Emmanuel ROCCA

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Electrochemical behavior of deeply corroded 2024 aluminum alloy: insights from electrochemical and microscopy analyses

Roua Kaddah , Delphine Veys-Renaux , Emmanuel Rocca

Electrochimica Acta, 2026, 555, pp.148416. ⟨10.1016/j.electacta.2026.148416⟩

Article dans une revue hal-05515209v1

Protections anticorrosion des alliages d’aluminium

Emmanuel Rocca

Techniques de l'Ingénieur - Corrosion Vieillissement, 2025, COR326v1, ⟨10.51257/a-v1-cor326⟩

Article dans une revue hal-05262565v1
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Corrosion resistance of an AlSi alloy (AS12) after sulfuric anodizing and MAO: Mechanisms and effect of sealing with sodium decanoate

Anas Ben Romdhane , Delphine Veys-Renaux , Khaled Elleuch , Emmanuel Rocca

Surface and Coatings Technology, 2025, 516, pp.132745. ⟨10.1016/j.surfcoat.2025.132745⟩

Article dans une revue hal-05457482v1
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Designing bipolar anodizing towards white anodic aluminum oxide (AAO)

A. Gasco Owens , Delphine Veys-Renaux , Emmanuel Rocca

Surfaces and Interfaces, 2024, 53, pp.105103. ⟨10.1016/j.surfin.2024.105103⟩

Article dans une revue hal-04796766v1
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α-Zirconium hydrogenophosphate as a nano-container of 2-aminobenzimidazole for the corrosion protection of zinc in NaCl medium

I. Bouali , Emmanuel Rocca , Delphine Veys-Renaux , B. Rhouta , A. Khalil

Dalton Transactions, 2024, 53 (18), pp.7857-7865. ⟨10.1039/d4dt00476k⟩

Article dans une revue hal-04796768v1
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Bipolar pulse anodizing of aluminum: Understanding the fundamental electrochemical mechanisms

A. Gasco-Owens , D. Veys-Renaux , Emmanuel Rocca

Electrochimica Acta, 2024, 492, pp.144303. ⟨10.1016/j.electacta.2024.144303⟩

Article dans une revue (article de synthèse) hal-04796759v1
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Intercalation of decanoate anions (C10) in layered double hydroxide Mg Al and its application as controlled-release corrosion inhibitor of steel

A. Aitaghzzaf , Y. Zarki , B. Rhouta , A. Khalil , Delphine Veys-Renaux et al.

Surface and Coatings Technology, 2024, 489, pp.131055. ⟨10.1016/j.surfcoat.2024.131055⟩

Article dans une revue hal-04796763v1

Comportement en corrosion des alliages d’aluminium

Emmanuel Rocca

Techniques de l'Ingénieur - Corrosion Vieillissement, 2023, COR325v2, ⟨10.51257/a-v2-cor325⟩

Article dans une revue hal-05262572v1

Reverse scan polarization of anodic aluminum oxide until detachment in sulfuric acid: Mechanisms and morphologies

A. Gasco Owens , D. Veys-Renaux , E. Rocca

Electrochimica Acta, 2022, 435, pp.141361. ⟨10.1016/j.electacta.2022.141361⟩

Article dans une revue hal-03934968v1

Electrochemical coating of zinc carboxylate: A new protection for zinc in atmospheric conditions

Emmanuel Rocca , Sophie Jacques

Surface and Coatings Technology, 2022, 429, pp.127940. ⟨10.1016/j.surfcoat.2021.127940⟩

Article dans une revue (article de synthèse) hal-04963501v1
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Mechanism of alteration of the surface of lead crystal glass in contact with food: A chemical study of the surface layer

Guillaume Lecanuet , Emmanuel Rocca , Patricia Hee , Marie-Alice Skaper , Christophe Rapin

Applied Surface Science, 2022, 580, pp.152281. ⟨10.1016/j.apsusc.2021.152281⟩

Article dans une revue hal-03934986v1

60 Years’ marine corrosion of aluminium alloy 24S (2024) from an historic aircraft wreck site: implications for conservation

Emmanuel Rocca , J. Tardelli , F. Mirambet

Corrosion Engineering, Science and Technology, 2021, 56 (3), pp.279-288. ⟨10.1080/1478422X.2020.1859708⟩

Article dans une revue (article de synthèse) hal-04963495v1
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Sealing mechanism of nanoporous alumina in fluorozirconate salt containing solutions

Najat Chahboun , Delphine Veys-Renaux , Emmanuel Rocca

Applied Surface Science, 2021, 541, pp.148459. ⟨10.1016/j.apsusc.2020.148459⟩

Article dans une revue (article de synthèse) hal-04963491v1
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Large-pores anodizing of 5657 aluminum alloy in phosphoric acid: an in-situ electrochemical study

A. Gasco-Owens , Delphine Veys-Renaux , V. Cartigny , Emmanuel Rocca

Electrochimica Acta, 2021, 382, pp.138303. ⟨10.1016/j.electacta.2021.138303⟩

Article dans une revue (article de synthèse) hal-04963493v1

α-Zirconium orthophosphate as a new Zn-free anticorrosive pigment in organic coatings

I. Bouali , Emmanuel Rocca , Delphine Veys-Renaux , A. Khalil , B. Rhouta et al.

Journal of Solid State Electrochemistry, 2020, 25 (3), pp.831-840. ⟨10.1007/s10008-020-04862-1⟩

Article dans une revue (article de synthèse) hal-04963490v1
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Influence of nettle extract on zinc electrodeposition in an acidic bath: Electrochemical effect and coating morphology

A. Zaabar , E. Rocca , Delphine Veys-Renaux , R. Aitout , H. Hammache et al.

Hydrometallurgy, 2020, 191, pp.105186 -. ⟨10.1016/j.hydromet.2019.105186⟩

Article dans une revue hal-03488731v1

Pomegranate peels crude extract as a corrosion inhibitor of mild steel in HCl medium: Passivation and hydrophobic effect

Ahmed Ait Aghzzaf , Delphine Veys-Renaux , Emmanuel Rocca

Materials and Corrosion / Werkstoffe und Korrosion, 2020, 71 (1), pp.148-154. ⟨10.1002/maco.201911049⟩

Article dans une revue (article de synthèse) hal-04963497v1
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In situ spectroelectrochemical ellipsometry using super continuum white laser: Study of the anodization of magnesium alloy

Alexandre Zimmer , Delphine Veys-Renaux , Laurent Broch , Nicolas Stein , Emmanuel Rocca

Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures, 2019, 37 (6), pp.062911. ⟨10.1116/1.5122320⟩

Article dans une revue hal-02355013v1
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Electrochemical behavior of thick rust layers on steel artefact: Mechanism of corrosion inhibition

Emmanuel Rocca , Hadri Faiz , Philippe Dillmann , Delphine D. Neff , François Mirambet

Electrochimica Acta, 2019, 316, pp.219-227. ⟨10.1016/j.electacta.2019.05.107⟩

Article dans une revue cea-02401231v1
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Rapid sealing of an alumina nanoporous network grown by anodizing and dye-filled

Vincent Cartigny , Delphine Veys-Renaux , Patricia Desenne , Emmanuel Rocca

Surface and Coatings Technology, 2019, 364, pp.369 - 376. ⟨10.1016/j.surfcoat.2019.03.004⟩

Article dans une revue hal-03485919v1
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Conversion of steel by polyphenolic model molecules: Corrosion inhibition mechanism by rutin, esculin, esculetol

Delphine Veys-Renaux , Solenn Reguer , Ludovic Bellot-Gurlet , François Mirambet , Emmanuel Rocca

Corrosion Science, 2018, 136, pp.1 - 8. ⟨10.1016/j.corsci.2018.02.015⟩

Article dans une revue hal-01756156v1

Ca2+-exchange in layered zirconium orthophosphate, α-ZrP: Chemical study and potential application for zinc corrosion inhibition

Imane Bouali , Emmanuel Rocca , Delphine Veys-Renaux , Benaissa Rhouta , Aziza Khalil et al.

Applied Surface Science, 2017, 422, pp.778-786. ⟨10.1016/j.apsusc.2017.06.083⟩

Article dans une revue (article de synthèse) istex hal-04963499v1

Oxide Growth Mechanism on Mg AZ91 Alloy by Anodizing: Combination of Electrochemical and Ellipsometric In-Situ Measurements

Alexandre Zimmer , Delphine Veys-Renaux , Laurent Broch , Nicolas Stein , Emmanuel Rocca

Journal of The Electrochemical Society, 2017, 164 (14), pp.C1059-C1066. ⟨10.1149/2.1421714jes⟩

Article dans une revue hal-02900731v1

Grafted palygorskite as containers of heptanoate for corrosion protection of steel in NaCl medium

A. Aïtaghzzaf , B. Rhouta , Emmanuel Rocca , A. Khalil

Corrosion Science, 2017, 114, pp.88-95. ⟨10.1016/j.corsci.2016.10.028⟩

Article dans une revue (article de synthèse) istex hal-04963503v1

Corrosion resistance in artificial saliva of titanium anodized by plasma electrolytic oxidation in Na3PO4

Delphine Veys-Renaux , Zouhir Ait El Haj , Emmanuel Rocca

Surface and Coatings Technology, 2016, 285, pp.214-219. ⟨10.1016/j.surfcoat.2015.11.028⟩

Article dans une revue (article de synthèse) istex hal-04963511v1

Anodizing of multiphase aluminium alloys in sulfuric acid: in-situ electrochemical behaviour and oxide properties

Delphine Veys-Renaux , Najat Chahboun , Emmanuel Rocca

Electrochimica Acta, 2016, 211, pp.1056-1065. ⟨10.1016/j.electacta.2016.06.131⟩

Article dans une revue (article de synthèse) istex hal-04963510v1

Synchrotron radiation contribution to the study of aluminium corrosion layers of air and space museum aircrafts for their preservation

F. Mirambet , D. Vantelon , S. Reguer , Emmanuel Rocca

Journal of Analytical Atomic Spectrometry, 2016, 31 (8), pp.1631-1637. ⟨10.1039/c6ja00072j⟩

Article dans une revue (article de synthèse) hal-04963513v1

Corrosion inhibition of carbon steel in acidic medium by orange peel extract and its main antioxidant compounds

Nouha M'Hiri , Delphine Veys-Renaux , Emmanuel Rocca , Irina Ioannou , Nourhene Mihoubi Boudhrioua et al.

Corrosion Science, 2016, 102, pp.55-62. ⟨10.1016/j.corsci.2015.09.017⟩

Article dans une revue istex hal-01264845v1

Local Evolution of pH with Time Determined by Shear Force‐based Scanning Electrochemical Microscopy: Surface Reactivity of Anodized Aluminium

Mathieu Etienne , Emmanuel Rocca , Najat Chahboun , Delphine Veys-Renaux

Electroanalysis, 2016, 28 (10), pp.2466-2471. ⟨10.1002/elan.201600294⟩

Article dans une revue (article de synthèse) istex hal-04963506v1

Electrochemical behaviour of titanium in KOH at high potential

Aude Mathis , Emmanuel Rocca , Delphine Veys-Renaux , J. Tardelli

Electrochimica Acta, 2015, ⟨10.1016/j.electacta.2015.11.027⟩

Article dans une revue istex hal-01299933v1

Initial stages of multi-phased aluminium alloys anodizing by MAO: micro-arc conditions and electrochemical behaviour

Delphine Veys-Renaux , Emmanuel Rocca

Journal of Solid State Electrochemistry, 2015, 19 (10), pp.3121-3129. ⟨10.1007/s10008-015-2935-3⟩

Article dans une revue hal-01295125v1

Electrochemical behavior of zinc in KOH media at high voltage: Micro-arc oxidation of zinc

Emmanuel Rocca , Delphine Veys-Renaux , Khadoudj Guessoum

Journal of Electroanalytical Chemistry, 2015, 754, pp.125-132. ⟨10.1016/j.jelechem.2015.06.021⟩

Article dans une revue istex hal-01295121v1

Sealing of Anodized Multiphase Aluminum Alloys with Cr(+III)/Zr(+IV) Salts: Characterization and Corrosion Behavior

Najat Chahboun , Emmanuel Rocca , Delphine Veys-Renaux , Myriam Augros , Malik Boutoba et al.

Journal of The Electrochemical Society, 2015, 163 (3), pp.C69-C75. ⟨10.1149/2.0201603jes⟩

Article dans une revue (article de synthèse) hal-04963515v1

Heptanoic acid adsorption on grafted palygorskite and its application as controlled-release corrosion inhibitor of steel

A. Ait Aghzzaf , B. Rhouta , E. Rocca , A. Khalil , C. Caillet et al.

Materials Chemistry and Physics, 2014, 148 (1-2), pp.335-342. ⟨10.1016/j.matchemphys.2014.07.052⟩

Article dans une revue istex hal-01076883v1
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Initial stages of AZ91 Mg alloy micro-arc anodizing: Growth mechanisms and effect on the corrosion resistance

Delphine Veys-Renaux , Emmanuel Rocca , J. Martin , Gérard Henrion

Electrochimica Acta, 2014, 124, pp.36-45. ⟨10.1016/j.electacta.2013.08.023⟩

Article dans une revue hal-03612261v1

Corrosion inhibition of zinc by calcium exchanged beidellite clay mineral: A new smart corrosion inhibitor

A. Ait Aghzzaf , B. Rhouta , Emmanuel Rocca , A. Khalil , J. Steinmetz

Corrosion Science, 2014, 80, pp.46-52. ⟨10.1016/j.corsci.2013.10.037⟩

Article dans une revue istex hal-01291814v1

Corrosion behavior of AZ91 Mg alloy anodized by low-energy micro-arc oxidation: Effect of aluminates and silicates

Delphine Veys-Renaux , C. -E. Barchiche , Emmanuel Rocca

Surface and Coatings Technology, 2014, 251, pp.232-238. ⟨10.1016/j.surfcoat.2014.04.031⟩

Article dans une revue istex hal-01291829v1

Dealloying of Al2Cu, Al7Cu2Fe, and Al2CuMg intermetallic phases to form nanoparticulate copper films

S. Lebouil , J. Tardelli , Emmanuel Rocca , P. Volovitch , K. Ogle

Materials and Corrosion / Werkstoffe und Korrosion, 2014, 65 (4), pp.416-424. ⟨10.1002/maco.201307550⟩

Article dans une revue istex hal-01291823v1

New zinc-rare earth alloys: Influence of intermetallic compounds on the corrosion resistance

Delphine Veys-Renaux , Khadoudj Guessoum , Emmanuel Rocca , Nicolas David , Kamel Belhamel

Corrosion Science, 2013, 77, pp.342-349. ⟨10.1016/j.corsci.2013.08.024⟩

Article dans une revue istex hal-01289985v1

Micro-arc oxidation of AZ91 Mg alloy: An in-situ electrochemical study

Delphine Veys-Renaux , Emmanuel Rocca , Gerard Henrion

Electrochemistry Communications, 2013, 31, pp.42-45. ⟨10.1016/j.elecom2013.02.023⟩

Article dans une revue hal-01285343v1

Compact Metal-Organic Frameworks for Anti-Corrosion Applications: New Binary Linear Saturated Carboxylates of Zinc

Adel Mesbah , Sophie Jacques , Emmanuel Rocca , Michel François , Jean Steinmetz

European Journal of Inorganic Chemistry, 2011, 2011 (8), pp.1315-1321

Article dans une revue hal-02035688v1

Crystal structure and phase transition of bis-aqua-sebacato magnesium Mg(C10H16O4)2(H2O)2

Adel Mesbah , Lionel Aranda , Jean Steinmetz , Emmanuel Rocca , Michel François

Solid State Sciences, 2011, 13 (7), pp.1438-1442

Article dans une revue hal-02036416v1

Study of archaeological artefacts to refine the model of iron long-term indoor atmospheric corrosion

Judith Monnier , Ludovic Legrand , Ludovic Bellot-Gurlet , Eddy Foy , Solenn Reguer et al.

Journal of Nuclear Materials, 2008, 379 (1-3), pp.105-111. ⟨10.1016/j.jnucmat.2008.06.008⟩

Article dans une revue istex hal-01676905v1

Inhibitors for magnesium corrosion: Metal organic frameworks

Adel Mesbah , Caroline Juers , Françoise Lacouture , Stéphane Mathieu , Emmanuel Rocca et al.

Solid State Sciences, 2007, 9 (3-4), pp.322-328. ⟨10.1016/j.solidstatesciences.2006.12.007⟩

Article dans une revue istex hal-02029806v1

Structures of magnesium and zinc long aliphatic chains carboxylates

Adel Mesbah , C. Juers , M. Francois , E. Rocca , J. Steinmetz

Zeitschrift für Kristallographie Supplements, 2007, 2007 (suppl_26), pp.593-598. ⟨10.1524/zksu.2007.2007.suppl_26.593⟩

Article dans une revue hal-02030619v1

Intercalation in Zinc-Layered Hydroxide: Zinc Hydroxyheptanoate Used as Protective Material on Zinc

Emmanuel Rocca , Céline Caillet , Adel Mesbah , Michel François , Jean Steinmetz

Chemistry of Materials, 2006, 18 (26), pp.6186-6193. ⟨10.1021/cm0616026⟩

Article dans une revue istex hal-02029477v1

Corrosion of materials used as cutting tools of wood

M. Gauvent , E. Rocca , P.J. Meausoone , P. Brenot

Wear, 2006, 261 (9), pp.1051-1055. ⟨10.1016/j.wear.2006.03.036⟩

Article dans une revue istex hal-03007855v1

In situ ellipsometric and electrochemical monitoring of the oxidation of a Pb–Ca–Sn alloy used in the lead acid batteries

N. Stein , G. Bourguignon , L. Raboin , L. Broch , L. Johann et al.

Thin Solid Films, 2004, 455-456, pp.735-741. ⟨10.1016/j.tsf.2003.11.259⟩

Article dans une revue istex hal-02900547v1