Iker Del Rosal

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Publications

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Mono- to Tetra-nuclear Iron Dichloride Complexes Bearing N -(Fluoro)-aryl-Substituted Iminopyridine Ligands: Synthesis, Structures, Magnetic Properties, and Polymerization of Isoprene

Obaid Hashmi , Raphael Caulier , Frederic Capet , Olivier Mentré , Claire Minaud et al.

Inorganic Chemistry, 2025, 64 (29), pp.14836-14852. ⟨10.1021/acs.inorgchem.5c01030⟩

Article dans une revue hal-05163264v1
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Synergistic C–H bond activation across molybdenum–iridium multiply bonded complexes: a cascade of transformations

Zachary Dubrawski , Iker del Rosal , Erwann Jeanneau , Laurent Maron , Chloé Thieuleux et al.

Chemical Science, 2025, ⟨10.1039/D5SC03465E⟩

Article dans une revue hal-05173362v1
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Biplane-like small N-heterocyclic carbenes as effective ligands in challenging Ru-catalyzed metathesis of sterically crowded olefins

Paweł Krzesiński , Chiara Dinoi , Iker Del rosal , Laure Vendier , Pavel Kumandin et al.

Chem Catalysis, 2025, 5 (5), pp.101292. ⟨10.1016/j.checat.2025.101292⟩

Article dans une revue hal-04542322v2
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Probing Structural Diversity in a Series of Perhydrocarbyl Heterobimetallic Complexes Associating Tantalum and 3d (Cr, Mn, Fe, Co, Ni) Transition Metals

Till Neumann , Iker del Rosal , Laurent Maron , Erwann Jeanneau , Vincent Maurel et al.

Inorganic Chemistry, 2025, 64 (43), pp.21353-21367. ⟨10.1021/acs.inorgchem.5c02380⟩

Article dans une revue hal-05505845v1
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Effect of Nitrogen and Phosphorus Doping of Reduced Graphene Oxide in the Hydrogen Evolution Catalytic Activity of Supported Ru Nanoparticles

Laura Mallón , Javier Navarro-Ruiz , Christian Cerezo-Navarrete , Nuria Romero , Iker del Rosal et al.

ACS Applied Materials & Interfaces, 2025, 17 (4), pp.6198-6210. ⟨10.1021/acsami.4c15547⟩

Article dans une revue hal-04931941v1
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Room-Temperature H<sub>2</sub> Splitting and N<sub>2</sub>-Hydrogenation Induced by a Neutral Lu(II) Complex

Evangelos Papangelis , Luca Demonti , Iker del Rosal , Angus Shephard , Laurent Maron et al.

Journal of the American Chemical Society, 2025, 147 (11), pp.9752-9763. ⟨10.1021/jacs.4c18416⟩

Article dans une revue hal-05213394v1

Oxidative Addition of E-H (E=C, N) Bonds to Transient Uranium(II) Centers

Wei Fang , Yafei Li , Tianze Zhang , Thayalan Rajeshkumar , Iker Del rosal et al.

Angewandte Chemie International Edition, 2024, 63 (32), ⟨10.1002/anie.202407339⟩

Article dans une revue hal-04707677v1
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Photolysis-driven bond activation by thorium and uranium tetraosmate polyhydride complexes

Christopher Ye , Iker del Rosal , Sheridon Kelly , I. Joseph Brackbill , Laurent Maron et al.

Chemical Science, In press, ⟨10.1039/D4SC02380C⟩

Article dans une revue hal-04611467v1

Straightforward construction of a rare-earth diphosphanato complex from white phosphorus: synthesis and reactivity

Fangjun Zhang , Iker Del rosal , Keyu Han , Jie Zhang , Laurent Maron et al.

Inorganic Chemistry Frontiers, 2024, 11 (6), pp.1742-1753. ⟨10.1039/d3qi02680a⟩

Article dans une revue hal-04707645v1
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Probing Basal and Prismatic Planes of Graphitic Materials for Metal Single Atom and Subnanometer Cluster Stabilization

Mathieu Vidal , Jyoti Pandey , Javier Navarro-Ruiz , Joris Langlois , Yann Tison et al.

Chemistry - A European Journal, 2024, 30 (50), pp.e202400669. ⟨10.1002/chem.202400669⟩

Article dans une revue hal-04677240v1
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Synthesis, Structure, and Bonding of Actinide–Rhenium Polyhydrides

Christopher Ye , Iker del Rosal , Sheridon Kelly , Erik Ouellette , Laurent Maron et al.

Inorganic Chemistry, In press, ⟨10.1021/acs.inorgchem.4c03449⟩

Article dans une revue hal-04749940v1
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Reduction of CS 2 to an ethanetetrathiolate by a hydride-bridged uranium–iridium heterobimetallic complex

Christopher Z Ye , Iker del Rosal , Erik T Ouellette , Stephan Hohloch , Laurent Maron et al.

Chemical Communications, In press, ⟨10.1039/D4CC02482F⟩

Article dans une revue hal-04724457v1
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π-Bonding of Group 11 Metals to a Tantalum Alkylidyne Alkyl Complex Promotes Unusual Tautomerism to Bis-alkylidene and CO 2 to Ketenyl Transformation

Abdelhak Lachguar , Iker del Rosal , Laurent Maron , Erwann Jeanneau , Laurent Veyre et al.

Journal of the American Chemical Society, 2024, ⟨10.1021/jacs.4c02172⟩

Article dans une revue hal-04630141v1
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Mechanism of Hydrogen Spillover on Metal-Doped Carbon Materials: Surface Carboxylic Groups Are Key

Javier Navarro-Ruiz , Jérémy Audevard , Mathieu Vidal , Cristian Campos , Iker del Rosal et al.

ACS Catalysis, 2024, 14 (9), pp.7111-7126. ⟨10.1021/acscatal.4c00293⟩

Article dans une revue hal-04587084v1
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CO<sub>2</sub> cleavage by tantalum/M (M = iridium, osmium) heterobimetallic complexes

Abdelhak Lachguar , Christopher Z Ye , Sheridon N Kelly , Erwann Jeanneau , Iker del Rosal et al.

Chemical Communications, 2024, 60 (61), pp.7878-7881. ⟨10.1039/D4CC02207F⟩

Article dans une revue hal-04738526v1
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Isolation of C1 through C4 derivatives from CO using heteroleptic uranium( iii ) metallocene aryloxide complexes

Robert Ward , Iker Del Rosal , Steven Kelley , Laurent Maron , Justin Walensky

Chemical Science, 2023, 14 (8), pp.2024-2032. ⟨10.1039/d2sc06375a⟩

Article dans une revue hal-04218352v1
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“Cocktail”-type catalysis on bimetallic systems for cinnamaldehyde selective hydrogenation: Role of isolated single atoms, nanoparticles and single atom alloys

Jérémy Audevard , Javier Navarro-Ruiz , Vincent Bernardin , Régis Philippe , Anna Corrias et al.

Journal of Catalysis, 2023, 425, pp.245-259. ⟨10.1016/j.jcat.2023.06.023⟩

Article dans une revue hal-04139552v1
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Deactivation of Pd/C catalysts by irreversible loss of hydrogen spillover ability of the carbon support

Laurent Vanoye , Boris Guicheret , Camila Rivera-Cárcamo , Jérémy Audevard , Javier Navarro-Ruiz et al.

Journal of Catalysis, 2023, 424, pp.173-188. ⟨10.1016/j.jcat.2023.05.006⟩

Article dans une revue hal-04113228v1

A binuclear guanidinate yttrium carbyne complex: unique reactivity toward unsaturated C-N, C-O and C-S bonds

Wen Jiang , Feng Kong , Iker Del rosal , Meng Li , Kai Wang et al.

Chemical Science, 2023, ⟨10.1039/d3sc03483f⟩

Article dans une revue hal-04707640v1

Synthesis and Reactivity of a Zinc Diazoalkyl Complex: [3+2] Cycloaddition Reaction with Carbon Monoxide

Shengjie Jiang , Yanping Cai , Thayalan Rajeshkumar , Iker Del rosal , Laurent Maron et al.

Angewandte Chemie International Edition, 2023, 62 (34), ⟨10.1002/anie.202307244⟩

Article dans une revue hal-04707653v1
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An Experimental and Computational Investigation Rules Out Direct Nucleophilic Addition on the N2 Ligand in Manganese Dinitrogen Complex [Cp(CO)2Mn(N2)]

Quentin Le Dé , Amal Bouammali , Christian Bijani , Laure Vendier , Iker Del rosal et al.

Angewandte Chemie International Edition, 2023, 62 (40), pp.e202305235. ⟨10.1002/anie.202305235⟩

Article dans une revue hal-04159061v1
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Adjustment of the Single Atom/Nanoparticle Ratio in Pd/CNT Catalysts for Phenylacetylene Selective Hydrogenation

Jérémy Audevard , Javier Navarro-Ruiz , Vincent Bernardin , Yann Tison , Anna Corrias et al.

ChemCatChem, 2023, 15 (11), pp.e202300036. ⟨10.1002/cctc.202300036⟩

Article dans une revue hal-04102599v1
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On the use of 17 O NMR for understanding molecular and silica-grafted tungsten oxo siloxide complexes

Y. Bouhoute , D. Grekov , N. Merle , K. Szeto , C. Larabi et al.

Dalton Transactions, 2023, 52 (28), pp.9573-9581. ⟨10.1039/D3DT01593A⟩

Article dans une revue hal-04238255v1

Multimetallic Uranium Nitride Cubane Clusters from Dinitrogen Cleavage

Mikhail S. Batov , Iker Del rosal , Rosario Scopelliti , Farzaneh Fadaei-Tirani , Ivica Zivkovic et al.

Journal of the American Chemical Society, 2023, 145 (48), pp.26435-26443. ⟨10.1021/jacs.3c10617⟩

Article dans une revue hal-04707678v1

Isolation of C1 through C4 derivatives from CO using heteroleptic uranium(III) metallocene aryloxide complexes (vol 14, pg 2024, 2023)

Robert J. Ward , Iker Del Rosal , Steven P. Kelley , Laurent Maron , Justin R. Walensky

Chemical Science, 2023, 14 (12), pp.3385. ⟨10.1039/d3sc90046k⟩

Article dans une revue hal-04707634v1

Organotitanium Complexes Supported by a Dianionic Pentadentate Ligand

Daniel Beh , Alejandro Cuellar de Lucio , Iker del Rosal , Laurent Maron , Denis Spasyuk et al.

Organometallics, 2023, 42 (11), pp.1149-1157. ⟨10.1021/acs.organomet.2c00609⟩

Article dans une revue hal-04218412v1
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1,2-Palladasilacyclobutene: The Missing Link in the Pd-Catalyzed Annulation of Alkynes for the Silirene-to-Silole Transformation

Marc Devillard , Chiara Dinoi , Iker Del rosal , Clément Orione , Marie Cordier et al.

Inorganic Chemistry, 2023, 62 (19), pp.7250-7263. ⟨10.1021/acs.inorgchem.3c00045⟩

Article dans une revue hal-04115375v1
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A Versatile Strategy for the Formation of Hydride-Bridged Actinide-Iridium Multimetallics

Christopher Z Ye , Iker Del rosal , Michael A Boreen , Erik T Ouellette , Dominic Russo et al.

Chemical Science, 2022, ⟨10.1039/D2SC04903A⟩

Article dans une revue hal-03909474v1
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Ruthenium icosahedra and ultrathin platelets: the role of surface chemistry on the nanoparticle structure

Raj Kumar Ramamoorthy , Katerina Soulantica , Iker Del rosal , Raul Arenal , Philippe Decorse et al.

Chemistry of Materials, 2022, 34 (7), pp.2931-2944. ⟨10.1021/acs.chemmater.1c03452⟩

Article dans une revue hal-03644170v1
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Ruthenium nanoparticles canopied by heptagon-containing saddle-shaped nanographenes as efficient aromatic hydrogenation catalysts

Christian Cerezo-Navarrete , Arthur David , Adrián García-Zaragoza , Marcos Codesal , Pascual Oña-Burgos et al.

Chemical Science, 2022, 13 (44), pp.13046-13059. ⟨10.1039/d2sc04228b⟩

Article dans une revue hal-04104569v1
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Hydroboration of vinyl halides with mesitylborane: a direct access to (mesityl)(alkyl)haloboranes

Marc Devillard , Marie Cordier , Thierry Roisnel , Chiara Dinoi , Iker Del rosal et al.

Chemical Communications, 2022, 58 (10), pp.1589-1592. ⟨10.1039/D1CC06365K⟩

Article dans une revue hal-03539282v1
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Rational Preparation of Well-Defined Multinuclear Iridium-Aluminum Polyhydride Clusters and Comparative Reactivity

Leon Escomel , Naime Soule , Emmanuel Robin , Iker del Rosal , Laurent Maron et al.

Inorganic Chemistry, 2022, 61 (15), pp.5715-5730. ⟨10.1021/acs.inorgchem.1c03120⟩

Article dans une revue hal-03714651v1

Synthesis and Reactivity of Triangular Heterometallic ComplexesContaining Zn-Zn Bond br

Shengjie Jiang , Yanping Cai , Ambre Carpentier , Iker del Rosal , Laurent Maron et al.

Inorganic Chemistry, 2022, 61 (20), pp.8083-8089. ⟨10.1021/acs.inorgchem.2c00956⟩

Article dans une revue hal-03714644v1
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Supramolecular nanocapsules as two-fold stabilizers of outer-cavity sub-nanometric Ru NPs and inner-cavity ultra-small Ru clusters

Ernest Ubasart , Irene Mustieles Marin , Juan Manuel Asensio , Gabriel Mencia , Ángela M López-Vinasco et al.

Nanoscale Horizons, 2022, 7 (6), pp.607 - 615. ⟨10.1039/d1nh00677k⟩

Article dans une revue hal-04222757v1

A Masked Form of an O‐Borylated Breslow Intermediate for the Diastereoselective FLP‐Type Activation of Aldehydes

Angelica Mejia Fajardo , Nicolas Queyriaux , Aurèle Camy , Laure Vendier , Mary Grellier et al.

Chemistry - A European Journal, 2022, 28 (10), pp.e202104122. ⟨10.1002/chem.202104122⟩

Article dans une revue hal-03669849v1

Surface reactions of ammonia on ruthenium nanoparticles revealed by 15 N and 13 C solid-state NMR

Niels Rothermel , Hans-Heinrich Limbach , Iker del Rosal , Romuald Poteau , Gabriel Mencia et al.

Catalysis Science & Technology, 2021, 11 (13), pp.4509-4520. ⟨10.1039/d0cy02476g⟩

Article dans une revue hal-04222858v1
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Bimetallic RuNi nanoparticles as catalysts for upgrading biomass: metal dilution and solvent effects on selectivity shifts

Miquel Cardona-Farreny , Pierre Lecante , Jerome Esvan , Chiara Dinoi , Iker Del rosal et al.

Green Chemistry, 2021, 23 (21), pp.8480-8500. ⟨10.1039/D1GC02154K⟩

Article dans une revue hal-03412846v1
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A Uranium(II) Arene Complex That Acts as a Uranium(I) Synthon

Mark D. Straub , Erik T. Ouellette , Michael A. Boreen , R. David Britt , Khetpakorn Chakarawet et al.

Journal of the American Chemical Society, 2021, 143 (47), pp.19748-19760. ⟨10.1021/jacs.1c07854⟩

Article dans une revue hal-03717277v1

Hydrosilylative reduction of carbon dioxide by a homoleptic lanthanum aryloxide catalyst with high activity and selectivity

Kejian Chang , Iker del Rosal , Xizhou Zheng , Laurent Maron , Xin Xu

Dalton Transactions, 2021, 50 (22), pp.7804-7809. ⟨10.1039/d1dt01074c⟩

Article dans une revue hal-03717252v1
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Synthesis, Characterization, and Comparative Theoretical Investigation of Dinitrogen-Bridged Group 6-Gold Heterobimetallic Complexes

David Specklin , Anaïs Coffinet , Laure Vendier , Iker Del rosal , Chiara Dinoi et al.

Inorganic Chemistry, 2021, 60 (8), pp.5545-5562. ⟨10.1021/acs.inorgchem.0c03271⟩

Article dans une revue hal-03176320v2
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Computational Design of Pd Nanocluster and Pd Single-Atom Catalysts Supported on O-Functionalized Graphene

Javier Navarro-Ruiz , Camila Rivera-Cárcamo , Bruno Machado , Philippe Serp , Iker Del rosal et al.

ACS Applied Nano Materials, 2021, 4 (11), pp.12235-12249. ⟨10.1021/acsanm.1c02743⟩

Article dans une revue hal-03627539v1

Nickel-catalyzed synthesis of Zn(i)-Zn(i) bonded compounds

Shengjie Jiang , Yanping Cai , Ambre Carpentier , Iker del Rosal , Laurent Maron et al.

Chemical Communications, 2021, 57 (100), pp.13696-13699. ⟨10.1039/d1cc05719g⟩

Article dans une revue hal-03717250v1
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Uncatalyzed Formation of Polyaminoboranes from Diisopropylaminoborane and Primary Amines: a Kinetically Controlled Polymerization Reaction

Marc Devillard , Carlos Antonio de Albuquerque Pinheiro , Elsa Caytan , Claire Roiland , Chiara Dinoi et al.

Advanced Synthesis and Catalysis, 2021, 363 (9), pp.2417-2426. ⟨10.1002/adsc.202001458⟩

Article dans une revue hal-03127420v1
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A combined theoretical/experimental study highlighting the formation of carbides on Ru nanoparticles during CO hydrogenation

Ionut-Tudor Moraru , Luis Martínez-Prieto , Yannick Coppel , Bruno Chaudret , Lucy Cusinato et al.

Nanoscale, 2021, 13 (14), pp.6902-6915. ⟨10.1039/D0NR08735A⟩

Article dans une revue hal-03202748v1

Scandium and lanthanum hydride complexes stabilized by super-bulky penta-arylcyclopentadienyl ligands

Yang Wang , Iker del Rosal , Guorui Qin , Lanxiao Zhao , Laurent Maron et al.

Chemical Communications, 2021, 57 (63), pp.7766-7769. ⟨10.1039/d1cc01841h⟩

Article dans une revue hal-03717282v1
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Strongly Polarized Iridium δ− –Aluminum δ+ Pairs: Unconventional Reactivity Patterns Including CO 2 Cooperative Reductive Cleavage

Léon Escomel , Iker del Rosal , Laurent Maron , Erwann Jeanneau , Laurent Veyre et al.

Journal of the American Chemical Society, 2021, 143 (12), pp.4844-4856. ⟨10.1021/jacs.1c01725⟩

Article dans une revue hal-03357324v1
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Control of the single atom/nanoparticle ratio in Pd/C catalysts to optimize the cooperative hydrogenation of alkenes

Camila Rivera‐cárcamo , I.C. Gerber , Iker Del rosal , B. Guicheret , Rubén Castro Contreras et al.

Catalysis Science & Technology, 2021, 11 (3), pp.984-999. ⟨10.1039/d0cy01938k⟩

Article dans une revue hal-03148510v1

Calcium-mediated C(sp(3))-H Activation and Alkylation of Alkylpyridines

Xizhou Zheng , Iker del Rosal , Xian Xu , Yingming Yao , Laurent Maron et al.

Inorganic Chemistry, 2021, 60 (7), pp.5114-5121. ⟨10.1021/acs.inorgchem.1c00161⟩

Article dans une revue hal-03717254v1

Molecular Thorium Trihydrido Clusters Stabilized by Cyclopentadienyl Ligands

Runhai Chen , Guorui Qin , Shihui Li , Alison J. Edwards , Ross O. Piltz et al.

Angewandte Chemie International Edition, 2020, 59 (28), pp.11250-11255. ⟨10.1002/anie.202002303⟩

Article dans une revue hal-03925198v1
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Catalysis to discriminate single atoms from subnanometric ruthenium particles in ultra-high loading catalysts

Camila Rivera‐cárcamo , Faqiang Leng , I.C. Gerber , Iker Del rosal , Romuald Poteau et al.

Catalysis Science & Technology, 2020, 10 (14), pp.4673-4683. ⟨10.1039/D0CY00540A⟩

Article dans une revue hal-02904642v1

Comparative Insertion Reactivity of CO, CO2, (BuCN)-Bu-t, and (BuNC)-Bu-t into Thorium- and Uranium-Phosphorus Bonds

Michael L. Tarlton , Iker del Rosal , Sean P. Vilanova , Steven P. Kelley , Laurent Maron et al.

Organometallics, 2020, 39 (11), pp.2152-2161. ⟨10.1021/acs.organomet.0c00221⟩

Article dans une revue hal-03925196v1
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Mechanistic Investigations via DFT Support the Cooperative Heterobimetallic C-H and O-H Bond Activation Across Ta=Ir Multiple Bonds

Iker Del rosal , Sébastien Lassalle , Laurent Maron , Chiara Dinoi , Chloé Thieuleux et al.

Dalton Transactions, 2020, ⟨10.1039/D0DT03818K⟩

Article dans une revue hal-03009651v1
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Hydrogen isotope exchange catalyzed by Ru nanocatalysts: labelling of complex molecules containing N-heterocycles and reaction mechanism insights

Viktor Pfeifer , Marie Certiat , Donia Bouzouita , Alberto Palazzolo , Sébastien Garcia-Argote et al.

Chemistry - A European Journal, 2020, 26, pp.4988-4996. ⟨10.1002/chem.201905651⟩

Article dans une revue cea-02487414v1
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How Cu I and Na I Interact with Faujasite Zeolite? A Theoretical Investigation

Hugo Petitjean , Christine Lepetit , Zalfa Nour , Romuald Poteau , Iker Del rosal et al.

Journal of Physical Chemistry C, 2020, 124 (51), pp.28026-28037. ⟨10.1021/acs.jpcc.0c06862⟩

Article dans une revue hal-03117227v1

NH3 formation from N2 and H2 mediated by molecular tri-iron complexes

Matthias Reiners , Dirk Baabe , Katharina Münster , Marc-Kevin Zaretzke , Matthias Freytag et al.

Nature Chemistry, 2020, 12 (8), pp.740-746. ⟨10.1038/s41557-020-0483-7⟩

Article dans une revue hal-03150029v1

Nickel(0)-Induced beta-H Elimination of Magnesium Alkyls: Formation and Reactivity of Heterometallic Hydrides

Jiasu Huang , Xizhou Zheng , Iker del Rosal , Bei Zhao , Laurent Maron et al.

INORGANIC CHEMISTRY, 2020, 59 (18), pp.13473-13480. ⟨10.1021/acs.inorgchem.0c01885⟩

Article dans une revue hal-03925186v1
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Divergent uranium-versusphosphorus-based reduction of Me(3)SiN(3)with steric modification of phosphido ligands

Robert J. Ward , Pokpong Rungthanaphatsophon , Iker del Rosal , Steven P. Kelley , Laurent Maron et al.

Chemical Science, 2020, 11 (22), pp.5830-5835. ⟨10.1039/d0sc02261f⟩

Article dans une revue hal-03925194v1
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3D Ruthenium Nanoparticle Covalent Assemblies from Polymantane Ligands for Confined Catalysis

Yuanyuan Min , Houssein Nasrallah , Didier Poinsot , Pierre Lecante , Yann Tison et al.

Chemistry of Materials, 2020, 32 (6), pp.2365-2378. ⟨10.1021/acs.chemmater.9b04737⟩

Article dans une revue hal-02541912v1
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When organophosphorus ruthenium complexes covalently bind to ruthenium nanoparticles to form nanoscale hybrid materials

Elena Martín Morales , Yannick Coppel , Pierre Lecante , Iker Del rosal , Romuald Poteau et al.

Chemical Communications, 2020, 56 (29), pp.4059-4062. ⟨10.1039/d0cc00442a⟩

Article dans une revue hal-02569549v1
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Rationalizing the Reactivity of Mixed Allyl Rare-Earth Borohydride Complexes with DFT Studies

Sami Fadlallah , Jashvini Jothieswaran , Iker Del rosal , Laurent Maron , Fanny Bonnet et al.

Catalysts, 2020, 10, pp.820. ⟨10.3390/catal10080820⟩

Article dans une revue hal-02926044v1
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Stepwise Construction of Silica-supported Tantalum/Iridium Heteropolymetallic Catalysts Using Surface Organometallic Chemistry

Sébastien Lassalle , Ribal Jabbour , Iker Del rosal , Laurent Maron , Emiliano Fonda et al.

Journal of Catalysis, 2020, ⟨10.1016/j.jcat.2020.10.016⟩

Article dans une revue hal-02985281v1
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DFT calculations in periodic boundary conditions of gas-phase acidities and of transition-metal anionic clusters: case study with carboxylate-stabilized ruthenium clusters

Roberto Gonzalez-Gomez , Iker Del rosal , Karine Philippot , Romuald Poteau

Theoretical Chemistry Accounts: Theory, Computation, and Modeling, 2019, 138 (8), pp.95. ⟨10.1007/s00214-019-2484-4⟩

Article dans une revue hal-02388707v1

Reductive CO 2 Homocoupling: Synthesis of a Borylated C 3 Carbohydrate

Aurélien Béthegnies , Yannick Escudié , Nelson Nuñez‐dallos , Laure Vendier , John Hurtado et al.

ChemCatChem, 2019, 11, pp.760-765. ⟨10.1002/cctc.201801875⟩

Article dans une revue hal-02330570v1
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Carboxylic acid-capped ruthenium nanoparticles: experimental and theoretical case study with ethanoic acid

Roberto Gonzalez-Gomez , Lucy Cusinato , Christian Bijani , Yannick Coppel , Pierre Lecante et al.

Nanoscale, 2019, 11 (19), pp.9392-9409. ⟨10.1039/c9nr00391f⟩

Article dans une revue hal-02131929v1

Alternative (kappa(1)-N:eta(6)-arene vs. kappa(2)-N,N) coordination of a sterically demanding amidinate ligand: are size and electronic structure of the Ln ion decisive factors?

Aleksei O. Tolpygin , Andrei S. Shavyrin , Anton V. Cherkasov , Georgy K. Fukin , Iker del Rosal et al.

Dalton Transactions, 2019, 48 (23), pp.8317-8326. ⟨10.1039/c9dt01162e⟩

Article dans une revue hal-04022178v1

Formation of an alpha-Diimine from Isocyanide Coupling Using Thorium(IV) and Uranium(IV) Phosphido-Methyl Complexes

Pokpong Rungthanaphatsophon , Iker del Rosal , Robert J. Ward , Sean P. Vilanova , Steven P. Kelley et al.

Organometallics, 2019, 38 (8), pp.1733-1740. ⟨10.1021/acs.organomet.9b00043⟩

Article dans une revue hal-04022184v1

Supported lanthanide catalysts: Role of the grafting on the stereochemical outcome of beta-butyrolactone ROP reaction

Adrien Bathellier , Chiara Dinoi , Iker del Rosal , Laurent Maron

Abstracts of Papers of the American Chemical Society, 2019, 258

Article dans une revue hal-03925218v1

Polymerization of rac ‐Lactide Using Achiral Iron Complexes: Access to Thermally Stable Stereocomplexes

Paul Marin , Mathieu J.‐l. Tschan , Florence Isnard , Carine Robert , Pierre Haquette et al.

Angewandte Chemie International Edition, 2019, 58 (36), pp.12585-12589. ⟨10.1002/anie.201903224⟩

Article dans une revue hal-03365174v1

Efficient CO2 transformation under ambient condition by heterobimetallic rare earth complexes: Experimental and computational evidences of a synergistic effect

Liye Qu , Iker del Rosal , Qingyan Li , Yaorong Wang , Dan Yuan et al.

Journal of CO2 Utilization, 2019, 33, pp.413-418. ⟨10.1016/j.jcou.2019.07.008⟩

Article dans une revue hal-04022172v1

Corrigendum: Surprising Differences of Alkane C‐H Activation Catalyzed by Ruthenium Nanoparticles: Complex Surface‐Substrate Recognition?

Niels Rothermel , Donia Bouzouita , Tobias Röther , Iker Del rosal , Simon Tricard et al.

ChemCatChem, 2019, 11 (2), pp.893-893. ⟨10.1002/cctc.201802065⟩

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Single-site cobalt and zinc catalysts for the ring-opening polymerization of lactide

Paul Marin , M.J.-L. Tschan , P. Haquette , Thierry Roisnel , Iker Del rosal et al.

European Polymer Journal, 2019, 120, pp.109208. ⟨10.1016/j.eurpolymj.2019.08.035⟩

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Grafting of a new bis-silylamido aluminum species on silica: insight from solid-state NMR into interactions with the surface

Tom Vancompernolle , Nicolas Merle , Frédéric Capet , Iker Del rosal , Laurent Maron et al.

Dalton Transactions, 2019, 48 (16), pp.5243 - 5252. ⟨10.1039/c9dt00845d⟩

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Monomeric thorium dihydrido complexes: versatile precursors to actinide metallacycles

Guorui Qin , Yang Wang , Xianghui Shi , Iker del Rosal , Laurent Maron et al.

Chemical Communications, 2019, 55 (59), pp.8560-8563. ⟨10.1039/c9cc04013g⟩

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Scandium alkyl and hydride complexes supported by a pentadentate diborate ligand: reactions with CO2 and N2O

Daniel W. Beh , Warren E. Piers , Iker del Rosal , Laurent Maron , Benjamin S. Gelfand et al.

Dalton Transactions, 2018, 47 (38), pp.13680-13688. ⟨10.1039/c8dt03313g⟩

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Mechanistic Studies on the Catalytic Synthesis of BN Heterocycles (1H-2,1-Benzazaboroles) at Ruthenium

Marion Beguerie , Chiara Dinoi , Iker Del rosal , Charly Faradji , Gilles Alcaraz et al.

ACS Catalysis, 2018, 8 (2), pp.939-948. ⟨10.1021/acscatal.7b03461⟩

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Surprising Differences of Alkane C‐H Activation Catalyzed by Ruthenium Nanoparticles: Complex Surface‐Substrate Recognition?

Niels Rothermel , Donia Bouzouita , Tobias Röther , Torsten Gutmann , Iker Del rosal et al.

ChemCatChem, 2018, 10 (19), pp.4243-4247. ⟨10.1002/cctc.201801022⟩

Article dans une revue hal-02296026v1

Functionalization of Carbon Monoxide and tert-Butyl Nitrile by Intramolecular Proton Transfer in a Bis(Phosphido) Thorium Complex

Sean P. Vilanova , Iker del Rosal , Michael L. Tarlton , Laurent Maron , Justin R. Walensky

Angewandte Chemie International Edition, 2018, 57 (51), pp.16748-16753. ⟨10.1002/anie.201810511⟩

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Side Arm Twist on Zn-Catalyzed Hydrosilylative Reduction of CO2 to Formate and Methanol Equivalents with High Selectivity and Activity

Guoqin Feng , Chongyang Du , Li Xiang , Iker del Rosal , Guangyu Li et al.

ACS Catalysis, 2018, 8 (5), pp.4710-4718. ⟨10.1021/acscatal.8b01033⟩

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Unprecedented Reaction Mode of Phosphorus in Phosphinidene Rare-Earth Complexes: A Joint Experimental-Theoretical Study

Haiwen Tian , Jianquan Hong , Kai Wang , Iker del Rosal , Laurent Maron et al.

Journal of the American Chemical Society, 2018, 140 (1), pp.102-105. ⟨10.1021/jacs.7b11032⟩

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Reversing Conventional Reactivity of Mixed Oxo/Alkyl Rare-Earth Complexes: Non-Redox Oxygen Atom Transfer

Jianquan Hong , Haiwen Tian , Lixin Zhang , Xigeng Zhou , Iker del Rosal et al.

Angewandte Chemie International Edition, 2018, 57 (4), pp.1062-1067. ⟨10.1002/anie.201711305⟩

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Silica-Grafted Lanthanum Benzyl Species: Synthesis, Characterization, and Catalytic Applications

Tom Vancompernolle , Andreia Valente , Thomas Chenal , Philippe Zinck , Iker Del rosal et al.

Organometallics, 2017, 36 (20), pp.3912 - 3920. ⟨10.1021/acs.organomet.7b00538⟩

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Shape, electronic structure and steric effects of organometallic nanocatalysts: relevant tools to improve the synergy between theory and experiment

Lucy Cusinato , Iker Del rosal , Romuald Poteau

Dalton Transactions, 2017, 46 (2), pp.378-395. ⟨10.1039/C6DT04207D⟩

Article dans une revue hal-01961183v1

Mechanistic Aspects of the Polymerization of Lactide Using a Highly Efficient Aluminum(III) Catalytic System

Carine Robert , Thibault E. Schmid , Vincent Richard , Pierre Haquette , Sumesh K. Raman et al.

Journal of the American Chemical Society, 2017, 139 (17), pp.6217--6225. ⟨10.1021/jacs.7b01749.s001⟩

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Zwitterionic amidinates as effective ligands for platinum nanoparticle hydrogenation catalysts

Luis Miguel Martinez-Pietro , Israel Cano , A. Marquez , Edwin A Baquero , Simon Tricard et al.

Chemical Science, 2017, 8 (4), pp.2931-2941. ⟨10.1039/C6SC05551F⟩

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Gold(I)-Catalysed Asymmetric Hydroamination of Alkenes: A Silver- and Solvent-Dependent Enantiodivergent Reaction

Marc-Antoine Abadie , Xavier Trivelli , Florian Medina , Nathalie Duhal , Mostafa Kouach et al.

Chemistry - A European Journal, 2017, 23 (45), pp.10777 - 10788. ⟨10.1002/chem.201701301⟩

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Silica-Supported Tungsten Neosilyl Oxo Precatalysts: Impact of the Podality on Activity and Stability in Olefin Metathesis

D. Grekov , Y. Bouhoute , K. Szeto , Nicolas Merle , A. de Mallmann et al.

Organometallics, 2016, 35 (13), pp.2188-2196. ⟨10.1021/acs.organomet.6b00220⟩

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Effects of the Grafting of Lanthanum Complexes on a Silica Surface on the Reactivity: Influence on Ethylene, Propylene, and 1,3-Butadiene Homopolymerization

Iker Del rosal , Ahmed Yahia , Laurent Maron

Inorganic Chemistry, 2016, 55 (20), pp.10024-10033

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The Nature of Secondary Interactions at Electrophilic Metal Sites of Molecular and Silica-Supported Organolutetium Complexes from Solid-State NMR Spectroscopy.

Matthew P Conley , Giuseppe Lapadula , Kevin Sanders , David Gajan , Anne Lesage et al.

Journal of the American Chemical Society, 2016, 138 (11), pp.3831-3843. ⟨10.1021/jacs.6b00071⟩

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New perspectives in organolanthanide chemistry from redox to bond metathesis: insights from theory

Christos E. Kefalidis , Ludovic Castro , Iker Del rosal , Laurent Maron , Lionel Perrin

Chemical Society Reviews, 2016, 45 (9), pp.2516-2543

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Theoretical characterization of the surface composition of ruthenium nanoparticles in equilibrium with syngas

Lucy Cusinato , Luis Miguel Martinez-Pietro , Bruno Chaudret , Iker Del rosal , Romuald Poteau

Nanoscale, 2016, 8 (21), pp.10974-10992

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17 O MAS NMR studies of oxo-based olefin metathesis catalysts: a critical assessment of signal enhancement methods

D. Grekov , Y. Bouhoute , Iker Del rosal , Laurent Maron , M. Taoufik et al.

Physical Chemistry Chemical Physics, 2016, 18 (40), pp.28157-28163. ⟨10.1039/C6CP04667C⟩

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Modification of silica-supported tungsten neosilyl oxo precatalysts: impact of substituted phenol on activity and stability in olefin metathesis

Yassine Bouhoute , Iker Del rosal , K. Szeto , Nicolas Merle , D. Grekov et al.

Catalysis Science & Technology, 2016, 6 (24), pp.8532-8539

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Grafting of lanthanide complexes on silica surfaces dehydroxylated at 200 °C: a theoretical investigation

Iker Del rosal , I.C. Gerber , Romuald Poteau , Laurent Maron

New Journal of Chemistry, 2015, 39 (10), pp.7703-7715

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DFT investigations on the ring-opening polymerization of substituted cyclic carbonates catalyzed by zinc-{β-diketiminate} complexes

Iker Del rosal , Pierre Brignou , Sophie M. Guillaume , Jean-François Carpentier , Laurent Maron

Polymer Chemistry, 2015, 6 (17), pp.3336--3352. ⟨10.1039/C5PY00313J⟩

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Enantiospecific C-H activation using ruthenium nanocatalysts

Céline Taglang , Luis Miguel Martinez-Pietro , Iker Del rosal , Laurent Maron , Romuald Poteau et al.

Angewandte Chemie International Edition, 2015, 54 (36), pp.10474-10477. ⟨10.1002/anie.201504554⟩

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Amido Analogues of Nonbent Lanthanide (II) and Calcium Metallocenes. Heterolytic Cleavage of π-Bond Ln–Carbazolyl Ligand Promoted by Lewis Base Coordination

Alexander Selikhov , Anton Cherkasov , Georgy Fukin , Alexander A. Trifonov , Iker Del rosal et al.

Organometallics, 2015, 34 (3), pp.555-562

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Accessing Realistic Models for the WO 3 –SiO 2 Industrial Catalyst through the Design of Organometallic Precursors

Y. Bouhoute , D. Grekov , K. Szeto , Nicolas Merle , A. de Mallmann et al.

ACS Catalysis, 2015, ACS Catalysis, 6 (1), pp.1-18. ⟨10.1021/acscatal.5b01744⟩

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Metallacyclic yttrium alkyl and hydrido complexes: synthesis, structures and catalytic activity in intermolecular olefin hydrophosphination and hydroamination

Alexander A. Kissel , Tatyana V. Mahrova , Dmitry M. Lyubov , Anton V. Cherkasov , Georgy K. Fukin et al.

Dalton Transactions, 2015, 44 (27), pp.12137-12148

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Yttrium Dihydride Cation [YH 2 (THF) 2 ] + n : Aggregate Formation and Reaction with (NNNN)-Type Macrocycles

Stefan Arndt , Mathias Kramer , Waldemar Fegler , Yumiko Nakajima , Iker Del rosal et al.

Organometallics, 2015, 34 (15), pp.3739-3747

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Heteronuclear NMR Spectroscopy as a Surface-Selective Technique: A Unique Look at the Hydroxyl Groups of γ-Alumina.

Mostafa Taoufik , Kai Szeto , Nicolas Merle , Iker Del rosal , Laurent Maron et al.

Chemistry - A European Journal, 2014, 20 (14), pp.4038-4046

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To Bend or Not To Bend: Experimental and Computational Studies of Structural Preference in Ln(Tp iPr 2 ) 2 (Ln = Sm, Tm)

Aurélien Momin , Lee Carter , Yi Yang , Robert Mcdonald , Stéphanie Essafi (née Labouille) et al.

Inorganic Chemistry, 2014, 53 (22), pp.12066-12075

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Well-Defined Supported Mononuclear Tungsten Oxo Species as Olefin Metathesis Pre-Catalysts

Yassine Bouhoute , Anthony Garron , Denys Grekov , Nicolas Merle , Kai Szeto et al.

ACS Catalysis, 2014, 4 (11), pp.4232-4241

Article dans une revue hal-01969421v1

PMLABe Diol Synthesized by Ring-Opening Polymerization of Racemic Benzyl β-Malolactonate Initiated by Rare-Earth Trisborohydride Complexes: An Experimental and DFT Study

Cédric C. Jaffredo , Matthias Schmid , Iker Del rosal , Teddy Mevel , Peter Roesky et al.

Chemistry - A European Journal, 2014, 20 (44), pp.14387-14402

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Speciation of [Cp*2M2O5] in Polar and Donor Solvents

Pelin Sözen-Aktaş , Iker Del rosal , Eric Manoury , Funda Demirhan , Agustí Lledós et al.

Chemistry - A European Journal, 2013, 19 (12), pp.3969-3985. ⟨10.1002/chem.201203075⟩

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Ring-opening polymerization of racemic β-butyrolactone promoted by rare earth trisborohydride complexes towards a PHB-diol: an experimental and DFT study

Sophie M. Guillaume , Liana Annunziata , Iker Del rosal , Christophe Iftner , Laurent Maron et al.

Polymer Chemistry, 2013, 4 (10), pp.3077-3087. ⟨10.1039/C3PY00056G⟩

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Small Changes Have Consequences: Lessons from Tetrabenzyltitanium and -zirconium Surface Organometallic Chemistry

Nicolas Popoff , Jeff Espinas , Jérémie Pelletier , Benoît Macqueron , Kai Szeto et al.

Chemistry - A European Journal, 2013, 19 (3), pp.964-973. ⟨10.1002/chem.201202737⟩

Article dans une revue istex hal-02043430v1
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Ligand-Field Theory-Based Analysis of the Adsorption Properties of Ruthenium Nanoparticles

Iker Del rosal , Maxime Mercy , I.C. Gerber , Romuald Poteau

ACS Nano, 2013, ⟨10.1021/nn403364p⟩

Article dans une revue hal-02366322v1

17 O NMR Gives Unprecedented Insights into the Structure of Supported Catalysts and Their Interaction with the Silica Carrier

Nicolas Merle , Julien Trébosc , Anne Baudouin , Iker Del rosal , Laurent Maron et al.

Journal of the American Chemical Society, 2012, 134 (22), pp.9263 - 9275. ⟨10.1021/ja301085m⟩

Article dans une revue hal-01702437v1

DFT investigations on the ring-opening polymerization of cyclic carbonates catalyzed by zinc-{β-diiminate} complexes

Iker Del rosal , Pierre Brignou , Sophie M. Guillaume , Jean-François Carpentier , Laurent Maron

Polymer Chemistry, 2011, 2 (11), pp.2564-2573. ⟨10.1039/C1PY00309G⟩

Article dans une revue hal-00652161v1
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Multicentered effective group potentials: ligand-field effects in organometallic clusters and dynamical study of chemical reactivity

Christophe Raynaud , Iker Del rosal , Franck Jolibois , Laurent Maron , Romuald Poteau

Theoretical Chemistry Accounts: Theory, Computation, and Modeling, 2010, 126 (3-4), pp.151-163. ⟨10.1007/s00214-009-0615-z⟩

Article dans une revue istex hal-00493604v1

Hydrido-Ruthenium Cluster Complexes as Models for Reactive Surface Hydrogen Species of Ruthenium Nanoparticles. Solid-State 2 H NMR and Quantum Chemical Calculations

Torsten Gutmann , Bernadeta Walaszek , Xu Yeping , Maria Wächtler , Iker Del rosal et al.

Journal of the American Chemical Society, 2010, 132 (33), pp.11759-11767. ⟨10.1021/ja104229a⟩

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A one-pot organometallic approach to access hybrid nanomaterials based on organophosphorous transition metal complexes covalenttly bonded to metal nanoparticles

Elena Martín Morales , Yannick Coppel , Iker Del rosal , Romuald Poteau , Pierre Sutra et al.

Polymat 2019, 10th International Conference on Polymers and Advanced Materials, Oct 2019, Huatulco, Mexico. pp.67-70

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A one-pot organometallic approach to access hybrid nanomaterials based on organophosphorus transition metal complexes covalently bonded to metal nanoparticles

Elena Martín Morales , Yannick Coppel , Iker Del rosal , Romuald Poteau , Pierre Sutra et al.

Polymat 2019 : 10th International Conference on Polymers and Advanced Materials, Oct 2019, Huatulco, Mexico. pp.67-70

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Phosphine Based Gold Catalysts for the Asymmetric Hydroamination of Alkenes: Effects of Silver, Anion and Solven

Christophe Michon , Marc O. Abadie , Fernando Torres Medina , Xavier Trivelli , Frédéric Capet et al.

28th International Conference on Organometallic Chemistry, ICOMC 2018, Jul 2018, Florence (IT), France

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Advanced Solid-State NMR as a Key Tool for the Deeper Understanding of Heterogeneous Catalysts

D. Grekov , Nicolas Merle , Kai Chung Szeto , Yassine Bouhoute , Iker Del rosal et al.

ZING conference, May 2016, Varna, Bulgaria

Communication dans un congrès hal-02309346v1

17O MAS NMR as a tool for understanding the molecular structure of supported catalysts

D. Grekov , L. Delevoye , Régis M. Gauvin , Yassine Bouhoute , Mostafa Taoufik et al.

SMARTER 5, Sep 2016, Bayreuth, Germany

Communication dans un congrès hal-02309317v1

Accessing the structure of well-defined grafted catalysts with experimental and first principles 17O Solid State NMR methodology

D. Grekov , Yassine Bouhoute , Iker Del rosal , Mostafa Taoufik , Régis M. Gauvin et al.

Journées Nord-Ouest Européennes des Jeunes Chercheurs (JNOEJC), Jun 2016, Lille, France

Communication dans un congrès hal-02309335v1

Advanced solid-state NMR as a key tool for the deeper understanding of heterogeneous catalysts

Régis M. Gauvin , L. Delevoye , Mostafa Taoufik , Iker Del rosal , Laurent Maron

Indo-French Symposium 2016 “Catalysis for Sustainable and Environmental Chemistry” – NCL, Jun 2016, Lille, France

Communication dans un congrès hal-02309342v1

Advanced Solid-State NMR as a Key Tool for the Deeper Understanding of Heterogeneous Catalysts

D. Grekov , Nicolas Merle , Kai Chung Szeto , Yassine Bouhoute , Iker Del rosal et al.

1st French-Portuguese NMR GERM Conference, Apr 2016, Lisbon, Portugal

Communication dans un congrès hal-02309343v1

Well-defined group VI oxo derivatives supported on silica by SOMC: Model of industrial olefin metathesis catalyst

Nicolas Merle , Yassine Bouhoute , Kai Chung Szeto , Aimery de Mallmann , Iker Del rosal et al.

251th ACS Meeting, Mar 2016, San Diego, United States

Communication dans un congrès hal-02333529v1

17O MAS NMR Studies of oxo-based Olefin Metathesis Catalysts: a Critical Assessment of Signal Enhancement Methods

D. Grekov , L. Delevoye , Régis M. Gauvin , Yassine Bouhoute , Mostafa Taoufik et al.

Conférence du Réseau RMN Grand Bassin Parisien, Sep 2016, Rennes, France

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17O MAS NMR as a tool for understanding the molecular structure of supported catalysts

Denys Grekov , Laurent Delevoye , Régis Gauvin , Yassine Bouhoute , Mostafa Taoufik et al.

Congrès du Groupement d’Études de Résonance Magnétique (GERM 2015), May 2015, Sète, France

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17O MAS NMR as a tool for understanding the molecular structure of supported catalysts

Denys Grekov , Laurent Delevoye , Régis Gauvin , Yassine Bouhoute , Mostafa Taoufik et al.

Congrès de la Société Chimique de France (SCF 2015), Jul 2015, Lille, France

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On the Track to Silica-Supported Tungsten Oxo Metathesis Catalysts: Input from 17O Solid-State NMR

Nicolas Merle , Guillaume Girard , Nicolas Popoff , Julien Trébosc , Iker Del rosal et al.

9th Alpine Conference, Sep 2015, Chamonix, France

Communication dans un congrès hal-02310779v1