Sylvain Caillol

Research Director, CNRS

300

Documents

Current affiliations

1100807

Researcher identifiers

sylvain-caillol
0000-0003-3106-5547
Google Scholar : https://scholar.google.com/citations?user=JzeGb0kAAAAJ&hl=fr&oi=ao
IdRef : 069796688

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Publications

	4-Vinyl Guaiacol: A Key Intermediate for Biobased Polymers Elena Rigo , Cédric Totée , Vincent Ladmiral , Sylvain Caillol , Patrick Lacroix-Desmazes Molecules, 2024, 29 (11), pp.2507. ⟨10.3390/molecules29112507⟩ Journal articles hal-04588339v1
	Understanding associative polymer self-assembly with shrinking gate fluorescence correlation spectroscopy Timothy J Murdoch , Baptiste Quienne , Julien Pinaud , Sylvain Caillol , Ignacio Martín-Fabiani Nanoscale, 2024, 16 (26), pp.12660-12669. ⟨10.1039/D4NR00737A⟩ Journal articles hal-04636329v1
	Evaluation of Porous (Poly(lactide-co-glycolide)-co-(ε-caprolactone)) Polyurethane for Use in Orthopedic Scaffolds Gaëlle Savin , Océane Sastourne-Array , Sylvain Caillol , Audrey Bethry , Michel Assor Molecules, 2024, 29 (4), pp.766. ⟨10.3390/molecules29040766⟩ Journal articles hal-04446053v1
	Phosphorus acid: an asset for flame-retardant sustainable vitrimers Florian Cuminet , Nathan Vanachte , Chloé Farina , Maxinne Denis , Claire Negrell Polymer Chemistry, 2024, 15 (12), pp.1212-1226. ⟨10.1039/d3py01328f⟩ Journal articles hal-04511242v1
	Ring‐opening (co)polymerization of cardanol glycidyl ether Emma Mongkhoun , Gholamreza Charmi , Justine Grier--Boisgontier , Fato Niang , Margot Gomes Polymers for Advanced Technologies, 2024, 35 (2), pp.e6320. ⟨10.1002/pat.6320⟩ Journal articles hal-04454021v1
	Sustainable polyurethanes: toward new cutting-edge opportunities Aliénor Delavarde , Gaelle Savin , Paul Derkenne , Marine Boursier , Roberto Morales-Cerrada Progress in Polymer Science, 2024, 151, pp.101805. ⟨10.1016/j.progpolymsci.2024.101805⟩ Journal articles hal-04489278v1
	Closed-loop recyclability of a biomass-derived epoxy-amine thermoset by methanolysis Xianyuan Wu , Peter Hartmann , Dimitri Berne , Mario de Bruyn , Florian Cuminet Science, 2024, 384 (6692), pp.156. ⟨10.1126/science.adj9989⟩ Journal articles hal-04543082v1
	Flame-retardant performance of phosphorylated furan-containing alkyd resins Maxinne Denis , Damien Le Borgne , Rodolphe Sonnier , Sylvain Caillol , Claire Negrell Green materials, In press, 11, pp.1-15. ⟨10.1680/jgrma.22.00093⟩ Journal articles hal-04143482v1
	Hafnium coordination vitrimer based on carboxylate exchange: synthesis, properties, and mechanistic investigations on the [Hf 6 O 4 (OH) 4 (O 2 CMe) 12 ] 2 model compound Meenu Murali , Dimitri Berne , Jean‐claude Daran , Christian Bijani , Eric Manoury European Journal of Inorganic Chemistry, 2024, 27 (8), pp.e202300672. ⟨10.1002/ejic.202300672⟩ Journal articles hal-04427867v1
	Collagen/polyester-polyurethane porous scaffolds for use in meniscal repair Gaëlle Savin , Sylvain Caillol , Audrey Bethry , Eric Rondet , Michel Assor Biomaterials Science, 2024, 12 (11), pp.2960-2977. ⟨10.1039/d4bm00234b⟩ Journal articles hal-04591584v1
	On Sustainability Aspects of the Synthesis of Five-Membered Cyclic Carbonates Federico Mundo , Sylvain Caillol , Vincent Ladmiral , Michael a R Meier ACS Sustainable Chemistry & Engineering, 2024, 12 (17), pp.6452-6466. ⟨10.1021/acssuschemeng.4c01274⟩ Journal articles hal-04564897v1
	Fully bio-sourced catalyst-free covalent adaptable networks from epoxidized soybean oil and L-tartaric acid Neymara C Nepomuceno , Camille Bakkali-Hassani , Renate Wellen , Sylvain Caillol , Claire Negrell European Polymer Journal, 2024, 212, pp.113074. ⟨10.1016/j.eurpolymj.2024.113074⟩ Journal articles hal-04568256v1
	Adhesion theories: A didactic review about a century of progress Léo Bricotte , Kamel Chougrani , Valérie Alard , Vincent Ladmiral , Sylvain Caillol International Journal of Adhesion and Adhesives, 2024, 132, pp.103673. ⟨10.1016/j.ijadhadh.2024.103673⟩ Journal articles hal-04495883v1
	Biobased Composites from Eugenol- and Coumarin-Derived Methacrylic Latex and Hemp Nanocellulose: Cross-Linking via [2 + 2] Photocycloaddition and Barrier Properties Sara Dalle Vacche , Samantha Molina-Gutiérrez , Giuseppe Ferraro , Vincent Ladmiral , Sylvain Caillol ACS Sustainable Chemistry & Engineering, 2024, 12 (23), pp.8741-8751. ⟨10.1021/acssuschemeng.4c01365⟩ Journal articles hal-04607104v1
	Combination of Fluorine and Tertiary Amine Activation in Catalyst-Free Thia-Michael Covalent Adaptable Networks Dimitri Berne , Rinaldo Poli , Sylvain Caillol , Vincent Ladmiral , Eric Leclerc Macromolecules, 2023, 56 (20), pp.8260-8274. ⟨10.1021/acs.macromol.3c01129⟩ Journal articles hal-04232888v1
	Recent advances in radical polymerization of bio-based monomers in aqueous dispersed media Elena Rigo , Vincent Ladmiral , Sylvain Caillol , Patrick Lacroix-Desmazes RSC Sustainability, 2023, 1, pp.788. ⟨10.1039/d3su00097d⟩ Journal articles hal-04122374v1
	One Step Closer to Coatings Applications Utilizing Self-Stratification: Effect of Rheology Modifiers Timothy Murdoch , Baptiste Quienne , Maialen Argaiz , Radmila Tomovska , Edgar Espinosa ACS Applied Polymer Materials, 2023, 5 (8), pp.6672-6684. ⟨10.1021/acsapm.3c01288⟩ Journal articles hal-04184185v1
	Bio-sourced alternatives to diglycidyl ether of bisphenol A in epoxy–amine thermosets Romain Tavernier , Mona Semsarilar , Sylvain Caillol Green materials, inPress, pp.1-47. ⟨10.1680/jgrma.23.00027⟩ Journal articles hal-04222577v1
	Editorial: 2023 is a remarkable year for green chemistry and Green Materials Sylvain Caillol Green materials, 2023, 11 (1), pp.1-2. ⟨10.1680/jgrma.2023.11.1.1⟩ Journal articles hal-04027176v1
	Lignin-based Bisguaiacol diisocyanate: a green route for the synthesis of biobased polyurethanes Sébastien Lemouzy , Aliénor Delavarde , Frédéric Lamaty , Xavier Bantreil , Julien Pinaud Green Chemistry, 2023, 25 (12), pp.4833-4839. ⟨10.1039/d3gc00704a⟩ Journal articles hal-04133269v1
	From vineyards to reshapable materials: α-CF 2 activation in 100% resveratrol-based catalyst-free vitrimers Florian Cuminet , Sébastien Lemouzy , Éric Dantras , Éric Leclerc , Vincent Ladmiral Polymer Chemistry, 2023, 14 (12), pp.1387-1395. ⟨10.1039/d3py00017f⟩ Journal articles hal-04041913v1
	From natural phenols to biobased epoxy resins Sylvain Caillol Revue francaise d'allergologie, 2023, 63 (3), pp.103286. ⟨10.1016/j.reval.2023.103286⟩ Journal articles hal-03951346v1
	Photoactivable alizarin and eugenol-based materials for antibacterial applications Christine Elian , Baptiste Quienne , Sonia Lajnef , Fabienne Peyrot , Régis Moilleron European Polymer Journal, 2023, 197, pp.112369. ⟨10.1016/j.eurpolymj.2023.112369⟩ Journal articles hal-04188733v1
	A Blooming Season for Natural Polymers and Biopolymers Sylvain Caillol Molecules, 2023, 28, pp.3207. ⟨10.3390/molecules28073207⟩ Journal articles hal-04057526v1
	Catalyst‐Free Thia‐Michael Addition to alpha‐Trifluoromethylacrylates for 3D Network Synthesis Dimitri Berne , Sebastien Lemouzy , Pascale Guiffrey , Sylvain Caillol , Vincent Ladmiral Chemistry - A European Journal, inPress, 29 (20), pp.e202203712. ⟨10.1002/chem.202203712⟩ Journal articles hal-03972802v1
	Influence of Phosphorus Structures and Their Oxidation States on Flame-Retardant Properties of Polyhydroxyurethanes Maxinne Denis , Guilhem Coste , Rodolphe Sonnier , Sylvain Caillol , Claire Negrell Molecules, 2023, 28 (2), pp.611. ⟨10.3390/molecules28020611⟩ Journal articles hal-03931988v1
	Cardanol: a small giant of the future of biobased aromatic polymers and additives Sylvain Caillol European Polymer Journal, 2023, 193, pp.112096. ⟨10.1016/j.eurpolymj.2023.112096⟩ Journal articles hal-04089370v1
	Polyhydroxyurethane Covalent Adaptable Networks: Looking for Suitable Catalysts Camille Bakkali-Hassani , Dimitri Berne , Pauline Bron , Lourdes Irusta , Haritz Sardon Polymer Chemistry, 2023, 14 (31), pp.3610-3620. ⟨10.1039/d3py00579h⟩ Journal articles hal-04178773v1
	Des résines alkydes hydrides aux propriétés ignifugeantes pour la formulation de revêtements Damien Le Borgne , Maxinne Denis , Laurent Cubizolles , Rodolphe Sonnier , Sylvain Caillol L'Actualité Chimique, 2023, N° 484-485, pp.78-82 Journal articles hal-04233175v1
	Understanding glycidylation reaction for the formation of pure mono, diglycidyl and dual monomers as glycidyl methacrylate of vanillyl alcohol Sylvain Caillol , Rémi Auvergne , Abdelatif Manseri , Gilles Boutevin , Bernard Boutevin Journal of Applied Polymer Science, 2023, 140 (10), pp.e53596. ⟨10.1002/app.53596⟩ Journal articles hal-03975512v1
	Dynamic PEG-PLA/hydroxyurethane networks based on imine bonds as reprocessable elastomeric biomaterials Mathilde Grosjean , Dimitri Berne , Sylvain Caillol , Vincent Ladmiral , Benjamin Nottelet Biomacromolecules, 2023, 24 (8), pp.3472-3483. ⟨10.1021/acs.biomac.3c00229⟩ Journal articles hal-04188736v1
	Synthesis and characterization of original fluorinated bis-cyclic carbonates and xanthates from a fluorinated epoxide Ali Alaaeddine , Vincent Ladmiral , Wassim El Malti , Lolwa Haydar , Sylvain Caillol Comptes Rendus. Chimie, 2023, 26 (G1), pp.19 - 28. ⟨10.5802/crchim.216⟩ Journal articles hal-03989242v2
	Transamidation vitrimers enabled by neighboring fluorine atom activation Dimitri Berne , Gwendal Tanguy , Sylvain Caillol , Rinaldo Poli , Vincent Ladmiral Polymer Chemistry, 2023, 14, pp.3479. ⟨10.1039/d3py00577a⟩ Journal articles hal-04174700v1
	Triple Benefits of Cardanol as Chain Stopper, Flame Retardant and Reactive Diluent for Greener Alkyd Coating Maxinne Denis , Cédric Totée , Damien Le Borgne , Rodolphe Sonnier , Sylvain Caillol Organics, 2023, 4 (1), pp.109 - 125. ⟨10.3390/org4010009⟩ Journal articles hal-04037375v1
	Dihydroxyacetone: A User Guide for a Challenging Bio-Based Synthon Léo Bricotte , Kamel Chougrani , Valérie Alard , Vincent Ladmiral , Sylvain Caillol Molecules, 2023, 28 (6), pp.2724. ⟨10.3390/molecules28062724⟩ Journal articles hal-04035566v1
	Synthesis of a transesterification vitrimer activated by fluorine from an α,αdifluoro carboxylic acid and a diepoxy Florian Cuminet , Sylvain Caillol , Éric Dantras , Eric Leclerc , Sébastien Lemouzy European Polymer Journal, 2023, 182, pp.111718. ⟨10.1016/j.eurpolymj.2022.111718⟩ Journal articles hal-03880200v1
	How phosphinated hydroxyurethane groups improve chemical resistance and flame retardant properties of alkyd resins? Maxinne Denis , Alan Paré , Damien Le Borgne , Rodolphe Sonnier , Sylvain Caillol Polymer Degradation and Stability, 2023, 216, pp.110477. ⟨10.1016/j.polymdegradstab.2023.110477⟩ Journal articles hal-04168894v1
	Hydroxyurethane modifiers (HUM): an environmentally-friendly route to improve chemical resistance of alkyd coatings Maxinne Denis , Alan Paré , Damien Le Borgne , Sylvain Caillol , Claire Negrell Progress in Organic Coatings, 2023, 183, pp.107734. ⟨10.1016/j.porgcoat.2023.107734⟩ Journal articles hal-04137302v1
	Eco-Friendly Synthesis of Cardanol-Based AB Monomer for Formaldehyde-Free Phenolic Thermosets Benoit Briou , Lucas Jégo , Thomas de Dios Miguel , Nicolas Duguet , Sylvain Caillol RSC Sustainability, 2023, 1 (4), pp.994-1005. ⟨10.1039/D3SU00058C⟩ Journal articles hal-04155005v1
	Paving the Way towards Sustainability of Polyurethanes: Synthesis and Properties of Terpene-Based Diisocyanate Aliénor Delavarde , Sebastien Lemouzy , Aurélien Lebrun , Julien Pinaud , Sylvain Caillol Molecules, 2023, 28 (20), pp.7133. ⟨10.3390/molecules28207133⟩ Journal articles hal-04246489v1
	Editorial: Green materials, a growing science and industry! Sylvain Caillol Green materials, 2023, 11 (4), pp.145-146. ⟨10.1680/jgrma.2023.11.4.145⟩ Journal articles hal-04375712v1
	Cardanol-modified alkyd resins: novel route to make greener alkyd coatings Maxinne Denis , Cédric Totee , Damien Le Borgne , Sylvain Caillol , Claire Negrell Progress in Organic Coatings, 2022, 172, pp.107087. ⟨10.1016/j.porgcoat.2022.107087⟩ Journal articles hal-03750083v1
	Editorial: Green chemistry and green materials evolve in a changing world Sylvain Caillol Green materials, 2022, 10 (2), pp.49-50. ⟨10.1680/jgrma.2022.10.2.49⟩ Journal articles hal-03698956v1
	Taking advantage of β-hydroxy amine enhanced reactivity and functionality for the synthesis of dual covalent adaptable networks Dimitri Berne , Guilhem Coste , Roberto Morales-Cerrada , Marine Boursier , Julien Pinaud Polymer Chemistry, 2022, 13 (25), pp.3806. ⟨10.1039/d2py00274d⟩ Journal articles hal-03706971v1
	Phosphorus modified cardanol: a greener route to reduce volatile organic compounds and impart flame retardant properties to alkyd resin coatings Maxinne Denis , Damien Le Borgne , Rodolphe Sonnier , Sylvain Caillol , Cédric Totee Molecules, 2022, 27 (15), pp.4880. ⟨10.3390/molecules27154880⟩ Journal articles hal-03741352v1
	Bio-sourced monomers and cationic photopolymerization–The green combination towards eco-friendly and non-toxic materials Lucie Pierau , Christine Elian , Jun Akimoto , Yoshihiro Ito , Sylvain Caillol Progress in Polymer Science, 2022, 127, pp.101517. ⟨10.1016/j.progpolymsci.2022.101517⟩ Journal articles hal-03558759v1
	Thia-Michael Reaction: The Route to Promising Covalent Adaptable Networks ? Dimitri Berne , Vincent Ladmiral , Eric Leclerc , Sylvain Caillol Polymers, 2022, 14, pp.4457. ⟨10.3390/polym14204457⟩ Journal articles hal-03825128v1
	Biobased Composites by Photoinduced Polymerization of Cardanol Methacrylate with Microfibrillated Cellulose Alessandra Vitale , Samant Molina-Gutiérrez , W.S. Jennifer Li , Sylvain Caillol , Vincent Ladmiral Materials, 2022, Photofabrication of Biobased Polymers and Composites, 15, pp.339. ⟨10.3390/ma15010339⟩ Journal articles hal-03513881v1
	Biobased catalyst-free Covalent Adaptable Networks based on CF 3activated synergistic aza-Michael exchange and transesterification Dimitri Berne , Baptiste Quienne , Sylvain Caillol , Eric Leclerc , Vincent Ladmiral Journal of Materials Chemistry A, 2022, 10 (47), pp.25085-25097. ⟨10.1039/d2ta05067f⟩ Journal articles hal-03887709v1
	Synthesis of Hydrophobically modified ethoxylated non-isocyanate urethanes (HENIURs) and their use as rheology additives Baptiste Quienne , Julien Pinaud , Sylvain Caillol European Polymer Journal, 2022, 175, pp.111384. ⟨10.1016/j.eurpolymj.2022.111384⟩ Journal articles hal-03706671v1
	Synthesis of polyester thermosets via internally catalyzed Michael-addition of methylene compounds on a 2-(trifluoromethyl)acrylate-derived building block Dimitri Berne , Sylvain Caillol , Vincent Ladmiral , Eric Leclerc European Polymer Journal, 2022, 175, pp.111362. ⟨10.1016/j.eurpolymj.2022.111362⟩ Journal articles hal-03698974v1
	Synthesis of reactive phosphorus-based carbonate for flame retardant polyhydroxyurethane foams Guilhem Coste , Maxinne Denis , Rodolphe Sonnier , Sylvain Caillol , Claire Negrell-Guirao Polymer Degradation and Stability, 2022, 202, pp.110031-110202. ⟨10.1016/j.polymdegradstab.2022.110031⟩ Journal articles hal-03695980v1
	Thiol-Ene Coupling of High Oleic Sunflower Oil towards Application in the Modification of Flexible Polyurethane Foams Sylwia Dworakowska , Adrien Cornille , Dariusz Bogdal , Bernard Boutevin , Sylvain Caillol Materials, 2022, 15, pp.628. ⟨10.3390/ma15020628⟩ Journal articles hal-03526702v1
	Catalyst-free transesterification vitrimers: activation via α-difluoroesters Florian Cuminet , Dimitri Berne , Sébastien Lemouzy , Éric Dantras , Christine Joly-Duhamel Polymer Chemistry, 2022, 13 (18), pp.2651-2658. ⟨10.1039/d2py00124a⟩ Journal articles hal-03663953v1
	Photochemical [2+2] cycloaddition of biobased latexes for composites with microfibrillated cellulose Sara Dalle Vacche , Samantha Molina-Gutiérrez , Vincent Ladmiral , Sylvain Caillol , Roberta Bongiovanni Chemical Engineering Transactions, 2022, 92, pp.277-282. ⟨10.3303/CET2292047⟩ Journal articles hal-03735509v1
	Non-isocyanate Polyurethane Foams based on Six-membered cyclic Carbonates Guilhem Coste , Dimitri Berne , Vincent Ladmiral , Claire Negrell , Sylvain Caillol European Polymer Journal, 2022, 176, pp.111392. ⟨10.1016/j.eurpolymj.2022.111392⟩ Journal articles hal-03719091v1
	Coordination adaptable networks: zirconium(IV) carboxylates. Meenu Murali , Dimitri Berne , Christine Joly-Duhamel , Sylvain Caillol , Eric Leclerc Chemistry - A European Journal, 2022, 28 (61), pp.e202202058. ⟨10.1002/chem.202202058⟩ Journal articles hal-03739165v1
	Valuing CO2 in the development of polymer materials Abderrahmane Ballamine , Abdellah Kotni , Jean-Pierre Llored , Sylvain Caillol Science and Technology for Energy Transition, 2022, 77, pp.1. ⟨10.2516/stet/2021001⟩ Journal articles hal-03550337v1
	Upcycling biobased polyurethane foams into thermosets: toward the closing of the loop Baptiste Quienne , Florian Cuminet , Julien Pinaud , Mona Semsarilar , Didier Cot ACS Sustainable Chemistry & Engineering, 2022, 10 (21), pp.7041-7049. ⟨10.1021/acssuschemeng.2c00950⟩ Journal articles hal-03681986v1
	Green synthesis of biobased soft foams by Aza-Michael reaction Guilhem Coste , Claire Negrell , Luc Averous , Sylvain Caillol ACS Sustainable Chemistry & Engineering, 2022, 10 (26), pp.8549-8558. ⟨10.1021/acssuschemeng.2c01885⟩ Journal articles hal-03712818v1
	Atmospheric removal of methane by enhancing the natural hydroxyl radical sink Yuyin Wang , Tingzhen Ming , Wei Li , Qingchun Yuan , Renaud de Richter Greenhouse Gases: Science and Technology, 2022, 12 (6), pp.784-795. ⟨10.1002/ghg.2191⟩ Journal articles hal-03884207v1
	Catalyst-Free Epoxy Vitrimers Based on Transesterification Internally Activated by an α–CF 3 Group Dimitri Berne , Florian Cuminet , Sébastien Lemouzy , Christine Joly-Duhamel , Rinaldo Poli Macromolecules, 2022, 55, pp.1669-1679. ⟨10.1021/acs.macromol.1c02538⟩ Journal articles hal-03583794v1
	Solvent-free synthesis of a formaldehyde-free benzoxazine monomer: study of its curing acceleration effect for commercial benzoxazine Romain Tavernier , Lérys Granado , Monique Tillard , Louis van Renterghem , Thomas-Xavier Métro Polymer Chemistry, 2022, 13 (40), pp.5745-5756. ⟨10.1039/d2py00462c⟩ Journal articles hal-03819630v1
	Thermal Degradation of Fluorosilicone Elastomers Emmanuel Richaud , Leticia Pires , Sébastien Roland , Laurianne Truffault , Lucien Laiarinandrasana Macromolecular Symposia, 2022, 405 (1), pp.2100220. ⟨10.1002/masy.202100220⟩ Journal articles hal-03825121v2
	Sustainable design of vanillin-based vitrimers using vinylogous urethane chemistry Stéphanie Engelen , Aleksandra Alicja Wróblewska , Kevin de Bruycker , Resat Aksakal , Vincent Ladmiral Polymer Chemistry, 2022, 13 (18), pp.2665-2673. ⟨10.1039/d2py00351a⟩ Journal articles hal-03663919v1
	Editorial: Like 200 hundred years ago, we need green chemistry and materials to push back the frontiers of science Sylvain Caillol Green materials, 2022, 10 (3), pp.97 - 98. ⟨10.1680/jgrma.2022.10.3.97⟩ Journal articles hal-03787639v1
	Transcarbamoylation in polyurethanes: underestimated exchange reactions? Camille Bakkali-Hassani , Dimitri Berne , Vincent Ladmiral , Sylvain Caillol Macromolecules, 2022, 55 (18), pp.7974-7991. ⟨10.1021/acs.macromol.2c01184⟩ Journal articles hal-03789967v1
	Synergistic effect of DOPO and VMDMS for flame retardancy of alkyd resins Maxinne Denis , Damien Le Borgne , Rodolphe Sonnier , Sylvain Caillol , Claire Negrell Progress in Organic Coatings, 2022, 172, pp.107086. ⟨10.1016/j.porgcoat.2022.107086⟩ Journal articles hal-03750097v1
	CNSL, a Promising Building Blocks for Sustainable Molecular Design of Surfactants: A Critical Review Audrey Roy , Pauline Fajardie , Benedicte B. Lepoittevin , Jérôme Baudoux , Vincent Lapinte Molecules, 2022, 27 (4), pp.1443. ⟨10.3390/molecules27041443⟩ Journal articles hal-03582761v1
	Perspectives on removal of atmospheric methane Tingzhen Ming , Wei Li , Qingchun Yuan , Philip Davies , Renaud de Richter Advances in Applied Energy, 2022, 5, pp.100085. ⟨10.1016/j.adapen.2022.100085⟩ Journal articles hal-03544601v1
	Cascade (Dithio)carbonate Ring Opening Reactions for Self‐Blowing Polyhydroxythiourethane Foams Guilhem Coste , Claire Negrell , Sylvain Caillol Macromolecular Rapid Communications, 2022, Sustainable Green Polymerizations, 43 (13), pp.2100833. ⟨10.1002/marc.202100833⟩ Journal articles hal-03715385v1
	Understanding the reshaping of fluorinated polyester vitrimers by kinetic and DFT studies of the transesterification reaction Sébastien Lemouzy , Florian Cuminet , Dimitri Berne , Sylvain Caillol , Vincent Ladmiral Chemistry - A European Journal, 2022, 28 (48), pp.e202201135. ⟨10.1002/chem.202201135⟩ Journal articles hal-03689286v1
	Synthesis of Diols from Jojoba Oil via Rhodium-Catalyzed Reductive Hydroformylation: a Smart Way to Access Biobased Polyurethanes Chryslain Becquet , Michel Ferreira , Hervé Bricout , Baptiste Quienne , Sylvain Caillol Green Chemistry, 2022, 24 (20), pp.7906-7912. ⟨10.1039/D2GC02534E⟩ Journal articles hal-03820164v1
	Fully Bio-Based Thermosetting Polyurethanes from Bio-Based Polyols and Isocyanates Roberto Morales-Cerrada , Romain Tavernier , Sylvain Caillol Polymers, 2021, 13 (8), pp.1255. ⟨10.3390/polym13081255⟩ Journal articles hal-03197000v1
	A nature-based negative emissions technology able to remove atmospheric methane and other greenhouse gases Tingzhen Ming , Renaud de Richter , Franz Dietrich Oeste , Robert Tulip , Sylvain Caillol Atmospheric Pollution Research, 2021, 12 (5), pp.101035. ⟨10.1016/j.apr.2021.02.017⟩ Journal articles hal-03222327v1
	Neighboring Group Participation and internal catalysis effects on exchangeable covalent bonds: Application to the thriving field of vitrimers chemistry Florian Cuminet , Sylvain Caillol , Éric Dantras , Eric Leclerc , Vincent Ladmiral Macromolecules, 2021, 54 (9), pp.3927-3961. ⟨10.1021/acs.macromol.0c02706⟩ Journal articles hal-03224634v1
	Surfactant properties of chemically modified chitooligosaccharides and their potential application in bitumen emulsions Camille Chapelle , Ghislain David , Sylvain Caillol , Claire Negrell , Sylvain Catrouillet Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2021, 628, pp.127327. ⟨10.1016/j.colsurfa.2021.127327⟩ Journal articles hal-03325899v1
	Enhanced aminolysis of cyclic carbonates by β-hydroxyamines for fully biobased polyhydroxyurethanes Baptiste Quienne , Rinaldo Poli , Julien Pinaud , Sylvain Caillol Green Chemistry, 2021, 23 (4), pp.1678-1690. ⟨10.1039/d0gc04120c⟩ Journal articles hal-03155254v1
	Diels-Alder-Chitosan based dissociative covalent adaptable networks Camille Chapelle , Baptiste Quienne , Céline Bonneaud , Ghislain David , Sylvain Caillol Carbohydrate Polymers, 2021, 253, pp.117222. ⟨10.1016/j.carbpol.2020.117222⟩ Journal articles hal-02985047v1
	Functionalization of Chitosan Oligomers: From Aliphatic Epoxide to Cardanol-Grafted Oligomers for Oil-in-Water Emulsions Camille Chapelle , Ghislain David , Sylvain Caillol , Claire Negrell , Graziella Durand Biomacromolecules, 2021, 22 (2), pp.846-854. ⟨10.1021/acs.biomac.0c01576⟩ Journal articles hal-03134434v1
	Editorial Special Issue “Natural Polymers and Biopolymers II” Sylvain Caillol Molecules, 2021, Natural Polymers and Biopolymers II, 26, pp.112. ⟨10.3390/molecules26010112⟩ Journal articles hal-03090125v1
	Bio-based poly(ester- alt -thioether)s synthesized by organo-catalyzed ring-opening copolymerizations of eugenol-based epoxides and N -acetyl homocysteine thiolactone Simon Le Luyer , Baptiste Quienne , Matthieu Bouzaid , Philippe Guégan , Sylvain Caillol Green Chemistry, 2021, 23 (19), pp.7743-7750. ⟨10.1039/D1GC02138A⟩ Journal articles hal-03359482v2
	Special Issue: 1 st French-Japanese Symposium: Recent Progress and Challenges in Polymer Science Editorial Vincent Ladmiral , Sylvain Caillol European Polymer Journal, 2021, 149, pp.110392. ⟨10.1016/j.eurpolymj.2021.110392⟩ Journal articles hal-03164526v1
	Terpenoid-derived conjugated dienes with exo-methylene and 6membered ring: high cationic reactivity, regioselective living cationic polymerization, and random and block copolymerization with vinyl ethers Takenori Nishida , Kotaro Satoh , Masazumi Tamura , Yingai Li , Keiichi Tomishige Polymer Chemistry, 2021, 12 (9), pp.1186-1198. ⟨10.1039/d1py00035g⟩ Journal articles hal-03163687v1
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	A chemical platform approach on cardanol oil: from the synthesis of building blocks to polymer synthesis Fanny Jaillet , Emilie Darroman , Bernard Boutevin , Sylvain Caillol OCL Oilseeds and fats crops and lipids, 2016, 23 (5), pp.511-518. ⟨10.1051/ocl/2016022⟩ Journal articles hal-01379610v1
	Lignin-derivednon-toxicaldehydesforecofriendlytanninadhesives for woodpanels Francisco Santiago-Medina , Gabriel Foyer , Antonio Pizzi , Sylvain Caillol , Luc Delmotte International Journal of Adhesion and Adhesives, 2016, 70, pp.239-248. ⟨10.1016/j.ijadhadh.2016.07.002⟩ Journal articles hal-01348982v1
	Synthesis of novel vinylester from biobased phloroglucinol Fanny Jaillet , Hélène Nouailhas , Bernard Boutevin , Sylvain Caillol Green materials, 2016, 4 (2), pp.63-71. ⟨10.1680/jgrma.16.00005⟩ Journal articles hal-01351732v1
	Fighting global warming by greenhouse gas removal: destroying atmospheric nitrous oxide thanks to synergies between two breakthrough technologies Tingzhen Ming , Renaud de Richter , Shen Sheng , Sylvain Caillol Environmental Science and Pollution Research, 2016, 23, pp.6119-6138. ⟨10.1007/s11356-016-6103-9⟩ Journal articles hal-01261267v1
	Diels–Alder thermoreversible isocyanate-free polyurethanes Dolci Elena , Guillaume Michaud , Frédéric Simon , Stéphane Fouquay , Rémi Auvergne Green materials, 2016, 4, pp.160-170. ⟨10.1680/jgrma.16.00018⟩ Journal articles hal-01440970v1

Sylvain Caillol

Presentation

Publications

4-Vinyl Guaiacol: A Key Intermediate for Biobased Polymers

Understanding associative polymer self-assembly with shrinking gate fluorescence correlation spectroscopy

Evaluation of Porous (Poly(lactide-co-glycolide)-co-(ε-caprolactone)) Polyurethane for Use in Orthopedic Scaffolds

Phosphorus acid: an asset for flame-retardant sustainable vitrimers

Ring‐opening (co)polymerization of cardanol glycidyl ether

Sustainable polyurethanes: toward new cutting-edge opportunities

Closed-loop recyclability of a biomass-derived epoxy-amine thermoset by methanolysis

Flame-retardant performance of phosphorylated furan-containing alkyd resins

Hafnium coordination vitrimer based on carboxylate exchange: synthesis, properties, and mechanistic investigations on the [Hf 6 O 4 (OH) 4 (O 2 CMe) 12 ] 2 model compound

Collagen/polyester-polyurethane porous scaffolds for use in meniscal repair

On Sustainability Aspects of the Synthesis of Five-Membered Cyclic Carbonates

Fully bio-sourced catalyst-free covalent adaptable networks from epoxidized soybean oil and L-tartaric acid

Adhesion theories: A didactic review about a century of progress

Biobased Composites from Eugenol- and Coumarin-Derived Methacrylic Latex and Hemp Nanocellulose: Cross-Linking via [2 + 2] Photocycloaddition and Barrier Properties

Combination of Fluorine and Tertiary Amine Activation in Catalyst-Free Thia-Michael Covalent Adaptable Networks

Recent advances in radical polymerization of bio-based monomers in aqueous dispersed media

One Step Closer to Coatings Applications Utilizing Self-Stratification: Effect of Rheology Modifiers

Bio-sourced alternatives to diglycidyl ether of bisphenol A in epoxy–amine thermosets

Editorial: 2023 is a remarkable year for green chemistry and Green Materials

Lignin-based Bisguaiacol diisocyanate: a green route for the synthesis of biobased polyurethanes

From vineyards to reshapable materials: α-CF 2 activation in 100% resveratrol-based catalyst-free vitrimers

From natural phenols to biobased epoxy resins

Photoactivable alizarin and eugenol-based materials for antibacterial applications

A Blooming Season for Natural Polymers and Biopolymers

Catalyst‐Free Thia‐Michael Addition to alpha‐Trifluoromethylacrylates for 3D Network Synthesis

Influence of Phosphorus Structures and Their Oxidation States on Flame-Retardant Properties of Polyhydroxyurethanes

Cardanol: a small giant of the future of biobased aromatic polymers and additives

Polyhydroxyurethane Covalent Adaptable Networks: Looking for Suitable Catalysts

Des résines alkydes hydrides aux propriétés ignifugeantes pour la formulation de revêtements

Understanding glycidylation reaction for the formation of pure mono, diglycidyl and dual monomers as glycidyl methacrylate of vanillyl alcohol

Dynamic PEG-PLA/hydroxyurethane networks based on imine bonds as reprocessable elastomeric biomaterials

Synthesis and characterization of original fluorinated bis-cyclic carbonates and xanthates from a fluorinated epoxide

Transamidation vitrimers enabled by neighboring fluorine atom activation

Triple Benefits of Cardanol as Chain Stopper, Flame Retardant and Reactive Diluent for Greener Alkyd Coating

Dihydroxyacetone: A User Guide for a Challenging Bio-Based Synthon

Synthesis of a transesterification vitrimer activated by fluorine from an α,αdifluoro carboxylic acid and a diepoxy

How phosphinated hydroxyurethane groups improve chemical resistance and flame retardant properties of alkyd resins?

Hydroxyurethane modifiers (HUM): an environmentally-friendly route to improve chemical resistance of alkyd coatings

Eco-Friendly Synthesis of Cardanol-Based AB Monomer for Formaldehyde-Free Phenolic Thermosets

Paving the Way towards Sustainability of Polyurethanes: Synthesis and Properties of Terpene-Based Diisocyanate

Editorial: Green materials, a growing science and industry!

Cardanol-modified alkyd resins: novel route to make greener alkyd coatings

Editorial: Green chemistry and green materials evolve in a changing world

Taking advantage of β-hydroxy amine enhanced reactivity and functionality for the synthesis of dual covalent adaptable networks

Phosphorus modified cardanol: a greener route to reduce volatile organic compounds and impart flame retardant properties to alkyd resin coatings

Bio-sourced monomers and cationic photopolymerization–The green combination towards eco-friendly and non-toxic materials

Thia-Michael Reaction: The Route to Promising Covalent Adaptable Networks ?

Biobased Composites by Photoinduced Polymerization of Cardanol Methacrylate with Microfibrillated Cellulose

Biobased catalyst-free Covalent Adaptable Networks based on CF 3activated synergistic aza-Michael exchange and transesterification

Synthesis of Hydrophobically modified ethoxylated non-isocyanate urethanes (HENIURs) and their use as rheology additives

Synthesis of polyester thermosets via internally catalyzed Michael-addition of methylene compounds on a 2-(trifluoromethyl)acrylate-derived building block

Synthesis of reactive phosphorus-based carbonate for flame retardant polyhydroxyurethane foams

Thiol-Ene Coupling of High Oleic Sunflower Oil towards Application in the Modification of Flexible Polyurethane Foams

Catalyst-free transesterification vitrimers: activation via α-difluoroesters

Photochemical [2+2] cycloaddition of biobased latexes for composites with microfibrillated cellulose

Non-isocyanate Polyurethane Foams based on Six-membered cyclic Carbonates

Coordination adaptable networks: zirconium(IV) carboxylates.

Valuing CO2 in the development of polymer materials

Upcycling biobased polyurethane foams into thermosets: toward the closing of the loop

Green synthesis of biobased soft foams by Aza-Michael reaction

Atmospheric removal of methane by enhancing the natural hydroxyl radical sink

Catalyst-Free Epoxy Vitrimers Based on Transesterification Internally Activated by an α–CF 3 Group

Solvent-free synthesis of a formaldehyde-free benzoxazine monomer: study of its curing acceleration effect for commercial benzoxazine

Thermal Degradation of Fluorosilicone Elastomers

Sustainable design of vanillin-based vitrimers using vinylogous urethane chemistry

Editorial: Like 200 hundred years ago, we need green chemistry and materials to push back the frontiers of science

Transcarbamoylation in polyurethanes: underestimated exchange reactions?

Synergistic effect of DOPO and VMDMS for flame retardancy of alkyd resins

CNSL, a Promising Building Blocks for Sustainable Molecular Design of Surfactants: A Critical Review

Perspectives on removal of atmospheric methane

Cascade (Dithio)carbonate Ring Opening Reactions for Self‐Blowing Polyhydroxythiourethane Foams

Understanding the reshaping of fluorinated polyester vitrimers by kinetic and DFT studies of the transesterification reaction

Synthesis of Diols from Jojoba Oil via Rhodium-Catalyzed Reductive Hydroformylation: a Smart Way to Access Biobased Polyurethanes

Fully Bio-Based Thermosetting Polyurethanes from Bio-Based Polyols and Isocyanates

A nature-based negative emissions technology able to remove atmospheric methane and other greenhouse gases

Neighboring Group Participation and internal catalysis effects on exchangeable covalent bonds: Application to the thriving field of vitrimers chemistry

Surfactant properties of chemically modified chitooligosaccharides and their potential application in bitumen emulsions