Sylvain Caillol

315
Documents
Affiliation actuelle
  • Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier (ICGM)
Identifiants chercheurs
Contact

Présentation

Current Appointments Research Director CNRS (2019-present)

Previous Appointments CNRS - Research Scientist (2007-2019) Rhodia Group - Research Scientist (2001-2005) - Head of Polymer Department (2005-2007) - Aubervilliers, Lyon, France

Education Graduate Engineer - National Graduate School of Chemistry, Montpellier, 1998 MSc - Montpellier University, 1998 PhD - Bordeaux University, 2001 Habilitation - Montpellier University, 2012

Publishing and Societies Editor-in-Chief - Green Materials, ICE Section Editor-in-Chief - Molecules, MDPI Associate Editor - Progress in Organic Coatings, Elsevier Associate Editor - Journal of the American Oil Chemist's Society, Wiley Executive Board - European Polymer Journal, Elsevier Editorial Board - Polymers, Tetraedron Green Chem, Macromol Chairman of Oleochemistry Molecule and Polymer Science Division of European Federation for the Science and Technology of Lipids Vice President of Groupe Français des Polymères

Other Appointments UM6P - Adjunct Professor - Morocco

Recent Awards Award of Innovative Techniques for Environment - 2010 Green Materials Prizes - 2018 and 2020 RSC Pioneering Investigator - 2019 World Top Scientist List, Stanford University - 2021, 2022, 2023, 2024 Carnot Prize - 2023

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Publications

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Editorial: Chemistry in 2025: Shaping the future of sustainable innovation and eco-friendly materials

Sylvain Caillol
Green materials, 2025, 13 (1), pp.1-2. ⟨10.1680/jgrma.2025.13.1.1⟩
Article dans une revue hal-04967152 v1

Thermal and thermo-oxidative accelerated aging of fluorosilicone rubber

Leticia Pires , Alice Corfa , Vincent Ladmiral , Sylvain Caillol , Mohamed Dekar et al.
Polymer Degradation and Stability, 2025, 232, pp.111150. ⟨10.1016/j.polymdegradstab.2024.111150⟩
Article dans une revue hal-04854683 v1
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TBD-catalyzed anionic ring-opening polymerization of hexamethylcyclotrisiloxane: a new route for the controlled synthesis of PDMS

Alice Corfa , Sylvain Caillol , Julien Pinaud , Vincent Ladmiral
Polymer Chemistry, 2025, 16 (5), pp.577-588. ⟨10.1039/d4py01254b⟩
Article dans une revue hal-04918080 v1
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Comparative Life Cycle Assessment of Recyclable Polyhydroxyurethanes Synthesized from Five- and Six-Membered Carbonates

Pauline Bron , Olivier Talon , Camille Bakkali-Hassani , Lourdes Irusta , Haritz Sardon et al.
Macromol, 2025, 5 (1), pp.12. ⟨10.3390/macromol5010012⟩
Article dans une revue hal-04994617 v1
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Relationship between structure and thermal stability of fluorosilicones at high temperatures

Leticia Pires , Alice Corfa , Vincent Ladmiral , Sylvain Caillol , Sébastien Roland et al.
Polymer Degradation and Stability, 2025, 238, pp.111340. ⟨10.1016/j.polymdegradstab.2025.111340⟩
Article dans une revue hal-05032827 v1
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Fast Curing of a Biobased Polyhydroxyurethane Thermoset Using Near-Infrared Photothermal Effect

Philibert Lenormand , Rania Rejeb , Patrick Lacroix-Desmazes , Sylvain Caillol , Michael Schmitt et al.
ACS Sustainable Chemistry & Engineering, 2025, 13 (11), pp.4308-4318. ⟨10.1021/acssuschemeng.4c04946⟩
Article dans une revue hal-05035752 v1
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CNSL-based plasticizers, a promising and sustainable alternative to phthalates, a review

A. Gartili , V. Lapinte , S. Caillol , B. Briou , L. Jego
RSC Sustainability, 2025, 3 (1), pp.81-111. ⟨10.1039/D4SU00282B⟩
Article dans une revue hal-04890762 v1
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Eugenol’s journey to high-performance and fire-retardant biobased thermosets

Pierre Dellière , Camille Bakkali-Hassani , Sylvain Caillol
Current opinion in green and sustainable chemistry, 2025, 51, pp.100988. ⟨10.1016/j.cogsc.2024.100988⟩
Article dans une revue hal-04845347 v1
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Collagen/polyester-polyurethane porous scaffolds for use in meniscal repair

Gaëlle Savin , Sylvain Caillol , Audrey Bethry , Eric Rondet , Michel Assor et al.
Biomaterials Science, 2024, 12 (11), pp.2960-2977. ⟨10.1039/d4bm00234b⟩
Article dans une revue hal-04591584 v1
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On Sustainability Aspects of the Synthesis of Five-Membered Cyclic Carbonates

Federico Mundo , Sylvain Caillol , Vincent Ladmiral , Michael a R Meier
ACS Sustainable Chemistry & Engineering, 2024, 12 (17), pp.6452-6466. ⟨10.1021/acssuschemeng.4c01274⟩
Article dans une revue hal-04564897 v1
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Flame-retardant performance of phosphorylated furan-containing alkyd resins

Maxinne Denis , Damien Le Borgne , Rodolphe Sonnier , Sylvain Caillol , Claire Negrell
Green materials, 2024, 12 (3), pp.168-182. ⟨10.1680/jgrma.22.00093⟩
Article dans une revue hal-04143482 v1
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Hafnium coordination vitrimer based on carboxylate exchange: synthesis, properties, and mechanistic investigations on the [Hf 6 O 4 (OH) 4 (O 2 CMe) 12 ] 2 model compound

Meenu Murali , Dimitri Berne , Jean‐claude Daran , Christian Bijani , Eric Manoury et al.
European Journal of Inorganic Chemistry, 2024, 27 (8), pp.e202300672. ⟨10.1002/ejic.202300672⟩
Article dans une revue hal-04427867 v1
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Closed-loop recyclability of a biomass-derived epoxy-amine thermoset by methanolysis

Xianyuan Wu , Peter Hartmann , Dimitri Berne , Mario de Bruyn , Florian Cuminet et al.
Science, 2024, 384 (6692), pp.156. ⟨10.1126/science.adj9989⟩
Article dans une revue hal-04543082 v1
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Sustainable polyurethanes: toward new cutting-edge opportunities

Aliénor Delavarde , Gaelle Savin , Paul Derkenne , Marine Boursier , Roberto Morales-Cerrada et al.
Progress in Polymer Science, 2024, 151, pp.101805. ⟨10.1016/j.progpolymsci.2024.101805⟩
Article dans une revue (article de synthèse) hal-04489278 v1
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Ring‐opening (co)polymerization of cardanol glycidyl ether

Emma Mongkhoun , Gholamreza Charmi , Justine Grier--Boisgontier , Fato Niang , Margot Gomes et al.
Polymers for Advanced Technologies, 2024, 35 (2), pp.e6320. ⟨10.1002/pat.6320⟩
Article dans une revue hal-04454021 v1
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Phosphorus acid: an asset for flame-retardant sustainable vitrimers

Florian Cuminet , Nathan Vanachte , Chloé Farina , Maxinne Denis , Claire Negrell et al.
Polymer Chemistry, 2024, 15 (12), pp.1212-1226. ⟨10.1039/d3py01328f⟩
Article dans une revue hal-04511242 v1
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Bio-sourced alternatives to diglycidyl ether of bisphenol A in epoxy–amine thermosets

Romain Tavernier , Mona Semsarilar , Sylvain Caillol
Green materials, 2024, 12 (3), pp.121-167. ⟨10.1680/jgrma.23.00027⟩
Article dans une revue hal-04222577 v1
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One step beyond for CNSL‐based plasticizers for PVC: Use of cardol

Adélaïde Gartili , Sylvain Caillol , Benoît Briou , Vincent Lapinte
European Journal of Lipid Science and Technology, 2024, 126 (11), pp.2400086. ⟨10.1002/ejlt.202400086⟩
Article dans une revue hal-04766470 v1

Trifluoromethylated N,S -Acetal as a Chemical Platform for Covalent Adaptable Networks: Fast Thiol Exchange and Strong Hydrostability for a Highly Transparent Material

Sidonie Laviéville , Cédric Totée , Pascale Guiffrey , Sylvain Caillol , Camille Bakkali-Hassani et al.
Macromolecules, 2024, 57 (21), pp.10311-10323. ⟨10.1021/acs.macromol.4c01359⟩
Article dans une revue hal-04800578 v1
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Evaluation of Porous (Poly(lactide-co-glycolide)-co-(ε-caprolactone)) Polyurethane for Use in Orthopedic Scaffolds

Gaëlle Savin , Océane Sastourne-Array , Sylvain Caillol , Audrey Bethry , Michel Assor et al.
Molecules, 2024, 29 (4), pp.766. ⟨10.3390/molecules29040766⟩
Article dans une revue hal-04446053 v1
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4-Vinyl Guaiacol: A Key Intermediate for Biobased Polymers

Elena Rigo , Cédric Totée , Vincent Ladmiral , Sylvain Caillol , Patrick Lacroix-Desmazes
Molecules, 2024, 29 (11), pp.2507. ⟨10.3390/molecules29112507⟩
Article dans une revue hal-04588339 v1
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Understanding associative polymer self-assembly with shrinking gate fluorescence correlation spectroscopy

Timothy J Murdoch , Baptiste Quienne , Julien Pinaud , Sylvain Caillol , Ignacio Martín-Fabiani
Nanoscale, 2024, 16 (26), pp.12660-12669. ⟨10.1039/D4NR00737A⟩
Article dans une revue hal-04636329 v1
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Controlling Hybrid Polyhydroxyurethane Adhesive and Rheological Properties by Partial Carbonation of Biobased Epoxy Monomer

Pierre Delliere , Dorian Laborie , Sylvain Caillol , Camille Bakkali‐hassani
Macromolecular Rapid Communications, 2024, 45 (23), pp.2400542. ⟨10.1002/marc.202400542⟩
Article dans une revue hal-04830937 v1
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Star poly(lactide-co-glycolide) and poly(ε-caprolactone) polyurethanes with shape memory properties for biomedical applications

Gaëlle Savin , Iliass Kadmiri , Sylvain Caillol , Philippe Gonzalez , Aurélien Lebrun et al.
European Polymer Journal, In press, 220, pp.113442. ⟨10.1016/j.eurpolymj.2024.113442⟩
Article dans une revue hal-04699510 v1
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Adhesion theories: A didactic review about a century of progress

Léo Bricotte , Kamel Chougrani , Valérie Alard , Vincent Ladmiral , Sylvain Caillol
International Journal of Adhesion and Adhesives, 2024, 132, pp.103673. ⟨10.1016/j.ijadhadh.2024.103673⟩
Article dans une revue (article de synthèse) hal-04495883 v1
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Biobased Composites from Eugenol- and Coumarin-Derived Methacrylic Latex and Hemp Nanocellulose: Cross-Linking via [2 + 2] Photocycloaddition and Barrier Properties

Sara Dalle Vacche , Samantha Molina-Gutiérrez , Giuseppe Ferraro , Vincent Ladmiral , Sylvain Caillol et al.
ACS Sustainable Chemistry & Engineering, 2024, 12 (23), pp.8741-8751. ⟨10.1021/acssuschemeng.4c01365⟩
Article dans une revue hal-04607104 v1
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Fully bio-sourced catalyst-free covalent adaptable networks from epoxidized soybean oil and L-tartaric acid

Neymara C Nepomuceno , Camille Bakkali-Hassani , Renate Wellen , Sylvain Caillol , Claire Negrell
European Polymer Journal, 2024, 212, pp.113074. ⟨10.1016/j.eurpolymj.2024.113074⟩
Article dans une revue hal-04568256 v1
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Polyols from cashew nut shell liquid (CNSL): corner-stone building blocks for cutting-edge bio-based additives and polymers

Emilie Rojtman , Maxinne Denis , Camille Sirvent , Vincent Lapinte , Sylvain Caillol et al.
Polymer Chemistry, 2024, 15 (43), pp.4375-4415. ⟨10.1039/D4PY00851K⟩
Article dans une revue hal-04768483 v1
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Polyhydroxyurethane Covalent Adaptable Networks: Looking for Suitable Catalysts

Camille Bakkali-Hassani , Dimitri Berne , Pauline Bron , Lourdes Irusta , Haritz Sardon et al.
Polymer Chemistry, 2023, 14 (31), pp.3610-3620. ⟨10.1039/d3py00579h⟩
Article dans une revue hal-04178773 v1
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Cardanol: a small giant of the future of biobased aromatic polymers and additives

Sylvain Caillol
European Polymer Journal, 2023, 193, pp.112096. ⟨10.1016/j.eurpolymj.2023.112096⟩
Article dans une revue (article de synthèse) hal-04089370 v1
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Transamidation vitrimers enabled by neighboring fluorine atom activation

Dimitri Berne , Gwendal Tanguy , Sylvain Caillol , Rinaldo Poli , Vincent Ladmiral et al.
Polymer Chemistry, 2023, 14, pp.3479. ⟨10.1039/d3py00577a⟩
Article dans une revue hal-04174700 v1
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Dihydroxyacetone: A User Guide for a Challenging Bio-Based Synthon

Léo Bricotte , Kamel Chougrani , Valérie Alard , Vincent Ladmiral , Sylvain Caillol
Molecules, 2023, 28 (6), pp.2724. ⟨10.3390/molecules28062724⟩
Article dans une revue hal-04035566 v1
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Triple Benefits of Cardanol as Chain Stopper, Flame Retardant and Reactive Diluent for Greener Alkyd Coating

Maxinne Denis , Cédric Totée , Damien Le Borgne , Rodolphe Sonnier , Sylvain Caillol et al.
Organics, 2023, 4 (1), pp.109 - 125. ⟨10.3390/org4010009⟩
Article dans une revue hal-04037375 v1
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Synthesis and characterization of original fluorinated bis-cyclic carbonates and xanthates from a fluorinated epoxide

Ali Alaaeddine , Vincent Ladmiral , Wassim El Malti , Lolwa Haydar , Sylvain Caillol et al.
Comptes Rendus. Chimie, 2023, 26 (G1), pp.19 - 28. ⟨10.5802/crchim.216⟩
Article dans une revue hal-03989242 v2
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Synthesis of a transesterification vitrimer activated by fluorine from an α,αdifluoro carboxylic acid and a diepoxy

Florian Cuminet , Sylvain Caillol , Éric Dantras , Eric Leclerc , Sébastien Lemouzy et al.
European Polymer Journal, 2023, 182, pp.111718. ⟨10.1016/j.eurpolymj.2022.111718⟩
Article dans une revue hal-03880200 v1
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Dynamic PEG-PLA/hydroxyurethane networks based on imine bonds as reprocessable elastomeric biomaterials

Mathilde Grosjean , Dimitri Berne , Sylvain Caillol , Vincent Ladmiral , Benjamin Nottelet
Biomacromolecules, 2023, 24 (8), pp.3472-3483. ⟨10.1021/acs.biomac.3c00229⟩
Article dans une revue hal-04188736 v1

Des résines alkydes hydrides aux propriétés ignifugeantes pour la formulation de revêtements

Damien Le Borgne , Maxinne Denis , Laurent Cubizolles , Rodolphe Sonnier , Sylvain Caillol et al.
L'Actualité Chimique, 2023, N° 484-485, pp.78-82
Article dans une revue hal-04233175 v1
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Understanding glycidylation reaction for the formation of pure mono, diglycidyl and dual monomers as glycidyl methacrylate of vanillyl alcohol

Sylvain Caillol , Rémi Auvergne , Abdelatif Manseri , Gilles Boutevin , Bernard Boutevin et al.
Journal of Applied Polymer Science, 2023, 140 (10), pp.e53596. ⟨10.1002/app.53596⟩
Article dans une revue hal-03975512 v1
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From natural phenols to biobased epoxy resins

Sylvain Caillol
Revue Française d'Allergologie, 2023, 63 (3), pp.103286. ⟨10.1016/j.reval.2023.103286⟩
Article dans une revue hal-03951346 v1
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From vineyards to reshapable materials: α-CF 2 activation in 100% resveratrol-based catalyst-free vitrimers

Florian Cuminet , Sébastien Lemouzy , Éric Dantras , Éric Leclerc , Vincent Ladmiral et al.
Polymer Chemistry, 2023, 14 (12), pp.1387-1395. ⟨10.1039/d3py00017f⟩
Article dans une revue hal-04041913 v1
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Photoactivable alizarin and eugenol-based materials for antibacterial applications

Christine Elian , Baptiste Quienne , Sonia Lajnef , Fabienne Peyrot , Régis Moilleron et al.
European Polymer Journal, 2023, 197, pp.112369. ⟨10.1016/j.eurpolymj.2023.112369⟩
Article dans une revue hal-04188733 v1
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Influence of Phosphorus Structures and Their Oxidation States on Flame-Retardant Properties of Polyhydroxyurethanes

Maxinne Denis , Guilhem Coste , Rodolphe Sonnier , Sylvain Caillol , Claire Negrell
Molecules, 2023, 28 (2), pp.611. ⟨10.3390/molecules28020611⟩
Article dans une revue hal-03931988 v1
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A Blooming Season for Natural Polymers and Biopolymers

Sylvain Caillol
Molecules, 2023, 28, pp.3207. ⟨10.3390/molecules28073207⟩
Article dans une revue hal-04057526 v1
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Catalyst‐Free Thia‐Michael Addition to alpha‐Trifluoromethylacrylates for 3D Network Synthesis

Dimitri Berne , Sebastien Lemouzy , Pascale Guiffrey , Sylvain Caillol , Vincent Ladmiral et al.
Chemistry - A European Journal, 2023, 29 (20), pp.e202203712. ⟨10.1002/chem.202203712⟩
Article dans une revue hal-03972802 v1
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Lignin-based Bisguaiacol diisocyanate: a green route for the synthesis of biobased polyurethanes

Sébastien Lemouzy , Aliénor Delavarde , Frédéric Lamaty , Xavier Bantreil , Julien Pinaud et al.
Green Chemistry, 2023, 25 (12), pp.4833-4839. ⟨10.1039/d3gc00704a⟩
Article dans une revue hal-04133269 v1
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Editorial: 2023 is a remarkable year for green chemistry and Green Materials

Sylvain Caillol
Green materials, 2023, 11 (1), pp.1-2. ⟨10.1680/jgrma.2023.11.1.1⟩
Article dans une revue hal-04027176 v1
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One Step Closer to Coatings Applications Utilizing Self-Stratification: Effect of Rheology Modifiers

Timothy Murdoch , Baptiste Quienne , Maialen Argaiz , Radmila Tomovska , Edgar Espinosa et al.
ACS Applied Polymer Materials, 2023, 5 (8), pp.6672-6684. ⟨10.1021/acsapm.3c01288⟩
Article dans une revue hal-04184185 v1
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Combination of Fluorine and Tertiary Amine Activation in Catalyst-Free Thia-Michael Covalent Adaptable Networks

Dimitri Berne , Rinaldo Poli , Sylvain Caillol , Vincent Ladmiral , Eric Leclerc
Macromolecules, 2023, 56 (20), pp.8260-8274. ⟨10.1021/acs.macromol.3c01129⟩
Article dans une revue hal-04232888 v1
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Recent advances in radical polymerization of bio-based monomers in aqueous dispersed media

Elena Rigo , Vincent Ladmiral , Sylvain Caillol , Patrick Lacroix-Desmazes
RSC Sustainability, 2023, 1, pp.788. ⟨10.1039/d3su00097d⟩
Article dans une revue hal-04122374 v1
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How phosphinated hydroxyurethane groups improve chemical resistance and flame retardant properties of alkyd resins?

Maxinne Denis , Alan Paré , Damien Le Borgne , Rodolphe Sonnier , Sylvain Caillol et al.
Polymer Degradation and Stability, 2023, 216, pp.110477. ⟨10.1016/j.polymdegradstab.2023.110477⟩
Article dans une revue hal-04168894 v1
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Editorial: Green materials, a growing science and industry!

Sylvain Caillol
Green materials, 2023, 11 (4), pp.145-146. ⟨10.1680/jgrma.2023.11.4.145⟩
Article dans une revue hal-04375712 v1
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Paving the Way towards Sustainability of Polyurethanes: Synthesis and Properties of Terpene-Based Diisocyanate

Aliénor Delavarde , Sebastien Lemouzy , Aurélien Lebrun , Julien Pinaud , Sylvain Caillol
Molecules, 2023, 28 (20), pp.7133. ⟨10.3390/molecules28207133⟩
Article dans une revue hal-04246489 v1
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Hydroxyurethane modifiers (HUM): an environmentally-friendly route to improve chemical resistance of alkyd coatings

Maxinne Denis , Alan Paré , Damien Le Borgne , Sylvain Caillol , Claire Negrell
Progress in Organic Coatings, 2023, 183, pp.107734. ⟨10.1016/j.porgcoat.2023.107734⟩
Article dans une revue hal-04137302 v1
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Eco-Friendly Synthesis of Cardanol-Based AB Monomer for Formaldehyde-Free Phenolic Thermosets

Benoit Briou , Lucas Jégo , Thomas de Dios Miguel , Nicolas Duguet , Sylvain Caillol
RSC Sustainability, 2023, 1 (4), pp.994-1005. ⟨10.1039/D3SU00058C⟩
Article dans une revue hal-04155005 v1
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Green synthesis of biobased soft foams by Aza-Michael reaction

Guilhem Coste , Claire Negrell , Luc Averous , Sylvain Caillol
ACS Sustainable Chemistry & Engineering, 2022, 10 (26), pp.8549-8558. ⟨10.1021/acssuschemeng.2c01885⟩
Article dans une revue hal-03712818 v1
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Upcycling biobased polyurethane foams into thermosets: toward the closing of the loop

Baptiste Quienne , Florian Cuminet , Julien Pinaud , Mona Semsarilar , Didier Cot et al.
ACS Sustainable Chemistry & Engineering, 2022, 10 (21), pp.7041-7049. ⟨10.1021/acssuschemeng.2c00950⟩
Article dans une revue hal-03681986 v1
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Valuing CO2 in the development of polymer materials

Abderrahmane Ballamine , Abdellah Kotni , Jean-Pierre Llored , Sylvain Caillol
Science and Technology for Energy Transition, 2022, 77, pp.1. ⟨10.2516/stet/2021001⟩
Article dans une revue hal-03550337 v1
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Atmospheric removal of methane by enhancing the natural hydroxyl radical sink

Yuyin Wang , Tingzhen Ming , Wei Li , Qingchun Yuan , Renaud de Richter et al.
Greenhouse Gases: Science and Technology, 2022, 12 (6), pp.784-795. ⟨10.1002/ghg.2191⟩
Article dans une revue hal-03884207 v1
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CNSL, a Promising Building Blocks for Sustainable Molecular Design of Surfactants: A Critical Review

Audrey Roy , Pauline Fajardie , Benedicte B. Lepoittevin , Jérôme Baudoux , Vincent Lapinte et al.
Molecules, 2022, 27 (4), pp.1443. ⟨10.3390/molecules27041443⟩
Article dans une revue hal-03582761 v1
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Sustainable design of vanillin-based vitrimers using vinylogous urethane chemistry

Stéphanie Engelen , Aleksandra Alicja Wróblewska , Kevin de Bruycker , Resat Aksakal , Vincent Ladmiral et al.
Polymer Chemistry, 2022, 13 (18), pp.2665-2673. ⟨10.1039/d2py00351a⟩
Article dans une revue hal-03663919 v1
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Synergistic effect of DOPO and VMDMS for flame retardancy of alkyd resins

Maxinne Denis , Damien Le Borgne , Rodolphe Sonnier , Sylvain Caillol , Claire Negrell
Progress in Organic Coatings, 2022, 172, pp.107086. ⟨10.1016/j.porgcoat.2022.107086⟩
Article dans une revue hal-03750097 v1
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Editorial: Like 200 hundred years ago, we need green chemistry and materials to push back the frontiers of science

Sylvain Caillol
Green materials, 2022, 10 (3), pp.97 - 98. ⟨10.1680/jgrma.2022.10.3.97⟩
Article dans une revue hal-03787639 v1
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Transcarbamoylation in polyurethanes: underestimated exchange reactions?

Camille Bakkali-Hassani , Dimitri Berne , Vincent Ladmiral , Sylvain Caillol
Macromolecules, 2022, 55 (18), pp.7974-7991. ⟨10.1021/acs.macromol.2c01184⟩
Article dans une revue hal-03789967 v1
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Thermal Degradation of Fluorosilicone Elastomers

Emmanuel Richaud , Leticia Pires , Sébastien Roland , Laurianne Truffault , Lucien Laiarinandrasana et al.
Macromolecular Symposia, 2022, 405 (1), pp.2100220. ⟨10.1002/masy.202100220⟩
Article dans une revue hal-03825121 v2
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Catalyst-Free Epoxy Vitrimers Based on Transesterification Internally Activated by an α–CF 3 Group

Dimitri Berne , Florian Cuminet , Sébastien Lemouzy , Christine Joly-Duhamel , Rinaldo Poli et al.
Macromolecules, 2022, 55, pp.1669-1679. ⟨10.1021/acs.macromol.1c02538⟩
Article dans une revue hal-03583794 v1
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Solvent-free synthesis of a formaldehyde-free benzoxazine monomer: study of its curing acceleration effect for commercial benzoxazine

Romain Tavernier , Lérys Granado , Monique Tillard , Louis van Renterghem , Thomas-Xavier Métro et al.
Polymer Chemistry, 2022, 13 (40), pp.5745-5756. ⟨10.1039/d2py00462c⟩
Article dans une revue hal-03819630 v1
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Catalyst-free transesterification vitrimers: activation via α-difluoroesters

Florian Cuminet , Dimitri Berne , Sébastien Lemouzy , Éric Dantras , Christine Joly-Duhamel et al.
Polymer Chemistry, 2022, 13 (18), pp.2651-2658. ⟨10.1039/d2py00124a⟩
Article dans une revue hal-03663953 v1
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Photochemical [2+2] cycloaddition of biobased latexes for composites with microfibrillated cellulose

Sara Dalle Vacche , Samantha Molina-Gutiérrez , Vincent Ladmiral , Sylvain Caillol , Roberta Bongiovanni et al.
Chemical Engineering Transactions, 2022, 92, pp.277-282. ⟨10.3303/CET2292047⟩
Article dans une revue hal-03735509 v1
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Non-isocyanate Polyurethane Foams based on Six-membered cyclic Carbonates

Guilhem Coste , Dimitri Berne , Vincent Ladmiral , Claire Negrell , Sylvain Caillol
European Polymer Journal, 2022, 176, pp.111392. ⟨10.1016/j.eurpolymj.2022.111392⟩
Article dans une revue hal-03719091 v1
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Thiol-Ene Coupling of High Oleic Sunflower Oil towards Application in the Modification of Flexible Polyurethane Foams

Sylwia Dworakowska , Adrien Cornille , Dariusz Bogdal , Bernard Boutevin , Sylvain Caillol
Materials, 2022, 15, pp.628. ⟨10.3390/ma15020628⟩
Article dans une revue hal-03526702 v1
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Coordination adaptable networks: zirconium(IV) carboxylates.

Meenu Murali , Dimitri Berne , Christine Joly-Duhamel , Sylvain Caillol , Eric Leclerc et al.
Chemistry - A European Journal, 2022, 28 (61), pp.e202202058. ⟨10.1002/chem.202202058⟩
Article dans une revue hal-03739165 v1
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Biobased catalyst-free Covalent Adaptable Networks based on CF 3activated synergistic aza-Michael exchange and transesterification

Dimitri Berne , Baptiste Quienne , Sylvain Caillol , Eric Leclerc , Vincent Ladmiral
Journal of Materials Chemistry A, 2022, 10 (47), pp.25085-25097. ⟨10.1039/d2ta05067f⟩
Article dans une revue hal-03887709 v1
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Synthesis of reactive phosphorus-based carbonate for flame retardant polyhydroxyurethane foams

Guilhem Coste , Maxinne Denis , Rodolphe Sonnier , Sylvain Caillol , Claire Negrell-Guirao
Polymer Degradation and Stability, 2022, 202, pp.110031-110202. ⟨10.1016/j.polymdegradstab.2022.110031⟩
Article dans une revue hal-03695980 v1
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Synthesis of polyester thermosets via internally catalyzed Michael-addition of methylene compounds on a 2-(trifluoromethyl)acrylate-derived building block

Dimitri Berne , Sylvain Caillol , Vincent Ladmiral , Eric Leclerc
European Polymer Journal, 2022, 175, pp.111362. ⟨10.1016/j.eurpolymj.2022.111362⟩
Article dans une revue hal-03698974 v1
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Synthesis of Hydrophobically modified ethoxylated non-isocyanate urethanes (HENIURs) and their use as rheology additives

Baptiste Quienne , Julien Pinaud , Sylvain Caillol
European Polymer Journal, 2022, 175, pp.111384. ⟨10.1016/j.eurpolymj.2022.111384⟩
Article dans une revue hal-03706671 v1
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Biobased Composites by Photoinduced Polymerization of Cardanol Methacrylate with Microfibrillated Cellulose

Alessandra Vitale , Samant Molina-Gutiérrez , W.S. Jennifer Li , Sylvain Caillol , Vincent Ladmiral et al.
Materials, 2022, Photofabrication of Biobased Polymers and Composites, 15, pp.339. ⟨10.3390/ma15010339⟩
Article dans une revue hal-03513881 v1
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Bio-sourced monomers and cationic photopolymerization–The green combination towards eco-friendly and non-toxic materials

Lucie Pierau , Christine Elian , Jun Akimoto , Yoshihiro Ito , Sylvain Caillol et al.
Progress in Polymer Science, 2022, 127, pp.101517. ⟨10.1016/j.progpolymsci.2022.101517⟩
Article dans une revue hal-03558759 v1
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Taking advantage of β-hydroxy amine enhanced reactivity and functionality for the synthesis of dual covalent adaptable networks

Dimitri Berne , Guilhem Coste , Roberto Morales-Cerrada , Marine Boursier , Julien Pinaud et al.
Polymer Chemistry, 2022, 13 (25), pp.3806. ⟨10.1039/d2py00274d⟩
Article dans une revue hal-03706971 v1
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Thia-Michael Reaction: The Route to Promising Covalent Adaptable Networks ?

Dimitri Berne , Vincent Ladmiral , Eric Leclerc , Sylvain Caillol
Polymers, 2022, 14, pp.4457. ⟨10.3390/polym14204457⟩
Article dans une revue hal-03825128 v1
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Phosphorus modified cardanol: a greener route to reduce volatile organic compounds and impart flame retardant properties to alkyd resin coatings

Maxinne Denis , Damien Le Borgne , Rodolphe Sonnier , Sylvain Caillol , Cédric Totee et al.
Molecules, 2022, 27 (15), pp.4880. ⟨10.3390/molecules27154880⟩
Article dans une revue hal-03741352 v1
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Editorial: Green chemistry and green materials evolve in a changing world

Sylvain Caillol
Green materials, 2022, 10 (2), pp.49-50. ⟨10.1680/jgrma.2022.10.2.49⟩
Article dans une revue hal-03698956 v1
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Cardanol-modified alkyd resins: novel route to make greener alkyd coatings

Maxinne Denis , Cédric Totee , Damien Le Borgne , Sylvain Caillol , Claire Negrell
Progress in Organic Coatings, 2022, 172, pp.107087. ⟨10.1016/j.porgcoat.2022.107087⟩
Article dans une revue hal-03750083 v1
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Cascade (Dithio)carbonate Ring Opening Reactions for Self‐Blowing Polyhydroxythiourethane Foams

Guilhem Coste , Claire Negrell , Sylvain Caillol
Macromolecular Rapid Communications, 2022, Sustainable Green Polymerizations, 43 (13), pp.2100833. ⟨10.1002/marc.202100833⟩
Article dans une revue hal-03715385 v1
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Synthesis of Diols from Jojoba Oil via Rhodium-Catalyzed Reductive Hydroformylation: a Smart Way to Access Biobased Polyurethanes

Chryslain Becquet , Michel Ferreira , Hervé Bricout , Baptiste Quienne , Sylvain Caillol et al.
Green Chemistry, 2022, 24 (20), pp.7906-7912. ⟨10.1039/D2GC02534E⟩
Article dans une revue hal-03820164 v1
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Perspectives on removal of atmospheric methane

Tingzhen Ming , Wei Li , Qingchun Yuan , Philip Davies , Renaud de Richter et al.
Advances in Applied Energy, 2022, 5, pp.100085. ⟨10.1016/j.adapen.2022.100085⟩
Article dans une revue hal-03544601 v1
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Understanding the reshaping of fluorinated polyester vitrimers by kinetic and DFT studies of the transesterification reaction

Sébastien Lemouzy , Florian Cuminet , Dimitri Berne , Sylvain Caillol , Vincent Ladmiral et al.
Chemistry - A European Journal, 2022, 28 (48), pp.e202201135. ⟨10.1002/chem.202201135⟩
Article dans une revue hal-03689286 v1
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Hybrid alkyds, the glowing route to reach cutting-edge properties?

Fabien Chardon , Maxinne Denis , Claire Negrell , Sylvain Caillol
Progress in Organic Coatings, 2021, 151, pp.106025. ⟨10.1016/j.porgcoat.2020.106025⟩
Article dans une revue hal-03029357 v1
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Solvent-Free Design of Biobased Non-isocyanate Polyurethanes with Ferroelectric Properties

Valentina Sessini , Cuong Nguyen Thai , Harvey Amorín , Ricardo Jiménez , Cédric Samuel et al.
ACS Sustainable Chemistry & Engineering, 2021, 9 (44), pp.14946-14958. ⟨10.1021/acssuschemeng.1c05380⟩
Article dans une revue hal-03418893 v1
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Aromatic dialdehyde-based bisbenzoxazines: The influence of relative position of oxazine rings

Romain Tavernier , Lérys Granado , Gabriel Foyer , Ghislain David , Sylvain Caillol
Polymer, 2021, 216, pp.123270. ⟨10.1016/j.polymer.2020.123270⟩
Article dans une revue hal-03139504 v1
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Eugenol, a developing asset in biobased epoxy resins

Sylvain Caillol , Bernard Boutevin , Rémi Auvergne
Polymer, 2021, 223, pp.123663. ⟨10.1016/j.polymer.2021.123663⟩
Article dans une revue hal-03187955 v1
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Les polymères biosourcés, vecteurs d’innovations et acteurs d’un développement durable

Luc Avérous , Sylvain Caillol
L'Actualité Chimique, 2021, 456-457-458, pp.95-100
Article dans une revue hal-03058563 v1
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Eugenol, a promising building block for biobased polymers with cutting-edge properties

Roberto Morales-Cerrada , Samantha Molina-Gutierrez , Patrick Lacroix-Desmazes , Sylvain Caillol
Biomacromolecules, 2021, 22 (9), pp.3625-3648. ⟨10.1021/acs.biomac.1c00837⟩
Article dans une revue hal-03343073 v1
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Biobased Latexes from Natural Oil Derivatives

Zoriana Demchuk , Anne-Sophie Mora , Sanjana Choudhary , Sylvain Caillol , Andriy Voronov
Industrial Crops and Products, 2021, 162, pp.113237. ⟨10.1016/j.indcrop.2021.113237⟩
Article dans une revue hal-03119252 v1
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Enhanced aminolysis of cyclic carbonates by β-hydroxylamines for the production of fully biobased polyhydroxyurethanes

Baptiste Quienne , Rinaldo Poli , Julien Pinaud , Sylvain Caillol
Green Chemistry, 2021, 23 (4), pp.1678-1690. ⟨10.1039/D0GC04120C⟩
Article dans une revue hal-03148901 v1
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Terpenoid-derived conjugated dienes with exo-methylene and 6membered ring: high cationic reactivity, regioselective living cationic polymerization, and random and block copolymerization with vinyl ethers

Takenori Nishida , Kotaro Satoh , Masazumi Tamura , Yingai Li , Keiichi Tomishige et al.
Polymer Chemistry, 2021, 12 (9), pp.1186-1198. ⟨10.1039/d1py00035g⟩
Article dans une revue hal-03163687 v1
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Bio-based poly(ester- alt -thioether)s synthesized by organo-catalyzed ring-opening copolymerizations of eugenol-based epoxides and N -acetyl homocysteine thiolactone

Simon Le Luyer , Baptiste Quienne , Matthieu Bouzaid , Philippe Guégan , Sylvain Caillol et al.
Green Chemistry, 2021, 23 (19), pp.7743-7750. ⟨10.1039/D1GC02138A⟩
Article dans une revue hal-03359482 v2
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Special Issue: 1 st French-Japanese Symposium: Recent Progress and Challenges in Polymer Science Editorial

Vincent Ladmiral , Sylvain Caillol
European Polymer Journal, 2021, 149, pp.110392. ⟨10.1016/j.eurpolymj.2021.110392⟩
Article dans une revue hal-03164526 v1
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Editorial Special Issue “Natural Polymers and Biopolymers II”

Sylvain Caillol
Molecules, 2021, Natural Polymers and Biopolymers II, 26, pp.112. ⟨10.3390/molecules26010112⟩
Article dans une revue hal-03090125 v1
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Fully Bio-Based Thermosetting Polyurethanes from Bio-Based Polyols and Isocyanates

Roberto Morales-Cerrada , Romain Tavernier , Sylvain Caillol
Polymers, 2021, 13 (8), pp.1255. ⟨10.3390/polym13081255⟩
Article dans une revue hal-03197000 v1
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Functionalization of Chitosan Oligomers: From Aliphatic Epoxide to Cardanol-Grafted Oligomers for Oil-in-Water Emulsions

Camille Chapelle , Ghislain David , Sylvain Caillol , Claire Negrell , Graziella Durand et al.
Biomacromolecules, 2021, 22 (2), pp.846-854. ⟨10.1021/acs.biomac.0c01576⟩
Article dans une revue hal-03134434 v1
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Surfactant properties of chemically modified chitooligosaccharides and their potential application in bitumen emulsions

Camille Chapelle , Ghislain David , Sylvain Caillol , Claire Negrell , Sylvain Catrouillet et al.
Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2021, 628, pp.127327. ⟨10.1016/j.colsurfa.2021.127327⟩
Article dans une revue hal-03325899 v1
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Diels-Alder-Chitosan based dissociative covalent adaptable networks

Camille Chapelle , Baptiste Quienne , Céline Bonneaud , Ghislain David , Sylvain Caillol
Carbohydrate Polymers, 2021, 253, pp.117222. ⟨10.1016/j.carbpol.2020.117222⟩
Article dans une revue hal-02985047 v1

A nature-based negative emissions technology able to remove atmospheric methane and other greenhouse gases

Tingzhen Ming , Renaud de Richter , Franz Dietrich Oeste , Robert Tulip , Sylvain Caillol
Atmospheric Pollution Research, 2021, 12 (5), pp.101035. ⟨10.1016/j.apr.2021.02.017⟩
Article dans une revue hal-03222327 v1
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Neighboring Group Participation and internal catalysis effects on exchangeable covalent bonds: Application to the thriving field of vitrimers chemistry

Florian Cuminet , Sylvain Caillol , Éric Dantras , Eric Leclerc , Vincent Ladmiral
Macromolecules, 2021, 54 (9), pp.3927-3961. ⟨10.1021/acs.macromol.0c02706⟩
Article dans une revue hal-03224634 v1
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Enhanced aminolysis of cyclic carbonates by β-hydroxyamines for fully biobased polyhydroxyurethanes

Baptiste Quienne , Rinaldo Poli , Julien Pinaud , Sylvain Caillol
Green Chemistry, 2021, 23 (4), pp.1678-1690. ⟨10.1039/d0gc04120c⟩
Article dans une revue hal-03155254 v1
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Advances in chitooligosaccharides chemical modifications

Camille Chapelle , Ghislain David , Sylvain Caillol , Claire Negrell , Myriam Desroches Le Foll
Biopolymers, 2021, 112 (9), pp.e23461. ⟨10.1002/bip.23461⟩
Article dans une revue hal-03354382 v1
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Phosphonated and methacrylated biobased cardanol monomer: Synthesis, characterization and application

Wing-Sze Jennifer Li , Florian Cuminet , Vincent Ladmiral , Patrick Lacroix-Desmazes , Sylvain Caillol et al.
Progress in Organic Coatings, 2021, 153, pp.106093. ⟨10.1016/j.porgcoat.2020.106093⟩
Article dans une revue hal-03133446 v1
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Improved “cure on demand” of aromatic bismaleimide with thiol triggered by retro-Diels-Alder reaction

Vincent Froidevaux , Mélanie Decostanzi , Abdelatif Manseri , Sylvain Caillol , Bernard Boutevin et al.
Frontiers of Chemical Science and Engineering, 2021, 15 (2), pp.330-339. ⟨10.1007/s11705-020-1929-6⟩
Article dans une revue hal-03166843 v1
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Glycerol carbonate methacrylate: A cross-linking agent for hydroxyurethane-acrylate coatings

Roberto Morales-Cerrada , Bernard Boutevin , Sylvain Caillol
Progress in Organic Coatings, 2021, 151, pp.106078. ⟨10.1016/j.porgcoat.2020.106078⟩
Article dans une revue hal-03079021 v1
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Hybrid polyhydroxyurethanes: How to overcome limitations and reach cutting edge properties?

Yvan Ecochard , Sylvain Caillol
European Polymer Journal, 2020, 137, pp.109915. ⟨10.1016/j.eurpolymj.2020.109915⟩
Article dans une revue hal-02926323 v1
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Formaldehyde-Free Polybenzoxazines for High Performance Thermosets

Romain Tavernier , Lérys Granado , Gabriel Foyer , Ghislain David , Sylvain Caillol
Macromolecules, 2020, 53 (7), pp.2557-2567. ⟨10.1021/acs.macromol.0c00192⟩
Article dans une revue hal-02546388 v1
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Catalysis for highly thermostable phenol-terephthalaldehyde polymer networks

Lérys Granado , Romain Tavernier , Gabriel Foyer , Ghislain David , Sylvain Caillol
Chemical Engineering Journal, 2020, 379, pp.122237-122244. ⟨10.1016/j.cej.2019.122237⟩
Article dans une revue hal-02189447 v1
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Synthesis of Alkyl Sulfur‐Functionalized Oleic Acid‐Based Polymethacrylates and Their Application as Viscosity Index Improvers in a Mineral Paraffinic Lube Oil

Juliette Lomège , Claire Negrell , Jean‐jacques Robin , Vincent Lapinte , Sylvain Caillol
Journal of the American Oil Chemists' Society, 2020, 97 (3), pp.309-318. ⟨10.1002/aocs.12316⟩
Article dans une revue hal-02500509 v1
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Isocyanate-Free Fully Biobased Star Polyester-Urethanes: Synthesis and Thermal Properties

Baptiste Quienne , Nejib Kasmi , Reiner Dieden , Sylvain Caillol , Youssef Habibi
Biomacromolecules, 2020, 21 (5), pp.1943-1951. ⟨10.1021/acs.biomac.0c00156⟩
Article dans une revue hal-02570095 v1
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A perspective approach on the amine reactivity and the hydrogen bonds effect on epoxy-amine systems

Anne-Sophie Mora , Russell Tayouo , Bernard Boutevin , Ghislain David , Sylvain Caillol
European Polymer Journal, 2020, 123, pp.109460-109473. ⟨10.1016/j.eurpolymj.2019.109460⟩
Article dans une revue hal-02439746 v1
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Vanillin derivative as performing type I photoinitiator

Louise Breloy , Claire Negrell , Anne-Sophie Mora , Wing-Sze Jennifer Li , Vlasta Brezová et al.
European Polymer Journal, 2020, 132, pp.109727. ⟨10.1016/j.eurpolymj.2020.109727⟩
Article dans une revue hal-02566165 v1
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Properties of Coated Controlled Release Diammonium Phosphate (DAP) Fertilizers Prepared with the Use of Bio‐based Amino Oil

Asma Sofyane , Mohammed Lahcini , Abdellatif El Meziane , Mehdi Khouloud , Abdelmalek Dahchour et al.
Journal of the American Oil Chemists' Society, 2020, 97 (7), pp.751-763. ⟨10.1002/aocs.12360⟩
Article dans une revue hal-02893146 v1
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Photoinduced Polymerization of Eugenol-Derived Methacrylates

Samantha Molina-Gutiérrez , Sara Dalle Vacche , Alessandra Vitale , Vincent Ladmiral , Sylvain Caillol et al.
Molecules, 2020, 25, pp.3444. ⟨10.3390/molecules25153444⟩
Article dans une revue hal-02909145 v1
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Polyurethane Thermosets Using Lipidic Poly(α‐Hydroxyketone)

Benoît Briou , Nam Duc Vu , Sylvain Caillol , Jean-Jacques Robin , Nicolas Duguet et al.
Journal of the American Oil Chemists' Society, 2020, 97 (1), pp.81-91. ⟨10.1002/aocs.12289⟩
Article dans une revue hal-02428699 v1
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Radical aqueous emulsion copolymerization of eugenol-derived monomers for adhesive applications

Samantha Molina-Gutiérrez , W. S.Jennifer Li , Renaud Perrin , Vincent Ladmiral , Roberta Bongiovanni et al.
Biomacromolecules, 2020, 21, pp.4514-4521. ⟨10.1021/acs.biomac.0c00461⟩
Article dans une revue hal-02928837 v1
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FROM GAS RELEASE TO FOAM SYNTHESIS, THE SECOND BREATH OF BLOWING AGENTS

Guilhem Coste , Claire Negrell , Sylvain Caillol
European Polymer Journal, 2020, 140, pp.110029. ⟨10.1016/j.eurpolymj.2020.110029⟩
Article dans une revue hal-02948109 v1
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From Architectures to Cutting-Edge Properties, the Blooming World of Hydrophobically Modified Ethoxylated Urethanes (HEURs)

Baptiste Quienne , Julien Pinaud , Jean-Jacques Robin , Sylvain Caillol
Macromolecules, 2020, 53 (16), pp.6754-6766. ⟨10.1021/acs.macromol.0c01353⟩
Article dans une revue hal-02924196 v1
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Non-Conventional Features of Plant Oil-Based Acrylic Monomers in Emulsion Polymerization

Ananiy Kohut , Stanislav Voronov , Zoriana Demchuk , Vasylyna Kirianchuk , Kyle Kingsley et al.
Molecules, 2020, 25 (13), pp.2990. ⟨10.3390/molecules25132990⟩
Article dans une revue hal-02885847 v1
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Dynamic network based on eugenol-derived epoxy as promising sustainable thermoset materials

Connie Ocando , Yvan Ecochard , Mélanie Decostanzi , Sylvain Caillol , Luc Avérous
European Polymer Journal, 2020, 135, pp.109860. ⟨10.1016/j.eurpolymj.2020.109860⟩
Article dans une revue hal-02897377 v1
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Linseed Oil‐Based Thermosets by Aza‐Michael Polymerization

Yvan Ecochard , Rémi Auvergne , Bernard Boutevin , Sylvain Caillol
European Journal of Lipid Science and Technology, 2020, Special Issue: Fats and Oils as Renewable Feedstock for the Chemical Industry, 122, pp.1900145-1900153. ⟨10.1002/ejlt.201900145⟩
Article dans une revue hal-02356795 v1
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One-pot two-steps synthesis of hydroxymethylated unsaturated VHOSO. Application to the synthesis of biobased polyurethanes

Kévin Cousin , Baptiste Quienne , Julien Pinaud , Sylvain Caillol , Eric Monflier et al.
European Journal of Lipid Science and Technology, 2020, 122 (12), pp.2000158. ⟨10.1002/ejlt.202000158⟩
Article dans une revue hal-03035586 v1
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Polyhydroxybutyrate/hemp biocomposite: tuning performances by process and compatibilisation

François Touchaleaume , Romain Tessier , Rémi Auvergne , Sylvain Caillol , Sandrine Hoppe et al.
Green materials, 2019, 7 (4), pp.194-204. ⟨10.1680/jgrma.19.00005⟩
Article dans une revue hal-02196923 v1
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Biobased phenol and furan derivatives coupling for the synthesis of functional monomers

Mélanie Decostanzi , Rémi Auvergne , Bernard Boutevin , Sylvain Caillol
Green Chemistry, 2019, 21 (4), pp.724-747. ⟨10.1039/C8GC03541E⟩
Article dans une revue hal-02593309 v1
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Reactive jojoba and castor oils-based cyclic carbonates for biobased polyhydroxyurethanes

Chakib Mokhtari , Fouad Malek , Abdelatif Manseri , Sylvain Caillol , Claire Negrell
European Polymer Journal, 2019, 113, pp.18-28. ⟨10.1016/j.eurpolymj.2019.01.039⟩
Article dans une revue hal-01999957 v1
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Cardanol and Eugenol Based Flame Retardant Epoxy Monomers for Thermostable Networks

Yvan Ecochard , Mélanie Decostanzi , Claire Negrell , Rodolphe Sonnier , Sylvain Caillol
Molecules, 2019, 24 (9), pp.1818. ⟨10.3390/molecules24091818⟩
Article dans une revue hal-03582138 v1
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Emulsion Polymerization of Dihydroeugenol-, Eugenol-, and Isoeugenol-Derived Methacrylates

Samantha Molina-Gutiérrez , Vincent Ladmiral , Roberta Bongiovanni , Sylvain Caillol , Patrick Lacroix-Desmazes
Industrial and engineering chemistry research, 2019, 58, pp.21155−21164. ⟨10.1021/acs.iecr.9b02338⟩
Article dans une revue hal-02343297 v1
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Fatty Acid-Based Radically Polymerizable Monomers: From Novel Poly(meth)acrylates to Cutting-Edge Properties

Juliette Lomège , Vincent Lapinte , Claire Negrell , Jean-Jacques Robin , Sylvain Caillol
Biomacromolecules, 2019, 20 (1), pp.4-26. ⟨10.1021/acs.biomac.8b01156⟩
Article dans une revue hal-01987149 v1
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Eugenol: A Promising Building Block for Synthesis of Radically Polymerizable Monomers

Samantha Molina‐gutiérrez , Abdelatif Manseri , Vincent Ladmiral , Roberta Bongiovanni , Sylvain Caillol et al.
Macromolecular Chemistry and Physics, 2019, Bioinspired and Biobased Materials, 220 (14), pp.1900179-1900188. ⟨10.1002/macp.201900179⟩
Article dans une revue hal-02189509 v1
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Epoxidized Oleic Acid‐Based Polymethacrylates as Viscosity Index Improvers

Juliette Lomège , Vincent Lapinte , Claire Negrell , Jean‐jacques Robin , Sylvain Caillol
Journal of the American Oil Chemists' Society, 2019, 96 (4), pp.467-478. ⟨10.1002/aocs.12187⟩
Article dans une revue hal-02088457 v1
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Oleic acid-based poly(alkyl methacrylate) as bio-based viscosity control additive for mineral and vegetable oils

Juliette Lomège , Claire Negrell , Jean-Jacques Robin , Vincent Lapinte , Sylvain Caillol
Polymer Engineering and Science, 2019, Films and Membranes, 59 (S1), pp.E164-E170. ⟨10.1002/pen.24896⟩
Article dans une revue hal-01971387 v1
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Non-endocrine disruptor effect for cardanol based plasticizer

Benoit Briou , Sylvain Caillol , Jean-Jacques Robin , Vincent Lapinte
Industrial Crops and Products, 2019, 130, pp.1-8. ⟨10.1016/j.indcrop.2018.12.060⟩
Article dans une revue hal-01966233 v1
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From multi-functional siloxane-based cyclic carbonates to hybrid polyhydroxyurethane thermosets

Yvan Ecochard , Jules Leroux , Bernard Boutevin , Rémi Auvergne , Sylvain Caillol
European Polymer Journal, 2019, 120, pp.109280-109289. ⟨10.1016/j.eurpolymj.2019.109280⟩
Article dans une revue hal-02356796 v1
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Synthesis of biobased reactive hydroxyl amines by amination reaction of cardanol-based epoxy monomers

Anne-Sophie Mora , Russell Tayouo , Bernard Boutevin , Ghislain David , Sylvain Caillol
European Polymer Journal, 2019, 118, pp.429-436. ⟨10.1016/j.eurpolymj.2019.06.020⟩
Article dans une revue hal-02159911 v1
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Toward Sustainable Phenolic Thermosets with High Thermal Performances

Lérys Granado , Romain Tavernier , Ségolène Henry , Ruth Oye Auke , Gabriel Foyer et al.
ACS Sustainable Chemistry & Engineering, 2019, 7 (7), pp.7209-7217. ⟨10.1021/acssuschemeng.8b06286⟩
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Synthesis of Water-Soluble Allyl-Functionalized Oligochitosan and Its Modification by Thiol-Ene Addition in Water

Nicolas Illy , Ghislain David , Mike Robitzer , Rémi Auvergne , Sylvain Caillol
Journal of polymer science. Part A-1, Polymer chemistry, 2014, 52, pp.39-48. ⟨10.1002/pola.26967⟩
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Epoxidized rosin acids as co-precursors for epoxy resins

Anne-Laure Brocas , Audrey Llevot , Christos Mantzaridis , Gabriel Cendejas Santana , Rémi Auvergne et al.
Designed Monomers and Polymers, 2014, 17 (4), pp.301-310. ⟨10.1080/15685551.2013.840504⟩
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Free radical polymerization study of glycerin carbonate methacrylate for the synthesis of cyclic carbonate functionalized polymers

Fatoumata Camara , Sylvain Caillol , Bernard Boutevin
European Polymer Journal, 2014, 61, pp.133-144. ⟨10.1016/j.eurpolymj.2014.10.001⟩
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Functionalized green tea tannins as phenolic prepolymers forbio-based epoxy resins

Sofia Benyahya , Chahinaz Aouf , Sylvain Caillol , Bernard Boutevin , Jean-Pierre Pascault et al.
Industrial Crops and Products, 2014, 53, pp.296-307. ⟨10.1016/j.indcrop.2013.12.045⟩
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Fighting globalwarmingbyclimateengineering:IstheEarthradiation managementandthesolarradiationmanagementanyoption for fighting climatechange?

Tingzhen Ming , Renaud de Richter , Wei Liu , Sylvain Caillol
Renewable and Sustainable Energy Reviews, 2014, 31, pp.792-834. ⟨10.1016/j.rser.2013.12.032⟩
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Rational investigations in the ring opening of cyclic carbonates by amines

Marine Blain , Ludivine Jean-Gerard , Rémi Auvergne , Dominique Benazet , Sylvain Caillol et al.
Green Chemistry, 2014, 16, pp.4286-4291. ⟨10.1039/C4GC01032A⟩
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Biobased Thermosetting Epoxy: Present and Future

Rémi Auvergne , Sylvain Caillol , Ghislain David , Bernard Boutevin , Jean-Pierre Pascault
Chemical Reviews, 2014, 114, pp.1082-1115. ⟨10.1021/cr3001274⟩
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From glycidyl carbonate to hydroxyurethane sidegroups in alternating fluorinated copolymers

Roukaya Hamiye , A. Alaaeddine , M. Awada , Benjamin Campagne , Sylvain Caillol et al.
Polymer Chemistry, 2014, 5 (17), pp.5089-5099. ⟨10.1039/c4py00547c⟩
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Thiol-ene coupling: An efficient tool for the synthesis of new biobased aliphatic amines for epoxy curing

Adrien Cornille , Sylvain Caillol , Vincent Froidevaux , B. Boutevin , Claire Negrell-Guirao
Polymer, 2014, 55, pp.5561-5570. ⟨10.1016/j.polymer.2014.07.004⟩
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New prospects for the synthesis of N-alkyl phosphonate/phosphonic acid-bearing oligochitosan

Nicolas Illy , Guillaume Couture , Ghislain David , Rémi Auvergne , Sylvain Caillol et al.
RSC Advances, 2014, 4, pp.24042-24052. ⟨10.1039/c4ra02501f⟩
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Reactivity of secondary amines for the synthesis of non-isocyanate polyurethanes

Fatoumata Camara , Sofia Benyahya , Vincent Besse , Gilles Boutevin , Rémi Auvergne et al.
European Polymer Journal, 2014, 55, pp.17-26. ⟨10.1016/j.eurpolymj.2014.03.011⟩
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Tuning Structure and Rheology of Silica-Latex Nanocomposites with the Molecular Weight of Matrix Chains: A Coupled SAXS-TEM-Simulation Approach

Amélie Banc , Anne-Caroline Genix , Mathieu Chirat , Christelle Dupas , Sylvain Caillol et al.
Macromolecules, 2014, 47 (9), pp.3219-3230. ⟨10.1021/ma500465n⟩
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Improvement of corrosion protection of steel by incorporation of a new phosphonated fatty acid in a phosphorus-containing polymer coating obtained by UV curing

France Millet , Rémi Auvergne , Sylvain Caillol , Ghislain David , Abdelatif Manseri et al.
Progress in Organic Coatings, 2014, vol. 77 (n° 2), pp. 285-291. ⟨10.1016/j.porgcoat.2013.10.002⟩
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Synthesis of bio-based building blocks from vegetable oils: A platform chemicals approach

Myriam Desroches , Sofia Benyahya , Vincent Besse , Rémi Auvergne , Bernard Boutevin et al.
Lipid Technology, 2014, 26, pp.35-38. ⟨10.1002/lite.201400014⟩
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Vanillin, a promising biobased building-block for monomer synthesis

Maxence Fache , Emilie Darroman , Vincent Besse , Rémi Auvergne , Sylvain Caillol et al.
Green Chemistry, 2014, 16, pp.1987-1998. ⟨10.1039/C3GC42613K⟩
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Tara tannins as phenolic precursors of thermosetting epoxy resins

Chahinaz Aouf , Sofia Benyahya , Antoine Esnouf , Sylvain Caillol , Bernard Boutevin et al.
European Polymer Journal, 2014, 55, pp.186-198. ⟨10.1016/j.eurpolymj.2014.03.034⟩
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Functionalization of cardanol: towards biobased polymers and additives

Coline Voirin , Sylvain Caillol , Nilakshi Sadavarte , Bhausaheb Tawade , Bernard Boutevin et al.
Polymer Chemistry, 2013, 5, pp.3142-3162. ⟨10.1039/c3py01194a⟩
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Access to Nonisocyanate Poly(thio)urethanes: A Comparative Study

Vincent Besse , Gabriel Foyer , Rémi Auvergne , Sylvain Caillol , Bernard Boutevin
Journal of polymer science. Part A-1, Polymer chemistry, 2013, 51, pp.3284-3296. ⟨10.1002/pola.26722⟩
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Synthesis of isosorbide based polyurethanes: An isocyanate free method

Vincent Besse , Rémi Auvergne , Stéphane Carlotti , Gilles Boutevin , Belkacem Otazaghine et al.
Reactive and Functional Polymers, 2013, 73, pp.588-594. ⟨10.1016/j.reactfunctpolym.2013.01.002⟩
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Rosin acid oligomers as precursors of DGEBA-free epoxy resins

Christos Mantzaridis , Anne-Laure Brocas , Audrey Llevot , Gabriel Cendejas , Rémi Auvergne et al.
Green Chemistry, 2013, 15 (11), pp.3091-3098. ⟨10.1039/c3gc41004h⟩
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The influence of formulation and processing parameters on the thermal properties of a chitosan-epoxy prepolymer system

Nicolas Illy , Sofia Benyahya , Nelly Durand , Rémi Auvergne , Sylvain Caillol et al.
Polymer international, 2013, pp.420-426. ⟨10.1002/pi.4516⟩
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New biobased epoxy materials from cardanol

Fanny Jaillet , Emilie Darroman , Amédée Ratsimihety , Rémi Auvergne , Bernard Boutevin et al.
European Journal of Lipid Science and Technology, 2013, 116, pp.63-73. ⟨10.1002/ejlt.201300193⟩
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Synthesis and applications of unsaturated cyclocarbonates

Vincent Besse , Fatoumata Camara , Coline Voirin , Rémi Auvergne , Sylvain Caillol et al.
Polymer Chemistry, 2013, 4, pp.4545-4561. ⟨10.1039/c3py00343d⟩
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New biobased carboxylic acid hardeners for epoxy resins

Fanny Jaillet , Myriam Desroches , Rémi Auvergne , Bernard Boutevin , Sylvain Caillol
European Journal of Lipid Science and Technology, 2013, 115, pp.698-708. ⟨10.1002/ejlt.201200363⟩
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Synthesis of new polyurethanes from vegetable oil by thiol-ene coupling

Sylvain Caillol , Myriam Desroches , Stéphane Carlotti , Rémi Auvergne , Bernard Boutevin
Green materials, 2013, 1, pp.16-26. ⟨10.1680/gmat.12.00001⟩
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Synthesis of new polyester polyols from epoxidized vegetable oils and biobased acids

Sylvain Caillol , Myriam Desroches , Gilles Boutevin , Cedric Loubat , Rémi Auvergne et al.
European Journal of Lipid Science and Technology, 2012, 114, pp.1447-1459. ⟨10.1002/ejlt.201200199⟩
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Multi-functionalization of gallic acid. Synthesis of a novel bio-based epoxy resin

Chahinaz Aouf , Hélène Nouailhas , Maxence Fache , Sylvain Caillol , Bernard Boutevin et al.
European Polymer Journal, 2012, 49 (6), pp.1185-1195. ⟨10.1016/j.eurpolymj.2012.11.025⟩
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Synthesis of bio-based building blocks from vegetable oils: a platform chemicals approach

Myriam Desroches , Rémi Auvergne , Bernard Boutevin , Sylvain Caillol
OCL Oilseeds and fats crops and lipids, 2012, pp.1-7. ⟨10.1684/ocl.2012.0489⟩
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From Vegetable Oils to Polyurethanes: Synthetic Routes to Polyols and Main Industrial Products

Myriam Desroches , Maxime Escouvois , Rémi Auvergne , Sylvain Caillol , Bernard Boutevin
Polymer Reviews, 2012, 52 (1), pp.38. ⟨10.1080/15583724.2011.640443⟩
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Study of the O-glycidylation of natural phenolic compounds. The relationship between the phenolic structure and the reaction mechanism

Chahinaz Aouf , Christine Le Guernevé , Sylvain Caillol , Hélène Fulcrand
Tetrahedron, 2012, 69 (4), pp.1345-1353. ⟨10.1016/j.tet.2012.11.079⟩
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Structure-property relationships in polyhydroxyurethanes produced from terephthaloyl dicyclocarbonate with various polyamines

Sofia Benyahya , Jean-Pierre Habas , Rémi Auvergne , Vincent Lapinte , Sylvain Caillol
Polymer international, 2012, 61, pp.1666-1674. ⟨10.1002/pi.4257⟩
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Optimization of the synthesis of polyhydroxyurethanes using dynamic rheometry

Sofia Benyahya , Bernard Boutevin , Sylvain Caillol , Vincent Lapinte , Jean-Pierre Habas
Polymer international, 2012, 61, pp.918-925. ⟨10.1002/pi.4159⟩
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Synthesis of pseudo-telechelic diols by transesterification and thiol-ene coupling

Myriam Desroches , Sylvain Caillol , Rémi Auvergne , Bernard Boutevin
European Journal of Lipid Science and Technology, 2012, 114, pp.84. ⟨10.1002/ejlt.201100132⟩
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Synthèse de polyurethane à partir d'huiles fonctionnalisées par la réaction thiol-ène

Myriam Desroches , Sylvain Caillol , Stéphane Carlotti , Rémi Auvergne , Bernard Boutevin
Matériaux et Techniques, 2012, 100 (5), pp.479-492. ⟨10.1051/mattech/2012024⟩
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New biobased epoxy hardeners: Thiol-ene addition on oligobutadiene

Rémi Auvergne , Myriam Desroches , Sébastien Clerc , Stéphane Carlotti , Sylvain Caillol et al.
Reactive and Functional Polymers, 2012, 72 (6), pp.393-401. ⟨10.1016/j.reactfunctpolym.2012.03.001⟩
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Fighting globalwarmingbyphotocatalyticreductionofCO2 using giant photocatalyticreactors

Renaud de Richter , Tingzhen Ming , Sylvain Caillol
Renewable and Sustainable Energy Reviews, 2012, 19, pp.82-106. ⟨10.1016/j.rser.2012.10.026⟩
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Synthesis of Biobased Polyols by Thiol-Ene Coupling from Vegetable Oils

Myriam Desroches , Sylvain Caillol , Vincent Lapinte , Rémi Auvergne , Bernard Boutevin
International Journal of Biological Macromolecules, 2011, 44 (8), pp.2489. ⟨10.1021/ma102884w⟩
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Synthesis of glycerin carbonate-based intermediates using thiol-ene chemistry and isocyanate free polyhydroxyurethanes therefrom

Sofia Benyahya , Myriam Desroches , Rémi Auvergne , Stéphane Carlotti , Sylvain Caillol et al.
Polymer Chemistry, 2011, 2, pp.2661-2667. ⟨10.1039/c1py00289a⟩
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Controlled synthesis of polyepichlorohydrin with pendant cyclic carbonate functions for isocyanate-free polyurethane networks

Anne-Laure Brocas , Gabriel Cendejas , Sylvain Caillol , Alain Deffieux , Stéphane Carlotti
Journal of Polymer Science Part A: Polymer Chemistry, 2011, 49 (12), pp.2677-2684. ⟨10.1002/pola.24699⟩
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A Fully Biobased Epoxy Resin from Vegetable Oils: From the Synthesis of the Precursors by Thiol-ene Reaction to the Study of the Final Material

Mylene Stemmelen , Freddy Pessel , Vincent Lapinte , Sylvain Caillol , Jean-Pierre Habas et al.
Journal of Polymer Science Part A: Polymer Chemistry, 2011, 49 (11), pp.2434. ⟨10.1002/pola.24674⟩
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Biobased cross-linked polyurethanes obtained from ester/amide pseudo-diols of fatty acid derivatives synthesized by thiol-ene coupling

Myriam Desroches , Sylvain Caillol , Rémi Auvergne , Bernard Boutevin , Ghislain David
Polymer Chemistry, 2011, 3, pp.450. ⟨10.1039/c1py00479d⟩
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Fighting global warming: The potential of photocatalysis against CO2, CH4, N2O, CFCs, tropospheric O3, BC and other major contributors to climate change

Renaud de Richter , Sylvain Caillol
Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 2011, 12, pp.1-19. ⟨10.1016/j.jphotochemrev.2011.05.002⟩
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L'écoconception : un outil d'innovation pour une chimie durable

Sylvain Caillol
Techniques de l'Ingénieur, 2011, TI J4920, p1-14
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Synthesis and Properties of Biobased Epoxy Resins. Part 1. Glycidylation of Flavonoids by Epichlorohydrin (vol 49, pg 2261, 2011)

Hélène Nouailhas , Chahinaz Aouf Aouf , Christine Le Guerneve , Sylvain Caillol , Bernard Boutevin et al.
Journal of Polymer Science Part A: Polymer Chemistry, 2011, 49 (14), pp.3239 - 3239. ⟨10.1002/pola.24764⟩
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Les résines époxy biosourcées

Sylvain Caillol
Techniques de l'Ingénieur, 2011, TI IN136, p1-11
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Synthesis and Properties of Biobased Epoxy Resins. Part 1. Glycidylation of Flavonoids by Epichlorohydrin

Hélène Nouailhas , Chahinaz Aouf , Christine Le Guernevé , Sylvain Caillol , Bernard Boutevin et al.
Journal of polymer science: Part A, General papers, 2011, 49 (10), pp.2261-2270. ⟨10.1002/pola.24659⟩
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Matériaux polymères et développement durable

Jean-Louis Halary , Luc Avérous , Marie-Elisabeth Borredon , Serge Bourbigot , Bernard Boutevin et al.
L'Actualité Chimique, 2010, 338-39, pp.41-53
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Matériaux polymères et développement durable

Jean-Louis Halary , Luc Avérous , Marie-Elisabeth Borredon , Serge Bourbigot , Bernard Boutevin et al.
L'Actualité Chimique, 2010, 338-339, pp.41-53
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Matériaux Polymères et Développement Durable

Sylvain Caillol , Jean Louis Halary , Luc Averous , M.E. Borredon , Bernard Boutevin et al.
L'Actualité Chimique, 2010, 338-39, pp.41-53
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Analyse de cycle de vie et écoconception : les clés d'une chimie nouvelle

Sylvain Caillol
Réalités industrielles. Annales des mines, 2008, novembre, pp.34-41. ⟨10.3917/rindu.084.0034⟩
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Synthesis and Self-Assembly Properties of Peptide-Polylactide Block Copolymers

Sylvain Caillol , Sébastien Lecommandoux , Anne-Françoise Mingotaud , Michèle Schappacher , Alain Soum et al.
Macromolecules, 2003, 36 (4), pp.1118-1124. ⟨10.1021/ma021187c⟩
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Compositions cosmétiques comprenant un polymère issu de la DHA, procédé d’application de ce polymère, et procédé de synthèse

Sylvain Caillol , Vincent Ladmiral , Valérie Alard , Léo Bricotte , Kamel Chougrani
France, Patent n° : FR3137580. 2024
Brevet hal-04500228 v1

Covalently grafted alkyd resin with flame retardant properties for coating applications

Sylvain Caillol , Claire Negrell , Maxinne Denis , Damien Leborgne , Olivier Fahy
France, Patent n° : EP4282898A1. 2023
Brevet hal-04500225 v1

Nouveaux agents plastifiants, leur procédé de préparation et leur utilisation,

Sylvain Caillol , Vincent Lapinte , Lucas Jégo , Benoit Briou , Adélaide Gartili
France, Patent n° : FR3134105. 2023
Brevet hal-04500210 v1

Composition de résine polyuréthane biosourcée, procédé de fabrication et application notamment à la technique du doming

Sylvain Caillol , Julien Pinaud , Aliénor Delavarde , Sylvain Maillard
France, Patent n° : WO2023/156715. 2023
Brevet hal-04500217 v1

Oligomère biosourcé issu du chitosan et son utilisation comme émulsifiant cationique ou non ionique d’émulsion aqueuse de liant bitumineux ou non bitumineux

Sylvain Caillol , Ghislain David , Claire Negrell , Myriam Desroches Le Foll , Ibrahima Faye et al.
France, Patent n° : FR3098218. 2021
Brevet hal-04497758 v1

Procédé de fabrication d’un produit réticulé

Sylvain Caillol , Ghislain David , Romain Tavernier , Lérys Granado , Gabriel Foyer
France, Patent n° : US095077. 2021
Brevet hal-04497755 v1

Procédé de fabrication d’un monomère polybenzoxazine

Sylvain Caillol , Ghislain David , Romain Tavernier , Lérys Granado , Gabriel Foyer
France, Patent n° : WO188183. 2020
Brevet hal-04497754 v1

Reactive organic product and use thereof as a cross-linking agent in self-healing coatings

Sylvain Caillol , Rémi Auvergne , Bernard Boutevin , Jérôme Mazajczyk , Gregory Delmas
France, Patent n° : WO 189461. 2018
Brevet hal-02568564 v1

Reactive organic product and use thereof as a cross-linking agent in self-healing coatings

Sylvain Caillol , Rémi Auvergne , Bernard Boutevin , Jérôme Mazajczyk , Gregory Delmas
France, Patent n° : WO 189460. 2018
Brevet hal-02568562 v1

Nouveau procede de depolymerisation du chitosan

Sylvain Caillol , Ghislain David , Claire Negrell , Gerard Mignani
France, N° de brevet: FR3059330. 2018
Brevet hal-02568558 v1

Method for producing a thruster nozzle from composite materials

Sylvain Caillol , Ghislain David , Gabriel Foyer , Dominique Francois
France, Patent n° : WO2017068294. 2017
Brevet hal-02568441 v1

Appareillage orthopédique à base de fibres naturelles et d'une résine polyépoxyde sans bisphénol A, notamment biosourcée

Sylvain Caillol , Rémi Auvergne , Bernard Boutevin , Sofia Benyahya , David Denis
France, N° de brevet: EP 3238750. 2017
Brevet hal-02568555 v1

Non-bituminous binders made from biosourced phenolic compounds and manufacturing methods

Sylvain Caillol , Vincent Besse , Myriam Desroches Le Foll
France, Patent n° : EP 3121213A1. 2017
Brevet hal-02568434 v1

Composition de revêtement d'un verre creux

Sylvain Caillol , Feifei Ng , Perrine Lavalley-Maillet
France, N° de brevet: FR3059670. 2016
Brevet hal-02889231 v1

Biosourced polymer for manufacturing, via catalytic carbonation, a non-bituminous polyhydroxyurethane binder for roadway or civil engineering-related uses

Sylvain Caillol , Ghislain David , Nicolas Illy , Vincent Besse
France, Patent n° : WO2016135404. 2016
Brevet hal-02568431 v1

Method for producing an ablative resin

Sylvain Caillol , Ghislain David , Gabriel Foyer , Nadia Rodriguez
France, Patent n° : WO2016116699A1. 2016
Brevet hal-02568429 v1

Method for producing an ablative resin

Sylvain Caillol , Ghislain David , Gabriel Foyer , Claire Negrell , Nadia Rodriguez
France, Patent n° : WO2016116697A1. 2016
Brevet hal-02568430 v1

Combination of cork / polyepoxide binder and method for manufacturing same,

Sylvain Caillol , Rémi Auvergne , Bernard Boutevin , Emilie Darroman , Christophe Loisel et al.
France, Patent n° : WO2015/107114A1. 2015
Brevet hal-02568427 v1

Combination of cork / polyepoxide binder and method for manufacturing same

Sylvain Caillol , Rémi Auvergne , Bernard Boutevin , Emilie Darroman , Christophe Loisel et al.
France, Patent n° : WO2015/107114A1. 2015
Brevet hal-02568421 v1

Combination of cork / polyhydroxyurethane binder and method for manufacturing same

Sylvain Caillol , Rémi Auvergne , Bernard Boutevin , Emilie Darroman , Christophe Loisel et al.
France, Patent n° : WO2015/107113A1. 2015
Brevet hal-02568426 v1

Nappe de fibre de laine végétale imprégnée par une huile végétale époxydée

Jean-Pierre Habas , Mylene Stemmelen , Vincent Lapinte , Sylvain Caillol , Bernard Boutevin et al.
France, N° de brevet: FR2973813. 2012
Brevet hal-00746141 v1

SHEET OF VEGETABLE WOOL FIBRE IMPREGNATED WITH AN EPOXIDISED VEGETABLE OIL

Jean-Pierre Habas , Mylene Stemmelen , Vincent Lapinte , Sylvain Caillol , Bernard Boutevin et al.
United States, Patent n° : WO2012136940. 2012
Brevet hal-00746142 v1

Procédé de fonctionnalisation de corps gras d'origine naturelle

Sylvain Caillol , Bernard Boutevin , Myriam Desroches
Patent n° : WO2012001315. 2012
Brevet hal-00726061 v1

Nouvelles résines de type phénoplastes obtenues à partir de composes phénoliques et de durcisseurs macromoléculaire portant des fonctions aldéhydes

Bernard Boutevin , Carine Burguiere , Sylvain Caillol , Ghislain David
France, N° de brevet: FR2952937. 2011, pp.11
Brevet hal-00597184 v1

Procédé de préparation d'un composant comprenant au moins un motif béta-hyroxy-uréthane et/ou au moins un motif gamma-hydroxy-uréthane

Aurelien Soules , Sylvain Caillol , Bernard Boutevin , Jean-Paul Joubert , José Martins
Patent n° : FR1159818. 2011
Brevet hal-00923709 v1

Novel method for producing thermosetting epoxy resins

Bernard Boutevin , Sylvain Caillol , Carine Burguiere , Sylvie Rapior , Helene Fulcrand et al.
France, Patent n° : WO2010136725A1, EP2435493B1, JP2015078383A. 2010
Brevet hal-04859495 v1

Procédé d'élaboration de nouvelles résines thermodurcissables à partir de composés phénoliques naturels

Sylvain Caillol , Hélène Nouailhas , Bernard Boutevin , Helene H. Fulcrand-Hoh , Sylvie Rapior et al.
France, Patent n° : FR0902589. 2009, pp.22
Brevet hal-00560347 v1

Composés phénoliques naturels et leur mode d’activation pour la formulation de résines thermodurcissables

Hélène Nouailhas , Carine Burguière , Sylvain Caillol , Bernard Boutevin , Helene Fulcrand et al.
France, Patent n° : FR2946049. 2009
Brevet hal-04859482 v1

Colloidal suspension of submicronic particles for delivering active principles and method for preparing same

Sylvain Caillol , Rémi Meyrueix , Nathan Bryson , Alain Soum , Gérard Soula et al.
Patent n° : US2007190162. 2007, pp.36
Brevet hal-00356766 v1

Non-Conventional Features of Plant Oil-Based Acrylic Monomers in Emulsion Polymerization

Ananiy Kohut , Stanislav Voronov , Zoriana Demchuk , Vasylyna Kirianchuk , Kyle Kingsley et al.
Natural Polymers and Biopolymers II, MDPI, pp.439, 2021, 978-3-0365-0405-6
Chapitre d'ouvrage hal-03123798 v1

Limonene-Based Epoxy: Anhydride Thermoset Reaction Study

Guillaume Couture , Lérys Granado , Florent Fanget , Bernard Boutevin , Sylvain Caillol
Sylvain CAILLOL. Natural Polymers and Biopolymers II, MDPI, pp.291, 2021, 978-3-0365-0405-6
Chapitre d'ouvrage hal-03124604 v1

Photoinduced Polymerization of Eugenol-Derived Methacrylates

Samantha Molina-Gutiérrez , Sara Dalle Vacche , Alessandra Vitale , Vincent Ladmiral , Sylvain Caillol et al.
Natural Polymers and Biopolymers II, MDPI, pp.67, 2021, 978-3-0365-0405-6
Chapitre d'ouvrage hal-03124601 v1

Synthesis of Pluri-Functional Amine Hardeners from Bio-Based Aromatic Aldehydes for Epoxy Amine Thermosets

Anne-Sophie Mora , Russell Tayouo , Bernard Boutevin , Ghislain David , Sylvain Caillol
Sylvain CAILLOL. Natural Polymers and Biopolymers II, MDPI, pp.255, 2021, 978-3-0365-0405-6
Chapitre d'ouvrage hal-03124602 v1

Geoengineering: Sunlight reflection methods and negative emissions technologies for greenhouse gas removal

Renaud de Richter , Sylvain Caillol , Tingzhen Ming
Managing Global Warming – An interface of technology and human issues, 2018
Chapitre d'ouvrage hal-01927409 v1

Biosourced Epoxy Resins

Sylvain Caillol , Bernard Boutevin , Jean-Pierre Pascault
Handbook of Adhesive Technology, Third Edition, 2017
Chapitre d'ouvrage hal-01857329 v1

L'analyse de cycle de vie et la chimie verte : un regard - sur des outils d'innovation pour un développement durable

Sylvain Caillol
Thierry Hamaide, Rémi Deterre, Jean-François Feller. Impact environnemental des Matières Plastiques, Hermes, pp.5, 2014, 978-2-7462-4540-2
Chapitre d'ouvrage hal-00997706 v1

Lifecycle Assessment and Green Chemistry: A Look at Innovative Tools for Sustainable Development

Sylvain Caillol
Environmental Impact of Polymers , 2014
Chapitre d'ouvrage hal-01857326 v1

L’analyse de cycle de vie et la chimie verte : un regard - sur des outils d’innovation pour un développement durable

Sylvain Caillol
Impact environnemental des Matières Plastiques, , 2014
Chapitre d'ouvrage hal-01857330 v1

Life Cycle Assessment And Ecodesign: Innovation Tools For A Sustainable And Industrial Chemistry

Sylvain Caillol
The Philosophy of Chemistry: Practices, Methodologies, and Concepts, 2013
Chapitre d'ouvrage hal-01857332 v1

Lifecycle and Ecodesign : Innovation Tools for Sustainable Industrial C

Sylvain Caillol
ISTE. Process Engineering and Industrial Management, Wiley, pp.233-274, 2012
Chapitre d'ouvrage hal-00666683 v1

L'analyse de cycle de vie et l'écoconception : outils d'innovation pour une chimie industrielle soutenable

Sylvain Caillol
Hermes. Le génie des procédés et l'entreprise, Lavoisier, pp.5746, 2011
Chapitre d'ouvrage hal-00621268 v1

Peut-on concevoir pour produire sans dégrader?

Sylvain Caillol
Les Développements Durables, Sceren, pp.72, 2011, Questions Ouvertes
Chapitre d'ouvrage hal-00586353 v1