnes
Materials Proceedings, 2021, 5 (1), pp.55. ⟨10.3390/materproc2021005055⟩
Journal articles hal-03465544v1
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Physico-Chemical Characteristics of Spodumene Concentrate and Its Thermal Transformations

Allen Yushark Fosu , Ndue Kanari , Danièle Bartier , Harrison Hodge , James Vaughan
Materials, 2021, 14 (23), pp.7423. ⟨10.3390/ma14237423⟩
Journal articles hal-03465518v1

Development of a Novel Solvent Extraction Process to Recover Cobalt, Nickel, Manganese, and Lithium from Cathodic Materials of Spent Lithium-Ion Batteries

Wen Xuan , Antônio de Souza Braga , Alexandre Chagnes
ACS Sustainable Chemistry & Engineering, 2021, 10 (1), pp.582-593. ⟨10.1021/acssuschemeng.1c07109⟩
Journal articles insu-04470982v1
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Effect of the Addition of Amine in Organophosphorus Compounds on Molecular Structuration of Ionic Liquids–Application to Solvent Extraction

Soumaya Gmar , Fabrice Mutelet , Alexandre Chagnes
Molecules, 2020, 25 (11), pp.2584. ⟨10.3390/molecules25112584⟩
Journal articles hal-02922253v1
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Literature Review and Thermodynamic Modelling of Roasting Processes for Lithium Extraction from Spodumene

Allen Yushark Fosu , Ndue Kanari , James Vaughan , Alexandre Chagnes
Metals, 2020, 10 (10), pp.1312. ⟨10.3390/met10101312⟩
Journal articles hal-02953994v1
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Recovery of Metal Values from Ni-Cd Cake Waste Residue of an Iranian Zinc Plant by Hydrometallurgical Route

Sushanta Kumar , Maryam Kargar Razi , Mathieu Beuscher , Alexandre Chagnes
Metals, 2020, 10 (5), ⟨10.3390/met10050655⟩
Journal articles hal-02922251v1
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Recovery of metals in a double-stage continuous bioreactor for acidic bioleaching of printed circuit boards (PCBs)

Agathe Hubau , Michel Minier , Alexandre Chagnes , Catherine Joulian , Charline Silvente
Separation and Purification Technology, 2020, 238, pp.116481. ⟨10.1016/j.seppur.2019.116481⟩
Journal articles hal-02431903v1
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Sulfone Based-Electrolytes for Lithium-Ion Batteries: Cycling Performances and Passivation Layer Quality of Graphite and LiNi 1/3 Mn 1/3 Co 1/3 O 2 Electrodes

Benjamin Flamme , Jolanta Światowska , Mansour Haddad , Phannarath Phansavath , Virginie Ratovelomanana-Vidal
Journal of The Electrochemical Society, 2020, 167 (7), pp.070508. ⟨10.1149/1945-7111/ab63c3⟩
Journal articles hal-02436737v1
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Simulation of Solvent Extraction Flowsheets by a Global Model Combining Physicochemical and Engineering Approaches-Application to Cobalt(II) Extraction by D2EHPA

Alexandre Chagnes
Solvent Extraction and Ion Exchange, 2020, 38 (1), pp.3-13. ⟨10.1080/07366299.2019.1691135⟩
Journal articles hal-02424027v2
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Sulfone Based-Electrolytes for Lithium-Ion Batteries: Cycling Performances and Passivation Layer Quality of Graphite and LiNi 1/3 Mn 1/3 Co 1/3 O 2 Electrodes

Benjamin Flamme , Jolanta Swiatowska , Mansour Haddad , Phannarath Phansavath , Virginie Ratovelomanana-Vidal
Journal of The Electrochemical Society, 2020
Journal articles hal-03009869v1
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Investigation of the leaching mechanism of NMC 811 (LiNi 0.8 Mn 0.1 Co 0.1 O 2 ) by hydrochloric acid for recycling lithium ion battery cathodes

Wen Xuan , Akira Otsuki , Alexandre Chagnes
RSC Advances, 2019, ⟨10.1039/c9ra06686a⟩
Journal articles hal-02383642v1
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Advances in Hydrometallurgy

Alexandre Chagnes
Metals, 2019, 9 (2), pp.211. ⟨10.3390/met9020211⟩
Journal articles hal-02182967v1
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Recycling-oriented methodology to sample and characterize the metal composition of waste Printed Circuit Boards

Agathe Hubau , Alexandre Chagnes , Michel Minier , Solène Touzé , Simon Chapron
Waste Management, 2019, 91, pp.62-71. ⟨10.1016/j.wasman.2019.04.041⟩
Journal articles hal-02182965v1
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A fluoride-free liquid-liquid extraction process for the recovery and separation of niobium and tantalum from alkaline leach solutions

Gauthier J.-P. Deblonde , David Bengio , Denis Beltrami , Sarah Bélair , Gérard Cote
Separation and Purification Technology, 2019, 215, pp.634-643. ⟨10.1016/j.seppur.2019.01.052⟩
Journal articles hal-02182966v1
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Niobium and tantalum processing in oxalic-nitric media: Nb2O5·nH2O and Ta2O5·nH2O precipitation with oxalates and nitrates recycling

Gauthier J.-P. Deblonde , David Bengio , Denis Beltrami , Sarah Bélair , Gérard Cote
Separation and Purification Technology, 2019, 226, pp.209-217. ⟨10.1016/j.seppur.2019.05.087⟩
Journal articles hal-02182964v1

Les sels de lithium, à la base du stockage d'électricité

Alexandre Chagnes
Géosciences, 2018, Le sel, "aux confins de la terre et de l'eau", 22, pp.72
Journal articles hal-02265130v1
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Investigation of aggregation and acid dissociation of new cationic exchangers for liquid-liquid extraction

Kateryna Omelchuk , Moncef Stambouli , Alexandre Chagnes
Journal of Molecular Liquids, 2018, 262, pp.111-118. ⟨10.1016/j.molliq.2018.04.082⟩
Journal articles hal-01813755v1
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Continuous production of a biogenic ferric iron lixiviant for the bioleaching of printed circuit boards (PCBs)

Agathe Hubau , Michel Minier , Alexandre Chagnes , Catherine Joulian , Cédric Perez
Hydrometallurgy, 2018, 180, pp.180-191. ⟨10.1016/j.hydromet.2018.07.001⟩
Journal articles hal-02182968v1
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Anodic Stability of New Sulfone-Based Electrolytes for Lithium-Ion Batteries

Benjamin Flamme , Mansour Haddad , Phannarath Phansavath , Virginie Ratovelomanana-Vidal , Alexandre Chagnes
ChemElectroChem, 2018, 5 (16), pp.2279-2287. ⟨10.1002/celc.201701343⟩
Journal articles hal-02182970v1
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Chemical Degradation of a Mixture of tri-n-Octylamine and 1-Tridecanol in the Presence of Chromium(VI) in Acidic Sulfate Media

Alexandre Chagnes , Gérard Cote
Metals, 2018, 8 (1), pp.57. ⟨10.3390/met8010057⟩
Journal articles hal-02182973v1
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Characterization of palladium species after γ-irradiation of a TBP–alkane–Pd(NO 3 ) 2 system

Bénédicte Simon , Christine Bouyer , Stéphanie de Sio , Claude Berthon , Nathalie Boubals
RSC Advances, 2018, 8 (38), pp.21513-21527. ⟨10.1039/C8RA02695E⟩
Journal articles hal-02182974v1
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New cationic exchangers for the recovery of cobalt(II), nickel(II) and manganese(II) from acidic chloride solutions: Modelling of extraction curves

Kateryna Omelchuk , Alexandre Chagnes
Hydrometallurgy, 2018, 180, pp.96-103. ⟨10.1016/j.hydromet.2018.07.003⟩
Journal articles hal-02182969v1
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A review on clogging of recirculating steam generators in Pressurized-Water Reactors

Guangze Yang , Véronique Pointeau , Etienne Tevissen , Alexandre Chagnes
Progress in Nuclear Energy, 2017, 97, pp.182-196. ⟨10.1016/j.pnucene.2017.01.010⟩
Journal articles cea-02388689v1

Multinuclear Solid-State NMR Investigation of Hexaniobate and Hexatantalate Compounds

Gauthier J.-P. Deblonde , Cristina Coelho-Diogo , Alexandre Chagnes , Gérard Cote , Mark E. Smith
Inorganic Chemistry, 2016, 55 (12), pp.5946 - 5956. ⟨10.1021/acs.inorgchem.6b00345⟩
Journal articles hal-01429965v1

Physicochemical properties of novel cholinium ionic liquids for the recovery of silver from nitrate media

Rafael M. Rios-Vera , Juliette Sirieix-Plénet , Laurent Gaillon , Cécile Rizzi , Mario Ávila-Rodríguez
RSC Advances, 2015, 5 (95), pp.78268 - 78277. ⟨10.1039/c5ra14101j⟩
Journal articles hal-01519102v1

Investigation of the speciation of uranium(VI) in concentrated phosphoric acid and in synergistic extraction systems by time-resolved laser-induced fluorescence spectroscopy (TRLFS)

Denis Beltrami , Florence F. Mercier-Bion , Gérard Cote , Hamid Mokhtari , Bruno Courtaud
Journal of Molecular Liquids, 2014, 190, pp.42-49. ⟨10.1016/j.molliq.2013.10.013⟩
Journal articles hal-01157709v1
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Interphase chemistry of Si electrodes used as anodes in Li-ion batteries

Catarina Pereira-Nabais , Jolanta Swiatowska , Alexandre Chagnes , Francois Ozanam , Aurelien Gohier
Applied Surface Science, 2013, 266, pp.5-16. ⟨10.1016/j.apsusc.2012.10.165⟩
Journal articles hal-00793814v1

IR Fingerprints of U(VI) Nitrate Monoamides Complexes: A Joint Experimental and Theoretical Study

Antonio Prestianni , Laurent Joubert , Alexandre Chagnes , Gerard Cote , Marie-Noelle Ohnet
Journal of Physical Chemistry A, 2010, 114 (40), pp.10878-10884. ⟨10.1021/JP106467P⟩
Journal articles cea-03095730v1
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The speciation of titanium(IV) in concentrated phosphoric acid : A spectroscopical and TD-DFT study.

Lucas Mangold , Hubert Halleux , Aurélien Moncomble , Gérard Cote , Alexandre Chagnes
IUPAC CCCE 2021, Aug 2021, Ottawa (virtual), Canada
Conference papers hal-03418105v1
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Metal recovery from printed circuit boards (PCBs) by acidophilic bioleaching

Agathe Hubau , Alexandre Chagnes , Michel Minier , Anne-Gwenaelle Guezennec
International Biohydrometallurgy Symposium - IBS 2019, Oct 2019, Fukuoka, Japan
Conference papers hal-02274137v1
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Recent Advances in Hydrometallurgy for the Development of a Sustainable Production of Lithium-Ion Batteries

Alexandre Chagnes
ALTA 2019 - Lithium processing conference, May 2019, Perth, Australia
Conference papers hal-02270375v1
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Liquid-Liquid Extraction of Cobalt(II), Nickel(II) and Manganese(II) from Acidic Chloride Media

Alexandre Chagnes , Kateryna Omelchuk
Extraction 2018: Proceedings of the First Global Conference on Extractive Metallurgy, Aug 2018, Ottawa, Canada
Conference papers hal-02270376v1
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Diphasic acid-basic properties of new organophosphorus extractants

Kateryna Omelchuk , Moncef Stambouli , Alexandre Chagnes
The 21st International Solvent Exctraction Conference - ISEC 2017, Nov 2017, Miyazaki, Japan
Conference papers hal-01814007v1

Ressources minérales et transitions

Michel Cathelineau , Alexandre Chagnes
Chailleux, S., Le Berre S. et Gunzburger Y. (dir.), Ressources minérales et transitions », Trajectoires politiques du sous-sol français au 21ème siècle. Peter Lang Ed., Bruxelles, Ecopolis, N°38 ., Peter Lang Verlag, 2022, ⟨10.3726/b19795⟩
Book sections hal-04273067v1
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LabEx RESSOURCES21, strategic metals of the XXIst century

Alexandre Chagnes , Michel Cathelineau , Frédéric Villiéras , Olga Chernoburova , Isabelle Abildtrup
Activity report N° 8, Université de lorraine; CNRS; INRAE; ANR (Agence Nationale de la Recherche - France). 2023
Reports hal-04122069v1
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PROPRIÉTÉS DE TRANSPORT DANS LES ÉLECTROLYTES CONCENTRÉS À BASE DE γ-BUTYROLACTONE. APPLICATION AUX ACCUMULATEURS RECHARGEABLES AU LITHIUM.

Alexandre Chagnes
Autre. Université François Rabelais - Tours; Ecole nationale superieure agronomique de montpellier - AGRO M, 2002. Français. ⟨NNT : ⟩
Theses tel-00009718v1
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La physicochimie au service des Ressources et de l'Energie

Alexandre Chagnes
Chimie théorique et/ou physique. Université d'Orsay, 2012
Habilitation à diriger des recherches tel-02265239v1