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Sylvain Caillol

Research Director, CNRS
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**Current Appointments** **Research Director CNRS (2019-present)** **Previous Appointments** CNRS - Research Scientist (2007-2019) Rhodia Group - Research Scientist (2001-2005) - Head of Polymer Department (2005-2007) - Aubervilliers, Lyon, France **Education** Graduate Engineer - National Graduate School of Chemistry, Montpellier, 1998 MSc - Montpellier University, 1998 PhD - Bordeaux University, 2001 Habilitation - Montpellier University, 2012 **Publishing and Societies** Editor-in-Chief - Green Materials, ICE Section Editor-in-Chief - Molecules, MDPI Associate Editor - Journal of the American Oil Chemist's Society, Wiley Executive Board - European Polymer Journal, Elsevier Editorial Board - Polymers, Tetraedron Green Chem, Macromol Chairman of Oleochemistry Molecule and Polymer Science Division of European Federation for the Science and Technology of Lipids Vice President of Groupe Français des Polymères **Recent Awards** Award of Innovative Techniques for Environment - 2010 Green Materials Prizes - 2018 and 2020 RSC Pioneering Investigator - 2019 World Top Scientist List, Stanford Univ - since 2021

Publications

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Recent advances in radical polymerization of bio-based monomers in aqueous dispersed media

Elena Rigo , Vincent Ladmiral , Sylvain Caillol , Patrick Lacroix-Desmazes
RSC Sustainability, 2023, 1, pp.788. ⟨10.1039/d3su00097d⟩
Journal articles hal-04122374v1
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Editorial: 2023 is a remarkable year for green chemistry and Green Materials

Sylvain Caillol
Green materials, 2023, 11 (1), pp.1-2. ⟨10.1680/jgrma.2023.11.1.1⟩
Journal articles hal-04027176v1
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One Step Closer to Coatings Applications Utilizing Self-Stratification: Effect of Rheology Modifiers

Timothy Murdoch , Baptiste Quienne , Maialen Argaiz , Radmila Tomovska , Edgar Espinosa
ACS Applied Polymer Materials, 2023, 5 (8), pp.6672-6684. ⟨10.1021/acsapm.3c01288⟩
Journal articles hal-04184185v1
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Polyhydroxyurethane Covalent Adaptable Networks: Looking for Suitable Catalysts

Camille Bakkali-Hassani , Dimitri Berne , Pauline Bron , Lourdes Irusta , Haritz Sardon
Polymer Chemistry, 2023, 14 (31), pp.3610-3620. ⟨10.1039/d3py00579h⟩
Journal articles hal-04178773v1
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Cardanol: a small giant of the future of biobased aromatic polymers and additives

Sylvain Caillol
European Polymer Journal, 2023, 193, pp.112096. ⟨10.1016/j.eurpolymj.2023.112096⟩
Journal articles hal-04089370v1
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How phosphinated hydroxyurethane groups improve chemical resistance and flame retardant properties of alkyd resins?

Maxinne Denis , Alan Paré , Damien Le Borgne , Rodolphe Sonnier , Sylvain Caillol
Polymer Degradation and Stability, 2023, 216, pp.110477. ⟨10.1016/j.polymdegradstab.2023.110477⟩
Journal articles hal-04168894v1
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Hydroxyurethane modifiers (HUM): an environmentally-friendly route to improve chemical resistance of alkyd coatings

Maxinne Denis , Alan Paré , Damien Le Borgne , Sylvain Caillol , Claire Negrell
Progress in Organic Coatings, 2023, 183, pp.107734. ⟨10.1016/j.porgcoat.2023.107734⟩
Journal articles hal-04137302v1
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Eco-Friendly Synthesis of Cardanol-Based AB Monomer for Formaldehyde-Free Phenolic Thermosets

Benoit Briou , Lucas Jégo , Thomas de Dios Miguel , Nicolas Duguet , Sylvain Caillol
RSC Sustainability, 2023, 1 (4), pp.994-1005. ⟨10.1039/D3SU00058C⟩
Journal articles hal-04155005v1
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Transamidation vitrimers enabled by neighboring fluorine atom activation

Dimitri Berne , Gwendal Tanguy , Sylvain Caillol , Rinaldo Poli , Vincent Ladmiral
Polymer Chemistry, 2023, 14, pp.3479. ⟨10.1039/d3py00577a⟩
Journal articles hal-04174700v1
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Synthesis and characterization of original fluorinated bis-cyclic carbonates and xanthates from a fluorinated epoxide

Ali Alaaeddine , Vincent Ladmiral , Wassim El Malti , Lolwa Haydar , Sylvain Caillol
Comptes Rendus. Chimie, 2023, 26 (G1), pp.19 - 28. ⟨10.5802/crchim.216⟩
Journal articles hal-03989242v2
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Dihydroxyacetone: A User Guide for a Challenging Bio-Based Synthon

Léo Bricotte , Kamel Chougrani , Valérie Alard , Vincent Ladmiral , Sylvain Caillol
Molecules, 2023, 28 (6), pp.2724. ⟨10.3390/molecules28062724⟩
Journal articles hal-04035566v1
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Triple Benefits of Cardanol as Chain Stopper, Flame Retardant and Reactive Diluent for Greener Alkyd Coating

Maxinne Denis , Cédric Totée , Damien Le Borgne , Rodolphe Sonnier , Sylvain Caillol
Organics, 2023, 4 (1), pp.109 - 125. ⟨10.3390/org4010009⟩
Journal articles hal-04037375v1
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Synthesis of a transesterification vitrimer activated by fluorine from an α,αdifluoro carboxylic acid and a diepoxy

Florian Cuminet , Sylvain Caillol , Éric Dantras , Eric Leclerc , Sébastien Lemouzy
European Polymer Journal, 2023, 182, pp.111718. ⟨10.1016/j.eurpolymj.2022.111718⟩
Journal articles hal-03880200v1
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Lignin-based Bisguaiacol diisocyanate: a green route for the synthesis of biobased polyurethanes

Sébastien Lemouzy , Aliénor Delavarde , Frédéric Lamaty , Xavier Bantreil , Julien Pinaud
Green Chemistry, 2023, 25 (12), pp.4833-4839. ⟨10.1039/d3gc00704a⟩
Journal articles hal-04133269v1
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Catalyst‐Free Thia‐Michael Addition to alpha‐Trifluoromethylacrylates for 3D Network Synthesis

Dimitri Berne , Sebastien Lemouzy , Pascale Guiffrey , Sylvain Caillol , Vincent Ladmiral
Chemistry - A European Journal, inPress, 29 (20), pp.e202203712. ⟨10.1002/chem.202203712⟩
Journal articles hal-03972802v1
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A Blooming Season for Natural Polymers and Biopolymers

Sylvain Caillol
Molecules, 2023, 28, pp.3207. ⟨10.3390/molecules28073207⟩
Journal articles hal-04057526v1
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From natural phenols to biobased epoxy resins

Sylvain Caillol
Revue francaise d'allergologie, 2023, 63 (3), pp.103286. ⟨10.1016/j.reval.2023.103286⟩
Journal articles hal-03951346v1
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From vineyards to reshapable materials: α-CF 2 activation in 100% resveratrol-based catalyst-free vitrimers

Florian Cuminet , Sébastien Lemouzy , Éric Dantras , Éric Leclerc , Vincent Ladmiral
Polymer Chemistry, 2023, 14 (12), pp.1387-1395. ⟨10.1039/d3py00017f⟩
Journal articles hal-04041913v1
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Influence of Phosphorus Structures and Their Oxidation States on Flame-Retardant Properties of Polyhydroxyurethanes

Maxinne Denis , Guilhem Coste , Rodolphe Sonnier , Sylvain Caillol , Claire Negrell
Molecules, 2023, 28 (2), pp.611. ⟨10.3390/molecules28020611⟩
Journal articles hal-03931988v1
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Photoactivable alizarin and eugenol-based materials for antibacterial applications

Christine Elian , Baptiste Quienne , Sonia Lajnef , Fabienne Peyrot , Régis Moilleron
European Polymer Journal, 2023, 197, pp.112369. ⟨10.1016/j.eurpolymj.2023.112369⟩
Journal articles hal-04188733v1
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Understanding glycidylation reaction for the formation of pure mono, diglycidyl and dual monomers as glycidyl methacrylate of vanillyl alcohol

Sylvain Caillol , Rémi Auvergne , Abdelatif Manseri , Gilles Boutevin , Bernard Boutevin
Journal of Applied Polymer Science, 2023, 140 (10), pp.e53596. ⟨10.1002/app.53596⟩
Journal articles hal-03975512v1
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Flame-retardant performance of phosphorylated furan-containing alkyd resins

Maxinne Denis , Damien Le Borgne , Rodolphe Sonnier , Sylvain Caillol , Claire Negrell
Green materials, inPress, 11, pp.1-15. ⟨10.1680/jgrma.22.00093⟩
Journal articles hal-04143482v1
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Dynamic PEG-PLA/hydroxyurethane networks based on imine bonds as reprocessable elastomeric biomaterials

Mathilde Grosjean , Dimitri Berne , Sylvain Caillol , Vincent Ladmiral , Benjamin Nottelet
Biomacromolecules, 2023, 24 (8), pp.3472-3483. ⟨10.1021/acs.biomac.3c00229⟩
Journal articles hal-04188736v1
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Editorial: Green chemistry and green materials evolve in a changing world

Sylvain Caillol
Green materials, 2022, 10 (2), pp.49-50. ⟨10.1680/jgrma.2022.10.2.49⟩
Journal articles hal-03698956v1
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Cardanol-modified alkyd resins: novel route to make greener alkyd coatings

Maxinne Denis , Cédric Totee , Damien Le Borgne , Sylvain Caillol , Claire Negrell
Progress in Organic Coatings, 2022, 172, pp.107087. ⟨10.1016/j.porgcoat.2022.107087⟩
Journal articles hal-03750083v1
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Taking advantage of β-hydroxy amine enhanced reactivity and functionality for the synthesis of dual covalent adaptable networks

Dimitri Berne , Guilhem Coste , Roberto Morales-Cerrada , Marine Boursier , Julien Pinaud
Polymer Chemistry, 2022, 13 (25), pp.3806. ⟨10.1039/d2py00274d⟩
Journal articles hal-03706971v1
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Bio-sourced monomers and cationic photopolymerization–The green combination towards eco-friendly and non-toxic materials

Lucie Pierau , Christine Elian , Jun Akimoto , Yoshihiro Ito , Sylvain Caillol
Progress in Polymer Science, 2022, 127, pp.101517. ⟨10.1016/j.progpolymsci.2022.101517⟩
Journal articles hal-03558759v1
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Thia-Michael Reaction: The Route to Promising Covalent Adaptable Networks ?

Dimitri Berne , Vincent Ladmiral , Eric Leclerc , Sylvain Caillol
Polymers, 2022, 14, pp.4457. ⟨10.3390/polym14204457⟩
Journal articles hal-03825128v1
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Phosphorus modified cardanol: a greener route to reduce volatile organic compounds and impart flame retardant properties to alkyd resin coatings

Maxinne Denis , Damien Le Borgne , Rodolphe Sonnier , Sylvain Caillol , Cédric Totee
Molecules, 2022, 27 (15), pp.4880. ⟨10.3390/molecules27154880⟩
Journal articles hal-03741352v1
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Upcycling biobased polyurethane foams into thermosets: toward the closing of the loop

Baptiste Quienne , Florian Cuminet , Julien Pinaud , Mona Semsarilar , Didier Cot
ACS Sustainable Chemistry & Engineering, 2022, 10 (21), pp.7041-7049. ⟨10.1021/acssuschemeng.2c00950⟩
Journal articles hal-03681986v1
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Atmospheric removal of methane by enhancing the natural hydroxyl radical sink

Yuyin Wang , Tingzhen Ming , Wei Li , Qingchun Yuan , Renaud de Richter
Greenhouse Gases: Science and Technology, 2022, 12 (6), pp.784-795. ⟨10.1002/ghg.2191⟩
Journal articles hal-03884207v1
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Valuing CO2 in the development of polymer materials

Abderrahmane Ballamine , Abdellah Kotni , Jean-Pierre Llored , Sylvain Caillol
Science and Technology for Energy Transition, 2022, 77, pp.1. ⟨10.2516/stet/2021001⟩
Journal articles hal-03550337v1
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Green synthesis of biobased soft foams by Aza-Michael reaction

Guilhem Coste , Claire Negrell , Luc Averous , Sylvain Caillol
ACS Sustainable Chemistry & Engineering, 2022, 10 (26), pp.8549-8558. ⟨10.1021/acssuschemeng.2c01885⟩
Journal articles hal-03712818v1
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Cascade (Dithio)carbonate Ring Opening Reactions for Self‐Blowing Polyhydroxythiourethane Foams

Guilhem Coste , Claire Negrell , Sylvain Caillol
Macromolecular Rapid Communications, 2022, Sustainable Green Polymerizations, 43 (13), pp.2100833. ⟨10.1002/marc.202100833⟩
Journal articles hal-03715385v1
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Understanding the reshaping of fluorinated polyester vitrimers by kinetic and DFT studies of the transesterification reaction

Sébastien Lemouzy , Florian Cuminet , Dimitri Berne , Sylvain Caillol , Vincent Ladmiral
Chemistry - A European Journal, 2022, 28 (48), pp.e202201135. ⟨10.1002/chem.202201135⟩
Journal articles hal-03689286v1
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Perspectives on removal of atmospheric methane

Tingzhen Ming , Wei Li , Qingchun Yuan , Philip Davies , Renaud de Richter
Advances in Applied Energy, 2022, 5, pp.100085. ⟨10.1016/j.adapen.2022.100085⟩
Journal articles hal-03544601v1
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Synthesis of Diols from Jojoba Oil via Rhodium-Catalyzed Reductive Hydroformylation: a Smart Way to Access Biobased Polyurethanes

Chryslain Becquet , Michel Ferreira , Hervé Bricout , Baptiste Quienne , Sylvain Caillol
Green Chemistry, 2022, 24 (20), pp.7906-7912. ⟨10.1039/D2GC02534E⟩
Journal articles hal-03820164v1
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CNSL, a Promising Building Blocks for Sustainable Molecular Design of Surfactants: A Critical Review

Audrey Roy , Pauline Fajardie , Benedicte B. Lepoittevin , Jérôme Baudoux , Vincent Lapinte
Molecules, 2022, 27 (4), pp.1443. ⟨10.3390/molecules27041443⟩
Journal articles hal-03582761v1
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Biobased Composites by Photoinduced Polymerization of Cardanol Methacrylate with Microfibrillated Cellulose

Alessandra Vitale , Samant Molina-Gutiérrez , W.S. Jennifer Li , Sylvain Caillol , Vincent Ladmiral
Materials, 2022, Photofabrication of Biobased Polymers and Composites, 15, pp.339. ⟨10.3390/ma15010339⟩
Journal articles hal-03513881v1
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Synthesis of Hydrophobically modified ethoxylated non-isocyanate urethanes (HENIURs) and their use as rheology additives

Baptiste Quienne , Julien Pinaud , Sylvain Caillol
European Polymer Journal, 2022, 175, pp.111384. ⟨10.1016/j.eurpolymj.2022.111384⟩
Journal articles hal-03706671v1
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Biobased catalyst-free Covalent Adaptable Networks based on CF 3activated synergistic aza-Michael exchange and transesterification

Dimitri Berne , Baptiste Quienne , Sylvain Caillol , Eric Leclerc , Vincent Ladmiral
Journal of Materials Chemistry A, 2022, 10 (47), pp.25085-25097. ⟨10.1039/d2ta05067f⟩
Journal articles hal-03887709v1
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Synthesis of reactive phosphorus-based carbonate for flame retardant polyhydroxyurethane foams

Guilhem Coste , Maxinne Denis , Rodolphe Sonnier , Sylvain Caillol , Claire Negrell-Guirao
Polymer Degradation and Stability, 2022, 202, pp.110031-110202. ⟨10.1016/j.polymdegradstab.2022.110031⟩
Journal articles hal-03695980v1
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Synthesis of polyester thermosets via internally catalyzed Michael-addition of methylene compounds on a 2-(trifluoromethyl)acrylate-derived building block

Dimitri Berne , Sylvain Caillol , Vincent Ladmiral , Eric Leclerc
European Polymer Journal, 2022, 175, pp.111362. ⟨10.1016/j.eurpolymj.2022.111362⟩
Journal articles hal-03698974v1
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Photochemical [2+2] cycloaddition of biobased latexes for composites with microfibrillated cellulose

Sara Dalle Vacche , Samantha Molina-Gutiérrez , Vincent Ladmiral , Sylvain Caillol , Roberta Bongiovanni
Chemical Engineering Transactions, 2022, 92, pp.277-282. ⟨10.3303/CET2292047⟩
Journal articles hal-03735509v1
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Coordination adaptable networks: zirconium(IV) carboxylates.

Meenu Murali , Dimitri Berne , Christine Joly-Duhamel , Sylvain Caillol , Eric Leclerc
Chemistry - A European Journal, 2022, 28 (61), pp.e202202058. ⟨10.1002/chem.202202058⟩
Journal articles hal-03739165v1
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Catalyst-free transesterification vitrimers: activation via α-difluoroesters

Florian Cuminet , Dimitri Berne , Sébastien Lemouzy , Éric Dantras , Christine Joly-Duhamel
Polymer Chemistry, 2022, 13 (18), pp.2651-2658. ⟨10.1039/d2py00124a⟩
Journal articles hal-03663953v1
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Thiol-Ene Coupling of High Oleic Sunflower Oil towards Application in the Modification of Flexible Polyurethane Foams

Sylwia Dworakowska , Adrien Cornille , Dariusz Bogdal , Bernard Boutevin , Sylvain Caillol
Materials, 2022, 15, pp.628. ⟨10.3390/ma15020628⟩
Journal articles hal-03526702v1
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Non-isocyanate Polyurethane Foams based on Six-membered cyclic Carbonates

Guilhem Coste , Dimitri Berne , Vincent Ladmiral , Claire Negrell , Sylvain Caillol
European Polymer Journal, 2022, 176, pp.111392. ⟨10.1016/j.eurpolymj.2022.111392⟩
Journal articles hal-03719091v1
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Editorial: Like 200 hundred years ago, we need green chemistry and materials to push back the frontiers of science

Sylvain Caillol
Green materials, 2022, 10 (3), pp.97 - 98. ⟨10.1680/jgrma.2022.10.3.97⟩
Journal articles hal-03787639v1
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Transcarbamoylation in polyurethanes: underestimated exchange reactions?

Camille Bakkali-Hassani , Dimitri Berne , Vincent Ladmiral , Sylvain Caillol
Macromolecules, 2022, 55 (18), pp.7974-7991. ⟨10.1021/acs.macromol.2c01184⟩
Journal articles hal-03789967v1
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Thermal Degradation of Fluorosilicone Elastomers

Emmanuel Richaud , Leticia Pires , Sébastien Roland , Laurianne Truffault , Lucien Laiarinandrasana
Macromolecular Symposia, 2022, 405 (1), pp.2100220. ⟨10.1002/masy.202100220⟩
Journal articles hal-03825121v2
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Sustainable design of vanillin-based vitrimers using vinylogous urethane chemistry

Stéphanie Engelen , Aleksandra Alicja Wróblewska , Kevin de Bruycker , Resat Aksakal , Vincent Ladmiral
Polymer Chemistry, 2022, 13 (18), pp.2665-2673. ⟨10.1039/d2py00351a⟩
Journal articles hal-03663919v1
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Synergistic effect of DOPO and VMDMS for flame retardancy of alkyd resins

Maxinne Denis , Damien Le Borgne , Rodolphe Sonnier , Sylvain Caillol , Claire Negrell
Progress in Organic Coatings, 2022, 172, pp.107086. ⟨10.1016/j.porgcoat.2022.107086⟩
Journal articles hal-03750097v1
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Catalyst-Free Epoxy Vitrimers Based on Transesterification Internally Activated by an α–CF 3 Group

Dimitri Berne , Florian Cuminet , Sébastien Lemouzy , Christine Joly-Duhamel , Rinaldo Poli
Macromolecules, 2022, 55, pp.1669-1679. ⟨10.1021/acs.macromol.1c02538⟩
Journal articles hal-03583794v1
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Solvent-free synthesis of a formaldehyde-free benzoxazine monomer: study of its curing acceleration effect for commercial benzoxazine

Romain Tavernier , Lérys Granado , Monique Tillard , Louis van Renterghem , Thomas-Xavier Métro
Polymer Chemistry, 2022, 13 (40), pp.5745-5756. ⟨10.1039/d2py00462c⟩
Journal articles hal-03819630v1
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Fully Bio-Based Thermosetting Polyurethanes from Bio-Based Polyols and Isocyanates

Roberto Morales-Cerrada , Romain Tavernier , Sylvain Caillol
Polymers, 2021, 13 (8), pp.1255. ⟨10.3390/polym13081255⟩
Journal articles hal-03197000v1
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Surfactant properties of chemically modified chitooligosaccharides and their potential application in bitumen emulsions

Camille Chapelle , Ghislain David , Sylvain Caillol , Claire Negrell , Sylvain Catrouillet
Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2021, 628, pp.127327. ⟨10.1016/j.colsurfa.2021.127327⟩
Journal articles hal-03325899v1
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Diels-Alder-Chitosan based dissociative covalent adaptable networks

Camille Chapelle , Baptiste Quienne , Céline Bonneaud , Ghislain David , Sylvain Caillol
Carbohydrate Polymers, 2021, 253, pp.117222. ⟨10.1016/j.carbpol.2020.117222⟩
Journal articles hal-02985047v1
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Neighboring Group Participation and internal catalysis effects on exchangeable covalent bonds: Application to the thriving field of vitrimers chemistry

Florian Cuminet , Sylvain Caillol , Éric Dantras , Eric Leclerc , Vincent Ladmiral
Macromolecules, 2021, 54 (9), pp.3927-3961. ⟨10.1021/acs.macromol.0c02706⟩
Journal articles hal-03224634v1

A nature-based negative emissions technology able to remove atmospheric methane and other greenhouse gases

Tingzhen Ming , Renaud de Richter , Franz Dietrich Oeste , Robert Tulip , Sylvain Caillol
Atmospheric Pollution Research, 2021, 12 (5), pp.101035. ⟨10.1016/j.apr.2021.02.017⟩
Journal articles hal-03222327v1
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Enhanced aminolysis of cyclic carbonates by β-hydroxyamines for fully biobased polyhydroxyurethanes

Baptiste Quienne , Rinaldo Poli , Julien Pinaud , Sylvain Caillol
Green Chemistry, 2021, 23 (4), pp.1678-1690. ⟨10.1039/d0gc04120c⟩
Journal articles hal-03155254v1
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Functionalization of Chitosan Oligomers: From Aliphatic Epoxide to Cardanol-Grafted Oligomers for Oil-in-Water Emulsions

Camille Chapelle , Ghislain David , Sylvain Caillol , Claire Negrell , Graziella Durand
Biomacromolecules, 2021, 22 (2), pp.846-854. ⟨10.1021/acs.biomac.0c01576⟩
Journal articles hal-03134434v1
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Hybrid alkyds, the glowing route to reach cutting-edge properties?

Fabien Chardon , Maxinne Denis , Claire Negrell , Sylvain Caillol
Progress in Organic Coatings, 2021, 151, pp.106025. ⟨10.1016/j.porgcoat.2020.106025⟩
Journal articles hal-03029357v1
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Aromatic dialdehyde-based bisbenzoxazines: The influence of relative position of oxazine rings

Romain Tavernier , Lérys Granado , Gabriel Foyer , Ghislain David , Sylvain Caillol
Polymer, 2021, 216, pp.123270. ⟨10.1016/j.polymer.2020.123270⟩
Journal articles hal-03139504v1
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Solvent-Free Design of Biobased Non-isocyanate Polyurethanes with Ferroelectric Properties

Valentina Sessini , Cuong Nguyen Thai , Harvey Amorín , Ricardo Jiménez , Cédric Samuel
ACS Sustainable Chemistry & Engineering, 2021, 9 (44), pp.14946-14958. ⟨10.1021/acssuschemeng.1c05380⟩
Journal articles hal-03418893v1
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Advances in chitooligosaccharides chemical modifications

Camille Chapelle , Ghislain David , Sylvain Caillol , Claire Negrell , Myriam Desroches Le Foll
Biopolymers, 2021, 112 (9), pp.e23461. ⟨10.1002/bip.23461⟩
Journal articles hal-03354382v1
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Phosphonated and methacrylated biobased cardanol monomer: Synthesis, characterization and application

Wing-Sze Jennifer Li , Florian Cuminet , Vincent Ladmiral , Patrick Lacroix-Desmazes , Sylvain Caillol
Progress in Organic Coatings, 2021, 153, pp.106093. ⟨10.1016/j.porgcoat.2020.106093⟩
Journal articles hal-03133446v1
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Glycerol carbonate methacrylate: A cross-linking agent for hydroxyurethane-acrylate coatings

Roberto Morales-Cerrada , Bernard Boutevin , Sylvain Caillol
Progress in Organic Coatings, 2021, 151, pp.106078. ⟨10.1016/j.porgcoat.2020.106078⟩
Journal articles hal-03079021v1
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Improved “cure on demand” of aromatic bismaleimide with thiol triggered by retro-Diels-Alder reaction

Vincent Froidevaux , Mélanie Decostanzi , Abdelatif Manseri , Sylvain Caillol , Bernard Boutevin
Frontiers of Chemical Science and Engineering, 2021, 15 (2), pp.330-339. ⟨10.1007/s11705-020-1929-6⟩
Journal articles hal-03166843v1
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Eugenol, a developing asset in biobased epoxy resins

Sylvain Caillol , Bernard Boutevin , Rémi Auvergne
Polymer, 2021, 223, pp.123663. ⟨10.1016/j.polymer.2021.123663⟩
Journal articles hal-03187955v1
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Eugenol, a promising building block for biobased polymers with cutting-edge properties

Roberto Morales-Cerrada , Samantha Molina-Gutierrez , Patrick Lacroix-Desmazes , Sylvain Caillol
Biomacromolecules, 2021, 22 (9), pp.3625-3648. ⟨10.1021/acs.biomac.1c00837⟩
Journal articles hal-03343073v1
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Les polymères biosourcés, vecteurs d’innovations et acteurs d’un développement durable

Luc Avérous , Sylvain Caillol
L'Actualité Chimique, 2021, 456-457-458, pp.95-100
Journal articles hal-03058563v1
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Biobased Latexes from Natural Oil Derivatives

Zoriana Demchuk , Anne-Sophie Mora , Sanjana Choudhary , Sylvain Caillol , Andriy Voronov
Industrial Crops and Products, 2021, 162, pp.113237. ⟨10.1016/j.indcrop.2021.113237⟩
Journal articles hal-03119252v1
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Special Issue: 1 st French-Japanese Symposium: Recent Progress and Challenges in Polymer Science Editorial

Vincent Ladmiral , Sylvain Caillol
European Polymer Journal, 2021, 149, pp.110392. ⟨10.1016/j.eurpolymj.2021.110392⟩
Journal articles hal-03164526v1
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Editorial Special Issue “Natural Polymers and Biopolymers II”

Sylvain Caillol
Molecules, 2021, Natural Polymers and Biopolymers II, 26, pp.112. ⟨10.3390/molecules26010112⟩
Journal articles hal-03090125v1
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Bio-based poly(ester- alt -thioether)s synthesized by organo-catalyzed ring-opening copolymerizations of eugenol-based epoxides and N -acetyl homocysteine thiolactone

Simon Le Luyer , Baptiste Quienne , Matthieu Bouzaid , Philippe Guégan , Sylvain Caillol
Green Chemistry, 2021, 23 (19), pp.7743-7750. ⟨10.1039/D1GC02138A⟩
Journal articles hal-03359482v2
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Terpenoid-derived conjugated dienes with exo-methylene and 6membered ring: high cationic reactivity, regioselective living cationic polymerization, and random and block copolymerization with vinyl ethers

Takenori Nishida , Kotaro Satoh , Masazumi Tamura , Yingai Li , Keiichi Tomishige
Polymer Chemistry, 2021, 12 (9), pp.1186-1198. ⟨10.1039/d1py00035g⟩
Journal articles hal-03163687v1
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Enhanced aminolysis of cyclic carbonates by β-hydroxylamines for the production of fully biobased polyhydroxyurethanes

Baptiste Quienne , Rinaldo Poli , Julien Pinaud , Sylvain Caillol
Green Chemistry, 2021, 23 (4), pp.1678-1690. ⟨10.1039/D0GC04120C⟩
Journal articles hal-03148901v1
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Hybrid polyhydroxyurethanes: How to overcome limitations and reach cutting edge properties?

Yvan Ecochard , Sylvain Caillol
European Polymer Journal, 2020, 137, pp.109915. ⟨10.1016/j.eurpolymj.2020.109915⟩
Journal articles hal-02926323v1
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Catalysis for highly thermostable phenol-terephthalaldehyde polymer networks

Lérys Granado , Romain Tavernier , Gabriel Foyer , Ghislain David , Sylvain Caillol
Chemical Engineering Journal, 2020, 379, pp.122237-122244. ⟨10.1016/j.cej.2019.122237⟩
Journal articles hal-02189447v1
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Formaldehyde-Free Polybenzoxazines for High Performance Thermosets

Romain Tavernier , Lérys Granado , Gabriel Foyer , Ghislain David , Sylvain Caillol
Macromolecules, 2020, 53 (7), pp.2557-2567. ⟨10.1021/acs.macromol.0c00192⟩
Journal articles hal-02546388v1
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Linseed Oil‐Based Thermosets by Aza‐Michael Polymerization

Yvan Ecochard , Rémi Auvergne , Bernard Boutevin , Sylvain Caillol
European Journal of Lipid Science and Technology, 2020, Special Issue: Fats and Oils as Renewable Feedstock for the Chemical Industry, 122, pp.1900145-1900153. ⟨10.1002/ejlt.201900145⟩
Journal articles hal-02356795v1
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Dynamic network based on eugenol-derived epoxy as promising sustainable thermoset materials

Connie Ocando , Yvan Ecochard , Mélanie Decostanzi , Sylvain Caillol , Luc Avérous
European Polymer Journal, 2020, 135, pp.109860. ⟨10.1016/j.eurpolymj.2020.109860⟩
Journal articles hal-02897377v1
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One-pot two-steps synthesis of hydroxymethylated unsaturated VHOSO. Application to the synthesis of biobased polyurethanes

Kévin Cousin , Baptiste Quienne , Julien Pinaud , Sylvain Caillol , Eric Monflier
European Journal of Lipid Science and Technology, 2020, 122 (12), pp.2000158. ⟨10.1002/ejlt.202000158⟩
Journal articles hal-03035586v1
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Synthesis of Alkyl Sulfur‐Functionalized Oleic Acid‐Based Polymethacrylates and Their Application as Viscosity Index Improvers in a Mineral Paraffinic Lube Oil

Juliette Lomège , Claire Negrell , Jean‐jacques Robin , Vincent Lapinte , Sylvain Caillol
Journal of the American Oil Chemists' Society, 2020, 97 (3), pp.309-318. ⟨10.1002/aocs.12316⟩
Journal articles hal-02500509v1
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Isocyanate-Free Fully Biobased Star Polyester-Urethanes: Synthesis and Thermal Properties

Baptiste Quienne , Nejib Kasmi , Reiner Dieden , Sylvain Caillol , Youssef Habibi
Biomacromolecules, 2020, 21 (5), pp.1943-1951. ⟨10.1021/acs.biomac.0c00156⟩
Journal articles hal-02570095v1
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Vanillin derivative as performing type I photoinitiator

Louise Breloy , Claire Negrell , Anne-Sophie Mora , Wing-Sze Jennifer Li , Vlasta Brezová
European Polymer Journal, 2020, 132, pp.109727. ⟨10.1016/j.eurpolymj.2020.109727⟩
Journal articles hal-02566165v1
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A perspective approach on the amine reactivity and the hydrogen bonds effect on epoxy-amine systems

Anne-Sophie Mora , Russell Tayouo , Bernard Boutevin , Ghislain David , Sylvain Caillol
European Polymer Journal, 2020, 123, pp.109460-109473. ⟨10.1016/j.eurpolymj.2019.109460⟩
Journal articles hal-02439746v1
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From Architectures to Cutting-Edge Properties, the Blooming World of Hydrophobically Modified Ethoxylated Urethanes (HEURs)

Baptiste Quienne , Julien Pinaud , Jean-Jacques Robin , Sylvain Caillol
Macromolecules, 2020, 53 (16), pp.6754-6766. ⟨10.1021/acs.macromol.0c01353⟩
Journal articles hal-02924196v1
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Non-Conventional Features of Plant Oil-Based Acrylic Monomers in Emulsion Polymerization

Ananiy Kohut , Stanislav Voronov , Zoriana Demchuk , Vasylyna Kirianchuk , Kyle Kingsley
Molecules, 2020, 25 (13), pp.2990. ⟨10.3390/molecules25132990⟩
Journal articles hal-02885847v1
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Radical aqueous emulsion copolymerization of eugenol-derived monomers for adhesive applications

Samantha Molina-Gutiérrez , W. S.Jennifer Li , Renaud Perrin , Vincent Ladmiral , Roberta Bongiovanni
Biomacromolecules, 2020, 21, pp.4514-4521. ⟨10.1021/acs.biomac.0c00461⟩
Journal articles hal-02928837v1
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FROM GAS RELEASE TO FOAM SYNTHESIS, THE SECOND BREATH OF BLOWING AGENTS

Guilhem Coste , Claire Negrell , Sylvain Caillol
European Polymer Journal, 2020, 140, pp.110029. ⟨10.1016/j.eurpolymj.2020.110029⟩
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Photoinduced Polymerization of Eugenol-Derived Methacrylates

Samantha Molina-Gutiérrez , Sara Dalle Vacche , Alessandra Vitale , Vincent Ladmiral , Sylvain Caillol
Molecules, 2020, 25, pp.3444. ⟨10.3390/molecules25153444⟩
Journal articles hal-02909145v1
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Polyurethane Thermosets Using Lipidic Poly(α‐Hydroxyketone)

Benoit Briou , Nam Duc Vu , Sylvain Caillol , Jean‐jacques Robin , Nicolas Duguet
Journal of the American Oil Chemists' Society, 2020, 97 (1), pp.81-91. ⟨10.1002/aocs.12289⟩
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Properties of Coated Controlled Release Diammonium Phosphate (DAP) Fertilizers Prepared with the Use of Bio‐based Amino Oil

Asma Sofyane , Mohammed Lahcini , Abdellatif El Meziane , Mehdi Khouloud , Abdelmalek Dahchour
Journal of the American Oil Chemists' Society, 2020, 97 (7), pp.751-763. ⟨10.1002/aocs.12360⟩
Journal articles hal-02893146v1
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Eugenol-based thermally stable thermosets by Alder-ene reaction: From synthesis to thermal degradation

Mélanie Decostanzi , Romain Tavernier , Gaelle Fontaine , Serge Bourbigot , Claire Negrell
European Polymer Journal, 2019, 117, pp.337-346. ⟨10.1016/j.eurpolymj.2019.05.018⟩
Journal articles hal-02135059v1
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Water-Soluble 2,5-Anhydro- d -mannofuranose Chain End Chitosan Oligomers of a Very Low Molecular Weight: Synthesis and Characterization

Camille Chapelle , Ghislain David , Sylvain Caillol , Claire Negrell , Graziella Durand
Biomacromolecules, 2019, 20 (12), pp.4353-4360. ⟨10.1021/acs.biomac.9b01003⟩
Journal articles hal-02406342v1
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Synergistic Effects of Cardanol- and High Oleic Soybean Oil Vinyl Monomers in Miniemulsion Polymers

Zoriana Demchuk , W. S Jennifer Li , Hermella Eshete , Sylvain Caillol , Andriy Voronov
ACS Sustainable Chemistry & Engineering, 2019, 7 (10), pp.9613−9621. ⟨10.1021/acssuschemeng.9b01137⟩
Journal articles hal-02138104v1
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Cardanol and Eugenol Based Flame Retardant Epoxy Monomers for Thermostable Networks

Yvan Ecochard , Mélanie Decostanzi , Claire Negrell , Rodolphe Sonnier , Sylvain Caillol
Molecules, 2019, 24 (9), pp.1818. ⟨10.3390/molecules24091818⟩
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Polyhydroxybutyrate/hemp biocomposite: tuning performances by process and compatibilisation

François Touchaleaume , Romain Tessier , Rémi Auvergne , Sylvain Caillol , Sandrine Hoppe
Green materials, 2019, 7 (4), pp.194-204. ⟨10.1680/jgrma.19.00005⟩
Journal articles hal-02196923v1
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Biobased phenol and furan derivatives coupling for the synthesis of functional monomers

Mélanie Decostanzi , Rémi Auvergne , Bernard Boutevin , Sylvain Caillol
Green Chemistry, 2019, 21 (4), pp.724-747. ⟨10.1039/C8GC03541E⟩
Journal articles hal-02593309v1
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Emulsion Polymerization of Dihydroeugenol-, Eugenol-, and Isoeugenol-Derived Methacrylates

Samantha Molina-Gutiérrez , Vincent Ladmiral , Roberta Bongiovanni , Sylvain Caillol , Patrick Lacroix-Desmazes
Industrial and engineering chemistry research, 2019, 58, pp.21155−21164. ⟨10.1021/acs.iecr.9b02338⟩
Journal articles hal-02343297v1
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Reactive jojoba and castor oils-based cyclic carbonates for biobased polyhydroxyurethanes

Chakib Mokhtari , Fouad Malek , Abdelatif Manseri , Sylvain Caillol , Claire Negrell
European Polymer Journal, 2019, 113, pp.18-28. ⟨10.1016/j.eurpolymj.2019.01.039⟩
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Radical polymerization of biobased monomers in aqueous dispersed media

Samantha Molina-Gutiérrez , Vincent Ladmiral , Roberta Bongiovanni , Sylvain Caillol , Patrick Lacroix-Desmazes
Green Chemistry, 2019, 21 (1), pp.36-53. ⟨10.1039/c8gc02277a⟩
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Cardanol‐Based Epoxy Monomers for High Thermal Properties Thermosets

Anne‐sophie Mora , Mélanie Decostanzi , Ghislain David , Sylvain Caillol
European Journal of Lipid Science and Technology, 2019, 121 (8), pp.1800421-1800428. ⟨10.1002/ejlt.201800421⟩
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Fatty Acid-Based Radically Polymerizable Monomers: From Novel Poly(meth)acrylates to Cutting-Edge Properties

Juliette Lomège , Vincent Lapinte , Claire Negrell , Jean-Jacques Robin , Sylvain Caillol
Biomacromolecules, 2019, 20 (1), pp.4-26. ⟨10.1021/acs.biomac.8b01156⟩
Journal articles hal-01987149v1
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Eugenol: A Promising Building Block for Synthesis of Radically Polymerizable Monomers

Samantha Molina‐gutiérrez , Abdelatif Manseri , Vincent Ladmiral , Roberta Bongiovanni , Sylvain Caillol
Macromolecular Chemistry and Physics, 2019, Bioinspired and Biobased Materials, 220 (14), pp.1900179-1900188. ⟨10.1002/macp.201900179⟩
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From hydroxyurethane methacrylates to hybrid nonisocyanate polyurethanes

Mélanie Decostanzi , Céline ´ Bonneaud , Sylvain Caillol
Journal of Polymer Science Part A: Polymer Chemistry, 2019, 57 (11), pp.1224-1232. ⟨10.1002/pola.29379⟩
Journal articles hal-02127075v1
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Ferulic acid-based reactive core–shell latex by seeded emulsion polymerization

Wing Sze Jennifer Li , Vincent Ladmiral , Hisaaki Takeshima , Kotaro Satoh , Masami Kamigaito
Polymer Chemistry, 2019, 10 (23), pp.3116-3126. ⟨10.1039/c9py00079h⟩
Journal articles hal-02153011v1
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From the synthesis of biobased cyclic carbonate to polyhydroxyurethanes: a promising route towards renewable NonIsocyanate Polyurethanes

Camille Carré , Yvan Ecochard , Sylvain Caillol , Luc Averous
ChemSusChem, 2019, 12 (15), pp.3410-3430. ⟨10.1002/cssc.201900737⟩
Journal articles hal-02270138v1
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Synthesis of biobased reactive hydroxyl amines by amination reaction of cardanol-based epoxy monomers

Anne-Sophie Mora , Russell Tayouo , Bernard Boutevin , Ghislain David , Sylvain Caillol
European Polymer Journal, 2019, 118, pp.429-436. ⟨10.1016/j.eurpolymj.2019.06.020⟩
Journal articles hal-02159911v1
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Non-endocrine disruptor effect for cardanol based plasticizer

Benoit Briou , Sylvain Caillol , Jean-Jacques Robin , Vincent Lapinte
Industrial Crops and Products, 2019, 130, pp.1-8. ⟨10.1016/j.indcrop.2018.12.060⟩
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From multi-functional siloxane-based cyclic carbonates to hybrid polyhydroxyurethane thermosets

Yvan Ecochard , Jules Leroux , Bernard Boutevin , Rémi Auvergne , Sylvain Caillol
European Polymer Journal, 2019, 120, pp.109280-109289. ⟨10.1016/j.eurpolymj.2019.109280⟩
Journal articles hal-02356796v1
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Toward Sustainable Phenolic Thermosets with High Thermal Performances

Lérys Granado , Romain Tavernier , Ségolène Henry , Ruth Oye Auke , Gabriel Foyer
ACS Sustainable Chemistry & Engineering, 2019, 7 (7), pp.7209-7217. ⟨10.1021/acssuschemeng.8b06286⟩
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Oleic acid-based poly(alkyl methacrylate) as bio-based viscosity control additive for mineral and vegetable oils

Juliette Lomège , Claire Negrell , Jean-Jacques Robin , Vincent Lapinte , Sylvain Caillol
Polymer Engineering and Science, 2019, Films and Membranes, 59 (S1), pp.E164-E170. ⟨10.1002/pen.24896⟩
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Epoxidized Oleic Acid‐Based Polymethacrylates as Viscosity Index Improvers

Juliette Lomège , Vincent Lapinte , Claire Negrell , Jean‐jacques Robin , Sylvain Caillol
Journal of the American Oil Chemists' Society, 2019, 96 (4), pp.467-478. ⟨10.1002/aocs.12187⟩
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From monomer synthesis to polymers with pendant aldehyde groups

Claire Negrell , Coline Voirin , Bernard Boutevin , Vincent Ladmiral , Sylvain Caillol
European Polymer Journal, 2018, 109, pp.544 - 563. ⟨10.1016/j.eurpolymj.2018.10.039⟩
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Cardanol-based polymer latex by radical aqueous miniemulsion polymerization

Wing Sze Jennifer Li , Claire Negrell , Vincent Ladmiral , Josephine Lai-Kee-Him , Patrick Bron
Polymer Chemistry, 2018, 9 (18), pp.2468 - 2477. ⟨10.1039/C8PY00167G⟩
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Cardanol-Based and Formaldehyde-Free Flexible Phenolic Networks

Benoit Briou , Sylvain Caillol , Jean-Jacques Robin , Vincent Lapinte
European Journal of Lipid Science and Technology, 2018, 120 (7), pp.1800175-1800183. ⟨10.1002/ejlt.201800175⟩
Journal articles hal-01832078v1
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Cardanol: A promising building block for biobased polymers and additives

Sylvain Caillol
Current opinion in green and sustainable chemistry, 2018, 14, pp.26-32. ⟨10.1016/j.cogsc.2018.05.002⟩
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Synthesis of Bio-Based Polyurethanes from Jojoba Oil

Chakib Mokhtari , Fouad Malek , Sylvain Caillol , Claire Negrell
European Journal of Lipid Science and Technology, 2018, 120 (3), ⟨10.1002/ejlt.201700414⟩
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Fatty acid-based cross-linkable polymethacrylate coatings

Mélanie Decostanzi , Juliette Lomège , Yvan Ecochard , Anne-Sophie Mora , Claire Negrell
Progress in Organic Coatings, 2018, 124, pp.147 - 157. ⟨10.1016/j.porgcoat.2018.08.001⟩
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Comparative curing kinetics study of high char yield formaldehyde- and terephthalaldehyde-phenolic thermosets

Lérys Granado , Romain Tavernier , Gabriel Foyer , Ghislain David , Sylvain Caillol
Thermochimica Acta, 2018, 667, pp.42-49. ⟨10.1016/j.tca.2018.06.013⟩
Journal articles hal-01854078v1
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Limonene-Based Epoxy: Anhydride Thermoset Reaction Study

Guillaume Couture , Lérys Granado , Florent Fanget , Bernard Boutevin , Sylvain Caillol
Molecules, 2018, 23, pp.2739-2754. ⟨10.3390/molecules23112739⟩
Journal articles hal-01902819v1
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Synthesis of plant oil-based amide copolymethacrylates and their use as viscosity index improvers

Juliette Lomège , Violette Mohring , Vincent Lapinte , Claire Negrell , Jean-Jacques Robin
European Polymer Journal, 2018, 109, pp.435-446. ⟨10.1016/j.eurpolymj.2018.10.015⟩
Journal articles hal-01907227v1
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Vanillin-derived amines for bio-based thermosets

Anne-Sophie Mora , Russell Tayouo , Bernard Boutevin , Ghislain David , Sylvain Caillol
Green Chemistry, 2018, 20, pp.4075-4084. ⟨10.1039/C8GC02006J⟩
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Fatty acid-based methacrylate polymers as viscosity modifiers for mineral oils

Juliette Lomège , Claire Negrell , Jean-Jacques Robin , Vincent Lapinte , Sylvain Caillol
Green materials, 2018, 6 (3), pp.97 - 107. ⟨10.1680/jgrma.18.00014⟩
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Synthesis of sol-gel hybrid polyhydroxyurethanes

Mélanie Decostanzi , Yvan Ecochard , Sylvain Caillol
European Polymer Journal, 2018, 109, pp.1 - 7. ⟨10.1016/j.eurpolymj.2018.08.054⟩
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Polymères biosourcés Principaux enjeux et perspectives

Luc Avérous , Henri Cramail , Sylvain Caillol
L'Actualité Chimique, 2017
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A study of cyclic carbonate aminolysis at room temperature: effect of cyclic carbonate structures and solvents on polyhydroxyurethane synthesis

Adrien Cornille , Marine Blain , Rémi Auvergne , Bruno Andrioletti , Bernard Boutevin
Polymer Chemistry, 2017, 8, pp.592-604. ⟨10.1039/c6py01854h⟩
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A perspective approach to sustainable routes for non-isocyanate polyurethanes

Adrien Cornille , Rémi Auvergne , Oleg Figovsky , Bernard Boutevin , Sylvain Caillol
European Polymer Journal, 2017, 87, pp.535-552. ⟨10.1016/j.eurpolymj.2016.11.027⟩
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Hydrogen bonds prevent obtaining high molar mass PHUs

Marine Blain , Adrien Cornille , Bernard Boutevin , Rémi Auvergne , Dominique Benazet
Journal of Applied Polymer Science, 2017, 134 (44958-44970), ⟨10.1002/app.44958⟩
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New bio-based epoxy materials and foams from microalgal oil

Claire Negrell-Guirao , Adrien Cornille , Patricia de Andrade Nascimiento , Jean-Jacques Robin , Sylvain Caillol
European Journal of Lipid Science and Technology, 2017, 119, pp.1600214-1600227. ⟨10.1002/ejlt.201600214⟩
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Climate engineering by mimicking natural dust climate control: the iron salt aerosol method

Oeste Franz Dietrich , Renaud de Richter , Tingzhen Ming , Sylvain Caillol
Earth System Dynamics Discussions , 2017, 8, pp.1-54. ⟨10.5194/esd-8-1-2017⟩
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Biobased and Aromatic Reversible Thermoset Networks from Condensed Tannins via the Diels−Alder Reaction

Antoine Duval , Guillaume Couture , Sylvain Caillol , Luc Averous
ACS Sustainable Chemistry & Engineering, 2017, 5, pp.1199-1207. ⟨10.1021/acssuschemeng.6b02596⟩
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Synthesis of hybrid polyhydroxyurethanes by Michael addition

Adrien Cornille , Yvan Ecochard , Marine Blain , Bernard Boutevin , Sylvain Caillol
European Polymer Journal, 2017, 96, pp.370 - 382. ⟨10.1016/j.eurpolymj.2017.09.028⟩
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Sustainable cardanol-based ionic surfactants

Ibrahima Faye , Vincent Besse , Ghislain David , Sylvain Caillol
Green materials, 2017, pp.144-152. ⟨10.1680/jgrma.17.00018⟩
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Eugenol bio-based epoxy thermosets: from cloves to applied materials

Ibrahima Faye , Mélanie Decostanzi , Yvan Ecochard , Sylvain Caillol
Green Chemistry, 2017, 19 (21), pp.5236 - 5242. ⟨10.1039/c7gc02322g⟩
Journal articles hal-01626684v1
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Bio-Based Aromatic Epoxy Monomers for Thermoset Materials

Feifei Ng , Guillaume Couture , Coralie Philippe , Bernard Boutevin , Sylvain Caillol
Molecules, 2017, 22 (1), pp.149. ⟨10.3390/molecules22010149⟩
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THERMORESPONSIVE ISOCYANATE-FREE POLYURETHANES SYNTHESIZED BY DIELS-ALDER POLYADDITION

Dolci Elena , Guillaume Michaud , Frédéric Simon , Stéphane Fouquay , Rémi Auvergne
Scientific Israel Technological Advantages, 2017, 19, pp.29-42
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Aromatic biobased polymer latex from cardanol

Vincent Ladmiral , Renaud Jeannin , Kepa Fernandes Lizarazu , Joséphine Lai Kee Him , Patrick Bron
European Polymer Journal, 2017, 93, pp.785-794. ⟨10.1016/j.eurpolymj.2017.04.003⟩
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Reactivity and kinetics of HDI-iminooxadiazinedione: Application to polyurethane synthesis

Mélanie Decostanzi , Rémi Auvergne , Emilie Darroman , Bernard Boutevin , Sylvain Caillol
European Polymer Journal, 2017, 96, pp.443 - 451. ⟨10.1016/j.eurpolymj.2017.09.032⟩
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Novel biobased and food contact epoxy coatings for glass toughening applications

Feifei Ng , Laurent Bonnet , Ghislain David , Sylvain Caillol
Progress in Organic Coatings, 2017, 109, pp.1-8. ⟨10.1016/j.porgcoat.2017.04.008⟩
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Chemo-Enzymatic Synthesis and Characterization of Renewable Thermoplastic and Thermoset Isocyanate-Free Poly(hydroxy)urethanes from Ferulic Acid Derivatives

Raphaël Menard , Sylvain Caillol , Florent Allais
ACS Sustainable Chemistry & Engineering, 2017, 5 (2), pp.1446-1456. ⟨10.1021/acssuschemeng.6b02022⟩
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Thermoresponsive crosslinked isocyanate-free polyurethanes by Diels-Alder polymerization

Dolci Elena , Vincent Froidevaux , Guillaume Michaud , Frederic Simon , Rémi Auvergne
Journal of Applied Polymer Science, 2017, 134, pp.44408-44419. ⟨10.1002/app.44408⟩
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Ferulic acid-based renewable esters and amides-containing epoxythermosets from wheat bran and beetroot pulp: Chemo-enzymaticsynthesis and thermo-mechanical properties characterization

Raphaël Menard , Sylvain Caillol , Florent Allais
Industrial Crops and Products, 2017, 95, pp.83-95. ⟨10.1016/j.indcrop.2016.10.016⟩
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Removal of non-CO2 greenhouse gases by large-scale atmospheric solar photocatalysis

Renaud de Richter , Tingzhen Ming , Philip L. Davies , Wei Liu , Sylvain Caillol
Progress in Energy and Combustion Science, 2017, 60, pp.68-96. ⟨10.1016/j.pecs.2017.01.001⟩
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Maleimides as a building block for the synthesis of high properties polymers

Dolci Elena , Vincent Froidevaux , Christine Joly-Duhamel , Rémi Auvergne , Bernard Boutevin
Polymer Reviews, 2016, 56, pp.512-556. ⟨10.1080/15583724.2015.1116094⟩
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Room temperature flexible isocyanate-free polyurethane foams

Adrien Cornille , Camille Guillet , Sofia Benyahya , Claire Negrell-Guirao , Bernard Boutevin
European Polymer Journal, 2016, 84, pp.873-888. ⟨10.1016/j.eurpolymj.2016.05.032⟩
Journal articles hal-01409561v1
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A chemical platform approach on cardanol oil: from the synthesis of building blocks to polymer synthesis

Fanny Jaillet , Emilie Darroman , Bernard Boutevin , Sylvain Caillol
OCL Oilseeds and fats crops and lipids, 2016, 23 (5), pp.511-518. ⟨10.1051/ocl/2016022⟩
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Synthesis of novel vinylester from biobased phloroglucinol

Fanny Jaillet , Hélène Nouailhas , Bernard Boutevin , Sylvain Caillol
Green materials, 2016, 4 (2), pp.63-71. ⟨10.1680/jgrma.16.00005⟩
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Fighting global warming by greenhouse gas removal: destroying atmospheric nitrous oxide thanks to synergies between two breakthrough technologies

Tingzhen Ming , Renaud de Richter , Shen Sheng , Sylvain Caillol
Environmental Science and Pollution Research, 2016, 23, pp.6119-6138. ⟨10.1007/s11356-016-6103-9⟩
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Lignin-derivednon-toxicaldehydesforecofriendlytanninadhesives for woodpanels

Francisco Santiago-Medina , Gabriel Foyer , Antonio Pizzi , Sylvain Caillol , Luc Delmotte
International Journal of Adhesion and Adhesives, 2016, 70, pp.239-248. ⟨10.1016/j.ijadhadh.2016.07.002⟩
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Syntheses of epoxyurethane polymers from isocyanate free oligo-polyhydroxyurethane

Adrien Cornille , Julien Serres , Guillaume Michaud , Frédéric Simon , Stéphane Fouquay
European Polymer Journal, 2016, 75, pp.175-189. ⟨10.1016/j.eurpolymj.2015.12.017⟩
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Synthesis of Aminotelechelic Prepolymers to Circumvent the Carbonation of Amines in Epoxy Coatings

Marine Blain , Jean-Gérard Ludivine , Dominique Benazet , Bernard Boutevin , Bruno Andrioletti
Macromolecular Materials and Engineering, 2016, 301, pp.682-693. ⟨10.1002/mame.201500402⟩
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Epoxy thermosets from model mixtures of the lignin-to-vanillin process

Maxence Fache , Bernard Boutevin , Sylvain Caillol
Green Chemistry, 2016, 18, pp.712-725. ⟨10.1039/c5gc01070e⟩
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Biobased Amines: From Synthesis to Polymers; Present and Future

Vincent Froidevaux , Claire Negrell , Sylvain Caillol , Jean-Pierre Pascault , Bernard Boutevin
Chemical Reviews, 2016, 116, pp.14181-14224. ⟨10.1021/acs.chemrev.6b00486⟩
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Aromatic dialdehyde precursors from lignin derivatives for the synthesis of formaldehyde-free and high char yield phenolic resins

Gabriel Foyer , Bibi-Hadidja Chanfi , David Virieux , Ghislain David , Sylvain Caillol
European Polymer Journal, 2016, 77, pp.65-74. ⟨10.1016/j.eurpolymj.2016.02.018⟩
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Fighting global warming by GHG removal: Destroying CFCs and HCFCs in solar-wind power plant hybrids producing renewable energy with no-intermittency

Renaud de Richter , Tingzhen Ming , Sylvain Caillol , Wei Liu
International Journal of Greenhouse Gas Control, 2016, 49, pp.449-472. ⟨10.1016/j.ijggc.2016.02.027⟩
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An efficient catalytic system based on chitosan derivative containing both carboxylic acid and quaternary ammonium moieties for the synthesis of cyclic carbonates

Vincent Besse , Nicolas Illy , Ghislain David , Sylvain Caillol , Bernard Boutevin
ChemSusChem, 2016, 9, pp.2167-2173. ⟨10.1002/cssc.201600499⟩
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Improved cardanol derived epoxy coatings

Emilie Darroman , Nelly Durand , Bernard Boutevin , Sylvain Caillol
Progress in Organic Coatings, 2016, 91, pp.9-16. ⟨10.1016/j.porgcoat.2015.11.012⟩
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Diels–Alder thermoreversible isocyanate-free polyurethanes

Dolci Elena , Guillaume Michaud , Frédéric Simon , Stéphane Fouquay , Rémi Auvergne
Green materials, 2016, 4, pp.160-170. ⟨10.1680/jgrma.16.00018⟩
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Vanillin Production from Lignin and Its Use as a Renewable Chemical

Maxence Fache , Bernard Boutevin , Sylvain Caillol
ACS Sustainable Chemistry & Engineering, 2016, 4, pp.35-46. ⟨10.1021/acssuschemeng.5b01344⟩
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Editorial : Special Issue on Sustainable Routes to Polyurethanes

Sylvain Caillol , Henri Cramail , Filip E. Du Prez
European Polymer Journal, 2016, 84, pp.734-735. ⟨10.1016/j.eurpolymj.2016.10.025⟩
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New method for the synthesis of formaldehyde-free phenolic resins from lignin-based aldehyde precursors

Gabriel Foyer , Bibi-Hadidja Chanfi , Bernard Boutevin , Sylvain Caillol , Ghislain David
European Polymer Journal, 2016, 74, pp.296-309. ⟨10.1016/j.eurpolymj.2015.11.036⟩
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Promising mechanical and adhesive properties of isocyanate-free poly(hydroxyurethane)

Adrien Cornille , Guillaume Michaud , Frederic Simon , Stéphane Fouquay , Rémi Auvergne
European Polymer Journal, 2016, 84, pp.404-420. ⟨10.1016/j.eurpolymj.2016.09.048⟩
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Urea- and Thiourea-Catalyzed Aminolysis of Carbonates

Marine Blain , Honman Yau Yau , Jean-Gérard Ludivine , Rémi Auvergne , Dominique Benazet
ChemSusChem, 2016, 9, pp.2269-2272. ⟨10.1002/cssc.201600778⟩
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Synthesis of novel biobased vinylester from dicyclopentadiene prepolymer, cashew nut shell liquid and soybean oil

Fanny Jaillet , Hélène Nouailhas , Bernard Boutevin , Sylvain Caillol
European Journal of Lipid Science and Technology, 2016, 118 (1336-1349), ⟨10.1002/ejlt.201500550⟩
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Activated anionic ring-opening polymerization for the synthesis of reversibly cross-linkable poly-(propylene oxide) based on furan/maleimide chemistry

Roos Kevin , Dolci Elena , Stéphane Carlotti , Sylvain Caillol
Polymer Chemistry, 2016, 7, pp.1612-1622. ⟨10.1039/c5py01778e⟩
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Image document

Phosphorylation of bio-based compounds: the state of the art

Nicolas Illy , Maxence Fache , Raphaël Ménard , Claire Negrell , Sylvain Caillol
Polymer Chemistry, 2015, 6 (35), pp.6257-6291. ⟨10.1039/c5py00812c⟩
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A new way of creating cellular polyurethane materials: NIPU foams

Adrien Cornille , Sylwia Dworakowska , Dariusz Bogdal , Bernard Boutevin , Sylvain Caillol
European Polymer Journal, 2015, 66, pp.129-138. ⟨10.1016/j.eurpolymj.2015.01.034⟩
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New aromatic amine based on cardanol giving new biobased epoxy networks with cardanol

Emilie Darroman , Lea Bonnot , Rémi Auvergne , Bernard Boutevin , Sylvain Caillol
European Journal of Lipid Science and Technology, 2015, 117, pp.178-189. ⟨10.1002/ejlt.201400248⟩
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Formulation of bio-based epoxy foams from epoxidized cardanol and vegetable oil amine

Sylwia Dworakowska , Adrien Cornille , Dariusz Bogdal , Bernard Boutevin , Sylvain Caillol
European Journal of Lipid Science and Technology, 2015, 117, pp.1893-1902. ⟨10.1002/ejlt.201500232⟩
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New vanillin-derived diepoxy monomers for the synthesis of biobased thermosets

Maxence Fache , Rémi Auvergne , Bernard Boutevin , Sylvain Caillol
European Polymer Journal, 2015, 67, pp.527-538. ⟨10.1016/j.eurpolymj.2014.10.011⟩
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Synthesis of novel vinylester from dicyclopentadiene prepolymer

Fanny Jaillet , Hélène Nouailhas , Bernard Boutevin , Sylvain Caillol
European Polymer Journal, 2015, 71, pp.248-258. ⟨10.1016/j.eurpolymj.2015.08.002⟩
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Aldehyde functional monomer as efficient cross-linkable comonomerwith biobased phenols in acrylic coatings

Gabriel Foyer , Morgane Barriol , Claire Negrell-Guirao , Sylvain Caillol , Ghislain David
Progress in Organic Coatings, 2015, 84, pp.1-8. ⟨10.1016/j.porgcoat.2015.02.006⟩
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Editorial : Special Issue on Synthesis and Characterization of Renewable Thermoset Resins and Composites

Sylvain Caillol , Mats Johansson
European Polymer Journal, 2015, 67, pp.373-374. ⟨10.1016/j.eurpolymj.2015.03.004⟩
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Synthesis of cardanol oil building blocks for polymer synthesis

Fanny Jaillet , Emilie Darroman , Amédée Ratsimihety , Bernard Boutevin , Sylvain Caillol
Green materials, 2015, 3, pp.1-29. ⟨10.1680/jgrma.15.00004⟩
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Synthesis of Advanced Nanoreinforced Polyurethane with Thiolene Photografted Organo-Modified Layered Double Hydroxide

Audrey Ramone , Audrey Diouf-Lewis , Florence Delor-Jestin , Rémi Auvergne , Sylvain Caillol
European Journal of Inorganic Chemistry, 2015, 2015, pp.1203-1211. ⟨10.1002/ejic.201402602⟩
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How to explain low molar masses in PolyHydroxyUrethanes (PHUs)

Vincent Besse , Fatoumata Camara , Françoise Méchin , Etienne Fleury , Sylvain Caillol
European Polymer Journal, 2015, 71, pp.1-11. ⟨10.1016/j.eurpolymj.2015.07.020⟩
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Biobased epoxy thermosets from vanillin-derived oligomers

Maxence Fache , Arnaud Viola , Rémi Auvergne , Bernard Boutevin , Sylvain Caillol
European Polymer Journal, 2015, 68, pp.526-535. ⟨10.1016/j.eurpolymj.2015.03.048⟩
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Vanillin, a key-intermediate of biobased polymers

Maxence Fache , Bernard Boutevin , Sylvain Caillol
European Polymer Journal, 2015, 68, pp.488-502. ⟨10.1016/j.eurpolymj.2015.03.050⟩
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New cardanol/sucrose epoxy blends for biobased coatings

Emilie Darroman , Nelly Durand , Bernard Boutevin , Sylvain Caillol
Progress in Organic Coatings, 2015, 83, pp.47-54. ⟨10.1016/j.porgcoat.2015.02.002⟩
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Remendable thermosetting polymers for isocyanate-free adhesives: a preliminary study</