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Frederic Thibault-Starzyk

115
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Presentation

### Directeur de Recherche CNRS #### CAREER - 2016-20 Director of the [Maison Française](http://mfo.ac.uk), University of Oxford - 2012-16 Director, [Catalysis and Spectrochemistry Laboratory](https://www.lcs.ensicaen.fr), CNRS, ENSICAEN-University of Caen - 2009 Research Director, CNRS - 2003-04 Visiting scientist in the Surface Science Group, Prof. Sir David King, Cambridge (UK), fellowship at Churchill College - 1994 Chargé de Recherche (Research Scientist) in the CNRS - 1992-94 postdoc with Prof P.A. Jacobs (Katholieke Universiteit Leuven, Belgium), Marie Curie grant. - 1992 PhD organic chemistry in Caen, with a grant from the National Agency for Research on AIDS (ANRS). #### RESEARCH INTERESTS AND KEY-WORDS Heterogeneous catalysis, Infrared spectroscopy, time resolved chemistry, interface & surface chemistry, zeolites, micro & mesoporous materials #### KEY POINTS AND AWARDS - Founder and president of the Foundation for the Maison Francaise d'Oxford - Representative of the CNRS for the Universities Lorraine and Champagne-Ardenne 2020-23 - Senior Associate, Pembroke College Oxford, 2017-22 - President of the French Zeolite Association 2009-2014 - Treasurer of the Federation of European Zeolite Associations 2014 - Laureate of the first Toyota Call in 2007 - French Government Fellow, Churchill College, Cambridge, 2004 - Prize of the Catalysis Division of the French Chemical Society in 2000 - 120 publications in peer reviewed journals, 25 invited lectures, 1 book, 3 chapters, 1 patent - Board of the International Conference on Operando Spectroscopy 2000-2016 - Chairman Internat. Conference on Operando Spectroscopy, OperandoV, Deauville (FR), May 2015
### Directeur de Recherche CNRS #### CARRIERE - 2024 Chargé de Mission pour la Direction de l'Appui aux Partenariats Publics du CNRS - 2020-23 Adjoint au Directeur Scientifique Référent du CNRS pour les sites Lorraine et Champagne-Ardenne - 2016-20 Directeur de la [Maison française d'Oxford](http://mfo.ac.uk), CNRS-Ministère de l'Europe et des Affaires Etrangères-Université d'Oxford - 2012-16 Directeur du [Laboratoire Catalyse et Spectrochimie](https://www.lcs.ensicaen.fr), CNRS, ENSICAEN-Université de Caen - 2009 Directeur de Recherche CNRS - 2003-04 Mis à disposition à l'Université de Cambridge (UK), groupe de Science des Surfaces avec David King, sur un fellowship de Churchill College - 1994 Chargé de Recherche CNRS - 1992-94 Post-doctorat avec Pierre A. Jacobs (Katholieke Universiteit Leuven, Belgique), bourse Marie Curie. - 1992 Doctorat de Chimie Organique à Caen, avec Didier Villemin, sur une bourse de l'Agence Nationale de Recherche sur le SIDA (ANRS). #### DOMAINES ET MOTS-CLÉS Catalyse Hétérogène, spectroscopie infrarouge, chimie résolue en temps, chimie des surfaces et interfaces, zéolithes, silice, matériaux micro et mésoporeux #### FAITS MARQUANTS ET RECOMPENSES - Fondateur et président de la Fondation pour la Maison française d'Oxford - Senior Associate, Pembroke College Oxford, 2017-22 - Président du Groupe Français des Zéolithes 2009-2014 - Trésorier de la Federation of European Zeolite Associations 2014 - Lauréat du first Toyota Call en 2007 - French Government Fellow, Churchill College, Cambridge, 2004 - Prix de la Division Catalyse de la Société Chimique de France en 2000 - 120 articles à comité de lecture, 25 conférence invités internationales, 1 livre, 3 chapitres, 1 brevet - Comité de l'International Conference on Operando Spectroscopy 2000-2016 - Président de l'Internat. Conference on Operando Spectroscopy, OperandoV, Deauville (FR), May 2015

Publications

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Unveiling the potential of surfactant Pluronic-P123 application during the synthesis of Ni-hydrotalcite-derived catalysts for low-temperature CO2 methanation: A novel approach

Minh Nguyen-Quang , Federico Azzolina-Jury , Frédéric Thibault-Starzyk , Arnaud Travert , Magdalena Ziąbka
Applied Materials Today, 2023, 32, pp.101805. ⟨10.1016/j.apmt.2023.101805⟩
Journal articles hal-04295398v1
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Evidence of Synergy Effects between Zinc and Copper Oxides with Acidic Sites on Natural Zeolite during Photocatalytic Oxidation of Ethylene Using Operando DRIFTS Studies

Norberto Abreu , Héctor Valdés , Claudio Zaror , Tatianne Ferreira de Oliveira , Federico Azzolina-Jury
Catalysts, 2023, 13 (3), pp.610. ⟨10.3390/catal13030610⟩
Journal articles hal-04295403v1
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Observation of surface species in plasma-catalytic dry reforming of methane in a novel atmospheric pressure dielectric barrier discharge in situ IR cell

Joran van Turnhout , Domenico Aceto , Arnaud Travert , Philippe Bazin , Frédéric Thibault-Starzyk
Catalysis Science & Technology, 2022, 12 (22), pp.6676-6686. ⟨10.1039/D2CY00311B⟩
Journal articles hal-04295411v1
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Removal of chlorinated volatile organic compounds onto natural and Cu-modified zeolite: The role of chemical surface characteristics in the adsorption mechanism

Héctor Valdés , Andrés L Riquelme , Víctor A Solar , Federico Azzolina-Jury , Frederic Thibault-Starzyk
Separation and Purification Technology, 2021, 258, pp.118080. ⟨10.1016/j.seppur.2020.118080⟩
Journal articles hal-03024978v1
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New insight of the influence of acidic surface sites of zeolite on the ability to remove gaseous ozone using operando DRIFTS studies

Héctor Valdés , Francisco J Ulloa , Víctor A Solar , Manuel S Cepeda , Federico Azzolina-Jury
Microporous and Mesoporous Materials, 2020, 294, pp.109912. ⟨10.1016/j.micromeso.2019.109912⟩
Journal articles hal-02419105v1
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Probing the acid sites of zeolites with pyridine: quantitative AGIR measurements of the molar absorption coefficients

Vladimir Zholobenko , Cátia Freitas , Martin Jendrlin , Philippe Bazin , Arnaud Travert
Journal of Catalysis, 2020, 385, pp.52--60. ⟨10.1016/j.jcat.2020.03.003⟩
Journal articles hal-02500425v1
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Low-pressure glow discharge plasma-assisted catalytic CO2 hydrogenation—The effect of metal oxide support on the performance of the Ni-based catalyst

Radosław Dębek , Federico Azzolina-Jury , Arnaud Travert , Françoise Mauge , Frederic Thibault-Starzyk
Catalysis Today, 2019, 337, pp.182-194. ⟨10.1016/j.cattod.2019.03.039⟩
Journal articles hal-02267588v1

Entschlüsselung des Kieselsäure/ Silan-Reaktionsmechanismus zur Entwicklung von Reifen mit geringem Rollwiderstand. Teil 1 – Charakterisierung durch In-situ-IR-Spektroskopie

Frederic Thibault-Starzyk , Anke Blume
GAK Gummi Fasern Kunststoffe, 2017, 70 (4), pp.220-226
Journal articles hal-01831432v1

Selective response of pyrylium-functionalized nanozeolites in the visible spectrum towards volatile organic compounds

Frederic Thibault-Starzyk , Mohamad El-Roz , Hussein Awala , Svetlana Mintova
Sensors and Actuators B: Chemical, 2017, 249, pp.114 - 122. ⟨10.1016/j.snb.2017.04.038⟩
Journal articles hal-01831406v1

Chemical engineering aspects of plasma-assisted CO 2 hydrogenation over nickel zeolites under partial vacuum

Federico Azzolina-Jury , Diogo Bento , Carlos Henriques , Frederic Thibault-Starzyk
Journal of CO2 Utilization, 2017, 22, pp.97 - 109. ⟨10.1016/j.jcou.2017.09.017⟩
Journal articles hal-01831362v1

Deciphering the silica/silane reaction mechanism for the development of a new generation of low rolling resistance tires Part 2 – Transfer of results from model examinations into practice

Frederic Thibault-Starzyk , Anke Blume
RFP Rubber, fibres, plastics international : Magazine for the polymer industry, 2017, 12 (4), pp.236-241
Journal articles hal-01831426v1

Influence de la structure sur la relation acidité-activité dans les zéolites acides

S Joly , J Saussey , A Janin , Frederic Thibault-Starzyk , Jc Lavalley
Journal de Chimie Physique, 2017, 94, pp.1838-1847. ⟨10.1051/jcp/1997941838⟩
Journal articles hal-04299994v1

Mechanism of Low Pressure Plasma-Assisted CO2 Hydrogenation Over Ni-USY by Microsecond Time-resolved FTIR Spectroscopy

Frederic Thibault-Starzyk , Federico Azzolina-Jury
Topics in Catalysis, 2017, 60 (19-20), pp.1709 - 1721. ⟨10.1007/s11244-017-0849-2⟩
Journal articles hal-01831389v1

Influence of Microwave-Assisted Synthesis Parameters on ZSM-11 Zeolite Production Without Seeding

Federico Azzolina-Jury , Frédéric Thibault-Starzyk
Current Microwave Chemistry, 2016, 3 (2), pp.102-113. ⟨10.2174/2213335602666150716164633⟩
Journal articles hal-01296719v1
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Towards biolubricant compatible vegetable oils by pore mouth hydrogenation with shape-selective Pt/ZSM-5 catalysts

J. van Aelst , A. Philippaerts , E. Bartholomeeusen , E. Fayad , Frederic Thibault-Starzyk
Catalysis Science & Technology, 2016, 6 (8), pp.2820 - 2828. ⟨10.1039/C6CY00498A⟩
Journal articles hal-01831411v1
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On the enhancing effect of Ce in Pd-MOR catalysts for NOx CH4-SCR: A structure-reactivity study

Acácio Nobre Mendes , Vladimir L Zholobenko , Frédéric Thibault-Starzyk , Patrick Da Costa , Carlos Henriques
Applied Catalysis B: Environmental, 2016, 195, pp.121 - 131. ⟨10.1016/j.apcatb.2016.05.004⟩
Journal articles hal-01831394v1

Pore Occupancy Changes Water/Ethanol Separation in a Metal–Organic Framework—Quantitative Map of Coadsorption by IR

Frederic Thibault-Starzyk , Mohamad El-Roz , Philippe Bazin , Tadeja Birsa Čelič , Nataša Zabukovec Logar
Journal of Physical Chemistry C, 2015, 119 (39), pp.22570 - 22576. ⟨10.1021/acs.jpcc.5b07183⟩
Journal articles hal-01831399v1

Unraveling the mechanism of catalytic reactions through combined kinetic and thermodynamic analyses: Application to the condensation of ethanol

Frédéric Meunier , J. Scalbert , F. Thibault-Starzyk
Comptes Rendus. Chimie, 2015, 18 (3), pp.345-350. ⟨10.1016/j.crci.2014.07.002⟩
Journal articles hal-01172536v1

Advances in design and modeling of porous materials

André Ayral , Sylvie Calas-Etienne , Benoit Coasne , André Deratani , Alexis Evstratov
The European Physical Journal. Special Topics, 2015, 224, pp.1653. ⟨10.1140/epjst/e2015-02487-6⟩
Journal articles hal-01227244v1

On the mechanism of methanol photooxidation to methylformate and carbon dioxide on TiO 2 : an operando-FTIR study

Frederic Thibault-Starzyk , Mohamad El-Roz , Philippe Bazin , Marco Daturi
Physical Chemistry Chemical Physics, 2015, 17 (17), pp.11277 - 11283. ⟨10.1039/C5CP00726G⟩
Journal articles hal-01831395v1
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Catalytic ozonation with γ-Al2O3 to enhance the degradation of refractory organics in water

Jullian Vittenet , Aboussaoud Wael , Mendret Julie , Jean-Stephane Pic , Hubert Jean-Stephane
Applied Catalysis A : General, 2015, 504, pp.519-532. ⟨10.1016/j.apcata.2014.10.037⟩
Journal articles hal-01079847v1

Unraveling the mechanism of chemical reactions through thermodynamic analyses: A short review

Frédéric Meunier , J. Scalbert , F. Thibault-Starzyk
Applied Catalysis A : General, 2015, ⟨10.1016/j.apcata.2014.12.028⟩
Journal articles hal-01229991v1

Probing zeolites by vibrational spectroscopies

Frederic Thibault-Starzyk , Silvia Bordiga , Carlo Lamberti , Francesca Bonino , Arnaud Travert
Chemical Society Reviews, 2015, 44 (20), pp.7262 - 7341. ⟨10.1039/C5CS00396B⟩
Journal articles hal-01831400v1

Speciation of adsorbates on surface of solids by infrared spectroscopy and chemometrics

Franck Vilmin , Philippe Bazin , Frederic Thibault-Starzyk , Arnaud Travert
Analytica Chimica Acta, 2015, 891, pp.79 - 89. ⟨10.1016/j.aca.2015.06.006⟩
Journal articles hal-01831407v1

Reactivity of Bis[3-(triethoxysilyl)propyl] Tetrasulfide (TESPT) Silane Coupling Agent over Hydrated Silica: Operando IR Spectroscopy and Chemometrics Study

Franck Vilmin , Ilaria Bottero , Arnaud Travert , Nicolas Malicki , Fabien Gaboriaud
Journal of Physical Chemistry C, 2014, 118 (8), pp.4056 - 4071. ⟨10.1021/jp408600h⟩
Journal articles hal-01831403v1

Ultra-fast framework stabilization of Ge-rich zeolites by low-temperature plasma treatment

Mohamad El-Roz , Louwanda Lakiss , Aurelie Vicente , Krassimir Bozhilov , Frederic Thibault-Starzyk
Chemical Science, 2014, 5 (1), pp.68-80. ⟨10.1039/c3sc51892b⟩
Journal articles hal-02403238v1

Liquid phase cyclohexene oxidation over vanadia based catalysts with tert-butyl hydroperoxide: Epoxidation versus allylic oxidation

Frederic Thibault-Starzyk , Sanaa El-Korso , Ilyes Khaldi , Sumeya Bedrane , Abderrahim Choukchou-Braham
Journal of Molecular Catalysis A: Chemical, 2014, 394, pp.89 - 96. ⟨10.1016/j.molcata.2014.07.002⟩
Journal articles hal-01831387v1
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The Oil Shale Transformation in the Presence of an Acidic BEA Zeolite under Microwave Irradiation

Ana Neto , Sébastien Thomas , Gary Bond , Frederic Thibault-Starzyk , Filipa Ribeiro
Energy & Fuels, 2014, 28 (4), pp.2365 - 2377. ⟨10.1021/ef4023898⟩
Journal articles hal-01831409v1

Infrared study of the silica/silane reaction. Part II

Anke Blume , Mohamad El-Roz , Frederic Thibault-Starzyk
KGK Kautschuk, Gummi, Kunststoffe, 2014, 67 (number of volumes: 5), pp.53--57
Journal articles hal-01840256v1

Ethanol condensation to butanol at high temperatures over a basic heterogeneous catalyst: How relevant is acetaldehyde self-aldolization?

J. Scalbert , F. Thibault-Starzyk , R. Jacquot , D. Morvan , Frédéric Meunier
Journal of Catalysis, 2014, 311, pp.28-32. ⟨10.1016/j.jcat.2013.11.004⟩
Journal articles hal-01057389v1
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Incorporation of clusters of titanium oxide in Beta zeolite structure by a new cold TiCl4-plasma process: physicochemical properties and photocatalytic activity

Mohamad El-Roz , Louwanda Lakiss , Jaafar El Fallah , Oleg Lebedev , Frederic Thibault-Starzyk
Physical Chemistry Chemical Physics, 2013, 15 (38), pp.16198. ⟨10.1039/C3CP52478G⟩
Journal articles hal-01963797v1

Quantification of silanol sites for the most common mesoporous ordered silicas and organosilicas: total versus accessible silanols

Frederic Thibault-Starzyk , Matthias Ide , Mohamad El-Roz , Els de Canck , Aurélie Vicente
Physical Chemistry Chemical Physics, 2013, 15 (2), pp.642 - 650. ⟨10.1039/c2cp42811c⟩
Journal articles hal-01831402v1
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Operando Infrared (IR) Coupled to SSITKA for Photocatalysis: Reactivity and Mechanistic Studies

Mohamad El-Roz , Philippe Bazin , Marco Daturi , Frederic Thibault-Starzyk
ACS Catalysis, 2013, 3 (12), pp.2790-2798
Journal articles hal-01963787v1

Adsorption of CO 2 , CH 4 , and H 2 O in Zeolite ZSM-5 Studied Using In Situ ATR-FTIR Spectroscopy

Lindsay Ohlin , Philippe Bazin , Frederic Thibault-Starzyk , Jonas Hedlund , Mattias Grahn
Journal of Physical Chemistry C, 2013, 117 (33), pp.16972 - 16982. ⟨10.1021/jp4037183⟩
Journal articles hal-01831319v1
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Study of Hydrothermal Stability and Water Sorption Characteristics of 3-Dimensional Zn-Based Trimesate

Tadeja Birsa Čelič , Matjaž Mazaj , Nathalie Guillou , Erik Elkaim , Mohamad El Roz
Journal of Physical Chemistry C, 2013, 117 (28), pp.14608-14617. ⟨10.1021/jp4036327⟩
Journal articles hal-01963791v1
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Hardwood lignin pyrolysis in the presence of nano-oxide particles embedded onto natural clinoptilolite

Nevenka Rajić , Nataša Zabukovec Logar , Aleksander Rečnik , Mohamad El-Roz , Frederic Thibault-Starzyk
Microporous and Mesoporous Materials, 2013, 176, pp.162-167. ⟨10.1016/j.micromeso.2013.04.005⟩
Journal articles hal-01963788v1

Infrared Study of the Silica/Silane Reaction

A. Blume , Mohamad El-Roz , Frederic Thibault-Starzyk
KGK-KAUTSCHUK GUMMI KUNSTSTOFFE, 2013, 66 (10), pp.63--70
Journal articles hal-01840296v1

Catalytic CO2 valorization into CH4 on Ni-based ceria-zirconia. Reaction mechanism by operando IR spectroscopy

P. Aldana , F. Ocampo , K. Kobl , B. Louis , F. Thibault-Starzyk
Catalysis Today, 2013, 215, pp.201 - 207. ⟨10.1016/j.cattod.2013.02.019⟩
Journal articles hal-01831356v1

An operando-IR study of photocatalytic reaction of methanol on new *BEA supported TiO2 catalyst

Mohamad El-Roz , Philipe Bazin , Frederic Thibault-Starzyk
Catalysis Today, 2013, 205, pp.111 - 119. ⟨10.1016/j.cattod.2012.08.023⟩
Journal articles hal-01831350v1

Incorporation of clusters of titanium oxide in Beta zeolite structure by a new cold TiCl4-plasma process: physicochemical properties and photocatalytic activity

Mohamad El-Roz , Louwanda Lakiss , Jaafar El Fallah , Oleg Lebedev , Frederic Thibault-Starzyk
Physical Chemistry Chemical Physics, 2013, 15 (38), pp.16198. ⟨10.1039/c3cp52478g⟩
Journal articles hal-02403249v1

Effective bulk and surface temperatures of the catalyst bed of FT-IR cells used for in situ and operando studies

H. G. Li , M. Rivallan , F. Thibault-Starzyk , Arnaud Travert , F. C. Meunier
Physical Chemistry Chemical Physics, 2013, 15, pp.7321-7327. ⟨10.1039/c3cp50442e⟩
Journal articles hal-00832821v1

Adsorption of CO2, CH4, and H2O in Zeolite ZSM-5 Studied Using In Situ ATR-FTIR Spectroscopy

Lindsay Ohlin , Philippe Bazin , Frederic Thibault-Starzyk , Jonas Hedlund , Mattias Grahn
Journal of Physical Chemistry C, 2013, 117 (33), pp.16972--16982
Journal articles hal-01840278v1
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Immobilization of TiO2 nanoparticles on natural Luffa cylindrica fibers for photocatalytic applications

Mohamad El-Roz , Zeinab Haidar , Louwanda Lakiss , Joumana Toufaily , Frederic Thibault-Starzyk
RSC Advances, 2013, 3 (10), pp.3438-3445. ⟨10.1039/c2ra22438k⟩
Journal articles hal-01963800v1

In Situ FT-IR Investigation of Etravirine Speciation in Pores of SBA-15 Ordered Mesoporous Silica Material upon Contact with Water

Frederic Thibault-Starzyk , Randy Mellaerts , Elie Fayad , Guy van den Mooter , Patrick Augustijns
Molecular Pharmaceutics, 2013, 10 (2), pp.567 - 573. ⟨10.1021/mp300229q⟩
Journal articles hal-01831380v1

In situ FTIR studies of propene adsorption over Ag- and Cu-exchanged Y zeolites

Frederic Thibault-Starzyk , F. Benaliouche , Y. Boucheffa
Microporous and Mesoporous Materials, 2012, 147 (1), pp.10 - 16. ⟨10.1016/j.micromeso.2011.04.040⟩
Journal articles hal-01831382v1

Insights into the Mechanisms of Isopropanol Conversion on ?-Al2O3 by Dielectric Barrier Discharge

M. Rivallan , E. Fourre , S. Aiello , J.M. Tatibouet , F. Thibault-Starzyk
Plasma Processes and Polymers, 2012, 9 (9), pp.850-854. ⟨10.1002/ppap.201200021⟩
Journal articles hal-00829755v1

Cold plasma as environmentally benign approach for activation of zeolite nanocrystals

Mohamad El Roz , Louwanda Lakiss , Valentin Valtchev , Svetlana Mintova , Frederic Thibault-Starzyk
Microporous and Mesoporous Materials, 2012, 158, pp.148 - 154. ⟨10.1016/j.micromeso.2012.03.003⟩
Journal articles hal-01831371v1
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New Operando IR Technique to Study the Photocatalytic Activity and Selectivity of TiO 2 Nanotubes in Air Purification: Influence of Temperature, UV Intensity, and VOC Concentration

Mohamad El-Roz , Monika Kus , Pegie Cool , Frederic Thibault-Starzyk
Journal of Physical Chemistry C, 2012, 116 (24), pp.13252-13263. ⟨10.1021/jp3034819⟩
Journal articles hal-02430232v1

A critical overview of the catalytic potential of zeolite supported metal complexes

D. de Vos , Frederic Thibault-Starzyk , P. Knops-Gerrits , R. Parton , P. Jacobs
Macromolecular Symposia, 2011, 80 (1), pp.157-184. ⟨10.1002/masy.19940800112⟩
Journal articles hal-04299588v1

Combination of mid-infrared spectroscopy and curve resolution method to follow the antioxidant action of alkylated diphenylamines

N. Gracia , S. Thomas , F. Thibault-Starzyk , O. Lerasle , L. Duponchel
Chemometrics and Intelligent Laboratory Systems, 2011, 106, pp.210 - 215. ⟨10.1016/j.chemolab.2010.08.017⟩
Journal articles hal-00666075v1

Pt speciation on ZSM-5 by IR of probes co-adsorption and chemometric analysis

Frederic Thibault-Starzyk , Sébastien Thomas , Mickael Rivallan , Muriel Lepage , Nobuyuki Takagi
Microporous and Mesoporous Materials, 2011, 140 (1-3), pp.103 - 107. ⟨10.1016/j.micromeso.2010.10.046⟩
Journal articles hal-01831401v1

The Porosity, Acidity, and Reactivity of Dealuminated Zeolite ZSM-5 at the Single Particle Level: The Influence of the Zeolite Architecture

Frederic Thibault-Starzyk , Luis Aramburo , Lukasz Karwacki , Pablo Cubillas , Shunsuke Asahina
Chemistry - A European Journal, 2011, 17 (49), pp.13773 - 13781. ⟨10.1002/chem.201101361⟩
Journal articles hal-01831410v1

Design of hierarchically structured catalysts by mordenites recrystallization: Application in naphthalene alkylation

I.I. Ivanova , A.S. Kuznetsov , E.E. Knyazeva , F. Fajula , F. Thibault-Starzyk
Catalysis Today, 2011, 168 (1), pp.133-139. ⟨10.1016/j.cattod.2010.11.091⟩
Journal articles hal-00602562v1

Synthesis and catalytic properties of hierarchical micro/mesoporous materials based on FER zeolite

Yu.P. Khitev , Yu.G. Kolyagin , I.I. Ivanova , O.A. Ponomareva , F. Thibault-Starzyk
Microporous and Mesoporous Materials, 2011, 146, pp.201-207. ⟨10.1016/j.micromeso.2011.05.003⟩
Journal articles hal-00645124v1

Analysing and understanding the active site by IR spectroscopy

Alexandre Vimont , Frederic Thibault-Starzyk , Marco Daturi
Chemical Society Reviews, 2010, 39 (12), ⟨10.1039/b919543m⟩
Journal articles hal-01831352v1

Plasma Synthesis of Highly Dispersed Metal Clusters Confined in Nanosized Zeolite

Frederic Thibault-Starzyk , Mickael Rivallan , Ivan Yordanov , Sébastien Thomas , Christine Lancelot
ChemCatChem, 2010, 2 (9), pp.1074 - 1078. ⟨10.1002/cctc.201000113⟩
Journal articles hal-01831398v1

Aluminium triplets in dealuminated zeolites detected by Al-27 NMR correlation spectroscopy

Nicolas Malicki , Gregor Mali , Anne-Agathe Quoineaud , Patrick Bourges , Laurent J Simon
Microporous and Mesoporous Materials, 2010, 129 (1-2), pp.100--105. ⟨10.1016/j.micromeso.2009.09.003⟩
Journal articles hal-01840518v1

Interaction of water and ammonium in NaHY zeolite as detected by combined IR and gravimetric analysis (AGIR)

Frederic Thibault-Starzyk , Philippe Bazin , Aurélie Alenda
Dalton Transactions, 2010, 39 (36), ⟨10.1039/c0dt00158a⟩
Journal articles hal-01831386v1

Combination of mid-infrared spectroscopy and chemometric factorization tools to study the oxidation of lubricating base oils

N. Gracia , S. Thomas , P. Bazin , L. Duponchel , F. Thibault-Starzyk
Catalysis Today, 2010, 155, pp.255 - 260. ⟨10.1016/j.cattod.2009.11.012⟩
Journal articles hal-00563913v1

Evolution of Platinum Particles Dispersed on Zeolite upon Oxidation Catalysis and Ageing

Frederic Thibault-Starzyk , Mickael Rivallan , Sébastien Thomas , Muriel Lepage , Nobuyuki Takagi
ChemCatChem, 2010, 2 (12), pp.1599 - 1605. ⟨10.1002/cctc.201000182⟩
Journal articles hal-01831376v1

Platinum Sintering on H-ZSM-5 Followed by Chemometrics of CO Adsorption and 2D Pressure-Jump IR Spectroscopy of Adsorbed Species

Mickael Rivallan , Etienne Seguin , Sebastien Thomas , Muriel Lepage , Nobuyuki Takagi
Angewandte Chemie International Edition, 2010, 49 (4), pp.785--789
Journal articles hal-01840496v1

Microsecond time-resolved Fourier transform infrared analytics in a low pressure glow discharge reactor

Frederic Thibault-Starzyk , Mickael Rivallan , Sébastien Aiello
Review of Scientific Instruments, 2010, 81 (10), ⟨10.1063/1.3492094⟩
Journal articles hal-01831392v1

Quantification of enhanced acid site accessibility in hierarchical zeolites - The accessibility index

F. Thibault-Starzyk , I. Stan , S. Abello , A. Bonilla , K. Thomas
Journal of Catalysis, 2009, 264 (1), pp.11-14. ⟨10.1016/j.jcat.2009.03.006⟩
Journal articles hal-01711609v1

Real-Time Infrared Detection of Cyanide Flip on Silver-Alumina NOx Removal Catalyst

Frederic Thibault-Starzyk , Etienne Seguin , Sébastien Thomas , Marco Daturi , Heike Arnolds
Science, 2009, 324 (5930), pp.1048-1051. ⟨10.1126/science.1169041⟩
Journal articles hal-01831404v1

Infrared and microwaves at 5.8 GHz in a catalytic reactor

Etienne Seguin , Sebastien Thomas , Philippe Bazin , Gary Bond , Carlos Henriques
Physical Chemistry Chemical Physics, 2009, 11 (11), pp.1697--1701
Journal articles hal-01840536v1

New insights on zeolite chemistry by advanced IR and NMR characterization tools

Jean-Pierre Gilson , Christian Fernandez , Frederic Thibault-Starzyk
Journal of Molecular Catalysis A: Chemical, 2009, 305 (1-2), pp.54-59. ⟨10.1016/j.molcata.2009.02.036⟩
Journal articles hal-01711611v1

Mesoporous aluminophosphate thin films with cubic pore arrangement

M. Mazaj , S. Costacurta , N. Zabukovec Logar , G. Mali , N. Novak Tusar
Langmuir, 2008, 24, pp.6220-6224. ⟨10.1021/la703574⟩
Journal articles hal-00346263v1

Operando infrared study of the reaction of triethoxypropylsilane with silica

A. Blume , M. Janik , H. J. P. Gallas , F. Thibault-Starzyk , A. Vimont
KGK-Kautschuk Gummi Kuntstoffe, 2008, 61, pp.359-362
Journal articles hal-00346268v1

Unusual Carbonyl-Nitrosyl Complexes of Rh2+ in Rh-ZSM-5: A Combined FTIR Spectroscopy and Computational Study

E. Ivanova , M. Mihaylov , H.A. Aleksandrov , M. Daturi , F. Thibault-Starzyk
Journal of Physical Chemistry C, 2007, 111 (28), pp.10412-10418. ⟨10.1021/jp067531f⟩
Journal articles hal-00346256v1

Influence of annealing temperature on the CO sensing mechanism for tin dioxide based sensors - Operando studies

Dorota Koziej , Karine Thomas , N. Barsan , Frederic Thibault-Starzyk , Udo Weimar
Catalysis Today, 2007, 126, pp.211-218. ⟨10.1016/j.cattod.2007.03.011⟩
Journal articles hal-00226334v1

FTIR spectroscopy study of CO and NO adsorption and co-adsorption on Pt/TiO2

Elena Ivanova , M. Mihaylov , Frederic Thibault-Starzyk , Marco Daturi , K. Hadjiivanov
Journal of Molecular Catalysis A: Chemical, 2007, 274, pp.179-184. ⟨10.1016/j.molcata.2007.05.006⟩
Journal articles hal-00226333v1

MOF materials as catalysts for organic transformations and as selective hosts in recognition of organics

Luc Alaerts , Frederic Thibault-Starzyk , Etienne Seguin , J.F. M. Denayer , Pierre A. Jacobs
Studies in Surface Science and Catalysis, 2007, 170, pp.1996-2003
Journal articles hal-00226326v1

A new model for acid sites in dealuminated Y zeolites

Nicolas Malicki , P. Beccat , P. Bourges , C. Fernandez , Anne-Agate Quoineaud
Studies in Surface Science and Catalysis, 2007, 170, pp.762-770
Journal articles hal-00226264v1

The use of the consecutive adsorption of pyridine bases and carbon monoxide in the IR spectroscopic study of the accessibility of acid sites in microporous/mesoporous materials

N.S. Nesterenko , F. Thibault-Starzyk , V. Montouillout , V.V. Yushchenko , C. Fernandez
Kinetics and Catalysis, 2006, 47 (1), pp.40-48. ⟨10.1134/S0023158406010071⟩
Journal articles hal-00154833v1

REACTIVITY OF PHOSPHONIC KETENE DITHIOACETALS TOWARDS NUCLEOPHILES

Didier Villemin , Frédéric Thibault-Starzyk
Phosphorus, Sulfur, and Silicon and the Related Elements, 2006, 80 (1-4), pp.251-254. ⟨10.1080/10426509308036897⟩
Journal articles hal-04299740v1

Multiplex MQMAS NMR of quadrupolar nuclei.

Nicolas Malicki , Luís Mafra , Anne-Agathe Quoineaud , João Rocha , Frédéric Thibault-Starzyk
Solid State Nuclear Magnetic Resonance, 2005, 28 (1), pp.13-21. ⟨10.1016/j.ssnmr.2005.02.007⟩
Journal articles hal-00776044v1

NO2 disproportionation for the IR characterisation of basic zeolites

Olivier Marie , Nicolas Malicki , Catherine Pommier , Pascale Massiani , Ann Vos
Chemical Communications, 2005, pp.1049-1051
Journal articles hal-00126967v1

Conversion of xylene over mordenites: an operando infrared spectroscopy study of the effect of Na+

Pascale Massiani , Olivier Marie , Frédéric Thibault-Starzyk
Journal of Catalysis, 2004, 230, pp.28-37
Journal articles hal-00126974v1

Accessibility of the acid sites in dealuminated small-port mordenites studied by FTIR of co-adsorbed alkylpyridines and CO

N.S. Nesterenko , F. Thibault-Starzyk , V. Montouillout , V.V. Yuschenko , C. Fernandez
Microporous and Mesoporous Materials, 2004, 71 (1-3), pp.157 - 166. ⟨10.1016/j.micromeso.2004.03.028⟩
Journal articles hal-01831315v1

IR Spectroscopic Evidence for the Absence of Structural Hydroxyl Groups in Cloverite

Frédéric Thibault-Starzyk , André Janin , Jean‐claude Lavalley
Angewandte Chemie International Edition in English, 2003, 36 (9), pp.989-991. ⟨10.1002/anie.199709891⟩
Journal articles hal-04299983v1

Manganese-Containing Silica-Based Microporous Molecular Sieve MnS-1: Synthesis and Characterization

Nataša Novak Tušar , Nataša Zabukovec Logar , Iztok Arčon , Frederic Thibault-Starzyk , Alenka Ristić
Chemistry of Materials, 2003, 15 (25), pp.4745 - 4750. ⟨10.1021/cm031091c⟩
Journal articles hal-01831285v1

Schiff Base Complexes with Five‐Coordinate Cobalt as Dioxygen Activating Sites in Zeolites

Dirk de Vos , Frédéric Thibault-Starzyk , Peter Jacobs
Angewandte Chemie International Edition in English, 2003, 33 (4), pp.431-433. ⟨10.1002/anie.199404311⟩
Journal articles hal-04299644v1

Large-Pore FAPO-36: Synthesis and Characterization

Alenka Ristić , Nataša Novak Tušar , Iztok Arčon , Nataša Zabukovec Logar , Frederic Thibault-Starzyk
Chemistry of Materials, 2003, 15 (19), pp.3643 - 3649. ⟨10.1021/cm0310263⟩
Journal articles hal-01831280v1

Incorporation of heteroatoms (Me=Zn, Co, Mn) into framework sites of the gallophosphate molecular sieve ULM-5

Maja Mrak , Nataša Novak Tušar , Alenka Ristić , Iztok Arčon , Frederic Thibault-Starzyk
Microporous and Mesoporous Materials, 2002, 56 (3), pp.257-266. ⟨10.1016/S1387-1811(02)00490-0⟩
Journal articles hal-04300935v1

Synthesis and characterization of triclinic MeAPO-34 (Me=Zn, Fe) molecular sieves

Alenka Ristić , Nataša Novak Tušar , Iztok Arčon , Frederic Thibault-Starzyk , Darko Hanžel
Microporous and Mesoporous Materials, 2002, 56 (3), pp.303-315. ⟨10.1016/S1387-1811(02)00504-8⟩
Journal articles hal-04300946v1

Vibrational studies of iron phthalocyanines in zeolites

Peter-Paul H.J.M. Knops-Gerrits , Frédéric Thibault-Starzyk , Rudy Parton
Studies in Surface Science and Catalysis, 2002, Studies in Surface Science and Catalysis, 142, pp.1809-1816. ⟨10.1016/S0167-2991(02)80356-1⟩
Journal articles hal-04300911v1

Infrared evidence for the reversible protonation of acetonitrile at high temperature in mordenite

J. Czyzniewska , S. Chenevarin , Frederic Thibault-Starzyk
Studies in Surface Science and Catalysis, 2002, Studies in Surface Science and Catalysis, 142, pp.335-342. ⟨10.1016/S0167-2991(02)80046-5⟩
Journal articles hal-04300924v1

NO+ ions as IR probes for the location of OH groups and Na+ ions in main channels and side pockets of mordenite

Carlos Henriques , Olivier Marie , Frédéric Thibault-Starzyk , Jean-Claude Lavalley
Microporous and Mesoporous Materials, 2001, 50 (2-3), pp.167-171. ⟨10.1016/S1387-1811(01)00444-9⟩
Journal articles hal-04300298v1

12-O-01 - 2D correlation IR spectroscopy of xylene isomerisation on H-MFI zeolite

Frederic Thibault-Starzyk , A. Vimont , J.-P. Gilson
Studies in Surface Science and Catalysis, 2001, Studies in Surface Science and Catalysis, 135, pp.133. ⟨10.1016/S0167-2991(01)81193-9⟩
Journal articles hal-04300091v1

2D-COS IR study of coking in xylene isomerisation on H-MFI zeolite

Frédéric Thibault-Starzyk , Alexandre Vimont , Jean-Pierre Gilson
Catalysis Today, 2001, 70 (1-3), pp.227-241. ⟨10.1016/S0920-5861(01)00420-5⟩
Journal articles hal-04300209v1
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Isomorphous Substitution of Framework Atoms by Titanium in VPI-5 Aluminophosphate Molecular Sieve

Nataša Novak Tušar , Nataša Zabukovec Logar , Iztok Arčon , Frederic Thibault-Starzyk , Venčeslav Kaučič
CROATICA CHEMICA ACTA, 2001, 74 (4), pp.837-849
Journal articles hal-04300258v1

2D correlation IR spectroscopy of xylene isomerisation on H-MFI zeolite

F. Thibault-Starzyk , A. Vimont , Christian Fernandez , J.-P. Gilson
Chemical Communications, 2000, 12, pp.1003-1004. ⟨10.1039/b002007i⟩
Journal articles hal-01711644v1

Confirmation of the strongest nitriles–hydroxy groups interaction in the side pockets of mordenite zeolites

Olivier Marie , Frederic Thibault-Starzyk , Jean-Claude Lavalley
Physical Chemistry Chemical Physics, 2000, 2 (22), pp.5341-5349. ⟨10.1039/B005901N⟩
Journal articles hal-04300078v1

In situ infrared study of hydroxyl groups poisoned by coke formation from hydrocarbons conversion on H-zeolites

A. Vimont , O. Marie , J.P. Gilson , J. Saussey , Frederic Thibault-Starzyk
Studies in Surface Science and Catalysis, 1999, Studies in Surface Science and Catalysis, 126, pp.147-154. ⟨10.1016/S0167-2991(99)80461-3⟩
Journal articles hal-04300021v1

Infrared Spectroscopic Study of the Acidobasic Properties of Beta Zeolite

A. Vimont , Frederic Thibault-Starzyk , J. Lavalley
Journal of Physical Chemistry B, 1999, 104 (2), pp.286-291. ⟨10.1021/jp992550t⟩
Journal articles hal-04300034v1

Confinement of Acetonitrile Molecules in Mordenite. A Computer Modeling Study

Konstantin Smirnov , Frédéric Thibault-Starzyk
Journal of Physical Chemistry B, 1999, 103 (40), pp.8595-8601. ⟨10.1021/jp991520n⟩
Journal articles hal-04300010v1

Correlation between activity and acidity on zeolites: a high temperature infrared study of adsorbed acetonitrile

Frédéric Thibault-Starzyk , Arnaud Travert , Jacques Saussey , Jean‐claude Lavalley
Topics in Catalysis, 1998, 6 (1/4), pp.111-118. ⟨10.1023/A:1019182826692⟩
Journal articles hal-04300003v1

Acidity in working Zeolites: use of a stabilised Carbenium in a new Route for the Synthesis of secondary Amides on ZSM-5

Frederic Thibault-Starzyk , Mohammed Bettahar , Jacques Saussey , Jean-Claude Lavalley
Studies in Surface Science and Catalysis, 1997, Studies in Surface Science and Catalysis, 105, pp.925-931. ⟨10.1016/S0167-2991(97)80723-9⟩
Journal articles hal-04299966v1

IR evidence of zeolitic hydroxy insertion in amide formation by the Ritter reaction

Frederic Thibault-Starzyk , Roland Payen , Jean-Claude Lavalley
Chemical Communications, 1996, 23, pp.2667. ⟨10.1039/CC9960002667⟩
Journal articles hal-04299975v1

Thiol-oxidation with zeolite encapsulated phthalocyanines: influence of the solid support

Frédéric Thibault-Starzyk , Mark van Puymbroeck , Rudy Parton , Pierre Jacobs
Journal of Molecular Catalysis A: Chemical, 1996, 109 (1), pp.75-79. ⟨10.1016/1381-1169(96)00026-X⟩
Journal articles hal-04299961v1

Stacked phthalocyanines in VPI-5 pores as evidenced by CPDOR 1H27Al NMR

Rudy Parton , Frédéric Thibault-Starzyk , Reinoud Reynders , Piet Grobet , Pierre Jacobs
Journal of Molecular Catalysis A: Chemical, 1995, 97 (3), pp.183-186. ⟨10.1016/1381-1169(94)00074-3⟩
Journal articles hal-04299942v1

Adipic Acid Synthesis via Oxidation of Cyclohexene over Zeolite occulded Manganese Diimine Complexes

P.P. Knops-Gerrits , Frederic Thibault-Starzyk , P.A. Jacobs
Studies in Surface Science and Catalysis, 1994, Studies in Surface Science and Catalysis, 84, pp.1411-1418. ⟨10.1016/S0167-2991(08)63682-4⟩
Journal articles hal-04299925v1

Oxidation of cyclohexanone and cyclohexane to adipic acid by iron-phthalocyanine on zeolite Y

Frederic Thibault-Starzyk , R.F. Parton , P.A. Jacobs
Studies in Surface Science and Catalysis, 1994, Studies in Surface Science and Catalysis, 84, pp.1419-1424. ⟨10.1016/S0167-2991(08)63683-6⟩
Journal articles hal-04299928v1

Catalytic Properties of VPI-5 Encaged Ironphthalocyanines

Rudy Parton , Cvetana Bezoukhanova , Frédéric Thibault-Starzyk , Reinoud Reynders , Piet Grobet
Studies in Surface Science and Catalysis, 1994, Studies in Surface Science and Catalysis, 84, pp.813-820. ⟨10.1016/S0167-2991(08)64084-7⟩
Journal articles hal-04299934v1

Zeolite-encapsulated Mn(II) complexes as catalysts for selective alkene oxidation

Peter-Paul Knops-Gerrits , Dirk de Vos , Frédéric Thibault-Starzyk , Pierre Jacobs
Nature, 1994, 369 (6481), pp.543-546. ⟨10.1038/369543a0⟩
Journal articles hal-04299931v1

A Convenient Synthesis of Cyclopropanes from Olefin and Carbon Acid Compounds. Synthesis of Tetraethyl Cyclopropanediyldiphosphonates

Didier Villemin , Frédéric Thibault-Starzyk , Messaoud Hachemi
Synthetic Communications, 1994, 24 (10), pp.1425-1431. ⟨10.1080/00397919408011746⟩
Journal articles hal-04299937v1

Synthesis of a New Sulfur Analog of PMEA

Didier Villemin , Frédéric Thibault-Starzyk
Synthetic Communications, 1993, 23 (8), pp.1053-1059. ⟨10.1080/00397919308018581⟩
Journal articles hal-04299755v1

A Convenient Synthesis of α-Ketodithioesters from Methylketones

Didier Villemin , Frédéric Thibault-Starzyk
SYNLETT, 1993, 1993 (02), pp.148-148. ⟨10.1055/s-1993-22383⟩
Journal articles hal-04299722v1

An Easy Formation of Dithioacetals on Alumina-KF Under Microwave Irradiation. Synthesis of new Potential Antiviral Phosphonates

Didier Villemin , Abdelkrim Ben Alloum , Frédéric Thibault-Starzyk
Synthetic Communications, 1992, 22 (9), pp.1359-1366. ⟨10.1080/00397919208019319⟩
Journal articles hal-04299787v1

NEW CONVENIENT SYNTHESIS OF PHOSPHONIC KETENE DITHIOACETALS USING POTASSIUM FLUORIDE ON ALUMINA

Didier Villemin , Frédéric Thibault-Starzyk , Eric Esprimont
Phosphorus, Sulfur, and Silicon and the Related Elements, 1992, 70 (1), pp.117-120. ⟨10.1080/10426509208049159⟩
Journal articles hal-04299775v1

Domestic microwave ovens in the laboratory

Didier Villemin , Frederic Thibault-Starzyk
Journal of Chemical Education, 1991, 68 (4), pp.346. ⟨10.1021/ed068p346⟩
Journal articles hal-04299804v1
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Clays and Zeolites

Frederic Thibault-Starzyk
Between Nature and Society: Biographies of Materials (Ed. B. Bensaude-Vincent), 2022, 9789811251740
Book sections hal-03813852v1

2D-IR pressure jump spectroscopy for the study of adsorbed species on zeolites (2D-PJAS-IR)

F. Thibault-Starzyk , S. Chenevarin , Christian Fernandez
VanSteen, E. and Claeys, M. and Callanan, L. H. Recent Advances in the Science and Technology of Zeolites and Related Materials, Pts a - C, 154, pp.1730-1736, 2004, Studies in Surface Science and Catalysis
Book sections hal-01711625v1
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Infrared Spectroscopy: Classical Methods

Jacques Saussey , Frederic Thibault-Starzyk
Bert Marc Weckhuysen. In Situ Characterization of Catalysts, American Scientific Publishers, pp.15-31, 2004, 1-58883-026-8
Book sections hal-04661179v1