Eddy Dib

70 %
Libre accès
61
Documents
Affiliations actuelles
  • Conditions Extrêmes et Matériaux : Haute Température et Irradiation (CEMHTI)
  • Laboratoire catalyse et spectrochimie (LCS)
Contact

Présentation

Mes recherches portent sur la compréhension des relations entre l'agencement atomique et les propriétés des zéolites et des zéotypes, notamment les aluminophosphates. J'associe des méthodes de synthèse et de modification à des approches spectroscopiques et de modélisation afin de contrôler la distribution des sites actifs. Mes travaux se concentrent sur l'interface organique-inorganique ou gaz-solide pour comprendre la formation des cristaux, sonder la connectivité des pores et améliorer la réactivité et les phénomènes d'adsorption.


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Publications

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Tuning the arrangement of atoms in SAPO-34 molecular sieves for a deeper understanding of their performance in the MTO reaction

Ludovica Pace , Junwei Wu , Marco G Geloso , Francesco Dalena , Diogenes Honorato-Piva et al.

Catalysis Science & Technology, 2026, ⟨10.1039/D5CY01271F⟩

Article dans une revue hal-05474160v1
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Time-Domain NMR to investigate the confinement of water in ultra-thin BPH zeolites

Svetlana Mintova , Mariia Ivanova , Eddy Dib , Edwin B. Clatworthy , Leonid Grunin Article dans une revue hal-05474182v1
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Spectroscopic characterization of black N- and P-doped zeolite templated carbons

Shuang Tan , Francesco Dalena , Igor Golub , Eddy Dib , Oleg Filippov et al.

Microporous and Mesoporous Materials, 2025, 381, ⟨10.1016/j.micromeso.2024.113347⟩

Article dans une revue hal-04760400v1
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Enhanced Catalytic Ring-Opening of Propylene Oxide Using a Germanium Containing MFI Zeolite Catalyst with High Selectivity

Francesco Dalena , Qiudi Yue , Eddy Dib , Abdelhafid Aitblal , Diogenes Honorato Piva et al.

ACS Catalysis, 2025, 15 (10), pp.8024-8035. ⟨10.1021/acscatal.5c01891⟩

Article dans une revue hal-05142618v1
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Asymmetric molecular-driven aluminum distribution and nanocrystalline assembly in BEA zeolite catalyst

Bo Wang , Eddy Dib , Xinyu You , Ruizhe Zhang , Yanfeng Shen et al.

ACS Catalysis, 2025, 15, pp.19410-19423. ⟨10.1021/acscatal.5c04930⟩

Article dans une revue hal-05368744v1
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Weaving zeolite into long-lived catalysts

Bo Wang , Zhengxing Qin , Ruizhe Zhang , Simona Moldovan , Nourrdine Chaouati et al.

Advanced Functional Materials, 2025, ⟨10.1002/adfm.202528025⟩

Article dans une revue hal-05474133v1
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Tuning the atomic ordering of AFI framework with templates charge

Eddy Dib , Ludovica Pace , Vincent Sarou-Kanian , Francesco Dalena , Diogenes Honorato-Piva et al.

Microporous and Mesoporous Materials, 2025, 381, pp.113339. ⟨10.1016/j.micromeso.2024.113339⟩

Article dans une revue hal-05142707v1
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Germanium atoms exceed the tetrahedral coordination in MFI zeolite

Eddy Dib , Qiudi Yue , Giorgia Confalonieri , Davide Salusso , Georgi Vayssilov et al.

Journal of the American Chemical Society, 2025, 147 (4), pp.3274-3282. ⟨10.1021/jacs.4c13278⟩

Article dans une revue hal-05142700v1
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The impact of “empty-corner” tetrahedra in the synthesis of MFI type zeolites: unveiling selenium stereoactivity

Mishel Markovski , Abdallah Amedlous , Eddy Dib , Anna Kaleta , Francesco Dalena et al.

Inorganic Chemistry Frontiers, 2025, 12, pp.3886-3897. ⟨10.1039/d5qi00567a⟩

Article dans une revue hal-05011660v1
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Simultaneous Modulation of Mesoporosity and Al Siting for Superior Performance Zeolite Catalyst in Ethylene Dehydroaromatization to Aromatics

Yanfeng Shen , Zhengxing Qin , Antoine Beuque , Eddy Dib , Shunsuke Asahina et al.

Angewandte Chemie International Edition, 2025, 64 (37), pp.e202508909. ⟨10.1002/anie.202508909⟩

Article dans une revue hal-05368552v1
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Boron's role in altering MFI-type zeolite

Vladislav Rac , Vesna Rakić , Ana Palčić , Eddy Dib , Georgeta Postole et al.

Microporous and Mesoporous Materials, 2025, 384, pp.113454. ⟨10.1016/j.micromeso.2024.113454⟩

Article dans une revue hal-05362964v1
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Evaluation of zeolite composites by IR and NMR spectroscopy

Francesco Dalena , Eddy Dib , Barbara Onida , Giorgia Ferrarelli , Marco Daturi et al.

Molecules, 2024, 29 (18), pp.4450. ⟨10.3390/molecules29184450⟩

Article dans une revue hal-04808051v1
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Elucidating Silanol Removal in MFI Nanosized Zeolites Through Controlled Post-Synthesis Hydrothermal Treatments

Hugo Cruchade , Francesco Dalena , Eddy Dib , Abdelhafid Aitblal , Diogenes Honorato Piva et al.

Surfaces and Interfaces, 2024, 55, pp.105360. ⟨10.1016/j.surfin.2024.105360⟩

Article dans une revue hal-04808048v1
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Highly hydrophobic zeolite ZSM-8 with perfect framework structure obtained in a strongly acidic medium

Yiqing Sun , Qiaolin Lang , Guangying Fu , Haonuan Zhao , Eddy Dib et al.

Microporous and Mesoporous Materials, 2024, 363, pp.112839. ⟨10.1016/j.micromeso.2023.112839⟩

Article dans une revue hal-04285111v1
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Ultra-thin BPH nanosheets with exceptional water adsorption properties

Edwin Clatworthy , Rémy Guillet-Nicolas , Philippe Boullay , Michael Badawi , Yann Foucaud et al.

ACS Materials Letters, 2024, 6 (10), pp.4690-4696. ⟨10.1021/acsmaterialslett.4c01625⟩

Article dans une revue hal-04808044v1
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A stable zeolite with atomically ordered and interconnected mesopore channel

Peng Lu , Jiaoyan Xu , Yiqing Sun , Rémy Guillet-Nicolas , Tom Willhammar et al.

Nature, 2024, 636 (8042), pp.368-373. ⟨10.1038/s41586-024-08206-1⟩

Article dans une revue hal-05371019v1
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Unrevealing the effect of templates on atomic scale ordering and hydrophilic properties of aluminophosphates

Ludovica Pace , Eddy Dib , Diogenes Honorato-Piva , Valérie Ruaux , Aurelie Vicente et al.

Inorganic Chemistry Frontiers, 2024, 11 (18), pp.6178-6189. ⟨10.1039/D4QI01240B⟩

Article dans une revue hal-04808041v1
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Investigating the Physicochemical Properties of an Extra-large Pore Aluminosilicate ZEO-1

Mohammad Fahda , Jawad Fayek , Eddy Dib , Hugo Cruchade , Nathan Pichot et al.

Chemistry of Materials, 2024, 36 (11), pp.5405-5421. ⟨10.1021/acs.chemmater.4c00186⟩

Article dans une revue hal-04588196v1
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Insight on MWW siliceous zeolites: from 2D precursors toward 3D structure

Francesca Rosso , Alessia Airi , Matteo Signorile , Eddy Dib , Silvia Bordiga et al.

Microporous and Mesoporous Materials, 2024, 366, pp.112924. ⟨10.1016/j.micromeso.2023.112924⟩

Article dans une revue hal-04654227v1
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Flexibility in zeolites: origin, limits, and evaluation

Sajjad Ghojavand , Eddy Dib , Svetlana Mintova

Chemical Science, In press, ⟨10.1039/D3SC03934J⟩

Article dans une revue (article de synthèse) hal-04283447v1
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The Chemical Shift Anisotropy: A Promising Parameter To Distinguish The 29 Si NMR Peaks In Zeolites

Eddy Dib , Svetlana Mintova , Georgi Vayssilov , Hristiyan Aleksandrov , Marina Carravetta

Journal of Physical Chemistry C, 2023, 127 (22), pp.10792-10796. ⟨10.1021/acs.jpcc.3c01533⟩

Article dans une revue hal-04283471v1
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Coke Relocation and Mo Immobilization in Donut-Shaped Mo/HZSM-5 Catalysts for Methane Dehydroaromatization

Ming Cheng , Hugo Cruchade , Ludovic Pinard , Eddy Dib , Honghai Liu et al.

Journal of Materials Chemistry A, 2023, ⟨10.1039/D3TA05418G⟩

Article dans une revue hal-04283486v1
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Impact of Mineralizing Agents on Aluminum Distribution and Acidity of ZSM‐5 Zeolites

Shadi Al-Nahari , Eddy Dib , Claudia Cammarano , Etienne Saint-Germes , Dominique Massiot et al.

Angewandte Chemie International Edition, 2023, 62 (7), pp.e202217992. ⟨10.1002/anie.202217992⟩

Article dans une revue hal-03941911v1
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Interplay between alkali-metal cations and silanol sites in nanosized CHA zeolite: implications for CO2 adsorption

Sajjad Ghojavand , Eddy Dib , Jérôme Rey , Ayoub Daouli , Edwin Clatworthy et al.

Communications Chemistry, 2023, 6, pp.134. ⟨10.1038/s42004-023-00918-1⟩

Article dans une revue hal-04283478v1
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CO 2 adsorption behaviour of nanosized CHA zeolites synthesised in the presence of barium or calcium cations

Aymeric Magisson , Edwin Clatworthy , Sajjad Ghojavand , Philippe Bazin , Valérie Ruaux et al.

Advanced Sustainable Systems, In press, ⟨10.1002/adsu.202300326⟩

Article dans une revue hal-04283454v1
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Acidic medium synthesis of zeolites – an avenue to control the structure-directing power of organic templates

Guangying Fu , Eddy Dib , Qiaolin Lang , Haonuan Zhao , Songxia Wang et al.

Dalton Transactions, 2022, 51 (30), pp.11499-11506. ⟨10.1039/D2DT01554D⟩

Article dans une revue hal-03779241v1
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The challenge of silanol species characterization in zeolites

Florent Dubray , Eddy Dib , Izabel Medeiros-Costa , Cindy Aquino , Delphine Minoux et al.

Inorganic Chemistry Frontiers, 2022, 9 (6), pp.1125-1133. ⟨10.1039/D1QI01483H⟩

Article dans une revue hal-04295903v1
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Silicalite-1 formation in acidic medium: synthesis conditions and physicochemical properties

Xiaobo Yang , Eddy Dib , Qiaolin Lang , Hailing Guo , Guangying Fu et al.

Microporous and Mesoporous Materials, 2022, 329, pp.111537. ⟨10.1016/j.micromeso.2021.111537⟩

Article dans une revue hal-03423400v1
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Engineering RHO nanozeolite: controlling the particle morphology, Al and cation content, stability, and flexibility

Edwin B. Clatworthy , Arnold A. Paecklar , Eddy Dib , Maxime Debost , Nicolas Barrier et al.

ACS Applied Energy Materials, 2022, 5 (5), pp.6032-6042. ⟨10.1021/acsaem.2c00439⟩

Article dans une revue hal-03752212v1
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Hydroxyl environments in zeolites probed by deuterium solid-state MAS NMR combined with IR spectroscopy

Eddy Dib , Edwin Clatworthy , Louwanda Lakiss , Valérie Ruaux , Svetlana Mintova

Inorganic Chemistry Frontiers, 2022, 9 (12), pp.2964-2968. ⟨10.1039/D2QI00824F⟩

Article dans une revue hal-04295954v1
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Access to sodalite cages in ion-exchanged nanosized FAU zeolites probed by hyperpolarized 129Xe NMR and DFT calculations

Eddy Dib , Jérôme Rey , Aurelie Vicente , Shrikant Kunjir , Hussein Awala et al.

Microporous and Mesoporous Materials, 2022, 338, pp.111965. ⟨10.1016/j.micromeso.2022.111965⟩

Article dans une revue hal-03752221v1
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Host-Guest Silicalite-1 Zeolites: Correlated Disorder and Phase Transition Inhibition by a Small Guest Modification

Marco Fabbiani , Shadi Al-Nahari , Laura Piveteau , Eddy Dib , Vasyl Veremeienko et al.

Chemistry of Materials, 2022, 34 (1), pp.366-387. ⟨10.1021/acs.chemmater.1c03721⟩

Article dans une revue hal-03507387v1
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Unraveling the Effect of Silanol Defects on the Insertion of Single-Site Mo in the MFI Zeolite Framework

Izabel Medeiros-Costa , Eddy Dib , Florent Dubray , Simona Moldovan , Jean-Pierre Gilson et al.

Inorganic Chemistry, 2022, 61 (3), pp.1418-1425. ⟨10.1021/acs.inorgchem.1c03076⟩

Article dans une revue hal-03752182v1
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Superacidity and spectral signatures of hydroxyl groups in zeolites

Georgi N Vayssilov , Hristiyan A Aleksandrov , Eddy Dib , Izabel Medeiros Costa , Nikolai Nesterenko et al.

Microporous and Mesoporous Materials, 2022, 343, pp.112144. ⟨10.1016/j.micromeso.2022.112144⟩

Article dans une revue hal-03752240v1
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Exploration, explanation and exploitation of hydroxyls in zeolites

Eddy Dib , Edwin Clatworthy , Hugo Cruchade , Izabel Medeiros-Costa , Nikolai Nesterenko et al.

National Science Review, 2022, ⟨10.1093/nsr/nwac081⟩

Article dans une revue hal-03752218v1
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The role of mixed alkali metal cations on the formation of nanosized CHA zeolite from colloidal precursor suspension

Sajjad Ghojavand , Edwin B Clatworthy , Aurélie Vicente , Eddy Dib , Valérie Ruaux et al.

Journal of Colloid and Interface Science, 2021, 604, pp.350-357. ⟨10.1016/j.jcis.2021.06.176⟩

Article dans une revue hal-03414919v1
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Complex H-bonded silanol network in zeolites revealed by IR and NMR spectroscopy combined with DFT calculations †

Eddy Dib , Izabel Medeiros Costa , Georgi N Vayssilov , Hristiyan A Aleksandrov , Svetlana Mintova

Journal of Materials Chemistry A, 2021, ⟨10.1039/D1TA06908J⟩

Article dans une revue hal-03414980v1
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Control the position of framework defects in zeolites by changing the symmetry of organic structure directing agents

Eddy Dib , Julien Grand , Antoine Gedeon , Svetlana Mintova , Christian Fernandez

Microporous and Mesoporous Materials, 2021, 315, pp.110899, 1-4. ⟨10.1016/j.micromeso.2021.110899⟩

Article dans une revue hal-03143342v1
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Silanol defects engineering and healing in zeolites: Opportunities to fine-tune their properties and performances

Izabel C Medeiros-Costa , Eddy Dib , Nikolai Nesterenko , Jean-Pierre Dath , Jean-Pierre Gilson et al.

Chemical Society Reviews, 2021, 50 (19), pp.11156-11179. ⟨10.1039/D1CS00395J⟩

Article dans une revue hal-03414915v1
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Zeolite Structure Direction: Identification, Strength and Involvement of Weak CH⋅⋅⋅O Hydrogen Bonds

Tzonka Mineva , Eddy Dib , Arnold Gaje , Hugo Petitjean , Jean-Louis Bantignies et al.

ChemPhysChem, 2020, 21 (2), pp.149-153. ⟨10.1002/cphc.201900953⟩

Article dans une revue hal-02405117v1

Recrystallization on Alkaline Treated Zeolites in the Presence of Pore-Directing Agents

Eddy Dib , Hussein El Siblani , Shrikant M. Kunjir , Aurelie Vicente , Nicolas Nuttens et al.

Crystal Growth & Design, 2018, 18 (4), pp.2010--2015. ⟨10.1021/acs.cgd.7b01416⟩

Article dans une revue hal-01840134v1

ZSM-5 Zeolite: Complete Al Bond Connectivity and Implications on Structure Formation from Solid-State NMR and Quantum Chemistry Calculations

Eddy Dib , Tzonka Mineva , Emmanuel Veron , Vincent Sarou-Kanian , Franck Fayon et al.

Journal of Physical Chemistry Letters, 2018, 9, pp.19 - 24. ⟨10.1021/acs.jpclett.7b03050⟩

Article dans une revue hal-01667318v1

Intermolecular interactions in AST zeolites through 14N NMR and DFT calculations

Dib Eddy , Freire Mélanie , Valérie Pralong , Tzonka Mineva , Bruno Alonso

Acta Crystallographica Section C : Crystal Structure Communications [1968-2013], 2017, 73, pp.202. ⟨10.1107/S2053229616017022⟩

Article dans une revue hal-01534161v1

Probing Disorder in Al-ZSM-5 Zeolites by 14 N NMR Spectroscopy

Eddy Dib , Tzonka Mineva , Philippe Gaveau , Emmanuel Véron , Vincent Sarou-Kanian et al.

Journal of Physical Chemistry C, 2017, 121 (29), pp.15831 - 15841. ⟨10.1021/acs.jpcc.7b04861⟩

Article dans une revue hal-01576192v1

One-pot synthesis of silanol-free nanosized MFI zeolite

Julien Grand , Siddulu Naidu Talapaneni , Aurélie Vicente , Christian Fernandez , Eddy Dib et al.

Nature Materials, 2017, 16 (10), pp.1010-1015. ⟨10.1038/nmat4941⟩

Article dans une revue hal-02410389v1

11 B MAS NMR Study of the Thermolytic Dehydrocoupling of Two Ammonia Boranes upon the Release of One Equivalent of H 2 at Isothermal Conditions

Jean-Fabien Petit , Eddy Dib , Philippe Gaveau , Philippe Miele , Bruno Alonso et al.

ChemistrySelect, 2017, 2 (29), pp.9396 - 9401. ⟨10.1002/slct.201702227⟩

Article dans une revue hal-01670986v1

Recent advances in 14N solid state NMR

Dib Eddy , Tzonka Mineva , Bruno Alonso

Annual Reports on NMR Spectroscopy, 2016, 87, pp.175-235. ⟨10.1016/bs.arnmr.2015.08.002⟩

Article dans une revue hal-01295010v1

14N NMR of tetrapropylammonium based crystals

Dib Eddy , Tzonka Mineva , Philippe Gaveau , Bruno Alonso

The European Physical Journal. Special Topics, 2015, 224, pp.1769-1773. ⟨10.1140/epjst/e2015-02497-4⟩

Article dans une revue hal-01186125v1

Structure-Directing Agent Governs the Location of Silanol Defects in Zeolites

E. Dib , J. Grand , S. Mintova , Christian Fernandez

Chemistry of Materials, 2015, 27 (22), pp.7577-7579. ⟨10.1021/acs.chemmater.5b03668⟩

Article dans une revue hal-01711599v1

Preferential orientations of structure directing agents in zeolites

Eddy Dib , Antoine Gimenez , Tzonka Mineva , Bruno Alonso

Dalton Transactions, 2015, 44, pp.16680-16683. ⟨10.1039/C5DT02558C⟩

Article dans une revue hal-01203808v1

DFT-D Study of N-14 Nuclear Quadrupolar Interactions in Tetra-n-alkyl Ammonium Halide Crystals

Eddy Dib , Bruno Alonso , Tzonka Mineva

Journal of Physical Chemistry A, 2014, 118 (19), pp.3525-3533. ⟨10.1021/jp502858n⟩

Article dans une revue hal-01011041v1

14N Solid-State NMR: A sensitive probe of the local order in zeolites

Dib Eddy , Tzonka Mineva , Philippe Gaveau , Bruno Alonso

Physical Chemistry Chemical Physics, 2013, 15, pp.18349-18352. ⟨10.1039/C3CP51845K⟩

Article dans une revue hal-00873646v1
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29Si NMR to probe 27Al distribution in zeolites

Eddy Dib , Edwin B. Clatworthy , Arnold Paecklar , Julien Grand , Nicolas Barrier et al.

The 21st International Zeolite Conference, Jul 2025, Dalian, China

Communication dans un congrès hal-05349668v1

Tuning the aluminum distribution and acidity of ZSM-5 zeolites using the mineralizing agents during syntheses

Shadi Al-nahari , Eddy Dib , Claudia Cammarano , Etienne Saint-Germes , Dominique Massiot et al.

Balard Chemistry Conferences BCC2023, Jun 2023, Montpellier, France

Communication dans un congrès hal-05068138v1

Tuning the aluminum distribution and acidity of ZSM-5 zeolites using the mineralizing agents during syntheses

Shadi Al-nahari , Eddy Dib , Claudia Cammarano , Etienne Saint-Germes , Dominique Massiot et al.

The 9th Conference of the Federation of the European Zeolite Associations, Jul 2023, Portoroz, Slovenia

Communication dans un congrès hal-05068135v1

Is nmr a suitable tools to study defects in zeolites?

Christian Fernandez , Eddy Dib

NMR-CAT 2017 : Catalysis by design using NMR, Mar 2017, Lille, France

Communication dans un congrès hal-01711685v1

RECRYSTALLIZATION ON ALKALINE TREATED ZEOLITES IN THE PRESENCE OF PORE DIRECTING AGENTS

Christian Fernandez , Eddy Dib , Hussein El Siblani , Aurélie Vicente

10th Alpine Conference On Solid State NMR, Sep 2017, Chamonix, France

Communication dans un congrès hal-01711686v1

On the Recrystallization of Hierarchical Zeolites using Pore Directing Agents

Christian Fernandez , Eddy Dib

11th International Symposium On The Characterization OF Porous Solids (COP-XI), May 2017, Avignon, France

Communication dans un congrès hal-01711688v1

The location of defects in zeolites is governed by the SDA

Eddy Dib , Grand Julien , Svetlana Mintova , Christian Fernandez

18th International Zeolite Conference (IZC), Jun 2016, Rio de Janeiro, Brazil

Communication dans un congrès hal-02070738v1