Bastien Michelet

41
Documents

Publications

Publications

Deposit thumbnail

Regulating the Acidity of HF/Pyridine Media to Control the Chemodivergent Fluoro- and Hydro-Heteroalkylation of Olefins

Mélissa Longuet , Fabien Naullet , Alexandre Pérochon , Agnès Martin-Mingot , Frédéric Guégan et al.

Journal of the American Chemical Society, 2025, 147 (32), pp.29079-29087. ⟨10.1021/jacs.5c07526⟩

Article dans une revue hal-05221813v1
Deposit thumbnail

Benzophenone-Based Phenylogous Peptide Linkage via Friedel–Crafts Acylation

Hao Wu , Yuko Otani , Ying Zhou , Bastien Michelet , Sebastien Thibaudeau et al.

Organic Letters, In press, ⟨10.1021/acs.orglett.5c03833⟩

Article dans une revue hal-05321949v1
Deposit thumbnail

Activation of N-containing olefins and alkynes with superacids

Delphine Pichon-Barré , Hélène Carreyre , Frédéric Lecornué , Agnès Martin-Mingot , Bastien Michelet et al.

Comptes Rendus. Chimie, 2025, 28, pp.727-754. ⟨10.5802/crchim.416⟩

Article dans une revue (compte-rendu de lecture) hal-05321953v1
Deposit thumbnail

Determination of the Hammett Acidity of HF/Base Reagents

Mélissa Longuet , Kassandra Vitse , Agnès Martin-Mingot , Bastien Michelet , Frédéric Guégan et al.

Journal of the American Chemical Society, 2024, ⟨10.1021/jacs.4c02344⟩

Article dans une revue (article de synthèse) hal-04552304v1

Glycosylium Ions in Superacid Mimic the Transition State of Enzyme Reactions

Mathilde Armand , Alba Nin-Hill , Ana Ardá , Emanuela Berrino , Jérôme Désiré et al.

Journal of the American Chemical Society, 2024, 146 (47), pp.32618-32626. ⟨10.1021/jacs.4c11677⟩

Article dans une revue hal-05326476v1
Deposit thumbnail

Leveraging long-lived arenium ions in superacid for meta-selective methylation

Paul Bourbon , Kassandra Vitse , Agnès Martin-Mingot , Hugo Geindre , Frédéric Guégan et al.

Nature Communications, 2024, 15 (1), pp.7435. ⟨10.1038/s41467-024-49421-8⟩

Article dans une revue hal-04680872v1
Deposit thumbnail

Glycosylium Ions in Superacid Mimic the Transition State of Enzyme Reactions

Mathilde Armand , Alba Nin-Hill , Ana Ardá , Emanuela Berrino , Jérôme Désiré et al.

Journal of the American Chemical Society, 2024, 146 (47), pp.32618-32626. ⟨10.1021/jacs.4c11677⟩

Article dans une revue hal-05176253v1
Deposit thumbnail

Superacid-Synthesized Fluorinated Diamines Act as Selective hCA IV Inhibitors

Emanuela Berrino , Bastien Michelet , Kassandra Vitse , Alessio Nocentini , Gianluca Bartolucci et al.

Journal of Medicinal Chemistry, 2024, ⟨10.1021/acs.jmedchem.4c01795⟩

Article dans une revue hal-04753033v1
Deposit thumbnail

Enantioselective Organocatalysis and Superacid Activation: Challenges and Opportunities

Bastien Michelet , Agnès Martin-Mingot , Jean Rodriguez , Sébastien Thibaudeau , Damien Bonne

Chemistry - A European Journal, 2023, 29 (35), pp.e202300440. ⟨10.1002/chem.202300440⟩

Article dans une revue hal-04047011v1
Deposit thumbnail

Exploring F/CF3 substituted oxocarbenium ions for the diastereoselective assembly of highly substituted tetrahydrofurans

Anthony J Fernandes , Bastien Michelet , Armen Panossian , Agnès Martin-Mingot , Frédéric R Leroux et al.

Chemical Communications, 2023, 59 (27), pp.4083-4086. ⟨10.1039/d2cc06521e⟩

Article dans une revue hal-04046996v1
Deposit thumbnail

Exploring Superacid‐Promoted Skeletal Reorganization of Aliphatic Nitrogen‐Containing Compounds

Maxime Artault , Thomas Cantin , Mélissa Longuet , Kassandra Vitse , Christ Daniel Matatu Mbengo et al.

Angewandte Chemie International Edition, 2023, 63 (1), pp.e202316458. ⟨10.1002/anie.202316458⟩

Article dans une revue hal-04520297v1
Deposit thumbnail

Hidden Heptacyclic Chiral N-Acyl Iminium Ions: a New Entry to Enantioenriched Polycyclic Azepanes and Azocanes by Superacid-Promoted Intramolecular Pictet-Spengler Reaction

Yasmin Reviriot , Bastien Michelet , Rodolphe Beaud , Agnès Martin-Mingot , Frédéric Guégan et al.

Chemistry - A European Journal, 2022, 28 (25), pp.e202200432. ⟨10.1002/chem.202200432⟩

Article dans une revue hal-03769652v1

A general synthesis of azetidines by copper-catalysed photoinduced anti-Baldwin radical cyclization of ynamides

Clément Jacob , Hajar Baguia , Amaury Dubart , Samuel Oger , Pierre Thilmany et al.

Nature Communications, 2022, 13 (1), pp.560. ⟨10.1038/s41467-022-28098-x⟩

Article dans une revue hal-03798007v1
Deposit thumbnail

Superacid‐Mediated Late‐Stage Aromatic Polydeuteration of Pharmaceuticals

Emeline Appert , Agnès Martin-Mingot , Omar Karam , Fabien Zunino , Bastien Michelet et al.

Chemistry - A European Journal, 2022, 28 (49), pp.e202201583. ⟨10.1002/chem.202201583⟩

Article dans une revue hal-03769665v1
Deposit thumbnail

Insight into the Ferrier rearrangement by combining flash chemistry and superacids

Naresh Bhuma , Ludivine Lebedel , Hiroki Yamashita , Yutaka Shimizu , Zahra Abada et al.

Angewandte Chemie International Edition, 2021, 60 (4), pp.2036-2041. ⟨10.1002/anie.202010175⟩

Article dans une revue hal-03007376v1
Deposit thumbnail

CF3-substituted carbocations: underexploited intermediates with great potential in modern synthetic chemistry

Anthony J Fernandes , Armen Panossian , Bastien Michelet , Agnès Martin-Mingot , Frédéric Leroux et al.

Beilstein Journal of Organic Chemistry, 2021, 17, pp.343-378. ⟨10.3762/bjoc.17.32⟩

Article dans une revue hal-03154651v1
Deposit thumbnail

Complementary Site-Selective Sulfonylation of Aromatic Amines by Superacid Activation

Paul Bourbon , Emeline Appert , Agnès Martin-Mingot , Bastien Michelet , Sébastien Thibaudeau

Organic Letters, 2021, 23 (11), pp.4115-4120. ⟨10.1021/acs.orglett.1c00994⟩

Article dans une revue hal-03358394v1
Deposit thumbnail

Modulating the Efficacy of Carbonic Anhydrase Inhibitors through Fluorine Substitution

Emanuela Berrino , Bastien Michelet , Agnès Martin-Mingot , Fabrizio Carta , Claudiu T Supuran et al.

Angewandte Chemie International Edition, 2021, 60 (43), pp.23068-23082. ⟨10.1002/anie.202103211⟩

Article dans une revue hal-03358401v1
Deposit thumbnail

Formation of synthetically relevant CF3-substituted phenonium ions in superacid media

Anthony J Fernandes , Bastien Michelet , Armen Panossian , Agnès Martin-Mingot , Frédéric R. Leroux et al.

RSC Advances, 2021, 11 (41), pp.25695 - 25699. ⟨10.1039/d1ra04901a⟩

Article dans une revue hal-03325280v1
Deposit thumbnail

Enantioenriched Methylene-Bridged Benzazocanes Synthesis by Organocatalytic and Superacid Activations

Rodolphe Beaud , Bastien Michelet , Yasmin Reviriot , Agnès Martin-Mingot , Jean Rodriguez et al.

Angewandte Chemie International Edition, 2020, 59 (3), pp.1279-1285. ⟨10.1002/anie.201912043⟩

Article dans une revue hal-02436747v1
Deposit thumbnail

Access to Optically-Pure Benzosultams by Superelectrophilic Activation

Bastien Michelet , Ugo Castelli , Emeline Appert , Maude Boucher , Kassandra Vitse et al.

Organic Letters, 2020, 22 (13), pp.4944-4948. ⟨10.1021/acs.orglett.0c01301⟩

Article dans une revue hal-03016554v1

[(DPEPhos)(bcp)Cu]PF<sub>6</sub>: A General and Broadly Applicable Copper-Based Photoredox Catalyst

Hajar Baguia , Christopher Deldaele , Bastien Michelet , Jérôme Beaudelot , Cédric Theunissen et al.

Journal of visualized experiments : JoVE, 2019, 147, ⟨10.3791/59739⟩

Article dans une revue hal-03007750v1

Direct and Selective C-H Carbamoylation of (Hetero)aromatics with TMSOTf-Activated Carbamoyl Chloride

Ayaka Uehara , Sandra Olivero , Bastien Michelet , Agnès Martin-Mingot , Sébastien Thibaudeau et al.

European Journal of Organic Chemistry, 2019, 2019 (1), pp.46-49. ⟨10.1002/ejoc.201801338⟩

Article dans une revue hal-03007761v1

Superelectrophilic activation in superacid HF/SbF5: Expanding molecular diversity in nitrogen-containing compounds series by fluorination

Bastien Michelet , Hélène Carreyre , Frédéric Lecornué , Agnès Mingot , Sébastien Thibaudeau

Journal of Fluorine Chemistry, 2018, 214, pp.68-79. ⟨10.1016/j.jfluchem.2018.04.017⟩

Article dans une revue hal-03007791v1

A General Copper-based Photoredox Catalyst for Organic Synthesis: Scope, Application in Natural Product Synthesis and Mechanistic Insights

Christopher Deldaele , Bastien Michelet , Hajar Baguia , Sofia Kajouj , Eugenie Romero et al.

CHIMIA, 2018, 72 (9), pp.621-629. ⟨10.2533/chimia.2018.621⟩

Article dans une revue hal-03007774v1

Copper-Catalyzed Photoinduced Radical Domino Cyclization of Ynamides and Cyanamides: A Unified Entry to Rosettacin, Luotonin A, and Deoxyvasicinone

Hajar Baguia , Christopher Deldaele , Eugénie Romero , Bastien Michelet , Gwilherm Evano

Synthesis: Journal of Synthetic Organic Chemistry, 2018, 50 (15), pp.3022-3030. ⟨10.1055/s-0037-1610134⟩

Article dans une revue hal-03007805v1

Catalytic Activity of Gold(I) Complexes with Hemilabile P,N Ligands

Bastien Michelet , David Lebœuf , Christophe Bour , Karel Škoch , Filip Horký et al.

ChemPlusChem, 2017, 82 (3), pp.442-448. ⟨10.1002/cplu.201600562⟩

Article dans une revue hal-03007828v1

A General Copper Catalyst for Photoredox Transformations of Organic Halides

Bastien Michelet , Christopher Deldaele , Sofia Kajouj , Cécile Moucheron , Gwilherm Evano

Organic Letters, 2017, 19 (13), pp.3576-3579. ⟨10.1021/acs.orglett.7b01518⟩

Article dans une revue hal-03007815v1

The anionic chemistry of ynamides: A review

Gwilherm Evano , Bastien Michelet , Chunyang Zhang

Comptes Rendus. Chimie, 2017, 20 (6), pp.648-664. ⟨10.1016/j.crci.2016.12.002⟩

Article dans une revue hal-03007821v1

A Journey in the Chemistry of Ynamides: From Synthesis to Applications

Gwilherm Evano , Nicolas Blanchard , Guillaume Compain , Alexis Coste , Charles Demmer et al.

Chemistry Letters, 2016, 45 (6), pp.574-585. ⟨10.1246/cl.160260⟩

Article dans une revue hal-03007853v1

Harnessing the Lewis Acidity of HFIP through its Cooperation with a Calcium(II) Salt: Application to the Aza-Piancatelli Reaction

David Lebøeuf , Lucile Marin , Bastien Michelet , Alejandro Perez-Luna , Régis Guillot et al.

Chemistry - A European Journal, 2016, 22 (45), pp.16165--16171. ⟨10.1002/chem.201603592⟩

Article dans une revue istex hal-01712359v1

Catalytic applications of [IPr·GaX 2 ][SbF 6 ] and related species

Bastien Michelet , Shun Tang , Guillaume Thiery , Julien Monot , Huijing Li et al.

Organic Chemistry Frontiers, 2016, 3 (12), pp.1603-1613. ⟨10.1039/C6QO00470A⟩

Article dans une revue hal-03007837v1

Non-Innocent Behavior of Substrate Backbone Esters in Metal-Catalyzed Carbocyclizations and Friedel–Crafts Reactions of Enynes and Arenynes

Bastien Michelet , Guillaume Thiery , Christophe Bour , Vincent Gandon

Journal of Organic Chemistry, 2015, 80 (21), pp.10925-10938. ⟨10.1021/acs.joc.5b02052⟩

Article dans une revue hal-03007863v1
Deposit thumbnail

Dibromoindium( iii ) cations as a π-Lewis acid: characterization of [IPr·InBr 2 ][SbF 6 ] and its catalytic activity towards alkynes and alkenes

Bastien Michelet , Jean-Rémy Colard-Itté , Guillaume Thiery , Régis Guillot , Christophe Bour et al.

Chemical Communications, 2015, 51 (34), pp.7401-7404. ⟨10.1039/C5CC00740B⟩

Article dans une revue hal-03007870v1

Ca II -Catalyzed Alkenylation of Alcohols with Vinylboronic Acids

David Lebœuf , Marc Presset , Bastien Michelet , Christophe Bour , Sophie Bezzenine-Lafollée et al.

Chemistry - A European Journal, 2015, 21 (31), pp.11001-11005. ⟨10.1002/chem.201501677⟩

Article dans une revue istex hal-03007865v1

Gallium-Assisted Transfer Hydrogenation of Alkenes

Bastien Michelet , Christophe Bour , Vincent Gandon

Chemistry - A European Journal, 2014, 20 (44), pp.14488-14492. ⟨10.1002/chem.201404139⟩

Article dans une revue istex hal-03007877v1

Cationic Gallium(III) Halide Complexes: A New Generation of π-Lewis Acids

Shun Tang , Julien Monot , Ahmad El-Hellani , Bastien Michelet , Régis Guillot et al.

Chemistry - A European Journal, 2012, 18 (33), pp.10239-10243. ⟨10.1002/chem.201201202⟩

Article dans une revue istex hal-03007906v1

Four-Membered Rings With Two Nitrogen Atoms

Frédéric Lecornué , Bastien Michelet

David StC Black; Janine Cossy; Christian V. Stevens. Comprehensive Heterocyclic Chemistry IV, Volume 2: Four-membered Heterocycles, and all Fused Systems with a Four-membered Heterocyclic Ring, 2, Elsevier, pp.403-457, 2022, 978-0-12-818656-5. ⟨10.1016/B978-0-12-818655-8.00153-0⟩

Chapitre d'ouvrage hal-03363494v1

Gallium Trichloride

Masahiko Yamaguchi , Shigeki Matsunaga , Masakatsu Shibasaki , Bastien Michelet , Christophe Bour et al.

Encyclopedia of Reagents for Organic Synthesis, John Wiley & Sons, Ltd, 2014, ⟨10.1002/047084289X.rn00118u.pub3⟩

Chapitre d'ouvrage hal-03007900v1