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    50

    Publications


    Journal articles41 documents

    • Bruno Fabre, Clement Falaise, Emmanuel Cadot. Polyoxometalates-Functionalized Electrodes for (Photo)Electrocatalytic Applications: Recent Advances and Prospects. ACS Catalysis, 2022, 12 (19), pp.12055-12091. ⟨10.1021/acscatal.2c01847⟩. ⟨hal-03827489⟩
    • Sa Yao, Clement Falaise, Nathalie Leclerc, Catherine Roch-Marchal, Mohamed Haouas, et al.. Improvement of the Hydrolytic Stability of the Keggin Molybdo- and Tungsto-Phosphate Anions by Cyclodextrins. Inorganic Chemistry, 2022, 61 (9), pp.4193-4203. ⟨10.1021/acs.inorgchem.2c00095⟩. ⟨hal-03642661⟩
    • Anton Ivanov, Mohamed Haouas, Darya Evtushok, Tatiana Pozmogova, Tatiana Golubeva, et al.. Stabilization of Octahedral Metal Halide Clusters by Host–Guest Complexation with γ-Cyclodextrin: Toward Nontoxic Luminescent Compounds. Inorganic Chemistry, 2022, 61 (36), pp.14462-14469. ⟨10.1021/acs.inorgchem.2c02468⟩. ⟨hal-03774212⟩
    • Soumaya Khlifi, Jérôme Marrot, Mohamed Haouas, William Shepard, Clement Falaise, et al.. Chaotropic Effect as Assembly Motif to Construct Supramolecular Cyclodextrin-Polyoxometalate based Frameworks. Journal of the American Chemical Society, 2022, 144 (10), pp.4469-4477. ⟨10.1021/jacs.1c12049⟩. ⟨hal-03645356⟩
    • Ibrahima Fa Bamba, Clément Falaise, Jérôme Marrot, Gildas K Gbassi, Patrick Atheba, et al.. Revisiting the Three-Vanadium Sandwich Type Polyoxometalates: Structures, Solution Behavior and Redox Properties. Inorganic Chemistry, 2022, 61 (21), pp.8309-8319. ⟨10.1021/acs.inorgchem.2c00776⟩. ⟨hal-03703957⟩
    • Nathalie Leclerc, Mohamed Haouas, Clement Falaise, Serge Al Bacha, Loïc Assaud, et al.. Supramolecular Association between γ-Cyclodextrin and Preyssler-Type Polyoxotungstate. Molecules, 2021, 26 (17), pp.5126. ⟨10.3390/molecules26175126⟩. ⟨hal-03347643⟩
    • Ibrahima Fa Bamba, Clement Falaise, Jérôme Marrot, Patrick Atheba, Gildas Gbassi, et al.. Host‐Guest Complexation Between Cyclodextrins and Hybrid Hexavanadates: What are the Driving Forces?. Chemistry - A European Journal, In press, ⟨10.1002/chem.202102684⟩. ⟨hal-03380437⟩
    • Yevheniia Smortsova, Clement Falaise, Anam Fatima, Minh‐huong Ha‐thi, Rachel Méallet‐renault, et al.. Time-Resolved Spectroscopy and High Efficiency Light-driven Hydrogen Evolution of a {Mo 3 S 4 }-Containing Polyoxometalate-Based System. Chemistry - A European Journal, In press, ⟨10.1002/chem.202102693⟩. ⟨hal-03415475⟩
    • Clement Falaise, Soumaya Khlifi, Pierre Bauduin, Philipp Schmid, William Shepard, et al.. Host in Host Supramolecular Core-Shell Type Systems Based on Giant Ring-Shaped Polyoxometalates. Angewandte Chemie International Edition, 2021, 60 (25), pp.14146-14153. ⟨10.1002/anie.202102507⟩. ⟨hal-03194295⟩
    • Ibrahima Fa Bamba, Clement Falaise, Gildas Gbassi, Patrick Atheba, Mohamed Haouas, et al.. N-tert-butoxycarbonyl (BOC) protected [V 6 O 13 {(OCH 2 ) 3 CNH 2 } 2 ] 2− : synthesis, structural characterization, and solution behavior. Journal of Coordination Chemistry, In press, pp.1-12. ⟨10.1080/00958972.2020.1830074⟩. ⟨hal-03000863⟩
    • Sa Yao, Clement Falaise, Anton Ivanov, Nathalie Leclerc, Max Hohenschutz, et al.. Hofmeister effect in the Keggin-type polyoxotungstate series. Inorganic Chemistry Frontiers, 2020, ⟨10.1039/D0QI00902D⟩. ⟨hal-03000838⟩
    • Ian Colliard, Clement Falaise, May Nyman. Bridging the Transuranics with Uranium(IV) Sulfate Aqueous Species and Solid Phases. Inorganic Chemistry, 2020. ⟨hal-03018170⟩
    • Anton Ivanov, Clement Falaise, Alexandra A Shmakova, Nathalie Leclerc-Laronze, Stéphane Cordier, et al.. Cyclodextrin-Assisted Hierarchical Aggregation of Dawson-type Polyoxometalate in the Presence of {Re6Se8} Based Clusters. Inorganic Chemistry, 2020, 59 (16), pp.11396-11406. ⟨10.1021/acs.inorgchem.0c01160⟩. ⟨hal-02930227⟩
    • Anton Ivanov, Tatiana Pozmogova, Anastasiya Solovieva, Tatiana Frolova, Olga Sinitsyna, et al.. From Specific γ‐CD/[Nb 6 Cl 12 (H 2 O) 6 ] 2+ Recognition to Biological Activity Tuning. Chemistry - A European Journal, 2020, 26 (33), pp.7479-7485. ⟨10.1002/chem.202000739⟩. ⟨hal-03000995⟩
    • Clement Falaise, A Ivanov, Yann Molard, Maria Amela-Cortés, Michael A. Shestopalov, et al.. From supramolecular to solid state chemistry: crystal engineering of luminescent materials by trapping molecular clusters in an aluminium-based host matrix. Materials Horizons, 2020, 7 (9), pp.2399-2406. ⟨10.1039/d0mh00637h⟩. ⟨hal-02948359⟩
    • Jeoffrey Tourneur, Bruno Fabre, Gabriel Loget, Antoine Vacher, Cristelle Mériadec, et al.. Molecular and Material Engineering of Photocathodes Derivatized with Polyoxometalate-Supported {Mo3S4} HER Catalysts. Journal of the American Chemical Society, 2019, 141 (30), pp.11954-11962. ⟨10.1021/jacs.9b03950⟩. ⟨hal-02278037⟩
    • Anton Ivanov, Clement Falaise, David Landy, Mohamed Haouas, Yuri V Mironov, et al.. Tuning the chaotropic effect as an assembly motif through one-electron transfer in a rhenium cluster. Chemical Communications, 2019, 55 (67), pp.9951-9954. ⟨10.1039/c9cc05136h⟩. ⟨hal-02335733⟩
    • Manal Diab, Sébastien Floquet, Mohamed Haouas, Pavel Abramov, Xavier López, et al.. Encapsulation of Chaotropic closo -Decahydrodecaborate Clusters Within Cyclodextrins: Synthesis, Solution Studies, and DFT Calculations. European Journal of Inorganic Chemistry, 2019, 2019 (29), pp.3373-3382. ⟨10.1002/ejic.201900602⟩. ⟨hal-02335711⟩
    • Anton A Ivanov, Clement Falaise, Kevin Laouer, François Hache, Pascale Changenet, et al.. Size-Exclusion Mechanism Driving Host-Guest Interactions between Octahedral Rhenium Clusters and Cyclodextrins. Inorganic Chemistry, 2019, 58 (19), pp.13184-13194. ⟨10.1021/acs.inorgchem.9b02048⟩. ⟨hal-02307027⟩
    • Clement Falaise, Karoly Kozma, May Nyman. Thorium Oxo‐Clusters as Building Blocks for Open Frameworks. Chemistry - A European Journal, 2018, 24 (53), pp.14226-14232. ⟨10.1002/chem.201802671⟩. ⟨hal-02339812⟩
    • Anton A Ivanov, Clement Falaise, Pavel A Abramov, Michael A Shestopalov, Kaplan Kirakci, et al.. Host-Guest Binding Hierarchy within Redox- and Luminescence-Responsive Supramolecular Self-Assembly Based on Chalcogenide Clusters and γ-Cyclodextrin. Chemistry - A European Journal, 2018, 24 (51), pp.13467-13478. ⟨10.1002/chem.201802102⟩. ⟨hal-01863768⟩
    • Clement Falaise, Mhamad Aly Moussawi, Sébastien Floquet, Pavel Abramov, Maxim Sokolov, et al.. Probing Dynamic Library of Metal-Oxo Building Blocks with γ-Cyclodextrin. Journal of the American Chemical Society, 2018, 140 (36), pp.11198-11201. ⟨10.1021/jacs.8b07525⟩. ⟨hal-02335637⟩
    • Mohamed Haouas, Clement Falaise, Charlotte Martineau-Corcos, Emmanuel Cadot. Cyclodextrin-Driven Formation of Double Six-Ring (D6R) Silicate Cage: NMR Spectroscopic Characterization from Solution to Crystals. Crystals, 2018, 8 (12), pp.457. ⟨10.3390/cryst8120457⟩. ⟨hal-02335645⟩
    • Clement Falaise, Christophe Volkringer, Raynald Giovine, Benedicte Prelot, Marielle Huvé, et al.. Capture of actinides (Th4+, [UO2]2+) and surrogating lanthanide (Nd3+) in the porous Metal-Organic Framework MIL-100(Al) from water : selectivity and imaging of embedded nanoparticles. Dalton Transactions, 2017, 46, pp.12010-12014. ⟨10.1039/C7DT02155K⟩. ⟨hal-01573645⟩
    • Nicolas Martin, Christophe Volkringer, Clement Falaise, Natacha Henry, Thierry Loiseau. Synthesis and Crystal Structure Characterization of Thorium Trimesate Coordination Polymers. Crystal Growth & Design, 2016, 16 (3), pp.1667 - 1678. ⟨10.1021/acs.cgd.5b01746⟩. ⟨hal-01782551⟩
    • Clement Falaise, J. Delille, C. Volkringer, H. Vezin, P. Rabu, et al.. Series of hydrated heterometallic uranyl-cobalt(II) coordination polymers with aromatic polycarboxylate ligands: Formation of U=O—Co bonding upon dehydration process. Inorganic Chemistry, 2016, 55 (20), pp.10453 - 10466. ⟨10.1021/acs.inorgchem.6b01697⟩. ⟨hal-01399287⟩
    • Nicolas Martin, Clement Falaise, Christophe Volkringer, Natacha Henry, Pierre Farger, et al.. Hydrothermal Crystallization of Uranyl Coordination Polymers Involving an Imidazolium Dicarboxylate Ligand: Effect of pH on the Nuclearity of Uranyl-Centered Subunits. Inorganic Chemistry, 2016, 55 (17), pp.8697 - 8705. ⟨10.1021/acs.inorgchem.6b01232⟩. ⟨hal-01782670⟩
    • Alexis Munn, Franck Millange, Michel Frigoli, Nathalie Guillou, Clement Falaise, et al.. Iodine sequestration by thiol-modified MIL-53(Al). CrystEngComm, 2016, 18 (41), pp.8108 - 8114. ⟨10.1039/c6ce01842d⟩. ⟨hal-01782683⟩
    • C. Volkringer, Clement Falaise, P. Devaux, R. Giovine, V. Stevenson, et al.. Stability of metal–organic frameworks under gamma irradiation. Chemical Communications, 2016, 52 (84), pp.12502 - 12505. ⟨10.1039/c6cc06878b⟩. ⟨hal-01782677⟩
    • Clement Falaise, Christoph Volkringer, Christoph Hennig, Thierry Loiseau. Ex-Situ Kinetic Investigations of the Formation of the Poly-Oxo Cluster U38. Chemistry - A European Journal, 2015, 21 (46), pp.16654 - 16664. ⟨10.1002/chem.201502207⟩. ⟨hal-01780684⟩
    • Clement Falaise, Jason Delille, Christophe Volkringer, Thierry Loiseau. Solvothermal Synthesis of Tetravalent Uranium with Isophthalate or Pyromellitate Ligands. European Journal of Inorganic Chemistry, 2015, 2015 (17), pp.2813 - 2821. ⟨10.1002/ejic.201500204⟩. ⟨hal-01780676⟩
    • Clement Falaise, Jean-Sébastien Charles, Christophe Volkringer, Thierry Loiseau. Thorium Terephthalates Coordination Polymers Synthesized in Solvothermal DMF/H2O System. Inorganic Chemistry, 2015, 54 (5), pp.2235 - 2242. ⟨10.1021/ic502725y⟩. ⟨hal-01780626⟩
    • Clement Falaise, Ayalew Assen, Ionut Mihalcea, Christophe Volkringer, Adel Mesbah, et al.. Coordination polymers of uranium( iv ) terephthalates. Dalton Transactions, 2015, 44 (6), pp.2639 - 2649. ⟨10.1039/C4DT02343A⟩. ⟨hal-01780615⟩
    • Sylvain Duval, Sébastien Béghin, Clement Falaise, Xavier Trivelli, Pierre Rabu, et al.. Stabilization of Tetravalent 4f (Ce), 5d (Hf), or 5f (Th, U) Clusters by the [α-SiW9O34 ]10– Polyoxometalate. Inorganic Chemistry, 2015, 54 (17), pp.8271 - 8280. ⟨10.1021/acs.inorgchem.5b00786⟩. ⟨hal-01780681⟩
    • Ionut Mihalcea, Clement Falaise, Christophe Volkringer, Natacha Henry, Thierry Loiseau. Room temperature crystallization of trichlorodioxouranate [UO2Cl3(L)] species in molecular assemblies involving aliphatic dicarboxylate linkers. Inorganic Chemistry Communications, 2014, 44, pp.63 - 66. ⟨10.1016/j.inoche.2014.02.040⟩. ⟨hal-01780309⟩
    • Clement Falaise, Christophe Volkringer, Thierry Loiseau. Isolation of thorium benzoate polytypes with discrete ThO8 square antiprismatic units involved in chain-like assemblies. Inorganic Chemistry Communications, 2014, 39, pp.26 - 30. ⟨10.1016/j.inoche.2013.10.030⟩. ⟨hal-01780286⟩
    • Clement Falaise, Christophe Volkringer, Jean-François Vigier, Arnaud Beaurain, Pascal Roussel, et al.. Isolation of the Large {Actinide} 38 Poly-oxo Cluster with Uranium. Journal of the American Chemical Society, 2013, 135 (42), pp.15678 - 15681. ⟨10.1021/ja4067207⟩. ⟨hal-01780283⟩
    • Clement Falaise, Christophe Volkringer, Thierry Loiseau. Mixed Formate-Dicarboxylate Coordination Polymers with Tetravalent Uranium: Occurrence of Tetranuclear {U 4 O 4 } and Hexanuclear {U 6 O 4 (OH) 4 } Motifs. Crystal Growth & Design, 2013, 13 (7), pp.3225 - 3231. ⟨10.1021/cg400643g⟩. ⟨hal-01780273⟩
    • Clement Falaise, Christophe Volkringer, Jean-François Vigier, Natacha Henry, Arnaud Beaurain, et al.. Three-Dimensional MOF-Type Architectures with Tetravalent Uranium Hexanuclear Motifs (U 6 O 8 ). Chemistry - A European Journal, 2013, 19 (17), pp.5324 - 5331. ⟨10.1002/chem.201203914⟩. ⟨hal-01780264⟩
    • Jakub Olchowka, Clement Falaise, Christophe Volkringer, Natacha Henry, Thierry Loiseau. Structural Observations of Heterometallic Uranyl Copper(II) Carboxylates and Their Solid-State Topotactic Transformation upon Dehydration. Chemistry - A European Journal, 2013, 19 (6), pp.2012 - 2022. ⟨10.1002/chem.201203748⟩. ⟨hal-01780234⟩
    • Clement Falaise, Christophe Volkringer, Jacques Facqueur, Till Bousquet, Laurent Gasnot, et al.. Capture of iodine in highly stable metal–organic frameworks: a systematic study. Chemical Communications, 2013, 49 (87), ⟨10.1039/C3CC43728K⟩. ⟨hal-01780277⟩

    Conference papers9 documents

    • Sylvain Duval, Sébastien Béghin, Clement Falaise, Xavier Trivelli, Pierre Rabu, et al.. Stabilisation de clusters tétravalents 4f (Ce), 5d (Hf) et 5f (Th, U) par le polyoxométallate [SiW9O34]10. Congrès 2015 de la Société Chimique de France, Jul 2015, Lille, France. ⟨hal-02320013⟩
    • Christophe Volkringer, Clement Falaise, Raynald Giovine, Philippe Devaux, Marielle Declomesnil, et al.. Capture de radionucléides dans les solides poreux de type Metal-Organique Framework. Congrès 2015 de la Société Chimique de France, Jul 2015, Lille, France. ⟨hal-02318810⟩
    • Nicolas P. Martin, Clement Falaise, Christophe Volkringer, Natacha Henry, Thierry Loiseau. Synthèse et caractérisation de nouveaux trimésates de thorium. Congrès 2015 de la Société Chimique de France, Jul 2015, Lille, France. ⟨hal-02320164⟩
    • Clement Falaise, Christophe Volkringer, Christoph Hennig, Thierry Loiseau. Chemistry of tetravalent actinide (U and Th) carboxylates: isolation of oxo/hydroxo polynuclear clusters. Pacifichem 2015, Dec 2015, Honolulu, United States. ⟨hal-02318873⟩
    • Nicolas P. Martin, Clement Falaise, Christophe Volkringer, Natacha Henry, Thierry Loiseau. Synthesis and characterization of new thorium-based carboxylates. Journées Nord-Ouest Européennes des Jeunes Chercheurs, May 2015, Rouen, France. ⟨hal-02320107⟩
    • Raynald Giovine, Clement Falaise, Christophe Volkringer, Philippe Devaux, Marielle Declomesnil, et al.. Capture of radionuclides in Metal-Organique Framework (MOF). Journées Nord-Ouest Européennes des Jeunes Chercheurs, May 2015, Rouen, France. ⟨hal-02318846⟩
    • Christophe Volkringer, Clement Falaise, Raynald Giovine, Philippe Devaux, Marielle Declomesnil, et al.. Capture de radionucléides dans les solides poreux de type Metal-Organique Framework. 4ème journées de l’Association Française de l’Adsorption (AFA), Feb 2015, Paris, France. ⟨hal-02318787⟩
    • Christophe Volkringer, Clement Falaise, Raynald Giovine, Philippe Devaux, Bénédicte Prelot, et al.. Capture of radionuclides in porous metal organic frameworks (MOFs). 39th Edition of the MRS 2015 – Scientific Basis for Nuclear Waste Management, Nov 2015, Montpellier, France. ⟨hal-02318849⟩
    • Christophe Volkringer, Clement Falaise, Raynald Giovine, Philippe Devaux, Marielle Declomesnil, et al.. Capture de radionucléides dans les solides poreux de type Metal-Organique Framework. Groupe Français des Zéolithes, Mar 2015, Saint Valéry s/Somme, France. ⟨hal-02318816⟩