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Mireia Rodriguez-Zubiri

Senior CNRS Researcher CEISAM Institute Nantes, France " Sustainable homogeneous and heterogeneous organometallic catalysis for the synthesis of highly valuable compounds"
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  • https://www.univ-nantes.fr/mireia-rodriguez-i-zubiri

Presentation

**Dr. Mireia RODRIGUEZ-ZUBIRI (CNRS Researcher – HDR)** ###### **Researcher ID :** [E-8709-2017](https://www.webofscience.com/wos/author/rid/E-8709-2017) ###### ORCID : [0000-0001-8229-0774](https://orcid.org/my-orcid?orcid=0000-0001-8229-0774) ###### IdHAL : [mireia-rodriguez-zubiri](/) **CEISAM Institute, Nantes Université, Nantes, France** +33 251 125 697 mireia.rodriguez@univ-nantes.fr **FORMATION** 1999-2002 : **PhD in Organometallic Chemistry,** Chemistry School, Purdie Building, University of St Andrews (Scotland). Supervisors : Prof. David J. Cole-Hamilton, Prof. J. Derek Woollins, Prof. Alexandra M. Z. Slawin. 1999 : **Master in Bio-Inorganic Chemistry**, Faculty of Mathematics and Natural Sciences, University of Leiden (Netherlands). Supervisors: Prof Jan Reedijk, Dr Jan-Maarten Teuben. 1993-1999 : **University studies in Chemistry**, University of València (Spain). University degree Master 2 Chemistry. **ACTIVITES DE RECHERCHE** 2012- : **Senior CNRS Researcher**, CEISAM Institute, Nantes, France. *Topic* : « Continuous Flow Synthesis ». *Topic* : « Transition metals catalysed C-C and C-X coupling reactions: towards a heterogeneous version » 2005-2012 : **CNRS Researcher**, Laboratory LCC, Toulouse, France. *Topic* : « Intermolecular Hydroamination of α-Olefins ». *Design of new platinum and rhodium-based catalytic systems for the intermolecular hydroamination reaction in the presence of molten salts, their kinetic and theoretical studies.* 2004-2005 : **Assistant Professor** (12 months), Laboratoire de Synthèse Organométallique et Réactivité (UMR 7565), University of Lorraine. Scientific Advisor: Prof Yves Fort. *Topics* : « Synthesis of new polyheteroaromatic phosphorus ligands » and « Carbon Nanotubes Functionalisation ». *Synthesis of phosphorous multisite ligands from deficient heteroaromatic compounds in the presence of Li-superbases. Functionalisation of carbon nanotubes using the classical organic strategy and their covalent incorporation in a polymeric matrix for the transfer of promising mechanical properties.* 2003-2004 : **Post-doctoral fellow** **« poste rouge CNRS »** Associated Researcher (12 months), Laboratoire LCC, Strasbourg (University of Strasbourg, UMR 7513). Scientific Advisor: Dr Pierre Braunstein. *Topic* : « Synthesis of new clusters containing diphosphino- and/or alkyne functionalised ligands as magnetic and electronic nanoparticles precursors ». *Synthesis and characterisation of P-S ligands, their cobalt metallic clusters, their assembling dendrimers containing 12-14 cobalt atoms and their grafting into inorganic matrix.* *Funding* : C.N.R.S and the European Postgraduate School (C.N.R.S-Graduiertenkolleg 532) 1999-2002 : **PhD Thesis in Organometallic Chemistry** (3 years). Supervisors: Prof David J. Cole-Hamilton, Prof J. Derek Woollins, Prof Alexandra M. Z. Slawin, University of St Andrews, Scotland. sous la direction du Prof. David J. Cole-Hamilton, Prof. J. Derek Woollins et Dr. Alexandra M. Z. Slawin, Université de St Andrews, Ecosse. *Funding* : « Design, Synthesis and Catalysis with P-N Ligands ». *Synthesis of new P-N ligands, their coordination chemistry and their catalytic performance in the hydroformylation of olefins and the allylic alkylation reaction. Modelling studies on the structural properties of the new bis(aminophosphines) ligands.* *Funding* : EPSRC and University of St. Andrews. 1999 : **Master Project** (7 months), Faculty of Mathematics and Natural Sciences, University of Leiden, The Netherlands. Supervisors: Prof Jan Reedijk, Dr Jan-Maarten Teuben. *Title* : « Platinum Antitumoral Chemistry ». *Kinetic studies of the interaction process between platinum complexes (cisplatin models) and model proteins and peptides in order to find out their role in the platinum metabolism (ADN platination).*

Research domains

Chemical Sciences

Skills

homogeneous and heterogeneous catalysts organometallic chemistry catalysis coordination chemistry transition metal complexes green chemistry sustainability flow chemistry

Publications

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Analytical Tools Integrated in Continuous-Flow Reactors: Which One for What?

Mireia Rodriguez-Zubiri , François-Xavier Felpin
Organic Process Research and Development, 2022, 26 (6), pp.1766-1793. ⟨10.1021/acs.oprd.2c00102⟩
Journal articles hal-03800179v1
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Development of a continuous flow synthesis of FGIN-1-27 enabled by in-line 19 F NMR analyses and optimization algorithms

N. Vasudevan , Ehu Aka , Elvina Barré , Eric Wimmer , Daniel Cortés-Borda
Reaction Chemistry & Engineering, 2021, 6 (10), pp.1983-1992. ⟨10.1039/D1RE00220A⟩
Journal articles hal-03800286v1
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Direct C−H Arylation of Indole‐3‐Acetic Acid Derivatives Enabled by an Autonomous Self‐Optimizing Flow Reactor

N. Vasudevan , Eric Wimmer , Elvina Barré , Daniel Cortés‐borda , Mireia Rodriguez-Zubiri
Advanced Synthesis and Catalysis, 2021, 363 (3), pp.791-799. ⟨10.1002/adsc.202001217⟩
Journal articles hal-03143311v1
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Comparing Gas–Liquid Segmented and Tube-in-Tube Setups for the Aerobic Dimerization of Desmethoxycarpacine with an Automated Flow Platform

Ehu Camille Aka , Eric Wimmer , Elvina Barré , Daniel Cortés-Borda , Tchirioua Ekou
Organic Process Research and Development, 2020, 24 (5), pp.745-751. ⟨10.1021/acs.oprd.9b00525⟩
Journal articles hal-03003776v1
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Merging gradient-based methods to improve benchtop NMR spectroscopy: A new tool for flow reaction optimization

Shrikant Kunjir , Mireia Rodriguez-Zubiri , Vincent Coeffard , François-Xavier Felpin , Patrick Giraudeau
ChemPhysChem, 2020, 21 (20), pp.2311-2319. ⟨10.1002/cphc.202000573⟩
Journal articles hal-02999906v1
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Reconfigurable Flow Platform for Automated Reagent Screening and Autonomous Optimization for Bioinspired Lignans Synthesis

Ehu Camille Aka , Eric Wimmer , Elvina Barré , Natarajan Vasudevan , Daniel Cortes-Borda
Journal of Organic Chemistry, 2019, 84 (21), pp.14101-14112. ⟨10.1021/acs.joc.9b02263⟩
Journal articles hal-02371113v1
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Ultra-fast Suzuki and Heck reactions for the synthesis of styrenes and stilbenes using arenediazonium salts as super-electrophiles

Marina E. Trusova , Mireia Rodriguez-Zubiri , Ksenia V. Kutonova , Nicole Jung , Stefan Braese
Organic Chemistry Frontiers, 2018, 5 (1), pp.41-45. ⟨10.1039/c7qo00750g⟩
Journal articles hal-02141027v1
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An Autonomous Self-Optimizing Flow Reactor for the Synthesis of Natural Product Carpanone

Daniel Cortés-Borda , Eric Wimmer , Boris Gouilleux , Elvina Barré , Nicolas Oger
Journal of Organic Chemistry, 2018, 83 (23), pp.14286-14299. ⟨10.1021/acs.joc.8b01821⟩
Journal articles hal-01980485v1

Wilkinson-Type Immobilized Catalyst on Diamond Nanoparticles for Alkene Reduction

Clémence Queffelec , Simon Schlindwein , Dietrich Gudat , Virginie Silvestre , Mireia Rodriguez-Zubiri
ChemCatChem, 2017, 9 (3), pp.432 - 439. ⟨10.1002/cctc.201601424⟩
Journal articles hal-01898602v1
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The promoting effect of pyridine ligands in the Pd-catalysed Heck-Matsuda reaction

Walid Khodja , Alexandre Leclair , Jordi Rull-Barrull , Francoise Zammattio , Ksenia V. Kutonova
New Journal of Chemistry, 2016, 40 (10), pp.8855-8862. ⟨10.1039/c6nj01717g⟩
Journal articles hal-02141582v1
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Optimizing the Heck-Matsuda Reaction in Flow with a Constraint-Adapted Direct Search Algorithm

Daniel Cortes-Borda , Ksenia V. Kutonova , Corentin Jamet , Marina E. Trusova , Francoise Zammattio
Organic Process Research and Development, 2016, 20 (11), pp.1979-1987. ⟨10.1021/acs.oprd.6b00310⟩
Journal articles hal-02141343v1

Ultrafast 2D NMR on a benchtop spectrometer: Applications and perspectives

Boris Gouilleux , Benoît Charrier , Serge Akoka , François-Xavier Felpin , Mireia Rodriguez-Zubiri
Trends in Analytical Chemistry, 2016, 83, pp.65-75. ⟨10.1016/j.trac.2016.01.014⟩
Journal articles hal-03143407v1
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Real-time reaction monitoring by ultrafast 2D NMR on a benchtop spectrometer

Boris Gouilleux , Benoit Charrier , Ernesto Danieli , Jean-Nicolas Dumez , Serge Akoka
Analyst, 2015, 140 (23), pp.7854-7858. ⟨10.1039/c5an01998b⟩
Journal articles hal-02142137v1
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Pt-catalysed intermolecular hydroamination of non-activated olefins using a novel family of catalysts: Arbuzov-type phosphorus metal complexes

Mireia Rodriguez-Zubiri , Stephane Anguille , Jean-Jacques Brunet , Jean-Claude Daran
Journal of Molecular Catalysis A: Chemical, 2013, 379, pp.103-111. ⟨10.1016/j.molcata.2013.07.020⟩
Journal articles hal-02142395v1
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Intermolecular Rhodium-Catalysed Hydroamination of Non-Activated Olefins: Effect of Olefin, Amine, Phosphine and Phosphonium Salt

Mireia Rodriguez-Zubiri , Christine Baudequin , Aurélien Béthegnies , Jean-Jacques Brunet
ChemPlusChem, 2012, 77 (6), pp.445-454. ⟨10.1002/cplu.201200017⟩
Journal articles hal-01016806v1
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Kinetico-Mechanistic Information about Alkene Hydroamination with Aniline in Bromide-Rich Ionic Media: Importance of Solvolysis

Gabriel Aullón , Kerman Gómez , Gabriel González , Susanna Jansat , Manuel Martínez
Inorganic Chemistry, 2011, 50 (12), pp.5628-5636. ⟨10.1021/Ic2003222⟩
Journal articles hal-02950603v1
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Hydroamination of ethylene by aniline: catalysis in water

Pavel Dub , Mireia Rodriguez-Zubiri , Christine Baudequin , Rinaldo Poli
Green Chemistry, 2010, 12 (8), pp.1392-1396. ⟨10.1039/C004727A⟩
Journal articles hal-02385300v1
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Experimental (IR, Raman) and Computational Analysis of a Series of PtBr 2 Derivatives: Vibrational Coupling in the Coordinated Ethylene and Pt−Br Modes

Pavel Dub , Oleg Filippov , Natalia Belkova , Mireia Rodriguez-Zubiri , Rinaldo Poli
Journal of Physical Chemistry A, 2009, 113 (22), pp.6348-6355. ⟨10.1021/jp902394j⟩
Journal articles hal-03143334v1
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Platinum-Catalyzed Ethylene Hydroamination with Aniline: Synthesis, Characterization, and Studies of Intermediates

Pavel Dub , Mireia Rodriguez-Zubiri , Jean-Claude Daran , Jean-Jacques Brunet , Rinaldo Poli
Organometallics, 2009, 28 (16), pp.4764-4777. ⟨10.1021/om9002494⟩
Journal articles hal-03143329v1

Assembling metals and clusters around an octaphosphine ligand based on N-substituted bis(diphenylphosphanyl)amines: structural characterization of dendrimer-like Co 12 and Co 16 branched clusters

Mireia Rodriguez-Zubiri , Vito Gallo , Jacky Rosé , Richard Welter , Pierre Braunstein
Chemical Communications, 2008, 1, pp.64-66. ⟨10.1039/B713540H⟩
Journal articles hal-03143337v1

Rhodium-Catalyzed Hydroamination of Ethylene. Highly Promoting Effect of Iodide Ions

Christine Baudequin , Jean-Jacques Brunet , Mireia Rodriguez-Zubiri
Organometallics, 2007, 26 (22), pp.5264-5266. ⟨10.1021/om7009073⟩
Journal articles hal-02385356v1

Efficient microwave-assisted radical functionalization of single-wall carbon nanotubes

Jie Liu , Mireia Rodriguez I Zubiri , Brigitte Vigolo , M. Dossot , Yves Fort
Carbon, 2007, 45 (4), pp.885 - 891. ⟨10.1016/j.carbon.2006.11.006⟩
Journal articles hal-01848664v1

Microwave-Assisted Functionalization of Single-Wall Carbon Nanotubes Through Diazonium

Jie Liu , Mireia Rodriguez I Zubiri , Brigitte Vigolo , M. Dossot , Bernard Humbert
Journal of Nanoscience and Nanotechnology, 2007, 7 (10), pp.3519 - 3523. ⟨10.1166/jnn.2007.819⟩
Journal articles hal-01849011v1

Intermolecular hydroamination of non-activated alkenes catalyzed by Pt(II) or Pt(IV)-n-Bu4PX (X=Cl, Br, I) systems: Key effect of the halide anion

Mireia Rodriguez-Zubiri , Stephane Anguille , Jean-Jacques Brunet
Journal of Molecular Catalysis A: Chemical, 2007, 271 (1-2), pp.145-150. ⟨10.1016/j.molcata.2007.02.011⟩
Journal articles hal-03143341v1

Platinum-Catalyzed Intermolecular Hydroamination of Alkenes: Halide-Anion-Promoted Catalysis

Jean-Jacques Brunet , Ngoc-Chau Chu , Mireia Rodriguez-Zubiri
European Journal of Inorganic Chemistry, 2007, 2007 (30), pp.4711-4722. ⟨10.1002/ejic.200700737⟩
Journal articles hal-03143338v1

Sidewall functionalization of single-wall carbon nanotubes (SWNTs) through aryl free radical addition

Jie Liu , Mireia Rodriguez I. Zubiri , Manuel Dossot , Brigitte Vigolo , Robert Hauge
Chemical Physics Letters, 2006, 430 (1-3), pp.93-96. ⟨10.1016/j.cplett.2006.08.099⟩
Journal articles hal-03143350v1

Synthesis and structure of new phosphines containing P–N bonds

Mireia Rodriguez I Zubiri , Heather Milton , Alexandra M.Z. Slawin , J. Derek Woollins
Inorganica Chimica Acta Reviews, 2004, 357 (4), pp.1243-1246. ⟨10.1016/j.ica.2003.10.028⟩
Journal articles hal-03143361v1

The preparation and complexation of 5,10-bis(diphenylphosphino)phenazine

Mireia Rodriguez I Zubiri , Heather Milton , David Cole-Hamilton , Alexandra M.Z. Slawin , J.Derek Woollins
Inorganic Chemistry Communications, 2004, 7 (2), pp.201-203. ⟨10.1016/j.inoche.2003.10.019⟩
Journal articles hal-03143369v1

The preparation and coordination of 1,3-C6H4-{C(O)N(PPh2)CH2Ph}2 – a new multidentate ligand

M. Rodriguez I Zubiri , Heather Milton , Alexandra M.Z. Slawin , J. Derek Woollins
Polyhedron, 2004, 23 (5), pp.865-868. ⟨10.1016/j.poly.2003.12.005⟩
Journal articles hal-03143365v1

Bis(phosphine) derivatives of diamines

Mireia Rodriguez I. Zubiri , Heather Milton , David Cole-Hamilton , Alexandra M.Z. Slawin , J. Derek Woollins
Polyhedron, 2004, 23 (4), pp.693-699. ⟨10.1016/j.poly.2003.11.048⟩
Journal articles hal-03143367v1

SYNTHESIS AND USES OF PHOSPHINES CONTAINING P-N BONDS

Mireia Rodriguez I Zubiri , J. Derek Woollins
Comments on Inorganic Chemistry, 2003, 24 (5-6), pp.189-252. ⟨10.1080/02603590390464216⟩
Journal articles hal-03143371v1

The preparation and coordination chemistry of phosphorus(III) derivatives of piperazine and homopiperazine

M. Rodriguez I Zubiri , Alexandra M.Z. Slawin , Matthew Wainwright , J.Derek Woollins
Polyhedron, 2002, 21 (17), pp.1729-1736. ⟨10.1016/S0277-5387(02)01007-0⟩
Journal articles hal-03143373v1

P–N bond formation as a route to a highly electron rich bidentate phosphine ligand and its application in homogenous catalysis

Mireia Rodriguez I Zubiri , Matthew Clarke , Douglas Foster , David Cole-Hamilton , Alexandra Slawin
Journal of the Chemical Society Dalton Transactions, 2001, 7, pp.969-971. ⟨10.1039/B101656N⟩
Journal articles hal-03143379v1

Synthesis of New Phosphino-Amines, their Metal Complexes and their Application in Catalysis

Mireia Rodriguez Izubiri , Alexandra Slawin , David Cole-Hamilton , J. Derek Woollins
Phosphorus, Sulfur, and Silicon and the Related Elements, 2001, 169 (1), pp.117-120. ⟨10.1080/10426500108546604⟩
Journal articles hal-03143383v1

Glutathione readily replaces the thioether on platinum in the reaction with [Pt(dien)(GSMe)]2+ (GSMe = S-methylated glutathione); a model study for cisplatin–protein interactions

Jan-Maarten Teuben , Mireia Rodriguez I Zubiri , Jan Reedijk
Journal of the Chemical Society Dalton Transactions, 2000, 3, pp.369-372. ⟨10.1039/A908135F⟩
Journal articles hal-03143386v1