Laurent Delbreilh

Dr. Laurent DELBREILH Associate Professor in the University of Rouen since September 2006 Section CNU : 28 Physics Researcher in Physics Researcher in GPM laboratory, UMR CNRS 6634, Co-Coordinator of « Physics Mention » Licence at the University of Rouen. Coordinator of Material Science specialty 3rd year Licence at University of Rouen Member of l’Association Française de Calorimétrie et d'Analyse Thermique (AFCAT) et de l’International Committee of Thermal Analysis and Calorimetry (ICTAC) depuis 2008. Education 2016 : “Habilitation à Diriger la Recherche” HDR 2004 : PhD. Of the University of Toulouse (F) in Polymer Physics Current Position Since 2016: Maître de Conférences HDR/ Associate Professor in the Physics research Department of the University of Rouen. Since 2014 : Visiting Adjunct Research Professor at the Mechanical and Materials Engineering department at University of Nebraska Lincoln (UNL) USA 2006/2016 : Maitre de conférences/Assistant Professor in the Physics research Department of the University of Rouen 2004/2006 : Assistant in the Physics research Department of the University of Rouen. Supervision Activities 50 Students in Master Degree 11 Students in PhD Thesis Scientific Activities: My research activities mainly concern the field of the physics of glasses, physics of disordered matter and more particularly the physics of polymers and nowadays of biopolymers. I work more specifically on the study of dynamics in amorphous phases, mainly in polymers but also for other glass formers. The various works that I have implemented, or in which I have participated, are at the intersection of two issues: - A more fundamental theme which aims to understand the physical mechanisms and the laws of behavior for glass-forming liquids below and above the glass transition temperature. - A theme with a more "materials" approach aimed at studying the impact of modifications of amorphous phases, in a physicochemical manner. This produces different relaxation environments. The principle of the environment is seen here in the broad sense since under this term we can group together: - microstructures in the case of semi-crystalline polymers - geometric confinement - fillers or nano-fillers in the case of composites - additives - nano-texturing ... These two approaches are most often interconnected in my work since the fundamental understanding of relaxation phenomena in amorphous "model" materials allows a more precise reading of the phenomena observed during an application on more complex materials.
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Documents

Présentation

Domaines de recherche

Matière Molle [cond-mat.soft] Science des matériaux [cond-mat.mtrl-sci] Physique [physics] Matériaux

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Publications

Synthesis and properties of poly (alkylene trans-1,4-cyclohexanedicarboxylate)s with different glycolic subunits

Giulia Guidotti , Clément Fosse , Michelina Soccio , Massimo Gazzano , Valentina Siracusa et al.
Polymer Degradation and Stability, 2024, 230, pp.111050. ⟨10.1016/j.polymdegradstab.2024.111050⟩
Article dans une revue hal-04766109 v1
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Conception and validation of A 3d printed learning model of supra condylar fracture of children

Alexis Lubet , Mariette Renaux-Petel , Laurent Delbreilh , Agnès Liard-Zmuda , Annabelle Auble et al.
Heliyon, 2024, 10 (10), pp.e30741. ⟨10.1016/j.heliyon.2024.e30741⟩
Article dans une revue hal-04573395 v1

Multi-center evaluation of the first, low-cost, open source and totally 3D-printed pediatric laparoscopic trainer

Alexis Lubet , Mariette Renaux-Petel , Jean-Baptiste Marret , Julien Rod , Louis Sibert et al.
Heliyon, 2024, 10 (24), pp.e40550. ⟨10.1016/j.heliyon.2024.e40550⟩
Article dans une revue hal-04842467 v1
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Study of PVAc/EVA polymer series: Influence of the inter-/intra-molecular interaction ratio on the molecular mobility at the glass transition

Jules Trubert , Liubov Matkovska , Allisson Saiter-Fourcin , Laurent Delbreilh
The Journal of Chemical Physics, 2024, 161 (20), pp.201101. ⟨10.1063/5.0233715⟩
Article dans une revue hal-04802317 v1
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Use of negative thermal expansion to design scaffolds for cultured meat

Kossi Loic M. Avegnon , Andrew Bedke , Jacob Minyard , Marie-Rose Garda , Laurent Delbreilh et al.
Materials & Design, 2024, 242, pp.112992. ⟨10.1016/j.matdes.2024.112992⟩
Article dans une revue hal-04573404 v1
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Highlighting the interdependence between volumetric contribution of fragility and cooperativity for polymeric segmental relaxation

Jules Trubert , Liubov Matkovska , Allisson Saiter-Fourcin , Laurent Delbreilh
The Journal of Chemical Physics, 2024, 160 (4), pp.044909. ⟨10.1063/5.0187941⟩
Article dans une revue hal-04427941 v1

Traversing with quantitative fidelity through the glass transition of amorphous polymers: Modeling the thermodynamic dilatational flow of polycarbonate

Mehrdad Negahban , Wenlong Li , Jean-Marc Saiter , Laurent Delbreilh , Kyle Strabala et al.
Journal of Rheology, 2023, 67 (3), pp.749. ⟨10.1122/8.0000607⟩
Article dans une revue hal-04092073 v1

Glass and sub-glass relaxation changes induced by thermal ageing of epoxy-amine polymer networks – A DMA study

Romain Delannoy , Blandine Quelennec , Vincent Tognetti , Laurent Delbreilh , Nicolas Delpouve et al.
Polymer Degradation and Stability, 2023, 216, pp.110487. ⟨10.1016/j.polymdegradstab.2023.110487⟩
Article dans une revue hal-04271921 v1

Enzymatic degradation and ageing of additively manufactured soy-based scaffolds for cell-cultured meat

A. Garrett , K.L.M. Avegnon , Laurent Delbreilh , Nicolas Delpouve , M.P. Sealy
CIRP Annals - Manufacturing Technology, 2023, ⟨10.1016/j.cirp.2023.04.020⟩
Article dans une revue hal-04111741 v1
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Microstructural consequences of isothermal crystallization in homo- and co-polyesters based on 2,5- and 2,4-furandicarboxylic acid

Aurélie Bourdet , Clément Fosse , Marie-Rose Garda , Shanmugam Thiyagarajan , Laurent Delbreilh et al.
Polymer, 2023, pp.125835. ⟨10.1016/j.polymer.2023.125835⟩
Article dans une revue hal-04020682 v1

Effect of Chemical Composition on Molecular Mobility and Phase Coupling in Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) and Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) with Different Comonomer Contents

Clément Fosse , Antonella Esposito , Pierre Lemechko , Yoga Sugama Salim , Valerio Causin et al.
Journal of Polymers and the Environment, 2023, ⟨10.1007/s10924-023-02882-2⟩
Article dans une revue hal-04095807 v1

Post‐curing and structural relaxation of epoxy networks during early stages of aging for civil engineering applications

Sanaa Oumnas , Blandine Quelennec , Emmanuel Richaud , Alexis Duthoit , Nicolas Delpouve et al.
Applied Research, 2023, ⟨10.1002/appl.202200090⟩
Article dans une revue hal-04042345 v1
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Effect of physical and chemical ageing on barrier properties of epoxy coating

Blandine Quelennec , Zhibo Duan , Romain Delannoy , Nicolas Gay , Matthieu Briffaut et al.
Construction and Building Materials, 2023, 409, pp.133908. ⟨10.1016/j.conbuildmat.2023.133908⟩
Article dans une revue hal-04272058 v1

Transition of elastomers from a rubber to glassy state under laser shock conditions

Corentin Le Bras , Clément Fosse , Laurent Delbreilh , Matthieu Gervais , M. Ayad et al.
Soft Matter, 2022, 18 (31), pp.5782-5790. ⟨10.1039/D2SM00056C⟩
Article dans une revue hal-03779187 v1

Cooperativity and fragility in furan-based polyesters with different glycolic subunits as compared to their terephthalic counterparts

Clément Fosse , Antonella Esposito , Shanmugam Thiyagarajan , Michelina Soccio , Nadia Lotti et al.
Journal of Non-Crystalline Solids, 2022, 597, pp.121907. ⟨10.1016/j.jnoncrysol.2022.121907⟩
Article dans une revue hal-03779120 v1

Segmental Relaxation Dynamics in Amorphous Polylactide Exposed to UV Light

Steven Araujo , Chloé Sainlaud , Nicolas Delpouve , Emmanuel Richaud , Laurent Delbreilh et al.
Macromolecular Chemistry and Physics, 2022, 223 (16), pp.2200085. ⟨10.1002/macp.202200085⟩
Article dans une revue hal-03779180 v1

Understanding biomanufacturing of soy-based scaffolds for cell-cultured meat by vat polymerization

M.P. Sealy , K.L.M Avegnon , A. Garrett , Laurent Delbreilh , S. Bapat et al.
CIRP Annals - Manufacturing Technology, 2022, 71 (1), pp.209-212. ⟨10.1016/j.cirp.2022.04.001⟩
Article dans une revue hal-03722942 v1
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Multiscale Analysis of Segmental Relaxation in PC/PETg Multilayers: Evidence of Immiscible Nanodroplets

Bidur Rijal , Laurent Delbreilh , Cyrille Sollogoub , Eric Baer , Allisson Saiter
Macromolecules, 2022, 55 (15), pp.6562-6572. ⟨10.1021/acs.macromol.2c00691⟩
Article dans une revue hal-04077837 v1

Correction to: Physical aging of multilayer polymer films—influence of layer thickness on enthalpy relaxation process, effect of confinement

Khadidja Arabeche , Laurent Delbreilh , Eric Baer
Journal of Polymer Research, 2022, 29 (1), pp.12. ⟨10.1007/s10965-021-02862-x⟩
Article dans une revue hal-03722947 v1
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Physical Aging of an Epoxy Resin for Civil Engineering Applications from Fast Scanning Calorimetry Investigations

Blandine Quelennec , Nicolas Delpouve , Laurent Delbreilh , Romain Delannoy , Emmanuel Richaud
Macromolecular Symposia, 2022, Times of Polymers and Composites (TOP), 405 (1), pp.2100230. ⟨10.1002/masy.202100230⟩
Article dans une revue hal-04077208 v1
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Production of Reproducible Filament Batches for the Fabrication of 3D Printed Oral Forms

Stéphane Roulon , Ian Soulairol , Valérie Lavastre , Nicolas Payre , Maxime Cazes et al.
Pharmaceutics, 2021, 13 (4), pp.472. ⟨10.3390/pharmaceutics13040472⟩
Article dans une revue hal-03187215 v1
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On the improvement of thermo-mechanical behavior of carbon/polyphenylene sulfide laminated composites upon annealing at high temperature

Benoît Vieille , E. Ernault , Nicolas Delpouve , J-D. Pujols Gonzalez , Antonella Esposito et al.
Composites Part B: Engineering, 2021, 216, pp.108858. ⟨10.1016/j.compositesb.2021.108858⟩
Article dans une revue hal-03192259 v1

Physical aging of multilayer polymer films—influence of layer thickness on enthalpy relaxation process, effect of confinement

Khadidja Arabeche , Laurent Delbreilh , Eric Baer
Journal of Polymer Research, 2021, 28 (11), pp.431. ⟨10.1007/s10965-021-02809-2⟩
Article dans une revue hal-03543481 v1
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D-Sorbitol Physical Properties Effects on Filaments Used by 3D Printing Process for Personalized Medicine

Stéphane Roulon , Ian Soulairol , Maxime Cazes , Léna Lemierre , Nicolas Payre et al.
Molecules, 2021, 26 (10), pp.3000. ⟨10.3390/molecules26103000⟩
Article dans une revue hal-03268248 v1
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Molecular mobility in amorphous biobased copolyesters obtained with 2,5- and 2,4-furandicarboxylate acid

Aurélie Bourdet , Steven Araujo , Shanmugam Thiyagarajan , Laurent Delbreilh , Antonella Esposito et al.
Polymer, 2021, 213, pp.123225. ⟨10.1016/j.polymer.2020.123225⟩
Article dans une revue hal-03331596 v1
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Water-Induced Breaking of Interfacial Cohesiveness in a Poly(lactic acid)/Miscanthus Fibers Biocomposite

Nicolas Delpouve , Hajar Faraj , Clément Demarest , Eric Dontzoff , Marie-Rose Garda et al.
Polymers, 2021, 13 (14), pp.2285. ⟨10.3390/polym13142285⟩
Article dans une revue hal-03331594 v1
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Fragility of short‐chain poly(lactic acid)s derivatives by combining dielectric spectroscopy and fast scanning calorimetry

Sareh Mahmoudian Moghaddam , Blandine Quelennec , Nicolas Delpouve , Bienvenu Atawa , Laurent Delbreilh et al.
Journal of Polymer Science, 2021, 59 (14), pp.1571-1577. ⟨10.1002/pol.20210129⟩
Article dans une revue hal-03331591 v1
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Amorphous rigidification and cooperativity drop in semi−crystalline plasticized polylactide

Nagihan Varol , Nicolas Delpouve , Steven Araujo , Sandra Domenek , Alain Guinault et al.
Polymer, 2020, 194, pp.1-9. ⟨10.1016/j.polymer.2020.122373⟩
Article dans une revue hal-02539613 v1

Physical and rheological properties of biodegradable poly(butylene succinate)/Alfa fiber composites

Khadidja Arabeche , Fatiha Abdelmalek , Laurent Delbreilh , Latéfa Zair , Abdelkader Berrayah
Journal of Thermoplastic Composite Materials, 2020, pp.089270572090409. ⟨10.1177/0892705720904098⟩
Article dans une revue hal-03032863 v1

Highlight of primary and secondary relaxations in amorphous stereocomplex polylactides

Nagihan Varol , X. Monnier , Laurent Delbreilh , Allisson Saiter , K. Fatyeyeva et al.
Express Polymer Letters, 2020, 14 (1), pp.48-62. ⟨10.3144/expresspolymlett.2020.5⟩
Article dans une revue hal-02355911 v1
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Polymer additive manufacturing of ABS structure: Influence of printing direction on mechanical properties

Hossein Ramezani Dana , Fabrice Barbe , Laurent Delbreilh , Mouldi Ben Azzouna , Alain Guillet et al.
Journal of Manufacturing Processes, 2019, 44, pp.288-298. ⟨10.1016/j.jmapro.2019.06.015⟩
Article dans une revue hal-02327086 v1
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Low velocity impact of ABS after shot peening predefined layers during additive manufacturing

Haitham Hadidi , Brady Mailand , Tayler Sundermann , Ethan Johnson , Gurucharan Madireddy et al.
Procedia Manufacturing, 2019, 34, pp.594-602. ⟨10.1016/j.promfg.2019.06.169⟩
Article dans une revue hal-02277318 v1

Quantifying Polymer Chain Orientation in Strong and Tough Nanofibers with Low Crystallinity: Toward Next Generation Nanostructured Superfibers

Dimitry Papkov , Nicolas Delpouve , Laurent Delbreilh , Steven Araujo , Taylor Stockdale et al.
Article dans une revue hal-02129923 v1
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Determination of the equilibrium enthalpy of melting of two-phase semi-crystalline polymers by fast scanning calorimetry

Clément Fosse , Aurélie Bourdet , Esteve Ernault , Antonella Esposito , Nicolas Delpouve et al.
Thermochimica Acta, 2019, 677, pp.67-78. ⟨10.1016/j.tca.2019.03.035⟩
Article dans une revue hal-02154859 v1
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Cooperativity Scaling and Free Volume in Plasticized Polylactide

Steven Araujo , Nicolas Delpouve , Sandra Domenek , Alain Guinault , Roman Golovchak et al.
Macromolecules, 2019, 52 (16), pp.6107-6115. ⟨10.1021/acs.macromol.9b00464⟩
Article dans une revue hal-02277312 v1
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Dielectric and calorimetric signatures of chain orientation in strong and tough ultrafine electrospun polyacrylonitrile

Steven Araujo , Nicolas Delpouve , Laurent Delbreilh , Dimitry Papkov , Yuris Dzenis et al.
Polymer, 2019, pp.121638. ⟨10.1016/j.polymer.2019.121638⟩
Article dans une revue hal-02178782 v1

Investigation of Drug–Excipient Interactions in Biclotymol Amorphous Solid Dispersions

Benjamin Schammé , Nicolas Couvrat , Vincent Tognetti , Laurent Delbreilh , Valérie Dupray et al.
Molecular Pharmaceutics, 2018, 15 (3), pp.1112-1125. ⟨10.1021/acs.molpharmaceut.7b00993⟩
Article dans une revue hal-01857154 v1
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Reducing the Gap between the Activation Energy Measured in the Liquid and the Glassy States by Adding a Plasticizer to Polylactide

Steven Araujo , Nicolas Delpouve , Alexandre Dhotel , Sandra Domenek , Alain Guinault et al.
ACS Omega, 2018, 3 (12), pp.17092-17099. ⟨10.1021/acsomega.8b02474⟩
Article dans une revue hal-02061741 v1

Vitrification of two active pharmaceutical ingredients by fast scanning calorimetry: From structural relaxation to nucleation phenomena

Xavier Monnier , Quentin Viel , Benjamin Schammé , Samuel Petit , Laurent Delbreilh et al.
International Journal of Pharmaceutics, 2018, 536 (1), pp.426 - 433. ⟨10.1016/j.ijpharm.2017.12.013⟩
Article dans une revue hal-01857176 v1

Molecular Mobility in Amorphous Biobased Poly(ethylene 2,5-furandicarboxylate) and Poly(ethylene 2,4-furandicarboxylate)

Aurélie Bourdet , Antonella Esposito , Shanmugam Thiyagarajan , Laurent Delbreilh , Frederic Affouard et al.
Macromolecules, 2018, 51 (5), pp.1937-1945. ⟨10.1021/acs.macromol.8b00108⟩
Article dans une revue hal-02061738 v1

Enhancement of the Physical and Chemical Stability of Amorphous Drug–Polymer Mixtures via Cryogenic Comilling

Michela Romanini , Marta Lorente , Benjamin Schammé , Laurent Delbreilh , Valérie Dupray et al.
Macromolecules, 2018, 51 (22), pp.9382-9392. ⟨10.1021/acs.macromol.8b01271⟩
Article dans une revue hal-02048482 v1

Microstructural properties and dielectric relaxations of partially fluorinated copolymers

Jorge Arturo Soto Puente , Laurent Delbreilh , Jens Dittmer , Valérie Briand , Sébastien Vernay et al.
Polymer, 2018, 157, pp.50-58. ⟨10.1016/j.polymer.2018.10.020⟩
Article dans une revue hal-02061723 v1

Molecular Mobility of an Amorphous Chiral Pharmaceutical Compound: Impact of Chirality and Chemical Purity

Quentin Viel , Laurent Delbreilh , Gérard Coquerel , Samuel Petit , Eric Dargent
Journal of Physical Chemistry B, 2017, 121 (32), pp.7729 - 7740. ⟨10.1021/acs.jpcb.7b05667⟩
Article dans une revue hal-01927923 v1

Insights on the Physical State Reached by an Active Pharmaceutical Ingredient upon High-Energy Milling

Benjamin Schammé , Xavier Monnier , Nicolas Couvrat , Laurent Delbreilh , Valérie Dupray et al.
Journal of Physical Chemistry B, 2017, 121 (19), pp.5142 - 5150. ⟨10.1021/acs.jpcb.7b02247⟩
Article dans une revue hal-01766057 v1

Compactness/density assessment of newly-paved highway containing recycled asphalt pavement by means of non-nuclear method

Steven Araujo , Bruno Beaucamp , Laurent Delbreilh , Eric Dargent , Cyrille Fauchard
Construction and Building Materials, 2017, 154, pp.1151 - 1163. ⟨10.1016/j.conbuildmat.2017.07.075⟩
Article dans une revue hal-01765957 v1

Influence of Crystallinity on the Dielectric Relaxations of Poly(Butylene Succinate) and Poly[(Butylene Succinate)- Co -(Butylene Adipate)]

Sébastien Charlon , Laurent Delbreilh , Eric Dargent , Nadège Follain , Jérémie Soulestin et al.
European Polymer Journal, 2016, 84, pp.366-376. ⟨10.1016/j.eurpolymj.2016.09.045⟩
Article dans une revue hal-01954223 v1

Molecular Relaxations in Supercooled Liquid and Glassy States of Amorphous Quinidine: Dielectric Spectroscopy and Density Functional Theory Approaches

Benjamin Schammé , Mélanie Mignot , Nicolas Couvrat , Vincent Tognetti , Laurent Joubert et al.
Journal of Physical Chemistry B, 2016, 120 (30), pp.7579-7592. ⟨10.1021/acs.jpcb.6b04242⟩
Article dans une revue hal-01928417 v1
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Rock permittivity characterization and application of electromagnetic mixing models for density/compactness assessment of HMA by means of step‐frequency radar

Steven Araujo , Laurent Delbreilh , Laurent Laguerre , Hervé Dumont , Eric Dargent et al.
Near Surface Geophysics, 2016, 14 (6), pp.551-562. ⟨10.3997/1873-0604.2016031⟩
Article dans une revue hal-02178143 v1

From a Three-Phase Model to a Continuous Description of Molecular Mobility in Semicrystalline Poly(Hydroxybutyrate- \emphCo -Hydroxyvalerate)

Antonella Esposito , Nicolas Delpouve , Valerio Causin , Alexandre Dhotel , Laurent Delbreilh et al.
Macromolecules, 2016, 49 (13), pp.4850-4861. ⟨10.1021/acs.macromol.6b00384⟩
Article dans une revue hal-01954226 v1

Transformation of an active pharmaceutical ingredient upon high-energy milling: A process-induced disorder in Biclotymol

Benjamin Schammé , Nicolas Couvrat , Pascal Malpeli , Emeline Dudognon , Laurent Delbreilh et al.
International Journal of Pharmaceutics, 2016, 499 (1-2), pp.67 - 73. ⟨10.1016/j.ijpharm.2015.12.032⟩
Article dans une revue hal-01928396 v1
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Correlated and cooperative motions in segmental relaxation: Influence of constitutive unit weight and intermolecular interactions

Bidur Rijal , Jorge Arturo Soto Puente , Bienvenu Atawa , Laurent Delbreilh , Kateryna Fatyeyeva et al.
Physical Review E , 2016, 94 (6), pp.062502. ⟨10.1103/PhysRevE.94.062502⟩
Article dans une revue hal-02130947 v1

From monomers to self-assembled monolayers: the evolution of molecular mobility with structural confinements

Alexandre Dhotel , Ziguang Chen , Jianing Sun , Boulos Youssef , Jean-Marc Saiter et al.
Soft Matter, 2015, 11 (4), pp.719-731. ⟨10.1039/C4SM01893A⟩
Article dans une revue hal-02129972 v1

Molecular mobility and physical ageing of plasticized poly(lactide)

Larisa Dobircau , Nicolas Delpouve , Romuald Herbinet , Sandra Domenek , Loïc Le Pluart et al.
Polymer Engineering and Science, 2015, 55 (4), pp.858-865. ⟨10.1002/pen.23952⟩
Article dans une revue istex hal-01173856 v1

Combining Flash DSC, DSC and broadband dielectric spectroscopy to determine fragility

Alexandre Dhotel , Bidur Rijal , Laurent Delbreilh , Eric Dargent , Allisson Saiter
Journal of Thermal Analysis and Calorimetry, 2015, 121 (1), pp.453-461. ⟨10.1007/s10973-015-4650-9⟩
Article dans une revue hal-02129983 v1

Quasi-isothermal and heat–cool protocols from MT-DSC

Bidur Rijal , Laurent Delbreilh , Jean-Marc Saiter , Andreas Schönhals , Allisson Saiter
Journal of Thermal Analysis and Calorimetry, 2015, 121 (1), pp.381-388. ⟨10.1007/s10973-015-4671-4⟩
Article dans une revue hal-02129993 v1
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Segmental mobility and glass transition of poly(ethylene-vinyl acetate) copolymers : Is there a continuum in the dynamic glass transitions from PVAc to PE?

J.A.S Puente , B Rijal , Laurent Delbreilh , K Fatyeyeva , Allisson Saiter et al.
Polymer, 2015, 76, pp.213-219. ⟨10.1016/j.polymer.2015.09.007⟩
Article dans une revue hal-01199668 v1

Dynamic Heterogeneity and Cooperative Length Scale at Dynamic Glass Transition in Glass Forming Liquids

Bidur Rijal , Laurent Delbreilh , Allisson Saiter
Macromolecules, 2015, 48 (22), pp.8219-8231. ⟨10.1021/acs.macromol.5b01152⟩
Article dans une revue hal-02156938 v1

Crystallization kinetics and molecular mobility of an amorphous active pharmaceutical ingredient: A case study with Biclotymol

Benjamin Schammé , Nicolas Couvrat , Pascal Malpeli , Laurent Delbreilh , Valérie Dupray et al.
International Journal of Pharmaceutics, 2015, 490 (1-2), pp.248 - 257. ⟨10.1016/j.ijpharm.2015.05.036⟩
Article dans une revue hal-01928832 v1

Fragility and molecular mobility in micro- and nano-layered PC/PMMA films

K. Arabeche , Laurent Delbreilh , J.-M. Saiter , G.H. Michler , R. Adhikari et al.
Polymer, 2014, 55 (6), pp.1546-1551. ⟨10.1016/j.polymer.2014.02.006⟩
Article dans une revue hal-02130064 v1

Anisotropic loss of toughness with physical aging of work toughened polycarbonate

Kyle Strabala , Shawn Meagher , Charles Landais , Laurent Delbreilh , Mehrdad Negahban et al.
Polymer Engineering and Science, 2014, 54 (4), pp.794-804. ⟨10.1002/pen.23615⟩
Article dans une revue istex hal-02130057 v1
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Structural Dependence of the Molecular Mobility in the Amorphous Fractions of Polylactide

Nicolas Delpouve , Laurent Delbreilh , Grégory Stoclet , Allisson Saiter , Eric Dargent
Macromolecules, 2014, 47 (15), pp.5186-5197. ⟨10.1021/ma500839p⟩
Article dans une revue hal-01199661 v1

Thermal growth of organic supramolecular crystals with screw dislocations

Alexandre Dhotel , Laurent Delbreilh , Boulos Youssef , Jinyue Jiang , Gérard Coquerel et al.
Journal of Thermal Analysis and Calorimetry, 2013, 112 (1), pp.301 - 305. ⟨10.1007/s10973-012-2827-z⟩
Article dans une revue istex hal-01930173 v1

Self-assembly of organic-inorganic hybrid nanolayers: effect of endgroup polarity on nanostructures

A. Dhotel , Z. Xu , L. Delbreilh , B. Youssef , J.M. Saiter et al.
MATEC Web of Conferences, 2013, 3, pp.01016. ⟨10.1051/matecconf/20130301016⟩
Article dans une revue hal-02330921 v1

Development of poly(isobutylene-co-isoprene)/reduced graphene oxide nanocomposites for barrier, dielectric and sensingapplications

Sadasivuni Kishor Kumar , Mickaël Castro , Allisson Saiter , Laurent Delbreilh , Jean Francois Feller et al.
Materials Letters, 2013, 96, pp.109-112. ⟨10.1016/j.matlet.2013.01.036⟩
Article dans une revue istex hal-02114197 v1
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Cooperativity length scale in nanocomposites: Interfacial and confinement effects

Allisson Saiter , D. Prevosto , E. Passaglia , H. Couderc , L. Delbreilh et al.
Physical Review E : Statistical, Nonlinear, and Soft Matter Physics, 2013, 88 (4), ⟨10.1103/PhysRevE.88.042605⟩
Article dans une revue hal-02156914 v1

Dielectric relaxations in polyhydroxyalkanoates/organoclay nanocomposites

R. Crétois , Laurent Delbreilh , E. Dargent , N. Follain , Laurent Lebrun et al.
European Polymer Journal, 2013, 49 (11), pp.3434-3444. ⟨10.1016/j.eurpolymj.2013.07.009⟩
Article dans une revue hal-02159353 v1

Vibro-Acoustic Behaviour in Biosourced Composites

L. Dobircau , L. Rupert , J. Turner , Laurent Delbreilh , E. Dargent et al.
Macromolecular Symposia, 2013, 328 (1), pp.56-63. ⟨10.1002/masy.201350606⟩
Article dans une revue istex hal-02159348 v1

Study of the cooperativity at the glass transition temperature in PC/PMMA multilayered films: Influence of thickness reduction from macro- to nanoscale

Khadija Arabeche , Laurent Delbreilh , Rameshwar Adhikari , Georg H. Michler , Anne Hiltner et al.
Polymer, 2012, 53 (6), pp.1355-1361. ⟨10.1016/j.polymer.2012.01.045⟩
Article dans une revue hal-02114180 v1

Supramolecular Nanolayer Reconfiguration after Molecular Intercalation

Alexandre Dhotel , Hui Li , Lucia Fernandez-Ballester , Laurent Delbreilh , Boulos Youssef et al.
Journal of Physical Chemistry C, 2011, 115 (21), pp.10351-10356. ⟨10.1021/jp112025p⟩
Article dans une revue hal-02330955 v1
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Temperature dependence of the characteristic length scale for glassy dynamics: Combination of dielectric and specific heat spectroscopy

Allisson Saiter , L. Delbreilh , H. Couderc , K. Arabeche , A. Schönhals et al.
Physical Review E : Statistical, Nonlinear, and Soft Matter Physics, 2010, 81 (4), pp.041805. ⟨10.1103/PhysRevE.81.041805⟩
Article dans une revue hal-02114159 v1

Relaxation modes in glassy polymers: A temporal analysis by the simplex method of isothermal depolarisation current measurements

Manil Soufi , Mohammed Benzohra , Laurent Delbreilh , Ahmed Hamou , Jean-Marc Saiter
Physica B: Condensed Matter, 2009, 404 (20), pp.3679-3683. ⟨10.1016/j.physb.2009.06.135⟩
Article dans une revue hal-02159331 v1

Glass transition investigated by a combined protocol using thermostimulated depolarization currents and differential scanning calorimetry

Laurent Delbreilh , M. Negahban , M. Benzohra , C. Lacabanne , J.M. Saiter
Journal of Thermal Analysis and Calorimetry, 2009, 96 (3), pp.865-871. ⟨10.1007/s10973-009-0060-1⟩
Article dans une revue hal-02159311 v1

Fabrication and characterization of multi-filament copper matrix–polyethylene fibres composite wire

Alain Guillet , E. Dargent , Laurent Delbreilh , Philippe Pareige , J.-M. Saiter
Composites Science and Technology, 2009, 69 (7-8), pp.1218-1224. ⟨10.1016/j.compscitech.2009.02.035⟩
Article dans une revue istex hal-02159319 v1
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Study of poly(bisphenol A carbonate) relaxation kinetics at the glass transition temperature

Laurent Delbreilh , Eric Dargent , Jean Grenet , Jean-Marc Saiter , Alain Bernès et al.
European Polymer Journal, 2007, vol. 43 (1), pp. 249-254. ⟨10.1016/j.eurpolymj.2006.09.019⟩
Article dans une revue hal-00808431 v1

Glass Transition Temperature and Value of the Relaxation Time at Tg in Vitreous Polymers

Jean Marc Saiter , Jean J. Grenet , Eric Dargent , Allisson Saiter , Laurent Delbreilh
Macromolecular Symposia, 2007, 258 (1), pp.152-161. ⟨10.1002/masy.200751217⟩
Article dans une revue istex hal-02156329 v1

Relaxation in poly-(ethylene terephthalate glycol)/montmorillonite nanocomposites studied by dielectric methods

H. Couderc , L. Delbreilh , Allisson Saiter , J. Grenet , N. de Souza et al.
Journal of Non-Crystalline Solids, 2007, 353 (47-51), pp.4334-4338. ⟨10.1016/j.jnoncrysol.2007.03.046⟩
Article dans une revue istex hal-02156327 v1

Effect of macromolecular orientation on the structural relaxation mechanisms of poly(ethylene terephthalate)

E. Dargent , E. Bureau , Laurent Delbreilh , A. Zumailan , J.M. M Saiter
Polymer, 2005, 46 (9), pp.3090-3095. ⟨10.1016/j.polymer.2005.01.096⟩
Article dans une revue istex hal-02114194 v1

Secondary Retardation/Relaxation Processes in Bisphenol A Polycarbonate: Thermostimulated Creep and Dynamic Mechanical Analysis Combined Investigations

Laurent Delbreilh , A. Bernès , C. Lacabanne
International Journal of Polymer Analysis and Characterization, 2005, 10 (1-2), pp.41-56. ⟨10.1080/10236660500345885⟩
Article dans une revue hal-02159290 v1

Design of a thermostimulated creep measurement system using magnetic fields for polymers

Dogan Ogreten , Laurent Delbreilh , Colette Lacabanne
Review of Scientific Instruments, 2004, 75 (7), pp.2271-2275. ⟨10.1063/1.1763258⟩
Article dans une revue hal-02159278 v1

Dynamic Mechanical Analysis of ABS From Hybrid Additive Manufacturing by Fused Filament Fabrication and Shot Peening

Haitham Hadidi , Brady Mailand , Tayler Sundermann , Ethan Johnson , Rakeshkumar Karunakaran et al.
ASME 2020 15th International Manufacturing Science and Engineering Conference, Sep 2020, Virtual, United States. ⟨10.1115/MSEC2020-8253⟩
Communication dans un congrès hal-03187218 v1

Rigid amorphous fraction in different molecular weight polylactic acid after cold crystallization from the glassy state

Yoga Sugama Salim , Antonella Esposito , Loïc Le Pluart , Esteve Ernault , Nicolas Delpouve et al.
Journées GFP Grand Ouest, May 2019, Orléans, France
Communication dans un congrès hal-02295866 v1

Effect of Molecular Weights on the Physical Properties and Microstructure of Poly(lactic acid)

Yoga Sugama Salim , Esteve Ernault , Nicolas Delpouve , Benoît Vieille , Laurent Delbreilh et al.
25eme congrès général de la société française de physique, Jul 2019, Nantes, France
Communication dans un congrès hal-02295880 v1
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Influence de la fraction amorphe rigide sur le comportement à rupture de composites Carbone/PPS

Estève Ernault , Benoît Vieille , Nicolas Delpouve , Juan Daniel Pujols Gonzalez , Laurent Delbreilh
21ème Journées Nationales sur les Composites, École Nationale Supérieure d'Arts et Métiers (ENSAM) - Bordeaux, Jul 2019, Bordeaux, Talence, France
Communication dans un congrès hal-02420710 v1

Relaxation dynamics in plasticized polylactide

Nicolas Delpouve , Steven Araujo , Sandra Domenek , Alain Guinault , Laurent Delbreilh et al.
9th International Conference on Times of Polymers and Composites. From Aerospace to Nanotechnology, Jun 2018, Ischia, Italy. pp.020055, ⟨10.1063/1.5045917⟩
Communication dans un congrès hal-02061764 v1

Influence de la Fraction Amorphe Rigide sur les Propriétés Mécaniques d'un Composite Carbone/Polysulfure de Phenylène

Esteve Ernault , Nicolas Delpouve , Benoît Vieille , Yoga Sugama Salim , Antonella Esposito et al.
DEPPOS 2018, Sep 2018, La Bresse, France
Communication dans un congrès hal-02294722 v1

Etude de la cinétique de cristallisation et de la dynamique moléculaire du poly(éthylène-2,5-furandicarboxylate) biosourcés

Aurélie Bourdet , Antonella Esposito , Shanmugam Thiyagarajan , Laurent Delbreilh , B. Schammé et al.
49èmes Journées de Calorimétrie et d'Analyse Thermique (JCAT49), May 2018, Saint-Etienne, France
Communication dans un congrès hal-02317874 v1

Parametric study of the compactness assessment of a new road containing recycled asphalt pavement through non-nuclear method

Steven Araujo , Bruno Beaucamp , Laurent Delbreilh , Eric Dargent , Cyrille Fauchard
2017 9th International Workshop on Advanced Ground Penetrating Radar (IWAGPR), Jun 2017, Edinburgh, France. ⟨10.1109/iwagpr.2017.7996089⟩
Communication dans un congrès hal-01766119 v1

Transformation of an active pharmaceutical ingredient upon high-energy milling: a case study with Biclotymol

B. Schammé , N. Couvrat , P. Malpelli , E. Dudognon , L. Delbreilh et al.
Colloque Francophone de Cristallisation et de Précipitation Industrielles (CRISTAL-8), May 2016, Rouen, France
Communication dans un congrès hal-01939501 v1

Transformation d’un principe actif sous broyage haute-énergie : cas du Biclotymol

Benjamin Schammé , Nicolas Couvrat , Pascal Malpeli , Emeline Dudognon , Laurent Delbreilh et al.
CRISTAL 8 (Cristallisation et précipitation industrielles), May 2016, Rouen, France
Communication dans un congrès hal-02468844 v1

Role of molecular mobility and fragility on physical stability of two amorphous pharmaceuticals in the supercooled and glassy states

B. Schammé , L. Delbreilh , V. Dupray , E. Dargent , G. Coquerel
PolyChar 23, May 2015, Nebraska, United States
Communication dans un congrès hal-01940511 v1

Role of plasticizing molecules on the amorphous phase dynamics of polylactide

Nicolas Delpouve , Laurent Delbreilh , Sandra Domenek , Eric Dargent
Polychar 22 World Forum on Advanced Materials, Stellenbosch University. ZAF., Apr 2014, Stellenbosch, South Africa
Communication dans un congrès hal-01269156 v1

Crystallization and phase transitions of Biclotymol polymorphs

B. Schammé , L. Delbreilh , V. Dupray , G. Coquerel
JCAT (Journées de Calorimétrie et d’Analyse Thermique), May 2014, Rouen, France
Communication dans un congrès hal-01940951 v1

Microstructure, amorphous phase dynamics and barrier properties in multilayer coextruded polylactide

Samira Fernandes Nassar , Nicolas Delpouve , Alain Guinault , Laurent Delbreilh , Cyrille Sollogoub et al.
Polychar 22 World Forum on Advanced Materials, Stellenbosch University. ZAF., Apr 2014, Stellenbosch, South Africa
Communication dans un congrès hal-01269145 v1

Order-Disorder transitions: investigations in a series of triazole ketones

S. Clevers , Céline Rougeot , M. Sanselme , V. Dupray , F. Taulelle et al.
CGOM-11 (Crystal Growth of Organic Molecules), Jun 2014, Kyoto, Japan
Communication dans un congrès hal-01941027 v1

Thermally stimulated depolarization currents and dielectric spectroscopy analysis of plasticized amorphous polylactide

Steven Araujo , Alexandre Dhotel , Nicolas Delpouve , Laurent Delbreilh , Sandra Domenek et al.
45. French Conference on Calorimetry and Thermal Analysis (JCAT 45), Groupe Français d’Études et d’Applications des Polymères. FRA., May 2014, Rouen, France
Communication dans un congrès hal-01269157 v1

Order-Disorder Transition Investigated by Temperature Resolved Second Harmonic Generation (TR-SHG)

S. Clevers , Céline Rougeot , M. Sanselme , F. Taulelle , C. Martineau et al.
Journées CNRS Cristech, Oct 2014, Autrans, France
Communication dans un congrès hal-01941131 v1

Molecular mobility, crystallization kinetics and physical stability of amorphous Biclotymol

B. Schammé , N. Couvrat , L. Delbreilh , V. Dupray , E. Dargent et al.
Condensed Matter 2014 (25th Conference of the Condensed Matter Division), Aug 2014, Paris, France
Communication dans un congrès hal-01941046 v1

Crystalline forms of the amorphous phase behavior in PLA films

Samira Fernandes Nassar , Alain Guinault , Cyrille Sollogoub , Laurent Delbreilh , Sandra Domenek
45. French Conference on Calorimetry and Thermal Analysis (JCAT 45), Groupe Français d’Études et d’Applications des Polymères. FRA., May 2014, Rouen, France
Communication dans un congrès hal-01269153 v1

Thermal and physical stability of amorphous Biclotymol

B. Schammé , L. Delbreilh , N. Couvrat , V. Dupray , G. Coquerel
Condensed Matter 2014 (25th Conference of the Condensed Matter Division), Aug 2014, Paris, France
Communication dans un congrès hal-01941049 v1

Behavior of Biclotymol: from high-energy milling to supercooled melt

B. Schammé , N. Couvrat , P. Malpeli , L. Delbreilh , V. Dupray et al.
BIWIC (21st International Workshop on Industrial Crystallization), Sep 2014, Rouen, France
Communication dans un congrès hal-01941095 v1

7.Effects of milling on polymorphism of biclotymol

B. Schammé , V. Dupray , L. Delbreihl , G. Coquerel
XXXX èmes JEEP (Joint European days on Equilibrium between Phases), Mar 2014, Lyon, France
Communication dans un congrès hal-01940890 v1

Amorphous phase molecular mobility of palsticized poly(lactic acid)

Nicolas Delpouve , L. Delbreilh , Alain Guinault , Sandra Domenek , Eric Dargent
4. International Conference on Biodegradable and Biobased Polymers (Biopol 2013), Aug 2012, Rome, Italy
Communication dans un congrès hal-01173852 v1

Effect of two plasticizers on the physical aging of polylactide

L Dobricau , Nicolas Delpouve , R Herbinet , Cecile Courgneau , L. Delbreilh et al.
4. International Conference on Biodegradable and Biobased Polymers (Biopol 2013), Aug 2012, Rome, Italy
Communication dans un congrès hal-01173857 v1

Study of Physical ageing in amorphous polymer by Thermo-Stimulated Currents (TSC)

Laurent Delbreilh , A. Bemes , C. Lacabanne
2005 12th International Symposium on Electrets, Sep 2005, Salvador, Brazil. pp.491-494
Communication dans un congrès hal-02159413 v1

Physical ageing influence on chains dynamic of polycarbonate by thermo-stimulated currents (TSC)

Laurent Delbreilh , A. Bernès , C. Lacabanne
Proceedings of the 2004 IEEE International Conference on Solid Dielectrics, Jul 2004, Toulouse, France. pp.75-78
Communication dans un congrès hal-02159408 v1