EMMANUEL MAGNIER

139
Documents

Présentation

Publications

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Publications

Pentafluoroethyl Sulfoximine Reagent for the Photocatalytic Pentafluoroethylation–Difunctionalization of Styrene Derivatives

Lu Lin , Gabriel Goujon , Bruce Pégot , Guillaume Dagousset , Elsa Anselmi et al.

Organic Letters, 2026, 28 (5), pp.1715-1719. ⟨10.1021/acs.orglett.5c05212⟩

Article dans une revue hal-05497401v1
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Metal‐Free Multicatalytic Decarbonylation of Aldehydes Driven by Light

Augustin Nouaille , Francesco Terzani , Yara Fakih , Jérôme Hannedouche , Emmanuel Magnier et al.

Angewandte Chemie International Edition, 2025, 64 (15), pp.e202424459. ⟨10.1002/anie.202424459⟩

Article dans une revue hal-04949214v1

Advances in Radical Remote γ-Functionalization of α,β-Unsaturated Carbonyl Compounds

Soumaya Jemail , Emmanuel Magnier , Maxime Vitale , Guillaume Dagousset

Synthesis: Journal of Synthetic Organic Chemistry, 2025, ⟨10.1055/a-2705-6364⟩

Article dans une revue hal-05364841v1
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Radical photochemical difluorosulfoximination of alkenes and propellanes

Simone Baldon , Julien Paut , Elsa Anselmi , Guillaume Dagousset , Béatrice Tuccio et al.

Chemical Science, In press, ⟨10.1039/d5sc01068c⟩

Article dans une revue hal-05019725v1
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Preparation of Se(IV) Aryltrifluoromethylselenide Dichlorides

Julien Paut , Gabriel Goujon , Arnaud de Zordo-Banliat , Guillaume Dagousset , Jorge Juan Cabrera-Trujillo et al.

European Journal of Organic Chemistry, 2025, ⟨10.1002/ejoc.202500865⟩

Article dans une revue hal-05380927v1

Multigram-Scale Synthesis and Study of Reactivity of Two Difluoromethylating Reagents Based on Sulfoximine Skeletons

Gabriel Goujon , Marina Briand , Nathalie Leclerc , Bruce Pégot , Guillaume Dagousset et al.

Organic Process Research and Development, 2025, ⟨10.1021/acs.oprd.5c00148⟩

Article dans une revue hal-05143166v1
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Photocatalytic α‐Difluoroalkoxyketones Synthesis via Radical Intermolecular Alkoxylation of Difluoroenol Silyl Ethers

Julien Paut , Simone Baldon , Elsa Anselmi , Luca Dell'Amico , Guillaume Dagousset et al.

Advanced Synthesis and Catalysis, 2024, ⟨10.1002/adsc.202400510⟩

Article dans une revue hal-04680319v1

Photocatalyzed One‐Pot Selective Synthesis of γ‐(per)fluoroalkenylated α,β‐Unsaturated Carbonyl Compounds

Marina Briand , Emmanuel Magnier , Elsa Anselmi , Guillaume Dagousset

Advanced Synthesis and Catalysis, 2024, ⟨10.1002/adsc.202400462⟩

Article dans une revue hal-04665645v1
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Site‐Selective γ‐Trihalomethylation and γ‐Dihalomethylidenation of Silyl Dienol Ethers under Organophotoredox Catalysis

Camille Banoun , Flavien Bourdreux , Emmanuel Magnier , Guillaume Dagousset

Chemistry - A European Journal, 2024, ⟨10.1002/chem.202403598⟩

Article dans une revue hal-04833542v1

Light‐Driven Synthesis and Functionalization of Bicycloalkanes, Cubanes and Related Bioisosteres

Sara Cuadros , Julien Paut , Elsa Anselmi , Guillaume Dagousset , Emmanuel Magnier et al.

Angewandte Chemie International Edition, 2024, ⟨10.1002/anie.202317333⟩

Article dans une revue hal-04451019v1
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One‐Pot Regioselective γ‐Trifluoromethylthiolation and γ‐Methylthiolation of Enals

Camille Banoun , Killian Henault , Emmanuel Magnier , Guillaume Dagousset

European Journal of Organic Chemistry, In press, ⟨10.1002/ejoc.202400119⟩

Article dans une revue hal-04533535v1
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From perfluoroalkyl aryl sulfoxides to ortho thioethers

Yang Li , Guillaume Dagousset , Emmanuel Magnier , Bruce Pégot

Beilstein Journal of Organic Chemistry, 2024, 20, pp.2108-2113. ⟨10.3762/bjoc.20.181⟩

Article dans une revue hal-04689107v1
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Electrophilic Fluorination of Silyl Dienol Ethers: a General and Selective Access to γ‐Fluoro Enals

Yang Li , Marina Briand , Karinne Miqueu , Elsa Anselmi , Emmanuel Magnier et al.

Chemistry - A European Journal, 2024, 30 (10), pp.e202303545. ⟨10.1002/chem.202303545⟩

Article dans une revue hal-04404468v1
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Cyclic Sulfoximines as Methyl and Perdeuteromethyl Transfer Agents and Their Applications in Photoredox Catalysis

Peng Wu , Gabriel Goujon , Shulei Pan , Béatrice Tuccio , Bruce Pégot et al.

Angewandte Chemie International Edition, 2024, ⟨10.1002/anie.202412418⟩

Article dans une revue hal-04785277v1
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Focus on Physico‐Chemical Properties of Sulfoximines: Acidity, Basicity and Lipophilicity

Elsa Anselmi , Bénédicte Montigny , Märt Lõkov , Carmen Kesküla , Jan Erik Soosaar et al.

Chemistry - A European Journal, 2024, 31 (1), pp.e202402329. ⟨10.1002/chem.202402329⟩

Article dans une revue hal-04814363v1
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NMR and DFT Studies with a Doubly Labelled 15 N/ 6 Li S ‐Trifluoromethyl Sulfoximine Reveal Why a Directed ortho ‐Lithiation Requires an Excess of n ‐BuLi

Matthieu Hédouin , Anne‐laure Barthelemy , Nicolas Vanthuyne , Hend Besrour , Jacques Maddaluno et al.

Angewandte Chemie International Edition, 2023, 62 (5), pp.e202214106. ⟨10.1002/anie.202214106⟩

Article dans une revue hal-03912827v1

Perfluoroalkyl Selenoxides, Selenones and Selenoximines: General Preparation and Properties

Arnaud de Zordo-Banliat , Kevin Grollier , Nicolas Vanthuyne , Sébastien Floquet , Thierry Billard et al.

Angewandte Chemie International Edition, 2023, 62 (12), ⟨10.1002/anie.202300951⟩

Article dans une revue hal-04046563v1
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Perfluoroalkylated Sulfoximines as Analogues of Togni Reagents: The Crucial Role of Fluorine Atoms for the Stability of Hypervalent Iodine Scaffolds

Thibaut Duhail , Jorna Kalim , Jérôme Marrot , Bruce Pégot , Emmanuel Magnier et al.

European Journal of Organic Chemistry, In press, ⟨10.1002/ejoc.202300963⟩

Article dans une revue hal-04316672v1
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Benzodithiazoles‐Sulfoximines: Preparation, Properties and Reactivities as Radical Perfluoroalkylating Agents

Thibaut Duhail , Samir Messaoudi , Guillaume Dagousset , Jérôme Marrot , Christiane André-Barrès et al.

Advanced Synthesis and Catalysis, 2023, 365 (14), pp.2392-2399. ⟨10.1002/adsc.202300553⟩

Article dans une revue hal-04161292v1

Recent Uses of Photogenerated Oxygen-Centered Radicals in Intermolecular C-O Bond Formation

Camille Banoun , Emmanuel Magnier , Guillaume Dagousset

SYNLETT, 2023, ⟨10.1055/a-2131-4126⟩

Article dans une revue hal-04231477v1
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The revival of Enantioselective Perfluoroalkylation – Update of New Synthetic Approaches from 2015–2022

Marina Briand , Elsa Anselmi , Guillaume Dagousset , Emmanuel Magnier

Chemical Record, 2023, ⟨10.1002/tcr.202300114⟩

Article dans une revue hal-04125052v1
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Vinylic Trifluoromethylselenolation via Pd‐Catalyzed C−H Activation

Arnaud de Zordo-Banliat , Kevin Grollier , Jordan Vigier , Erwann Jeanneau , Guillaume Dagousset et al.

Chemistry - A European Journal, In press, ⟨10.1002/chem.202202299⟩

Article dans une revue hal-03784203v1
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Remote Radical Trifluoromethylation: A Unified Approach to the Selective Synthesis of γ-Trifluoromethyl α,β-Unsaturated Carbonyl Compounds

Marina Briand , Linh Thai , Flavien Bourdreux , Nicolas Vanthuyne , Xavier Moreau et al.

Organic Letters, 2022, 24 (51), pp.9375-9380. ⟨10.1021/acs.orglett.2c03676⟩

Article dans une revue hal-03936896v1

Fluorine and chalcogen atoms: An association of benefactors

Emmanuel Magnier , Guillaume Dagousset

Tetrahedron, 2022, 113, pp.132754. ⟨10.1016/j.tet.2022.132754⟩

Article dans une revue hal-03687520v1

Dual Photocatalysis for the Straightforward Coupling of Thiosugars and Arylsulfoximines: Towards Unprecedented Cyclic Heteroatomic Structures

Thibaut Duhail , Mingxiang Zhu , Coralie Rombault , Guillaume Dagousset , Samir Messaoudi et al.

European Journal of Organic Chemistry, In press, ⟨10.1002/ejoc.202200173⟩

Article dans une revue hal-03668549v1
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Synthesis, Physical Properties and Application of a Series of New Polyoxometalate-Based Ionic Liquids

Yohan Martinetto , Salomé Basset , Bruce Pégot , Catherine Roch-Marchal , Franck Camerel et al.

Molecules, 2021, 26 (2), ⟨10.3390/molecules26020496⟩

Article dans une revue hal-03120947v1
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Structure and Reactivity of N‐Heterocyclic Alkynyl Hypervalent Iodine Reagents

Eliott Le Du , Thibaut Duhail , Matthew Wodrich , Rosario Scopelliti , Farzaneh Fadaei‐tirani et al.

Chemistry - A European Journal, 2021, 27 (42), ⟨10.1002/chem.202101475⟩

Article dans une revue hal-03265356v1
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Radical α-Trifluoromethoxylation of Ketones under Batch and Flow Conditions by Means of Organic Photoredox Catalysis

Thibaut Duhail , Tommaso Bortolato , Javier Mateos , Elsa Anselmi , Benson Jelier et al.

Organic Letters, 2021, 23 (18), pp.7088-7093. ⟨10.1021/acs.orglett.1c02494⟩

Article dans une revue hal-03380290v1
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Solvent free nucleophilic selenocyanation with [bmim][SeCN]. Direct access to perfluoroalkylselenide compounds

Arnaud De-Zordo Banliat , Kévin Grollier , Aurélie Damond , Thierry Billard , Guillaume Dagousset et al.

Tetrahedron, 2021, 101, pp.132507. ⟨10.1016/j.tet.2021.132507⟩

Article dans une revue hal-03834344v1
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(Trifluoromethylselenyl)methylchalcogenyl as emerging fluorinated groups: synthesis under photoredox catalysis and determination of the lipophilicity

Kevin Grollier , Arnaud de Zordo‐banliat , Flavien Bourdreux , Bruce Pegot , Guillaume Dagousset et al.

Chemistry - A European Journal, 2021, 27 (19), pp.6028-6033. ⟨10.1002/chem.202100053⟩

Article dans une revue hal-03407531v1
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Intermolecular C-O Bond Formation with Alkoxyl Radicals: Photoredox-Catalyzed α-Alkoxylation of Carbonyl Compounds

Camille Banoun , Flavien Bourdreux , Emmanuel Magnier , Guillaume Dagousset

Organic Letters, 2021, 23 (22), pp.8926-8930. ⟨10.1021/acs.orglett.1c03444⟩

Article dans une revue hal-03487851v1
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A decatungstate-based Ionic liquid exhibiting very low dielectric constant suitable for acting as solvent and catalyst for oxidation of organic substrates

Yohan Martinetto , Bruce Pégot , Catherine Roch , Mohamed Haouas , Betty Cottyn Boitte et al.

New Journal of Chemistry, 2021, 45 (22), pp.9751-9755. ⟨10.1039/D1NJ01214B⟩

Article dans une revue hal-03231821v1
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Fe-mediated nucleophilic trifluoromethylselenolation of activated alkyl bromides via umpolung reactivity of trifluoromethyl tolueneselenosulfinate

Kevin Grollier , Emmanuel Chefdeville , Arnaud de Zordo-Banliat , Bruce Pegot , Guillaume Dagousset et al.

Tetrahedron, 2021, 100, pp.132498. ⟨10.1016/j.tet.2021.132498⟩

Article dans une revue hal-03834329v1
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Aryl Fluoroalkyl Sulfoxides: Optical Stability and p K a Measurement

Amélia Messara , Nicolas Vanthuyne , Patrick Diter , Mourad Elhabiri , Armen Panossian et al.

European Journal of Organic Chemistry, 2021, 2021 (36), ⟨10.1002/ejoc.202100816⟩

Article dans une revue hal-03319682v1
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Visible-Light-Induced Metal-Free Trifluoromethylselenolation of Electron-Rich Heteroarenes Using the Nucleophilic Me4N][SeCF3] Reagent

Arnaud de Zordo-Banliat , Lucas Barthélémy , Flavien Bourdreux , Béatrice N. Tuccio , Guillaume Dagousset et al.

European Journal of Organic Chemistry, 2020, 2020 (4), pp.506-509. ⟨10.1002/ejoc.201901793⟩

Article dans une revue hal-02861697v1
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Controlled decomposition of SF6 by electrochemical reduction

Sébastien Bouvet , Bruce Pégot , Stéphane Sengmany , Erwan Le Gall , Eric Léonel et al.

Beilstein Journal of Organic Chemistry, 2020, 16, pp.2948 - 2953. ⟨10.3762/bjoc.16.244⟩

Article dans une revue hal-03097747v1

Pyridinium Salts as Redox‐Active Functional Group Transfer Reagents

Simon Rössler , Benson Jelier , Emmanuel Magnier , Guillaume Dagousset , Erick Carreira et al.

Angewandte Chemie International Edition, 2020, 59 (24), pp.9264-9280. ⟨10.1002/anie.201911660⟩

Article dans une revue hal-02992788v1
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Metal-Free Visible-Light-Mediated Hydrotrifluoromethylation of Unactivated Alkenes and Alkynes in Continuous Flow

Anne-Laure Barthelemy , Guillaume Dagousset , Emmanuel Magnier

European Journal of Organic Chemistry, 2020, 2020 (10), pp.1429-1432. ⟨10.1002/ejoc.201901252⟩

Article dans une revue hal-02992749v1
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Metal-free nucleophilic trifluoromethylselenolation via an iodide-mediated umpolung reactivity of trifluoromethylselenotoluenesulfonate

Kevin Grollier , Alexis Taponard , Arnaud de Zordo-Banliat , Emmanuel Magnier , Thierry Billard

Beilstein Journal of Organic Chemistry, 2020, 16, pp.3032 - 3037. ⟨10.3762/bjoc.16.252⟩

Article dans une revue hal-03097741v1
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Direct Trifluoromethylation of Alcohols Using a Hypervalent Iodosulfoximine Reagent

Jorna Kalim , Thibaut Duhail , Ewa Pietrasiak , Elsa Anselmi , Emmanuel Magnier et al.

Chemistry - A European Journal, 2020, ⟨10.1002/chem.202005104⟩

Article dans une revue hal-03121267v1
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Optimization and Gram-Scale Preparation of S -Trifluoromethyl Sulfoximines and Sulfilimino Iminiums, Powerful Reagents for the Late Stage Introduction of the CF 3 Group

Anne-Laure Barthelemy , Victor Certal , Guillaume Dagousset , Elsa Anselmi , Luc Bertin et al.

Organic Process Research and Development, 2020, 24 (5), pp.704-712. ⟨10.1021/acs.oprd.9b00403⟩

Article dans une revue hal-03097860v1
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Environmentally Compatible Access to α‐Trifluoromethylseleno‐Enones

Kevin Grollier , Alexis Taponard , Clément Ghiazza , Emmanuel Magnier , Thierry Billard

Helvetica Chimica Acta, 2020, 103 (11), ⟨10.1002/hlca.202000185⟩

Article dans une revue hal-03033317v1
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Photoredox-Catalyzed Selective Synthesis of Allylic Perfluoroalkanes from Alkenes

Anne‐laure Barthelemy , F. Bourdreux , Guillaume Dagousset , Emmanuel Magnier

Chemistry - A European Journal, 2020, 26 (45), pp.10213-10216. ⟨10.1002/chem.202002046⟩

Article dans une revue hal-02992795v1
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Synthesis of S-Trifluoromethyl S-Arylsulfoximine Thioglycosides through Pd-Catalyzed Migita Cross-Coupling

Nedjwa Bennai , Nada Ibrahim , Jérôme C. Marrot , Mohamed Belkadi , Mouâd Alami et al.

European Journal of Organic Chemistry, 2020, 2020 (31), pp.4972-4981. ⟨10.1002/ejoc.202000821⟩

Article dans une revue hal-02938398v1

Four-Component Photoredox-Mediated Azidoalkoxy-trifluoromethylation of Alkenes

Guillaume Levitre , Guillaume Dagousset , Elsa Anselmi , Béatrice Tuccio , Emmanuel Magnier et al.

Organic Letters, 2019, 21 (15), pp.6005-6010. ⟨10.1021/acs.orglett.9b02152⟩

Article dans une revue hal-02347070v1
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Correction: Modulation of the mechanical energy storage performance of the MIL-47(V<sup>IV</sup>) metal organic framework by ligand functionalization

Pascal G. Yot , Mohammad Wahiduzzaman , Erik Elkaim , Pierre Fertey , Paul Fabry et al.

Dalton Transactions, 2019, 48, pp.2823 - 2823. ⟨10.1039/c9dt90029b⟩

Article dans une revue hal-05404846v1
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Merging hypervalent iodine and sulfoximine chemistry: a new electrophilic trifluoromethylation reagent

Jorna Kalim , Thibaut Duhail , Thanh-Nghi Le , Nicolas Vanthuyne , Elsa Anselmi et al.

Chemical Science, 2019, 10 (45), pp.10516-10523. ⟨10.1039/c9sc04289j⟩

Article dans une revue hal-02514618v1
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General, Practical and Selective Oxidation Protocol for CF<sub>3</sub>S into CF<sub>3</sub>S(O) Group

Liubov Sokolenko , Raisa Orlova , Andrey Filatov , Yurii Yagupolskii , Emmanuel Magnier et al.

Molecules, 2019, 24 (7), pp.1249. ⟨10.3390/molecules24071249⟩

Article dans une revue hal-02358280v1
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Divergent Synthesis of 1,2-Benzo[ e ]thiazine and Benzo[ d ]thiazole Analogues Containing a S -Trifluoromethyl Sulfoximine Group: Preparation and New Properties of the Adachi Reagent

Anne-Laure Barthelemy , Elsa Anselmi , Thanh-Nghi Le , Giang Vo-Thanh , Régis Guillot et al.

Journal of Organic Chemistry, 2019, 84 (7), pp.4086-4094. ⟨10.1021/acs.joc.9b00079⟩

Article dans une revue hal-02093608v1
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Ni/Photoredox-Dual-Catalyzed Functionalization of 1-Thiosugars

Mingxiang Zhu , Guillaume Dagousset , Mouad Alami , Emmanuel Magnier , Samir Messaoudi

Organic Letters, 2019, 21 (13), pp.5132-5137. ⟨10.1021/acs.orglett.9b01730⟩

Article dans une revue hal-02396639v1

Correction: Modulation of the mechanical energy storage performance of the MIL-47(V IV ) metal organic framework by ligand functionalization

Pascal G. Yot , Mohammad Wahiduzzaman , Erik Elkaim , Pierre Fertey , Paul Fabry et al.

Dalton Transactions, 2019, 48 (8), pp.2823-2823. ⟨10.1039/c9dt90029b⟩

Article dans une revue hal-02333360v1

Intermolecular Trapping of Alkoxyl Radicals with Alkenes: A New Route to Ether Synthesis

Anne-Laure Barthelemy , Béatrice Tuccio , Emmanuel Magnier , Guillaume Dagousset

SYNLETT, 2019, 30 (13), pp.1489-1495. ⟨10.1055/s-0037-1611785⟩

Article dans une revue hal-02347568v1
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Spin trapping : la chasse aux intermédiaires radicalaires

Christiane André-Barrès , Jacques Lalevée , Elsa Anselmi , Guillaume Dagousset , Emmanuel Magnier et al.

L'Actualité Chimique, 2019

Article dans une revue hal-03011793v1

Facile Preparation of Vinyl S -Trifluoromethyl N H Aryl Sulfoximines

Anne-Laure Barthelemy , Alexis Prieto , Patrick Diter , Jérôme Hannedouche , Martial Toffano et al.

European Journal of Organic Chemistry, 2018, 2018 (27-28), pp.3764-3770. ⟨10.1002/ejoc.201800324⟩

Article dans une revue hal-02358294v1
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Imidazolium‐Based Ionic Liquids as Efficient Reagents for the C−O Bond Cleavage of Lignin

Marina Thierry , Amel A. Majira , Bruce Pegot , Laurent Cezard , Flavien Bourdreux et al.

ChemSusChem, 2018, 11 (2), pp.439-448. ⟨10.1002/cssc.201701668⟩

Article dans une revue hal-01817782v1

One-Pot Synthesis of Aryl- and Alkyl S -Perfluoroalkylated NH -Sulfoximines from Sulfides

Slim Chaabouni , Jean-François Lohier , Anne-Laure Barthelemy , Thomas Glachet , Elsa Anselmi et al.

Chemistry - A European Journal, 2018, 24 (64), pp.17006-17010. ⟨10.1002/chem.201805055⟩

Article dans une revue hal-01926255v1

Photoredox‐Initiated 1,2‐Difunctionalization of Alkenes with N ‐Chloro S ‐Fluoroalkyl Sulfoximines

Alexis Prieto , Patrick Diter , Martial Toffano , Jérôme Hannedouche , Emmanuel Magnier

Advanced Synthesis and Catalysis, 2018, 361 (3), pp.436-440. ⟨10.1002/adsc.201801207⟩

Article dans une revue hal-02358288v1

Recent trends in perfluorinated sulfoximines

Anne-Laure Barthelemy , Emmanuel Magnier

Comptes Rendus. Chimie, 2018, 21 (8), pp.711-722. ⟨10.1016/j.crci.2018.01.004⟩

Article dans une revue hal-02358299v1

Direct Trifluoromethylthiolation Reactions Involving Radical Processes

Anne-Laure Barthelemy , Emmanuel Magnier , Guillaume Dagousset

Synthesis: Journal of Synthetic Organic Chemistry, 2018, 50 (24), pp.4765-4776. ⟨10.1055/s-0037-1611278⟩

Article dans une revue hal-02347500v1

Alkoxyl Radicals Generated under Photoredox Catalysis: A Strategy for anti-Markovnikov Alkoxylation Reactions

Anne-Laure Barthelemy , Beátrice Tuccio , Emmanuel Magnier , Guillaume Dagousset

Angewandte Chemie International Edition, 2018, 57 (42), pp.13790--13794. ⟨10.1002/anie.201806522⟩

Article dans une revue hal-02091883v1

Ionic Liquids for Fast and Solvent-Free Nucleophilic Trifluoromethylthiolation of Alkyl Halides and Alcohols

Elsa Anselmi , Cédric Simon , Jerome Marrot , Patrick Bernardelli , Laurent Schio et al.

European Journal of Organic Chemistry, 2017, 2017 (42), pp.6319-6326. ⟨10.1002/ejoc.201701222⟩

Article dans une revue hal-02624958v1

CF 3 S(O) n -containing enaminones as precursors for the synthesis of pyrimidine-4(3 H )-ones

Liubov Sokolenko , Yurii Yagupolskii , Liliia Kumanetska , Jérôme Marrot , Emmanuel Magnier et al.

Tetrahedron Letters, 2017, 58 (13), pp.1308-1311. ⟨10.1016/j.tetlet.2017.02.046⟩

Article dans une revue hal-05130991v1
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Dichlorotrifluoromethoxyacetic acid: Preparation and reactivity

Riadh Zriba , Alaric Desmarchelier , Frederic Cadoret , Sebastien Bouvet , Anne-Laure Barthelemy et al.

Molecules, 2017, 22 (6), pp.1-7. ⟨10.3390/molecules22060966⟩

Article dans une revue hal-01606613v1

Fluorinated sulfilimino iminiums: a versatile source of perfluoroalkyl radicals under photoredox catalysis

Marion Daniel , Guillaume Dagousset , Patrick Diter , Pierre-André Klein , Beátrice Tuccio et al.

Angewandte Chemie International Edition, 2017, ⟨10.1002/anie.201700290⟩

Article dans une revue hal-02113752v1
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Evaluation of Efficient and Practical Methods for the Preparation of Functionalized Aliphatic Trifluoromethyl Ethers

Taras M Sokolenko , Maya I Dronkina , Emmanuel Magnier , Lev M Yagupolskii , Yurii L Yagupolskii

Molecules, 2017, 22 (5), pp.804. ⟨10.3390/molecules22050804⟩

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Fluoroalkyl Amino Reagents for the Introduction of the Fluoro(trifluoromethoxy)methyl Group onto Arenes and Heterocycles

Etienne Schmitt , Sebastien Bouvet , Bruce Pegot , Armen Panossian , Jean-Pierre Vors et al.

Organic Letters, 2017, 19 (18), pp.4960-4963. ⟨10.1021/acs.orglett.7b02444⟩

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Generation of the SCF3 radical by photoredox catalysis: Intra- and intermolecular carbotrifluoromethylthiolation of alkenes

Guillaume Dagousset , Cédric Simon , Elsa Anselmi , Béatrice Tuccio , Thierry Billard et al.

Chemistry - A European Journal, 2017, 23 (18), pp.4282-4286. ⟨10.1002/chem.201700734⟩

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Selective carboxylate directed ortho functionalization in copper catalyzed reactions of polyiodo aromatics: A straightforward preparation of 5,7-diiodo-1H-isochromen-1-ones

Elsa Anselmi , Zineb Bahlaouan , Samuel Inack Ngi , Jean Luc Parrain , Emmanuel Magnier et al.

European Journal of Organic Chemistry, 2017, 41, pp.6131-6136. ⟨10.1002/ejoc.201700859⟩

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S -Trifluoromethyl Sulfoximine as a Directing Group in Ortho -Lithiation Reaction toward Structural Complexity

Thanh-Nghi Le , Patrick Diter , Bruce Pégot , Chloée Bournaud , Martial Toffano et al.

Organic Letters, 2016, 18 (19), pp.5102-5105. ⟨10.1021/acs.orglett.6b02548⟩

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Synthesis of N-Alkenyl and N-Alkynyl S-Perfluoroalkylated Sulfoximines by Copper Catalysis

Elsa Anselmi , - Thanh Nghi Le , Sebastien Bouvet , Patrick Diter , Bruce Pegot et al.

European Journal of Organic Chemistry, 2016, 25, pp.4423 - 4428. ⟨10.1002/ejoc.201600649⟩

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Photoredox-Catalyzed Three-Component Tandem Process: An Assembly of Complex Trifluoromethylated Phthalans and Isoindolines

Lucie Jarrige , Aude Carboni , Guillaume Dagousset , Guillaume Levitre , Emmanuel Magnier et al.

Organic Letters, 2016, 18 (12), pp.2906-2909. ⟨10.1021/acs.orglett.6b01257⟩

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Functionalized S-perfluorinated sulfoximines: Preparation and evaluation in catalytic processes

Thanh-Nghi Le , Patrick Diter , Bruce Pégot , Chloée Bournaud , Martial Toffano et al.

Journal of Fluorine Chemistry, 2015, 179, pp.179-187. ⟨10.1016/j.jfluchem.2015.06.020⟩

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Difluoromethyl and Chlorofluoromethyl Sulfoximines: Synthesis and Evaluation as Electrophilic Perfluoroalkylating Reagents

Bruce Pégot , Céline Urban , Aaron Bourne , Thanh Nghi Le , Sébastien Bouvet et al.

European Journal of Organic Chemistry, 2015, 2015 (14), pp.3069-3075. ⟨10.1002/ejoc.201500201⟩

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Oxidative desulfurization–fluorination reaction promoted by [bdmim][F] for the synthesis of difluorinated methyl ethers

Sébastien Bouvet , Bruce Pégot , Patrick Diter , Jérôme Marrot , Emmanuel Magnier

Tetrahedron Letters, 2015, 56 (13), pp.1682-1686. ⟨10.1016/j.tetlet.2015.02.034⟩

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Arylation of perfluoroalkyl vinyl sulfoxides via the Heck reaction

Liubov V. Sokolenko , Yurii L. Yagupolskii , Yurii G. Vlasenko , Liudmila N. Babichenko , Volidimir O. Lipetskij et al.

Tetrahedron Letters, 2015, 56 (10), pp.1259-1262. ⟨10.1016/j.tetlet.2015.01.136⟩

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Le fluor en chimie organique : une montée en puissance (Fluorine in organic chemistry gaining momentum)

Thierry Billard , Emmanuel Magnier , Jean-Pierre Vors

L'Actualité Chimique, 2015, 393-394, pp.56-61

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Three-Component Photoredox-Mediated Chloro-, Bromo-, or Iodotrifluoromethylation of Alkenes

Aude Carboni , Guillaume Dagousset , Emmanuel Magnier , Geraldine Masson

Synthesis: Journal of Synthetic Organic Chemistry, 2015, 47 (16), pp.2439-2445. ⟨10.1055/s-0034-1378715⟩

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Solvent free nucleophilic introduction of fluorine with [bmim][F]

Sébastien Bouvet , Bruce Pégot , Jérome Marrot , Emmanuel Magnier

Tetrahedron Letters, 2014, 55 (4), pp.826 - 829. ⟨10.1016/j.tetlet.2013.12.020⟩

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Photoredox-induced three-component azido- and aminotrifluoromethylation of alkenes.

Guillaume Dagousset , Aude Carboni , Emmanuel Magnier , Géraldine Masson

Organic Letters, 2014, 16 (16), pp.4340-4343. ⟨10.1021/ol5021477⟩

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A Complete Separation of Hexane Isomers by a Functionalized Flexible Metal Organic Framework

Patricia Mendes , Patricia Horcajada , Sébastien Rives , Alirio Egidio Rodrigues , Thomas Devic et al.

Advanced Functional Materials, 2014, xx (xx), ⟨10.1002/adfm.201401974⟩

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Photoredox-induced three-component oxy-, amino-, and carbotrifluoromethylation of enecarbamates

Aude Carboni , Guillaume Dagousset , Emmanuel Magnier , Géraldine Masson

Organic Letters, 2014, 16 (4), pp.1240-1243. ⟨10.1021/ol500374e⟩

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First Isolation of Enantiopure Perfluoroalkylated Sulfilimines and Sulfoximines

Thanh-Nghi Le , Emilie Kolodziej , Patrick Diter , Bruce Pégot , Chloée Bournaud et al.

CHIMIA, 2014, 68 (6), pp.410. ⟨10.2533/chimia.2014.410⟩

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Extended and functionalized porous iron( III ) tri- or dicarboxylates with MIL-100/101 topologies

Patricia Horcajada , Hubert Chevreau , Daniela Heurtaux , Farah Benyettou , Fabrice Salles et al.

Chemical Communications, 2014, 50, pp.6872--6874. ⟨10.1039/c4cc02175d⟩

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One pot and selective intermolecular aryl- and heteroaryl-trifluoromethylation of alkenes by photoredox catalysis.

Aude Carboni , Guillaume Dagousset , Emmanuel Magnier , Géraldine Masson

Chemical Communications, 2014, 50 (91), pp.14197-14200

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A Mild and Efficient Procedure for the N-Functionalization of S-Perfluoroalkylated Aryl Sulfoximines

Yohan Macé , Céline Constant-Urban , Sébastien Bouvet , Bruce Pégot , Chloée Bournaud et al.

Synthesis: Journal of Synthetic Organic Chemistry, 2013, 45 (11), pp.1505-1512. ⟨10.1055/s-0033-1338440⟩

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Perfluoroalkylated Bis(sulfilimine)s and Bis(sulfoximine)s by a Ritter‐Type Reaction

Bruce Pégot , Céline Urban , Patrick Diter , Emmanuel Magnier

European Journal of Organic Chemistry, 2013, 2013 (34), pp.7800 - 7808. ⟨10.1002/ejoc.201301017⟩

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Tuning the electrocatalytic hydrogen evolution reaction promoted by [Mo2O2S2]-based molybdenum cycles in aqueous medium.

Akram Hijazi , Justin Claude Kemmegne-Mbouguen , Sébastien Floquet , Jérôme Marrot , Jennifer Fize et al.

Dalton Transactions, 2013, 42 (14), pp.4848-58. ⟨10.1039/c2dt32447d⟩

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Impact of the Flexible Character of MIL-88 Iron(III) Dicarboxylates on the Adsorption of n-Alkanes

Naseem A. Ramsahye , Thuy Khuong Trung , Lorna Scott , Farid Nouar , Thomas Devic et al.

Chemistry of Materials, 2013, 25 (3), pp.479-488. ⟨10.1021/cm303830b⟩

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Ionic liquids as new media for electrophilic trifluoromethylation reactions

Bruce Pégot , Yohan Macé , Céline Urban , Patrick Diter , Jean-Claude Blazejewski et al.

Journal of Fluorine Chemistry, 2012, 134, pp.156-159. ⟨10.1016/j.jfluchem.2011.03.004⟩

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The New Age of Electrophilic Perfluoro­alk­ylation Reactions

Yohan Macé , Emmanuel Magnier

European Journal of Organic Chemistry, 2012, 2012 (13), pp.2479-2494. ⟨10.1002/ejoc.201101535⟩

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Octupolar derivatives functionalized with superacceptor peripheral groups Synthesis and evaluation of the electron-withdrawing ability of potent unusual groups

Cédric Rouxel , C. Le Droumaguet , Y. Macé , S. Clift , O. Mongin et al.

Chemistry - A European Journal, 2012, 18 (39), pp.12487-12497. ⟨10.1002/chem.201103460⟩

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Efficient copper-induced coupling between NH-fluoroalkylated sulfoximines and aryl iodides or bromides

Yohan Macé , Bruce Pégot , Régis Guillot , Chloée Bournaud , Martial Toffano et al.

Tetrahedron, 2011, 67 (39), pp.7575-7580. ⟨10.1016/j.tet.2011.07.060⟩

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Effect of NH2 and CF3 functionalization on the hydrogen sorption properties of MOFs

Claudia Zlotea , Delphine Phanon , Matjaz Mazaj , Daniela Heurtaux , Vincent Guillerm et al.

Dalton Transactions, 2011, 40 (18), pp.4879. ⟨10.1039/c1dt10115c⟩

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Sulfoximines as a Versatile Scaffold for Electrophilic Fluoroalkylating Reagents

Céline Urban , Frédéric Cadoret , Jean‐claude Blazejewski , Emmanuel Magnier

European Journal of Organic Chemistry, 2011, 2011 (25), pp.4862-4867. ⟨10.1002/ejoc.201100503⟩

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How linker's modification controls swelling properties of highly flexible iron(III) dicarboxylates MIL-88

Patricia Horcajada , F. Salles , Thomas Devic , Guillaume Maurin , Alexandre Vimont et al.

Journal of the American Chemical Society, 2011, pp.17839. ⟨10.1021/ja206936e⟩

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Self‐Immolative Reduction of Trifluoromethyl Sulfoxides Promoted by Trifluoromethanesulfonic Anhydride

Yohan Macé , Jean‐claude Blazejewski , Charlotte Pradet , Emmanuel Magnier

European Journal of Organic Chemistry, 2010, 2010 (30), pp.5772-5776. ⟨10.1002/ejoc.201001069⟩

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Functionalization in Flexible Porous Solids: Effects on the Pore Opening and the Host-Guest Interactions

Thomas Devic , Patricia Horcajada , C. Serre , Fabrice Salles , Guillaume Maurin et al.

Journal of the American Chemical Society, 2010, 132 (3), pp.1127-1136. ⟨10.1021/ja9092715⟩

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Divergent Preparation of Fluoroalkylated Sulfilimine and Sulfilimino Iminium Salts

Céline Urban , Yohan Macé , Frédéric Cadoret , Jean‐claude Blazejewski , Emmanuel Magnier

Advanced Synthesis and Catalysis, 2010, 352 (16), pp.2805-2814. ⟨10.1002/adsc.201000494⟩

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Mechanistical insight into ‘electrophilic’ trifluoromethylation with S-(trifluoromethyl)dibenzothiophenium salts

Yohan Macé , Charlotte Pradet , Matthew Popkin , Jean-Claude Blazejewski , Emmanuel Magnier

Tetrahedron Letters, 2010, 51 (41), pp.5388-5391. ⟨10.1016/j.tetlet.2010.07.154⟩

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Sulfilimines and Sulfoximines by Reaction of Nitriles with Perfluoroalkyl Sulfoxides

Yohan Macé , Céline Urban , Charlotte Pradet , Jérôme Marrot , Jean‐claude Blazejewski et al.

European Journal of Organic Chemistry, 2009, 2009 (19), pp.3150-3153. ⟨10.1002/ejoc.200900410⟩

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Aromatic and Benzylic C–H Bond Functionalization Upon Reaction between Nitriles and Perfluoroalkyl Sulfoxides

Yohan Macé , Céline Urban , Charlotte Pradet , Jean‐claude Blazejewski , Emmanuel Magnier

European Journal of Organic Chemistry, 2009, 2009 (31), pp.5313-5316. ⟨10.1002/ejoc.200900873⟩

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Effect of Fluorination on the Pharmacological Profile of 11β Isomers of Fulvestrant in Breast Carcinoma Cells

Vangelis Agouridas , Emmanuel Magnier , Jean-Claude Blazejewski , Ioanna Laïos , Anny Cleeren et al.

Journal of Medicinal Chemistry, 2009, 52 (3), pp.883-887. ⟨10.1021/jm801154q⟩

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Preparation and Reactivity of some New Keto- and Styrene-Based Trifluoromethoxylated Synthons

Riadh Zriba , Emmanuel Magnier , Jean-Claude Blazejewski

SYNLETT, 2009, 2009 (07), pp.1131-1135. ⟨10.1055/s-0028-1088155⟩

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Benchmark and Solvent‐Free Preparation of Sulfonium Salt Based Electrophilic Trifluoromethylating Reagents

Yohan Macé , Benoit Raymondeau , Charlotte Pradet , Jean‐claude Blazejewski , Emmanuel Magnier

European Journal of Organic Chemistry, 2009, 2009 (9), pp.1390-1397. ⟨10.1002/ejoc.200801222⟩

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The trifluoromethoxy group as a fluorine twin in the Diels–Alder reactions of halogenated quinones

Emmanuel Magnier , Patrick Diter , Jean-Claude Blazejewski

Tetrahedron Letters, 2008, 49 (31), pp.4575-4578. ⟨10.1016/j.tetlet.2008.05.104⟩

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Fluorous tolerance of the estrogen receptor alpha as probed by 11-polyfluoroalkylestradiol derivatives

Vangelis Agouridas , Jean-Claude Blazejewski , Anny Cleeren , Ioanna Laïos , Guy Leclercq et al.

Steroids, 2008, 73 (3), pp.320-327. ⟨10.1016/j.steroids.2007.11.002⟩

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Synthesis of N-tetrasubstituted cyclam derivatives appended with sulfonyl or sulfinyl groups via aza-Michael addition

Augustin de Castries , Aude Escande , Hélène Fensterbank , Emmanuel Magnier , Jérôme Marrot et al.

Tetrahedron, 2007, 63 (41), pp.10330-10336. ⟨10.1016/j.tet.2007.07.067⟩

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Evaluation of Zard trifluoromethylketone synthesis for the preparation of potential bifunctional fluorinated synthons

Patrick Diter , Emmanuel Magnier , Jean-Claude Blazejewski

Journal of Fluorine Chemistry, 2007, 128 (10), pp.1235-1240. ⟨10.1016/j.jfluchem.2007.05.002⟩

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Straightforward One-Pot Synthesis of Trifluoromethyl Sulfonium Salts

Marc Tordeux , Emmanuel Magnier , Jean-Claude Blazejewski , Claude Wakselman

Angewandte Chemie International Edition, 2006, 45, pp.1279. ⟨10.1002/anie.200503776⟩

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Selective Michael additions of primary and secondary amines to perfluoroalkylated sulfoxides and sulfones as a tool for fluorous tagging

Caroline Magnier-Bouvier , Jean-Claude Blazejewski , Chantal Larpent , Emmanuel Magnier

Tetrahedron Letters, 2006, 47 (51), pp.9121-9124. ⟨10.1016/j.tetlet.2006.10.077⟩

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An Expedient Synthesis of Perfluorinated Tetraazamacrocycles: New Ligands for Copper-Catalyzed Oxidation under Fluorous Biphasic Conditions

Augustin de Castries , Emmanuel Magnier , Sophie Monmotton , Hélène Fensterbank , Chantal Larpent

European Journal of Organic Chemistry, 2006, 20, pp.4685. ⟨10.1002/ejoc.200600523⟩

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Loss of antagonistic activity of tamoxifen by replacement of one N-methyl of its side chain by fluorinated residues

Vangelis Agouridas , Anny Cleeren , Elyane Kizilian , Emmanuel Magnier , Jean-Claude Blazejewski et al.

Bioorganic and Medicinal Chemistry, 2006, 14 (22), pp.7531-7538. ⟨10.1016/j.bmc.2006.07.012⟩

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Superacidifiers: Assessing the Activation and the Mode of Charge Transmission of the Extraordinary Electron-Withdrawing SO 2 CF 3 and S(O)(NSO 2 CF 3 )CF 3 Substituents in Carbanion Stabilization

François Terrier , Emmanuel Magnier , Elyane Kizilian , Claude Wakselman , Erwin Buncel

Journal of the American Chemical Society, 2005, 127 (15), pp.5563-5571. ⟨10.1021/ja0436291⟩

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Synthesis of 11β-Perfluorohexylestradiol

Vangelis Agouridas , Jean-Claude Blazejewski , Emmanuel Magnier , Matthew Popkin

Journal of Organic Chemistry, 2005, 70 (22), pp.8907-8912. ⟨10.1021/jo051424k⟩

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Synthesis of Fluoroalkyl Vinyl Sulfoxides and their Use in Diels-Alder Reactions

Joëlle Moïse , Régis Goumont , Emmanuel Magnier , Claude Wakselman

Synthesis: Journal of Synthetic Organic Chemistry, 2004, 2004 (14), pp.2297-2302. ⟨10.1055/s-2004-831201⟩

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29/28, 30/28Silicon, 34/32sulfur and 80/77selenium isotope-induced fluorine chemical shifts through two bonds

Marc Tordeux , Emmanuel Magnier , Jérôme Guidotti , Patrick Diter , Claude Wakselman

Magnetic Resonance in Chemistry, 2004, 42, pp.700. ⟨10.1002/mrc.1422⟩

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Acidity Inversions of α-NO 2 and α-SO 2 CF 3 Activated Carbon Acids as a Result of Contrasting Solvent Effects on Transfer from Water to Dimethyl Sulfoxide Solutions

Régis Goumont , Emmanuel Magnier , Elyane Kizilian , François Terrier

Journal of Organic Chemistry, 2003, 68 (17), pp.6566-6570. ⟨10.1021/jo034244o⟩

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The Preparation of Aliphatic Fluorinated Sulfoximines

Emmanuel Magnier , Claude Wakselman

Synthesis: Journal of Synthetic Organic Chemistry, 2003, 2003 (04), pp.0565-0569. ⟨10.1055/s-2003-37651⟩

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Perfluoroalkylation of 2-mercaptoethanol as a key step for a new synthesis of perfluoroalkyl vinyl sulfides, sulfoxides and sulfones

Marc Tordeux , Emmanuel Magnier , Régis Goumont , Karine Magder , Claude Wakselman

Journal of Fluorine Chemistry, 2003, 124, pp.55. ⟨10.1016/S0022-1139(03)00170-2⟩

Article dans une revue istex hal-00094395v1

A Mild and Practical Preparation of Trifluoromethaneselenenyl Chloride

Emmanuel Magnier , Claude Wakselman

Collection of Czechoslovak Chemical Communications, 2002, 67 (9), pp.1262-1266. ⟨10.1135/cccc20021262⟩

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A Convenient Access to Perfluoroalkyl Selenoethers and Selenyl Chlorides

Emmanuel Magnier , Erica Vit , Claude Wakselman

SYNLETT, 2001, 2001 (08), pp.1260-1262. ⟨10.1055/s-2001-16050⟩

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Observations on the versatility of methylenecyclopropanes as olefinic components in the intramolecular Pauson–Khand reaction

Hervé Corlay , Eric Fouquet , Emmanuel Magnier , William Motherwell

Chemical Communications, 1999, 2, pp.183-184. ⟨10.1039/A807333C⟩

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Manzamine alkaloids, syntheses and synthetic approaches

Emmanuel Magnier , Yves Langlois

Tetrahedron, 1998, 54 (23), pp.6201-IN2. ⟨10.1016/S0040-4020(98)00357-3⟩

Article dans une revue hal-05123447v1

Formal synthesis of Manzamine C via a sila-Cope elimination

Thierry Vidal , Emmanuel Magnier , Yves Langlois

Tetrahedron, 1998, 54 (22), pp.5959-5966. ⟨10.1016/S0040-4020(98)00270-1⟩

Article dans une revue hal-05123448v1

Zincke-bradsher convergent strategy for the synthesis of the ABE tricyclic core of Manzamine A

Emmanuel Magnier , Yves Langlois

Tetrahedron Letters, 1998, 39 (8), pp.837-840. ⟨10.1016/S0040-4039(97)10744-4⟩

Article dans une revue hal-05123449v1

Stereoselective synthesis of the tricyclic core of manzamine a: The bradsher cycloaddition route

Emmanuel Magnier , Claude Mérienne , Yves Langlois

Tetrahedron Letters, 1995, 36 (52), pp.9475-9478. ⟨10.1016/0040-4039(95)02071-3⟩

Article dans une revue hal-05123452v1

Recent developments in the preparation of molecules merging fluorine and chalcogen atoms

Emmanuel Magnier

23TH International Symposium of Fluorine Chemistry, Jul 2023, Québec (CA), Canada

Communication dans un congrès hal-04373929v1

S-perfluoroalkyl sulfoximines: from synthesis to reactivity on photoredox catalysis

Emmanuel Magnier

France-Japan joint symposium on organofluorine chemistry, Nov 2019, Strasbourg, France

Communication dans un congrès hal-04373926v1

Photoredox catalysis: a powerful tool to prepare perfluoroalkylated and trifluoromethylthiolated molecules

Emmanuel Magnier

10ème Conférence Internationale de Chimie Toulouse-Kiev (ICTK - 10), Jun 2019, Toulouse, France

Communication dans un congrès hal-04401739v1

S-perfluoroalkyl sulfoximines: from synthesis to reactivity on photoredox catalysis

Emmanuel Magnier

Organic chemistry in Paris, Conférences de l’institut de chimie du Collège de France, Sep 2019, Paris, France

Communication dans un congrès hal-04373922v1

S-Perfluoroalkyl sulfoximines: preparation and use as source of radicals under photoredox catalysis

Emmanuel Magnier

Progress in Organofluorine Chemistry, Le studium conference, Oct 2018, Orléans, France

Communication dans un congrès hal-04373918v1

New and general access to S-perfluoroalkyl NH sulfoximines

Slim Chaabouni , Lohier Jean-François , Anne-Laure Barthelemy , Thomas Glachet , Elsa Anselmi et al.

22nd International Symposium on fluorine chemistry, Jul 2018, Oxford, United Kingdom

Communication dans un congrès hal-01828289v1

New and general access to S-perfluoroalkyl NH sulfoximines

Emmanuel Magnier

22st International Symposium on Fluorine Chemistry (22stISFC), Jul 2018, Oxford, United Kingdom

Communication dans un congrès hal-04373912v1

New and general access to S-perfluoroalkyl NH sulfoximines

Slim Chaabouni , Lohier Jean-François , Anne-Laure Barthelemy , Thomas Glachet , Elsa Anselmi et al.

Journée scientifique du labex CHARM3AT, Jun 2018, Cachan, France

Communication dans un congrès hal-01828299v1

Hypervalent Iodosulfoximines synthesis - An access to new perfluoroalkylating reagents

Emmanuel Magnier

55th Bürgenstock Conference, May 2022, Brunnen, Switzerland.

Poster de conférence hal-04400529v1

S-perfluoroalkylated sulfoximines : synthesis and properties

Emmanuel Magnier

54th Bürgenstock Conference, May 2019, Brunnen, Switzerland

Poster de conférence hal-04422847v1

Construction of S-RF Sulfilimines and S-RF Sulfoximines

Emmanuel Magnier

Emerging Fluorinated Motifs - Synthesis, Properties and Applications, 2020

Chapitre d'ouvrage hal-04386034v1