Philipp Gotico

39
Documents

Publications

Publications

Image document

Metal-free visible-light carbonylation of alkyl iodides to amides <i>via</i> consecutive photoinduced electron transfer

Fatima Akhssas , Guillaume Chu , Meriem El Malamy , Naomi Illi , Jasmine Hertzog et al.
Chemical Science, 2026, ⟨10.1039/d5sc09778a⟩
Article dans une revue hal-05448010 v1
Image document

Hinged Carboxylate in the Artificial Distal Pocket of an Iron Porphyrin Enhances CO2 Electroreduction at Low Overpotential

Adrien Smith , Philipp Gotico , Régis Guillot, , Stéphane Le Gac , Winfried Leibl et al.
Advanced Science, 2025, pp.2500482. ⟨10.1002/advs.202500482⟩
Article dans une revue hal-04919704 v1
Image document

Iron porphyrin flanked by viologen redox units for persistent carbon dioxide reduction in the presence of oxygen

Haroon Rashid , Diana Dragoe , Atanu Rana , Serena de Beer , Philipp Gotico et al.
Chemical Science, In press, ⟨10.1039/D5SC02722E⟩
Article dans une revue hal-05354586 v1
Image document

Light-Activated Artificial CO2-Reductase: Structure and Activity

Raphaël J. Labidi , Bruno Faivre , Philippe Carpentier , Julien Pérard , Philipp Gotico et al.
Journal of the American Chemical Society, 2024, 146 (41), pp.28296-28305. ⟨10.1021/jacs.4c08927⟩
Article dans une revue hal-04735117 v1
Image document

Cobalt tetracationic 3,4‐pyridinoporphyrazine for direct CO 2 to methanol conversion escaping the CO intermediate pathway

Chanjuan Zhang , Jorge Follana-Berna , Diana Dragoe , Zakaria Halime , Philipp Gotico et al.
Angewandte Chemie International Edition, 2024, 63 (50), pp.e202411967. ⟨10.1002/anie.202411967⟩
Article dans une revue hal-05352180 v1
Image document

Second Coordination Sphere Effect Shifts CO 2 to CO Reduction by Iron Porphyrin from Fe 0 to Fe I

Sk Amanullah , Philipp Gotico , Marie Sircoglou , Winfried Leibl , Manuel Llansola-Portoles et al.
Angewandte Chemie International Edition, 2024, 63 (4), pp.e202314439. ⟨10.1002/anie.202314439⟩
Article dans une revue hal-04441669 v1
Image document

Time‐Resolved Mechanistic Depiction of Photoinduced CO 2 Reduction Catalysis on a Urea‐Modified Iron Porphyrin

Daniel H Cruz Neto , Eva Pugliese , Philipp Gotico , Annamaria Quaranta , Winfried Leibl et al.
Angewandte Chemie International Edition, 2024, 63 (32), ⟨10.1002/anie.202407723⟩
Article dans une revue hal-04735575 v1
Image document

Proton domino reactions at an imidazole relay control the oxidation of a TyrZ-His$_{190}$ artificial mimic of photosystem II

Sujitraj Sheth , Philipp Gotico , Christian Herrero , Annamaria Quaranta , Ally Aukauloo et al.
Chemistry - A European Journal, 2024, 30 (36), pp.e202400862. ⟨10.1002/chem.202400862⟩
Article dans une revue hal-05354583 v1
Image document

Visible-Light-Driven Carbon Dioxide Reduction Catalyzed by Iron Schiff-Base Complexes

Iulia Cocosila , Albert Solé-Daura , Philipp Gotico , Jérémy Forte , Yun Li et al.
ACS Catalysis, 2024, 14 (12), pp.9618-9627. ⟨10.1021/acscatal.4c01639⟩
Article dans une revue hal-05065220 v1
Image document

Photocatalytic CO2 reduction by Ni-substituted polyoxometalates: Structure-activity relationships and mechanistic insights

Khadija Talbi , Francesc Penas-Hidalgo , Amanda Robinson , Philipp Gotico , Winfried Leibl et al.
Applied Catalysis B: Environmental, 2024, 345, pp.123681. ⟨10.1016/j.apcatb.2023.123681⟩
Article dans une revue hal-04451023 v1
Image document

Tracking photoinduced charge separation in a perfluorinated Zn-tetraphenylporphyrin sensitizer

Daniel H Cruz Neto , Philipp Gotico , Thu-Trang Tran , Caroline Szantai , Zakaria Halime et al.
New Journal of Chemistry, 2024, 48 (34), pp.14896-14903. ⟨10.1039/d4nj02484b⟩
Article dans une revue hal-04735554 v1
Image document

Bio‐Inspired Bimetallic Cooperativity Through a Hydrogen Bonding Spacer in CO 2 Reduction

Chanjuan Zhang , Philipp Gotico , Regis Guillot , Diana Dragoe , Winfried Leibl et al.
Angewandte Chemie International Edition, 2023, 62 (8), ⟨10.1002/anie.202214665⟩
Article dans une revue hal-04231635 v1
Image document

Bimetallic Molecular Catalyst Design for Carbon Dioxide Reduction

Philipp Gotico , Zakaria Halime , Winfried Leibl , Ally Aukauloo
ChemPlusChem, In press, 88 (8), pp.e202300222. ⟨10.1002/cplu.202300222⟩
Article dans une revue hal-04173491 v1
Image document

Light-Driven Hydrogen Evolution Reaction Catalyzed by a Molybdenum-Copper Artificial Hydrogenase

Raphaël J Labidi , Bruno Faivre , Philippe Carpentier , Giulia Veronesi , Albert Solé- Daura et al.
Journal of the American Chemical Society, 2023, 145 (25), pp.13640-13649. ⟨10.1021/jacs.3c01350⟩
Article dans une revue hal-04128647 v1
Image document

Unlocking full and fast conversion in photocatalytic carbon dioxide reduction for applications in radio-carbonylation

Serena Monticelli , Alex Talbot , Philipp Gotico , Fabien Caillé , Olivier Loreau et al.
Nature Communications, 2023, 14 (1), pp.4451. ⟨10.1038/s41467-023-40136-w⟩
Article dans une revue hal-04231644 v1
Image document

Photocatalytic generation of a non-heme Fe(III)-hydroperoxo species with O_2 in water for oxygen atom transfer reaction

Eva Pugliese , Nhat Tam Vo , Alain Boussac , Frédéric Banse , Yasmina Mekmouche et al.
Chemical Science, 2022, 2012, ⟨10.1039/D2SC03129A⟩
Article dans une revue hal-03795563 v1
Image document

Proton-controlled Action of an Imidazole as Electron Relay in a Photoredox Triad

Philipp Gotico , Christian Herrero , Stefano Protti , Annamaria Quaranta , Sujitraj Sheth et al.
Photochemical & Photobiological Sciences , 2022, 21 (2), pp.247-259. ⟨10.1007/s43630-021-00163-2⟩
Article dans une revue hal-03865137 v1
Image document

Subtleties in Nature inspire catalyst design for carbon dioxide reduction

Philipp Gotico
L'Actualité Chimique, 2022, 476, pp.21-25
Article dans une revue hal-04173541 v1
Image document

Dissection of light-induced charge accumulation at a highly active iron porphyrin: insights in the photocatalytic CO$_2$ reduction

Eva Pugliese , Philipp Gotico , Iris Wehrung , Bernard Boitrel , Annamaria Quaranta et al.
Angewandte Chemie International Edition, 2022, 61 (14), pp.e202117530. ⟨10.1002/anie.202117530⟩
Article dans une revue hal-03594100 v1
Image document

Imbroglio at a photoredox-iron-porphyrin catalyst dyad for the photocatalytic CO 2 reduction

Adelais Trapali , Philipp Gotico , Christian Herrero , Minh-Huong Ha-Thi , Thomas Pino et al.
Comptes Rendus. Chimie, 2021, 24 (S3), pp.1-14. ⟨10.5802/crchim.104⟩
Article dans une revue hal-03423940 v1
Image document

Tracking Charge Accumulation in a Functional Triazole‐Linked Ruthenium‐Rhenium Dyad Towards Photocatalytic Carbon Dioxide Reduction

Philipp Gotico , Thu‐trang Tran , Aurelie Baron , Boris Vauzeilles , Christophe Lefumeux et al.
ChemPhotoChem, In press, ⟨10.1002/cptc.202100010⟩
Article dans une revue hal-03279658 v1
Image document

Shaping the Electrocatalytic Performance of Metal Complexes for CO2 Reduction

Philipp Gotico , Winfried A Leibl , Zakaria Halime , Ally Aukauloo
ChemElectroChem, In press, ⟨10.1002/celc.202100476⟩
Article dans une revue hal-03279622 v1
Image document

Through‐Space Electrostatic Interactions Surpass Classical Through‐Bond Electronic Effects in Enhancing CO 2 Reduction Performance of Iron Porphyrins

Asma Khadhraoui , Philipp Gotico , Winfried Leibl , Zakaria Halime , Ally Aukauloo
ChemSusChem, 2021, 14 (5), pp.1308-1315. ⟨10.1002/cssc.202002718⟩
Article dans une revue hal-03279600 v1
Image document

Cover Feature: Spectroscopic Characterisation of a Bio‐Inspired Ni‐Based Proton Reduction Catalyst Bearing a Pentadentate N 2 S 3 Ligand with Improved Photocatalytic Activity

Philipp Gotico , Dooshaye Moonshiram , Cunming Liu , Xiaoyi Zhang , Régis Guillot et al.
Chemistry - A European Journal, 2020, 26 (13), pp.2763-2763. ⟨10.1002/chem.202000227⟩
Article dans une revue hal-03279666 v1
Image document

Recent advances in metalloporphyrin-based catalyst design towards carbon dioxide reduction: from bio-inspired second coordination sphere modifications to hierarchical architectures

Philipp Gotico , Zakaria Halime , Ally Aukauloo
Dalton Transactions, 2020, ⟨10.1039/c9dt04709c⟩
Article dans une revue hal-02481325 v1
Image document

Atropisomeric Hydrogen Bonding Control for CO 2 Binding and Enhancement of Electrocatalytic Reduction at Iron Porphyrins

Philipp Gotico , Loïc Roupnel , Regis Guillot , Marie Sircoglou , Winfried Leibl et al.
Angewandte Chemie International Edition, 2020, ⟨10.1002/anie.202010859⟩
Article dans une revue hal-03016806 v1
Image document

Second-Sphere Biomimetic Multipoint Hydrogen-Bonding Patterns to Boost CO2 Reduction of Iron Porphyrins

Philipp Gotico , Bernard Boitrel , Régis Guillot , Marie Sircoglou , Annamaria Quaranta et al.
Angewandte Chemie International Edition, 2019, 58 (14), pp.4504-4509. ⟨10.1002/anie.201814339⟩
Article dans une revue hal-02050269 v1
Image document

Spectroscopic Characterization of Bio-inspired Ni-based Proton Reduction Catalyst Bearing Pentadentate N2S3 Ligand with Improved Photocatalytic Activity

Annamaria Quaranta , Winfried Leibl , Ally Aukauloo , Philipp Gotico , Dooshaye Moonshiram et al.
Chemistry - A European Journal, 2019, ⟨10.1002/chem.201904934⟩
Article dans une revue hal-02379389 v1
Image document

Visible-Light-Driven Reduction of CO2 to CO and Its Subsequent Valorization in Carbonylation Chemistry and 13C Isotope Labeling

Philipp Gotico , Antonio Vecchio , Davide Audisio , Annamaria Quaranta , Zakaria Halime et al.
ChemPhotoChem, 2018, 2 (8), pp.715-719. ⟨10.1002/cptc.201800012⟩
Article dans une revue cea-02503934 v1
Image document

Local ionic liquid environment at a modified iron porphyrin catalyst enhances the electrocatalytic performance of CO2 to CO reduction in water

Asma Khadhraoui , Philipp Gotico , Bernard Boitrel , Winfried Leibl , Zakaria Halime et al.
Chemical Communications, 2018, 54 (82), pp.11630-11633. ⟨10.1039/c8cc06475j⟩
Article dans une revue hal-01935369 v1

Mimicking Functional Features of CO Dehydrogenase Toward Improved Catalyst Design for CO2 Conversion

Philipp Gotico
The Many Facets of Photosynthesis 2025, French Society of Photosynthesis; GDR Integrative Biology of CO2 Capture; French Society of Photosynthesis, May 2025, Paris, France
Communication dans un congrès hal-05493235 v1

Deciphering Catalysis Control Through Bio-inspired Strategies

Philipp Gotico
Department Lectures, Service de Bioénergétique, Biologie Structurale et Mécanismes, Institut des Sciences du Vivant Frédéric Joliot, Feb 2025, Gif Sur Yvette, France
Communication dans un congrès hal-05493308 v1

From Nature’s Blueprints to Chemical Innovations: Harnessing Sunlight and Valorizing Carbon Dioxide

Philipp Gotico
I2BC Midday Lectures, Institut de biologie intégrative de la cellule (I2BC), Nov 2025, Gif Sur Yvette, France
Communication dans un congrès hal-05493222 v1

Leveraging CODH Enzyme Functionality for CO2 Reduction Catalyst Design

Philipp Gotico
Department Lecture Series, Ludwig Maximilian University of Munich, Nov 2025, Munich, Germany
Communication dans un congrès hal-05493297 v1
Image document

Photocatalytic reduction by molecular systems combining Porphyrins and N-Heterocyclic Carbene-Metal complexes

Asmae Bousfiha , Ludivine Poyac , Philipp Gotico , Charles Devillers , Zakaria Halime et al.
Meeting Club I2BC Transverse Axis 4, Oct 2023, Gif sur Yvette, France
Communication dans un congrès hal-04762857 v1
Image document

Combining Artificial and Bacterial Photosynthesis for CO2 Conversion

Albert Buenos , Philipp Gotico , Anja Krieger‐liszkay
9ièmes Journées Nationales des Carburants Solaires, Jul 2025, Strasbourg, France
Poster de conférence hal-05493919 v1
Image document

Development of porphyrin-based photocathodes for CO2 reduction

Sana Fatima , Philipp Gotico , Zakaria Halime
9ièmes Journées Nationales des Carburants Solaires, Jul 2025, Strasbourg, France
Poster de conférence hal-05493257 v1
Image document

Harnessing light for smarter CO2 reduction on hybrid electrodes

Abhayashri Kamath Kandel , Philipp Gotico
9ièmes Journées Nationales des Carburants Solaires, Jul 2025, Strasboug, France
Poster de conférence hal-05493182 v1