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thierry Brotin

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Understanding the surrounding effects on Raman optical activity signatures of a chiral cage system: Cryptophane-PP-111

Lou C.G. D’haese , Nicolas Daugey , Delphine Pitrat , Thierry Brotin , Josef Kapitán
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy [1994-..], 2024, 306, pp.123484. ⟨10.1016/j.saa.2023.123484⟩
Journal articles hal-04267790v1

A Water-Soluble Cryptophane Decorated with Aromatic Amine Groups Shows High Affinity for Cesium and Thallium(I)

Rajaa Benchouaia , Martin Doll , Patrick Berthault , Kévin Chighine , Estelle Léonce
Journal of Organic Chemistry, 2024, ⟨10.1021/acs.joc.3c02791⟩
Journal articles hal-04524120v1
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Subtle Stereochemical Effects Influence Binding and Purification Abilities of an Fe II 4 L 4 Cage

Weichao Xue , Luca Pesce , Adinarayana Bellamkonda , Tanya K Ronson , Kai Wu
Journal of the American Chemical Society, 2023, 145 (9), pp.5570-5577. ⟨10.1021/jacs.3c00294⟩
Journal articles hal-04216375v1
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Allosterically Regulated Guest Binding Determines Framework Symmetry for an Fe II 4 L 4 Cage

Weichao Xue , Kai Wu , Nianfeng Ouyang , Thierry Brotin , Jonathan R Nitschke
Angewandte Chemie International Edition, 2023, 62 (18), pp.e202301319. ⟨10.1002/anie.202301319⟩
Journal articles hal-04218728v1
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Access to the Syn diastereomers of cryptophane cages using HFIP

Oriane Della-Negra , Yoann Cirillo , Thierry Brotin , Jean-Pierre Dutasta , Pierre-Loic Saaidi
Chemical Communications, 2022, 58 (20), pp.3330-3333. ⟨10.1039/D1CC06607B⟩
Journal articles hal-03850423v1
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Impact of the Syn / Anti Relative Configuration of Cryptophane-222 on the Binding Affinity of Cesium and Thallium

Thierry Brotin , Patrick Berthault , Kévin Chighine , Erwann Jeanneau
ACS Omega, 2022, 7 (51), pp.48361-48371. ⟨10.1021/acsomega.2c06570⟩
Journal articles hal-04194498v1
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Study of syn and anti Xenon-Cryptophanes Complexes Decorated with Aromatic Amine Groups: Chemical Platforms for Accessing New Cryptophanes

Martin Doll , Patrick Berthault , Estelle Léonce , Céline Boutin , Erwann Jeanneau
Journal of Organic Chemistry, 2022, 87 (5), pp.2912-2920. ⟨10.1021/acs.joc.1c02774⟩
Journal articles hal-03850410v1
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Are the physical properties of Xe@cryptophane complexes easily predictable? the case of $syn$ and $anti$ tris-$aza$-cryptophanes

Martin Doll , Patrick Berthault , Estelle Léonce , Céline Boutin , Thierry Buffeteau
Journal of Organic Chemistry, 2021, 86 (11), pp.7648-7658. ⟨10.1021/acs.joc.1c00701⟩
Journal articles cea-03250187v1
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Enantiopure Cryptophane Derivatives: Synthesis and Chiroptical Properties

Orsola Baydoun , Thierry Buffeteau , T. Brotin
Chirality, In press, ⟨10.1002/chir.23347⟩
Journal articles hal-03342930v1
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Thermodynamic Contribution of Water in Cryptophane Host–Guest Binding Reaction

Daryl K Eggers , Sherry Fu , Dominic V Ngo , Elizabeth H Vuong , T. Brotin
Journal of Physical Chemistry B, 2020, 124 (30), pp.6585-6591. ⟨10.1021/acs.jpcb.0c05354⟩
Journal articles hal-03343470v1
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Selective Capture of Thallium and Cesium by a Cryptophane Soluble at Neutral pH

Thierry Brotin , Patrick Berthault , Delphine Pitrat , Jean-Christophe Mulatier
Journal of Organic Chemistry, 2020, 85, pp.9622-9630. ⟨10.1021/acs.joc.0c00950⟩
Journal articles cea-02883381v1
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Diastereomeric stilbenoid glucoside dimers from the rhizomes of Gnetum africanum

Julien Gabaston , Thierry Buffeteau , Thierry Brotin , Jonathan Bisson , Caroline Rouger
Phytochemistry Letters, 2020, 39, pp.151-156. ⟨10.1016/j.phytol.2020.08.004⟩
Journal articles hal-03016445v1

Synthesis of Cryptophane-223-Type Derivatives with Dual Functionalization

Orsola Baydoun , Nicolas de Rycke , Estelle Léonce , Céline Boutin , Patrick Berthault
Journal of Organic Chemistry, 2019, 84, pp.9127-9137. ⟨10.1021/acs.joc.9b01093⟩
Journal articles cea-02183121v1
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Chiroptical study of cryptophanes subjected to self‐encapsulation

Orsola Baydoun , Thierry Buffeteau , Nicolas Daugey , Marion Jean , Nicolas Vanthuyne
Chirality, 2019, ⟨10.1002/chir.23079⟩
Journal articles hal-02141856v1
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Enantiopure [Cs$^+$/Xe$\subset$Cryptophane]$\subset$Fe$^{II}$$_4$L$_4$ Hierarchical Superstructures

Dawei Zhang , Tanya K. Ronson , Jake L. Greenfield , Thierry Brotin , Patrick Berthault
Journal of the American Chemical Society, 2019, 141 (20), pp.8339-8345. ⟨10.1021/jacs.9b02866⟩
Journal articles cea-02117134v1
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Bioinspired Oxidation of Methane in the Confined Spaces of Molecular Cages

Sk Asif Ikbal , Cédric Colomban , Dawei Zhang , Magalie Delecluse , Thierry Brotin
Inorganic Chemistry, 2019, 58 (11), pp.7220-7228. ⟨10.1021/acs.inorgchem.9b00199⟩
Journal articles hal-02129474v1
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Bimodal detection of proteins by $^{129}$Xe NMR and fluorescence spectroscopy

Emilie Mari , Yasmina Bousmah , Céline Boutin , Estelle Léonce , Gaëlle Milanole
ChemBioChem, 2019, 20, pp.1450-1457. ⟨10.1002/cbic.201800802⟩
Journal articles cea-01988479v1
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Chiroptical properties of 2,2’-bioxirane

Nicolas Daugey , Nicolas de Rycke , T. Brotin , T. Buffeteau
Chirality, 2018, 30 (4), pp.342-350. ⟨10.1002/chir.22814⟩
Journal articles hal-01962169v1
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Optimized Continuous Application of Hyperpolarized Xenon to Liquids

B. Niederländer , P. Blümler , T. Brotin , D. van Dusschoten , A. Offenhäusser
Journal of Physical Chemistry A, 2018, 122 (48), pp.9359-9369. ⟨10.1021/acs.jpca.8b09479⟩
Journal articles hal-02322503v1
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Synthesis of Cryptophane-B. Crystal Structure and Study of its Complex with Xenon.

Thierry Brotin , Erwann Jeanneau , Patrick Berthault , Estelle Léonce , Delphine Pitrat
Journal of Organic Chemistry, 2018, 83, pp.14465-14471. ⟨10.1021/acs.joc.8b02246⟩
Journal articles cea-01922217v1
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Accurate pH sensing via hyperpolarized $^{129}$Xe NMR

Patrick Berthault , Estelle Léonce , Jean-Pierre Dognon , Delphine Pitrat , Jean-Christophe Mulatier
Chemistry - A European Journal, inPress, 24, pp.6534-6537. ⟨10.1002/chem.201800900⟩
Journal articles cea-01720386v1
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Enantioselective Complexation of Chiral Oxirane Derivatives by an Enantiopure Cryptophane in Water

Nicolas de Rycke , Marion Jean , Nicolas Vanthuyne , Thierry Buffeteau , T. Brotin
European Journal of Organic Chemistry, 2018, 2018 (13), pp.1601-1607. ⟨10.1002/ejoc.201800142⟩
Journal articles hal-01955471v1
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Bimodal Fluorescence/{129}Xe NMR Probe for Molecular Imaging and Biological Inhibition of EGFR in Non-Small Cell Lung Cancer

Gaëlle Milanole , Bo Gao , Audrey Paoletti , Grégory Pieters , Christophe Dugave
Bioorganic and Medicinal Chemistry, 2017, 25, pp.6653-6660. ⟨10.1016/j.bmc.2017.11.002⟩
Journal articles cea-01630103v1
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Role of the Methoxy Groups in Cryptophanes for Complexation of Xenon. Conformational Selection Evidenced by 129 Xe-1 H NMR SPINOE Experiments

Patrick Berthault , Céline Boutin , Estelle Léonce , Erwann Jeanneau , Thierry Brotin
ChemPhysChem, 2017, 18, pp.1561-1568. ⟨10.1002/cphc.201700266⟩
Journal articles cea-01510320v1
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Experimental and Theoretical Study of the Complexation of Cesium and Thallium Cations by a Water-Soluble Cryptophane

Laure-Lise Chapellet , Jean-Pierre Dognon , Marion Jean , Nicolas Vanthuyne , Patrick Berthault
ChemistrySelect, 2017, 2, pp.5292-5300. ⟨10.1002/slct.201700979⟩
Journal articles cea-01556375v1
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Chiroptical properties of cryptophane-111

Thierry Buffeteau , Delphine Pitrat , Nicolas Daugey , Nathalie Calin , Marion Jean
Physical Chemistry Chemical Physics, 2017, 19 (28), pp.18303 - 18310. ⟨10.1039/c7cp02045g⟩
Journal articles hal-01682735v1
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Unsaturated cryptophanes: toward dual PHIP/hyperpolarised xenon sensors

Gaspard Huber , Estelle Léonce , Orsola Baydoun , Nicolas de Rycke , Thierry Brotin
Magnetic Resonance in Chemistry, inPress, 56, pp.672-678. ⟨10.1002/mrc.4691⟩
Journal articles cea-01660523v1

Immobilization of Cryptophane Derivatives onto γ-Fe 2 O 3 Core–Shell Magnetic Nanoparticles

Elise Siurdyban , Thierry Brotin , David Talaga , Karine Heuzé , Luc Vellutini
Journal of Physical Chemistry C, 2016, 120 (12), pp.6583 - 6590. ⟨10.1021/acs.jpcc.5b12514⟩
Journal articles hal-01896315v1

Unusual Chiroptical Properties of the Cryptophane-222 Skeleton

Delphine Pitrat , Nicolas Daugey , Marion Jean , Nicolas Vanthuyne , Frank Wien
Journal of Physical Chemistry B, 2016, 120 (49), pp.12650-12659. ⟨10.1021/acs.jpcb.6b09771⟩
Journal articles hal-01412985v1
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A doubly responsive probe for the detection of Cys4-tagged proteins

Naoko Kotera , Emmanuelle Dubost , Gaëlle Milanole , Eric Doris , Edmond Gravel
Chemical Communications, 2015, 51, pp.11482-11484. ⟨10.1039/C5CC04721H⟩
Journal articles hal-01187782v1

Investigation of chloromethane complexes of cryptophane-A analogue with butoxy groups using C-13 NMR in the solid state and solution along with single crystal X-ray diffraction

Emilie Steiner , Renny Mathew , Iwan Zimmermann , Thierry Brotin , Mattias Edén
Magnetic Resonance in Chemistry, 2015, 53 (8), pp.596-602. ⟨10.1002/mrc.4265⟩
Journal articles hal-01234423v1

Synthesis of cryptophanes With Two Different Reaction Sites: Chemical Platforms for Xenon Biosensing

Laure-Lise Chapellet , James Robert Cochrane , Emilie Mari , Céline Boutin , Patrick Berthault
Journal of Organic Chemistry, 2015, 80, pp.6143-6151. ⟨10.1021/acs.joc.5b00653⟩
Journal articles hal-01187801v1

Chemical Shielding Anisotropies for Chloroform Exchanging between a Free Site and a Complex with Cryptophane-D: A Cross-Correlated NMR Relaxation Study

Emilie Steiner , Thierry Brotin , Zoltan Takacs , Jozef Kowalewski
Journal of Physical Chemistry B, 2015, 119 (35), pp.11760-11767. ⟨10.1021/acs.jpcb.5b05218⟩
Journal articles hal-01234422v1

Chiroptical Properties of Cryptophane-223 and -233 Investigated by ECD, VCD, and ROA Spectroscopy

Thierry Brotin , Nicolas Daugey , Nicolas Vanthuyne , Erwann Jeanneau , Laurent Ducasse
Journal of Physical Chemistry B, 2015, 119 (27), pp.8631-8639. ⟨10.1021/acs.jpcb.5b04539⟩
Journal articles hal-01234424v1

NMR Investigation of Chloromethane Complexes of Cryptophane-A and Its Analogue with Butoxy Groups

Z. Takacs , E. Steiner , J. Kowalewski , T. Brotin
Journal of Physical Chemistry B, 2014, 118 (8), pp.2134 - 2146. ⟨10.1021/jp4105272⟩
Journal articles hal-01896756v1

Chiroptical Properties of Nona- and Dodecamethoxy Cryptophanes

Thierry Brotin , Nicolas Vanthuyne , Dominique Cavagnat , Laurent Ducasse , Thierry Buffeteau
Journal of Organic Chemistry, 2014, 79 (13), pp.6028 - 6036. ⟨10.1021/jo500621g⟩
Journal articles hal-01889531v1

Raman Optical Activity of Enantiopure Cryptophanes

Nicolas Daugey , Thierry Brotin , Nicolas Vanthuyne , Dominique Cavagnat , Thierry Buffeteau
Journal of Physical Chemistry B, 2014, 118 (19), pp.5211 - 5217. ⟨10.1021/jp502652p⟩
Journal articles hal-01889532v1

Smart Detection of Toxic Metal Ions, Pb2+ and Cd2+, Using a 129Xe NMR-Based Sensor

Nawal Tassali , Naoko Kotera , Céline Boutin , Estelle Léonce , Yves Boulard
Analytical and Bioanalytical Chemistry, 2014, 86 (3), pp.1783-1788. ⟨10.1021/ac403669p⟩
Journal articles hal-01117441v1

Immobilization of Cryptophane Derivatives onto SiO 2 /Au and Au Substrates

Elise Siurdyban , Thierry Brotin , Karine Heuzé , Luc Vellutini , Thierry Buffeteau
Langmuir, 2014, 30 (49), pp.14859 - 14867. ⟨10.1021/la5039156⟩
Journal articles hal-01896769v1

Synthesis of Highly Substituted Cryptophane Derivatives

Thierry Brotin , Dominique Cavagnat , Erwann Jeanneau , Thierry Buffeteau
Journal of Organic Chemistry, 2013, 78 (12), pp.6143 - 6153. ⟨10.1021/jo4007738⟩
Journal articles hal-01896992v1

Cryptophanes

Thierry Brotin , Jean-Pierre Dutasta
Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, 2013, Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, pp.1. ⟨10.1016/B978-0-12-409547-2.05605-5⟩
Journal articles hal-01117268v1

Enantiopure Supramolecular Cages: Synthesis and Chiral Recognition Properties

Thierry Brotin , Laure Guy , Alexandre Martinez , Jean-Pierre Dutasta
Topics in current chemistry, 2013, 341, pp.177-230. ⟨10.1007/128_2013_487⟩
Journal articles hal-01117438v1

Influence of the Cavity Size of Water-Soluble Cryptophanes on Their Binding Properties for Cesium and Thallium Cations

Thierry Brotin , Sylvie Goncalves , Patrick Berthault , Dominique Cavagnat , Thierry Buffeteau
Journal of Physical Chemistry B, 2013, 117 (41), pp.12593 - 12601. ⟨10.1021/jp4074009⟩
Journal articles hal-01889527v1

Host-guest complexes between cryptophane-C and chloromethanes revisited

Z. Takacs , M. Soltesova , J. Kowalewski , Jérôme Lang , Thierry Brotin
Magnetic Resonance in Chemistry, 2013, 51 (1), pp.19-31. ⟨10.1002/mrc.3898⟩
Journal articles hal-01117199v1

Ultrafast Z-Spectroscopy for 129 Xe NMR-Based Sensors

Céline Boutin , Estelle Léonce , Thierry Brotin , Alexej Jerschow , Patrick Berthault
Journal of Physical Chemistry Letters, 2013, 4 (23), pp.4172 - 4176. ⟨10.1021/jz402261h⟩
Journal articles hal-01896791v1

Inclusion of Chloromethane Guests Affects Conformation and Internal Dynamics of Cryptophane-D Host

Zoltan Takacs , Thierry Brotin , Jean-Pierre Dutasta , Jan Lang , Guido Todde
Journal of Physical Chemistry B, 2012, 116 (27), pp.7898 - 7913. ⟨10.1021/jp303469x⟩
Journal articles hal-01896993v1

Water-Soluble Molecular Capsule for the Complexation of Cesium and Thallium Cations

Thierry Brotin , Dominique Cavagnat , Patrick Berthault , Roland Montserret , Thierry Buffeteau
Journal of Physical Chemistry B, 2012, 116 (35), pp.10905 - 10914. ⟨10.1021/jp305110k⟩
Journal articles hal-01889595v1

A Sensitive Zinc-Activated 129Xe MRI Probe

Naoko Kotera , Nawal Tassali , Estelle Léonce , Céline Boutin , Patrick Berthault
Angewandte Chemie International Edition, 2012, 51 (17), pp.4100-4103. ⟨10.1002/anie.201109194⟩
Journal articles hal-01117150v1

Enantioselective Complexation of Chiral Propylene Oxide by an Enantiopure Water-Soluble Cryptophane

Aude Bouchet , Thierry Brotin , Mathieu Linares , Hans Agren , Dominique Cavagnat
Journal of Organic Chemistry, 2011, 76 (10), pp.4178 - 4181. ⟨10.1021/jo200519r⟩
Journal articles hal-01889599v1

Conformational Effects Induced by Guest Encapsulation in an Enantiopure Water-Soluble Cryptophane

Aude Bouchet , Thierry Brotin , Mathieu Linares , Hans Ågren , Dominique Cavagnat
Journal of Organic Chemistry, 2011, 76 (5), pp.1372 - 1383. ⟨10.1021/jo102350g⟩
Journal articles hal-01898934v1

Cell uptake of a biosensor detected by hyperpolarized 129Xe NMR: The transferrin case

Céline Boutin , Antoine Stopin , Fatimazohra Lenda , Thierry Brotin , Jean-Pierre Dutasta
Bioorganic and Medicinal Chemistry, 2011, 19 (13), pp.4135-4143. ⟨10.1016/j.bmc.2011.05.002⟩
Journal articles hal-01116905v1

Influence of the Chemical Structure of Water-Soluble Cryptophanes on Their Overall Chiroptical and Binding Properties

Aude Bouchet , Thierry Brotin , Mathieu Linares , Dominique Cavagnat , Thierry Buffeteau
Journal of Organic Chemistry, 2011, 76 (19), pp.7816 - 7825. ⟨10.1021/jo201167w⟩
Journal articles hal-01889602v1

NMR investigation of guest-host complex between chloroform and cryptophane C

Z. Takacs , M. Šoltésová , D. Kotsyubynskyy , J. Kowalewski , Jérôme Lang
Magnetic Resonance in Chemistry, 2010, pp.623-629. ⟨10.1002/mrc.2637⟩
Journal articles hal-01116897v1

Induced Chiroptical Changes of a Water-Soluble Cryptophane by Encapsulation of Guest Molecules and Counterion Effects

Aude Bouchet , Thierry Brotin , Dominique Cavagnat , Thierry Buffeteau
Chemistry - A European Journal, 2010, 16 (15), pp.4507 - 4518. ⟨10.1002/chem.200902740⟩
Journal articles hal-01889622v1

A Water-Soluble Xe@cryptophane-111 Complex Exhibits Very High Thermodynamic Stability and a Peculiar 129Xe NMR Chemical Shift

Robert M. Fairchild , Akil I. Joseph , K. Travis Holman , Heather A. Fogarty , Thierry Brotin
Journal of the American Chemical Society, 2010, 132 (44), pp.15505-15507. ⟨10.1021/ja1071515⟩
Journal articles hal-01116900v1

Effect of pH and Counterions on the Encapsulation Properties of Xenon in Water-Soluble Cryptophanes

Patrick Berthault , Hervé Desvaux , Thierry Wendlinger , Marina Gyejacquot , Antoine Stopin
Chemistry - A European Journal, 2010, 16 (43), pp.12941-12946. ⟨10.1002/chem.201001170⟩
Journal articles hal-01116898v1

Encapsulation of Small Gas Molecules by Cryptophane-111 in Organic Solution. 1. Size- and Shape-Selective Complexation of Simple Hydrocarbons

Kathleen E. Chaffee , Heather A. Fogarty , Thierry Brotin , Boyd M. Goodson , Jean-Pierre Dutasta
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 2009, 113 (49), pp.13675-13684. ⟨10.1021/jp903452k⟩
Journal articles hal-01116892v1

Cryptophanes and Their Complexes—Present and Future

Thierry Brotin , Jean-Pierre Dutasta
Chemical Reviews, 2009, 109 (1), pp.88-130. ⟨10.1021/cr0680437⟩
Journal articles hal-01116835v1

Studies of Inclusion Complexes of Dichloromethane in Cryptophanes by Exchange Kinetics and 13 C NMR in Solution and the Solid State

S. Nikkhou Aski , A. Lo , T. Brotin , J. Dutasta , M. Edén
Journal of Physical Chemistry C, 2008, 112 (36), pp.13873 - 13881. ⟨10.1021/jp8039498⟩
Journal articles hal-01889741v1

Conformational Changes in Cryptophane Having C 1 -Symmetry Studied by Vibrational Circular Dichroism

Thierry Brotin , Dominique Cavagnat , Thierry Buffeteau
Journal of Physical Chemistry A, 2008, 112 (36), pp.8464 - 8470. ⟨10.1021/jp804450w⟩
Journal articles hal-01889735v1

Synthesis and Chiroptical Properties of Cryptophanes Having C 1 -Symmetry

Dominique Cavagnat , Thierry Buffeteau , Thierry Brotin
Journal of Organic Chemistry, 2008, 73 (1), pp.66 - 75. ⟨10.1021/jo701662w⟩
Journal articles hal-01889644v1

Optimization of Xenon Biosensors for Detection of Protein Interactions

Thomas Lowery , Sandra García , Lana Chavez , E. Janette Ruiz , Tom Wu
ChemBioChem, 2006, 7 (1), pp.65 - 73. ⟨10.1002/cbic.200500327⟩
Journal articles hal-01906225v1

Water Soluble Cryptophanes Showing Unprecedented Affinity for Xenon: Candidates as NMR-Based Biosensors

Gaspard Huber , Thierry Brotin , Lionel Dubois , Hervé Desvaux , Jean-Pierre Dutasta
Journal of the American Chemical Society, 2006, 128 (18), pp.6239 - 6246. ⟨10.1021/ja060266r⟩
Journal articles hal-01897101v1

Vibrational circular dichroism study of optically pure cryptophane-A

Thierry Buffeteau , Dominique Cavagnat , Thierry Brotin , Jean-Pierre Dutasta
Journal of the American Chemical Society, 2006, 128, pp.5533-5540. ⟨10.1021/ja0603148⟩
Journal articles hal-00109886v1

Improved Synthesis of Functional CTVs and Cryptophanes Using Sc(OTf) 3 as Catalyst

Thierry Brotin , Vincent Roy , Jean-Pierre Dutasta
Journal of Organic Chemistry, 2005, 70 (16), pp.6187 - 6195. ⟨10.1021/jo050495g⟩
Journal articles hal-01906921v1

Raman Microspectrometry as a New Approach to the Investigation of Molecular Recognition in Solids: Chloroform-Cryptophane Complexes

Dominique Cavagnat , Thierry Brotin , Jean-Luc Bruneel , Jean-Pierre Dutasta , Alain Thozet
The Journal of physical chemistry, 2004, 108, pp.5572 -5581. ⟨10.1021/jp0375158S1089-5647(03)07515-1⟩
Journal articles hal-00018724v1

Synthesis and application of cryptophanol hosts: 129Xe NMR spectroscopy of a deuterium-labeled (Xe)2@bis-cryptophane complex

Magali Darzac , Thierry Brotin , Laurence Rousset-Arzel , Denis Bouchu , Jean-Pierre Dutasta
New Journal of Chemistry, 2004, 28 (4), ⟨10.1039/b312979a⟩
Journal articles hal-01907030v1

Raman Microspectrometry as a New Approach to the Investigation of Molecular Recognition in Solids: Chloroform−Cryptophane Complexes

Dominique Cavagnat , Thierry Brotin , Jean-Luc Bruneel , Jean-Pierre Dutasta , Alain Thozet
Journal of Physical Chemistry B, 2004, 108 (18), pp.5572 - 5581. ⟨10.1021/jp0375158⟩
Journal articles hal-01907027v1

Magnetic chiroptical effects in surface second harmonic reflection

Marie-Claire Schanne-Klein , François Hache , Thierry Brotin , Chantal Andraud , A. Collet
Chemical Physics Letters, 2001, 338 (2-3), pp.159-166. ⟨10.1016/S0009-2614(01)00275-5⟩
Journal articles hal-00837026v1

Formation of cryptophanes from their precursors as viewed by liquid secondary ion mass spectrometry.

Thierry Brotin , M. Darzac , D. Forest , M. Becchi , Jp Dutasta
Journal of Mass Spectrometry, 2001, 36, pp.1092-1097
Journal articles hal-00314103v1

[n]-Polyenovanillins (n = 1−6) as New Push−Pull Polyenes for Nonlinear Optics:  Synthesis, Structural Studies, and Experimental and Theoretical Investigation of Their Spectroscopic Properties, Electronic Structures, and Quadratic Hyperpolarizabilities

Thierry Brotin , Chantal Andraud , Isabelle Ledoux , Sophie Brasselet , Joseph Zyss
Chemistry of Materials, 1996, 8 (4), pp.890-906. ⟨10.1021/cm9504899⟩
Journal articles hal-01322807v1

Theoretical and experimental investigations of the nonlinear optical properties of vanillin, polyenovanillin, and bisvanillin derivatives

Chantal Andraud , Thierry Brotin , C. Garcia , C. Pelle , Ph. Goldner
Journal of the American Chemical Society, 1994, 116, pp.2094-2102
Journal articles hal-00005952v1

Theoretical and experimental investigations of the nonlinear optical properties of vanillin, polyenovanillin, and bisvanillin derivatives

Chantal Andraud , Thierry Brotin , Chantal Garcia , Fabrienne Pelle , Philippe Goldner
Journal of the American Chemical Society, 1994, 116 (5), pp.2094-2102. ⟨10.1021/ja00084a055⟩
Journal articles hal-01322811v1

Toward new cryptophane analogs: synthesis and encapsulation properties of an unprecedented water-soluble azacryptophane

Rajaa Benchouaia , Martin Doll , Patrick Berthault , Kevin Chighine , Estelle Léonce
3rd French Supramolecular Chemistry Congress Supr@Paris2024, May 2024, Paris, France
Conference papers hal-04584742v1

Toward new cryptophane analogs: synthesis and encapsulation properties of an amphoteric azacryptophane

Rajaa Benchouaia , Martin Doll , T. Brotin , Nicolas De Rycke
Journées de Chimie Supramoléculaire (JCS) 2023, Jun 2023, Montpellier, France
Conference papers hal-04548556v1

CHIRAL ISOTOPOLOGUES OF CRYPTOPHANE-B: SYNTHESIS AND CHIROPTICAL PROPERTIES

T. Brotin , Nicolas Daugey , Nicolas Vanthuyne , Marion Jean , Erwann Jeanneau
Journées André collet de la chirality, Patrick Rosa; Reiko Oda; Elisabeth Hillard; Valérie Blanchet; François Riobe, Oct 2022, Biarritz, France
Conference papers hal-04270560v1

Syn and Anti Tris-Azacryptophanes: From Chiroptical Studies to Unpredictable Xe@Cryptophane Complexes Physical Properties

Martin Doll , T. Brotin , Nicolas De Rycke
4th SEEDS4CD virtual seminar, Mar 2021, Virtual conference, France
Conference papers hal-04548565v1

Are the physical properties of Xe@Cryptophane complexes easily predictable? The case of the syn and anti Tris-azacryptophanes

Martin Doll , Patrick Berthault , Estelle Léonce , Céline Boutin , Thierry Buffeteau
Journées de Chimie du Groupe de Recherche (GDR) Chirafun, Jeanne Crassous, Apr 2021, Virtual conference, France
Conference papers hal-04548598v1

Chiroptical Properties of Enantiopure Cryptophane Derivatives

T. Brotin
16th International Conference on Chiroptical Spectroscopy, Jun 2017, Rennes, France
Conference papers hal-02103506v1

Understanding the Unusual Properties of the cryptophane-222 skeleton

T. Brotin
Chirality 2016, Jul 2016, Heildeberg, Germany
Conference papers hal-02103501v1

A Structurally Modified Cryptophane and Its Applications for cation Encapsulation

T. Brotin , Laure-Lise Chapellet , Emma Gendre
Journées André collet de la Chiralité, Oct 2015, LYON, France
Conference papers hal-02103443v1

Xenon@cryptophane Complexes as New Contrast Agents for Resonance Magnetic Imaging

T. Brotin
e-COST event "Spin Hyperpolarization in NMR and MRI", Jun 2014, Zurich, Switzerland
Conference papers hal-02103468v1

Dernières avancées sur l'utilisation du xénon polarisé comme biosonde

Céline Boutin , Estelle Léonce , Emilie Mari , Guillaume Carret , Emmanuelle Dubost
GERM 2014 (Groupe d’Etude de Résonance Magnétique), Jun 2014, Biarritz, France
Conference papers cea-02361804v1

Application of microscopic models of chirality to second harmonic reflection

Marie-Claire Schanne-Klein , H. Mesnil , François Hache , Thierry Brotin , M. Alexandre
Novel organic material and technological advances for photonics : Proceedings of Symposium R of the 2001 E-MRS Spring Conference, Jun 2001, Strasbourg, France. pp.63-66, ⟨10.1016/S0379-6779(01)00594-X⟩
Conference papers hal-00845234v1

Toward new cryptophane analogs: Synthesis and encapsulation properties of an amphoteric azacryptophane

Rajaa Benchouaia , Martin Doll , T. Brotin , Nicolas De Rycke
Chimie Macrocyclique et Supramoléculaire (MACS) RSC2023, Dec 2023, Birmingham, United Kingdom
Conference poster hal-04548541v1

Enantioselective Recognition of Chiral Epoxide Derivatives by an Enantiopure Cryptophane in Water

Nicolas de Rycke , T. Brotin , Nicolas Vanthuyne , Marion Jean
Journées André Collet 2018, Sep 2018, Noirmoutier, France
Conference poster hal-02103313v1

Hydrocamic Acid Functionalized Cryptophane for Xe-based Biosensing Applications

T. Brotin , Orsola Baydoun , Nicolas de Rycke
Supr@Lyon, Dec 2018, LYON, France
Conference poster hal-02103436v1
Image document

Accurate determination of pH via hyperpolarized $^{129}$Xe NMR

Estelle Léonce , Thierry Brotin , Jean-Pierre Dognon , Patrick Berthault
39th FGMR Annual Discussion Meeting, Sep 2017, Bayreuth, Germany
Conference poster cea-02341010v1

Chiroptical Properties of 2,2’-Bisoxirane.

T. Brotin , Nicolas Daugey , Nicolas de Rycke , Thierry Buffeteau
16th International Conference on Chiroptical Spectroscopy, Jun 2017, Rennes, France
Conference poster hal-02103496v1

Enantioselective complexation of Chiral Epoxide Derivatives by an Enantiopure Cryptophane in Water.

T. Brotin , Nicolas de Rycke , Nicolas Vanthuyne , Marion Jean
16th International Conference on Chiroptical Spectroscopy, Jun 2017, Rennes, France
Conference poster hal-02103500v1

Enantioselective Recognition of Chiral Epoxide Derivatives by an Enantiopure Cryptophane in Water

Nicolas de Rycke , Nicolas Vanthuyne , Marion Jean , T. Brotin
16th International Conference on Chiroptical Spectroscopy - CD2017, Jun 2017, Rennes, France
Conference poster hal-02103325v1

Chiroptical properties of nona and Dodecamethoxy cryptophanes

T. Brotin , Nicolas Vanthuyne , Dominique Cavagnat , Laurent Ducasse , Thierry Buffeteau
Journées André Collet de la Chiralité, Oct 2015, LYON, France
Conference poster hal-02103449v1

Molecular Recognition of Caesium and thallium Cations by Enantiopure Cryptophanes.

T. Brotin , Patrick Berthault , Jean-Pierre Dognon , Dominique Cavagnat , Nicolas Vanthuyne
ISMCS-2015. The International Symposium on Macrocyclic and Supramolecular Chemistry, Jul 2015, Strasbourg, France
Conference poster hal-02103486v1

A doubly responsive probe for the detection of Cys4-tagged proteins

Emilie Mari , Naoko Kotera , Emmanuelle Dubost , Gaëlle Milanole , Eric Doris
International Symposium XeMAT 2015, Sep 2015, Dresden, Germany
Conference poster cea-02356699v1

Chiroptical Properties of Nona and Dodecamethoxy Cryptophanes.

T. Brotin , Nicolas Daugey , Dominique Cavagnat , Nicolas Vanthuyne , Thierry Buffeteau
Journées André Collet de la Chiralité, Oct 2015, LYON, France
Conference poster hal-02103492v1