Agnès MINGOT

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Publications

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Regulating the Acidity of HF/Pyridine Media to Control the Chemodivergent Fluoro- and Hydro-Heteroalkylation of Olefins

Mélissa Longuet , Fabien Naullet , Alexandre Pérochon , Agnès Martin-Mingot , Frédéric Guégan et al.

Journal of the American Chemical Society, 2025, 147 (32), pp.29079-29087. ⟨10.1021/jacs.5c07526⟩

Article dans une revue hal-05221813v1
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Activation of N-containing olefins and alkynes with superacids

Delphine Pichon-Barré , Hélène Carreyre , Frédéric Lecornué , Agnès Martin-Mingot , Bastien Michelet et al.

Comptes Rendus. Chimie, 2025, 28, pp.727-754. ⟨10.5802/crchim.416⟩

Article dans une revue (compte-rendu de lecture) hal-05321953v1
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Determination of the Hammett Acidity of HF/Base Reagents

Mélissa Longuet , Kassandra Vitse , Agnès Martin-Mingot , Bastien Michelet , Frédéric Guégan et al.

Journal of the American Chemical Society, 2024, ⟨10.1021/jacs.4c02344⟩

Article dans une revue (article de synthèse) hal-04552304v1

Glycosylium Ions in Superacid Mimic the Transition State of Enzyme Reactions

Mathilde Armand , Alba Nin-Hill , Ana Ardá , Emanuela Berrino , Jérôme Désiré et al.

Journal of the American Chemical Society, 2024, 146 (47), pp.32618-32626. ⟨10.1021/jacs.4c11677⟩

Article dans une revue hal-05326476v1
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Accumulation, Characterization and Reactivity of Chiral Ammonium-Carboxonium Dications in Superacid

Emanuela Berrino , Thomas Cantin , Maxime Artault , Frédéric Guégan , Agnès Mingot et al.

Angewandte Chemie International Edition, 2024, 63 (23), pp.e202404066. ⟨10.1002/anie.202404066⟩

Article dans une revue hal-04626794v1
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Leveraging long-lived arenium ions in superacid for meta-selective methylation

Paul Bourbon , Kassandra Vitse , Agnès Martin-Mingot , Hugo Geindre , Frédéric Guégan et al.

Nature Communications, 2024, 15 (1), pp.7435. ⟨10.1038/s41467-024-49421-8⟩

Article dans une revue hal-04680872v1
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Glycosylium Ions in Superacid Mimic the Transition State of Enzyme Reactions

Mathilde Armand , Alba Nin-Hill , Ana Ardá , Emanuela Berrino , Jérôme Désiré et al.

Journal of the American Chemical Society, 2024, 146 (47), pp.32618-32626. ⟨10.1021/jacs.4c11677⟩

Article dans une revue hal-05176253v1
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Superacid-Synthesized Fluorinated Diamines Act as Selective hCA IV Inhibitors

Emanuela Berrino , Bastien Michelet , Kassandra Vitse , Alessio Nocentini , Gianluca Bartolucci et al.

Journal of Medicinal Chemistry, 2024, ⟨10.1021/acs.jmedchem.4c01795⟩

Article dans une revue hal-04753033v1
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Enantioselective Organocatalysis and Superacid Activation: Challenges and Opportunities

Bastien Michelet , Agnès Martin-Mingot , Jean Rodriguez , Sébastien Thibaudeau , Damien Bonne

Chemistry - A European Journal, 2023, 29 (35), pp.e202300440. ⟨10.1002/chem.202300440⟩

Article dans une revue hal-04047011v1
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Exploring F/CF3 substituted oxocarbenium ions for the diastereoselective assembly of highly substituted tetrahydrofurans

Anthony J Fernandes , Bastien Michelet , Armen Panossian , Agnès Martin-Mingot , Frédéric R Leroux et al.

Chemical Communications, 2023, 59 (27), pp.4083-4086. ⟨10.1039/d2cc06521e⟩

Article dans une revue hal-04046996v1
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Exploring Superacid‐Promoted Skeletal Reorganization of Aliphatic Nitrogen‐Containing Compounds

Maxime Artault , Thomas Cantin , Mélissa Longuet , Kassandra Vitse , Christ Daniel Matatu Mbengo et al.

Angewandte Chemie International Edition, 2023, 63 (1), pp.e202316458. ⟨10.1002/anie.202316458⟩

Article dans une revue hal-04520297v1
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Hidden Heptacyclic Chiral N-Acyl Iminium Ions: a New Entry to Enantioenriched Polycyclic Azepanes and Azocanes by Superacid-Promoted Intramolecular Pictet-Spengler Reaction

Yasmin Reviriot , Bastien Michelet , Rodolphe Beaud , Agnès Martin-Mingot , Frédéric Guégan et al.

Chemistry - A European Journal, 2022, 28 (25), pp.e202200432. ⟨10.1002/chem.202200432⟩

Article dans une revue hal-03769652v1

Direct Superacid‐Promoted Difluoroethylation of Aromatics

Maxime Artault , Kassandra Vitse , Agnès Martin-Mingot , Sébastien Thibaudeau

Chemistry - A European Journal, 2022, 28 (6), ⟨10.1002/chem.202103926⟩

Article dans une revue hal-04139314v1
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Superacid‐Mediated Late‐Stage Aromatic Polydeuteration of Pharmaceuticals

Emeline Appert , Agnès Martin-Mingot , Omar Karam , Fabien Zunino , Bastien Michelet et al.

Chemistry - A European Journal, 2022, 28 (49), pp.e202201583. ⟨10.1002/chem.202201583⟩

Article dans une revue hal-03769665v1
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Insight into the Ferrier rearrangement by combining flash chemistry and superacids

Naresh Bhuma , Ludivine Lebedel , Hiroki Yamashita , Yutaka Shimizu , Zahra Abada et al.

Angewandte Chemie International Edition, 2021, 60 (4), pp.2036-2041. ⟨10.1002/anie.202010175⟩

Article dans une revue hal-03007376v1
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CF3-substituted carbocations: underexploited intermediates with great potential in modern synthetic chemistry

Anthony J Fernandes , Armen Panossian , Bastien Michelet , Agnès Martin-Mingot , Frédéric Leroux et al.

Beilstein Journal of Organic Chemistry, 2021, 17, pp.343-378. ⟨10.3762/bjoc.17.32⟩

Article dans une revue hal-03154651v1
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Complementary Site-Selective Sulfonylation of Aromatic Amines by Superacid Activation

Paul Bourbon , Emeline Appert , Agnès Martin-Mingot , Bastien Michelet , Sébastien Thibaudeau

Organic Letters, 2021, 23 (11), pp.4115-4120. ⟨10.1021/acs.orglett.1c00994⟩

Article dans une revue hal-03358394v1
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Modulating the Efficacy of Carbonic Anhydrase Inhibitors through Fluorine Substitution

Emanuela Berrino , Bastien Michelet , Agnès Martin-Mingot , Fabrizio Carta , Claudiu T Supuran et al.

Angewandte Chemie International Edition, 2021, 60 (43), pp.23068-23082. ⟨10.1002/anie.202103211⟩

Article dans une revue hal-03358401v1
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Formation of synthetically relevant CF3-substituted phenonium ions in superacid media

Anthony J Fernandes , Bastien Michelet , Armen Panossian , Agnès Martin-Mingot , Frédéric R. Leroux et al.

RSC Advances, 2021, 11 (41), pp.25695 - 25699. ⟨10.1039/d1ra04901a⟩

Article dans une revue hal-03325280v1
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Superelectrophilic Csp 3 –H bond fluorination of aliphatic amines in superacid: the striking role of ammonium–carbenium dications

Maxime Artault , N. Mokhtari , T. Cantin , Agnès Martin-Mingot , Sébastien Thibaudeau

Chemical Communications, 2020, 56 (44), pp.5905-5908. ⟨10.1039/d0cc02081h⟩

Article dans une revue hal-04537283v1
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Enantioenriched Methylene-Bridged Benzazocanes Synthesis by Organocatalytic and Superacid Activations

Rodolphe Beaud , Bastien Michelet , Yasmin Reviriot , Agnès Martin-Mingot , Jean Rodriguez et al.

Angewandte Chemie International Edition, 2020, 59 (3), pp.1279-1285. ⟨10.1002/anie.201912043⟩

Article dans une revue hal-02436747v1
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Evidence and exploitation of dicationic ammonium–nitrilium superelectrophiles: direct synthesis of unsaturated piperidinones

Thomas Cantin , Yvonne Morgenstern , Agnès Mingot , Andreas Kornath , Sébastien Thibaudeau

Chemical Communications, 2020, 56 (75), pp.11110-11113. ⟨10.1039/d0cc02910f⟩

Article dans une revue hal-04537571v1
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Complementary Site‐Selective Halogenation of Nitrogen‐Containing (Hetero)Aromatics with Superacids

Alexander Mamontov , Agnès Martin-Mingot , Benoit Métayer , Omar Karam , Fabien Zunino et al.

Chemistry - A European Journal, 2020, 26 (46), pp.10411-10416. ⟨10.1002/chem.202000902⟩

Article dans une revue hal-04537186v1
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Access to Optically-Pure Benzosultams by Superelectrophilic Activation

Bastien Michelet , Ugo Castelli , Emeline Appert , Maude Boucher , Kassandra Vitse et al.

Organic Letters, 2020, 22 (13), pp.4944-4948. ⟨10.1021/acs.orglett.0c01301⟩

Article dans une revue hal-03016554v1

Direct and Selective C-H Carbamoylation of (Hetero)aromatics with TMSOTf-Activated Carbamoyl Chloride

Ayaka Uehara , Sandra Olivero , Bastien Michelet , Agnès Martin-Mingot , Sébastien Thibaudeau et al.

European Journal of Organic Chemistry, 2019, 2019 (1), pp.46-49. ⟨10.1002/ejoc.201801338⟩

Article dans une revue hal-03007761v1

Evidence of Phosphonium-Carbenium Dication Formation in a Superacid: Precursor to Fluorinated Phosphine Oxides

Ugo Castelli , Jean-François Lohier , Ines Drukenmüller , Agnès Mingot , Christian Bachman et al.

Angewandte Chemie International Edition, 2019, 58 (5), pp.1355-1360. ⟨10.1002/anie.201811032⟩

Article dans une revue hal-02159927v1

Superelectrophilic activation in superacid HF/SbF5: Expanding molecular diversity in nitrogen-containing compounds series by fluorination

Bastien Michelet , Hélène Carreyre , Frédéric Lecornué , Agnès Mingot , Sébastien Thibaudeau

Journal of Fluorine Chemistry, 2018, 214, pp.68-79. ⟨10.1016/j.jfluchem.2018.04.017⟩

Article dans une revue istex hal-03007791v1
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Fluoroenesulphonamides: N -sulphonylurea isosteres showing nanomolar selective cancer-related transmembrane human carbonic anhydrase inhibition

Benoit Metayer , Andrea Angeli , Agnès Mingot , Kévin Jouvin , Gwilherm Evano et al.

Journal of Enzyme Inhibition and Medicinal Chemistry, 2018, 33 (1), pp.804-808. ⟨10.1080/14756366.2018.1461097⟩

Article dans une revue hal-02169774v1

Cationic polycyclization of ynamides: building up molecular complexity

Cédric Theunissen , Benoit Metayer , Morgan Lecomte , Nicolas Henry , Hwai-Chien Chan et al.

Organic & Biomolecular Chemistry, 2017, 15 (20), pp.4399-4416. ⟨10.1039/C7OB00850C⟩

Article dans une revue hal-02173400v1

HF-Induced Intramolecular C -Arylation and C -Alkylation/Fluorination of 2-Aminoglycopyranoses

Nicolas Probst , Amélie Martin , Jérôme Désiré , Agnès Mingot , Jerome Marrot et al.

Organic Letters, 2017, 19 (5), pp.1040 - 1043. ⟨10.1021/acs.orglett.7b00003⟩

Article dans une revue hal-01743477v1

Superacid-Catalyzed Trifluoromethylthiolation of Aromatic Amines

Longin Justin Clair Bonazaba milandou , Hélène Carreyre , Sébastien Alazet , Gino Greco , Agnès Martin-Mingot et al.

Angewandte Chemie, 2017, 129 (1), pp.175 - 178. ⟨10.1002/ange.201609574⟩

Article dans une revue hal-01598373v1

Innenrücktitelbild: Superacid-Catalyzed Trifluoromethylthiolation of Aromatic Amines (Angew. Chem. 1/2017)

Longin Justin Clair Bonazaba milandou , Hélène Carreyre , Sébastien Alazet , Gino Greco , Agnès Martin-Mingot et al.

Angewandte Chemie, 2017, 129 (1), pp.429 - 429. ⟨10.1002/ange.201611312⟩

Article dans une revue hal-01610193v1

Inside Back Cover: Superacid-Catalyzed Trifluoromethylthiolation of Aromatic Amines (Angew. Chem. Int. Ed. 1/2017)

Longin Justin Clair Bonazaba milandou , Hélène Carreyre , Sébastien Alazet , Gino Greco , Agnès Martin-Mingot et al.

Angewandte Chemie International Edition, 2017, 56 (1), pp.417 - 417. ⟨10.1002/anie.201611312⟩

Article dans une revue hal-01610196v1

A Journey in the Chemistry of Ynamides: From Synthesis to Applications

Gwilherm Evano , Nicolas Blanchard , Guillaume Compain , Alexis Coste , Charles Demmer et al.

Chemistry Letters, 2016, 45 (6), pp.574-585. ⟨10.1246/cl.160260⟩

Article dans une revue hal-03007853v1

Tandem superelectrophilic activation for the regioselective chlorofluorination of recalcitrant allylic amines

Le Darz Alexandre , Ugo Castelli , Naima Mokhtari , Agnès Martin-Mingot , Jerôme Marrot et al.

Tetrahedron, 2016, 72, pp.674-689 ⟨10.1016/j.tet.2015.12.013⟩

Article dans une revue istex hal-01505611v1

Catching elusive glycosyl cations in a condensed phase with HF/SbF₅ superacid

A. Martin , A. Arda , J. Désiré , A. Martin-Mingot , N. Probst et al.

Nature Chemistry, 2016, ⟨10.1038/nchem.2399⟩

Article dans une revue hal-01505628v1
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Synthetic deoxynojirimycin derivatives bearing a thiolated, fluorinated or unsaturated N-alkyl chain: identification of potent α-glucosidase and trehalase inhibitors as well as F508del-CFTR correctors.

V. Cendret , T. Legigan , A. Martin-Mingot , S. Thibaudeau , I. Adachi et al.

Organic & Biomolecular Chemistry, 2015, 13 (43), pp.10734-10744. ⟨10.1039/c5ob01526j⟩

Article dans une revue hal-01500682v1

Chemo- and Stereoselective Synthesis of Fluorinated Enamides from Ynamides in HF/Pyridine: Second-Generation Approach to Potent Ureas Bioisosteres

Benoit Metayer , Guillaume Compain , Kevin Jouvin , Agnès Martin-Mingot , Christian Bachmann et al.

Journal of Organic Chemistry, 2015, 80, pp.3397-3410. ⟨10.1021/jo502699y⟩

Article dans une revue hal-01360121v1

Keteniminium Ion-Initiated Cascade Cationic Polycyclization

C. Theunissen , B. Metayer , E. Henry , G. Compain , J. Marrot et al.

Journal of the American Chemical Society, 2014, 136 (36), pp.12528-12531. ⟨10.1021/ja504818p⟩

Article dans une revue hal-01063189v1

Superacid synthesis of halogen containing N-substituted-4-aminobenzene sulfonamides: New selective tumor-associated carbonic anhydrase inhibitors

G. Compain , A. Martin-Mingot , A. Maresca , S. Thibaudeau , C. T. Supuran

Bioorganic and Medicinal Chemistry, 2013, 21 (6), pp.1555-1563. ⟨10.1016/j.bmc.2012.05.037⟩

Article dans une revue hal-00839204v1

Superacid synthesized tertiary benzenesulfonamides and benzofuzed sultams act as selective hCA IX inhibitors: toward understanding a new mode of inhibition by tertiary sulfonamides

B. Metayer , A. Martin-Mingot , D. Vullo , C.T. Supuran , S. Thibaudeau

Organic & Biomolecular Chemistry, 2013, 11 (43), pp.7540-7549. ⟨10.1039/c3ob41538d⟩

Article dans une revue hal-00964957v1

Selective Anti-Markovnikov Cyclization and Hydrofluorination2 Reaction in Superacid HF/SbF5: A Tool in the Design of Nitrogen-Containing (Fluorinated) Polycyclic Systems

G. Compain , C. Bonneau , A. Martin-Mingot , S. Thibaudeau

Journal of Organic Chemistry, 2013, 78, pp.4463-4472. ⟨10.1021/jo400398y⟩

Article dans une revue hal-00918382v1

Stereoselective hydrofluorination of ynamides: a straightforward synthesis of novel alpha-fluoroenamides

G. Compain , K. Jouvin , A. Martin-Mingot , G. Evano , J. Marrot et al.

Chemical Communications, 2012, 48 (42), pp.5196-5198. ⟨10.1039/c2cc31768k⟩

Article dans une revue hal-00834286v1

Anti-Markovnikov additions to N-allylic derivatives involving ammonium-carbenium superelectrophiles

G. Compain , A. Martin-Mingot , G. Frapper , M.P. Jouannetaud , S. Thibaudeau

Chemical Communications, 2012, 48 (47), pp.5877-5879. ⟨10.1039/c2cc32246c⟩

Article dans une revue hal-00820212v1

Dications in superacid HF/SbF5: When superelectrophilic activation makes possible fluorination and/or C-H bond activation

A. Martin-Mingot , G. Compain , Franklin Liu , M.P. Jouannetaud , C. Bachmann et al.

Journal of Fluorine Chemistry, 2012, 134 (SI), pp.56-62. ⟨10.1016/j.jfluchem.2011.04.022⟩

Article dans une revue istex hal-00826922v1

High efficiency of superacid HF-SbF5 for the selective decrystallization-depolymerization of cellulose to glucose.

Agnès Martin-Mingot , Karine de Oliveira Vigier , François Jérôme , Sébastien Thibaudeau

Organic & Biomolecular Chemistry, 2012, 10 (13), pp.2521-4. ⟨10.1039/c2ob07143f⟩

Article dans une revue hal-00726568v1

Carbonic Anhydrases inhibitory effects of new benzenesulfonamides synthesized by using superacid chemistry

F. Lin , A. Martin-Mingot , F. Lecornué , M.P. Jouannetaud , A. Maresca et al.

Journal of Enzyme Inhibition and Medicinal Chemistry, 2012, 27 (6), pp.886-891. ⟨10.3109/14756366.2011.638921⟩

Article dans une revue hal-00823328v1

Deactivation and reactivation of noble metal catalysts tested in the Catalytic Wet Air Oxidation of phenol

Sylvain Keav , Agnès Martin , Jacques Barbier Jr. , Daniel Duprez

Catalysis Today, 2010, 151 (1-2), pp.143-147. ⟨10.1016/j.cattod.2010.01.025⟩

Article dans une revue hal-04999424v1

Nature du dépôt formé au cours de l’oxydation en voie humide catalysée du phénol

Sylvain Keav , Agnès Martin , Jacques Barbier Jr. , Daniel Duprez

Comptes Rendus. Chimie, 2010, 13 (5), pp.508-514. ⟨10.1016/j.crci.2010.02.001⟩

Article dans une revue hal-04999419v1