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Eric Clot

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Assessing Combinations of B(C6F5)3 and N2-Derived Molybdenum Nitrido Complexes for Heterolytic Bond Activation

Anaïs Coffinet , David Specklin , Quentin Le Dé , Soukaina Bennaamane , Luna Muñoz
Chemistry - A European Journal, 2023, 29 (26), pp.e202203774. ⟨10.1002/chem.202203774⟩
Journal articles hal-04007916v1
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Chirogenesis in Zinc Porphyrins: Theoretical Evaluation of Electronic Transitions, Controlling Structural Factors and Axial Ligation

Irina Osadchuk , Riina Aav , Victor Borovkov , Eric Clot
ChemPhysChem, 2021, 22 (17), pp.1817-1833. ⟨10.1002/cphc.202100345⟩
Journal articles hal-03608689v1
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Supramolecular Chirogenesis in Bis-Porphyrin: Crystallographic Structure and CD Spectra for a Complex with a Chiral Guanidine Derivative

Irina Osadchuk , Nele Konrad , Khai-Nghi Truong , Kari Rissanen , Eric Clot
Symmetry, 2021, 13 (2), pp.275. ⟨10.3390/sym13020275⟩
Journal articles hal-03190913v1
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Impact of the Alkali Metal on the Structural and Dynamic Properties of the Anionic Pentahydride Ruthenium Complexes [M(THF) x ][RuH 5 (PCy 3 ) 2 ] (M = Li, Na, K)

Ramaraj Ayyappan , Koushik Saha , Mary Grellier , Eric Clot , Laure Vendier
Organometallics, 2021, 40 (17), pp.3024-3032. ⟨10.1021/acs.organomet.1c00384⟩
Journal articles hal-03357901v1
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Benchmarking computational methods and influence of guest conformation on chirogenesis in zinc porphyrin complexes

Irina Osadchuk , Victor Borovkov , Riina Aav , Eric Clot
Physical Chemistry Chemical Physics, 2020, 22 (19), pp.11025-11037. ⟨10.1039/d0cp00965b⟩
Journal articles hal-02617464v1
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Efficient alkene hydrosilation with bis(8-quinolyl)phosphine (NPN) nickel catalysts. The dominant role of silyl-over hydrido-nickel catalytic intermediates

Jian Yang , Verònica Postils , Michael Lipschutz , Meg Fasulo , Christophe Raynaud
Chemical Science, 2020, 11 (19), pp.5043-5051. ⟨10.1039/D0SC00997K⟩
Journal articles hal-02617107v1
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Stepwise Functionalization of N 2 at Mo: Nitrido to Imido to Amido - Factors Favoring Amine Elimination from the Amido Complex

Soukaina Bennaamane , Maria F Espada , Ikram Yagoub , Nathalie Saffon‐merceron , Noel Nebra
European Journal of Inorganic Chemistry, 2020, 2020 (15-16), pp.1499-1505. ⟨10.1002/ejic.201901295⟩
Journal articles hal-03012876v1
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Regiospecificity in Ligand-Free Pd-Catalyzed C–H Arylation of Indoles: LiHMDS as Base and Transient Directing Group

Yorck Mohr , Marc Renom-Carrasco , Clément Demarcy , Elsje Alessandra Quadrelli , Clément Camp
ACS Catalysis, 2020, 10 (4), pp.2713-2719. ⟨10.1021/acscatal.9b04864⟩
Journal articles hal-02493979v1
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Supramolecular chirogenesis in zinc porphyrins: Complexation with enantiopure thiourea derivatives, binding studies and chirality transfer mechanism

Nele Konrad , Darya Meniailava , Irina Osadchuk , Jasper Adamson , Mohammed Hasan
Journal of Porphyrins and Phthalocyanines, 2020, 24 (05n07), pp.840-849. ⟨10.1142/S108842461950192X⟩
Journal articles hal-02617498v1
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A Career in Catalysis: Odile Eisenstein

David Balcells , Eric Clot , Stuart Macgregor , Feliu Maseras , Lionel Perrin
ACS Catalysis, 2019, 9 (11), pp.10375-10388. ⟨10.1021/acscatal.9b02498⟩
Journal articles hal-03006418v1
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Aerobic and Ligand-Free Manganese-Catalyzed Homocoupling of Arenes or Aryl Halides via in Situ Formation of Aryllithiums

Yujia Liu , Julien Berges , Yassir Zaid , Fouad Ouazzani Chahdi , Arie van Der Lee
Journal of Organic Chemistry, 2019, 84 (7), pp.4413-4420. ⟨10.1021/acs.joc.8b02834⟩
Journal articles hal-02076372v1
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Dehydrogenative coupling of 4-substituted pyridines mediated by a zirconium(ii) synthon: reaction pathways and dead ends

Lukas Merz , Hubert Wadepohl , Eric Clot , Lutz Gade
Chemical Science, 2018, 9 (23), pp.5223-5232. ⟨10.1039/C8SC01025K⟩
Journal articles hal-01818339v1

Ta-Catalyzed Hydroaminoalkylation of Alkenes: Insights into Ligand-Modified Reactivity Using DFT

Damon Gilmour , Jean Michel P. Lauzon , Eric Clot , Laurel Schafer
Organometallics, 2018, 37 (23), pp.4387-4394. ⟨10.1021/acs.organomet.8b00674⟩
Journal articles hal-01966073v1

Selective mono N-methylation of anilines with methanol catalyzed by rhenium complexes: An experimental and theoretical study

Duo Wei , Omar Sadek , Vincent Dorcet , Thierry Roisnel , Christophe Darcel
Journal of Catalysis, 2018, 366, pp.300 - 309. ⟨10.1016/j.jcat.2018.08.008⟩
Journal articles hal-01871104v1

Isolation and structural characterization of a titanacyclopropane as key intermediate in the double aryl Grignard addition to 2-(arylethynyl)pyridine derivatives

Francesco Foschi , Torsten Roth , Markus Enders , Hubert Wadepohl , Eric Clot
Chemical Communications, 2018, 54 (18), pp.2228 - 2231. ⟨10.1039/c8cc00478a⟩
Journal articles hal-01718895v1

Domino Pd 0 -Catalyzed C(sp3)-H Arylation/Electrocyclic Reactions via Benzazetidine Intermediates

Ronan Rocaboy , David Dailler , Florian Zellweger , Markus Neuburger , Christophe Salomé
Angewandte Chemie International Edition, 2018, 57 (37), pp.12131-12135. ⟨10.1002/anie.201807097⟩
Journal articles hal-01874239v1

Room-Temperature Functionalization of N2 to Borylamine at a Molybdenum Complex

Maria Espada , Soukaina Bennaamane , Qian Liao , Nathalie Saffon-Merceron , Stephane Massou
Angewandte Chemie International Edition, 2018, 57 (39), pp.12865-12868. ⟨10.1002/anie.201805915⟩
Journal articles hal-01882704v1

Mild Decarboxylative C−H Alkylation: Computational Insights for Solvent-Robust Ruthenium(II) Domino Manifold

N. Y. Phani Kumar , Torben Rogge , Santhivardhana Reddy Yetra , Alexander Bechtoldt , Eric Clot
Chemistry - A European Journal, 2017, 23 (69), pp.17449 - 17453. ⟨10.1002/chem.201703680⟩
Journal articles hal-01661618v1
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A mechanochemical approach to access the proline–proline diketopiperazine framework

Nicolas Pétry , Hafid Benakki , Eric Clot , Pascal Retailleau , Farhate Guenoun
Beilstein Journal of Organic Chemistry, 2017, 13, pp.2169 - 2178. ⟨10.3762/bjoc.13.217⟩
Journal articles hal-01619861v1
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Hydrogenation of Carbonyl Derivatives with a Well-Defined Rhenium Precatalyst

Duo Wei , Thierry Roisnel , Christophe Darcel , Eric Clot , Jean-Baptiste Sortais
ChemCatChem, 2017, 9 (1), pp.80-83. ⟨10.1002/cctc.201601141⟩
Journal articles hal-01435008v1

Reactions of Titanium Imides and Hydrazides with Boranes

Simona Mellino , Laura C. Stevenson , Eric Clot , Philip Mountford
Organometallics, 2017, 36, pp.3329−3342. ⟨10.1021/acs.organomet.7b00477⟩
Journal articles hal-01585569v1

N-Heterocyclic Carbene Iron Silyl Hydride Complexes

S. Quintero-Duque , H. Li , L.C. Misal Castro , V. Dorcet , T. Roisnel
Israel Journal of Chemistry, 2017, 57 (12), pp.1216-1221. ⟨10.1002/ijch.201700122⟩
Journal articles hal-01713508v1

New Scandium Borylimido Chemistry: Synthesis, Bonding, and Reactivity

Benjamin A. Clough , Simona Mellino , Eric Clot , Philip Mountford
Journal of the American Chemical Society, 2017, 139, pp.11165-11183. ⟨10.1021/jacs.7b05405⟩
Journal articles hal-01583862v1

New Titanium Borylimido Compounds: Synthesis, Structure, and Bonding

Benjamin A. Clough , Simona Mellino , Andrey V. Protchenko , Martin Slusarczyk , Laura C. Stevenson
Inorganic Chemistry, 2017, 56, pp.10794-10814. ⟨10.1021/acs.inorgchem.7b01831⟩
Journal articles hal-01583859v1

Deciphering Selectivity in Organic Reactions: A Multifaceted Problem

David Balcells , Eric Clot , Odile Eisenstein , Ainara Nova , Lionel Perrin
Accounts of Chemical Research, 2016, 49 (5), pp.1070-1078. ⟨10.1021/acs.accounts.6b00099⟩
Journal articles hal-01316472v1

η6-Arene-Zirconium-PNP-Pincer Complexes: Mechanism of Their Hydrogenolytic Formation and Their Reactivity as Zirconium(II) Synthons

Gudrun T. Plundrich , Hubert Wadepohl , Eric Clot , Lutz H. Gade
Chemistry - A European Journal, 2016, 22, pp.9283-9292. ⟨10.1002/chem.201601213⟩
Journal articles hal-01338976v1

Reactions of Titanium Hydrazides with Silanes and Boranes: N–N Bond Cleavage and N Atom Functionalization

Laura C Stevenson , Simona Mellino , Eric Clot , Philip Mountford
Journal of the American Chemical Society, 2015, 137, pp.10140-10143. ⟨10.1021/jacs.5b06627⟩
Journal articles hal-01185849v1

A Highly Effective Ruthenium System for the Catalyzed Dehydrogenative Cyclization of Amine–Boranes to Cyclic Boranes under Mild Conditions

Christopher J. Wallis , Gilles Alcaraz , Alban S. Petit , Amalia I. Poblador-Bahamonde , Eric Clot
Chemistry - A European Journal, 2015, 21, pp.13080-13090. ⟨10.1002/chem.201501569⟩
Journal articles hal-01188456v1

Controlling the Selectivity of C−H Activation in Pyridinium Triazolylidene Iridium Complexes: Mechanistic Details and Influence of Remote Substituents

Kate F. Donnelly , Ralte Lalrempuia , Helge Müller-Bunz , Eric Clot , Martin Albrecht
Organometallics, 2015, 34, pp.858-869. ⟨10.1021/om501197g⟩
Journal articles hal-01138729v1

Efficient PdO-catalyzed asymmetric activation of primary and secondary C-H bonds enabled by modular binepine ligands and carbonate bases.

Philipp M. Holstein , Maria Vogler , Paolo Larini , Guillaume Pilet , Eric Clot
ACS Catalysis, 2015, 5, ⟨10.1021/acscatal.5b00898⟩
Journal articles hal-01412734v1

Azaphilic versus Carbophilic Coupling at C=N Bonds: Key Steps in Titanium-Assisted Multicomponent Reactions

Torsten Roth , Hubert Wadepohl , Eric Clot , Lutz H. Gade
Chemistry - A European Journal, 2015, 21 (18730–18738), ⟨10.1002/chem.201503732⟩
Journal articles hal-01241045v1

Mechanistic Study of the Selectivity of Olefin versus Cyclobutene Formation by Palladium(0)-Catalyzed Intramolecular C(sp3)–H Activation

Christos E. Kefalidis , Michaël Davi , Philipp M. Holstein , Eric Clot , Olivier Baudoin
Journal of Organic Chemistry, 2014, 79 (24), pp.11903-11910. ⟨10.1021/jo501610x⟩
Journal articles hal-01098139v1

B–C Bond Cleavage and Ru–C Bond Formation from a Phosphinoborane: Synthesis of a Bis-σ Borane Aryl-Ruthenium Complex

Audrey Cassen , Laure Vendier , Jean-Claude Daran , Amalia Poblador-Bahamonde , Eric Clot
Organometallics, 2014, 33, pp.7157-7163. ⟨10.1021/om500972f⟩
Journal articles hal-01098138v1

B-H, C-H, and B-C Bond Activation: The Role of Two Adjacent Agostic Interactions

Audrey Cassen , Yann Gloaguen , Laure Vendier , Carine Guyard-Duhayon , Amalia Poblador-Bahamonde
Angewandte Chemie International Edition, 2014, 53, pp.7569-7573. ⟨10.1002/anie.201404753⟩
Journal articles hal-01053546v1

Linear-Selective Hydroarylation of Unactivated Terminal and Internal Olefins with Trifluoromethyl-Substituted Arenes

Joseph S. Bair , York Schramm , Alexey G. Sergeev , Eric Clot , Odile Eisenstein
Journal of the American Chemical Society, 2014, 136, pp.13098−13101. ⟨10.1021/ja505579f⟩
Journal articles hal-01067932v1

Monosubstituted Borane Ruthenium Complexes RuH2(η2:η2-H2BR)(PR′3)2: A General Approach to the Geminal Bis(σ-B-H) Coordination Mode

Yann Gloaguen , Gaëtan Bénac-Lestrille , Laure Vendier , Ulrike Helmstedt , Eric Clot
Organometallics, 2013, 32, pp.4868-4877. ⟨10.1021/om400610k⟩
Journal articles hal-00859736v1

Synthesis, Bonding and Reactivity of a Terminal Titanium Alkylidene Hydrazido Compound

Pei-Jen Tiong , Laura R. Groom , Eric Clot , Philip Mountford
Chemistry - A European Journal, 2013, 19, pp.4198-4216. ⟨10.1002/chem.201203905⟩
Journal articles hal-00801630v1

Ligand-controlled β-selective C(sp3)-H arylation of N-Boc-piperidines

Anthony Millet , Paolo Larini , Eric Clot , Olivier Baudoin
Chemical Science, 2013, 4, pp.2241-2247. ⟨10.1039/C3SC50428J⟩
Journal articles hal-00807150v1

Synthesis and Reactions of a Cyclopentadienyl-Amidinate Titanium tert-Butoxyimido Compound

Laura R. Groom , Andrew Schwarz , Ainara Nova , Eric Clot , Philip Mountford
Organometallics, 2013, 32, pp.7520-7539. ⟨10.1021/om401008a⟩
Journal articles hal-00922814v1

Synthesis of a ruthenium bis(diisopropylamino(isocyano)borane) complex from the activation of an amino(cyano)borane

Maximilian Joost , Gilles Alcaraz , Laure Vendier , Amalia Poblador-Bahamonde , Eric Clot
Dalton Transactions, 2013, 42, pp.776-781. ⟨10.1039/C2DT32274A⟩
Journal articles hal-00764430v1

On the mechanism of the palladium-catalyzed β-arylation of ester enolates.

Paolo Larini , Christos E. Kefalidis , Rodolphe Jazzar , Alice Renaudat , Eric Clot
Chemistry - A European Journal, 2012, 18 (7), pp.1932-44. ⟨10.1002/chem.201103153⟩
Journal articles hal-00691404v1

Hydride Ligands Make the Difference: Density Functional Study of the Mechanism of the Murai Reaction Catalyzed by [Ru(H)2(H2)2(PR3)2] (R=cyclohexyl)

Ulrike Helmstedt , Eric Clot
Chemistry - A European Journal, 2012, 18, pp.11449-11458. ⟨10.1002/chem.201200757⟩
Journal articles hal-00725864v1

Site selectivity and reversibility in the reactions of titanium hydrazides with Si-H, Si-X, C-X and H+ reagents: Ti[double bond, length as m-dash]Nα 1,2-silane addition, Nβ alkylation, Nα protonation and σ-bond metathesis

Pei-Jen Tiong , Ainara Nova , Andrew Schwarz , Jonathan D. Selby , Eric Clot
Dalton Transactions, 2012, 41, pp.2277-2288. ⟨10.1039/C2DT12359B⟩
Journal articles hal-00668164v1

Si–H and Si–Cl bond activation reactions of titanium hydrazides with silanes and subsequent Ti–H/E–H (E = Si or H) σ-bond metathesis

Pei-Jen Tiong , Ainara Nova-Flores , Eric Clot , Philip Mountford
Chemical Communications, 2011, 47, pp.3147-3149. ⟨10.1039/c0cc05165a⟩
Journal articles hal-00575214v1

Reaction site diversity in the reactions of titanium hydrazides with organic nitriles, isonitriles and isocyanates: Ti=Nα cycloaddition, Ti=Nα insertion and Nα-Nβ bond cleavage

A. Daniel Schofield , Ainara Nova-Flores , Jonathan D. Selby , Andrew D. Schwarz , Eric Clot
Chemistry - A European Journal, 2011, 17, pp.265-285. ⟨10.1002/chem.201002776⟩
Journal articles hal-00552889v1

Ruthenium agostic (phosphinoaryl)borane complexes: multinuclear solid-state and solution NMR, X-ray and DFT studies

Yann Gloaguen , Gilles Alcaraz , Alban Petit , Eric Clot , Yannick Coppel
Journal of the American Chemical Society, 2011, 133, pp.17232-17238. ⟨10.1021/ja203828r⟩
Journal articles hal-00637828v1

Dimethylaminoborane (H2BNMe2) coordination to late transition metal centers: snapshots of the B-H oxidative addition process

Gaëtan Bénac-Lestrille , Ulrike Helmstedt , Laure Vendier , Gilles Alcaraz , Eric Clot
Inorganic Chemistry, 2011, 50, pp.11039-11045. ⟨10.1021/ic201573q⟩
Journal articles hal-00637829v1

Reactions of Cyclopentadienyl-Amidinate Titanium Hydrazides with CO2, CS2, and Isocyanates: Ti=Nα Cycloaddition, Cycloaddition-Insertion, and Cycloaddition-NNR2 Group Transfer Reactions

Pei-Jen Tiong , Ainara Nova-Flores , Laura R. Groom , Andrew D. Schwarz , Jonathan D. Selby
Organometallics, 2011, 30, pp.1182-1201. ⟨10.1021/om101167p⟩
Journal articles hal-00575216v1

Titanium alkoxyimido (Ti=N-OR) complexes: reductive N-O bond cleavage at the boundary between hydrazide and peroxide ligands

Andrew D. Schwarz , Ainara Nova-Flores , Eric Clot , Philip Mountford
Chemical Communications, 2011, 47, pp.4926-4928. ⟨10.1039/c1cc10862j⟩
Journal articles hal-00586606v1

Titanium tert-Butoxyimido Compounds

Andrew Schwarz , Ainara Nova , Eric Clot , Philip Mountford
Inorganic Chemistry, 2011, 50, pp.12155-12171. ⟨10.1021/ic201896q⟩
Journal articles hal-00646018v1

New Sandwich and Half-Sandwich Titanium Hydrazido Compounds

Jonathan D. Selby , Marta Feliz , Andrew D. Schwarz , Eric Clot , Philip Mountford
Organometallics, 2011, 30, pp.2295-2307. ⟨10.1021/om200068k⟩
Journal articles hal-00586609v1

C−F and C−H Bond Activation of Fluorobenzenes and Fluoropyridines at Transition Metal Centers: How Fluorine Tips the Scales

Eric Clot , Odile Eisenstein , Naseralla Jasim , Stuart A Macgregor , John E. Macgrady
Accounts of Chemical Research, 2011, 44, pp.333-348. ⟨10.1021/ar100136x⟩
Journal articles hal-00593720v1

Mechanistic investigation of vinylic carbon–fluorine bond activation of perfluorinated cycloalkenes using Cp*2ZrH2 and Cp*2ZrHF

Bradley M. Kraft , Eric Clot , Odile Eisenstein , William W. Brennessel , William D. Jones
Journal of Fluorine Chemistry, 2010, 131, pp.1122-1132. ⟨10.1016/j.jfluchem.2010.05.003⟩
Journal articles hal-00531501v1

M═Nα Cycloaddition and Nα−Nβ Insertion in the Reactions of Titanium Hydrazido Compounds with Alkynes: A Combined Experimental and Computational Study

A. Daniel Schofield , Ainara Nova-Flores , Jonathan D. Selby , Catherine D. Manley , Andrew D. Schwarz
Journal of the American Chemical Society, 2010, 132, pp.10484-10497. ⟨10.1021/ja1036513⟩
Journal articles hal-00506947v1

Synthesis, structure, and reductive elimination in the series Tp′Rh(PR3)(ArF)H; Determination of rhodium–carbon bond energies of fluoroaryl substituents

Taro Tanabe , William W. Brennessel , Eric Clot , Odile Eisenstein , William D. Jones
Dalton Transactions, 2010, 39, pp.10495-10509. ⟨10.1039/C0DT00157K⟩
Journal articles hal-00530408v1

Importance of palladium–carbon bond energies in direct arylation of polyfluorinated benzenes

Julie Guihaume , Eric Clot , Odile Eisenstein , Robin N. Perutz
Dalton Transactions, 2010, 39, pp.10510-10519. ⟨10.1039/C0DT00296H⟩
Journal articles hal-00530410v1

C-H bond activation in transition metal species from a computational perspective

David Balcells , Eric Clot , Odile Eisenstein
Chemical Reviews, 2010, 110, pp.749-823. ⟨10.1021/cr900315k⟩
Journal articles hal-00455818v1

Palladium-catalyzed β arylation of carboxylic esters.

Alice Renaudat , Ludivine Jean-Gérard , Rodolphe Jazzar , Christos E. Kefalidis , Eric Clot
Angewandte Chemie International Edition, 2010, 49 (40), pp.7261-5. ⟨10.1002/anie.201003544⟩
Journal articles hal-00691422v1

Single and double substrate insertion into the Ti=Nα bonds of terminal titanium hydrazides

Pei-Jen Tiong , A. Daniel Schofield , Jonathan D. Selby , Ainara Nova , Eric Clot
Chemical Communications, 2010, pp.85-87. ⟨10.1039/b920090h⟩
Journal articles hal-00440776v1

Ruthenium bis(σ-B-H) aminoborane complexes from dehydrogenation of amine-boranes: trapping of H2B-NH2

Gilles Alcaraz , Laure Vendier , Eric Clot , Sylviane Sabo-Etienne
Angewandte Chemie International Edition, 2010, 49, pp.918-920. ⟨10.1002/anie.200905970⟩
Journal articles hal-00449215v1

Ruthenium, Rhodium, and Iridium Bis(σ-B−H) Diisopropylaminoborane Complexes†

Gilles Alcaraz , Adrian B. Chaplin , Charlotte J. Stevens , Eric Clot , Laure Vendier
Organometallics, 2010, 29, pp.5591-5595. ⟨10.1021/om1004995⟩
Journal articles hal-00531506v1

Intramolecular palladium-catalyzed alkane C-H arylation from aryl chlorides.

Sophie Rousseaux , Michaël Davi , Julien Sofack-Kreutzer , Cathleen Pierre , Christos E. Kefalidis
Journal of the American Chemical Society, 2010, 132 (31), pp.10706-16. ⟨10.1021/ja1048847⟩
Journal articles hal-00691425v1

DFT study of the mechanism of benzocyclobutene formation by palladium-catalysed C(sp3)-H activation: role of the nature of the base and the phosphine.

Christos E. Kefalidis , Olivier Baudoin , Eric Clot
Dalton Transactions, 2010, 39 (43), pp.10528-35. ⟨10.1039/c0dt00578a⟩
Journal articles hal-00691421v1

Diels–Alder reaction of vinylene carbonate and 2,5-dimethylfuran: kinetic vs. thermodynamic control

Céline Taffin , Glenda Kreutler , Damien Bourgeois , Eric Clot , Christian Perigaud
New Journal of Chemistry, 2010, 34, pp.517-525. ⟨10.1039/b9nj00536f⟩
Journal articles hal-00461208v1

Energetics of C-H Bond Activation of Fluorinated Aromatic Hydrocarbons Using a [Tp'Rh(CNneopentyl)] Complex

Meagan E. Evans , Catherine L. Burke , Sornanong Yaibuathes , Eric Clot , Odile Eisenstein
Journal of the American Chemical Society, 2009, 131, pp.13464-13473. ⟨10.1021/ja905057w⟩
Journal articles hal-00417808v1

Synthesis and structure of "16-electron" rhodium(III) catalysts for transfer hydrogenation of a cyclic imine: mechanistic implications

A. John Blacker , Eric Clot , Simon B. Duckett , Odile Eisenstein , Jake Grace
Chemical Communications, 2009, pp.6801-6803. ⟨10.1039/b912943j⟩
Journal articles hal-00429572v1

Self-aggregation tendency of all species involved in the catalytic cycle of bifunctional transfer hydrogenation

Gianluca Ciancaleoni , Cristiano Zuccaccia , Daniele Zuccaccia , Eric Clot , Alceo Macchioni
Organometallics, 2009, 28, pp.960-967. ⟨10.1021/om8009552⟩
Journal articles hal-00361659v1

Ion-Pairing in Organometallic Chemistry: Structure and Influence on Proton Transfer from a Computational Perspective

Eric Clot
European Journal of Inorganic Chemistry, 2009, pp.2319-2328. ⟨10.1002/ejic.200900151⟩
Journal articles hal-00382219v1

Exceptional Sensitivity of Metal-Aryl Bond Energies to ortho-Fluorine Substituents: Influence of the Metal, the Coordination Sphere, and the Spectator Ligands on M-C/H-C Bond Energy Correlations.

Eric Clot , Claire Mégret , Odile Eisenstein , Robin N. Perutz
Journal of the American Chemical Society, 2009, 131, pp.7817-7827. ⟨10.1021/ja901640m⟩
Journal articles hal-00391067v1

Reactions of cyclopentadienyl-amidinate titanium imido compounds with CO2: cycloaddition-extrusion vs. cycloaddition-insertion

Aldo E. Guiducci , Catherine L. Boyd , Eric Clot , Philip Mountford
Dalton Transactions, 2009, pp.5960-5979. ⟨10.1039/b901774g⟩
Journal articles hal-00382217v1

Phosphinoborane and sulfidoborohydride as chelating ligands in polyhydride ruthenium complexes: agostic σ-borane versus dihydroborate coordination

Yann Gloaguen , Gilles Alcaraz , Anne-Frédérique Pécharman , Eric Clot , Laure Vendier
Angewandte Chemie International Edition, 2009, 48, pp.2964-2968. ⟨10.1002/anie.200806178⟩
Journal articles hal-00371725v1

A terminal borylene ruthenium complex: from B-H activation to reversible hydrogen release

Gilles Alcaraz , Ulrike Helmstedt , Eric Clot , Laure Vendier , Sylviane Sabo-Etienne
Journal of the American Chemical Society, 2008, 130, pp.12878-12879. ⟨10.1021/ja805164n⟩
Journal articles hal-00321855v1

A NMR, X-ray, and DFT combined study on the regio-chemistry of nucleophilic addition to platinium(II) coordinated terminal olefins

Carmen R. Barone , Renzo Cini , Eric Clot , Odile Eisenstein , Luciana Maresca
Journal of Organometallic Chemistry, 2008, 693, pp.2819. ⟨10.1016/j.jorganchem.2008.05.040⟩
Journal articles hal-00308918v1

β-H transfer from the metallacyclobutane: a key step in the deactivation and byproduct formation for the well-defined silica-supported rhenium alkylidene alkene metathesis catalyst

Anne-Marie Leduc , Alain Salameh , Daravong Soulivong , Mathieu Chabanas , Jean-Marie Basset
Journal of the American Chemical Society, 2008, 130, pp.6288-6297. ⟨10.1021/ja800189a⟩
Journal articles hal-00277664v1

Cycloaddition reactions of transition metal hydrazides with alkynes and heteroalkynes: coupling of Ti=NNPh2 with PhCCMe, PhCCH, MeCN and tBuCP

Jonathan D. Selby , Christian Schulten , Andrew D. Schwarz , Andreas Stasch , Eric Clot
Chemical Communications, 2008, pp.5101-5103. ⟨10.1039/b813911c⟩
Journal articles hal-00321857v1

Syntheses, Reactivity and DFT Studies of Group 2 and Group 12 Metal Complexes of Tris(pyrazolyl)methanides Featuring "Free" Pyramidal Carbanions

Helen R. Bigmore , Jens Meyer , Ivo Krummenacher , Heinz Rüegger , Eric Clot
Chemistry - A European Journal, 2008, 14, pp.5918. ⟨10.1002/chem.200800181⟩
Journal articles hal-00308915v1

A weak donor, planar chelating bitriazole N-heterocyclic carbene ligand for ruthenium(II), palladium(II), and rhodium

Macarena Poyatos , William Mcnamara , Chris Incarvito , Eric Clot , Eduardo Peris
Organometallics, 2008, 27, pp.2128-2136. ⟨10.1021/om800021c⟩
Journal articles hal-00276099v1

Stereochemical nonrigidity of a chiral rhodium boryl hydride complex: a σ-borane complexe as transition state for isomerization.

Marius V. Campian , Eric Clot , Odile Eisenstein , Ulrike Helmstedt , Naseralla Jasim
Journal of the American Chemical Society, 2008, 130, pp.4375-4385. ⟨10.1021/ja077357o⟩
Journal articles hal-00267313v1

Synthesis, DFT Studies, and Reactions of Scandium and Yttrium Dialkyl Cations Containing Neutral fac-N3 and fac-S3 Donor Ligands

Cara S. Tredget , Eric Clot , Philip Mountford
Organometallics, 2008, 27, pp.3458. ⟨10.1021/om800279d⟩
Journal articles hal-00308912v1

Ti=NR vs. Ti-R' functional group selectivity in imido titanium alkyl cations from a DFT perspective

Marta Feliz , Paul Bolton , Philip Mountford , Eric Clot
Organometallics, 2008, 27, pp.6111-6122. ⟨10.1021/om8007103⟩
Journal articles hal-00321859v1

Synthesis of benzocyclobutenes by palladium-catalyzed C-H activation of methyl groups: method and mechanistic study

Manon Chaumontet , Riccardo Piccardi , Nicolas Audic , Julien Hitce , Jean-Louis Peglion
Journal of the American Chemical Society, 2008, 130, pp.15157-15166. ⟨10.1021/ja805598s⟩
Journal articles hal-00321861v1

Mechanism of Homogeneous Iridium-Catalyzed Alkylation of Amines with Alcohols from a DFT Study

David Balcells , Ainara Nova , Eric Clot , Dinakar Gnanamgari , Robert H. Crabtree
Organometallics, 2008, 27, pp.2529. ⟨10.1021/om800134d⟩
Journal articles hal-00284001v1

Dynamics of silica-supported catalysts determined by combining solid-state NMR spectroscopy and DFT calculations

Frédéric Blanc , Jean-Marie Basset , Christophe Copéret , Amritanshu Sinha , Zachary J. Tonzetich
Journal of the American Chemical Society, 2008, 130, pp.5886-5900. ⟨10.1021/ja077749v⟩
Journal articles hal-00276844v1

Titanium hydrazides supported by diamide-amine and related ligands: a combined experimental and DFT study

Jonathan D. Selby , Catherine D. Manley , Andrew D. Schwarz , Eric Clot , Philip Mountford
Organometallics, 2008, 27, pp.6479-6494. ⟨10.1021/om8007597⟩
Journal articles hal-00321856v1

Ti=NR vs. Ti-R' functional group selectivity in imido titanium alkyl cations from an experimental perspective

Paul Bolton , Marta Feliz , Andrew R. Cowley , Eric Clot , Philip Mountford
Organometallics, 2008, 27, pp.6096-6110. ⟨10.1021/om800709f⟩
Journal articles hal-00321860v1

Aliphatic versus Aromatic C-H Activation in the Formation of Abnormal Carbenes with Iridium: A Combined Experimental and Theoretical Study

Monica Viciano , Marta Feliz , Rosa Corberan , Jose A. Mata , Eric Clot
Organometallics, 2007, 26, pp.5304-5314. ⟨10.1021/om7006979⟩
Journal articles hal-00175178v1

Imidazolium Carboxylates as Versatile and Selective N-Heterocyclic Carbene Transfer Agents: Synthesis, Mechanism, and Applications

Adelina M. Voutchkova , Marta Feliz , Eric Clot , Odile Eisenstein , Robert H. Crabtree
Journal of the American Chemical Society, 2007, 129, pp.0000-0000. ⟨10.1021/ja0742885⟩
Journal articles hal-00175629v1

Computational structure–activity relationships in H2 storage: how placement of N atoms affects release temperatures in organic liquid storage materials

Eric Clot , Odile Eisenstein , Robert H. Crabtree
Chemical Communications, 2007, pp.2231-2233. ⟨10.1039/b705037b⟩
Journal articles hal-00166201v1

Structural and dynamic properties of propane coordinated to TpRh(CNR) from a confrontation between theory and experiment

Eric Clot , Odile Eisenstein , William D. Jones
Proceedings of the National Academy of Sciences of the United States of America, 2007, 104 (17), pp.6939-6944. ⟨10.1073/pnas.0609454104⟩
Journal articles hal-00143621v1

Mesitylborane as a Bis σ-B-H Ligand: An Unprecedented Bonding Mode to a Metal Center

Gilles Alcaraz , Eric Clot , Ulrike Helmstedt , Laure Vendier , Sylviane Sabo-Etienne
Journal of the American Chemical Society, 2007, 129, pp.8704-8705. ⟨10.1021/ja0733538⟩
Journal articles hal-00166205v1

Agostic interaction and intramolecular proton transfer from the protonation of dihydrogen ortho metalated ruthenium complexes

Andrew Toner , Jochen Matthes , Stephan Gründemann , Hans-Heinrich Limbach , Bruno Chaudret
Proceedings of the National Academy of Sciences of the United States of America, 2007, 104 (17), pp.6945-6950. ⟨10.1073/pnas.0608979104⟩
Journal articles hal-00143626v1

Interionic Structure of Ion Pairs and Ion Quadruples of Half-Sandwich Ruthenium(II) Salts Bearing -Diimine Ligands

Daniele Zuccaccia , Gianfranco Bellachioma , Giuseppe Cardaci , Gianluca Ciancaleoni , Cristiano Zuccaccia
Organometallics, 2007, 26, pp.3930-3946. ⟨10.1021/om7003157⟩
Journal articles hal-00166212v1

New ligand platforms for developing the chemistry of the Ti=N–NR2 functional group and the insertion of alkynes into the N–N bond of a Ti=N–NPh2 ligand

Jonathan D. Selby , Catherine D. Manley , Marta Feliz , Andrew D. Schwarz , Eric Clot
Chemical Communications, 2007, pp.4937-4939. ⟨10.1039/b711941k⟩
Journal articles hal-00174438v1

Understanding d0-Olefin Metathesis Catalysts: Which Metal, Which Ligands?

Albert Poater , Xavier Solans-Monfort , Eric Clot , Christophe Copéret , Odile Eisenstein
Journal of the American Chemical Society, 2007, 129, pp.8207-8216. ⟨10.1021/ja070625y⟩
Journal articles hal-00178673v1

Carbonyl(...)carbonyl interactions in first-row transition metal complexes

Hazel A. Sparkes , Paul R. Raithby , Eric Clot , Gregory P. Shields , James A. Chisholm
CrystEngComm, 2006, 8, pp.563-570. ⟨10.1039/B607531M⟩
Journal articles hal-00362456v1

AlMe3 and ZnMe2 adducts of a titanium imido methyl cation: A combined crystallographic, spectroscopic, and DFT study

Paul D. Bolton , Eric Clot , Andrew R. Cowley , Philip Mountford
Journal of the American Chemical Society, 2006, 128, pp.15005-15018. ⟨10.1021/ja065638a⟩
Journal articles hal-00362453v1

Experimental and DFT studies of cationic imido titanium alkyls: Agostic interactions and C-H bond and solvent activation reactions of isolobal analogues of group 4 metallocenium cations

Paul D. Bolton , Eric Clot , Nico Adams , Stuart R. Dubberley , Andrew R. Cowley
Organometallics, 2006, 25, pp.2806-2825. ⟨10.1021/om060096r⟩
Journal articles hal-00362463v1

Synthesis and ethylene polymerization capability of metallocene-like imido titanium dialkyl compounds and their reactions with AliBu3

Paul D. Bolton , Nico Adams , Eric Clot , Andrew R. Cowley , Paul J. Wilson
Organometallics, 2006, 25, pp.5549-5565. ⟨10.1021/om0606136⟩
Journal articles hal-00362455v1

Validation of the M-C/H-C bond enthalpy relationship through application of density functional theory

Eric Clot , Claire Mégret , Odile Eisenstein , Robin N. Perutz
Journal of the American Chemical Society, 2006, 128, pp.8350-8357. ⟨10.1021/ja061803a⟩
Journal articles hal-00362457v1

DFT calculations of d0 M(NR)(CHtBu)(X)(Y) (M = Mo, W; R = CPh3, 2,6-iPr-C6H3; X and Y=CH2tBu, OtBu, OSi(OtBu)3) olefin metathesis catalysts: structural, spectroscopic and electronic properties

Albert Poater , Xavier Solans-Monfort , Eric Clot , Christophe Copéret , Odile Eisenstein
Dalton Transactions, 2006, pp.3077-3087. ⟨10.1039/b604481f⟩
Journal articles hal-00362460v1

Selectivity in C-Cl Bond Activation of Dichloroarenes by the Photogenerated Cp*Re(CO)2 Fragment: Combined Experimental and DFT Studies

A. Aballay , E. Clot , O. Eisenstein , M. T. Garland , F. Godoy
New Journal of Chemistry, 2005, 29, pp.226
Journal articles hal-00020404v1

Reactions of Neutral and Cationic Diamide-Supported Imido Complexes with CO2 and Other Heterocumulenes: Issues of Site Selectivity

B. D. Ward , G. Orde , E. Clot , A. R. Cowley , L. H. Gade
Organometallics, 2005, 24, pp.2368
Journal articles hal-00020394v1

d0 Re-based olefin metathesis catalysts, Re(≡CR)(=CHR)(X)(Y): the key role of X and Y ligands for efficient active sites

X. Solans-Monfort , E. Clot , C. Copéret , O. Eisenstein
Journal of the American Chemical Society, 2005, 127, pp.14015
Journal articles hal-00020388v1

Structure and reactivity of trans-bis[2-(2-chloroethyl)pyridine]palladium chloride (1). A study on the elimination reaction with 1 and 2-(2-chloroethyl)pyridine induced by quinuclidine in acetonitrile"

S. Alunni , G. Bellachioma , E. Clot , T. del Giacco , L. Ottavi
Journal of Organometallic Chemistry, 2005, 70, pp.10688
Journal articles hal-00020383v1

Understanding Structural and Dynamic Properties of Well-Defined Re-Based Olefin Metathesis Catalysts, Re(≡CR)(=CHR)(X)(Y) from DFT and QM/MM Calculations

X. Solans-Monfort , E. Clot , C. Copéret , O. Eisenstein
Organometallics, 2005, 24, pp.1586
Journal articles hal-00020396v1

Well-defined imidotitanium alkyl cations: agostic interactions, migratory insertion vs. [2+2] cycloaddition, and the first structurally authenticated AlMe3 adduct of any transition metal alkyl cation

P. Bolton , E. Clot , A. R. Cowley , P. Mountford
Chemical Communications, 2005, 3313, pp.3313
Journal articles hal-00020390v1

Aggregation in Solution of Neutral Half-sandwich Ru(II) Precatalysts for Transfer Hydrogenation

D. Zuccaccia , E. Clot , A. Macchioni
New Journal of Chemistry, 2005, 29, pp.430
Journal articles hal-00020402v1

An anion-dependent switch in selectivity results from a change of C-H activation mechanism in the reaction of an imidazolium salt with IrH5(PPh3)2

L. N. Appelhans , D. Zuccaccia , A. Kovacevic , A. Chianese , J. Miecznikowski
Journal of the American Chemical Society, 2005, 127, pp.16299
Journal articles hal-00020386v1

Pendant Arm Functionalized Benzamidinate Titanium Imido Compounds: Experimental and Computational Studies of their Reactions with CO2

C. L. Boyd , E. Clot , A. E. Guiducci , P. Mountford
Organometallics, 2005, 24, pp.2347
Journal articles hal-00020398v1

Is the allylpalladium structure altered between solid and solutions?

Eric Clot , Odile Eisenstein , Tsu-Chien Weng , James Penner-Hahn , Kenneth G. Caulton
Journal of the American Chemical Society, 2004, 126, pp.9079-9084. ⟨10.1021/ja049091g⟩
Journal articles hal-00429078v1

Synthesis, reactivity, and computational studies of the cationic tungsten methyl complex [W(NPh)(N2Npy)Me]+ and related compounds (N2Npy = MeC(2-C5H4N)(CH2(NSiMe3)2)

Benjamin D. Ward , Gavin Orde , Eric Clot , Andrew R. Cowley , Lutz H. Gade
Organometallics, 2004, 23, pp.4444-4461. ⟨10.1021/om049701l⟩
Journal articles hal-00429075v1

Double geminal C-H activation and reversible α-elimination in 2-aminopyridine iridium(III) complexes: The role of hydrides and solvent in flattening the free energy surface

Eric Clot , Junyi Chen , Dong-Heon Lee , So Young Sung , Leah N. Appelhans
Journal of the American Chemical Society, 2004, 126, pp.8795-8804. ⟨10.1021/ja048473j⟩
Journal articles hal-00429085v1

Defluorination of perfluoropropene using Cp*2ZrH2 and Cp*2ZrHF: A mechanism investigation from a joint experimental-theoretical perspective

Eric Clot , Claire Mégret , Bradley M. Kraft , Odile Eisenstein , William D. Jones
Journal of the American Chemical Society, 2004, 126, pp.5647-5653. ⟨10.1021/ja0499243⟩
Journal articles hal-00429087v1

Agostic interactions from a computational perspective: One name, many interpretations

Eric Clot , Odile Eisenstein
Structure and Bonding, 2004, 113, pp.1-36. ⟨10.1007/b97940⟩
Journal articles hal-00429065v1

Ortho-metalated ruthenium hydrido dihydrogen complexes: Dynamics, exchange couplings, and reactivity

Jochen Matthes , Stephan Gründemann , Andrew Toner , Yannick Guari , Bruno Donnadieu
Organometallics, 2004, 23, pp.1424-1433. ⟨10.1021/om034259c⟩
Journal articles hal-00429089v1

Ion pairing effects in intramolecular heterolytic H2 activation in an Ir(III) complex: a combined theoretical/experimental study

Karine Gruet , Eric Clot , Odile Eisenstein , Dong-Heon Lee , Ben Patel
New Journal of Chemistry, 2003, 27, pp.80-87. ⟨10.1039/b207339k⟩
Journal articles hal-00429096v1

Bond energy M-C/H-C correlations: dual theoretical and experimental approach to the sensitivity of M-C bond strength to substituents

Eric Clot , Maria Besora , Feliu Maseras , Claire Mégret , Odile Eisenstein
Chemical Communications, 2003, pp.490-491. ⟨10.1039/b210036n⟩
Journal articles hal-00429095v1

cis-trans isomerisation of CpRe(CO)2(H)(Ar-F) (Ar-F = C6FnH5-n; n=0-5) is the rate determining step in C-H activation of fluoroarenes: a DFT study

Eric Clot , Beatriz Oelckers , Hugo A. Klahn , Odile Eisenstein , Robin N. Perutz
Dalton Transactions, 2003, pp.4065-4074. ⟨10.1039/b305064e⟩
Journal articles hal-00429090v1

PGSE and NOE NMR evidence for higher order aggregation in some cationic ruthenium complexes in both protic and aprotic solvents

Daniele Zuccaccia , Stefano Sabatini , Gianfranco Bellachioma , Giuseppe Cardaci , Eric Clot
Inorganic Chemistry, 2003, 42, pp.5465-5467. ⟨10.1021/ic034549l⟩
Journal articles hal-00429091v1

Biscarbene-Ruthenium Complexes in Catalysis: Novel Stereoselective Synthesis of (1E,3E)-1,4-Disubstituted-1,3-dienes via Head-to-Head Coupling of Terminal Alkynes and Addition of Carboxylic Acids

Jacques Le Paih , Florian Monnier , Sylvie Derien , Pierre H. Dixneuf , Eric Clot
Journal of the American Chemical Society, 2003, 125 (39), pp.11964 -11975. ⟨10.1021/ja0349554⟩
Journal articles hal-00164020v1

Outer sphere anion participation can modify the mechanism for conformer interconversion in Pd pincer complexes

John R. Miecznikowski , Stephan Gründemann , Martin Albrecht , Claire Mégret , Eric Clot
Dalton Transactions, 2003, pp.831-838. ⟨10.1039/b210784h⟩
Journal articles hal-00429094v1

Counter-ion effects switch ligand binding from C-2 to C-5 in kinetic carbenes formed from an imidazolium salt and IrH5(PPh3)2

A. Kovacevic , Stephan Gründemann , John R. Miecznikowski , Eric Clot , Odile Eisenstein
Chemical Communications, 2002, pp.2580-2581. ⟨10.1039/b207588c⟩
Journal articles hal-00429098v1

Interplay of weak interactions: An iridium(III) system with an agostic tert-butyl but a nonagostic isopropyl group

Eric Clot , Odile Eisenstein , Tiffany Dube , Jack W. Faller , Robert H. Crabtree
Organometallics, 2002, 21, pp.575-580. ⟨10.1021/om010802i⟩
Journal articles hal-00429099v1

Synthesis and reactivity of the imidotungsten methyl cation [W(N2Npy)(NPh)Me]+: CO2 adds to the W=NPh bond and does not insert into the W-Me bond

Benjamin D. Ward , Eric Clot , Stuart R. Dubberley , Lutz H. Gade , Philip Mountford
Chemical Communications, 2002, pp.2618-2619. ⟨10.1039/b208327b⟩
Journal articles hal-00429097v1

How hydrogen bonding affects ligand binding and fluxionality in transition metal complexes: a DFT study on interligand hydrogen bonds involving HF and H2O

Eric Clot , Odile Eisenstein , Robert H. Crabtree
New Journal of Chemistry, 2001, 25, pp.66-72. ⟨10.1039/b006829m⟩
Journal articles hal-00429105v1

Computed ligand electronic parameters, from quantum chemistry and their relation to Tolman parameters, Lever parameters, and Hammett constants

Lionel Perrin , Eric Clot , Odile Eisenstein , Jennifer Loch , Robert H. Crabtree
Inorganic Chemistry, 2001, 40, pp.5806-5811. ⟨10.1021/ic0105258⟩
Journal articles hal-00429103v1

Selective ion pairing in [Ir(bipy)H2(PRPh2)2]A (A = PF6, BF4, CF3SO3, BPh4, R = Me, ph): Experimental identification and theoretical understanding

Alceo Macchioni , Cristiano Zuccaccia , Eric Clot , Karine Gruet , Robert H. Crabtree
Organometallics, 2001, 20, pp.2367-2373. ⟨10.1021/om010015l⟩
Journal articles hal-00429104v1

Fate of CH2=CHE (E = H, OMe) in the presence of unsaturated Ru(X)(H)L2q+ (X = Cl, q=0; X = CO, q=1): Highly sensitive to X and E

Hélène Gérard , Eric Clot , Claude Giessner-Prettre , Kenneth G. Caulton , Ernest R. Davidson
Organometallics, 2000, 19, pp.2291-2298. ⟨10.1021/om991002z⟩
Journal articles hal-00429108v1

Coordinated carbenes from electron-rich olefins on RuHCl(PiPr3)2

J. N. Coalter , Jean-Claude Bollinger , J. C. Huffman , U. Werner-Zwanziger , Kenneth G. Caulton
New Journal of Chemistry, 2000, 24, pp.9-26. ⟨10.1039/a907624g⟩
Journal articles hal-00429110v1

Transition metal polyhydrides: From qualitative ideas to reliable computational studies

Feliu Maseras , Agusti Lledós , Eric Clot , Odile Eisenstein
Chemical Reviews, 2000, 100, pp.601-636. ⟨10.1021/cr980397d⟩
Journal articles hal-00429109v1

Ruthenium assisted reversible proton transfer from an aromatic carbon to a hydride

Andrew Toner , Stephan Gründemann , Eric Clot , Hans-Heinrich Limbach , Bruno Donnadieu
Journal of the American Chemical Society, 2000, 122, pp.6777-6778. ⟨10.1021/ja9943997⟩
Journal articles hal-00429107v1

18-electron Os(X)(CHR)(Cl)(CO)L2 (X = H, Cl): not octahedral and metastable?

Hélène Gérard , Eric Clot , Odile Eisenstein
New Journal of Chemistry, 1999, 23, pp.495-498. ⟨10.1039/a809997i⟩
Journal articles hal-00429114v1

Proton transfer in aminocyclopentadienyl ruthenium hydride complexes

José A. Ayllon , Stephen F. Sayers , Sylviane Sabo-Etienne , Bruno Donnadieu , Bruno Chaudret
Organometallics, 1999, 18, pp.3981-3990. ⟨10.1021/om990301l⟩
Journal articles hal-00429112v1

Heterolytic dihydrogen activation in an iridium complex with a pendant basic group

Dong-Heon Lee , Ben Patel , Eric Clot , Odile Eisenstein , Robert H. Crabtree
Chemical Communications, 1999, pp.297-298. ⟨10.1039/a808601j⟩
Journal articles hal-00429116v1

Computational and experimental test of steric influence on agostic interactions: A homologous series for Ir(III)

Alan C. Cooper , Eric Clot , John C. Huffman , William E. Streib , Feliu Maseras
Journal of the American Chemical Society, 1999, 121, pp.97-106. ⟨10.1021/ja981727e⟩
Journal articles hal-00429117v1

From inelastic neutron scattering to structural information. A two-dimensional parametrized model to study metal-(H2) interaction

Eric Clot , Juergen Eckert
Journal of the American Chemical Society, 1999, 121, pp.8855-8863. ⟨10.1021/ja9836141⟩
Journal articles hal-00429113v1

Conformational preferences of bis(acetonitrile)tetrachloro molybdenum(IV) and tungsten(IV). Crystal structure of WCl4(CH3CN)2 and DFT calculations

Alain Manteghetti , Claude Belin , Monique Tillard-Charbonnel , Jean-Louis Pascal , Eric Clot
New Journal of Chemistry, 1999, 23, pp.165-171
Journal articles hal-00429115v1

L‘ = CO vs Cl- Transposition: Remarkable Consequences for the Product of (L‘)−Ru(L)2-(H) and Vinyl Ether

Dejian Huang , Hélène Gérard , Eric Clot , Victor Young Jr. , William E. Streib
Organometallics, 1999, 18, pp.5441-5443. ⟨10.1021/om990649g⟩
Journal articles hal-00429111v1

Influence of ancillary ligands on the kinetics and the thermodynamics of H2 addition to IrXH2(PR3)2 (X = Cl, Br, I and R = H, Me): Comparison between density functional theory and perturbation theory

Eric Clot , Odile Eisenstein
Journal of Physical Chemistry A, 1998, 102, pp.3592-3598. ⟨10.1021/jp980284y⟩
Journal articles hal-00429121v1

Inertness of the aryl-F bond toward oxidative addition to osmium and rhodium complexes: Thermodynamic or kinetic origin?

Ramon Bosque , Eric Clot , Simona Fantacci , Feliu Maseras , Odile Eisenstein
Journal of the American Chemical Society, 1998, 120, pp.12634-12640. ⟨10.1021/ja9824573⟩
Journal articles hal-00429118v1

Isomeric hydrido/vinylidene, MH(halide)(C=CH2)L2, and ethylidyne, M(halide)(C-CH3)L2 (M = Os, Ru; L equals phosphine), are energetically similar but not interconverting

Montserrat Oliván , Eric Clot , Kenneth G. Caulton , Odile Eisenstein
Organometallics, 1998, 17, pp.897-901. ⟨10.1021/om9709493⟩
Journal articles hal-00429122v1

Carbene complexes from olefins, using RuHCl((PiPr3)2. Influence of the olefin substituent

J. N. Coalter , Greg. J. Spivak , Hélène Gérard , Eric Clot , Ernest R. Davidson
Journal of the American Chemical Society, 1998, 120, pp.9388-9389. ⟨10.1021/ja980518r⟩
Journal articles hal-00429119v1

Hydride is not a spectator ligand in the formation of hydrido vinylidene from terminal alkyne and ruthenium and osmium hydrides: Mechanistic differences

Montserrat Oliván , Eric Clot , Odile Eisenstein , Kenneth G. Caulton
Organometallics, 1998, 17, pp.3091-3100. ⟨10.1021/om971109r⟩
Journal articles hal-00429120v1

Quantum exchange coupling: A hypersensitive indicator of weak interactions

Roger Kuhlman , Eric Clot , Claude Leforestier , William E. Streib , Odile Eisenstein
Journal of the American Chemical Society, 1997, 119, pp.10153-10169. ⟨10.1021/ja970603j⟩
Journal articles hal-00429123v1

Dynamics on an ab-initio surface for calculating J(HH) NMR exchange coupling: the case of OsH3X(PH3)2

Eric Clot , Claude Leforestier , Odile Eisenstein , Michel Pélissier
Journal of the American Chemical Society, 1995, 117, pp.1797-1799. ⟨10.1021/ja00111a018⟩
Journal articles hal-00429124v1

An extremely low barrier to rotation of dihydrogen in the iridium complex IrClH22-H2)(PiPr3)2

Juergen Eckert , Craig M. Jensen , Ginger Jones , Eric Clot , Odile Eisenstein
Journal of the American Chemical Society, 1993, 115, pp.11056-11057. ⟨10.1021/ja00076a100⟩
Journal articles hal-00429125v1


Alberto Albinati , Vladimir I. Bakhmutov , Kenneth G. Caulton , Eric Clot , Juergen Eckert
Journal of the American Chemical Society, 1993, 115, pp.7300-7312. ⟨10.1021/ja00069a032⟩
Journal articles hal-00429126v1


Michael Haakansson , Susan Jagner , Eric Clot , Odile Eisenstein
Inorganic Chemistry, 1992, 31, pp.5389-5394. ⟨10.1021/ic00052a013⟩
Journal articles hal-00429129v1