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Nicolas Le Poul

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### Nicolas LE POUL (b. 1975) ### Education **2014** : Research habilitation (HDR), University of Brest (France) **2002** : PhD in Physical Chemistry, University of Exeter (UK) **1998** : Master in Molecular Chemistry, University of Rennes (France) ### Research carreer **Since 2006** : CNRS Researcher UMR CNRS UBO 6521, Brest, France **2006** : Research engineer Batscap-Bolloré (Quimper, France) 2004** : Post-doctoral fellow CEMCA, UMR CNRS UBO 6521 (Brest, France) **2002** : Post-doctoral fellow LRCS, UMR CNRS 6007 (Amiens, France) **1998-2001** : PhD student University of Exeter (UK) ### Research themes Molecular electrochemistry Cryo-electrochemistry and spectroelectrochemistry (UV-Vis, EPR, IR) Electrode fuctionnalization (SAMs, Diazonium) Small molecules activation (O2, H2O, CO2) Electrocatalysis ### Publications 58 publications in peer-review international journals Number of citations : 650 h-index : 16

Publications

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Phosphorescent cyclometalated platinum( ii ) complexes with phenyldiazine N^C ligands

Mariia Hruzd , Samia Kahlal , Nicolas Le Poul , Laurianne Wojcik , Marie Cordier
Dalton Transactions, 2023, 52 (7), pp.1927-1938. ⟨10.1039/D2DT03690H⟩
Journal articles hal-04016070v1
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Electrochemical monitoring of the Pseudomonas aeruginosa growth and the formation of a biofilm in TSB media

J. Pellé , M. Longo , Nicolas Le Poul , Stéphane Rioual , B. Lescop
Bioelectrochemistry, 2023, 150, pp.108344. ⟨10.1016/j.bioelechem.2022.108344⟩
Journal articles hal-03923889v1
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Symmetrical and Unsymmetrical Dicopper Complexes Based on Bis-Oxazoline Units: Synthesis, Spectroscopic Properties and Reactivity

James A Isaac , Gisèle Gellon , Florian Molton , Christian Philouze , Nicolas Le Poul
Inorganics, 2023, 11 (8), pp.332. ⟨10.3390/inorganics11080332⟩
Journal articles hal-04186397v1
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Tungsten and molybdenum dinitrogen complexes supported by a pentadentate tetrapodal phosphine ligand: comparative spectroscopic, electrochemical and reactivity studies

Jannik Junge , Sven Froitzheim , Tobias Engesser , Jan Krahmer , Christian Näther
Dalton Transactions, 2022, 51 (16), pp.6166-6176. ⟨10.1039/d1dt04212b⟩
Journal articles hal-03843352v1
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Electrocatalytic reduction of CO 2 in water by a C -functionalized Ni–cyclam complex grafted onto carbon

Amélie Forget , Matthieu Regnacq , Christophe Orain , Ewen Touzé , Evan Lelong
Chemical Communications, 2022, 58 (48), pp.6785-6788. ⟨10.1039/D2CC01667B⟩
Journal articles hal-03679753v1
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Luminescent cyclometalated alkynylplatinum(ii) complexes with 1,3-di(pyrimidin-2-yl)benzene ligands: synthesis, electrochemistry, photophysics and computational studies

Mariia Hruzd , Nicolas Le Poul , Marie Cordier , Samia Kahlal , Jean-Yves Saillard
Dalton Transactions, 2022, 51 (14), pp.5546-5560. ⟨10.1039/d1dt04237h⟩
Journal articles hal-03630992v1
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Electrochemically‐driven reduction of carbon dioxide mediated by mono‐reduced Mo‐diimine tetracarbonyl complexes: electrochemical, spectroelectrochemical and theoretical studies

Carlos Garcia Bellido , Lucia Álvarez-Miguel , Daniel Miguel , Noémie Lalaoui , Nolwenn Cabon
ChemElectroChem, 2021, 8 (10), pp.1899-1910. ⟨10.1002/celc.202100359⟩
Journal articles hal-03213553v1

Bioinspired Heterobimetallic Photocatalyst ( Ru II chrom −Fe III cat ) for Visible-Light-Driven C–H Oxidation of Organic Substrates via Dioxygen Activation

Siddhant Singh , Divyanshu Nautiyal , Franck Thetiot , Nicolas Le Poul , Tapas Goswami
Inorganic Chemistry, 2021, 60 (21), pp.16059-16064. ⟨10.1021/acs.inorgchem.1c02514⟩
Journal articles hal-03919329v1
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Low-temperature electrochemistry and spectroelectrochemistry for coordination compounds

Isidoro López , Nicolas Le Poul
Coordination Chemistry Reviews, 2021, 436, pp.213823. ⟨10.1016/j.ccr.2021.213823⟩
Journal articles hal-03188421v1
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N"N"C platinum (II) complexes based on phenyl-pyridin-2-ylpyrimidine ligands: synthesis, electrochemical and photophysical properties

Mariia Hruzd , Sebastien Gauthier , Julien Boixel , Samia Kahlal , Nicolas Le Poul
Dyes and Pigments, 2021, 194, pp.109622. ⟨10.1016/j.dyepig.2021.109622⟩
Journal articles hal-03331329v1
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Theoretical aspects of electrochemistry at low temperature

Isidoro López , Nicolas Le Poul
Journal of Electroanalytical Chemistry, 2021, 887, pp.115160. ⟨10.1016/j.jelechem.2021.115160⟩
Journal articles hal-03919306v1

Investigation of second-order nonlinear optical responses in a series of V-shaped binuclear platinum(II) complexes

Raphaël Durand , Sylvain Achelle , Françoise Robin-Le Guen , Elsa Caytan , Nicolas Le Poul
Dalton Transactions, 2021, 50 (13), pp.4623-4633. ⟨10.1039/d1dt00151e⟩
Journal articles hal-03194239v1
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Functionalizing Gold Nanoparticles with Calix[4]arenes Monolayers for Enhancing Selectivity and Stability in ORR Electrocatalysis

Quentin Lenne , Alice Mattiuzzi , Ivan Jabin , Nicolas Le Poul , Corinne Lagrost
Advanced Materials Interfaces, 2020, 7 (23), pp.2001557. ⟨10.1002/admi.202001557⟩
Journal articles hal-03013589v1
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Comparative studies of new pyranylidene-based sensitizers bearing single or double anchoring groups for dye-sensitized solar cells

Sebastien Gauthier , Françoise Robin-Le Guen , Laurianne Wojcik , Nicolas Le Poul , Aurélien Planchat
Solar Energy, 2020, 205, pp.310-319. ⟨10.1016/j.solener.2020.05.036⟩
Journal articles hal-02873424v1
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Tuning Inner-Sphere Electron Transfer in a Series of Copper/Nitrosoarene Adducts

Mohammad Amin Askari , Farshid Effaty , Federica Gennarini , Maylis Orio , Nicolas Le Poul
Inorganic Chemistry, 2020, 59, pp.8678 - 8689. ⟨10.1021/acs.inorgchem.9b03175⟩
Journal articles hal-02490219v1
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Mononuclear copper(II) complexes containing a macrocyclic ditopic ligand: synthesis, structures and properties

Massinissa Ayad , Philippe P. Schollhammer , Yves Le Mest , Laurianne Wojcik , François Pétillon
Inorganica Chimica Acta, 2019, 497, pp.119081. ⟨10.1016/j.ica.2019.119081⟩
Journal articles hal-02269763v1
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High-valence CuIICuIII species in action: demonstration of aliphatic C–H bond activation at room temperature

James Alfred Isaac , Aurore Thibon-Pourret , Amélie Durand , Christian Philouze , Nicolas Le Poul
Chemical Communications, 2019, 55 (84), pp.12711-12714. ⟨10.1039/C9CC04422A⟩
Journal articles hal-02308483v1
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Synthesis and properties of novel pyranylidene-based organic sensitizers for dye-sensitized solar cells

S. Gauthier , F. Robin-Le Guen , Laurianne Wojcik , Nicolas Le Poul , A. Planchat
Dyes and Pigments, 2019, 171, pp.107747. ⟨10.1016/j.dyepig.2019.107747⟩
Journal articles hal-02281770v1
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Insights into the radical-radical and radical-substrate dimerization processes for substituted phenylmethylenepyrans

Laurianne Wojcik , Isidoro López , Sebastien Gauthier , Nolwenn Cabon , Pascal Le Poul
Electrochimica Acta, 2019, 305, pp.304-311. ⟨10.1016/j.electacta.2019.03.046⟩
Journal articles hal-02096108v1

Methylthiazolyl Tacn Ligands for Copper Complexation and Their Bifunctional Chelating Agent Derivatives for Bioconjugation and Copper-64 Radiolabeling: An Example with Bombesin

Amaury Guillou , Luis M P Lima , David Esteban-Gómez , Nicolas Le Poul , Mark Bartholomä
Inorganic Chemistry, inPress, ⟨10.1021/acs.inorgchem.8b03280⟩
Journal articles hal-01997423v1

Effect of ligand exchange on the one-electron oxidation process of alkoxo or phenoxo bridged binuclear copper(II) complexes

Federica Gennarini , Amélie Kochem , James Isaac , Ali-Taher Mansour , Isidoro López
Inorganica Chimica Acta Reviews, 2018, 56 (15), pp.4266 - 4271. ⟨10.1016/j.ica.2017.09.067⟩
Journal articles hal-01639590v1

Push–pull D–π-Ru–π-A chromophores: synthesis and electrochemical, photophysical and second-order nonlinear optical properties

Raphaël Durand , Sébastien Gauthier , Sylvain Achelle , Thomas Groizard , Samia Kahlal
Dalton Transactions, 2018, 47 (11), pp.3965 - 3975. ⟨10.1039/C8DT00093J⟩
Journal articles hal-01731342v1

Selective EPR Detection of Primary Amines in Water with a Calix[6]azacryptand-Based Copper(II) Funnel Complex

Alex Inthasot , Nicolas Le Poul , Michel Luhmer , Benoit Colasson , Ivan Jabin
Inorganic Chemistry, 2018, 57 (7), pp.3646-3655. ⟨10.1021/acs.inorgchem.7b02541⟩
Journal articles hal-03824720v1
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Mononuclear iron(II) complexes containing a tripodal and macrocyclic nitrogen ligand: synthesis, reactivity and application in cyclohexane oxidation catalysis

Massinissa Ayad , Robertus J.M. Klein Gebbink , Yves Le Mest , Philippe P. Schollhammer , Nicolas Le Poul
Dalton Transactions, 2018, 47 (43), pp.15596-15612. ⟨10.1039/C8DT02952K⟩
Journal articles hal-01885668v1

Effect of Monoelectronic Oxidation of an Unsymmetrical Phenoxido-Hydroxido Bridged Dicopper(II) Complex

Aurore Thibon-Pourret , Federica Gennarini , Rolf David , James Isaac , Isidoro López
Inorganic Chemistry, 2018, 57 (19), pp.12364-12375
Journal articles hal-02048061v1

Gating the electron transfer at a monocopper centre through the supramolecular coordination of water molecules within a protein chamber mimic

Nicolas Le Poul , Benoit Colasson , Grégory Thiabaud , Dany Jeanne Dit Fouque , Claudio Iacobucci
Chemical Science, 2018, 9 (43), pp.8282-8290. ⟨10.1039/C8SC03124J⟩
Journal articles hal-03824727v1
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Mono- and Diplatinum Polyynediyl Complexes as Potential Push–Pull Chromophores: Synthesis, Characterization, TD-DFT Modeling, and Photophysical and NLO Properties

Sébastien Gauthier , Ariel Porter , Sylvain Achelle , Thierry Roisnel , Vincent Dorcet
Organometallics, 2018, 37 (14), pp.2231-2244. ⟨10.1021/acs.organomet.8b00223⟩
Journal articles hal-01834786v1

O-O bond cleavage by electrochemical reduction of a side-on peroxo dicopper model of hemocyanin.

Isidoro López , Ana Gabriela Porras Gutiérrez , Bénédicte Douziech , Laurianne Wojcik , Yves Le Mest
Chemical Communications, 2018, ⟨10.1039/C8CC01959B⟩
Journal articles hal-01769619v1

Selective EPR Detection of Primary Amines in Water with a Calix[6]azacryptand-Based Copper(II) Funnel Complex

Alex Inthasot , Nicolas Le Poul , Michel Luhmer , Benoit Colasson , Ivan Jabin
Inorganic Chemistry, 2018, ⟨10.1021/acs.inorgchem.7b02541⟩
Journal articles hal-01679879v1

Electrochemical Water Oxidation and Stereoselective Oxygen Atom Transfer Mediated by a Copper Complex

Maria-Chrysanthi Kafentzi , Raffaello Papadakis , Federica Gennarini , Amélie Kochem , Olga Iranzo
Chemistry - A European Journal, 2018, ECOSTBio – Spin States and Reactivity, 24 (20), pp.5213-5224. ⟨10.1002/chem.201704613⟩
Journal articles hal-01711795v1

Gating the electron transfer at a monocopper centre through the supramolecular coordination of water molecules within a protein chamber mimic

Nicolas Le Poul , Benoit Colasson , Grégory Thiabaud , Dany Jeanne Dit Fouque , Claudio Iacobucci
Chemical Science, 2018, 9 (43), pp.8282-8290. ⟨10.1039/C8SC03124J⟩
Journal articles hal-01874257v1
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Characterization of a Dinuclear Copper(II) Complex and Its Fleeting Mixed-Valent Copper(II)/Copper(III) Counterpart

Amélie Kochem , Federica Gennarini , Mehdi Yemloul , Maylis Orio , Nicolas Le Poul
ChemPlusChem, 2017, 82 (4), pp.615 - 624. ⟨10.1002/cplu.201600636⟩
Journal articles hal-01624533v1
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Characterization of a Dinuclear Copper(II) Complex and Its Fleeting Mixed-Valent Copper(II)/Copper(III) Counterpart

Amélie Kochem , Federica Gennarini , Mehdi Yemloul , Maylis Orio , Nicolas Le Poul
ChemPlusChem, 2017, Biofest, 82 (4), pp.615-624. ⟨10.1002/cplu.201600636⟩
Journal articles hal-01793247v1

“Two-Story” Calix[6]arene-Based Zinc and Copper Complexes: Structure, Properties, and O 2 Binding

Gaël de Leener , Diana Over , Coryse Smet , Damien Cornut , Ana Gabriela Porras-Gutierrez
Inorganic Chemistry, 2017, 56 (18), pp.10971-10983. ⟨10.1021/acs.inorgchem.7b01225⟩
Journal articles hal-03824702v1

Chemoselective guest-triggered shaping of a polynuclear Cu II calix[6]complex into a molecular host

Sarah Richard , Gaëtan Le Duc , Nicolas Le Poul , Yves Le Mest , Olivia Reinaud
Dalton Transactions, 2017, Dalton Trans., 46, pp.15249-15256. ⟨10.1039/c7dt03375c⟩
Journal articles hal-01626615v1
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Direct Determination of Electron-Transfer Properties of Dicopper-Bound Reduced Dioxygen Species by a Cryo-Spectroelectrochemical Approach.

Isidoro López , Rui Cao , David A. Quist , Kenneth D Karlin , Nicolas Le Poul
Chemistry - A European Journal, 2017, chemistry, a european journal, 23 (72), pp.18314-18319. ⟨10.1002/chem.201705066⟩
Journal articles hal-01636273v1
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Incorporation of a platinum center in the pi-conjugated core of push-pull chromophores for nonlinear optics (NLO)

Raphaël Durand , Sébastien Gauthier , Sylvain Achelle , Samia Kahlal , Jean-Yves Saillard
Dalton Transactions, 2017, 46 (9), pp.3059-3069. ⟨10.1039/c7dt00252a⟩
Journal articles hal-01500397v1

Selective EPR Detection of Primary Amines in Water with a Calix[6]azacryptand-Based Copper(II) Funnel Complex

Alex Inthasot , Nicolas Le Poul , Michel Luhmer , Benoit Colasson , Ivan Jabin
Inorganic Chemistry, 2017, 57 (7), pp.3646-3655. ⟨10.1021/acs.inorgchem.7b02541⟩
Journal articles hal-03154352v1

“Two-Story” Calix[6]arene-Based Zinc and Copper Complexes: Structure, Properties, and O 2 Binding

Gael de Leener , Diana Over , Coryse Smet , Damien Cornut , Ana Gabriela Porras-Gutierrez
Inorganic Chemistry, 2017, 56 (18), pp.10971 - 10983. ⟨10.1021/acs.inorgchem.7b01225⟩
Journal articles hal-01624540v1

Influence of Asymmetry on the Redox Properties of Phenoxo- and Hydroxo-Bridged Dicopper Complexes: Spectroelectrochemical and Theoretical Studies

Federica Gennarini , Rolf David , Isidoro López , Yves Le Mest , Marius Réglier
Inorganic Chemistry, 2017, 56 (14), pp.7707 - 7719. ⟨10.1021/acs.inorgchem.7b00338⟩
Journal articles hal-01624535v1
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Reversible redox switching of chromophoric phenylmethylenepyrans by carbon-carbon bond making/breaking

Laurianne Wojcik , François Michaud , Sebastien Gauthier , Nolwenn Cabon , Pascal Le Poul
Journal of Organic Chemistry, 2017, 82 (23), pp.12395 - 12405. ⟨10.1021/acs.joc.7b02199⟩
Journal articles hal-01624342v1
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Immobilization of Monolayers Incorporating Cu Funnel Complexes onto Gold Electrodes. Application to the Selective Electrochemical Recognition of Primary Alkylamines in Water

Gael de Leener , Ferdinand Evoung-Evoung , Angelique Lascaux , Jérémy Mertens , Ana Gabriela Porras-Gutierrez
Journal of the American Chemical Society, 2016, 138 (39), pp.12841--12853. ⟨10.1021/jacs.6b05317⟩
Journal articles hal-01395479v1

Improving the stability and inertness of Cu( ii ) and Cu( i ) complexes with methylthiazolyl ligands by tuning the macrocyclic structure

Mariane Le Fur , Maryline Beyler , Nicolas Le Poul , Luís M. P. Lima , Yves Le Mest
Dalton Transactions, 2016, 45 (17), pp.7406 - 7420. ⟨10.1039/C6DT00385K⟩
Journal articles hal-01518185v1

The synthesis of flexible tetrapyridylethanes from pyridylpyrylium dications

Pascal Le Poul , Nicolas Le Poul , Stéphane Golhen , Francoise Robin-Le Guen , Bertrand Caro
New Journal of Chemistry, 2016, 40 (7), pp.5666-5669. ⟨10.1039/c5nj03257a⟩
Journal articles hal-01310391v1

Cyclams with Ambidentate Methylthiazolyl Pendants for Stable, Inert, and Selective Cu(II) Coordination

Aurora Rodríguez-Rodríguez , Zakaria Halime , Luís M. P. Lima , Maryline Beyler , David Deniaud
Inorganic Chemistry, 2016, 55 (2), pp.619-632. ⟨10.1021/acs.inorgchem.5b01779⟩
Journal articles hal-01517782v1

Electrochemically and Chemically Induced Redox Processes in Molecular Machines

Nicolas Le Poul , Benoit Colasson
ChemElectroChem, 2015, 2 (4), pp.475. ⟨10.1002/celc.201402399⟩
Journal articles hal-01171145v1

Supramolecular Modeling of Mono-copper Enzyme Active Sites with Calix[6]arene-based Funnel Complexes

Nicolas Le Poul , Yves Le Mest , Ivan Jabin , Olivia Reinaud
Accounts of Chemical Research, 2015, 48 (7), pp.2097 - 2106. ⟨10.1021/acs.accounts.5b00152⟩
Journal articles hal-01538565v1
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Insights into water coordination associated with the Cu(II)/Cu(I) electron transfer at a biomimetic Cu centre.

Ana Gabriela Porras Gutiérrez , Joceline Zeitouny , Antoine Gomila , Bénédicte Douziech , Nathalie Cosquer
Dalton Transactions, 2014, 43 (17), pp.6436-45. ⟨10.1039/c3dt53548g⟩
Journal articles hal-01066935v1

Supramolecular Control of a Mononuclear Biomimetic Copper(II) Center: Bowl Complexes vs Funnel Complexes

Jerome Gout , Aleksandar Visnjevac , Stéphanie Rat , Arnaud Parrot , Assia Hessani
Inorganic Chemistry, 2014, 53 (12), pp.6224--6234. ⟨10.1021/ic500740r⟩
Journal articles hal-01175763v1

Aza and cyanobridged tripodal dinuclear copper(II) complexes: Electrochemical studies and structural evidence for an original azacyanocarbanion

Antoine Gomila , Bénédicte Douziech , Nathalie Cosquer , Nicolas Le Poul , François Michaud
Inorganica Chimica Acta, 2014, 411, pp.67--76. ⟨10.1016/j.ica.2013.11.024⟩
Journal articles hal-01175761v1

Synthesis, photovoltaic performances and TD-DFT modeling of push-pull diacetylide platinum complexes in TiO2 based dye-sensitized solar cells.

Sébastien Gauthier , Bertrand Caro , Françoise Robin-Le Guen , Nattamai Bhuvanesh , John A Gladysz
Dalton Transactions, 2014, 43 (29), pp.11233-42. ⟨10.1039/c4dt00301b⟩
Journal articles hal-01114401v1

Locally Induced and Self-Induced "Electroclick" onto a Self-Assembled Monolayer: Writing and Reading with SECM under Unbiased Conditions

Sebastien Lhenry , Yann R Leroux , Christophe Orain , Françoise Conan , Nathalie Cosquer
Langmuir, 2014, 30 (15), pp.4501-4508. ⟨10.1021/la405005f⟩
Journal articles hal-01151703v1

Synthesis of an unsymmetrical N-functionalized triazacyclononane ligand and its Cu(II) complex

Mélissa Roger , Véronique Patinec , Raphaël Tripier , Smail Triki , Nicolas Le Poul
Inorganica Chimica Acta, 2014, 417, pp.201--207. ⟨10.1016/j.ica.2013.12.036⟩
Journal articles hal-01175762v1
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Electron transfer properties of mono- and diferrocenyl based Cu complexes attached as self-assembled monolayers on gold electrodes by "self-induced" electroclick

Christophe Orain , Pascal Le Poul , Yves Le Mest , Nicolas Le Poul
Journal of electroanalytical chemistry and interfacial electrochemistry, 2013, 710, pp.48-58. ⟨10.1016/j.jelechem.2013.02.014⟩
Journal articles hal-00879630v1

Electrochemical behavior and dioxygen reactivity of tripodal dinuclear copper complexes linked by unsaturated rigid spacers

Antoine Gomila , Nicolas Le Poul , Jean-Michel Kerbaol , Nathalie Cosquer , Smail Triki
Dalton Transactions, 2013, 42 (6), pp.2238--2253. ⟨10.1039/c2dt31456h⟩
Journal articles hal-01175767v1

Bowl versus Funnel Supramolecular Concept for Cu-I Complexes within the Biomimetic Tris(imidazole) Core

Jerome Gout , Aleksandar Visnjevac , Stéphanie Rat , Olivia Bistri , Nicolas Le Poul
European Journal of Inorganic Chemistry, 2013, 2013 (29), pp.5171--5180. ⟨10.1002/ejic.201300733⟩
Journal articles hal-01175766v1

Differocenyl Pyrrylium Salts and Electron Rich Bispyran from Oxidative Coupling of Ferrocenylpyran. Example of Redox Systems Switched by Proton transfer

Fatou Ba , Nolwenn Cabon , Pascal Le Poul , Samia Kahlal , Jean-Yves Saillard
New Journal of Chemistry, 2013, 37 (7), pp.2066-2081. ⟨10.1039/C3NJ41126E⟩
Journal articles hal-00874189v1

Electrochemically Driven Cup-and-Ball Cu-I and Cu-II Complexes

Nicolas Menard , Yohann Heriot , Yves Le Mest , Olivia Reinaud , Nicolas Le Poul
Chemistry - A European Journal, 2013, 19 (32), pp.10611--10618. ⟨10.1002/chem.201301141⟩
Journal articles hal-01175765v1

Electrocatalytic reduction of nitrite ions by a copper complex attached as SAMs on gold by "self-induced electroclick": Enhancement of the catalytic rate by surface coverage decrease

Christophe Orain , Ana Gabriela Porras-Gutierrez , Ferdinand Evoung Evoung , Catherine Charles , Nathalie Cosquer
Electrochemistry Communications, 2013, 34, pp.204--207. ⟨10.1016/j.elecom.2013.06.014⟩
Journal articles hal-01175764v1

Synthesis and Studies of a Water-Soluble and Air-Stable Cu-I/Cu-II Open-Shell Funnel Complex

Grégory Thiabaud , Andrea Brugnara , Michaël Carboni , Nicolas Le Poul , Benoit Colasson
Organic Letters, 2012, 14 (10), pp.2500--2503. ⟨10.1021/ol3007875⟩
Journal articles hal-01175768v1
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Rate enhancement of the catechol oxidase activity of a series of biomimetic monocopper(II) complexes by introduction of non-coordinating groups in N-tripodal ligands

Ronan Marion , Nidal Saleh , Nicolas Le Poul , Didier Floner , Olivier Lavastre
New Journal of Chemistry, 2012, 36, pp.1828-1835. ⟨10.1039/C2NJ40265C⟩
Journal articles hal-00843848v1

A Generic Platform for the Addressable Functionalisation of Electrode Surfaces through Self-Induced "Electroclick"

Christophe Orain , Nicolas Le Poul , Antoine Gomila , Jean-Michel Kerbaol , Nathalie Cosquer
Chemistry - A European Journal, 2012, 18 (2), pp.594--602. ⟨10.1002/chem.201102620⟩
Journal articles hal-01175769v1

Tris(triazolyl) Calix[6]arene-Based Zinc and Copper Funnel Complexes: Imidazole-like or Pyridine-like? A Comparative Study

Benoit Colasson , Nicolas Le Poul , Yves Le Mest , Olivia Reinaud
Inorganic Chemistry, 2011, 50 (21), pp.10985--10993. ⟨10.1021/ic201540x⟩
Journal articles hal-01175770v1

Self-induced "electroclick" immobilization of a copper complex onto self-assembled monolayers on a gold electrode

Antoine Gomila , Nicolas Le Poul , Nathalie Cosquer , Jean-Michel Kerbaol , Jean-Marc Noël
Dalton Transactions, 2010, 39 (48), pp.11516--11518. ⟨10.1039/c0dt01093f⟩
Journal articles hal-01175772v1

Ferrocenyl and pyridyl methylenepyrans as potential precursors of organometallic electron-rich extended bipyrans: Synthesis, characterization and crystal structure

Fatou Ba , Françoise Robin-Le Guen , Nolwenn Cabon , Pascal Le Poul , Stéphane Golhen
Journal of Organometallic Chemistry, 2010, 695 (2), pp.235-243. ⟨10.1016/j.jorganchem.2009.10.006⟩
Journal articles hal-00917193v1

Electrochemically Triggered Double Translocation of Two Different Metal Ions with a Ditopic Calix[6]arene Ligand

Benoit Colasson , Nicolas Le Poul , Yves Le Mest , Olivia Reinaud
Journal of the American Chemical Society, 2010, 132 (12), pp.4393--4398. ⟨10.1021/ja910676z⟩
Journal articles hal-01175771v1

Mimicking the protein access channel to a metal center: effect of a funnel complex on dissociative versus associative copper redox chemistry

Nicolas Le Poul , Bénédicte Douziech , J. Zeitouny , G. Thiabaud , H. Colas
Journal of the American Chemical Society, 2009, 131, pp.17800-17807. ⟨10.1021/ja9055905⟩
Journal articles hal-00467992v1

Diferrocenylbispyrylium Salts and Electron-Rich Diferrocenylbispyran from Oxidative Coupling of Ferrocenylpyran. Induced Electron Transfer C-C Bond Making/Breaking Involving a Metallocenyl Radical Intermediate

Fatou Ba , Nolwenn Cabon , Francoise Robin-Le Guen , Pascal Le Poul , Nicolas Le Poul
Organometallics, 2008, 27 (24), pp.6396--6399. ⟨10.1021/om800638q⟩
Journal articles hal-01175773v1

Monocopper center embedded in a biomimetic cavity: From supramolecular control of copper coordination to redox regulation

Nicolas Le Poul , Morgan Campion , Bénédicte Douziech , Yannick Rondelez , Loic Le Clainche
Journal of the American Chemical Society, 2007, 129 (28), pp.8801--8810. ⟨10.1021/ja071219h⟩
Journal articles hal-01175774v1

Synthesis of bis-2H and 4H-chalcogenapyrans and benzochalcogenapyrans via Pd0 catalyzed dimerization of Fischer type carbene complexes: redox properties and electronic structure of these new extended electron rich molecules

Nadège Faux , Francoise Robin-Le Guen , Pascal Le Poul , Bertrand Caro , Nicolas Le Poul
Tetrahedron, 2007, 63 (30), pp.7142-7153. ⟨10.1016/j.tet.2007.04.099⟩
Journal articles hal-00363438v1

Determination of heterogeneous electron-transfer kinetics of decamethylferrocene at low temperatures (120 K < T < 200 K) by a.c. impedance

Nicolas Le Poul , Stephen J. Green , Yves Le Mest
Journal of electroanalytical chemistry and interfacial electrochemistry, 2006, 596 (1), pp.47--56. ⟨10.1016/j.jelechem.2006.07.005⟩
Journal articles hal-01175775v1

Electrochemical behavior of the tris(pyridine) - Cu funnel complexes: An overall induced-fit process involving an entatic state through a supramolecular stress

Nicolas Le Poul , M. Campion , G. Izzet , O. Reinaud , Bénédicte Douziech
Journal of the American Chemical Society, 2005, 127 (15), pp.5280--5281. ⟨10.1021/ja043073h⟩
Journal articles hal-01175776v1

Sub-T-c electron transfer at the Hg-HTSC/liquid-electrolyte interface

S. J. Green , Nicolas Le Poul , P. P. Edwards , G. Peacock
Journal of the American Chemical Society, 2003, 125 (13), pp.3686--3687. ⟨10.1021/ja034010m⟩
Journal articles hal-01175777v1

Development of potentiometric ion sensors based on insertion materials as sensitive element

Nicolas Le Poul , Emmanuel Baudrin , Mathieu Morcrette , Sylvain Gwizdala , Christian Masquelier
Solid State Ionics, 2003, 159(1-2), pp.149. ⟨10.1016/S0167-2738(02)00921-9⟩
Journal articles hal-00125497v1

Sub-T-c electron transfer at the HTSC/polymer interface

Nicolas Le Poul , S. J. Green , J. P. Attfield
Chemical Communications, 2003, 5, pp.638--639. ⟨10.1039/b300023k⟩
Journal articles hal-01175778v1

Reactivity of carbanions of Fischer-type carbene complexes with pyrylium salts. Synthesis and characterization of new gamma-methylenepyran carbene complexes via an addition-oxidation-deprotonation process

B. Caro , P. Le Poul , F. Robin-Le Guen , J. Y. Saillard , S. Kahlal
Tetrahedron, 2002, 58 (37), pp.PII S0040-4020(02)00800-1. ⟨10.1016/S0040-4020(02)00800-1⟩
Journal articles hal-01175779v1

Synthesis of new highly conjugated bis-(4H-pyrans) involving electron rich polyene linkage, by Pd degrees catalytic coupling of gamma-methylenepyran Fischer-type carbene complexes

F. Robin-Le Guen , P. Le Poul , B. Caro , N. Faux , Nicolas Le Poul
Tetrahedron Letters, 2002, 43 (21), pp.PII S0040-4039(02)00645-7. ⟨10.1016/S0040-4039(02)00645-7⟩
Journal articles hal-01175780v1