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Clément CAMP

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Clément Camp is currently a CNRS researcher in the Laboratoire de Chimie, Catalyse, Polymères et Procédés (C2P2 – UMR 5265), in Lyon (France). He earned the Agrégation of Science Physiques in 2009 and graduated in 2010 from the École Normale Supérieure de Lyon (France). He received his Ph.D. degree in 2013 from the University of Grenoble (France) for his work on the coordination chemistry and reactivity of low-valent *f*-element compounds, performed under the supervision of Dr. Marinella Mazzanti. He then joined Prof. John Arnold’s group at the University of California, Berkeley (USA) for postdoctoral training where he studied the activation of small molecules by transition metal complexes. His current research interests deal with surface organometallic chemistry and cooperative effects in catalysis. Clément has authored 52 scientific papers, tackling problems in inorganic and organometallic chemistry with elements from across the periodic table.


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Highly Selective and Efficient Perdeuteration of n‐Pentane via H/D Exchange Catalyzed by a Silica‐Supported Hafnium‐Iridium Bimetallic Complex

Andrey V Pichugov , Léon Escomel , Sébastien Lassalle , Julien Petit , Ribal Jabbour
Angewandte Chemie, 2024, ⟨10.1002/ange.202400992⟩
Journal articles hal-04497630v1
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Photolysis-driven bond activation by thorium and uranium tetraosmate polyhydride complexes

Christopher Ye , Iker del Rosal , Sheridon Kelly , I. Joseph Brackbill , Laurent Maron
Chemical Science, In press, ⟨10.1039/D4SC02380C⟩
Journal articles hal-04611467v1

An anthropocene-framed transdisciplinary dialog at the chemistry-energy nexus

Mathieu S Prévot , Valeria Finelli , Xavier Carrier , Gabriele Deplano , Margherita Cavallo
Chemical Science, inPress, ⟨10.1039/d4sc00099d⟩
Journal articles hal-04611454v1
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Alkane Elimination Preparation of Heterobimetallic MoAl Tetranuclear and Binuclear Complexes Promoting THF Ring Opening

Léon Escomel , Erwann Jeanneau , Chloé Thieuleux , Clément Camp
Inorganics, 2024, 12 (3), pp.72. ⟨10.3390/inorganics12030072⟩
Journal articles hal-04484746v1
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Luminescence of Lanthanide Complexes in Mesoporous Silica Matrices: A Textbook Example of Tris‐Dipicolinate Europium Complex Adsorbed in SBA‐15

Cristina Balogh , Isis N'Dala-Louika , Iurii Suleimanov , Anaïs Pons , Matthias Jouffrieau
Advanced Optical Materials, 2024, ⟨10.1002/adom.202400091⟩
Journal articles hal-04628180v1
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π-Bonding of Group 11 Metals to a Tantalum Alkylidyne Alkyl Complex Promotes Unusual Tautomerism to Bis-alkylidene and CO 2 to Ketenyl Transformation

Abdelhak Lachguar , Iker del Rosal , Laurent Maron , Erwann Jeanneau , Laurent Veyre
Journal of the American Chemical Society, 2024, ⟨10.1021/jacs.4c02172⟩
Journal articles hal-04630141v1
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Cooperative activation of carbon-hydrogen bonds by heterobimetallic systems

Abdelhak Lachguar , Andrey V Pichugov , Till Neumann , Zachary Dubrawski , Clément Camp
Dalton Transactions, 2023, ⟨10.1039/d3dt03571a⟩
Journal articles hal-04358145v1
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Investigation of the transition of amorphous Ti-thiolate prepared by hybrid atomic layer deposition/molecular layer deposition into titanium disulfide ultrathin film

Petros Abi Younes , Ashok-Kumar Yadav , Medet Zhukush , Van-Hoan Le , Hervé Roussel
Journal of Vacuum Science & Technology A, 2023, 41 (4), ⟨10.1116/6.0002448⟩
Journal articles hal-04138018v1
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MnBr(CO)5 : a commercially available highly active catalyst for olefin hydrosilylation under ambient air and green conditions

Anthony Vivien , Laurent Veyre , Raphaël Mirgalet , Clément Camp , Chloé Thieuleux
Green Chemistry, 2023, 25 (19), pp.7721-7728. ⟨10.1039/D3GC02385K⟩
Journal articles hal-04192149v1
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A Versatile Strategy for the Formation of Hydride-Bridged Actinide-Iridium Multimetallics

Christopher Z Ye , Iker Del Rosal , Michael A Boreen , Erik T Ouellette , Dominic Russo
Chemical Science, 2022, ⟨10.1039/D2SC04903A⟩
Journal articles hal-03909474v1
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Mn2(CO)10 and UV light: a promising combination for regioselective alkene hydrosilylation at low temperature

Anthony Vivien , Laurent Veyre , Raphael Mirgalet , Clément Camp , Chloé Thieuleux
Chemical Communications, 2022, ⟨10.1039/d2cc00377e⟩
Journal articles hal-03805073v1
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Highly dispersed silica-supported iridium and iridium–aluminium catalysts for methane activation prepared via surface organometallic chemistry

Léon Escomel , Daniel Abbott , Victor Mougel , Laurent Veyre , Chloé Thieuleux
Chemical Communications, 2022, 58 (59), pp.8214-8217. ⟨10.1039/D2CC02139K⟩
Journal articles hal-03739621v1
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Le tris-dipicolinate de lanthanide : un complexe à tout faire ?

Cristina Balogh , Isis N'Dala-Louika , Jeremy Salaam , Anthony D’aléo , Sandrine Denis‐quanquin
L'Actualité Chimique, 2022, 475
Journal articles hal-03812729v1
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Reactivity of Tantalum/Iridium and Hafnium/Iridium Alkyl Hydrides with Alkyl Lithium Reagents: Nucleophilic Addition, Alpha-H Abstraction, or Hydride Deprotonation?

Sébastien Lassalle , Julien Petit , Rosalyn Falconer , Valentin Hérault , Erwann Jeanneau
Organometallics, 2022, 41 (13), pp.1675-1687. ⟨10.1021/acs.organomet.2c00158⟩
Journal articles hal-03739634v1
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Rational Preparation of Well-Defined Multinuclear Iridium-Aluminum Polyhydride Clusters and Comparative Reactivity

Leon Escomel , Naime Soule , Emmanuel Robin , Iker del Rosal , Laurent Maron
Inorganic Chemistry, 2022, 61 (15), pp.5715-5730. ⟨10.1021/acs.inorgchem.1c03120⟩
Journal articles hal-03714651v1
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Development of Pd supported catalysts using thiol-functionalized mesoporous silica frameworks: application to the chemo-and regio-selective C-3 arylation of free-indole

Marc Renom Carrasco , Walid Khodja , Clément Demarcy , Laurent Veyre , Clément Camp
European Journal of Inorganic Chemistry, 2021, ⟨10.1002/ejic.202001086⟩
Journal articles hal-03805125v1
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Mo(VI) dithiocarbamate with no pre-existing Mo–S–Mo core as an active lubricant additive

M. Al Kharboutly , G. Veryasov , P. Gaval , A. Verchere , C. Camp
Tribology International, 2021, 154, pp.106690. ⟨10.1016/j.triboint.2020.106690⟩
Journal articles hal-02968749v1
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Co2(CO)8 as an efficient catalyst for the synthesis of functionalized polymethylhydrosiloxane oils and unconventional cross-linked materials

Martin Jakoobi , Vincent Dardun , Clément Camp , Chloé Thieuleux
Catalysis science and Technology, 2021, ⟨10.1039/D1CY00191D⟩
Journal articles hal-03215381v1
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Co2(CO)8 and unsaturated epoxides as unexpected partners in generating functionalized siloxane oils and cross-linked materials

Martin Jakoobi , Anthony Vivien , Clément Camp , Chloé Thieuleux
Catalysis Science & Technology, 2021, 11 (14), pp.4714-4718. ⟨10.1039/D1CY00920F⟩
Journal articles hal-03357171v1
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Unusually large "yaw" angle upon coordination of a new bulky unsymmetrical 3-hydroxyadamantyl-functionalized N- heterocyclic carbene ligand to rhodium(I)

Julien Petit , Paul-Alexis Pavard , Clément Camp
Mendeleev Communications, 2021, ⟨10.1016/j.mencom.2021.01.015⟩
Journal articles hal-02996511v1
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Strongly Polarized Iridium δ− –Aluminum δ+ Pairs: Unconventional Reactivity Patterns Including CO 2 Cooperative Reductive Cleavage

Léon Escomel , Iker del Rosal , Laurent Maron , Erwann Jeanneau , Laurent Veyre
Journal of the American Chemical Society, 2021, 143 (12), pp.4844-4856. ⟨10.1021/jacs.1c01725⟩
Journal articles hal-03357324v1
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A Family of Rhodium(I) NHC Chelates Featuring O-containing Tethers for Catalytic Tandem Alkene Isomerization-Hydrosilylation

Ravi Srivastava , Martin Jakoobi , Chloé Thieuleux , Elsje Alessandra Quadrelli , Clément Camp
Dalton Transactions, 2020, ⟨10.1039/D0DT03698F⟩
Journal articles hal-03015981v1
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Developing a Highly Active Catalytic System Based on Cobalt Nanoparticles for Terminal and Internal Alkene Hydrosilylation

Martin Jakoobi , Vincent Dardun , Laurent Veyre , Valérie Meille , Clément Camp
Journal of Organic Chemistry, 2020, 85 (18), pp.11732-11740. ⟨10.1021/acs.joc.0c01439⟩
Journal articles hal-02998618v1
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Mechanistic Investigations via DFT Support the Cooperative Heterobimetallic C-H and O-H Bond Activation Across Ta=Ir Multiple Bonds

Iker Del rosal , Sébastien Lassalle , Laurent Maron , Chiara Dinoi , Chloé Thieuleux
Dalton Transactions, 2020, ⟨10.1039/D0DT03818K⟩
Journal articles hal-03009651v1
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Stepwise Construction of Silica-supported Tantalum/Iridium Heteropolymetallic Catalysts Using Surface Organometallic Chemistry

Sébastien Lassalle , Ribal Jabbour , Iker Del rosal , Laurent Maron , Emiliano Fonda
Journal of Catalysis, 2020, ⟨10.1016/j.jcat.2020.10.016⟩
Journal articles hal-02985281v1
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Regiospecificity in Ligand-Free Pd-Catalyzed C–H Arylation of Indoles: LiHMDS as Base and Transient Directing Group

Yorck Mohr , Marc Renom-Carrasco , Clément Demarcy , Elsje Alessandra Quadrelli , Clément Camp
ACS Catalysis, 2020, 10 (4), pp.2713-2719. ⟨10.1021/acscatal.9b04864⟩
Journal articles hal-02493979v1
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Lability of Ta–NHC adducts as a synthetic route towards heterobimetallic Ta/Rh complexes

Ravi Srivastava , Elsje Alessandra Quadrelli , Clément Camp
Dalton Transactions, 2020, ⟨10.1039/D0DT00344A⟩
Journal articles hal-02495538v1
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Metal–Metal Synergy in Well-Defined Surface Tantalum–Iridium Heterobimetallic Catalysts for H/D Exchange Reactions

Sébastien Lassalle , Ribal Jabbour , Pauline Schiltz , Pierrick Berruyer , Tanya K Todorova
Journal of the American Chemical Society, 2019, ⟨10.1021/jacs.9b08311⟩
Journal articles hal-02382262v1
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Direct Synthesis of Cycloalkanes from Diols and Secondary Alcohols or Ketones Using a Homogeneous Manganese Catalyst

Akash Kaithal , Lisa-Lou Gracia , Clément Camp , Elsje Alessandra Quadrelli , Walter Leitner
Journal of the American Chemical Society, 2019, 141 (44), pp.17487-17492. ⟨10.1021/jacs.9b08832⟩
Journal articles hal-02367932v1

Electrocatalytic Performance of Titania Nanotube Arrays Coated with MoS 2 by ALD toward the Hydrogen Evolution Reaction

Yuanyuan Cao , Yanlin Wu , Clémence Badie , Stéphane Cadot , Clément Camp
ACS Omega, 2019, 4 (5), pp.8816-8823. ⟨10.1021/acsomega.9b00322⟩
Journal articles hal-02284907v1

Early/Late Heterobimetallic Tantalum/Rhodium Species Assembled Through a Novel Bifunctional NHC-OH Ligand

Ravi Srivastava , Raphaël Moneuse , Julien Petit , Paul-Alexis Pavard , Vincent Dardun
Chemistry - A European Journal, 2018, 24 (17), pp.4361--4370. ⟨10.1002/chem.201705507⟩
Journal articles hal-01877468v1
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On the alcoholysis of alkyl-aluminum (iii) alkoxy-NHC derivatives: reactivity of the Al-carbene Lewis pair versus Al-alkyl

Vincent Dardun , Léon Escomel , Erwann Jeanneau , Clément Camp
Dalton Transactions, 2018, 47 (31), pp.10429--10433. ⟨10.1039/C8DT01498A⟩
Journal articles hal-01877466v1


Chia-Wei Hsu , Yi-Chou Tsai , Brandi M Cossairt , Clément Camp , John Arnold
Inorganic Syntheses, 2018, 37, pp.123--134
Journal articles hal-01877467v1

A versatile route to homo-and hetero-bimetallic 5f−5f and 3d−5f complexes supported by a redox active ligand framework

Clément Camp , Davide Toniolo , Julie Andrez , Jacques Pécaut , Marinella Mazzanti
Dalton Transactions, 2017, 46 (34), pp.11145--11148. ⟨10.1039/C7DT01993A⟩
Journal articles hal-01877469v1

Photo-activation of d 0 niobium imido azides: en route to nitrido complexes

Clément Camp , Lauren N Grant , Robert G Bergman , John Arnold
Chemical Communications, 2016, 52 (32), pp.5538--5541
Journal articles hal-01877472v1

N−N bond cleavage in a nitrous oxide−NHC adduct promoted by a PNP pincer cobalt (I) complex

Clément Camp , Lara Ce Naested , Kay Severin , John Arnold
Polyhedron, 2016, 103, pp.157--163
Journal articles hal-01877470v1

On the non-innocence of “Nacnacs”: ligand-based reactivity in β-diketiminate supported coordination compounds

Clément Camp , John Arnold
Dalton Transactions, 2016, 45 (37), pp.14462--14498
Journal articles hal-01877471v1

Ferrocene-Based Tetradentate Schiff Bases as Supporting Ligands in Uranium Chemistry

Clément Camp , Lucile Chatelain , Victor Mougel , Jacques Pécaut , Marinella Mazzanti
Inorganic Chemistry, 2015, 54 (12), pp.5774-5783. ⟨10.1021/acs.inorgchem.5b00467⟩
Journal articles hal-01588141v1
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CO2 conversion to isocyanate via multiple N-Si bond cleavage at a bulky uranium(III) complex

Clément Camp , Lucile Chatelain , Christos E. Kefalidis , Jacques Pécaut , Laurent Maron
Chemical Communications, 2015, 51 (84), pp.15454-15457. ⟨10.1039/c5cc06707c⟩
Journal articles hal-01588142v1

CS2 activation at uranium(III) siloxide ate complexes: the effect of a Lewis acidic site

Clément Camp , Oliver Cooper , Julie Andrez , Jacques Pécaut , Marinella Mazzanti
Dalton Transactions, 2015, 44 (6), pp.2650-2656. ⟨10.1039/c4dt02585g⟩
Journal articles hal-01588140v1
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Uranium and thorium complexes of the phosphaethynolate ion

Clément Camp , Nicholas Settineri , Julia Lefèvre , Andrew R Jupp , José M Goicoechea
Chemical Science, 2015, 6 (11), pp.6379--6384. ⟨10.1039/c5sc02150b⟩
Journal articles hal-01877473v1

Theory and X-ray Absorption Spectroscopy for Aluminum Coordination Complexes−Al K-Edge Studies of Charge and Bonding in (BDI) Al,(BDI) AlR2, and (BDI) AlX2 Complexes

Alison B Altman , Cd Pemmaraju , Clément Camp , John Arnold , Stefan G Minasian
Journal of the American Chemical Society, 2015, 137 (32), pp.10304--10316
Journal articles hal-01877474v1

Multimetallic cooperativity in uranium-mediated CO2 activation

Oliver Cooper , Clément Camp , Jacques Pécaut , Christos E. Kefalidis , Laurent Maron
Journal of the American Chemical Society, 2014, 136 (18), pp.6716--6723. ⟨10.1021/ja5017624⟩
Journal articles hal-01877478v1

Two-electron versus one-electron reduction of chalcogens by uranium (III): synthesis of a terminal U (V) persulfide complex

Clément Camp , Maria Augusta Antunes , Gregorio García , Ilaria Ciofini , Isabel C Santos
Chemical Science, 2014, 5 (2), pp.841--846. ⟨10.1039/C3SC52742E⟩
Journal articles hal-01877477v1

Unusual activation of H 2 by reduced cobalt complexes supported by a PNP pincer ligand

Sergio S Rozenel , Rosa Padilla , Clément Camp , John Arnold
Chemical Communications, 2014, 50 (20), pp.2612--2614
Journal articles hal-01877476v1

Single-Molecule-Magnet Behavior in Mononuclear Homoleptic Tetrahedral Uranium (III) Complexes

Laura Cj Pereira , Clément Camp , Joana T Coutinho , Lucile Chatelain , Pascale Maldivi
Inorganic Chemistry, 2014, 53 (22), pp.11809--11811. ⟨10.1021/ic501520c⟩
Journal articles hal-01877479v1

Activation of White Phosphorus by Low-Valent Group 5 Complexes: Formation and Reactivity of cyclo-P4 Inverted Sandwich Compounds

Clément Camp , Laurent Maron , Robert G Bergman , John Arnold
Journal of the American Chemical Society, 2014, 136 (50), pp.17652--17661
Journal articles hal-01877475v1

Synthesis of Electron-Rich Uranium (IV) Complexes Supported by Tridentate Schiff Base Ligands and Their Multi-Electron Redox Chemistry

Clément Camp , Julie Andrez , Jacques Pécaut , Marinella Mazzanti
Inorganic Chemistry, 2013, 52 (12), pp.7078--7086. ⟨10.1021/ic4006218⟩
Journal articles hal-01877483v1

Controlled Thermolysis of Uranium (Alkoxy) siloxy Complexes: A Route to Polymetallic Complexes of Low-Valent Uranium

Clément Camp , Christos E. Kefalidis , Jacques Pécaut , Laurent Maron , Marinella Mazzanti
Angewandte Chemie International Edition, 2013, 52 (48), pp.12646--12650. ⟨10.1002/anie.201307291⟩
Journal articles hal-01877480v1

Tuning uranium−nitrogen multiple bond formation with ancillary siloxide ligands

Clément Camp , Jacques Pécaut , Marinella Mazzanti
Journal of the American Chemical Society, 2013, 135 (32), pp.12101--12111. ⟨10.1021/ja405815b⟩
Journal articles hal-01877481v1

Cation-Mediated Conversion of the State of Charge in Uranium Arene Inverted-Sandwich Complexes

Clément Camp , Victor Mougel , Jacques Pécaut , Laurent Maron , Marinella Mazzanti
Chemistry - A European Journal, 2013, 19 (51), pp.17528--17540. ⟨10.1002/chem.201302752⟩
Journal articles hal-01877482v1

Diamine bis (phenolate) as supporting ligands in organoactinide (iv) chemistry. Synthesis, structural characterization, and reactivity of stable dialkyl derivatives

Elsa Mora , Leonor Maria , Biplab Biswas , Clément Camp , Isabel C Santos
Organometallics, 2012, 32 (5), pp.1409--1422. ⟨10.1021/om3010806⟩
Journal articles hal-01877484v1

Multielectron redox chemistry of lanthanide Schiff-base complexes

Clément Camp , Valentin Guidal , Biplab Biswas , Jacques Pécaut , Lionel Dubois
Chemical Science, 2012, 3 (8), pp.2433--2448. ⟨10.1039/C2SC20476B⟩
Journal articles hal-01877485v1

Siloxides as Supporting Ligands in Uranium (III)-Mediated Small-Molecule Activation

Victor Mougel , Clément Camp , Jacques Pécaut , Christophe Copéret , Laurent Maron
Angewandte Chemie, 2012, 124 (49), pp.12446--12450. ⟨10.1002/anie.201206955⟩
Journal articles hal-01877486v1

Multielectron Redox Reactions Involving C- C Coupling and Cleavage in Uranium Schiff Base Complexes

Clément Camp , Victor Mougel , Pawel Horeglad , Jacques Pécaut , Marinella Mazzanti
Journal of the American Chemical Society, 2010, 132 (49), pp.17374--17377. ⟨10.1021/ja1089364⟩
Journal articles hal-01877487v1

Efficient and tunable synthesis of new polydentate bifunctional chelating agents using click chemistry

Clément Camp , Sandra Dorbes , Claude Picard , Eric Benoist
Tetrahedron Letters, 2008, 49 (12), pp.1979--1983. ⟨10.1016/j.tetlet.2008.01.086⟩
Journal articles hal-01877488v1