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Yann Sarazin

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Barium phosphidoboranes and related calcium complexes

Gabriel Dunes , Peter M. Chapple , Samia Kahlal , Thierry Roisnel , Jean-François Carpentier
Dalton Transactions, 2024, 53 (16), pp.6892-6905. ⟨10.1039/d4dt00487f⟩
Journal articles hal-04570681v1
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Iron(II)-Catalyzed Activation of Si–N and Si–O Bonds Using Hydroboranes

Mirela A. Farcaş-Johnson , Danila Gasperini , Andrew K. King , Sakshi Mohan , Adam N. Barrett
Organometallics, 2023, 42 (20), pp.3013-3024. ⟨10.1021/acs.organomet.3c00339⟩
Journal articles hal-04261558v1
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Lithium fluoroarylsilylamides and their structural features

Sakshi Mohan , Yahya Al Ayi , Savarithai Jenani Louis Anandaraj , Marie Cordier , Thierry Roisnel
Main Group Metal Chemistry, 2023, 46 (1), pp.20230012. ⟨10.1515/mgmc-2023-0012⟩
Journal articles hal-04149132v1
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Lateral Deprotometallation-Trapping Reactions on Methylated Pyridines, Quinolines and Quinoxalines Using Lithium Diethylamide

Mohamed Hasyeoui , Peter M. Chapple , Frédéric Lassagne , Thierry Roisnel , Marie Cordier
European Journal of Organic Chemistry, In press, ⟨10.1002/ejoc.202300555⟩
Journal articles hal-04193393v1
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Heteroleptic carbazolato-barium hydroborates and a related separated ion pair

Peter.M. Chapple , Thierry Roisnel , Marie Cordier , Jean-François Carpentier , Yann Sarazin
Polyhedron, 2022, 217, pp.115731. ⟨10.1016/j.poly.2022.115731⟩
Journal articles hal-03607938v1
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Bonding in Barium Boryloxides, Siloxides, Phenoxides and Silazides. A comparison with the lighter alkaline earths

Erwann Le Coz , Joanna Hammoud , Thierry Roisnel , Marie Cordier , Vincent Dorcet
Chemistry - A European Journal, 2021, 27 (46), pp.11966-11982. ⟨10.1002/chem.202101687⟩
Journal articles hal-03282741v1
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Bonding analysis in ytterbium(II) distannyl and related tetryls

Peter M Chapple , Julien Cartron , Ghanem Hamdoun , Marie Cordier , Samia Kahlal
Dalton Transactions, 2021, 50 (40), pp.14273-14284. ⟨10.1039/d1dt02355a⟩
Journal articles hal-03369223v1
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Bis(imino)carbazolate lead(II) fluoride and related halides

Peter M Chapple , Ghanem Hamdoun , Thierry Roisnel , Jean-François Carpentier , Hassan Oulyadi
Dalton Transactions, 2021, 50 (26), pp.9021-9025. ⟨10.1039/d1dt01615f⟩
Journal articles hal-03282745v1
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Metal-metal bonded alkaline-earth distannyls

Peter M. Chapple , Julien Cartron , Ghanem Hamdoun , Samia Kahlal , Marie Cordier
Chemical Science, 2021, 12 (20), pp.7098-7114. ⟨10.1039/d1sc00436k⟩
Journal articles hal-03245118v1
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Modular Synthesis of 9,10-Dihydroacridines through an ortho-C Alkenylation/Hydroarylation Sequence between Anilines and Aryl Alkynes in Hexafluoroisopropanol

Shengdong Wang , Guillaume Force , Jean-François Carpentier , Yann Sarazin , Christophe Bour
Organic Letters, 2021, 23 (7), pp.2565-2570. ⟨10.1021/acs.orglett.1c00487⟩
Journal articles hal-03245060v1
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Contemporary Molecular Barium Chemistry

Peter M. Chapple , Yann Sarazin
European Journal of Inorganic Chemistry, 2020, 2020 (35), pp.3321-3346. ⟨10.1002/ejic.202000501⟩
Journal articles hal-02928609v1
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A versatile nitrogen ligand for alkaline-earth chemistry

Peter M. Chapple , Marie Cordier , Vincent Dorcet , Thierry Roisnel , Jean-François Carpentier
Dalton Transactions, 2020, 49 (34), pp.11878-11889. ⟨10.1039/d0dt02236e⟩
Journal articles hal-02930349v1
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Synthesis of Bridged Tetrahydrobenzo[b]azepines and Derivatives through an Aza-Piancatelli Cyclization/Michael Addition Sequence

Shengdong Wang , Régis Guillot , Jean-François Carpentier , Yann Sarazin , Christophe Bour
Angewandte Chemie International Edition, 2020, 59 (3), pp.1134-1138. ⟨10.1002/anie.201911761⟩
Journal articles hal-02438534v1
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Bis(imino)carbazolate a master key for barium chemistry

Peter Chapple , Samia Kahlal , Julien Cartron , Thierry Roisnel , Vincent Dorcet
Angewandte Chemie International Edition, 2020, 59 (23), pp.9120-9126. ⟨10.1002/anie.202001439⟩
Journal articles hal-02498789v1
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Barium-catalysed dehydrocoupling of hydrosilanes and borinic acids: A mechanistic insight

Erwann Le Coz , Ziyun Zhang , Thierry Roisnel , Luigi Cavallo , Laura Falivene
Chemistry - A European Journal, 2020, 26 (16), pp.3535-3544. ⟨10.1002/chem.201904933⟩
Journal articles hal-02397300v1
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Lewis Acid/Hexafluoroisopropanol: A Promoter System for Selective ortho-C-Alkylation of Anilines with Deactivated Styrene Derivatives and Unactivated Alkenes

Shengdong Wang , Guillaume Force , Régis Guillot , Jean-François Carpentier , Yann Sarazin
ACS Catalysis, 2020, 10 (18), pp.10794-10802. ⟨10.1021/acscatal.0c02959⟩
Journal articles hal-02961178v1
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Alkaline-earth complexes with macrocyclic-functionalised bis(phenolate)s and bis(fluoroalkoxide)s

Joanna Hammoud , Fatima Abou-Khalil , Thierry Roisnel , Vincent Dorcet , Christophe Bour
Dalton Transactions, 2020, 49 (37), pp.13017-13028. ⟨10.1039/d0dt02573a⟩
Journal articles hal-02959795v1
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Lead(II) siloxides

Adrian-Alexandru Someșan , Erwann Le Coz , Ciprian I. Rat , Vincent Dorcet , Thierry Roisnel
Chemistry - A European Journal, 2019, 25 (71), pp.16236-16240. ⟨10.1002/chem.201904713⟩
Journal articles hal-02325636v1
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Barium siloxides and catalysed formation of Si-O-Si' motifs

Erwann Le Coz , Samia Kahlal , Jean-Yves Saillard , Thierry Roisnel , Vincent Dorcet
Chemistry - A European Journal, 2019, 25 (59), pp.13509-13513. ⟨10.1002/chem.201903676⟩
Journal articles hal-02280837v1
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Metal···F-C bonding in low-coordinate alkaline-earth fluoroarylamides

Yann Sarazin , Hanieh Roueindeji , Antsa Ratsifitahina , Thierry Roisnel , Vincent Dorcet
Chemistry - A European Journal, 2019, 25 (37), pp.8854-8864. ⟨10.1002/chem.201901262⟩
Journal articles hal-02120747v1
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Aminofluoroalkoxide amido and boryloxo lead(ii) complexes

Adrian-Alexandru Someşan , Thierry Roisnel , Vincent Dorcet , Cristian Silvestru , Yann Sarazin
Dalton Transactions, 2019, 48 (27), pp.9944-9948. ⟨10.1039/c9dt02110h⟩
Journal articles hal-02179649v1
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Heterobimetallic Ba/Li and Ca/Li amides and diphenylmethanide

Erwann Le Coz , Hanieh Roueindeji , Vincent Dorcet , Thierry Roisnel , Jean-François Carpentier
Dalton Transactions, 2019, 48 (17), pp.5500-5504. ⟨10.1039/c9dt00771g⟩
Journal articles hal-02120741v1
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Barium complexes with crown-ether-functionalised amidinate and iminoanilide ligands for the hydrophosphination of vinylarenes

Erwann Le Coz , Hanieh Roueindeji , Thierry Roisnel , Vincent Dorcet , Jean-François Carpentier
Dalton Transactions, 2019, 48 (25), pp.9173-9180. ⟨10.1039/c9dt01512d⟩
Journal articles hal-02150460v1
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Secondary interactions - Cement in trinuclear calcium complexes

Sorin-Claudiu Rosca , Vincent Dorcet , Jean-François Carpentier , Yann Sarazin
Inorganica Chimica Acta, 2018, 475, pp.59-64. ⟨10.1016/j.ica.2017.08.038⟩
Journal articles hal-01771100v1
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Low-Coordinate Barium Boryloxides: Synthesis and Dehydrocoupling Catalysis for the Production of Borasiloxanes

Erwann Le Coz , Vincent Dorcet , Thierry Roisnel , Sven Tobisch , J-F Carpentier
Angewandte Chemie International Edition, 2018, 57 (36), pp.11747-11751. ⟨10.1002/anie.201807297⟩
Journal articles hal-01862088v1
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Stable lead(II) boroxides

Adrian-Alexandru Somesan , Erwann Le Coz , Thierry Roisnel , Cristian Silvestru , Yann Sarazin
Chemical Communications, 2018, 54 (42), pp.5299-5302. ⟨10.1039/c8cc02459f⟩
Journal articles hal-01866167v1
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Heteroleptic lead(II)-halide complexes supported by a bulky iminoanilide ligand

Clément Bellini , Jean-François Carpentier , Vincent Dorcet , Anca Silvestru , Yann Sarazin
Main Group Metal Chemistry, 2017, 40 (3-4), pp.2515 - 2515. ⟨10.1515/mgmc-2017-0033⟩
Journal articles hal-01612237v1
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Tethered cationic alkaline earth – olefin complexes

Sorin-Claudiu Roşca , Vincent Dorcet , Thierry Roisnel , Jean-François Carpentier , Yann Sarazin
Dalton Transactions, 2017, 46 (43), pp.14785-14794. ⟨10.1039/C7DT03300A⟩
Journal articles hal-01620399v1
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Cadmium complexes bearing Me2N^E^O− (E = S, Se) organochalcogenoalkoxides and their zinc and mercury analogues

Alexandra Pop , Clément Bellini , Răzvan Șuteu , Vincent Dorcet , Thierry Roisnel
Dalton Transactions, 2017, 2017, 46 (10), pp.3179-3191. ⟨10.1039/C7DT00279C⟩
Journal articles hal-01469209v1
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π Ligands in Alkaline Earth Complexes

Sorin-Claudiu Roşca , Elsa Caytan , Vincent Dorcet , Thierry Roisnel , Jean-François Carpentier
Organometallics, 2017, 36 (7), pp.1269 - 1277. ⟨10.1021/acs.organomet.7b00006⟩
Journal articles hal-01500530v1
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K+···Cπ and K+···F Non-Covalent Interactions in π-Functionalized Potassium Fluoroalkoxides

Sorin-Claudiu Roşca , Hanieh Roueindeji , Vincent Dorcet , Thierry Roisnel , Jean-François Carpentier
Inorganics, 2017, 5 (1), pp.13. ⟨10.3390/inorganics5010013⟩
Journal articles hal-01517485v1

Alkaline Earth-Olefin Complexes with Secondary Interactions

Sorin-Claudiu Roşca , Chiara Dinoi , Elsa Caytan , Vincent Dorcet , Michel Etienne
Chemistry - A European Journal, 2016, 22 (19), pp.6505-6509. ⟨10.1002/chem.201601096⟩
Journal articles hal-01290444v1
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Tailored Cyclic and Linear Polycarbosilazanes by Barium-Catalyzed N−H/H−Si Dehydrocoupling Reactions

Clément Bellini , Clément Orione , Jean-François Carpentier , Yann Sarazin
Angewandte Chemie International Edition, 2016, 55 (11), pp.3744 - 3748. ⟨10.1002/anie.201511342⟩
Journal articles hal-01274835v1

Alkali-Metal-Catalyzed Cross-Dehydrogenative Couplings of Hydrosilanes with Amines

Srinivas Anga , Yann Sarazin , Jean-François Carpentier , Tarun K. Panda
ChemCatChem, 2016, 8 (7), pp.1373 - 1378. ⟨10.1002/cctc.201501356⟩
Journal articles hal-01295515v1
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Amino Ether-Phenolato Precatalysts of Divalent Rare Earths and Alkaline Earths for the Single and Double Hydrophosphination of Activated Alkenes

Ivan V. Basalov , Bo Liu , Thierry Roisnel , Anton V. Cherkasov , Georgy K. Fukin
Organometallics, 2016, 35 (19), pp.3261--3271. ⟨10.1021/acs.organomet.6b00252⟩
Journal articles hal-01395478v1

Calcium complexes with imino-phosphinanilido chalcogenide ligands for heterofunctionalisation catalysis

Srinivas Anga , Jean-François Carpentier , Tarun K. Panda , Thierry Roisnel , Yann Sarazin
RSC Advances, 2016, 6 (63), pp.57835--57843. ⟨10.1039/c6ra13117d⟩
Journal articles hal-01357393v1
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Sequential Barium-Catalysed N−H/H−Si Dehydrogenative Cross-Couplings: Cyclodisilazanes versus Linear Oligosilazanes

Clément Bellini , Thierry Roisnel , Jean-François Carpentier , Sven Tobisch , Yann Sarazin
Chemistry - A European Journal, 2016, 22 (44), pp.15733 - 15743. ⟨10.1002/chem.201603191⟩
Journal articles hal-01398042v1

Aluminium, gallium and indium complexes supported by a chiral phenolato-prolinolato dianionic ligand

Nicolas Maudoux , Eric Tan , Yuya Hu , Thierry Roisnel , Vincent Dorcet
Main Group Metal Chemistry, 2016, 39 (5-6), pp.131--143. ⟨10.1515/mgmc-2016-0036⟩
Journal articles hal-01438117v1

Calcium, Strontium and Barium Homogeneous Catalysts for Fine Chemicals Synthesis

Yann Sarazin , Jean-François Carpentier
Chemical Record, 2016, 16 (6), pp.2482--2505. ⟨10.1002/tcr.201600067⟩
Journal articles hal-01438126v1
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Alkaline-Earth-Catalysed Cross-Dehydrocoupling of Amines and Hydrosilanes: Reactivity Trends, Scope and Mechanism

Clément Bellini , Vincent Dorcet , Jean-François Carpentier , Sven Tobisch , Yann Sarazin
Chemistry - A European Journal, 2016, 22 (13), pp.4564 - 4583. ⟨10.1002/chem.201504316⟩
Journal articles hal-01274113v1

Highly Active, Chemo- and Regioselective Yb II and Sm II Catalysts for the Hydrophosphination of Styrene with Phenylphosphine

Ivan V. Basalov , Vincent Dorcet , Georgy K. Fukin , Jean-François Carpentier , Yann Sarazin
Chemistry - A European Journal, 2015, 21 (16), pp.6033 - 6036. ⟨10.1002/chem.201500380⟩
Journal articles hal-01445120v1

Structure vs 119Sn NMR Chemical Shift in Three-Coordinated Tin(II) Complexes: Experimental Data and Predictive DFT Computations

Lingfang Wang , Christos E. Kefalidis , Thierry Roisnel , Sourisak Sinbandhit , Laurent Maron
Organometallics, 2015, 34 (11), pp.2139-2150. ⟨10.1021/om5007566⟩
Journal articles hal-01114324v1

Discrete Cationic Complexes for Ring-Opening Polymerization Catalysis of Cyclic Esters and Epoxides.

Yann Sarazin , Jean-Francois Carpentier
Chemical Reviews, 2015, 115 (9), pp.3564--3614. ⟨10.1021/acs.chemrev.5b00033⟩
Journal articles hal-01153409v1

Structurally Characterized Lead(II) Alkoxides as Potent Ring-Opening Polymerization Catalysts.

Lingfang Wang , Sami Fadlallah , Clement Bellini , Clement Orione , Vincent Dorcet
Organometallics, 2015, 34 (7), pp.1321--1327. ⟨10.1021/acs.organomet.5b00052⟩
Journal articles hal-01153428v1
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Barium-Mediated Cross-Dehydrocoupling of Hydrosilanes with Amines

Clément Bellini , Jean-François Carpentier , Sven Tobisch , Yann Sarazin
Angewandte Chemie International Edition, 2015, 54 (26), pp.7679 - 7683. ⟨10.1002/anie.201502956⟩
Journal articles hal-01158456v1

Highly fluorinated tris(indazolyl)borate silylamido complexes of the heavier alkaline earth metals: synthesis, characterization, and efficient catalytic intramolecular hydroamination.

Nuria Romero , Sorin-Claudiu Roşca , Yann Sarazin , Jean-François Carpentier , Laure Vendier
Chemistry - A European Journal, 2015, 21 (10), pp.4115-4125. ⟨10.1002/chem.201405454⟩
Journal articles hal-01141110v1

Beyond Stereoselectivity, Switchable Catalysis: Some of the Last Frontier Challenges in Ring-Opening Polymerization of Cyclic Esters

Sophie M. Guillaume , Evgueni Kirillov , Yann Sarazin , Jean-François Carpentier
Chemistry - A European Journal, 2015, 21 (22), pp.7988 - 8003. ⟨10.1002/chem.201500613⟩
Journal articles hal-01139818v1

On the coordination chemistry of organochalcogenolates RNMe2^E− and RNMe2^E^O− (E = S, Se) onto lead(II) and lighter divalent tetrel elements

Alexandra Pop , Lingfang Wang , Vincent Dorcet , Thierry Roisnel , Jean-François Carpentier
Dalton Transactions, 2014, 43 (43), pp.16459-16474. ⟨10.1039/C4DT02252A⟩
Journal articles hal-01121155v1

Aluminum, Indium, and Mixed Yttrium–Lithium Complexes Supported by a Chiral Binap-Based Fluorinated Dialkoxide: Structural Features and Heteroselective ROP of Lactide

Nicolas Maudoux , Thierry Roisnel , Jean-François Carpentier , Yann Sarazin
Organometallics, 2014, 33 (20), pp.5740-5748. ⟨10.1021/om500458g⟩
Journal articles hal-01114338v1

Erratum: ‘Aluminum, calcium and zinc complexes supported by potentially tridentate iminophenolate ligands: synthesis and use in the ring-opening polymerization of lactide’, Applied Organometallic Chemistry, v. 26, issue 12, December 2012, pages 681-688

Miloud Bouyhayi , Yann Sarazin , Osvaldo L Casagrande Jr , Jean-François Carpentier
Applied Organometallic Chemistry, 2014, 28 (2), pp.136--136. ⟨10.1002/aoc.3088⟩
Journal articles hal-01153811v1

Divalent Heteroleptic Ytterbium Complexes – Effective Catalysts for Intermolecular Styrene Hydrophosphination and Hydroamination

Ivan V. Basalov , Sorin-Claudiu Roşca , Dmitrii M. Lyubov , Alexander N. Selikhov , Georgy K. Fukin
Inorganic Chemistry, 2014, 53 (3), pp.1654-1661. ⟨10.1021/ic4027859⟩
Journal articles hal-01121211v1

Potassium and Well-Defined Neutral and Cationic Calcium Fluoroalkoxide Complexes: Structural Features and Reactivity

Sorin-Claudiu Roşca , Thierry Roisnel , Vincent Dorcet , Jean-François Carpentier , Yann Sarazin
Organometallics, 2014, 33 (20), pp.5630-5642. ⟨10.1021/om500343w⟩
Journal articles hal-01114341v1
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Kinetic Analysis of the Immortal Ring-Opening Polymerization of Cyclic Esters: A Case Study with Tin(II) Catalysts

Lingfang Wang , Valentin Poirier , Fabio Ghiotto , Manfred Bochmann , Roderick D. Cannon
Biomacromolecules, 2014, 47 (8), pp.2574-2584. ⟨10.1021/ma500124k⟩
Journal articles hal-01114346v1

Chiral (1,2)-diphenylethylene-salen complexes of triel metals: coordination patterns and mechanistic considerations in the isoselective ROP of lactide.

Nicolas Maudoux , Thierry Roisnel , Vincent Dorcet , Jean-François Carpentier , Yann Sarazin
Chemistry - A European Journal, 2014, 20 (20), pp.6131-47. ⟨10.1002/chem.201304788⟩
Journal articles hal-01114344v1

C(sp₃)-H bond activation with triel metals: indium and gallium zwitterions through internal hydride abstraction in rigid salan ligands.

Nicolas Maudoux , Jian Fang , Thierry Roisnel , Vincent Dorcet , Laurent Maron
Chemistry - A European Journal, 2014, 20 (25), pp.7706-17. ⟨10.1002/chem.201402358⟩
Journal articles hal-01114342v1

Cyclohydroamination of aminoalkenes catalyzed by disilazide alkaline-earth metal complexes : reactivity patterns and deactivation pathways.

Bo Liu , Thierry Roisnel , Jean-François Carpentier , Yann Sarazin
Chemistry - A European Journal, 2013, 19 (8), pp.2784-802. ⟨10.1002/chem.201203562⟩
Journal articles hal-00824658v1

Alkali aminoether-phenolate complexes: synthesis, structural characterization and evidence for an activated monomer ROP mechanism.

Sorin-Claudiu Roşca , Dragoş-Adrian Roşca , Vincent Dorcet , Christopher M. Kozak , Francesca M. Kerton
Dalton Transactions, 2013, 42 (25), pp.9361-75. ⟨10.1039/c2dt32726k⟩
Journal articles hal-00879943v1

Heteroleptic Tin(II) Initiators for the Ring-Opening (Co)Polymerization of Lactide and Trimethylene Carbonate: Mechanistic Insights from Experiments and Computations.

Lingfang Wang , Christos E. Kefalidis , Sourisak Sinbandhit , Vincent Dorcet , Jean-Francois Carpentier
Chemistry - A European Journal, 2013, 19, pp.13463--13478. ⟨10.1002/chem.201301751⟩
Journal articles hal-01069851v1

Diamido-Ether Actinide Complexes as Initiators for Lactide Ring-Opening Polymerization

Cassandra E. Hayes , Yann Sarazin , Michael Katz , Jean-François Carpentier , Daniel B. Leznoff
Organometallics, 2013, 32 (5), pp.1183-1192. ⟨10.1021/om300993r⟩
Journal articles hal-00879957v1

Kinetic Analysis of the Living Ring-Opening Polymerisation of L-Lactide with Tin-(II) Initiators.

Lingfang Wang , Manfred Bochmann , Roderick D. Cannon , Jean-Francois Carpentier , Thierry Roisnel
European Journal of Inorganic Chemistry, 2013, 2013, pp.5896--5905. ⟨10.1002/ejic.201300964⟩
Journal articles hal-01069854v1

Discrete divalent rare-earth cationic ROP catalysts : ligand-dependent redox behavior and discrepancies with alkaline-earth analogues in a ligand-assisted activated monomer mechanism.

Bo Liu , Thierry Roisnel , Laurent Maron , Jean-François Carpentier , Yann Sarazin
Chemistry - A European Journal, 2013, 19 (12), pp.3986-94. ⟨10.1002/chem.201204340⟩
Journal articles hal-00824594v1
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Stable divalent germanium, tin and lead amino(ether)-phenolate monomeric complexes: structural features, inclusion heterobimetallic complexes, and ROP catalysis

Lingfang Wang , Sorin-Claudiu Roşca , Valentin Poirier , Sourisak Sinbandhit , Vincent Dorcet
Dalton Transactions, 2013, 43 (11), pp.4268 - 4286. ⟨10.1039/c3dt51681d⟩
Journal articles hal-00860197v1

Heteroleptic alkyl and amide iminoanilide alkaline earth and divalent rare earth complexes for the catalysis of hydrophosphination and (cyclo)hydroamination reactions.

Bo Liu , Thierry Roisnel , Jean-François Carpentier , Yann Sarazin
Chemistry - A European Journal, 2013, 19 (40), pp.13445-62. ⟨10.1002/chem.201301464⟩
Journal articles hal-00881408v1

Allyl strontium compounds: synthesis, molecular structure and properties.

Phillip Jochmann , Julien P Davin , Stefanie Maslek , Thomas P Spaniol , Yann Sarazin
Dalton Transactions, 2012, 41 (30), pp.9176-81. ⟨10.1039/c2dt30743j⟩
Journal articles hal-00805345v1

Highly effective alkaline earth catalysts for the sterically governed hydrophosphonylation of aldehydes and nonactivated ketones.

Bo Liu , Jean-François Carpentier , Yann Sarazin
Chemistry - A European Journal, 2012, 18 (42), pp.13259-64. ⟨10.1002/chem.201201489⟩
Journal articles hal-00805346v1

Aluminum, Calcium and Zinc Complexes Supported by Potentially Tridentate Imino-Phenolate Ligands: Synthesis and Use in the Ring-Opening Polymerization of Lactide

Miloud Bouyhayi , Yann Sarazin , Osvaldo L. Casagrande Jr , Jean-François Carpentier
Applied Organometallic Chemistry, 2012, 26 (12), pp.681-688. ⟨10.1002/aoc.2909⟩
Journal articles hal-00874218v1

Heteroleptic silylamido phenolate complexes of calcium and the larger alkaline earth metals: β-agostic Ae⋅⋅⋅Si-H stabilization and activity in the ring-opening polymerization of L-lactide.

Bo Liu , Thierry Roisnel , Jean-Paul Guégan , Jean-François Carpentier , Yann Sarazin
Chemistry - A European Journal, 2012, 18 (20), pp.6289-301. ⟨10.1002/chem.201103666⟩
Journal articles hal-00805319v1

Well-Defined, Solvent-Free Cationic Barium Complexes: Synthetic Strategies and Catalytic Activity in the Ring-Opening Polymerization of Lactide

Bo Liu , Thierry Roisnel , Yann Sarazin
Inorganica Chimica Acta, 2012, 380, pp.2-13. ⟨10.1016/j.ica.2011.09.020⟩
Journal articles hal-00872412v1

β-Diketiminate alkaline-earth cationic complexes: synthesis, structures, lactide polymerization and unusual oxidative reactivity of the ancillary ligand

Bo Liu , Vincent Dorcet , Laurent Maron , Jean-François Carpentier , Yann Sarazin
European Journal of Inorganic Chemistry, 2012, 2012 (18), pp.3023-3031. ⟨10.1002/ejic.201200183⟩
Journal articles hal-00874211v1
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When bigger is better: intermolecular hydrofunctionalizations of activated alkenes catalyzed by heteroleptic alkaline earth complexes.

Bo Liu , Thierry Roisnel , Jean-François Carpentier , Yann Sarazin
Angewandte Chemie International Edition, 2012, 51 (20), pp.4943-6. ⟨10.1002/anie.201200364⟩
Journal articles hal-00805321v1

Synthetic and mechanistic aspects of the immortal ring-opening polymerization of lactide and trimethylene carbonate with new homo- and heteroleptic tin(II)-phenolate catalysts.

Valentin Poirier , Thierry Roisnel , Sourisak Sinbandhit , Manfred Bochmann , Jean-François Carpentier
Chemistry - A European Journal, 2012, 18 (10), pp.2998-3013. ⟨10.1002/chem.201102261⟩
Journal articles hal-00805312v1

Isoselective Styrene Polymerization Catalyzed by ansa-Bis(indenyl) Allyl Rare Earth Complexes. Stereochemical and Mechanistic Aspects

Liana Annunziata , Anne-Sophie Rodrigues , Evgeny Kirillov , Yann Sarazin , Jun Okuda
Macromolecules, 2011, 44 (9), pp.3312-3322. ⟨10.1021/ma2003757⟩
Journal articles hal-00632223v1

Discrete, solvent-free alkaline-earth metal cations: metal***fluorine interactions and ROP catalytic activity.

Yann Sarazin , Bo Liu , Thierry Roisnel , Laurent Maron , Jean-François Carpentier
Journal of the American Chemical Society, 2011, 133 (23), pp.9069-87. ⟨10.1021/ja2024977⟩
Journal articles hal-00632235v1

Well-defined syndiotactic polystyrene-b-atactic polystyrene stereoblock polymers.

Liana Annunziata , Yann Sarazin , Michel Duc , Jean-François Carpentier
Macromolecular Rapid Communications, 2011, 32 (9-10), pp.751-7. ⟨10.1002/marc.201100072⟩
Journal articles hal-00632220v1

Zinc and magnesium complexes supported by bulky multidentate amino-ether phenolate ligands: potent pre-catalysts for the immortal ring-opening polymerisation of cyclic esters.

Valentin Poirier , Thierry Roisnel , Jean-François Carpentier , Yann Sarazin
Dalton Transactions, 2011, 40 (2), pp.523-34. ⟨10.1039/c0dt01219j⟩
Journal articles hal-00632108v1

Syndio- and Isoselective Coordinative Chain Transfer Polymerization of Styrene Promoted by ansa-Lanthanidocene/ Dialkylmagnesium Systems

Yann Sarazin , Pierre de Frémont , Liana Annunziata , Michel Duc , Jean-François Carpentier
Advanced Synthesis and Catalysis, 2011, 535 (8), pp.1367-1374. ⟨10.1002/adsc.201100059⟩
Journal articles hal-00632216v1

Discrete Base-Free Cationic Alkaline-Earth Complexes: Access and Catalytic Activity in the Polymerization of Lactide

Yann Sarazin , Valentin Poirier , Thierry Roisnel , Jean-François Carpentier
European Journal of Inorganic Chemistry, 2010, 2010 (22), pp.3423-3428. ⟨10.1002/ejic.201000558⟩
Journal articles hal-00576877v1

Discrete Allyl Complexes of Group 3 Metals and Lanthanides

Jean-François Carpentier , Sophie M. Guillaume , Evgueni Kirillov , Yann Sarazin
Comptes Rendus. Chimie, 2010, 13 (6-7), pp.608-625. ⟨10.1016/j.crci.2009.12.008⟩
Journal articles hal-00576860v1

Metal-Catalyzed Immortal Ring-Opening Polymerization of Lactones, Lactides and Cyclic Carbonates

Noureddine Ajellal , Jean-François Carpentier , Clémence Guillaume , Sophie M. Guillaume , Marion Helou
Dalton Transactions, 2010, 39 (36), pp.8363-8376. ⟨10.1039/C001226B⟩
Journal articles hal-00576871v1

Water-tolerant Catalyst Systems for the Bulk Cationic Polymerization of para-Methylstyrene and Indene

Jérôme Vergnaud , Yann Sarazin , Henri Strub , Jean-François Carpentier
European Polymer Journal, 2010, 46 (5), pp.1093-1099. ⟨10.1016/j.eurpolymj.2010.01.014⟩
Journal articles hal-00497847v1

One-Pot Synthesis of Lactide-Styrene Diblock Copolymers via Catalytic Immortal Ring-Opening Polymerization of Lactide and Nitroxide-Mediated Polymerization of Styrene

Valentin Poirier , Michel Duc , Jean-François Carpentier , Yann Sarazin
ChemSusChem, 2010, 3 (5), pp.579-590. ⟨10.1002/cssc.201000021⟩
Journal articles hal-00497860v1

Bis(dimethylsilyl)amide complexes of the alkaline-earth metals stabilized by β-Si-H agostic interactions: synthesis, characterization, and catalytic activity

Yann Sarazin , D. Roşca , Valentin Poirier , Thierry Roisnel , A. Silvestru
Organometallics, 2010, 29 (23), pp.6569-6577. ⟨10.1021/om100908q⟩
Journal articles hal-00589178v1

Versatile Catalytic Systems Based on Complexes of Zinc, Magnesium and Calcium Supported by a Bulky Bis(Morpholinomethyl)Phenoxy Ligand for the Large-Scale Immortal Ring-Opening Polymerisation of Cyclic Esters

V. Poirier , Thierry Roisnel , Jean-François Carpentier , Yann Sarazin
Dalton Transactions, 2009, pp.9820-9827. ⟨10.1039/b917799j⟩
Journal articles hal-00448594v1

On the Initiation Mechanism of Syndiospecific Styrene Polymerization Catalyzed by Single-Component ansa -Lanthanidocenes

Lionel Perrin , Yann Sarazin , Evgueni Kirillov , Jean-François Carpentier , Laurent Maron
Chemistry - A European Journal, 2009, 15 (15), pp.3773 - 3783. ⟨10.1002/chem.200802036⟩
Journal articles hal-00411131v1

Synthesis and structures of new binuclear zinc alkyl, aryl and aryloxo complexes

Yann Sarazin , Joseph A. Wright , Duncan A.J. Harding , Eddy Martin , Timothy J. Woodman
Journal of Organometallic Chemistry, 2008, 693 (8-9), pp.1494 - 1501. ⟨10.1016/j.jorganchem.2007.10.043⟩
Journal articles hal-01445066v1

Mixed-ligand iminopyrrolato-salicylaldiminato group 4 metal complexes: Optimising catalyst structure for ethylene/propylene copolymerisations

Lewis M. Broomfield , Yann Sarazin , Joseph A. Wright , David L. Hughes , William Clegg
Journal of Organometallic Chemistry, 2007, 692 (21), pp.4603 - 4611. ⟨10.1016/j.jorganchem.2007.04.047⟩
Journal articles hal-01445060v1

Thallium(I) Sandwich, Multidecker, and Ether Complexes Stabilized by Weakly-Coordinating Anions: A Spectroscopic, Structural, and Theoretical Investigation

Yann Sarazin , David L. Hughes , Nikolas Kaltsoyannis , Joseph A. Wright , Manfred Bochmann
Journal of the American Chemical Society, 2007, 129 (4), pp.881 - 894. ⟨10.1021/ja0657105⟩
Journal articles hal-01445054v1

Mono(arene) Complexes of Thallium(I) Supported by a Weakly Coordinating Anion

Yann Sarazin , Nikolas Kaltsoyannis , Joseph A. Wright , Manfred Bochmann
Organometallics, 2007, 26 (7), pp.1811 - 1815. ⟨10.1021/om061154b⟩
Journal articles hal-01445055v1

Cationic Brønsted Acids for the Preparation of SnIV Salts: Synthesis and Characterisation of [Ph3Sn(OEt2)][H2N{B(C6F5)3}2],[Sn(NMe2)3(HNMe2)2][B(C6F5)4] and [Me3Sn(HNMe2)2][B(C6F5)4]

Yann Sarazin , Simon J. Coles , David L. Hughes , Michael B. Hursthouse , Manfred Bochmann
European Journal of Inorganic Chemistry, 2006, 2006 (16), pp.3211 - 3220. ⟨10.1002/ejic.200600397⟩
Journal articles hal-01445044v1

Titanium, zinc and alkaline-earth metal complexes supported by bulky O,N,N,O-multidentate ligands: syntheses, characterisation and activity in cyclic esterpolymerisation

Yann Sarazin , Ruth H. Howard , David L. Hughes , Simon M. Humphrey , Manfred Bochmann
Dalton Transactions, 2006, pp.340 - 350. ⟨10.1039/b511851d⟩
Journal articles hal-01444985v1

Synthesis and crystal structure of [C6H5Hg(H2NSiMe3)][H2N{B(C6F5)3}2], a phenyl–mercury(II) cation stabilised by a non-coordinating counter-anion

Yann Sarazin , Joseph A. Wright , Manfred Bochmann
Journal of Organometallic Chemistry, 2006, 691 (26), pp.5680 - 5687. ⟨10.1016/j.jorganchem.2006.09.021⟩
Journal articles hal-01445049v1

Copolymerization of Propene and 5-Vinyl-2-Norbornene: A Simple Route to Polar Poly(propylene)s

Yann Sarazin , Gerhard Fink , Klaus Hauschild , Manfred Bochmann
Macromolecular Rapid Communications, 2005, 26 (15), pp.1208 - 1213. ⟨10.1002/marc.200500241⟩
Journal articles hal-01444978v1

Heterogenized “Ligand-Free” Lanthanide Catalysts for the Homo- and Copolymerization of Ethylene and 1,3-Butadiene

Timothy J. Woodman , Yann Sarazin , Gerhard Fink , Klaus Hauschild , Manfred Bochmann
Macromolecules, 2005, 38 (8), pp.3060 - 3067. ⟨10.1021/ma047454r⟩
Journal articles hal-01444966v1

Binary cerium(IV) tert-butoxides-dialkylmagnesium systems: Radical versus coordinative polymerization of styrene

Yann Sarazin , Thomas Chenal , André Mortreux , Hervé Vezin , Jean-François Carpentier
Journal of Molecular Catalysis A: Chemical, 2005, 238 (1-2), pp.207 - 214. ⟨10.1016/j.molcata.2005.05.025⟩
Journal articles hal-01444982v1

Chromium allyl and alkyl catalysts for the vinyl polymerization of norbornene and ethylene–norbornene copolymerizations

Timothy J. Woodman , Yann Sarazin , Shaun Garratt , Gerhard Fink , Manfred Bochmann
Journal of Molecular Catalysis A: Chemical, 2005, 235 (1-2), pp.88 - 97. ⟨10.1016/j.molcata.2005.03.017⟩
Journal articles hal-01444971v1

Synthesis and structure of [Cp2Zr(OPri)(HOPri)]+ and its activity in the polymerisation of propene oxide

Elaine Farrow , Yann Sarazin , David L. Hughes , Manfred Bochmann
Journal of Organometallic Chemistry, 2004, 689 (24), pp.4624 - 4629. ⟨10.1016/j.jorganchem.2004.07.012⟩
Journal articles hal-01444961v1

Novel Zinc and Magnesium Alkyl and Amido Cations for Ring-Opening Polymerization Reactions

Yann Sarazin , Mark Schormann , Manfred Bochmann
Organometallics, 2004, 23, pp.3296-3302. ⟨10.1021/om0497691⟩
Journal articles hal-01444938v1

Molecular s-Block Catalysts for Alkene Hydrophosphination and Related Reactions

Yann Sarazin , Jean-Francois Carpentier
Harder, S. Early Main Group Metal Catalysis: Concepts and Reactions, WILEY-V C H VERLAG GMBH, pp.93-121, 2020, 978-3-527-81801-3; 978-3-527-34448-2. ⟨10.1002/9783527818020.ch4⟩
Book sections hal-03367733v1

CHAPTER 4 Secondary (Agostic Si-H/Electrostatic C-F) interactions in alkaline earth-based catalysts

Yann Sarazin , J.-F. Carpentier
Noncovalent Interactions in Catalysis, 2019-January (37), Royal Society of Chemistry, pp.94-121, 2019, 9781788017237. ⟨10.1039/9781788016490-00094⟩
Book sections hal-02122160v1

Metal Phenolates as Polymerization Catalysts

Jean-François Carpentier , Evgeny Kirillov , Yann Sarazin
Metal Phenolates. Patai's Chemistry of Functional Groups, John Wiley & Sons, 2013, ⟨10.1002/9780470682531.pat0606⟩
Book sections hal-00881567v1

Alkaline-Earth Metal Complexes in Homogeneous Polymerization Catalysis

Jean-François Carpentier , Yann Sarazin
Sjoerd Harder. Alkaline-Earth Metal Compounds, Springer Berlin Heidelberg, pp.141-189, 2013, Topics in Organometallic Chemistry, 978-3-642-36269-9. ⟨10.1007/978-3-642-36270-5_5⟩
Book sections hal-00881542v1

Charge-Neutral and Cationic Complexes of Large Alkaline Earths for Ring-Opening Polymerization and Fine Chemicals Catalysis

Jean-François Carpentier , Bo Liu , Yann Sarazin
Armando J. L. Pombeiro. Advances in Organometallic Chemistry and Catalysis: The Silver/Gold Jubilee International Conference on Organometallic Chemistry Celebratory Book, John Wiley & Sons, pp.359-378, 2013, 978111851018. ⟨10.1002/9781118742952.ch28⟩
Book sections hal-00881556v1