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Coordination Variations within Binuclear Copper Dioxygen-Derived (Hydro)Peroxo and Superoxo Species; Influences upon Thermodynamic and Electronic Properties
Pradip Kumar Hota
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Anex Jose
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Sanjib Panda
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Eleanor Dunietz
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Austin Herzog
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Copper–oxygen adducts: new trends in characterization and properties towards C–H activation
Jonathan De Tovar
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Rébecca Leblay
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Yongxing Wang
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Laurianne Wojcik
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Aurore Thibon-Pourret
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Symmetrical and Unsymmetrical Dicopper Complexes Based on Bis-Oxazoline Units: Synthesis, Spectroscopic Properties and Reactivity
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Gisèle Gellon
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Florian Molton
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Christian Philouze
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Nicolas Le Poul
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Electrochemical monitoring of the Pseudomonas aeruginosa growth and the formation of a biofilm in TSB media
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Nicolas Le Poul
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Stéphane Rioual
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B. Lescop
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Phosphorescent cyclometalated platinum( ii ) complexes with phenyldiazine N^C ligands
Mariia Hruzd
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Samia Kahlal
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Nicolas Le Poul
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Laurianne Wojcik
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Marie Cordier
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Electrocatalytic reduction of CO 2 in water by a C -functionalized Ni–cyclam complex grafted onto carbon
Amélie Forget
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Matthieu Regnacq
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Christophe Orain
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Ewen Touzé
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Evan Lelong
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Luminescent cyclometalated alkynylplatinum(ii) complexes with 1,3-di(pyrimidin-2-yl)benzene ligands: synthesis, electrochemistry, photophysics and computational studies
Mariia Hruzd
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Nicolas Le Poul
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Marie Cordier
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Samia Kahlal
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Jean-Yves Saillard
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An ultrasensitive and highly selective nanomolar electrochemical sensor based on an electrocatalytic peak shift analysis approach for copper trace detection in water
Lylian Challier
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Amélie Forget
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Charlène Bazin
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Simon Tanniou
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Justine Le Doare
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Tungsten and molybdenum dinitrogen complexes supported by a pentadentate tetrapodal phosphine ligand: comparative spectroscopic, electrochemical and reactivity studies
Jannik Junge
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Sven Froitzheim
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Tobias Engesser
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Jan Krahmer
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Christian Näther
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Theoretical aspects of electrochemistry at low temperature
Isidoro López
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Investigation of second-order nonlinear optical responses in a series of V-shaped binuclear platinum(II) complexes
Raphaël Durand
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Sylvain Achelle
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Françoise Robin-Le Guen
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Elsa Caytan
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Nicolas Le Poul
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Electrochemically‐driven reduction of carbon dioxide mediated by mono‐reduced Mo‐diimine tetracarbonyl complexes: electrochemical, spectroelectrochemical and theoretical studies
Carlos Garcia Bellido
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Lucia Álvarez-Miguel
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Daniel Miguel
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Noémie Lalaoui
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Nolwenn Cabon
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N"N"C platinum (II) complexes based on phenyl-pyridin-2-ylpyrimidine ligands: synthesis, electrochemical and photophysical properties
Mariia Hruzd
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Sebastien Gauthier
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Julien Boixel
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Samia Kahlal
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Nicolas Le Poul
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Low-temperature electrochemistry and spectroelectrochemistry for coordination compounds
Isidoro López
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Nicolas Le Poul
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Bioinspired Heterobimetallic Photocatalyst ( Ru II chrom −Fe III cat ) for Visible-Light-Driven C–H Oxidation of Organic Substrates via Dioxygen Activation
Siddhant Singh
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Divyanshu Nautiyal
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Franck Thetiot
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Nicolas Le Poul
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Tapas Goswami
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Functionalizing Gold Nanoparticles with Calix[4]arenes Monolayers for Enhancing Selectivity and Stability in ORR Electrocatalysis
Quentin Lenne
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Alice Mattiuzzi
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Ivan Jabin
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Nicolas Le Poul
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Corinne Lagrost
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Comparative studies of new pyranylidene-based sensitizers bearing single or double anchoring groups for dye-sensitized solar cells
Sebastien Gauthier
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Françoise Robin-Le Guen
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Laurianne Wojcik
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Nicolas Le Poul
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Aurélien Planchat
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Tuning Inner-Sphere Electron Transfer in a Series of Copper/Nitrosoarene Adducts
Mohammad Amin Askari
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Farshid Effaty
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Federica Gennarini
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Maylis Orio
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Nicolas Le Poul
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Synthesis and properties of novel pyranylidene-based organic sensitizers for dye-sensitized solar cells
S. Gauthier
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F. Robin-Le Guen
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Laurianne Wojcik
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Nicolas Le Poul
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A. Planchat
Journal articles
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High-valence CuIICuIII species in action: demonstration of aliphatic C–H bond activation at room temperature
James Alfred Isaac
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Aurore Thibon-Pourret
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Amélie Durand
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Christian Philouze
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Nicolas Le Poul
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Insights into the radical-radical and radical-substrate dimerization processes for substituted phenylmethylenepyrans
Laurianne Wojcik
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Isidoro López
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Sebastien Gauthier
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Nolwenn Cabon
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Pascal Le Poul
Journal articles
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Mononuclear copper(II) complexes containing a macrocyclic ditopic ligand: synthesis, structures and properties
Massinissa Ayad
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Philippe P. Schollhammer
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Yves Le Mest
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Laurianne Wojcik
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François Pétillon
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Methylthiazolyl Tacn Ligands for Copper Complexation and Their Bifunctional Chelating Agent Derivatives for Bioconjugation and Copper-64 Radiolabeling: An Example with Bombesin
Amaury Guillou
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Luis M P Lima
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David Esteban-Gómez
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Nicolas Le Poul
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Mark Bartholomä
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Push–pull D–π-Ru–π-A chromophores: synthesis and electrochemical, photophysical and second-order nonlinear optical properties
Raphaël Durand
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Sébastien Gauthier
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Sylvain Achelle
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Thomas Groizard
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Samia Kahlal
Journal articles
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Selective EPR Detection of Primary Amines in Water with a Calix[6]azacryptand-Based Copper(II) Funnel Complex
Alex Inthasot
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Nicolas Le Poul
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Michel Luhmer
,
Benoit Colasson
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Ivan Jabin
Journal articles
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Gating the electron transfer at a monocopper centre through the supramolecular coordination of water molecules within a protein chamber mimic
Nicolas Le Poul
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Benoit Colasson
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Grégory Thiabaud
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Dany Jeanne Dit Fouque
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Claudio Iacobucci
Journal articles
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Electrochemical Water Oxidation and Stereoselective Oxygen Atom Transfer Mediated by a Copper Complex
Maria-Chrysanthi Kafentzi
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Raffaello Papadakis
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Federica Gennarini
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Amélie Kochem
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Olga Iranzo
Chemistry - A European Journal, 2018, ECOSTBio – Spin States and Reactivity, 24 (20), pp.5213-5224. ⟨10.1002/chem.201704613⟩
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Effect of ligand exchange on the one-electron oxidation process of alkoxo or phenoxo bridged binuclear copper(II) complexes
Federica Gennarini
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Amélie Kochem
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James Isaac
,
Ali-Taher Mansour
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Isidoro López
Journal articles
hal-01639590v1
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Gating the electron transfer at a monocopper centre through the supramolecular coordination of water molecules within a protein chamber mimic
Nicolas Le Poul
,
Benoit Colasson
,
Grégory Thiabaud
,
Dany Jeanne Dit Fouque
,
Claudio Iacobucci
Journal articles
hal-03824727v1
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Selective EPR Detection of Primary Amines in Water with a Calix[6]azacryptand-Based Copper(II) Funnel Complex
Alex Inthasot
,
Nicolas Le Poul
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Michel Luhmer
,
Benoit Colasson
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Ivan Jabin
Journal articles
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Mononuclear iron(II) complexes containing a tripodal and macrocyclic nitrogen ligand: synthesis, reactivity and application in cyclohexane oxidation catalysis
Massinissa Ayad
,
Robertus J.M. Klein Gebbink
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Yves Le Mest
,
Philippe P. Schollhammer
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Nicolas Le Poul
Journal articles
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Effect of Monoelectronic Oxidation of an Unsymmetrical Phenoxido-Hydroxido Bridged Dicopper(II) Complex
Aurore Thibon-Pourret
,
Federica Gennarini
,
Rolf David
,
James Isaac
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Isidoro López
Journal articles
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Mono- and Diplatinum Polyynediyl Complexes as Potential Push–Pull Chromophores: Synthesis, Characterization, TD-DFT Modeling, and Photophysical and NLO Properties
Sébastien Gauthier
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Ariel Porter
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Sylvain Achelle
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Thierry Roisnel
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Vincent Dorcet
Journal articles
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O-O bond cleavage by electrochemical reduction of a side-on peroxo dicopper model of hemocyanin.
Isidoro López
,
Ana Gabriela Porras Gutiérrez
,
Bénédicte Douziech
,
Laurianne Wojcik
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Yves Le Mest
Journal articles
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Chemoselective guest-triggered shaping of a polynuclear Cu II calix[6]complex into a molecular host
Sarah Richard
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Gaëtan Le Duc
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Nicolas Le Poul
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Yves Le Mest
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Olivia Reinaud
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Influence of Asymmetry on the Redox Properties of Phenoxo- and Hydroxo-Bridged Dicopper Complexes: Spectroelectrochemical and Theoretical Studies
Federica Gennarini
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Rolf David
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Isidoro López
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Yves Le Mest
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Marius Réglier
Journal articles
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“Two-Story” Calix[6]arene-Based Zinc and Copper Complexes: Structure, Properties, and O 2 Binding
Gael de Leener
,
Diana Over
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Coryse Smet
,
Damien Cornut
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Ana Gabriela Porras-Gutierrez
Journal articles
hal-01624540v1
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Chemoselective guest-triggered shaping of a polynuclear Cu II calix[6]complex into a molecular host
Sarah Richard
,
Gaëtan Le Duc
,
Nicolas Le Poul
,
Yves Le Mest
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Olivia Reinaud
Journal articles
hal-03824711v1
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Reversible redox switching of chromophoric phenylmethylenepyrans by carbon-carbon bond making/breaking
Laurianne Wojcik
,
François Michaud
,
Sebastien Gauthier
,
Nolwenn Cabon
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Pascal Le Poul
Journal articles
hal-01624342v1
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“Two-Story” Calix[6]arene-Based Zinc and Copper Complexes: Structure, Properties, and O 2 Binding
Gaël de Leener
,
Diana Over
,
Coryse Smet
,
Damien Cornut
,
Ana Gabriela Porras-Gutierrez
Journal articles
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Direct Determination of Electron-Transfer Properties of Dicopper-Bound Reduced Dioxygen Species by a Cryo-Spectroelectrochemical Approach.
Isidoro López
,
Rui Cao
,
David A. Quist
,
Kenneth D Karlin
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Nicolas Le Poul
Journal articles
hal-01636273v1
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Selective EPR Detection of Primary Amines in Water with a Calix[6]azacryptand-Based Copper(II) Funnel Complex
Alex Inthasot
,
Nicolas Le Poul
,
Michel Luhmer
,
Benoit Colasson
,
Ivan Jabin
Journal articles
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Incorporation of a platinum center in the pi-conjugated core of push-pull chromophores for nonlinear optics (NLO)
Raphaël Durand
,
Sébastien Gauthier
,
Sylvain Achelle
,
Samia Kahlal
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Jean-Yves Saillard
Journal articles
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Characterization of a Dinuclear Copper(II) Complex and Its Fleeting Mixed-Valent Copper(II)/Copper(III) Counterpart
Amélie Kochem
,
Federica Gennarini
,
Mehdi Yemloul
,
Maylis Orio
,
Nicolas Le Poul
Journal articles
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Characterization of a Dinuclear Copper(II) Complex and Its Fleeting Mixed-Valent Copper(II)/Copper(III) Counterpart
Amélie Kochem
,
Federica Gennarini
,
Mehdi Yemloul
,
Maylis Orio
,
Nicolas Le Poul
Journal articles
hal-01624533v1
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The synthesis of flexible tetrapyridylethanes from pyridylpyrylium dications
Pascal Le Poul
,
Nicolas Le Poul
,
Stéphane Golhen
,
Francoise Robin-Le Guen
,
Bertrand Caro
Journal articles
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Cyclams with Ambidentate Methylthiazolyl Pendants for Stable, Inert, and Selective Cu(II) Coordination
Aurora Rodríguez-Rodríguez
,
Zakaria Halime
,
Luís M. P. Lima
,
Maryline Beyler
,
David Deniaud
Journal articles
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Improving the stability and inertness of Cu( ii ) and Cu( i ) complexes with methylthiazolyl ligands by tuning the macrocyclic structure
Mariane Le Fur
,
Maryline Beyler
,
Nicolas Le Poul
,
Luís M. P. Lima
,
Yves Le Mest
Journal articles
hal-01518185v1
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Immobilization of Monolayers Incorporating Cu Funnel Complexes onto Gold Electrodes. Application to the Selective Electrochemical Recognition of Primary Alkylamines in Water
Gael de Leener
,
Ferdinand Evoung-Evoung
,
Angelique Lascaux
,
Jérémy Mertens
,
Ana Gabriela Porras-Gutierrez
Journal articles
hal-01395479v1
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Room-Temperature Characterization of a Mixed-Valent µ-Hydroxodicopper(II,III) Complex
James A Isaac
,
Franc A Gennarini
,
Isidoro López
,
Aurore Thibon-Pourret
,
Rolf David
Journal articles
hal-01475746v1
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Supramolecular Modeling of Mono-copper Enzyme Active Sites with Calix[6]arene-based Funnel Complexes
Nicolas Le Poul
,
Yves Le Mest
,
Ivan Jabin
,
Olivia Reinaud
Journal articles
hal-01538565v1
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Electrochemically and Chemically Induced Redox Processes in Molecular Machines
Nicolas Le Poul
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Benoit Colasson
Journal articles
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Insights into water coordination associated with the Cu(II)/Cu(I) electron transfer at a biomimetic Cu centre.
Ana Gabriela Porras Gutiérrez
,
Joceline Zeitouny
,
Antoine Gomila
,
Bénédicte Douziech
,
Nathalie Cosquer
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Supramolecular Control of a Mononuclear Biomimetic Copper(II) Center: Bowl Complexes vs Funnel Complexes
Jerome Gout
,
Aleksandar Visnjevac
,
Stéphanie Rat
,
Arnaud Parrot
,
Assia Hessani
Journal articles
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Locally Induced and Self-Induced "Electroclick" onto a Self-Assembled Monolayer: Writing and Reading with SECM under Unbiased Conditions
Sebastien Lhenry
,
Yann R Leroux
,
Christophe Orain
,
Françoise Conan
,
Nathalie Cosquer
Journal articles
hal-01151703v1
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Synthesis of an unsymmetrical N-functionalized triazacyclononane ligand and its Cu(II) complex
Mélissa Roger
,
Véronique Patinec
,
Raphaël Tripier
,
Smail Triki
,
Nicolas Le Poul
Journal articles
hal-01175762v1
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Synthesis, photovoltaic performances and TD-DFT modeling of push-pull diacetylide platinum complexes in TiO2 based dye-sensitized solar cells.
Sébastien Gauthier
,
Bertrand Caro
,
Françoise Robin-Le Guen
,
Nattamai Bhuvanesh
,
John A Gladysz
Journal articles
hal-01114401v1
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Aza and cyanobridged tripodal dinuclear copper(II) complexes: Electrochemical studies and structural evidence for an original azacyanocarbanion
Antoine Gomila
,
Bénédicte Douziech
,
Nathalie Cosquer
,
Nicolas Le Poul
,
François Michaud
Journal articles
hal-01175761v1
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Electrochemically Driven Cup-and-Ball Cu-I and Cu-II Complexes
Nicolas Menard
,
Yohann Heriot
,
Yves Le Mest
,
Olivia Reinaud
,
Nicolas Le Poul
Journal articles
hal-01175765v1
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Electrocatalytic reduction of nitrite ions by a copper complex attached as SAMs on gold by "self-induced electroclick": Enhancement of the catalytic rate by surface coverage decrease
Christophe Orain
,
Ana Gabriela Porras-Gutierrez
,
Ferdinand Evoung Evoung
,
Catherine Charles
,
Nathalie Cosquer
Journal articles
hal-01175764v1
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|
Bowl versus Funnel Supramolecular Concept for Cu-I Complexes within the Biomimetic Tris(imidazole) Core
Jerome Gout
,
Aleksandar Visnjevac
,
Stéphanie Rat
,
Olivia Bistri
,
Nicolas Le Poul
Journal articles
hal-01175766v1
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Electrochemical behavior and dioxygen reactivity of tripodal dinuclear copper complexes linked by unsaturated rigid spacers
Antoine Gomila
,
Nicolas Le Poul
,
Jean-Michel Kerbaol
,
Nathalie Cosquer
,
Smail Triki
Journal articles
hal-01175767v1
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Differocenyl Pyrrylium Salts and Electron Rich Bispyran from Oxidative Coupling of Ferrocenylpyran. Example of Redox Systems Switched by Proton transfer
Fatou Ba
,
Nolwenn Cabon
,
Pascal Le Poul
,
Samia Kahlal
,
Jean-Yves Saillard
Journal articles
hal-00874189v1
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|
Electron transfer properties of mono- and diferrocenyl based Cu complexes attached as self-assembled monolayers on gold electrodes by "self-induced" electroclick
Christophe Orain
,
Pascal Le Poul
,
Yves Le Mest
,
Nicolas Le Poul
Journal articles
hal-00879630v1
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A Generic Platform for the Addressable Functionalisation of Electrode Surfaces through Self-Induced "Electroclick"
Christophe Orain
,
Nicolas Le Poul
,
Antoine Gomila
,
Jean-Michel Kerbaol
,
Nathalie Cosquer
Journal articles
hal-01175769v1
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|
Rate enhancement of the catechol oxidase activity of a series of biomimetic monocopper(II) complexes by introduction of non-coordinating groups in N-tripodal ligands
Ronan Marion
,
Nidal Saleh
,
Nicolas Le Poul
,
Didier Floner
,
Olivier Lavastre
Journal articles
hal-00843848v1
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|
Synthesis and Studies of a Water-Soluble and Air-Stable Cu-I/Cu-II Open-Shell Funnel Complex
Grégory Thiabaud
,
Andrea Brugnara
,
Michaël Carboni
,
Nicolas Le Poul
,
Benoit Colasson
Journal articles
hal-01175768v1
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|
Tris(triazolyl) Calix[6]arene-Based Zinc and Copper Funnel Complexes: Imidazole-like or Pyridine-like? A Comparative Study
Benoit Colasson
,
Nicolas Le Poul
,
Yves Le Mest
,
Olivia Reinaud
Journal articles
hal-01175770v1
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|
Electrochemically Triggered Double Translocation of Two Different Metal Ions with a Ditopic Calix[6]arene Ligand
Benoit Colasson
,
Nicolas Le Poul
,
Yves Le Mest
,
Olivia Reinaud
Journal articles
hal-01175771v1
|
|
Self-induced "electroclick" immobilization of a copper complex onto self-assembled monolayers on a gold electrode
Antoine Gomila
,
Nicolas Le Poul
,
Nathalie Cosquer
,
Jean-Michel Kerbaol
,
Jean-Marc Noël
Journal articles
hal-01175772v1
|
|
Ferrocenyl and pyridyl methylenepyrans as potential precursors of organometallic electron-rich extended bipyrans: Synthesis, characterization and crystal structure
Fatou Ba
,
Françoise Robin-Le Guen
,
Nolwenn Cabon
,
Pascal Le Poul
,
Stéphane Golhen
Journal articles
hal-00917193v1
|
|
Mimicking the protein access channel to a metal center: effect of a funnel complex on dissociative versus associative copper redox chemistry
Nicolas Le Poul
,
Bénédicte Douziech
,
J. Zeitouny
,
G. Thiabaud
,
H. Colas
Journal articles
hal-00467992v1
|
|
Diferrocenylbispyrylium Salts and Electron-Rich Diferrocenylbispyran from Oxidative Coupling of Ferrocenylpyran. Induced Electron Transfer C-C Bond Making/Breaking Involving a Metallocenyl Radical Intermediate
Fatou Ba
,
Nolwenn Cabon
,
Francoise Robin-Le Guen
,
Pascal Le Poul
,
Nicolas Le Poul
Journal articles
hal-01175773v1
|
|
Monocopper center embedded in a biomimetic cavity: From supramolecular control of copper coordination to redox regulation
Nicolas Le Poul
,
Morgan Campion
,
Bénédicte Douziech
,
Yannick Rondelez
,
Loic Le Clainche
Journal articles
hal-01175774v1
|
|
Synthesis of bis-2H and 4H-chalcogenapyrans and benzochalcogenapyrans via Pd0 catalyzed dimerization of Fischer type carbene complexes: redox properties and electronic structure of these new extended electron rich molecules
Nadège Faux
,
Francoise Robin-Le Guen
,
Pascal Le Poul
,
Bertrand Caro
,
Nicolas Le Poul
Journal articles
hal-00363438v1
|
|
Determination of heterogeneous electron-transfer kinetics of decamethylferrocene at low temperatures (120 K < T < 200 K) by a.c. impedance
Nicolas Le Poul
,
Stephen J. Green
,
Yves Le Mest
Journal articles
hal-01175775v1
|
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Electrochemical behavior of the tris(pyridine) - Cu funnel complexes: An overall induced-fit process involving an entatic state through a supramolecular stress
Nicolas Le Poul
,
M. Campion
,
G. Izzet
,
O. Reinaud
,
Bénédicte Douziech
Journal articles
hal-01175776v1
|
|
Development of potentiometric ion sensors based on insertion materials as sensitive element
Nicolas Le Poul
,
Emmanuel Baudrin
,
Mathieu Morcrette
,
Sylvain Gwizdala
,
Christian Masquelier
Journal articles
hal-00125497v1
|
|
Sub-T-c electron transfer at the Hg-HTSC/liquid-electrolyte interface
S. J. Green
,
Nicolas Le Poul
,
P. P. Edwards
,
G. Peacock
Journal articles
hal-01175777v1
|
|
Sub-T-c electron transfer at the HTSC/polymer interface
Nicolas Le Poul
,
S. J. Green
,
J. P. Attfield
Journal articles
hal-01175778v1
|
|
Reactivity of carbanions of Fischer-type carbene complexes with pyrylium salts. Synthesis and characterization of new gamma-methylenepyran carbene complexes via an addition-oxidation-deprotonation process
B. Caro
,
P. Le Poul
,
F. Robin-Le Guen
,
J. Y. Saillard
,
S. Kahlal
Journal articles
hal-01175779v1
|
|
Synthesis of new highly conjugated bis-(4H-pyrans) involving electron rich polyene linkage, by Pd degrees catalytic coupling of gamma-methylenepyran Fischer-type carbene complexes
F. Robin-Le Guen
,
P. Le Poul
,
B. Caro
,
N. Faux
,
Nicolas Le Poul
Journal articles
hal-01175780v1
|