Emmanuel Nicolas

Researcher - Engineer

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Documents

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247338

Publications

	Hydrogenolysis of haloboranes: from synthesis of hydroboranes to formal hydroboration reactions Guilhem Zwart , Alexis Mifleur , Gabriel Durin , Emmanuel Nicolas , Thibault Cantat Angewandte Chemie International Edition, In press, ⟨10.1002/anie.202411468⟩ Journal articles hal-04688981v1
	Fluorophosphoniums as Lewis acids in organometallic catalysis: application to the carbonylation of β-lactones Marie-Hélène Pietraru , Louise Ponsard , Nicolas Lentz , Pierre Thuéry , Emmanuel Nicolas Chemical Communications, 2024, 60 (8), pp.1043-1046. ⟨10.1039/d3cc04282k⟩ Journal articles hal-04660725v1
	Formoxyboranes as hydroborane surrogates for the catalytic reduction of carbonyls through transfer hydroboration Gabriel Durin , R Martin Romero , Timothé Godou , Clément Chauvier , Pierre Thuéry Catalysis Science & Technology, 2024, 14 (7), pp.1848-1853. ⟨10.1039/d3cy01702h⟩ Journal articles hal-04660726v1
	Production of methane by catalytic decarboxylation of methyl formate as a liquid surrogate Nathan de Riggi , Arnaud Imberdis , Emmanuel Nicolas , Thibault Cantat Organometallics, 2024, pp.4c00023. ⟨10.1021/acs.organomet.4c00023⟩ Journal articles hal-04660735v1
	Direct Enthalpy Measurement for Hydrogenation of Liquid Organic Hydrogen Carriers by Differential Scanning Calorimetry under H2 Pressure Florian d'Ambra , Vicent Faucheux , Emmanuel Nicolas , Thibault Cantat , Gérard Gébel Industrial and engineering chemistry research, 2024, 63 (30), pp.13157-13168. ⟨10.1021/acs.iecr.4c01739⟩ Journal articles hal-04681564v1
	Fluorophosphoniums as Lewis acids in organometallic catalysis: application in cobalt-catalyzed carbonylation of β-lactones Marie-Hélène Pietraru , Louise Ponsard , Nicolas Lentz , Pierre Thuéry , Emmanuel Nicolas Chemical Communications, 2023, 60 (8), pp.1043-1046. ⟨10.26434/chemrxiv-2023-d3r4g⟩ Journal articles cea-04440608v1
	Metal‐Free Catalytic Hydrogenolysis of Chlorosilanes into Hydrosilanes with “Inverse” Frustrated Lewis Pairs Gabriel Durin , Jean‐claude Berthet , Pierre Thuéry , Emmanuel Nicolas , Thibault Cantat Chemistry - A European Journal, 2023, 29 (61), ⟨10.1002/chem.202302155⟩ Journal articles hal-04236744v1
	Vers la synthèse de réducteurs renouvelables à base de silicium Gabriel Durin , Jean-Claude Berthet , Emmanuel Nicolas , Thibault Cantat L'Actualité Chimique, 2023, 487, pp.14-20 Journal articles cea-04440659v1
	Catalytic Carbonylation of Acrylic Acid to Succinic Anhydride Marie‐Hélène Pietraru , Nicolas Lentz , Louise Ponsard , Emmanuel Nicolas , Thibault Cantat ChemCatChem, 2023, 15 (21), ⟨10.1002/cctc.202300720⟩ Journal articles cea-04440571v1
	Evaluation of acetophenone as a novel alcohol-cycloalkane bifunctional liquid organic hydrogen carrier (LOHC) Florian d'Ambra , Julia Levy , Parviz Hajiyev , Thibault Cantat , Gérard Gébel International Journal of Hydrogen Energy, 2023, 48 (85), pp.33207-33222. ⟨10.1016/j.ijhydene.2023.05.024⟩ Journal articles cea-04440528v1
	Metal‐Free Catalytic Hydrogenolysis of Silyl Triflates and Halides into Hydrosilanes Gabriel Durin , Albane Fontaine , Jean‐claude Berthet , Emmanuel Nicolas , Pierre Thuéry Angewandte Chemie International Edition, 2022, 61 (23), pp.e202200911. ⟨10.1002/anie.202200911⟩ Journal articles hal-04097568v1
	The Role of ($^{tBu}$POCOP)Ir(I) and iridium(III) pincer complexes in the catalytic hydrogenolysis of silyl triflates into hydrosilanes Gabriel Durin , Jean-Claude Berthet , Emmanuel Nicolas , Thibault Cantat Organometallics, 2021, 2021 (41), pp.1786-1796. ⟨10.1021/acs.organomet.1c00576⟩ Journal articles cea-03547778v1
	Catalytic challenges and strategies for the carbonylation of $\sigma$-bonds Tawfiq Nasr Allah , Louise Ponsard , Emmanuel Nicolas , Thibault Cantat Green Chemistry, 2021, 23, pp.723-739. ⟨10.1039/d0gc02343d⟩ Journal articles cea-03096007v1
	Copper–Ligand Cooperativity in H 2 Activation Enables the Synthesis of Copper Hydride Complexes Alicia Aloisi , Étienne Crochet , Emmanuel Nicolas , Jean-Claude Berthet , Camille Lescot Organometallics, 2021, 40 (13), pp.2064-2069. ⟨10.1021/acs.organomet.1c00212⟩ Journal articles hal-03432183v1
	A copper(I)‐catalyzed sulfonylative Hiyama cross‐coupling Aurélien Adenot , Lucile Anthore-Dalion , Emmanuel Nicolas , Jean-Claude Berthet , Pierre Thuéry Chemistry - A European Journal, 2021, 27 (72), pp.18047-18053. ⟨10.1002/chem.202103371⟩ Journal articles cea-03547768v1
	Additive-free formic acid dehydrogenation catalyzed by a cobalt complex Lentz Nicolas , Alicia Aloisi , Pierre Thuéry , Emmanuel Nicolas , Thibault Cantat Organometallics, 2021, 40 (5), pp.565-569. ⟨10.1021/acs.organomet.0c00777⟩ Journal articles cea-02933763v2
	Unlocking the catalytic hydrogenolysis of chlorosilanes into hydrosilanes with superbases Gabriel Durin , Jean-Claude Berthet , Emmanuel Nicolas , Thibault Cantat ACS Catalysis, 2021, 11 (17), pp.10855-10861. ⟨10.1021/acscatal.1c01515⟩ Journal articles cea-03547774v2
	Photocatalytic deoxygenation of N–O bonds with Rhenium complexes: from the reduction of nitrous oxide to pyridine N-oxides Marianne Kjellberg , Alexia Ohleier , Pierre Thuéry , Emmanuel Nicolas , Lucile Anthore-Dalion Chemical Science, 2021, 2021 (12), pp.10266-10272. ⟨10.1039/D1SC01974K⟩ Journal articles cea-03277737v2
	Coupling electrocatalytic CO2 reduction with thermocatalysis enables the formation of a lactone monomer Marc Fontecave , Louise Ponsard , Emmanuel Nicolas , Ngoc Huan Tran , Sarah Lamaison ChemSusChem, 2021, 14 (10), pp.2198-2204. ⟨10.1002/cssc.202100459⟩ Journal articles cea-03166022v1
	[(dcpp)Ni( η 2 -Arene)] Precursors: Synthesis, Reactivity, and Catalytic Application to the Suzuki–Miyaura Reaction Florian D’accriscio , Alexia Ohleier , Emmanuel Nicolas , Matthieu Demange , Olivier Thillaye Du Boullay Organometallics, 2020, 39 (10), pp.1688-1699. ⟨10.1021/acs.organomet.9b00834⟩ Journal articles hal-02911077v1
	Carbonylation of C-N Bonds in Tertiary Amines Catalyzed by Low Valent Iron Catalysts Tawfiq Nasr Allah , Solène Savourey , Jean-Claude Berthet , Emmanuel Nicolas , Thibault Cantat Angewandte Chemie International Edition, 2019, 58, pp.10884-10887. ⟨10.1002/anie.201903740⟩ Journal articles cea-02145076v1
	Catalytic Metal-Free Deoxygenation of Nitrous Oxide with Disilanes Lucile Anthore-Dalion , Emmanuel Nicolas , Thibault Cantat ACS Catalysis, 2019, 9, pp.11563-11567. ⟨10.1021/acscatal.9b04434⟩ Journal articles cea-02372787v1
	[4+2] versus [2+2] Homodimerization in P(V) Derivatives of 2,4-Disubstituted Phospholes Guillaume Bousrez , Emmanuel Nicolas , Agathe Martinez , Sylviane Chevreux , Florian Jaroschik Heteroatom Chemistry, 2019, 2019, pp.2596405. ⟨10.1155/2019/2596405⟩ Journal articles cea-02092318v1
	Synthesis, Characterization and Reactivity of Formal 20 Electron Zirconocene-Pentafulvene Complexes Florian Jaroschik , Manfred Penkhues , Bernard Bahlmann , Emmanuel Nicolas , Malte Fischer Organometallics, 2017, 36 (10), pp.2004-2013. ⟨10.1021/acs.organomet.7b00213⟩ Journal articles hal-01996040v1
	A Significant but Constrained Geometry Pt→Al Interaction: Fixation of CO 2 and CS 2 , Activation of H 2 and PhCONH 2 Marc Devillard , Richard Declercq , Emmanuel Nicolas , Andreas Ehlers , Jana Backs Journal of the American Chemical Society, 2016, 138 (14), pp.4917-4926. ⟨10.1021/jacs.6b01320⟩ Journal articles hal-03539232v1
	“(Diphosphine)Nickel”-Catalyzed Negishi Cross-Coupling: An Experimental and Theoretical Study Emmanuel Nicolas , Alexia Ohleier , Florian d'Accriscio , Anne-Frédérique Pécharman , Matthieu Demange Chemistry - A European Journal, 2015, 21 (21), pp.7690-7694 Journal articles hal-02001069v1
	Dative Au→Al Interactions: Crystallographic Characterization and Computational Analysis Marc Devillard , Emmanuel Nicolas , Andreas Ehlers , Jana Backs , Sonia Mallet-Ladeira Chemistry - A European Journal, 2015, 21 (1), pp.74-79. ⟨10.1002/chem.201405610⟩ Journal articles hal-03539254v1
	Ti-mediated intramolecular cyclopropanation of N-alkenyl thioamides: scope and mechanistic study Fabien Hermant , Emmanuel Nicolas , Yvan Six Tetrahedron, 2014, 70 (25), pp.3924-3930. ⟨10.1016/j.tet.2014.04.006⟩ Journal articles hal-01015278v1
	Reductive Alkylation of Thioamides with Grignard Reagents in the Presence of Ti(OiPr)4: Insight and Extension Fabien Hermant , Ewelina Urbańska , Sarah Seizilles de Mazancourt , Thomas Maubert , Emmanuel Nicolas Organometallics, 2014, 33 (20), pp.5643-5653. ⟨10.1021/om500603v⟩ Journal articles hal-01098819v1
	Novel zwitterionic complexes arising from the coordination of an ambiphilic phosphorus–aluminum ligand to gold Marc Devillard , Emmanuel Nicolas , Christian Appelt , Jana Backs , Sonia Mallet-Ladeira Chemical Communications, 2014, 50 (94), pp.14805-14808. ⟨10.1039/C4CC06992G⟩ Journal articles hal-03539248v1
	Reactivity differences between 2,4- and 2,5-disubstituted zirconacyclopentadienes: a highly selective and general approach to 2,4-disubstituted phospholes. Guillaume Bousrez , Florian Jaroschik , Agathe Martinez , Dominique Harakat , Emmanuel Nicolas Dalton Transactions, 2013, epub ahead of print. ⟨10.1039/c3dt51158h⟩ Journal articles hal-00839784v1
	CO Activation by (Diphosphane)platinum(0): Carbonate and Acetone Formation - Experimental and Mechanistic Study Nicolas Mézailles , Grégory Nocton , Emmanuel Nicolas European Journal of Inorganic Chemistry, 2013, 22-23, pp.4000-4007. ⟨10.1002/ejic.201300182⟩ Journal articles hal-00906325v1
	Room temperature reversible C-H activation mediated by a Pt(0) center, and stoichiometric biphenyl formation via solvent activation. Emmanuel Nicolas , X. F Le Goff , Stéphane Bouchonnet , Nicolas Mézailles Chemical Communications, 2012, 48 (67), pp.8350-2. ⟨10.1039/c2cc33847e⟩ Journal articles hal-00823000v1

	Catalytic carbonylation of acrylic acid to succinic anhydride: en route to the synthesis of a bio-based monomer Marie-Hélène Pietraru , Louise Ponsard , Nicolas Lentz , Emmanuel Nicolas , Thibault Cantat Symposium International sur la chimie durable (ISGC 2022), May 2022, La Rochelle, France Conference papers cea-03675178v1
	Photocatalytic deoxygenation of nitrogen oxide compounds Marianne Kjellberg , Emmanuel Nicolas , Lucile Anthore-Dalion , Alexia Ohleier , Annamaria Quaranta GECOM-CONCOORD 2022, May 2022, Sévrier, France Conference papers cea-03662299v1
	Photocatalytic deoxygenation of nitrogen oxide compounds Marianne Kjellberg , Annamaria Quaranta , Emmanuel Nicolas , Lucile Anthore-Dalion , Alexia Ohleier Symposium International sur la chimie durable (ISGC 2022), May 2022, La Rochelle, France Conference papers cea-03675180v1
	Catalytic carbonylation of acrylic acid to succinic anhydride: en route to the synthesis of a bio-based monomer Marie-Hélène Pietraru , Louise Ponsard , Nicolas Lentz , Emmanuel Nicolas , Thibault Cantat GreenCAt 2022 - 4th International Green Catalysis Symposium, Apr 2022, Rennes, France Conference papers cea-03654519v1

	A Combination of DFT and Spectroscopy Solves Photocatalytic Mechanisms: the Case of N-O bonds Emmanuel Nicolas , Marianne Kjellberg , Zineb El Moqaouil , Lucile Anthore-Dalion , Annamaria Quaranta DFT 2024, Aug 2024, Paris, France Conference poster hal-04689021v1
	Catalytic carbonylation of acrylic acid to succinic anhydride: en route to the synthesis of a bio-based monomer Marie-Hélène Pietraru , Louise Ponsard , Nicolas Lentz , Emmanuel Nicolas , Thibault Cantat Catalysis at the Energy - Chemistry Nexus 2022 Winter School, Mar 2022, Aussois, France. Conference poster cea-03654542v1
	Understanding the catalytic carbonylation of epoxides for the valorization of carbon monoxide Louise Ponsard , Emmanuel Nicolas , Thibault Cantat GECOM-CONCOORD 2019, May 2019, Erquy, France Conference poster cea-02339556v1
	Catalytic hydrogenolysis of silyl triflates to hydrosilanes using iridium pincer complexes Gabriel Durin , Jean-Claude Berthet , Emmanuel Nicolas , Pierre Thuéry , Thibault Cantat 12th International Scholl on Organometallic Chemistry “Marcial Moreno Mañas”, Jun 2019, Castellon, Spain Conference poster cea-02329217v1
	Formic acid disproportionation to methanol and CO$_2$ reduction Emmanuel Nicolas , Alicia Aloisi , Solene Savourey , Thibault Cantat GYSS@one-North, Jan 2018, Singapore, Singapore Conference poster cea-02339603v1
	To Bend or Not to Bend: Is CO2 Bending Required to Promote its Reduction? Emmanuel Nicolas , Niklas von Wolff , Thibault Cantat EuCOMC 2017, Jul 2017, Amsterdam, Netherlands Conference poster cea-02346348v1

	Metal-free catalytic hydrogenolysis of silyl triflates and halides into hydrosilanes Gabriel Durin , Albane Fontaine , Jean-Claude Berthet , Emmanuel Nicolas , Pierre Thuéry 2022 Preprints, Working Papers, ... cea-03540549v1
	The Role of (tBuPOCOP)Ir(I) and iridium(III) Pincer Complexes in the Catalytic Hydrogenolysis of Silyl Triflates into Hydrosilanes Gabriel Durin , Jean-Claude Berthet , Emmanuel Nicolas , Pierre Thuéry , Thibault Cantat 2021 Preprints, Working Papers, ... cea-03320572v1
	Copper-Ligand Cooperativity in H$_2$ Activation Enables the Synthesis of Copper Hydride Complexes Alicia Aloisi , Étienne Crochet , Emmanuel Nicolas , Jean-Claude Berthet , Camille Lescot 2021 Preprints, Working Papers, ... cea-03132894v1
	A copper(I)-catalyzed sulfonylative Hiyama cross-coupling Aurélien Adenot , Emmanuel Nicolas , Lucile Anthore-Dalion , Jean-Claude Berthet , Pierre Thuéry 2021 Preprints, Working Papers, ... cea-03284987v1

	Complexes de métaux réduits : Activation de liaisons C H et de petites molécules Emmanuel Nicolas Chimie inorganique. Ecole Polytechnique, 2013. Français. ⟨NNT : ⟩ Theses tel-01348272v1

	Petites Molécules pour la Chimie : Études Expérimentales et Théoriques Emmanuel Nicolas Catalyse. Université Paris-Saclay, 2024 Habilitation à diriger des recherches tel-04660760v1

Emmanuel Nicolas

Publications

Hydrogenolysis of haloboranes: from synthesis of hydroboranes to formal hydroboration reactions

Fluorophosphoniums as Lewis acids in organometallic catalysis: application to the carbonylation of β-lactones

Formoxyboranes as hydroborane surrogates for the catalytic reduction of carbonyls through transfer hydroboration

Production of methane by catalytic decarboxylation of methyl formate as a liquid surrogate

Direct Enthalpy Measurement for Hydrogenation of Liquid Organic Hydrogen Carriers by Differential Scanning Calorimetry under H2 Pressure

Fluorophosphoniums as Lewis acids in organometallic catalysis: application in cobalt-catalyzed carbonylation of β-lactones

Metal‐Free Catalytic Hydrogenolysis of Chlorosilanes into Hydrosilanes with “Inverse” Frustrated Lewis Pairs

Vers la synthèse de réducteurs renouvelables à base de silicium

Catalytic Carbonylation of Acrylic Acid to Succinic Anhydride

Evaluation of acetophenone as a novel alcohol-cycloalkane bifunctional liquid organic hydrogen carrier (LOHC)

Metal‐Free Catalytic Hydrogenolysis of Silyl Triflates and Halides into Hydrosilanes

The Role of ($^{tBu}$POCOP)Ir(I) and iridium(III) pincer complexes in the catalytic hydrogenolysis of silyl triflates into hydrosilanes

Catalytic challenges and strategies for the carbonylation of $\sigma$-bonds

Copper–Ligand Cooperativity in H 2 Activation Enables the Synthesis of Copper Hydride Complexes

A copper(I)‐catalyzed sulfonylative Hiyama cross‐coupling

Additive-free formic acid dehydrogenation catalyzed by a cobalt complex

Unlocking the catalytic hydrogenolysis of chlorosilanes into hydrosilanes with superbases

Photocatalytic deoxygenation of N–O bonds with Rhenium complexes: from the reduction of nitrous oxide to pyridine N-oxides

Coupling electrocatalytic CO2 reduction with thermocatalysis enables the formation of a lactone monomer

[(dcpp)Ni( η 2 -Arene)] Precursors: Synthesis, Reactivity, and Catalytic Application to the Suzuki–Miyaura Reaction

Carbonylation of C-N Bonds in Tertiary Amines Catalyzed by Low Valent Iron Catalysts

Catalytic Metal-Free Deoxygenation of Nitrous Oxide with Disilanes

[​4+2] versus [​2+2] Homodimerization in P(V) Derivatives of 2,4-Disubstituted Phospholes

Synthesis, Characterization and Reactivity of Formal 20 Electron Zirconocene-Pentafulvene Complexes

A Significant but Constrained Geometry Pt→Al Interaction: Fixation of CO 2 and CS 2 , Activation of H 2 and PhCONH 2

“(Diphosphine)Nickel”-Catalyzed Negishi Cross-Coupling: An Experimental and Theoretical Study

Dative Au→Al Interactions: Crystallographic Characterization and Computational Analysis

Ti-mediated intramolecular cyclopropanation of N-alkenyl thioamides: scope and mechanistic study

Reductive Alkylation of Thioamides with Grignard Reagents in the Presence of Ti(OiPr)4: Insight and Extension

Novel zwitterionic complexes arising from the coordination of an ambiphilic phosphorus–aluminum ligand to gold

Reactivity differences between 2,4- and 2,5-disubstituted zirconacyclopentadienes: a highly selective and general approach to 2,4-disubstituted phospholes.

CO Activation by (Diphosphane)platinum(0): Carbonate and Acetone Formation - Experimental and Mechanistic Study

Room temperature reversible C-H activation mediated by a Pt(0) center, and stoichiometric biphenyl formation via solvent activation.

Catalytic carbonylation of acrylic acid to succinic anhydride: en route to the synthesis of a bio-based monomer

Photocatalytic deoxygenation of nitrogen oxide compounds

Photocatalytic deoxygenation of nitrogen oxide compounds

Catalytic carbonylation of acrylic acid to succinic anhydride: en route to the synthesis of a bio-based monomer

A Combination of DFT and Spectroscopy Solves Photocatalytic Mechanisms: the Case of N-O bonds

Catalytic carbonylation of acrylic acid to succinic anhydride: en route to the synthesis of a bio-based monomer

Understanding the catalytic carbonylation of epoxides for the valorization of carbon monoxide

Catalytic hydrogenolysis of silyl triflates to hydrosilanes using iridium pincer complexes

Formic acid disproportionation to methanol and CO$_2$ reduction

To Bend or Not to Bend: Is CO2 Bending Required to Promote its Reduction?

Metal-free catalytic hydrogenolysis of silyl triflates and halides into hydrosilanes

The Role of (tBuPOCOP)Ir(I) and iridium(III) Pincer Complexes in the Catalytic Hydrogenolysis of Silyl Triflates into Hydrosilanes

Copper-Ligand Cooperativity in H$_2$ Activation Enables the Synthesis of Copper Hydride Complexes

A copper(I)-catalyzed sulfonylative Hiyama cross-coupling

Complexes de métaux réduits : Activation de liaisons C H et de petites molécules

Petites Molécules pour la Chimie : Études Expérimentales et Théoriques

[4+2] versus [2+2] Homodimerization in P(V) Derivatives of 2,4-Disubstituted Phospholes