
Valentin Valtchev
Présentation
Valentin VALTCHEV
Research Director CNRS, UMR6506, Laboratoire Catalyse et Spectrochimie, ENSICAEN - University of Caen – CNRS, 6 bd Maréchal Juin, 14050 Caen, FRANCE
Tel. +33231452733 ; Fax +33231452822 ; valentin.valtchev@ensicaen.fr
Education
Habilitation 2001 - University of Haute Alsace, France
Habilitation 1996 – Bulgarian Academy of Sciences, Bulgaria
Ph.D. in Chemistry (1991), Institute of Applied Mineralogy, Bulgarian Academy of Sciences
Master degree (M. S.) in Geochemistry (1985), University of Sofia
University education (B. S.) in Geochemistry (1983), University of Sofia
Positions
Thousand Talents fellow (2015 – 2020), Jilin University, Changchun, China
Research Director (DR1 CNRS, 2013 - now) Caen, France
Research Director (DR2 CNRS, 2006 - 2013) Mulhouse, France
Researcher Associate (2000 - 2006) Mulhouse, France
Professor (1996 – 2000) – Bulgaria Academy of Sciences, Bulgaria
Research interests
Ø Synthesis and characterization of microporous materials
Ø Mechanism of zeolite formation
Ø Nanosized microporous materials preparation (< 100 nm)
Ø Structure – properties relationship in microporous solids
Ø Post-synthesis modifications of zeolites
Ø Zeolite-containing composite materials
Scientific activities
Papers > 240, Patents 25, Book chapters 6, Books 6
More than 40 plenary and keynote lectures including at the most important events in the field of nanoporous materials
h-index 50 (35 average citation) Web of Science Core
**h-index 56 (Citations: 9900) Google knowledge
Honors
1) 2019- Chair of the “Breck committee” of the International Zeolite Association
2) 2017- Honorary Professor of China University of Petroleum
3) 2016- Elected President of the International Zeolite Association
4) 2016- “Donald Breck” award, the highest recognition of the International Zeolite Association
5) 2016- “La Recherche 2016: Chimie” award, France
6) 2015- Manager of the International Zeolite Association web site
7) 2014- “Baron fon Cronstedt” award, the highest recognition of the Federation of European Zeolite Associations
8) 2014- “Thousand Talents” Professor, Jilin University, China
9) 2011- paper selected amongst “Top 10 Breakthrough of the year” by the editors of Science
8) 1991 – Bulgaria “Young inventor”
Publications
Publications
Recent Advances in Zeolite Properties ControlGordon Research Conference, Aug 2023, New Hampshire, United States
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Empowering Sustainable Energy-Water-Environment Nexus: Green Promoters for Rapid Methane Hydrate FormationInternational Conference On Sustainable Energy-Water-Environment Nexus In Desert Climate (ICSEWEN23), QEERI, Oct 2023, Doha, Qatar
Communication dans un congrès
hal-04259009
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Zeolites Promoters for Sustainable Methane Storage38th Meeting of French Group of Zeolite (GFZ 2023), Mar 2023, Strabourg, France
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hal-04258828
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From Lab to Real World: Synergistic Use of Zeolites and Gas Hydrates for Energy Transition Applications3rd IRN Meeting CAS-CNRS, Jun 2023, Paris, France
Communication dans un congrès
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The energy transition – new opportunities for the zeolitic materials22nd Brazilian Congress in Catalysis, Sep 2023, Porto Alegre, Brazil
Communication dans un congrès
hal-04288708
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Probing the acidic properties of an extra-large pore aluminosilicate ZEO-1Symposium - Functional Porous Materials & Reticular Chemistry of Porous Polymers, Nov 2023, Haiko, China
Communication dans un congrès
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New insights in zeolite formation – New advances in zeolite properties controlFederation of European Zeolite Associations Conference, Jul 2023, Portorose, Slovenia
Communication dans un congrès
hal-04288729
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Microporous materials for energy-saving extraction of water from the air2023 International Conference on Green Carbon (ICFC2023), Jul 2023, Qingdao City, Shandong Province, China
Communication dans un congrès
hal-04288718
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Climate-Resilient Technologies: Adapting Methane Hydrate Transformations to Moderate Thermodynamic ConditionsThe 10th International Conference on Advanced Applied Raman Spectroscopy (RamanFest2023), Nov 2023, Paris, France
Communication dans un congrès
hal-04259038
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CH 4-CO2 Replacement Mechanism and Kinetics in Zeolitic Ice: Revealing the double occupation MechanismSCF (Société Chimique de France) 2023 Congress, The French Chemical Society, Jun 2023, Lille, France
Communication dans un congrès
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Green Promoters for Sustainable Energy Storage9th Conference of The European Zeolite Association (FEZA 2023), FEZA, Jul 2023, Portoroz-Portorose, Slovenia
Communication dans un congrès
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Revealing Acidic Zeolites: Role as New Kinetic Hydrate Promoters: A Combined Computational and Experimental Study37th meeting of French Group of Zeolite (GFZ), Mar 2022, Vogüé, France
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An Innovative Environmental Benign Approach to Enhance Methane Hydrate Kinetics in Near-Ambient and Moderate PressureSeventh International Conference on Multifunctional, Hybrid and Nanomaterials, Elsevier, Oct 2022, Genoa, Italy
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Acidic medium zeolite synthesis – an avenue to new materialsInternational conference: Matériaux 2022 – Lille, Oct 2022, Lille, France
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The energy transition – a new challenge for zeolite molecular sievesRomCat 2022, Jun 2022, Baile Govora, Romania
Communication dans un congrès
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Understanding CH4-CO2 Guest Exchange Mechanism between in sI Clathrate: CH4 Recovery and CO2 Storage Opportunities.Les Journées « HYDRATES 2022 », GDR2026 Hydrates de gaz, Nov 2022, Paris, France
Communication dans un congrès
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The future of zeolites in net carbon zero-transitioning economiesWorkshop: “Advancement of CO2 Utilization & Low Carbon Processes”, May 2022, Doha, Qatar
Communication dans un congrès
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Toward Economic Seawater based THF-Methane Hydrate Formation at Ambient Temperature: A Combined Experimental and Computational StudyConférence Internationale Matériaux, Oct 2022, Lille, France
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A Computational Insight of Guest Exchange Mechanism between CH4 and CO2 in SI Clathrate: CH4 Recovery and CO2 Storage Opportunities.TAMUQ-TotalEnergies Workshop" Successful Industry-Academia Collaboration in the Advancement of CO2 Utilization & Low Carbon Processes, Texas A&M University, May 2022, Doha, Qatar
Communication dans un congrès
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An Eco-Friendly Approach For Improved Methane Hydrate Kinetics In Near-Ambient Temperature and Moderate PressureACS Research Conference : Chemistry and Chemical Engineering in MENA, May 2022, Doha, Qatar
Communication dans un congrès
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Technology watch and achievements in programming on long vector processors.Journées Calcul Données : Rencontres scientifiques et techniques autour du calcul et des données, Le GIS FRANCE GRILLES,; GENCI; le GDR RSD; Silecs/Grid'5000 le Groupe Calcul, Oct 2022, Dijon, France
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Synergistic eco-friendly kinetic promoters for high methane storage in fresh and seawater-based hydrate.8th LCS Workshop ‘Zeolites in the Energy Transition’, LCS- CNRS, May 2022, Cabourg, France, France
Communication dans un congrès
hal-04257916
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Binary H2 -CH4 Clathrate for better hydrogen StorageI-EPE (Energie, Propulsion et En- vironment), Laboratoire de Catalyse et Spechtrochemie (LCS), Dec 2021, Caen, France
Communication dans un congrès
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Ab initio Mechanistic Insight into the Stability, Diffusion, and Storage Capacity of H2, CH4, and CO2 in sI Clathrate HydrateEuropean Congress and Exhibition on Advanced Materials and Processes - EUROMAT 2021, Sep 2021, Virtual, Austria
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Study of Mass transport properties of zeolites by combining Gravimetric and Infrared spectroscopyJournées Scientifiques de l’Association Française de l'Adsorption, Jan 2020, Paris Marne-la-Vallée, France
Communication dans un congrès
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Synthesis of ultra small zeolite units and their potential usesACS Research Conference: Chemistry and Chemical Engineering in MENA, Mar 2020, Doha, Qatar
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Prospects and Limitations of Zeolites in a Changing World36ème Réunion Annuelle du Groupe Français des Zéolithes, Mar 2020, Domaine Lou Capitelle, Vogüé, Ardèche, France
Communication dans un congrès
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In-situ and post-synthesis control of zeolite properties8th Serbian-Croatian-Slovenian Symposium on Zeolites, Oct 2019, Belgrade, Serbia
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Crystalline microporous materials – current trends3rd Workshop of Hierarchically-ordered Materials: From Theory to Applications, Sep 2019, Erlangen, Germany
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Zeolitic materials in the twilight zone between crystalline and amorphous4th EAZC, Jan 2019, Taormina, Italy
Communication dans un congrès
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Zeolite Materials: Current Challenges and Opportunities20th China Zeolite Conference, Oct 2019, Hangzhou, China
Communication dans un congrès
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Tuning Zeolite Properties: In-situ versus Post-Synthesis MethodsZeolites and Microporous Crystal, Aug 2018, Yokohama, Japan
Communication dans un congrès
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Tuning zeolite accessibility by in-situ and post-synthesis methods255th National Meeting and Exposition of the American-Chemical-Society (ACS) - Nexus of Food, Energy, and Water, Mar 2018, New Orleans, LA, United States
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Tuning the Properties of Relevant ZeolitesJSPS “Meet Industry and Academia” meeting, Aug 2018, Tokyo, Japan
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A study on the nature and location of active sites in Cu- and Fe- exchanged zeolites and their mechanical mixture for NH3-SCR reaction10th International Conference on Environmental Catalysis & 3rd International Symposium on Catalytic Science and Technology in Sustainable Energy and Environment (ICEC & EECAT 2018), Sep 2018, Tianjin, China
Communication dans un congrès
hal-02066186
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Designer zeolites: Smaller, more accessible, better and affordable255th National Meeting and Exposition of the American-Chemical-Society (ACS) - Nexus of Food, Energy, and Water, Mar 2018, New Orleans, LA, United States
Communication dans un congrès
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Embryonic Zeolites: Synthesis and Catalytic ApplicationsZeolite Forum, Dec 2018, Guangzhou, China
Communication dans un congrès
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Zeolite formation: new insights into nucleation mechanism31st China Chemical Society National Meeting, May 2018, Hangzhou, China
Communication dans un congrès
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Enhancement of Zeolite Active Site Accessibility: In-situ versus Post-synthesis Methods21st NECZA (North-East Zeolite Association Corridor), Dec 2017, Houstin Hall, United States
Communication dans un congrès
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Conversion of a large pore in extra-large pore zeoliteSymposium “Hybrid porous materials”, Jan 2016, Zhuhai, China
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High Visible Light Photoactivity of Plasma-Created Vanadium Clusters Supported on Nano-ZeolitesIZC, Jun 2016, Rio de Janeiro, Brazil
Communication dans un congrès
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“Hierarchical and Nanozeolites: Prospects”CICECO Jornadas: ENERGY – trends and Future Challenges, Jun 2016, Aveiro, Portugal
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The fluoride route to hierarchical zeolitesHiMAT: from theory to applications, Sep 2016, Erlangen, Germany
Communication dans un congrès
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Control of the morphology of zeolite crystalsSouth and East Asia Conference on Crystal Engineering, Sep 2016, Colombo, Sri Lanka
Communication dans un congrès
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Advances in Synthesis and Applications of Nanosized Zeolites40th ENSICAEN, May 2016, Caen, France
Communication dans un congrès
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A new strategy for treatment of glioblastoma via reoxygenation using zeolites nanocrystals6th International Symposium on Advanced Micro- and Mesoporous Materials (AMMM), Sep 2015, Sunset Resort, Bulgaria
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3D study of precursor gel morphology and kinetics of EMT zeolite nucleationPasifichem, Dec 2015, Honolulu, United States
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Post-synthesis modification of zeolites by fluoride medium treatment6th Croatian – Slovenian – Serbian Symposium on Zeolites, Oct 2015, Sibenik, Croatia
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Extra-large pore zeolites by the back door25th ITQ Anniversary Symposium, Oct 2015, Valencia, Spain
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Post Synthesis Expansion of Pore Dimensions in Zeolites7th International Workshop "Characterization of Porous Materials: from Angstroms to Millimeters", May 2015, Delray, United States
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Nano Versus Hierarchical Zeolites: Advantages and Disadvantages18th Chinese Zeolite Conference, Oct 2015, Shanghai, China
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Template-free nanosized faujasite-type zeolites31eme GFZ, Mar 2015, St Valéry sur Somme, France
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BEA-type films grown in fluoride media for applications in spacecraft industry4th International FEZA, Sep 2008, PARIS, France
Communication dans un congrès
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Zeolite crystal engineering2nd European Chemistry Congress, SymposiumVI.3 "Porous Materials", Sep 2008, Torino, Italy
Communication dans un congrès
hal-00336653
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Enhanced reactivity and sensitivity of metal-containing microporous materials.Plenary lecture WS-22 Gas and Radiation Sensors : properties, characterisation - Thin Films based sensors, Jul 2008, Salamanca, Spain
Communication dans un congrès
hal-00336661
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Nanoporous zinc-silicate rods: synthesis and characterization2nd International Symposium on Advanced Micro-and Mesoporous materials, Sep 2007, VARNA, Bulgaria. pp.372-378
Communication dans un congrès
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BEA-type films grown in fluoride media for applications in spacecraft industryJournée CNES Jeunes Chercheurs, Oct 2008, Toulouse, France
Communication dans un congrès
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Oxidative dehydrogenation of propane over Fe-BEA catalysts4th International FEZA, Sep 2008, PARIS, France
Communication dans un congrès
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Development and optimization of supported MFI-type membranes for hydrogen separation4th International FEZA Conference, Sep 2008, PARIS, France
Communication dans un congrès
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Supported zeolite composite membranes synthesized by controlling the penetration or gelation of the precursor into the support pores4th International FEZA, Sep 2008, PARIS, France
Communication dans un congrès
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Control of the morphology and particle size of boehmite nanoparticles synthesized under hydrothermal conditionsJournée NanoSMS, Institut Charles Sadron, Nov 2008, Strasbourg, France
Communication dans un congrès
hal-00346236
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Enhanced reactivity and sensitivity of metal-containing microporous materials. PlenaryWS-22 Gas and Radiation Sensors: Properties, Characterisation. Thin Films based sensors, Jul 2008, Salamanca, Spain
Communication dans un congrès
hal-03860509
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BEA-type films grown in fluoride media for applications in spacecraft industry4th International FEZA, Sep 2008, Paris, France. pp.677-680
Communication dans un congrès
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Oxidative dehydrogenation of propane over Fe-BEA catalysts4th International FEZA, Sep 2008, Paris, France. pp.1127-1130
Communication dans un congrès
hal-00345704
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Supported zeolite composite membranes synthesized by controlling the penetration or gelation of the precursor into the support pores4th International FEZA, Sep 2008, Paris, France. pp.645-648
Communication dans un congrès
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Control of the morphology and particle size of boehmite nanoparticles synthesized under hydrothermal conditionsJournée de l'Ecole Doctorale, Jun 2007, Mulhouse, France
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Matériaux oxydés et carbonés à porosité organisée obtenus par nanomoulage1ère Journée Scientifique du Pôle Matériaux et Nanosciences Alsace, Nov 2007, Mulhouse, France
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From Nanoconstituents towards Zeolite Macrostructures: Crystallization Mechanism and Controlled AssemblyPolish Zeolite Conference “Forum Zeolitowa”, Sep 2007, KOCIERZ, Poland
Communication dans un congrès
hal-00186992
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Kinetics of Silicalite-1 Film Growth on Α-Al2O3 Membrane Supports2nd International Symposium on Advanced micro- and mesoporous materials, Sep 2007, Varna, Bulgaria
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hal-00165023
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Synthesis of faujasite-type zeolitic membranes: an original in-situ process focusing on the rheological control of gel-like precursor species4th International Zeolite Membrane Meeting, Jul 2007, Zaragoza, Spain
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Nanoporous zinc-silicate rods: synthesis and characterization2nd International Symposium on Advanced micro- and mesoporous materials, Sep 2007, Varna, Bulgaria
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Contrôle de la morphologie et de la taille de nanoparticules de Boehmite synthétisées par voie hydrothermaleJournée de la Communication de la Société Française de Chimie, May 2007, Mulhouse, France
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Synthesis of biocompatible boehmite nanoparticles under hydrothermal conditionsNOIS, May 2007, Lacanau-Océan, France
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Advances in NanoZeolite Science: Crystallization Mechanism, Processing and Applications15th International Zeolite Conference, Pre-Conference School, Aug 2007, DALIAN, China
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Composites comprising polycrystalline spherical cores and well intergrown shells15th International Zeolite Conference, Aug 2007, Beijing, China
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Préparation de macrostructure zéolithiques avec morphologie prédéfinie et porosité hiérarchisée3ème réunion GFZ-GECat-DivCat (39ème réunion du GECat-DivCat, 23ème réunion du GFZ), May 2007, la Grande Motte, France
Communication dans un congrès
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Fluoride media synthesis of BEA-type filmsNano Mem Course, Nov 2007, Saragosse, Spain
Communication dans un congrès
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One-step Template Extraction and Alumination of BEC-type Zeolite15th International Zeolite Conference, Aug 2007, Beijing, China
Communication dans un congrès
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Preparation of EMT-type membrane and it's characterization through nanofiltration experiments15th International Zeolite Conference, Aug 2007, Beijing, China
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Preparation of silicalite-1 membranes on flat Α-Al2O3 and tubular TiO2 supports4th International Zeolite Membrane Meeting, Jul 2007, Zaragoza, Spain
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Preparation and properties of γ-Al2O3 films prepared by high temperature transformation of nanosized γ-AlOOH precursors2nd International Symposium ‘Advanced micro and mesoporous materials', Sep 2007, Varna, Bulgaria
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One-pot Template Extraction and Alumination of BEC-type Zeolite15th International Zeolite Conference, Aug 2007, Beijing, China. pp.616-621
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HR-TEM Investigation of Gel System Yielding Different Type of Zeolitic Materials15th International Zeolite Conference, Aug 2007, Beijing, China
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Mechanism of zeolite formation: Recent AdvancesConférence à l'INSTITUT FRANCAIS DU PETROLE, Apr 2007, SOLAIZE, France
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Micro-composite formés d'une couche continue de zéolithe recouvrant un cœur de zéolithe – Etude des processus de formationJournée de l'Ecole Doctorale, Ecole doctorale Pluridisciplinaire 271, UHA, MULHOUSE, France
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Effect of sodium polyacrylate on the hydrothermal synthesis of boehmite nanoparticlesGalerne 2006 "Matériaux et Biologie II", Sep 2006, Bollwiller, France
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Structure zéolithique organisée à porosité bimodale (micro/macro)22ème Réunion du Groupe Français des Zéolithes (GFZ), Mar 2006, La Rochelle, France
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Billes zéolithiques à porosité bimodale (micro/méso)22ème Réunion du Groupe Français des Zéolithes (GFZ), Mar 2006, La Rochelle, France
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Synthesis, surface modification and controlled assembly of porous nanoscale building blocksWorkshop - CNRS/DFG, Apr 2006, Bonn, Germany
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New Materials with Potential in Membrane TechnologyClub Français des Membranes, Réunion « Membranes, Energie et Chimie », Oct 2006, Rueil Malmaison, France
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De la synthèse à l'application potentielle des nanocristaux zéolithiquesConférence à l'Institut Français du Pétrole, Feb 2006, Lyon, France
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Morpho-synthèses par l'utilisation de matériaux naturels22ème Réunion du Groupe Français des Zéolithes (GFZ), Mar 2006, La Rochelle,, France
Communication dans un congrès
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Zeolite-zeolite composites with core-shell organisationInternational Symposium on Zeolites and Microporous Crystals, Jul 2006, Yonago, Japan
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Effect of crystal size on the spectroscopic and acidic properties oh H-ZSM-5Research advances in Rational Design of Catalysts and Sorbents, Dec 2006, Lyon, France
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Caractérisations par M.E.T. et RMN du 23Na de l'évolution du gel précurseur d'une zéolithe FAU9ème Réunion de Travail RMN du Solide, Nov 2006, Baume,, France
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Gel Transformation during precursor stages of zeolite NucleationInternational Symposium on Zeolites and Microporous Crystals, Jul 2006, Yonago, Japan
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Affiche : "Morpho-synthèses par l'utilisation de matériaux naturels22ème Conférence du GFZ, 2006, La Rochelle, France
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Préparation de macrostructures par l'utilisation de nanocristaux zéolithiquesConférence au Commissariat à l'Energie Atomique (CEA), Jun 2006, Saclay, France
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Matériaux à porosité hierarchisée : Nanoduplication d'empreintes biologicalEcole Galerne 2006, «Matériaux et Biologie II», Sep 2006, Bollwiller, France
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Préparation par nanomoulage d'un nouveau carbone poreux à partir d'un moule zéolithique de type EMT22ème Réunion du Groupe Français des Zéolithes (GFZ), Mar 2006, La Rochelle, France
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Caractérisations structurales de la réplique carbonée de la zéolithe EMC-2 : comparaison entre expériences et simulationsJournées scientifiques du Groupe Français d'Etude des Carbones, (GFEC), Apr 2006, Presqu'îles de Giens, France
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Room temperature synthesis : an efficient way for studying zeolite formation2005, pp.73-80
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Porous carbon beads prepared from ion-exchange resins via amorphous silica and zeolite Beta replicasInternational Conference on Carbon ‘Carbon'05', Jul 2005, Gyeongju, South Korea
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Topics in Chemistry and Material Science: Advanced Micro- and Mesoporous Materials..K. Hadzhiivanov and G. Vayssilov and Valentin Valtchev and Svetlana Mintova. Heron Press Science Series, edition: Heron Press Ltd, 2014
Ouvrages
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Emerging Applications of Zeolites.Zeolites and Ordered Porous Solids: Fundamentals and Applications, 3rd FEZA School on Zeolites: fundamentals and applications, J. Perez-Pariente and C. Martinez (Ed.), LAIMPRENTA CG, pp.245--300, 2011
Chapitre d'ouvrage
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Bioinspired porous materialsValentin Valtchev, Svetlana Mintova, Michael Tsapatsis. Ordered Porous Solids, Recent Advances and Prospects, Elsevier, pp.477-499, 2008, Chap. 18
Chapitre d'ouvrage
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Room temperature synthesis: an efficient way for studying the zeolite formationFrom basic research to industrial applications, pp.73-80, 2005, ⟨10.1016/S0167-2991(05)80324-6⟩
Chapitre d'ouvrage
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Promotion of Methane Hydrate FormationFrance, Patent n° : EP 4 227 387. 2023
Brevet
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Post-synthetic downsizing zeolite-type crystals and/or agglomerates thereof to nanosized particlesFrance, Patent n° : EP 18306502.8. 2018
Brevet
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Communication par Affiche : "Nanoparticules de Zéolithes microporeuses et Xe hyperpolarisé2006
Autre publication scientifique
hal-00161384
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Iodine Adsorption in Tetrathiafulvalene-Based Covalent Organic Frameworks2020
Pré-publication, Document de travail
hal-03034458
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