Clément CAMP

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Documents
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Publications

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Synergistic C–H bond activation across molybdenum–iridium multiply bonded complexes: a cascade of transformations

Zachary Dubrawski , Iker del Rosal , Erwann Jeanneau , Laurent Maron , Chloé Thieuleux et al.

Chemical Science, 2025, ⟨10.1039/D5SC03465E⟩

Article dans une revue hal-05173362v1
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Synthesis of perdeuterated pentane and THF under mild conditions by silica‐supported Ta/M (M = Co, Ir) heterobimetallic catalysts

Andrey V Pichugov , Abdelhak Lachguar , Vincent Maurel , Serge Gambarelli , Jean‐marie Mouesca et al.

Angewandte Chemie International Edition, 2025, 65 (5), pp.e22721. ⟨10.1002/anie.202522721⟩

Article dans une revue hal-05505867v1
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Mn-Catalyzed Regioselective Alkene Hydrosilylation: From Mechanism Investigation to the Design of a Pre-Catalyst Candidate

Ming-Yu Chen , Naïme Soulé , Alejandra Zuluaga , Antoine Frot , Anthony Vivien et al.

ACS Catalysis, 2025, 15 (19), pp.16840-16850. ⟨10.1021/acscatal.5c04086⟩

Article dans une revue hal-05406152v1
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Catalytic H/D exchange of (hetero)arenes with early–late polyhydride heterobimetallic complexes: impact of transition metal pairs

Abdelhak Lachguar , Till Neumann , Andrey V Pichugov , Erwann Jeanneau , Laurent Veyre et al.

Dalton Transactions, 2025, 54 (9), pp.3804-3811. ⟨10.1039/D4DT03171G⟩

Article dans une revue hal-05312405v1
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Probing Structural Diversity in a Series of Perhydrocarbyl Heterobimetallic Complexes Associating Tantalum and 3d (Cr, Mn, Fe, Co, Ni) Transition Metals

Till Neumann , Iker del Rosal , Laurent Maron , Erwann Jeanneau , Vincent Maurel et al.

Inorganic Chemistry, 2025, 64 (43), pp.21353-21367. ⟨10.1021/acs.inorgchem.5c02380⟩

Article dans une revue hal-05505845v1
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Visible-light driven H2 reductive elimination unlocks reactivity in polyhydrido niobium iridium clusters

Zachary Dubrawski , Samy Aïssiou , Erwann Jeanneau , Chloé Thieuleux , Clément Camp

Dalton Transactions, 2025, 55 (2), pp.620-629. ⟨10.1039/d5dt02432c⟩

Article dans une revue hal-05505841v1
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Flash Communication: Well-Defined Paramagnetic Polyhydrido-Bridged Iron–Iridium Clusters

Zachary Dubrawski , Billie Shearman , Naïme Soulé , Erwann Jeanneau , Chloé Thieuleux et al.

Organometallics, 2025, 44 (19), pp.2151-2155. ⟨10.1021/acs.organomet.5c00301⟩

Article dans une revue hal-05312410v1
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Highly Selective and Efficient Perdeuteration of n‐Pentane via H/D Exchange Catalyzed by a Silica‐Supported Hafnium‐Iridium Bimetallic Complex

Andrey V Pichugov , Léon Escomel , Sébastien Lassalle , Julien Petit , Ribal Jabbour et al.

Angewandte Chemie, 2024, ⟨10.1002/ange.202400992⟩

Article dans une revue hal-04497630v1
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Photolysis-driven bond activation by thorium and uranium tetraosmate polyhydride complexes

Christopher Ye , Iker del Rosal , Sheridon Kelly , I. Joseph Brackbill , Laurent Maron et al.

Chemical Science, In press, ⟨10.1039/D4SC02380C⟩

Article dans une revue hal-04611467v1
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An Anthropocene-Framed Transdisciplinary Dialog at the Chemistry-Energy Nexus

Mathieu S Prévot , Valeria Finelli , Xavier Carrier , Gabriele Deplano , Margherita Cavallo et al.

Chemical Science, 2024, 15, pp.9054-9086. ⟨10.1039/d4sc00099d⟩

Article dans une revue hal-04611454v1
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Synthesis, Structure, and Bonding of Actinide–Rhenium Polyhydrides

Christopher Ye , Iker del Rosal , Sheridon Kelly , Erik Ouellette , Laurent Maron et al.

Inorganic Chemistry, In press, ⟨10.1021/acs.inorgchem.4c03449⟩

Article dans une revue hal-04749940v1
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Reduction of CS 2 to an ethanetetrathiolate by a hydride-bridged uranium–iridium heterobimetallic complex

Christopher Z Ye , Iker del Rosal , Erik T Ouellette , Stephan Hohloch , Laurent Maron et al.

Chemical Communications, In press, ⟨10.1039/D4CC02482F⟩

Article dans une revue hal-04724457v1
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π-Bonding of Group 11 Metals to a Tantalum Alkylidyne Alkyl Complex Promotes Unusual Tautomerism to Bis-alkylidene and CO 2 to Ketenyl Transformation

Abdelhak Lachguar , Iker del Rosal , Laurent Maron , Erwann Jeanneau , Laurent Veyre et al.

Journal of the American Chemical Society, 2024, ⟨10.1021/jacs.4c02172⟩

Article dans une revue hal-04630141v1
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Luminescence of Lanthanide Complexes in Mesoporous Silica Matrices: A Textbook Example of Tris‐Dipicolinate Europium Complex Adsorbed in SBA‐15

Cristina Balogh , Isis N'Dala-Louika , Iurii Suleimanov , Anaïs Pons , Matthias Jouffrieau et al.

Advanced Optical Materials, 2024, ⟨10.1002/adom.202400091⟩

Article dans une revue hal-04628180v1
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CO<sub>2</sub> cleavage by tantalum/M (M = iridium, osmium) heterobimetallic complexes

Abdelhak Lachguar , Christopher Z Ye , Sheridon N Kelly , Erwann Jeanneau , Iker del Rosal et al.

Chemical Communications, 2024, 60 (61), pp.7878-7881. ⟨10.1039/D4CC02207F⟩

Article dans une revue hal-04738526v1
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Alkane Elimination Preparation of Heterobimetallic MoAl Tetranuclear and Binuclear Complexes Promoting THF Ring Opening

Léon Escomel , Erwann Jeanneau , Chloé Thieuleux , Clément Camp

Inorganics, 2024, 12 (3), pp.72. ⟨10.3390/inorganics12030072⟩

Article dans une revue hal-04484746v1
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MnBr(CO)5 : a commercially available highly active catalyst for olefin hydrosilylation under ambient air and green conditions

Anthony Vivien , Laurent Veyre , Raphaël Mirgalet , Clément Camp , Chloé Thieuleux

Green Chemistry, 2023, 25 (19), pp.7721-7728. ⟨10.1039/D3GC02385K⟩

Article dans une revue hal-04192149v1
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Investigation of the transition of amorphous Ti-thiolate prepared by hybrid atomic layer deposition/molecular layer deposition into titanium disulfide ultrathin film

Petros Abi Younes , Ashok-Kumar Yadav , Medet Zhukush , Van-Hoan Le , Hervé Roussel et al.

Journal of Vacuum Science & Technology A, 2023, 41 (4), ⟨10.1116/6.0002448⟩

Article dans une revue hal-04138018v1
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Cooperative activation of carbon-hydrogen bonds by heterobimetallic systems

Abdelhak Lachguar , Andrey V Pichugov , Till Neumann , Zachary Dubrawski , Clément Camp

Dalton Transactions, 2023, ⟨10.1039/d3dt03571a⟩

Article dans une revue hal-04358145v1
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Rational Preparation of Well-Defined Multinuclear Iridium-Aluminum Polyhydride Clusters and Comparative Reactivity

Leon Escomel , Naime Soule , Emmanuel Robin , Iker del Rosal , Laurent Maron et al.

Inorganic Chemistry, 2022, 61 (15), pp.5715-5730. ⟨10.1021/acs.inorgchem.1c03120⟩

Article dans une revue hal-03714651v1
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A Versatile Strategy for the Formation of Hydride-Bridged Actinide-Iridium Multimetallics

Christopher Z Ye , Iker Del rosal , Michael A Boreen , Erik T Ouellette , Dominic Russo et al.

Chemical Science, 2022, ⟨10.1039/D2SC04903A⟩

Article dans une revue hal-03909474v1
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Le tris-dipicolinate de lanthanide : un complexe à tout faire ?

Cristina Balogh , Isis N'Dala-Louika , Jeremy Salaam , Anthony D’aléo , Sandrine Denis‐quanquin et al.

L'Actualité Chimique, 2022, 475

Article dans une revue hal-03812729v1
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Reactivity of Tantalum/Iridium and Hafnium/Iridium Alkyl Hydrides with Alkyl Lithium Reagents: Nucleophilic Addition, Alpha-H Abstraction, or Hydride Deprotonation?

Sébastien Lassalle , Julien Petit , Rosalyn Falconer , Valentin Hérault , Erwann Jeanneau et al.

Organometallics, 2022, 41 (13), pp.1675-1687. ⟨10.1021/acs.organomet.2c00158⟩

Article dans une revue hal-03739634v1
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Highly dispersed silica-supported iridium and iridium–aluminium catalysts for methane activation prepared via surface organometallic chemistry

Léon Escomel , Daniel Abbott , Victor Mougel , Laurent Veyre , Chloé Thieuleux et al.

Chemical Communications, 2022, 58 (59), pp.8214-8217. ⟨10.1039/D2CC02139K⟩

Article dans une revue hal-03739621v1
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Mn2(CO)10 and UV light: a promising combination for regioselective alkene hydrosilylation at low temperature

Anthony Vivien , Laurent Veyre , Raphael Mirgalet , Clément Camp , Chloé Thieuleux

Chemical Communications, 2022, ⟨10.1039/d2cc00377e⟩

Article dans une revue hal-03805073v1
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Co2(CO)8 as an efficient catalyst for the synthesis of functionalized polymethylhydrosiloxane oils and unconventional cross-linked materials

Martin Jakoobi , Vincent Dardun , Clément Camp , Chloé Thieuleux

Catalysis science and Technology, 2021, ⟨10.1039/D1CY00191D⟩

Article dans une revue hal-03215381v1
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Mo(VI) dithiocarbamate with no pre-existing Mo–S–Mo core as an active lubricant additive

M. Al Kharboutly , G. Veryasov , P. Gaval , A. Verchere , C. Camp et al.

Tribology International, 2021, 154, pp.106690. ⟨10.1016/j.triboint.2020.106690⟩

Article dans une revue hal-02968749v1
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Development of Pd supported catalysts using thiol-functionalized mesoporous silica frameworks: application to the chemo-and regio-selective C-3 arylation of free-indole

Marc Renom Carrasco , Walid Khodja , Clément Demarcy , Laurent Veyre , Clément Camp et al.

European Journal of Inorganic Chemistry, 2021, ⟨10.1002/ejic.202001086⟩

Article dans une revue hal-03805125v1
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Unusually large "yaw" angle upon coordination of a new bulky unsymmetrical 3-hydroxyadamantyl-functionalized N- heterocyclic carbene ligand to rhodium(I)

Julien Petit , Paul-Alexis Pavard , Clément Camp

Mendeleev Communications, 2021, ⟨10.1016/j.mencom.2021.01.015⟩

Article dans une revue hal-02996511v1
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Co2(CO)8 and unsaturated epoxides as unexpected partners in generating functionalized siloxane oils and cross-linked materials

Martin Jakoobi , Anthony Vivien , Clément Camp , Chloé Thieuleux

Catalysis Science & Technology, 2021, 11 (14), pp.4714-4718. ⟨10.1039/D1CY00920F⟩

Article dans une revue hal-03357171v1
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Strongly Polarized Iridium δ− –Aluminum δ+ Pairs: Unconventional Reactivity Patterns Including CO 2 Cooperative Reductive Cleavage

Léon Escomel , Iker del Rosal , Laurent Maron , Erwann Jeanneau , Laurent Veyre et al.

Journal of the American Chemical Society, 2021, 143 (12), pp.4844-4856. ⟨10.1021/jacs.1c01725⟩

Article dans une revue hal-03357324v1
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Developing a Highly Active Catalytic System Based on Cobalt Nanoparticles for Terminal and Internal Alkene Hydrosilylation

Martin Jakoobi , Vincent Dardun , Laurent Veyre , Valérie Meille , Clément Camp et al.

Journal of Organic Chemistry, 2020, 85 (18), pp.11732-11740. ⟨10.1021/acs.joc.0c01439⟩

Article dans une revue hal-02998618v1
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Mechanistic Investigations via DFT Support the Cooperative Heterobimetallic C-H and O-H Bond Activation Across Ta=Ir Multiple Bonds

Iker Del rosal , Sébastien Lassalle , Laurent Maron , Chiara Dinoi , Chloé Thieuleux et al.

Dalton Transactions, 2020, ⟨10.1039/D0DT03818K⟩

Article dans une revue hal-03009651v1
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A Family of Rhodium(I) NHC Chelates Featuring O-containing Tethers for Catalytic Tandem Alkene Isomerization-Hydrosilylation

Ravi Srivastava , Martin Jakoobi , Chloé Thieuleux , Elsje Alessandra Quadrelli , Clément Camp

Dalton Transactions, 2020, ⟨10.1039/D0DT03698F⟩

Article dans une revue hal-03015981v1
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Lability of Ta–NHC adducts as a synthetic route towards heterobimetallic Ta/Rh complexes

Ravi Srivastava , Elsje Alessandra Quadrelli , Clément Camp

Dalton Transactions, 2020, ⟨10.1039/D0DT00344A⟩

Article dans une revue hal-02495538v1
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Regiospecificity in Ligand-Free Pd-Catalyzed C–H Arylation of Indoles: LiHMDS as Base and Transient Directing Group

Yorck Mohr , Marc Renom-Carrasco , Clément Demarcy , Elsje Alessandra Quadrelli , Clément Camp et al.

ACS Catalysis, 2020, 10 (4), pp.2713-2719. ⟨10.1021/acscatal.9b04864⟩

Article dans une revue hal-02493979v1
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Stepwise Construction of Silica-supported Tantalum/Iridium Heteropolymetallic Catalysts Using Surface Organometallic Chemistry

Sébastien Lassalle , Ribal Jabbour , Iker Del rosal , Laurent Maron , Emiliano Fonda et al.

Journal of Catalysis, 2020, ⟨10.1016/j.jcat.2020.10.016⟩

Article dans une revue hal-02985281v1
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Direct Synthesis of Cycloalkanes from Diols and Secondary Alcohols or Ketones Using a Homogeneous Manganese Catalyst

Akash Kaithal , Lisa-Lou Gracia , Clément Camp , Elsje Alessandra Quadrelli , Walter Leitner

Journal of the American Chemical Society, 2019, 141 (44), pp.17487-17492. ⟨10.1021/jacs.9b08832⟩

Article dans une revue hal-02367932v1
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Metal–Metal Synergy in Well-Defined Surface Tantalum–Iridium Heterobimetallic Catalysts for H/D Exchange Reactions

Sébastien Lassalle , Ribal Jabbour , Pauline Schiltz , Pierrick Berruyer , Tanya K Todorova et al.

Journal of the American Chemical Society, 2019, ⟨10.1021/jacs.9b08311⟩

Article dans une revue hal-02382262v1

Electrocatalytic Performance of Titania Nanotube Arrays Coated with MoS 2 by ALD toward the Hydrogen Evolution Reaction

Yuanyuan Cao , Yanlin Wu , Clémence Badie , Stéphane Cadot , Clément Camp et al.

ACS Omega, 2019, 4 (5), pp.8816-8823. ⟨10.1021/acsomega.9b00322⟩

Article dans une revue hal-02284907v1

SYNTHETIC ROUTE TO WHITE PHOSPHORUS (P4) AND ARSENIC TRIPHOSPHIDE (AsP3)

Chia-Wei Hsu , Yi-Chou Tsai , Brandi M Cossairt , Clément Camp , John Arnold et al.

Inorganic Syntheses, 2018, 37, pp.123--134

Article dans une revue hal-01877467v1

Early/Late Heterobimetallic Tantalum/Rhodium Species Assembled Through a Novel Bifunctional NHC-OH Ligand

Ravi Srivastava , Raphaël Moneuse , Julien Petit , Paul-Alexis Pavard , Vincent Dardun et al.

Chemistry - A European Journal, 2018, 24 (17), pp.4361--4370. ⟨10.1002/chem.201705507⟩

Article dans une revue hal-01877468v1
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On the alcoholysis of alkyl-aluminum (iii) alkoxy-NHC derivatives: reactivity of the Al-carbene Lewis pair versus Al-alkyl

Vincent Dardun , Léon Escomel , Erwann Jeanneau , Clément Camp

Dalton Transactions, 2018, 47 (31), pp.10429--10433. ⟨10.1039/C8DT01498A⟩

Article dans une revue hal-01877466v1

A versatile route to homo-and hetero-bimetallic 5f−5f and 3d−5f complexes supported by a redox active ligand framework

Clément Camp , Davide Toniolo , Julie Andrez , Jacques Pécaut , Marinella Mazzanti

Dalton Transactions, 2017, 46 (34), pp.11145--11148. ⟨10.1039/C7DT01993A⟩

Article dans une revue hal-01877469v1

On the non-innocence of “Nacnacs”: ligand-based reactivity in β-diketiminate supported coordination compounds

Clément Camp , John Arnold

Dalton Transactions, 2016, 45 (37), pp.14462--14498

Article dans une revue hal-01877471v1

Photo-activation of d 0 niobium imido azides: en route to nitrido complexes

Clément Camp , Lauren N Grant , Robert G Bergman , John Arnold

Chemical Communications, 2016, 52 (32), pp.5538--5541

Article dans une revue hal-01877472v1

N−N bond cleavage in a nitrous oxide−NHC adduct promoted by a PNP pincer cobalt (I) complex

Clément Camp , Lara Ce Naested , Kay Severin , John Arnold

Polyhedron, 2016, 103, pp.157--163

Article dans une revue hal-01877470v1
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CO2 conversion to isocyanate via multiple N-Si bond cleavage at a bulky uranium(III) complex

Clément Camp , Lucile Chatelain , Christos E. Kefalidis , Jacques Pécaut , Laurent Maron et al.

Chemical Communications, 2015, 51 (84), pp.15454-15457. ⟨10.1039/c5cc06707c⟩

Article dans une revue hal-01588142v1

Ferrocene-Based Tetradentate Schiff Bases as Supporting Ligands in Uranium Chemistry

Clément Camp , Lucile Chatelain , Victor Mougel , Jacques Pécaut , Marinella Mazzanti

Inorganic Chemistry, 2015, 54 (12), pp.5774-5783. ⟨10.1021/acs.inorgchem.5b00467⟩

Article dans une revue hal-01588141v1

Theory and X-ray Absorption Spectroscopy for Aluminum Coordination Complexes−Al K-Edge Studies of Charge and Bonding in (BDI) Al,(BDI) AlR2, and (BDI) AlX2 Complexes

Alison B Altman , Cd Pemmaraju , Clément Camp , John Arnold , Stefan G Minasian et al.

Journal of the American Chemical Society, 2015, 137 (32), pp.10304--10316

Article dans une revue hal-01877474v1

CS2 activation at uranium(III) siloxide ate complexes: the effect of a Lewis acidic site

Clément Camp , Oliver Cooper , Julie Andrez , Jacques Pécaut , Marinella Mazzanti

Dalton Transactions, 2015, 44 (6), pp.2650-2656. ⟨10.1039/c4dt02585g⟩

Article dans une revue hal-01588140v1
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Uranium and thorium complexes of the phosphaethynolate ion

Clément Camp , Nicholas Settineri , Julia Lefèvre , Andrew R Jupp , José M Goicoechea et al.

Chemical Science, 2015, 6 (11), pp.6379--6384. ⟨10.1039/c5sc02150b⟩

Article dans une revue hal-01877473v1

Activation of White Phosphorus by Low-Valent Group 5 Complexes: Formation and Reactivity of cyclo-P4 Inverted Sandwich Compounds

Clément Camp , Laurent Maron , Robert G Bergman , John Arnold

Journal of the American Chemical Society, 2014, 136 (50), pp.17652--17661

Article dans une revue hal-01877475v1

Unusual activation of H 2 by reduced cobalt complexes supported by a PNP pincer ligand

Sergio S Rozenel , Rosa Padilla , Clément Camp , John Arnold

Chemical Communications, 2014, 50 (20), pp.2612--2614

Article dans une revue hal-01877476v1

Two-electron versus one-electron reduction of chalcogens by uranium (III): synthesis of a terminal U (V) persulfide complex

Clément Camp , Maria Augusta Antunes , Gregorio García , Ilaria Ciofini , Isabel C Santos et al.

Chemical Science, 2014, 5 (2), pp.841--846. ⟨10.1039/C3SC52742E⟩

Article dans une revue hal-01877477v1

Multimetallic cooperativity in uranium-mediated CO2 activation

Oliver Cooper , Clément Camp , Jacques Pécaut , Christos E. Kefalidis , Laurent Maron et al.

Journal of the American Chemical Society, 2014, 136 (18), pp.6716--6723. ⟨10.1021/ja5017624⟩

Article dans une revue hal-01877478v1

Single-Molecule-Magnet Behavior in Mononuclear Homoleptic Tetrahedral Uranium (III) Complexes

Laura Cj Pereira , Clément Camp , Joana T Coutinho , Lucile Chatelain , Pascale Maldivi et al.

Inorganic Chemistry, 2014, 53 (22), pp.11809--11811. ⟨10.1021/ic501520c⟩

Article dans une revue hal-01877479v1

Controlled Thermolysis of Uranium (Alkoxy) siloxy Complexes: A Route to Polymetallic Complexes of Low-Valent Uranium

Clément Camp , Christos E. Kefalidis , Jacques Pécaut , Laurent Maron , Marinella Mazzanti

Angewandte Chemie International Edition, 2013, 52 (48), pp.12646--12650. ⟨10.1002/anie.201307291⟩

Article dans une revue istex hal-01877480v1

Synthesis of Electron-Rich Uranium (IV) Complexes Supported by Tridentate Schiff Base Ligands and Their Multi-Electron Redox Chemistry

Clément Camp , Julie Andrez , Jacques Pécaut , Marinella Mazzanti

Inorganic Chemistry, 2013, 52 (12), pp.7078--7086. ⟨10.1021/ic4006218⟩

Article dans une revue hal-01877483v1

Tuning uranium−nitrogen multiple bond formation with ancillary siloxide ligands

Clément Camp , Jacques Pécaut , Marinella Mazzanti

Journal of the American Chemical Society, 2013, 135 (32), pp.12101--12111. ⟨10.1021/ja405815b⟩

Article dans une revue hal-01877481v1

Cation-Mediated Conversion of the State of Charge in Uranium Arene Inverted-Sandwich Complexes

Clément Camp , Victor Mougel , Jacques Pécaut , Laurent Maron , Marinella Mazzanti

Chemistry - A European Journal, 2013, 19 (51), pp.17528--17540. ⟨10.1002/chem.201302752⟩

Article dans une revue istex hal-01877482v1

Multielectron redox chemistry of lanthanide Schiff-base complexes

Clément Camp , Valentin Guidal , Biplab Biswas , Jacques Pécaut , Lionel Dubois et al.

Chemical Science, 2012, 3 (8), pp.2433--2448. ⟨10.1039/C2SC20476B⟩

Article dans une revue hal-01877485v1

Diamine bis (phenolate) as supporting ligands in organoactinide (iv) chemistry. Synthesis, structural characterization, and reactivity of stable dialkyl derivatives

Elsa Mora , Leonor Maria , Biplab Biswas , Clément Camp , Isabel C Santos et al.

Organometallics, 2012, 32 (5), pp.1409--1422. ⟨10.1021/om3010806⟩

Article dans une revue hal-01877484v1

Siloxides as Supporting Ligands in Uranium (III)-Mediated Small-Molecule Activation

Victor Mougel , Clément Camp , Jacques Pécaut , Christophe Copéret , Laurent Maron et al.

Angewandte Chemie, 2012, 124 (49), pp.12446--12450. ⟨10.1002/anie.201206955⟩

Article dans une revue istex hal-01877486v1

Multielectron Redox Reactions Involving C- C Coupling and Cleavage in Uranium Schiff Base Complexes

Clément Camp , Victor Mougel , Pawel Horeglad , Jacques Pécaut , Marinella Mazzanti

Journal of the American Chemical Society, 2010, 132 (49), pp.17374--17377. ⟨10.1021/ja1089364⟩

Article dans une revue hal-01877487v1

Efficient and tunable synthesis of new polydentate bifunctional chelating agents using click chemistry

Clément Camp , Sandra Dorbes , Claude Picard , Eric Benoist

Tetrahedron Letters, 2008, 49 (12), pp.1979--1983. ⟨10.1016/j.tetlet.2008.01.086⟩

Article dans une revue istex hal-01877488v1