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Jérôme Canivet

Principal Investigator, CNRS
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Presentation

Jérôme Canivet was appointed CNRS researcher at the IRCELYON in 2010. Jérôme Canivet's team develop new catalytic systems answering current challenges in fine chemicals synthesis and clean energy production by unravelling novel molecular catalysts and heterogenizing within Porous Macroligands, a concept we established for synergistically bridging homogeneous and heterogenous catalysis. ![Poous Macroligands](https://encrypted-tbn0.gstatic.com/images?q=tbn%3AANd9GcT5TMm3jf9EpQguJG9Ap15NxixLcdhF6QHqLw&usqp=CAU) Thanks to their hybrid formulation, MOFs shall bridge the gap between pure inorganic and organic materials, thereby pushing the frontiers of knowledge ever further. Novel porous platforms allows adressing new challenges in heterogeneous catalysis whicle tackling issues on stability and control over active site: Metal-Organic Frameworks (MOF), Covalent Organic Frameworks (COF) and Conjugated Microporous Polymers (CMP). From MOF to COF and CMP, they present decreasing ordered structure and control over the porosity but increasing chemical stability. They thus appear as very appealing platforms and their use as macroligands for the heterogenization of molecular catalysts is further reducing the gap between homogeneous and heterogeneous catalysis. Research topics range from [C-C coupling](https://inc.cnrs.fr/fr/cnrsinfo/une-nouvelle-reaction-pour-la-catalyse-verte-au-nickel) to [asymmetry](https://anr.fr/Project-ANR-18-CE07-0025), [photocatalysis and green fuels](https://inc.cnrs.fr/fr/cnrsinfo/un-catalyseur-pour-transformer-le-co2-en-carburant-pour-piles-combustible). In 2018, Jérôme Canivet received the [Young Investigator Award](https://inc.cnrs.fr/fr/cnrsinfo/des-polymeres-poreux-pour-des-catalyseurs-solides-reutilisables) from the Catalysis Division of the French Chemical Society for creating trends reducing the gap between homogeneous and heterogeneous catalysis. Jérôme Canivet further aims at exploiting the confinement of molecular catalytic systems into porous structures for the improvement of their catalytic activity and selectivity, and he is coordinating cooperative projects on this topic. Personal web page **[here](https://www.ircelyon.univ-lyon1.fr/syrcel/card/JEC/)** For track records see *[**ORCID**](https://orcid.org/0000-0002-0458-3085)* Follow us on Twitter [**MOF@IRCELYON**](http://twitter.com/mofs_ircelyon?lang=fr)

Publications

Combined Covalent and Supramolecular Polymerization to Reinforce Perylenebisimide Photosynthetic "Quantasomes"

A. Ranscht , F. Rigodanza , T. Gobbato , I. Crea , E. Quadrelli
Chemistry - A European Journal, 2024, ⟨10.1002/chem.202303784⟩
Journal articles hal-04532345v1

MOF-Supported Heterogeneous Catalysts for Hydroformylation Reactions: A Minireview

P. Samanta , J. Canivet
ChemCatChem, 2024, ⟨10.1002/cctc.202301435⟩
Journal articles hal-04433675v1
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ZIF-8 thin films by a vapor-phase process: limits to growth

Virginie Perrot , Arthur Roussey , Anass Benayad , Marc Veillerot , Denis Mariolle
Nanoscale, 2023, 15, pp.7115 - 7125. ⟨10.1039/d3nr00404j⟩
Journal articles hal-04305100v1

N-Heterocyclic carbene-based porous polymer macroligand for the Ni-catalyzed C-H arylation of benzothiophenes

P. Samanta , R. Beucher , R. Riddhi , A. Ranscht , F. Wisser
Catalysis Science & Technology, 2023, 13 (20), pp.5825-5830. ⟨10.1039/d3cy01263h⟩
Journal articles hal-04272115v1

Unravelling the Molecular Structure and Confining Environment of an Organometallic Catalyst Heterogenized within Amorphous Porous Polymers

R. Jabbour , C. Ashling , T. Robinson , A. Khan , D. Wisser
Angewandte Chemie International Edition, 2023, ⟨10.1002/anie.202310878⟩
Journal articles hal-04229054v1
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Heterogenized Molecular Rhodium Phosphine Catalysts within Metal-Organic Frameworks for Alkene Hydroformylation

P. Samanta , A. Sole-Daura , R. Rajapaksha , F. Wisser , F. Meunier
ACS Catalysis, 2023, 13 (7), pp.4193-4204. ⟨10.1021/acscatal.3c00398⟩
Journal articles hal-04068263v1

Heterogenization of molecular catalysts within porous solids: the case of Ni-catalyzed ethylene oligomerization from zeolites to metal-organic frameworks

R. Rajapaksha , P. Samanta , E. Quadrelli , J. Canivet
Chemical Society Reviews, 2023, ⟨10.1039/d3cs00188a⟩
Journal articles hal-04272113v1

Molecular Rhodium Complex within N-Rich Porous Polymer Macroligand as Heterogeneous Catalyst for the Visible-Light Driven CO2 Photoreduction

R. Newar , A. Ghosh , R. Riddhi , R. Rajapaksha , P. Samanta
ADVANCED ENERGY AND SUSTAINABILITY RESEARCH, 2023, ⟨10.1002/aesr.202300209⟩
Journal articles hal-04343889v1
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Unravelling the Molecular Structure and Confining Environment of an Organometallic Catalyst Heterogenized within Amorphous Porous Polymers

Ribal Jabbour , Christopher W Ashling , Thomas C Robinson , Arafat Hossain Khan , Dorothea Wisser
Angewandte Chemie International Edition, 2023, 62 (44), pp.e202310878. ⟨10.1002/anie.202310878⟩
Journal articles hal-04304891v2
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Metal-Organic Framework Catalysts for Solar Fuels: Light-Driven Conversion of Carbon Dioxide into Formic Acid

J. Canivet , F. Wisser
ACS Applied Energy Materials, 2023, 6 (18), pp.9027-9043. ⟨10.1021/acsaem.2c03731⟩
Journal articles hal-04109799v1

Pyrene- and Bipyridine-based Covalent Triazine Framework as Versatile Platform for Photocatalytic Solar Fuels Production

M. Favaro , J. Yang , D. Ditz , H. Kucukkececi , M. Alkhurisi
ChemCatChem, 2023, ⟨10.1002/cctc.202300197⟩
Journal articles hal-04123075v1
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Finding the Sweet Spot of Photocatalysis-A Case Study Using Bipyridine-Based CTFs

M. Favaro , D. Ditz , J. Yang , S. Bergwinkl , A. Ghosh
ACS Applied Materials & Interfaces, 2022, 14 (12), pp.14182-14192. ⟨10.1021/acsami.1c24713⟩
Journal articles hal-03669108v1
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Nickel-Catalyzed Direct Arylation Polymerization for the Synthesis of Thiophene-Based Cross-linked Polymers

Y. Mohr , A. Ranscht , M. Alves-Favaro , E. Quadrelli , F. Wisser
Chemistry - A European Journal, 2022, 29 (2), pp.e202202667. ⟨10.1002/chem.202202667⟩
Journal articles hal-03884735v1
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Rhodium-Based Metal-Organic Polyhedra Assemblies for Selective CO2 Photoreduction

A. Ghosh , A. Legrand , R. Rajapaksha , G. Craig , C. Sassoye
Journal of the American Chemical Society, 2022, 144 (8), pp.3626-3636. ⟨10.1021/jacs.1c12631⟩
Journal articles hal-03636819v1
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Reusable Copper Catechol-based Porous Polymers for the Highly Efficient Heterogeneous Catalytic Oxidation of Secondary Alcohols

M. Henrion , Y. Mohr , K. Janssens , S. Smolders , A. Bugaev
ChemCatChem, 2022, ⟨10.1002/cctc.202200649⟩
Journal articles hal-03800735v1

A Disruptive Innovation for Upgrading Methane to C3 Commodity Chemicals Technical challenges faced by the C123 European consortium

A. Fonseca , R. Heyn , M. Froseth , J. Thybaut , J. Poissonnier
Johnson Matthey Technology Review, 2021, 65 (2), pp.311-329. ⟨10.1595/205651321X16051060155762⟩
Journal articles hal-03588729v1
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Heterogenization of a Molecular Ni Catalyst within a Porous Macroligand for the Direct C-H Arylation of Heteroarenes

Yorck Mohr , Marcelo Alves-Favaro , Rémy Rajapaksha , Gaëlle Hisler , Alisa Ranscht
ACS Catalysis, 2021, 11 (6), pp.3507-3515. ⟨10.1021/acscatal.1c00209⟩
Journal articles hal-03190555v1
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Des solides poreux comme macroligands solides pour un lien entre catalyse homogène et hétérogène

Jérôme Canivet , Florian Wisser
L'Actualité Chimique, 2020
Journal articles hal-02913022v1
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Nickel-catalyzed and Li-mediated regiospecific C-H arylation of benzothiophenes

Y. Mohr , G. Hisler , L. Grousset , Y. Roux , F. Wisser
Green Chemistry, 2020, 22 (10), pp.3155-3161. ⟨10.1039/d0gc00917b⟩
Journal articles hal-02877066v1
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Regiospecificity in Ligand-Free Pd-Catalyzed C–H Arylation of Indoles: LiHMDS as Base and Transient Directing Group

Yorck Mohr , Marc Renom-Carrasco , Clément Demarcy , Elsje Alessandra Quadrelli , Clément Camp
ACS Catalysis, 2020, 10 (4), pp.2713-2719. ⟨10.1021/acscatal.9b04864⟩
Journal articles hal-02493979v1
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Synthetic and computational assessment of a chiral metal-organic framework catalyst for predictive asymmetric transformation

J. Canivet , E. Bernoud , J. Bonnefoy , A. Legrand , T. Todorova
Chemical Science, 2020, 11 (33), pp.8800-8808. ⟨10.1039/d0sc03364b⟩
Journal articles hal-02935289v1
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Molecular Porous Photosystems Tailored for Long-Term Photocatalytic CO2 Reduction

F. Wisser , M. Duguet , Q. Perrinet , A. Ghosh , M. Alves-Favaro
Angewandte Chemie International Edition, 2020, 132 (13), pp.5154-5160. ⟨10.1002/anie.201912883⟩
Journal articles hal-02892502v1
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Porous Macroligands: Materials for Heterogeneous Molecular Catalysis

F. Wisser , Y. Mohr , J. Canivet , Elsje Alessandra Quadrelli
ChemCatChem, 2020, 12 (5), pp.1270-1275. ⟨10.1002/cctc.201902064⟩
Journal articles hal-02447092v1
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Microporous Polymers as Macroligands for Pentamethylcyclopentadienylrhodium Transfer-Hydrogenation Catalysts

F. Wisser , Y. Mohr , E. Quadrelli , D. Farrusseng , J. Canivet
ChemCatChem, 2018, 10 (8), pp.1778-1782. ⟨10.1002/cctc.201701836⟩
Journal articles hal-01790585v1
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Hammett Parameter in Microporous Solids as Macroligands for Heterogenized Photocatalysts

F. Wisser , P. Berruyer , L. Cardenas , Y. Mohr , E. Quadrelli
ACS Catalysis, 2018, 8 (3), pp.1653-1661. ⟨10.1021/acscatal.7b03998⟩
Journal articles hal-01756778v1
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Immobilization of a Full Photosystem in the Large-Pore MIL-101 Metal-Organic Framework for CO2 reduction

X. Wang , F. Wisser , J. Canivet , M. Fontecave , C. Mellot-Draznieks
ChemSusChem, 2018, 11 (18), pp.3315-3322. ⟨10.1002/cssc.201801066⟩
Journal articles hal-01886655v1
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Systematic study of the impact of MOF densification into tablets on textural and mechanical properties

J. Dhainaut , C. Avci-Camur , J. Troyano , A. Legrand , J. Canivet
CrystEngComm, 2017, 19 (29), pp.4211-4218. ⟨10.1039/c7ce00338b⟩
Journal articles hal-01580213v1
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Sensitive Photoacoustic IR Spectroscopy for the Characterization of Amino/Azido Mixed-Linker Metal-Organic Frameworks

J. Canivet , V Lysenko , J Lehtinen , A Legrand , F Wisser
ChemPhysChem, 2017, 18 (20), pp.2855-2858. ⟨10.1002/cphc.201700663⟩
Journal articles hal-01635508v1

A series of chiral metal–organic frameworks based on fluorene di- and tetra-carboxylates: syntheses, crystal structures and luminescence properties

Julien Robin , Nathalie Audebrand , Cyril Poriel , Jérôme Canivet , Guillaume Calvez
CrystEngComm, 2017, 19 (15), pp.2042 - 2056. ⟨10.1039/C7CE00108H⟩
Journal articles hal-01657851v1

Enhanced formation of > C1 Products in Electroreduction of CO2 by Adding a CO2 Adsorption Component to a Gas-Diffusion Layer-Type Catalytic Electrode

B. Marepally , C. Ampelli , C. Genovese , T. Saboo , S. Perathoner
ChemSusChem, 2017, 10 (22), pp.4442-4446. ⟨10.1002/cssc.201701506⟩
Journal articles hal-01671209v1

Molecular Level Characterization of the Structure and Interactions in Peptide-Functionalized Metal-Organic Frameworks.

Tanya K Todorova , Xavier Rozanska , Christel Gervais , Alexandre Legrand , Linh N Ho
Chemistry - A European Journal, 2016, 22 (46), pp.16531-16538. ⟨10.1002/chem.201603255⟩
Journal articles hal-01546494v1

Enhanced Ligand-Based Luminescence in Metal-Organic Framework Sensor

A. Legrand , A. Pastushenko , V. Lysenko , A. Geloen , E. A. Quadrelli
Chemnanomat, 2016, 2 (9), pp.866-872. ⟨10.1002/cnma.201600124⟩
Journal articles hal-01382691v1

A Pt/Al2O3-supported metal-organic framework film as the size-selective core-shell hydrogenation catalyst

S. Aguado , S. El-Jamal , Frédéric Meunier , J. Canivet , D. Farrusseng
Chemical Communications, 2016, 52 (44), pp.7161-7163. ⟨10.1039/c6cc03096c⟩
Journal articles hal-01336710v1

Origin of highly active metal-organic framework catalysts: defects? Defects!

J. Canivet , M. Vandichel , D. Farrusseng
Dalton Transactions, 2016, 45 (10), pp.4090-9. ⟨10.1039/c5dt03522h⟩
Journal articles hal-01293109v1

A Simple and Non-Destructive Method for Assessing the Incorporation of Bipyridine Dicarboxylates as Linkers within Metal-Organic Frameworks

Christopher H. Hendon , J. Bonnefoy , Elsje Alessandra Quadrelli , J. Canivet , Matthew B. Chambers
Chemistry - A European Journal, 2016, ⟨10.1002/chem.201600143⟩
Journal articles hal-01297664v1
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Enantiopure Peptide-Functionalized Metal-Organic Frameworks

J. Bonnefoy , A. Legrand , E. A. Quadrelli , J. Canivet , D. Farrusseng
Journal of the American Chemical Society, 2015, 137 (29), pp.9409-9416. ⟨10.1021/jacs.5b05327⟩
Journal articles hal-01198957v1

Photocatalytic Carbon Dioxide Reduction with Rhodium-based Catalysts in Solution and Heterogenized within Metal-Organic Frameworks

M. B. Chambers , X. Wang , N. Elgrishi , C. H. Hendon , A. Walsh
ChemSusChem, 2015, 8 (4), pp.603-608. ⟨10.1002/cssc.201403345⟩
Journal articles hal-01149254v1

Proline-functionalized metal-organic frameworks and their use in asymmetric catalysis: pitfalls in the MOFs rush

J. Canivet , D. Farrusseng
RSC Advances, 2015, 5 (15), pp.11254-11256. ⟨10.1039/c4ra12783h⟩
Journal articles hal-01149253v1

Superstructure of a Substituted Zeolitic Imidazolate Metal–Organic Framework Determined by Combining Proton Solid-State NMR Spectroscopy and DFT Calculations

Maria Baias , Anne Lesage , Sonia Aguado , Jérôme Canivet , Virginie Moizan-Baslé
Angewandte Chemie International Edition, 2015, 54 (20), pp.5971--5976. ⟨10.1002/anie.201500518⟩
Journal articles hal-01158452v1
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Water adsorption in MOFs: fundamentals and applications

Jérôme Canivet , Alexandra Fateeva , Youmin Guo , Benoit Coasne , David Farrusseng
Chemical Society Reviews, 2014, 43 (16), pp.5594 - 5617. ⟨10.1039/c4cs00078a⟩
Journal articles hal-03132964v1
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Structure-property relationships of water adsorption in metal-organic frameworks

J. Canivet , Jonathan Bonnefoy , C. Daniel , Alexandre Legrand , Benoit Coasne
New Journal of Chemistry, 2014, 38, pp.3102-3111. ⟨10.1039/c4nj00076e⟩
Journal articles hal-01057455v1

Water adsorption in MOFs: fundamentals and applications

J. Canivet , A. Fateeva , Y. M. Guo , Benoit Coasne , D. Farrusseng
Chemical Society Reviews, 2014, 43, pp.5594-5617. ⟨10.1039/c4cs00078a⟩
Journal articles hal-01073438v1

Antimicrobial activity of cobalt imidazolate metal-organic frameworks

S. Aguado , J. Quiros , J. Canivet , D. Farrusseng , K. Boltes
Chemosphere, 2014, 113, pp.188-192. ⟨10.1016/j.chemosphere.2014.05.029⟩
Journal articles hal-01073475v1

Assessing Chemical Heterogeneity at the Nanoscale in Mixed-Ligand Metal-Organic Frameworks with the PTIR Technique

A. M. Katzenmeyer , J. Canivet , G. Holland , D. Farrusseng , A. Centrone
Angewandte Chemie International Edition, 2014, 53, pp.2852-2856. ⟨10.1002/anie.201309295⟩
Journal articles hal-01057425v1

An alternative pathway for the synthesis of isocyanato- and urea-functionalised metal-organic frameworks

T. Lescouet , J. G. Vitillo , S. Bordiga , J. Canivet , D. Farrusseng
Dalton Transactions, 2013, 42, pp.8249-8258. ⟨10.1039/c3dt32714k⟩
Journal articles hal-00846444v1

Design of microporous mixed zinc-nickel triazolate metal-organic frameworks with functional ligands

S. Aguado , C. Aquino , C. Martineau , Y. V. Ryabchikov , V. Lysenko
CrystEngComm, 2013, 15, pp.9336-9339. ⟨10.1039/c3ce41260a⟩
Journal articles hal-00941351v1
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MOF-Supported Selective Ethylene Dimerization Single-Site Catalysts through One-Pot Postsynthetic Modification

J. Canivet , S. Aguado , Y. Schuurman , D. Farrusseng
Journal of the American Chemical Society, 2013, 135 (11), pp.4195-4198. ⟨10.1021/ja312120x⟩
Journal articles hal-00826367v1

Dynamic Nuclear Polarization Enhanced Solid-State NMR Spectroscopy of Functionalized Metal-Organic Frameworks

Aaron J. Rossini , Alexandre Zagdoun , Moreno Lelli , Jérôme Canivet , Sonia Aguado
Angewandte Chemie International Edition, 2012, 51 (1), pp.123-127. ⟨10.1002/anie.201106030⟩
Journal articles hal-00699781v1

Cu-mediated solid-state reaction in a post-functionalized metal-organic framework

M. Savonnet , J. Canivet , S. Gambarelli , Loic Dubois , Delphine Bazer-Bachi
CrystEngComm, 2012, 14, pp.4105-4108. ⟨10.1039/c2ce00017b⟩
Journal articles hal-00725789v1

Tailoring metal-organic framework catalysts by click chemistry

M. Savonnet , A. Camarata , J. Canivet , Delphine Bazer-Bachi , Nicolas Bats
Dalton Transactions, 2012, 41, pp.3945-3948. ⟨10.1039/c2dt11994c⟩
Journal articles hal-00700212v1

>> Nickel-Catalyzed C-H Arylation of Azoles with Haloarenes: Scope, Mechanism, and Applications to the Synthesis of Bioactive Molecules

T. Yamamoto , K. Muto , M. Komiyama , J. Canivet , J. Yamaguchi
Chemistry - A European Journal, 2011, None, pp.0113-10122. ⟨10.1002/chem.201101091⟩
Journal articles hal-00866515v1
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Engineering the Environment of a Catalytic Metal-Organic Framework by Postsynthetic Hydrophobization

Jérôme Canivet , Sonia Aguado , Cécile Daniel , David Farrusseng
ChemCatChem, 2011, 3, pp.675-678. ⟨10.1002/cctc.201000386⟩
Journal articles hal-00602745v1

Engineering structured MOF at nano and macroscales for catalysis and separation

S. Aguado , J. Canivet , D. Farrusseng
Journal of Materials Chemistry, 2011, 21, pp.7582-7588. ⟨10.1039/c1jm10787a⟩
Journal articles hal-00602736v1

Protection-deprotection Methods Applied to Metal-Organic Frameworks for the Design of Original Single-Site Catalysts

J. Canivet , D. Farrusseng
ChemCatChem, 2011, 3, pp.823-826. ⟨10.1002/cctc.201100002⟩
Journal articles hal-00602746v1
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Amino acid functionalized metal-organic frameworks by a soft coupling-deprotection sequence

J. Canivet , S. Aguado , G. Bergeret , D. Farrusseng
Chemical Communications, 2011, 47 (42), pp.11650-11652. ⟨10.1039/c1cc15541e⟩
Journal articles hal-00697859v1

Tuning the activity by controlling the wettability of MOF eggshell catalysts: A quantitative structure-activity study

S. Aguado , J. Canivet , Y. Schuurman , D. Farrusseng
Journal of Catalysis, 2011, 284, pp.207-214. ⟨10.1016/j.jcat.2011.10.002⟩
Journal articles hal-00697782v1

Facile shaping of an imidazolate-based MOF on ceramic beads for adsorption and catalytic applications

S. Aguado , J. Canivet , D. Farrusseng
Chemical Communications, 2010, 46 (42), pp.7999-8001. ⟨10.1039/c0cc02045a⟩
Journal articles hal-00537366v1

Nickel-catalyzed biaryl coupling of heteroarenes and aryl halides/triflates

J. Canivet , J. Yamaguchi , I. Ban , K. Itami
Organic Letters, 2009, None, pp.733-1736. ⟨10.1021/ol9001587⟩
Journal articles hal-00866514v1