Nicolas BLANCHARD

81
Documents

Présentation

Nicolas Blanchard studied chemistry at Paris 6 university and at the Ecole Normale Supérieure in Paris. He received his Ph.D. from the J. Cossy's laboratory in 2000. After postdoctoral studies with J.F. Nomant (Paris 6 University) and W. Roush (Michigan University, USA), he joined the CNRS as Chargé de Recherche in 2002 and became Directeur de Recherche in 2013. He is the head of the "Biomolecules, Synthesis and Methods" team within the LIMA laboratory (unistra-uha-cnrs). Since September 2021, Nicolas is a member of CoNRS Section 12 “Molecular architectures: synthesis, mechanisms and properties” (2021-2025 term, acting as president). Since January 2022, he is deputy director of the LIMA. Current research interests of Nicolas' group encompass the development of synthetic processes including metal-mediated transformations, pericyclic reactions and the synthesis of bioactive natural products with a focus on Mycobacterium ulcerans toxins, mycolactones. Nicolas received the "Advanced researcher award" of the French Chemical Society (2016), the "Distinguished Junior Membership" of the French Chemical Society (2015-2018), the "Syngenta Chemistry Lectureship" (2015), the "Guy Ourisson Award" (2014) and the "Bronze medal of the CNRS" (2012).

Publications

Publications

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Homolytic Photocleavage of the B–N Bond in N-Heterocyclic Carbene Borane Scaffolds: Towards Efficient Type I Photoinitiators

Sofia Telitel , Nicolas Blanchard , Bernadette Graff , Jacques Lalevée , Emmanuel Lacôte
Synthesis: Journal of Synthetic Organic Chemistry, In press, ⟨10.1055/s-0043-1773518⟩
Article dans une revue hal-04975615 v1
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Recent Advances in the Chemistry and Application of SF<sub>5</sub>-Compounds

Mariam Abd El Sater , Nicolas Blanchard , Vincent Bizet , Lucas Popek
Synthesis: Journal of Synthetic Organic Chemistry, In press, ⟨10.1055/a-2383-6620⟩
Article dans une revue (article de synthèse) hal-04759144 v1
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Palladium‐Catalyzed Regioselective Synthesis of 2‐SF 5 ‐Indenols and Further Derivatizations

Lucas Popek , Murat Cihan , Nicolas Blanchard , Vincent Bizet
Angewandte Chemie International Edition, 2024, ⟨10.1002/anie.202315909⟩
Article dans une revue hal-04757412 v1

Synthesis of Pentafluorosulfanylated Ynamides and Further Functionalizations

Lucas Popek , Gauthier Lefebvre , Vincent Debrauwer , David Roubaud , Nicolas Blanchard et al.
Organic Letters, 2024, 26 (48), pp.10369-10375. ⟨10.1021/acs.orglett.4c03972⟩
Article dans une revue hal-04975519 v1
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Synthesis of N -Alkyl Substituted Benzimidazoquinazolinones

Gaurav G Dake , Nicolas Blanchard , Krishna P Kaliappan
Article dans une revue hal-04666610 v1
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Expanding Radical Chloropentafluorosulfanylation of Alkynes

Thi Mo Nguyen , Lucas Popek , David Matchavariani , Nicolas Blanchard , Vincent Bizet et al.
Organic Letters, 2024, 26 (1), pp.365-369. ⟨10.1021/acs.orglett.3c04043⟩
Article dans une revue hal-04631759 v1
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Ambiphilic Reactivity of SF<sub>5</sub>‐Alkynes Applied to Regioselective and Stereodivergent Halogenation Reactions: An Experimental and Theoretical Case Study

David Matchavariani , Lucas Popek , Jorge Cabrera-Trujillo , Thi Mo Nguyen , Nicolas Blanchard et al.
Advanced Synthesis and Catalysis, 2024, 366 (16), pp.3481-3493. ⟨10.1002/adsc.202400446⟩
Article dans une revue hal-04606248 v1
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Tracking SF5I in the Iodopentafluorosulfanylation of Alkynes

Thi Mo Nguyen , Claude Legault , Nicolas Blanchard , Vincent Bizet , Dominique Cahard
Chemistry - A European Journal, 2023, ⟨10.1002/chem.202302914⟩
Article dans une revue hal-04234753 v1
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Regio‐ and Stereoselective Hydroelementation of SF5‐Alkynes and Further Functionalizations

Lucas Popek , Jorge Cabrera-Trujillo , Vincent Debrauwer , Nicolas Blanchard , Karinne Miqueu et al.
Angewandte Chemie International Edition, 2023, 62 (19), pp.e202300685. ⟨10.1002/anie.202300685⟩
Article dans une revue hal-04022814 v1
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Copper-Catalyzed, Ligand-Controlled N(sp3)- or N(sp)-Selective Arylation of Cyanamides

Jiaqi Fang , Oumaïma Bekkouch , Guilhem Zeiser , Yurii Zubchuk , Vincent Bizet et al.
Organic Letters, 2023, 25 (34), pp.6446-6451. ⟨10.1021/acs.orglett.3c02622⟩
Article dans une revue hal-04264724 v1
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A common mechanism of Sec61 translocon inhibition by small molecules

Samuel Itskanov , Laurie Wang , Tina Junne , Rumi Sherriff , Li Xiao et al.
Nature Chemical Biology, 2023, 19 (9), pp.1063-1071. ⟨10.1038/s41589-023-01337-y⟩
Article dans une revue hal-04262928 v1
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Ring-closing enyne metathesis of allylic and propargylic cyanamides

Jiaqi Fang , Sébastien Van Laethem , Nicolas Blanchard , Gwilherm Evano
ARKIVOC - Online Journal of Organic Chemistry, 2023, 2024 (2), pp.202312098. ⟨10.24820/ark.5550190.p012.098⟩
Article dans une revue hal-04666617 v1
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Divergent Synthesis of 6- or 7-Aza-Indazoles via Intramolecular Diels–Alder Cascade of Pyrazines

Nicolas Brach , Lucas Popek , Mathieu Truong , Claire Laurent , Vincent Bizet et al.
Organic Letters, In press, ⟨10.1021/acs.orglett.3c03052⟩
Article dans une revue hal-04262921 v1
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Radical Cyclization of Ynamides to Nitrogen Heterocycles

Chunyang Zhang , Nicolas Blanchard , Gwilherm Evano
Synthesis: Journal of Synthetic Organic Chemistry, 2022, ⟨10.1055/a-1868-8092⟩
Article dans une revue hal-03795794 v1
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Synthesis and further use of SF5 -alkynes as platforms for the design of more complex SF5 -containing products

Lucas Popek , Thi Mo Nguyen , Nicolas Blanchard , Dominique Cahard , Vincent Bizet
Tetrahedron, 2022, 117-118, pp.132814. ⟨10.1016/j.tet.2022.132814⟩
Article dans une revue hal-03717188 v1
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Molecular Mechanisms Underpinning the Circulation and Cellular Uptake of Mycobacterium ulcerans Toxin Mycolactone

Bruno Tello Rubio , Florence Bugault , Blandine Baudon , Bertrand Raynal , Sébastien Brûlé et al.
Frontiers in Pharmacology, 2021, 12, pp.733496. ⟨10.3389/fphar.2021.733496⟩
Article dans une revue hal-03358263 v1
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Synthesis and Physicochemical Properties of 2-SF5-(Aza)Indoles, a New Family of SF5 Heterocycles

Vincent Bizet , Vincent Debrauwer , Ivo Leito , Märt Lokov , Sofja Tshepelevitsh et al.
ACS Organic & Inorganic Au, In press, ⟨10.1021/acsorginorgau.1c00010⟩
Article dans une revue hal-03357583 v1
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Spatiotemporal analysis of mycolactone distribution in vivo reveals partial diffusion in the central nervous system

Emma Colucci-Guyon , Aline Rifflet , Sarah Saint-Auret , Anaëlle da Costa , Laurent Boucontet et al.
PLoS Neglected Tropical Diseases, 2020, 14 (12), pp.e0008878. ⟨10.1371/journal.pntd.0008878⟩
Article dans une revue pasteur-03046953 v1
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DABCO‐promoted Diaryl Thioether Formation by Metal‐catalyzed Coupling of Sodium Sulfinates and Aryl Iodides

Yanpeng Liu , Long Yin Lam , Jiqing Ye , Nicolas Blanchard , Cong Ma
Advanced Synthesis and Catalysis, 2020, 362 (12), pp.2326-2331. ⟨10.1002/adsc.202000221⟩
Article dans une revue hal-02991822 v1
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Optimized Synthesis of 7-Azaindazole by a Diels–Alder Cascade and Associated Process Safety

Nicolas Brach , Vincent Le Fouler , Vincent Bizet , Marian Lanz , Fabrice Gallou et al.
Organic Process Research and Development, 2020, 24 (5), pp.776-786. ⟨10.1021/acs.oprd.0c00184⟩
Article dans une revue hal-02991836 v1
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Ligand-Controlled Regiodivergent Palladium-Catalyzed Hydrogermylation of Ynamides

Vincent Debrauwer , Aneta Turlik , Lénaic Rummler , Alessandro Prescimone , Nicolas Blanchard et al.
Journal of the American Chemical Society, 2020, 142 (25), pp.11153-11164. ⟨10.1021/jacs.0c03556⟩
Article dans une revue hal-02868667 v1

Ruthenium-catalyzed ring-opening reaction of a 3-aza-2-oxabicyclo[2.2.1]hept-5-ene with amines — an unexpected mode of ring-opening

Katrina Tait , Samuel Koh , Nicolas Blanchard , William Tam
Canadian Journal of Chemistry, 2019, 97 (4), pp.310-316. ⟨10.1139/cjc-2018-0444⟩
Article dans une revue hal-02323304 v1
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Ipomoeassin F Binds Sec61α to Inhibit Protein Translocation

Guanghui Zong , Zhijian Hu , Sarah O’keefe , Dale Tranter , Michael Iannotti et al.
Journal of the American Chemical Society, 2019, 141 (21), pp.8450-8461. ⟨10.1021/jacs.8b13506⟩
Article dans une revue hal-02323236 v1
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Nusbiarylins, a new class of antimicrobial agents: Rational design of bacterial transcription inhibitors targeting the interaction between the NusB and NusE proteins

Yangyi Qiu , Shu Ting Chan , Lin Lin , Tsun Lam Shek , Tsz Fung Tsang et al.
Bioorganic Chemistry, 2019, 92, pp.103203. ⟨10.1016/j.bioorg.2019.103203⟩
Article dans une revue hal-02323331 v1
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Acid Fluorides in Transition-Metal Catalysis: A Good Balance between Stability and Reactivity

Vincent Bizet , Nicolas Blanchard
Angewandte Chemie International Edition, 2019, 58 (21), pp.6814-6817. ⟨10.1002/anie.201900591⟩
Article dans une revue hal-02289563 v1
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Activating Pyrimidines by Pre-distortion for the General Synthesis of 7-Aza-indazoles from 2-Hydrazonylpyrimidines via Intramolecular Diels–Alder Reactions

Vincent Le Fouler , Yu Chen , Vincent Gandon , Vincent Bizet , Christophe Salomé et al.
Journal of the American Chemical Society, 2019, 141 (40), pp.15901-15909. ⟨10.1021/jacs.9b07037⟩
Article dans une revue hal-02323378 v1

Discussion Addendum for: Synthesis of Ynamides by Copper-Mediated Coupling of 1,1-Dibromo-1-alkenes with Nitrogen Nucleophiles. Preparation of 4-Methyl-N-(2-phenylethynyl)-N-(phenylmethyl)benzenesulfonamide

Cédric Theunissen , Pierre Thilmany , Mounsef Lahboubi , Nicolas Blanchard , Gwilherm Evano
Organic Syntheses : An annual publication of satisfactory methods for the preparation of organic chemicals, 2019, 96, pp.195-213. ⟨10.15227/orgsyn.096.0195⟩
Article dans une revue hal-02323280 v1
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Design, Synthesis and Biological Evaluation of Antimicrobial Diarylimine and -amine Compounds Targeting the Interaction between the Bacterial NusB and NusE Proteins

Yangyi Qiu , Shu Ting Chan , Lin Lin , Tsun Lam Shek , Tsz Fung Tsang et al.
European Journal of Medicinal Chemistry, 2019, 178, pp.214-231. ⟨10.1016/j.ejmech.2019.05.090⟩
Article dans une revue hal-03079069 v1
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Recombinant Antibodies against Mycolactone

Leslie Naranjo , Fortunato Ferrara , Nicolas Blanchard , Caroline Demangel , Sara D’angelo et al.
Toxins, 2019, 11 (6), pp.346. ⟨10.3390/toxins11060346⟩
Article dans une revue hal-02323359 v1

Novel applications of fluorescent brighteners in aqueous visible-light photopolymerization: high performance water-based coating and LED-assisted hydrogel synthesis

X Zuo , Fabrice Morlet-Savary , M Schmitt , D Nouën , Nicolas Blanchard et al.
Polymer Chemistry, 2018, 9 (28), pp.3952-3958. ⟨10.1039/C8PY00584B⟩
Article dans une revue hal-02168643 v1

Copper-mediated synthesis of N-vinyl ynamides from N-vinyl carbamates

Vincent Le Fouler , Guillaume Duret , Philippe Bisseret , Nicolas Blanchard
Tetrahedron Letters, 2018, 59 (36), pp.3349-3352. ⟨10.1016/j.tetlet.2018.07.053⟩
Article dans une revue hal-02159670 v1
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Aryl transition metal chemical warheads for protein bioconjugation

Philippe Bisseret , H Abdelkafi , Nicolas Blanchard
Chemical Science, 2018, 9, pp.5132-5144. ⟨10.1039/C8SC00780B⟩
Article dans une revue hal-02153059 v1

Acid-catalyzed ring-opening reactions of a cyclopropanated 3-aza-2-oxabicyclo[2.2.1]hept-5-ene with alcohols

K Tait , A Horvath , Nicolas Blanchard , W Tam
Beilstein Journal of Organic Chemistry, 2017, 13, pp.2888-2894. ⟨10.3762/bjoc.13.281⟩
Article dans une revue hal-02153056 v1

Synthetic strategies towards mycolactone A/B, an exotoxin secreted by Mycobacterium ulcerans

Sarah Saint-Auret , H Abdelkafi , D Nouen , Philippe Bisseret , Nicolas Blanchard
Organic Chemistry Frontiers, 2017, 4, pp.2380-2386. ⟨10.1039/C7QO00608J⟩
Article dans une revue hal-02153057 v1
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Intramolecular inverse electron-demand [4+2] cycloadditions of ynamidyl-tethered pyrimidines: Comparative studies in trifluorotoluene and sulfolane

Morgan Donnard , Guillaume Duret , Philippe Bisseret , Nicolas Blanchard
Comptes Rendus. Chimie, 2017, 20 (6), pp.643-647. ⟨10.1016/j.crci.2017.01.007⟩
Article dans une revue hal-02105042 v1

Total Syntheses of Mycolactone A/B and its Analogues for the Exploration of the Biology of Buruli Ulcer

Sarah Saint-Auret , Anne-Caroline Chany , Virginie Casarotto , Cédric Tresse , Lise Parmentier et al.
CHIMIA, 2017, 71 (12), ⟨10.2533/chimia.2017.836⟩
Article dans une revue hal-02166539 v1

Intramolecular Inverse Electron-Demand [4+2] Cycloadditions of Ynamides with Pyrimidines: Scope and DFT Insights

Guillaume Duret , R Quinlan , B Yin , R Martin , Philippe Bisseret et al.
Journal of Organic Chemistry, 2017, 82, pp.1726-1742. ⟨10.1021/acs.joc.6b02986⟩
Article dans une revue hal-02161657 v1

Diels-Alder and Formal Diels-Alder Cycloaddition Reactions of Ynamines and Ynamides

Guillaume Duret , Vincent Le Fouler , Philippe Bisseret , Vincent Bizet , Nicolas Blanchard
European Journal of Organic Chemistry, 2017, ⟨10.1002/ejoc.201700986⟩
Article dans une revue hal-02161658 v1

Modular total syntheses of mycolactone A/B and its [ 2 H]- isotopologue

Sarah Saint-Auret , Hajer Abdelkafi , Didier Le Nouen , Laure Guenin-Macé , Caroline Demangel et al.
Organic & Biomolecular Chemistry, 2017, 15, pp.7518-7522. ⟨10.1039/C7OB01943B⟩
Article dans une revue pasteur-01666631 v1

Fluorescent Brighteners as Visible LED-Light Sensitive Photoinitiators for Free Radical Photopolymerizations

Xiaoling Zuo , Fabrice Morlet-Savary , Bernadette Graff , Nicolas Blanchard , Jean-Philippe Goddard et al.
Macromolecular Rapid Communications, 2016, 37 (10), pp.840-844. ⟨10.1002/marc.201600103⟩
Article dans une revue istex hal-04081790 v1

A Journey in the Chemistry of Ynamides: From Synthesis to Applications

Gwilherm Evano , Nicolas Blanchard , Guillaume Compain , Alexis Coste , Charles Demmer et al.
Chemistry Letters, 2016, 45 (6), pp.574-585. ⟨10.1246/cl.160260⟩
Article dans une revue hal-03007853 v1

A Straightforward Entry to γ-Trifluoromethylated Allenamides and Their Synthetic Applications

Céline Guissart , Aymeric Dolbois , Cédric Tresse , Sarah Saint-Auret , Gwilherm Evano et al.
SYNLETT, 2016, 27 (18), pp.2575-2580. ⟨10.1055/s-0035-1562518⟩
Article dans une revue hal-04601397 v1

Stereodivergent Hydrosilylation, Hydrostannylation, and Hydrogermylation of α-Trifluoromethylated Alkynes and Their Synthetic Applications

Cédric Tresse , Stéphane Schweizer , Philippe Bisseret , Jacques Lalevée , Gwilherm Evano et al.
Synthesis: Journal of Synthetic Organic Chemistry, 2016, 48 (19), pp.3317-3330. ⟨10.1055/s-0035-1561487⟩
Article dans une revue hal-04259242 v1
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Mycolactone subverts immunity by selectively blocking the Sec61 translocon.

Ludivine Baron , Anja Onerva Paatero , Jean-David Morel , Francis Impens , Laure Guenin-Macé et al.
Journal of Experimental Medicine, 2016, 213 (13), pp.2885-2896. ⟨10.1084/jem.20160662⟩
Article dans une revue pasteur-01432024 v1
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Shaping mycolactone for therapeutic use against inflammatory disorders

Laure Guenin-Mace , Ludivine Baron , Anne-Caroline Chany , Cédric Tresse , Sarah Saint-Auret et al.
Science Translational Medicine, 2015, 7 (289), pp.289ra85 - 289ra85. ⟨10.1126/scitranslmed.aab0458⟩
Article dans une revue pasteur-01382767 v1
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Boron chemistry in a new light

Guillaume Duret , Robert Quinlan , Philippe Bisseret , Nicolas Blanchard
Chemical Science, 2015, 6 (10), pp.5366-5382. ⟨10.1039/c5sc02207j⟩
Article dans une revue hal-05017297 v1
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Stereodivergent Hydrogermylations of α-Trifluoromethylated Alkynes and Their Applications in Cross-Coupling Reactions

Stéphane Schweizer , Cédric Tresse , Philippe Bisseret , Jacques Lalevée , Gwilherm Evano et al.
Organic Letters, 2015, 17 (7), pp.1794-1797. ⟨10.1021/acs.orglett.5b00579⟩
Article dans une revue hal-05017008 v1

Sonogashira reactions for the synthesis of polarized pentacene derivatives

Stéphane Schweizer , Guillaume Erbland , Philippe Bisseret , Jacques Lalevee , Didier Le Nouën et al.
Turkish Journal of Chemistry, 2015, 39 (6), pp.1180-1189. ⟨10.3906/kim-1505-117⟩
Article dans une revue hal-04259241 v1

Synthetic Variants of Mycolactone Bind and Activate Wiskott–Aldrich Syndrome Proteins

Anne-Caroline Chany , Romain Veyron-Churlet , Cédric Tresse , Véronique Mayau , Virginie Casarotto et al.
Journal of Medicinal Chemistry, 2014, 57 (17), pp.7382 - 7395. ⟨10.1021/jm5008819⟩
Article dans une revue pasteur-03320888 v1

Soft Photopolymerizations Initiated by Dye-Sensitized Formation of NHC-Boryl Radicals under Visible Light

Sofia Telitel , Stéphane Schweizer , Fabrice Morlet-Savary , Bernadette Graff , Théophile Tschamber et al.
Macromolecules, 2013, 46 (1), pp.43-48. ⟨10.1021/ma302009p⟩
Article dans une revue hal-00799223 v1

BODIPY derivatives and boranil as new photoinitiating systems of cationic polymerization exhibiting a tunable absorption in the 400–600 nm spectral range

Sofia Telitel , Nicolas Blanchard , Stéphane Schweizer , Fabrice Morlet-Savary , Bernadette Graff et al.
Polymer, 2013, 54 (8), pp.2071-2076. ⟨10.1016/j.polymer.2013.02.013⟩
Article dans une revue istex hal-04392000 v1

Iridium Photocatalysts in Free Radical Photopolymerization under Visible Lights

Jacques Lalevée , Mohamad Ali Tehfe , Frédéric Dumur , Didier Gigmes , Nicolas Blanchard et al.
ACS Macro Letters, 2012, 1, pp.286−290. ⟨10.1021/mz2001753⟩
Article dans une revue hal-01020217 v1

Photopolymerization of Cationic Monomers and Acrylate/Divinylether Blends under Visible Light Using Pyrromethene Dyes

Sofia Telitel , Jacques Lalevee , Nicolas Blanchard , Tuba Kavalli , Mohamad-Ali Tehfe et al.
Macromolecules, 2012, 45 (17), pp.6864-6868. ⟨10.1021/ma301293m⟩
Article dans une revue hal-04234058 v1

Photoredox Catalysis for Polymerization Reactions

Jacques Lalevée , Mohamad Ali Tehfe , Fabrice Morlet-Savary , Bernadette Graff , Frédéric Dumur et al.
CHIMIA, 2012, 66, pp.439-441. ⟨10.2533/chimia.2012.439⟩
Article dans une revue hal-01020212 v1

Tunable Organophotocatalysts for Polymerization Reactions Under Visible Lights

Mohamad-Ali Tehfe , Jacques Lalevee , Fabrice Morlet-Savary , Bernadette Graff , Nicolas Blanchard et al.
Macromolecules, 2012, 45 (4), pp.1746-1752. ⟨10.1021/ma300050n⟩
Article dans une revue hal-04288252 v1

Subtle Ligand Effects in Oxidative Photocatalysis with Iridium Complexes: Application to Photopolymerization

Jacques Lalevée , Mathieu Peter , Frédéric Dumur , Didier Gigmes , Nicolas Blanchard et al.
Chemistry - A European Journal, 2011, 17, pp.15027 - 15031. ⟨10.1002/chem.201101445⟩
Article dans une revue istex hal-01020222 v1

A Novel Photopolymerization Initiating System Based on an Iridium Complex Photocatalyst

Jacques Lalevee , Nicolas Blanchard , Mohamad-Ali Tehfe , Mathieu Peter , Fabrice Morlet-Savary et al.
Macromolecular Rapid Communications, 2011, 32 (12), pp.917-920. ⟨10.1002/marc.201100098⟩
Article dans une revue istex hal-04042064 v1

A Diverted Total Synthesis of Mycolactone Analogues: An Insight into Buruli Ulcer Toxins

Anne-Caroline Chany , Virginie Casarotto , Marjorie Schmitt , Céline Tarnus , Laure Guenin-Macé et al.
Chemistry - A European Journal, 2011, 17 (51), pp.14413-14419. ⟨10.1002/chem.201102542⟩
Article dans une revue istex hal-02128753 v1

Tandem Cationic and Sol-Gel Photopolymerizations of a Vinyl Ether Alkoxysilane

Abraham Chemtob , Cindy Belon , Celine Croutxe-Barghorn , Séverinne Rigolet , Loïc Vidal et al.
Polymer Engineering and Science, 2011, 51 (8), pp.1466-1475. ⟨10.1002/pen.21951⟩
Article dans une revue hal-04241841 v1

Decatungstate (W10O324-)/Silane: A New and Promising Radical Source Under Soft Light Irradiation

Jacques Lalevée , Nicolas Blanchard , Mohamad-Ali Tehfe , Jean Pierre Fouassier
Macromolecular Rapid Communications, 2011, 32 (11), pp.838-843. ⟨10.1002/marc.201100099⟩
Article dans une revue istex hal-04042076 v1

Household LED irradiation under air: cationic polymerization using iridium or ruthenium complex photocatalysts

Jacques Lalevee , Nicolas Blanchard , Mohamad Tehfe , Mathieu Peter , Fabrice Morlet-Savary et al.
Polymer Bulletin, 2011, 68, pp.341-347. ⟨10.1007/s00289-011-0541-9⟩
Article dans une revue istex hal-04247063 v1

Reaction between aminoalkyl radicals and akyl halides: Dehalogenation by electron transfer?

Jacques Lalevee , J.P. Fouassier , Nicolas Blanchard , Keith U. Ingold
Chemical Physics Letters, 2011, 511 (1-3), pp.156-158. ⟨10.1016/j.cplett.2011.05.055⟩
Article dans une revue istex hal-04234026 v1

Controlled synthesis of branched poly(vinyl acetate) s by xanthate-mediated RAFT self-condensing vinyl (co)polymerization

Julien Schmitt , Nicolas Blanchard , Julien Poly
Polymer Chemistry, 2011, 2 (10), pp.2231-2238. ⟨10.1039/c1py00231g⟩
Article dans une revue hal-04471933 v1

Efficient dual radical/cationic photoinitiator under visible light: a new concept

Jacques Lalevée , Nicolas Blanchard , Mohamad-Ali Tehfe , Mathieu Peter , Fabrice Morlet-Savary et al.
Polymer Chemistry, 2011, 2 (9), pp.1986--1991. ⟨10.1039/C1PY00140J⟩
Article dans une revue hal-01460319 v1

New thioxanthone and xanthone photoinitiators based on silyl radical chemistry

Jacques Lalevée , Nicolas Blanchard , Mohamad Ali Tehfe , Cédric Fries , Fabrice Morlet-Savary et al.
Polymer Chemistry, 2011, 2 (5), pp.1077--1084. ⟨10.1039/C0PY00392A⟩
Article dans une revue hal-01460320 v1
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Silyloxyamines as Sources of Silyl Radicals: ESR Spin Trapping, Laser Flash Photolysis Investigation and Photopolymerization Ability

David-Louis Versace , Mohamad Ali Tehfe , Jacques Lalevée , Virginie Casarotto , Nicolas Blanchard et al.
Journal of Physical Organic Chemistry, 2010, 24 (4), pp.342. ⟨10.1002/poc.1762⟩
Article dans une revue istex hal-00599801 v1

Silyl radical chemistry and conventional photoinitiators: A route for the design of efficient systems

Jacques Lalevee , Nicolas Blanchard , Anne-Caroline Chany , Mohamad El Roz , R. Souane et al.
Mcromolecules, 2009, 42(16), pp.6031-6037
Article dans une revue hal-00422938 v1

Effect of Lewis base coordination on boryl radical reactivity: investigation using laser flash photolysis and kinetic ESR?

Jacques Lalevee , Nicolas Blanchard , Anne-Caroline Chany , M. Ali Tehfe , Xavier Allonas et al.
Journal of Physical Organic Chemistry, 2009, x, ⟨10.1002/poc.1549(2009)⟩
Article dans une revue hal-00408131 v1

Tris(trimethylsilyl)silyl versus tris(trimethylsilyl)germyl: radical reactivity and oxidation ability

Jacques Lalevee , Nicolas Blanchard , Bernadette Graff , Xavier Allonas , Jean-Pierre Fouassier
Journal of Organometallic Chemistry, 2008, 693, pp.3643-3649
Article dans une revue hal-00335788 v1

New Photoiniferters: Respective Role of the Initiating and Persistent Radicals

Jacques Lalevee , Nicolas Blanchard , Mohamad El Roz , Xavier Allonas , Jean-Pierre Fouassier
Macromolecules, 2008, 41 (7), pp.2347-2352
Article dans une revue hal-00292708 v1

New photoinitiators based on the silyl radical chemistry: polymerization ability, ESR spin trapping and laser flash photolysis investigation

Jacques Lalevee , Nicolas Blanchard , Mohamad El Roz , Bernadette Graff , Xavier Allonas et al.
Macromolecules, 2008, 41 (12), pp.4180-4186
Article dans une revue hal-00292718 v1
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Pericyclic reactions of ynamides

Lénaic Rummler , Nicolas Brach , Pierre Delmée , Logan Charton , Vincent Bizet et al.
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Copper-Catalyzed C-C Bond Formation in Natural Product Synthesis

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